Temporal trends in the stable isotope composition of precipitation: a comparison between the eastern Mediterranean and central Europe

Stable isotopes in precipitation are recognized as a major tool for tracking the water cycle. The development of gridded datasets is a solution to the need for high-resolution isotopic data. The lack of measurement though, dictates the use of ??long-term average?? isotopic values, usually, calculated from short time series, of unequal durations and, sometimes, not even referring to the same time period. Thus, the influence of possible trends, that might be present in the isotopic data, should be accounted for. In the present work, we investigated the existence of temporal trends in the isotopic composition of precipitation of central Europe and eastern Mediterranean. Nine stations were selected, having time series extending over at least a 20-year-long period and fulfilling certain data completeness criteria. Possible trends were detected for three overlapping 20-year periods (1961?C1980, 1971?C1990, and 1981?C2000) using linear regression, the Mann?CKendall test, and a partial Mann?CKendall test, to compensate for the influence of meteorological parameters. We found that very few cases present statistically significant trends. There is significant variability of the observed trends, both on a seasonal and on a station basis, in the central Europe and the eastern Mediterranean area alike. Overall, the insignificance of the observed isotopic trends, and the lack of any coherent spatial and temporal patterns, seems to be supporting the current practice for estimating the long-term average isotopic composition of precipitation.     

The effects of below-cloud aerosol on the acidification process of rain

Using a model of the acidification process of rain, we calculate and analyze the effects and contributions of a below-cloud aerosol in its different concentrations and acidities on the pH and ion components of rain (SO ₄ ^2– , H⁺, NO ₃ ^– , NH ₄ ⁺ , etc.) under the conditions of different concentrations of pollution gases. The results show that the aerosol has an acidification or alkalization effect on the rain which changes the pHs of rain and aerosol. As acidifying pollution gas concentrations (SO₂, HNO₃) are low, the acid aerosol has important effects on the pH and H⁺ of rain, but as the gas concentrations are high, the acid aerosol has very little effect. The alkalizing aerosol makes the pH of rain increase by between 0.3 and 0.5 and neutralizes about 60% of H⁺ in the rain. As alkalizing pollution gas NH₃ exists, the acid aerosol has important effects on the pH and H⁺ of rain. But the alkalizing aerosol has very little effect, especially as the NH₃ concentration is high. The percentage contribution of the aerosol to SO ₄ ^2– in rain is generally 7–15%, the contribution of the aerosol to NO ₃ ^– is nearly the same as that of HNO₃=1 ppb, and the contribution of the aerosol to NH ₄ ⁺ is nearly the same as that of NH₃, from 5 to 7 ppb, and is an important source of NH ₄ ⁺ in rain. Finally, according to the actual conditions of typical regions in the south and north of China (Chongqing and Beijing), we analyze the effects of aerosol and pollution gases on the ion components of rain.     

Spring-summer temperatures since AD 1780 reconstructed from stable oxygen isotope ratios in white spruce tree-rings from the Mackenzie Delta,northwestern Canada

High-latitude δ¹⁸O archives deriving from meteoric water (e.g., tree-rings and ice-cores) can provide valuable information on past temperature variability, but stationarity of temperature signals in these archives depends on the stability of moisture source/trajectory and precipitation seasonality, both of which can be affected by atmospheric circulation changes. A tree-ring δ¹⁸O record (AD 1780–2003) from the Mackenzie Delta is evaluated as a temperature proxy based on linear regression diagnostics. The primary source of moisture for this region is the North Pacific and, thus, North Pacific atmospheric circulation variability could potentially affect the tree-ring δ¹⁸O-temperature signal. Over the instrumental period (AD 1892–2003), tree-ring δ¹⁸O explained 29 % of interannual variability in April–July minimum temperatures, and the explained variability increases substantially at lower-frequencies. A split-period calibration/verification analysis found the δ¹⁸O-temperature relation was time-stable, which supported a temperature reconstruction back to AD 1780. The stability of the δ¹⁸O-temperature signal indirectly implies the study region is insensitive to North Pacific circulation effects, since North Pacific circulation was not constant over the calibration period. Simulations from the NASA-GISS ModelE isotope-enabled general circulation model confirm that meteoric δ¹⁸O and precipitation seasonality in the study region are likely insensitive to North Pacific circulation effects, highlighting the paleoclimatic value of tree-ring and possibly other δ¹⁸O records from this region. Our δ¹⁸O-based temperature reconstruction is the first of its kind in northwestern North America, and one of few worldwide, and provides a long-term context for evaluating recent climate warming in the Mackenzie Delta region.     

The cold event 8200 years ago documented in oxygen isotope records of precipitation in Europe and Greenland

 Stable oxygen isotope ratios of ostracod valves in Late Glacial and Holocene sediments of core AS 92-5 from deep lake Ammersee (southern Germany) reflect variations of mean oxygen isotope ratios in past atmospheric precipitation. The record reconfirms the strong similarity of climate evolution in Europe and Greenland during the last deglaciation. For the first time in Europe, we find a 200-year-long negative δ¹⁸O-excursion, which is contemporaneous with the strongest negative δ¹⁸O-excursion in the Greenland ice around 8.2 ky before present. The 8.2 ky isotopic event on both sides of the North Atlantic ocean is interpreted as a cold period, most probably induced by a perturbation of the North Atlantic thermohaline circulation. We discuss two possible triggering mechanisms: (1) weak forcing (as proposed by Alley et al.), and (2) forcing by a strong and sudden freshwater pulse from the collapse of the Hudson Ice Dome. Received: 27 May 1997 / Accepted: 21 July 1997     

A stable oxygen, but not carbon, isotope chronology of Callitris columellaris reflects recent climate change in north-western Australia

We investigated the dendroclimatic potential of stable carbon (δ¹³C) and oxygen (δ¹⁸O) abundances in tree rings of Callitris columellaris F. Muell. Tree-ring chronologies were constructed from the central Pilbara, north-western Australia and span 1919–1999. Variation in δ¹⁸O was more strongly related to climate than δ¹³C; ecological and physiological factors may have dampened the climate signal in the δ¹³C chronology. Tree-ring δ¹⁸O was most strongly correlated with relative humidity (RH) and rainfall (r = −0.36 and −0.39) of the wettest months of the summer period, January and February. The correlation with RH reflects its effect on evaporative enrichment of leaf water. However, tree-ring δ¹⁸O may also partly reflect the variability in ¹⁸O signatures of rainfall, which are influenced by the amount of rainfall and atmospheric humidity. From the δ¹⁸O chronology, we inferred that from 1919 to 1955 summers were relatively dry and warm, but since 1955, summers in the Pilbara region have become increasingly cooler and more humid. Since 1980, conditions have been the wettest and coolest of the last 80 years. These inferred changes in climate correspond to a measured increase in rainfall since 1980 in north-western Australia associated with a greater intensity of tropical cyclones. We conclude that δ¹⁸O abundances in tree rings of C. columellaris have significant potential for reconstructing the climate of semi-arid Australia, a region for which observational climate records are sparse.     

Simulating the hydrological response to predicted climate change on a watershed in southern Alberta, Canada

The current body of research in western North America indicates that water resources in southern Alberta are vulnerable to climate change impacts. The objective of this research was to parameterize and verify the ACRU agro-hydrological modeling system for a small watershed in southern Alberta and subsequently simulate the change in future hydrological responses over 30-year simulation periods. The ACRU model successfully simulated monthly streamflow volumes (r ²?=?0.78), based on daily simulations over 27 years. The delta downscaling technique was used to perturb the 1961?C1990 baseline climate record from a range of global climate model (GCM) projections to provide the input for future hydrological simulations. Five future hydrological regimes were compared to the 1961?C1990 baseline conditions to determine the average net effect of change scenarios on the hydrological regime of the Beaver Creek watershed over three 30-year time periods (starting in 2010, 2040 and 2070). The annual projections of a warmer and mostly wetter climate in this region resulted in a shift of the seasonal streamflow distribution with an increase in winter and spring streamflow volumes and a reduction of summer and fall streamflow volumes over all time periods, relative to the baseline conditions (1961?C1990), for four of the five scenarios. Simulations of actual evapotranspiration and mean annual runoff showed a slight increase, which was attributed to warmer winters, resulting in more winter runoff and snowmelt events.     

合肥市降水化学组成成分分析

为研究合肥市降水的化学组成成分,于2010年4—9月在合肥市国家基本气象站设立了采样点,进行降水的采集,对降水化学组成成分进行了测定,并系统分析了化学组成成分的特点。结果表明:合肥降水中阴离子主要为SO24-,阳离子主要为NH4+和Ca2+,[SO24-]/[NO3-]当量浓度比值范围为1.23～6.33,大部分样本的比值<3,说明酸雨类型以硝硫混合型为主。降水的酸度与单一离子当量浓度的相关性并不明显,应该是受多种离子综合影响的结果,SO24-与NO3-,Ca2+与Mg2+,NH4+与SO24-,NH4+与NO3-均表现出较好的相关性。     

Estimation of the results of the cumulonimbus cloud modification aiming at hailstorm mitigation in Alberta (Canada) on the radar and numerical modeling data

In this paper, physical effects caused by a crystallizing reagent in the deep stable cloud, which was developing on July 7, 2006 in Alberta, Canada, are analysed. The ultimate goal of that experiment was reducing economical losses caused by hail. The radar data analysis and numerical modeling showed that use of the reagent allowed significant reducing the hail particles size.     

The influence of the ocean on the chemistry of precipitation in Nova Scotia*

Abstract

Between the fall of 1977 and December 1980, over 800 samples of precipitation were collected at 9 rural locations across Nova Scotia.

Average pH was 4.61, and an average conductivity of 25 μS cm^?1 confirmed the low ionic strength of rain and snow. Of all ions, chloride was the most abundant at 76 μeq L^?1 (2.7 mg L^?1). Oceanic origins were perceived as the source for chloride as well as for Na, Mg, 51 % of K, 21% of Ca, and 21% of SO₄, and the sea collectively accounted for 66% of all ions inNova Scotian precipitation. In contrast, the dominating ions in New York, New Hampshire, Ontario and Norway were H⁺ and SO₄.

In Nova Scotia, chloride concentrations in rain (mg L^?1) are a function of distance D (km) from the coast and may be described by the equation Cl [mg L^?1] = 4.5D^?0.42. It indicates that Cl concentrations are reduced by about 50% within 0.5 km of the coast, and 80% within 5 km. The continental North American chloride data examined are also consistent with the relationship.

The shape of the chloride curve is similar to curves others have developed from rain and lake water chemistry observations in Holland and the United Kingdom, although those, and other European data, indicate that the marine influence is less pronounced in northeastern North America.

The marine influence of precipitation chemistry on Nova Scotia has a maximum seasonal amplitude during the winter.     

降水对气溶胶粒子清除的参数化

本文主要讨论了碰并系数、雨滴谱和气溶胶谱对湿清除率的影响.在0.1μm相似文献   

The influence of precipitation intensity growth on the urban drainage systems designing

For 50 years of long observation period (1960–2009), on a high level of statistical significance (95 %), a decreasing trend of annual precipitation amounts and an increasing trend of the number of rainy days during the year (64 %) were found. For the seasonal changes (V–X), similarly, there was found a statistically significant (94 %) decreasing precipitation amount trend and an increasing trend of the number of rainy days (50 %). As far as the intensity of maximum precipitation is concerned, a very statistically significant increasing trend (95 %) was found. Taking as the basis, the model for a trend, defined for the period of 1960–2009, the increase of weighted average interval values of maximum precipitation amounts (h?≥?0.75?t ^0.5) in the year 2059 was estimated to be about 26 %, in comparison with the starting year 1960. An increasing trend of maximum precipitation frequency in Wroc?aw was also proved. To a safe sewerage systems designing in Wroc?aw according to current standards (EN 752 2008; DWA-A118 2006), the precipitation frequency to the simulations of excessive accumulation occurrences to the land level should be changed.     

Numerical experiments on the impacts of surface evaporation and fractionation factors on stable isotopes in precipitation

The isotope enabled atmospheric water balance model is applied to examine the spatial and temporal variations of δ¹⁸O in precipitation, amount effect and meteoric water lines (MWL) under four scenarios with different fractionation nature and surface evaporation inputs. The experiments are conducted under the same weather forcing in the framework of the water balance and stable water isotope balance. Globally, the spatial patterns of mean δ¹⁸O and global MWLs simulated by four simulation tests are in reasonably good agreement with the Global Network of Isotopes in Precipitation observations. The results indicate that the assumptions of equilibrium fractionation for simulating spatial distribution in mean annual δ¹⁸O and the global MWL, and kinetic fractionation in simulating δ¹⁸O seasonality are acceptable. In Changsha, four simulation tests all reproduce the observed seasonal variations of δ¹⁸O in precipitation. Compared with equilibrium fractionation, the depleted degree of stable isotopes in precipitation is enhanced under kinetic fractionation, in company with a decrease of isotopic seasonality and inter-event variability. The alteration of stable isotopes in precipitation caused by the seasonal variation of stable isotopes in vapour evaporated from the surface is opposite between cold and warm seasons. Four simulations all produce the amount effect commonly observed in monsoon areas. Under kinetic fractionation, the slope of simulated amount effect is closer to the observed one than other scenarios. The MWL for warm and humid climate in monsoon areas are well simulated too. The slopes and intercepts of the simulated MWLs decrease under kinetic fractionation.