冀东唐杖子金(钼)多金属矿区侵入岩体锆石U-Pb年龄、Hf同位素特征及其地质意义

唐杖子金(钼)多金属矿床位于冀东地区,矿区内出露的主要岩性为花岗斑岩、石英二长岩和辉绿岩。本文对矿区主要的侵入岩进行锆石U-Pb定年和Hf同位素研究,探讨成岩-成矿相互关系,获取岩体源区信息。锆石U-Pb定年结果显示,花岗斑岩~(206)Pb/~(238)U加权平均年龄分别是161. 2±0. 7Ma、173. 0±5. 5Ma,结合锆石特征、锆石U-Pb定年结果,推测该矿区存在两期花岗质岩浆侵位;辉绿岩~(206)Pb/~(238)U加权平均年龄为166. 0±0. 9Ma;石英二长岩~(206)Pb/~(238)U加权平均年龄为176. 7±3. 3Ma。唐杖子矿区辉钼矿Re-Os年龄为170Ma,从时间尺度上来看辉钼矿化与早期花岗斑岩(173Ma)关系密切。花岗斑岩εHf(t)=-24. 4~-14. 1,tCDM=2104~2744Ma,表明岩石来源于古老地壳;辉绿岩εHf(t)=7. 8~10. 9,tDM=391~523Ma,表明岩石源区为古生代的亏损地幔。唐杖子花岗斑岩和辉绿岩都形成于中侏罗世,成岩时代相近,但源区明显不同,表明冀东地区在中侏罗世既存在下地壳的部分熔融的过程(形成了唐杖子花岗斑岩),又存在亏损地幔物质上涌侵入地壳的过程(形成了唐杖子辉绿岩),暗示了华北克拉通东缘在中侏罗世经历了一次岩石圈减薄的过程。     

北秦岭南台钼多金属矿床成岩成矿年龄及锆石Hf同位素组成

南台钼多金属矿床是北秦岭典型的斑岩-矽卡岩型矿床,矿区内出露的岩浆岩主要有花岗斑岩、石英斑岩脉和爆破角砾岩,花岗斑岩内及接触带发育斑岩型和矽卡岩型钼多金属矿化。锆石LA-ICPMS定年测得花岗斑岩的U-Pb年龄为(151±1)Ma(N=12,MSWD=0.32),矿区内6件辉钼矿的Re-Os同位素模式年龄介于(146±2)～(151±2)Ma,其加权平均年龄为(148.8±1.7)Ma(N=6,MSWD=0.84)。成岩年龄与成矿年龄在误差范围内基本一致,表明南台钼多金属矿床形成于晚侏罗世,与其以北的华北克拉通南缘的主要斑岩型钼矿床大规模成矿时间一致。该花岗斑岩的锆石Hf同位素组成显示:176Hf/177Hf初始比值介于0.281 864～0.282 454,εHf(t)=-28.8～-7.9,两阶段模式年龄TDM2为2 654～1 506 Ma,均变化于一个较宽的范围,表明花岗斑岩的源区物质具有多源的特征,其中以壳源组分为主,可能有少量幔源组分的混入,暗示了成矿物质也可能主要来源于地壳,但地幔组分对成矿也有贡献。     

皖南宁国竹溪岭钨银矿床及相关岩体的同位素地质年龄

皖南宁国竹溪岭钨银矿床是近年来发现的一个与花岗岩类有关的矽卡岩型矿床,准确厘定其成矿年龄及相关侵入岩体的年龄有利于深入认识区域岩浆作用与成矿作用的规律。本文在矿床地质调查的基础上,应用现代同位素定年技术开展地质年代学研究,获得矿床矿石中的辉钼矿Re-Os模式年龄为142.7±2.1 Ma和142.9±2.1 Ma,相关侵入岩体花岗闪长岩、花岗斑岩和花岗闪长斑岩的LA-ICP-MS锆石U-Pb年龄分别为139.8±1.8 Ma、143.3±1.9 Ma、140.2±1.7 Ma,显示矿床的成矿年龄与侵入岩体的成岩年龄基本一致,为燕山晚期早白垩世。矿床矿石中的辉钼矿的Re含量指示成矿物质来源于地壳和地幔的混合;与成矿相关侵入岩的稀土元素和Hf同位素组成特征指示成岩物质也具有壳幔混源特征,显示成矿物质来源与成岩物质来源具有一致性。区域岩浆岩和矿床的对比表明,与之相邻的长江中下游地区、浙西地区和赣东北地区乃至整个华南地区这一时期发生了大规模的岩浆作用和钨锡多金属成矿作用,显示扬子板块在此阶段处于岩浆–成矿大爆发时期,皖南地区的成矿时代对应于华南中生代三次大规模岩浆作用和成矿作用的第二阶段。     

冈底斯中段岗讲斑岩铜钼矿床锆石U-Pb和辉钼矿Re-Os年代学及其地质意义

岗讲铜钼矿床是西藏冈底斯成矿带中段典型的斑岩型矿床,岗讲矿床成岩成矿时代、岩浆演化过程及其与成岩成矿关系尚不明确,利用LA-ICP-MS锆石U-Pb定年方法对岗讲矿区主要岩体二长花岗斑岩、花岗闪长斑岩和英云闪长玢岩成岩时代进行研究,获得锆石U-Pb年龄加权平均值分别为16.6±0.3 Ma (MSWD=0.94,n=10)、16.1±0.2 Ma (MSWD=1.07,n=12)、14.4±0.4 Ma (MSWD=1.12,n=7);同时采用辉钼矿Re-Os同位素测年方法首次对岗讲矿床石英硫化物脉中的辉钼矿进行定年,获得12件辉钼矿Re-Os同位素模式年龄集中于13.24±0.20 Ma~13.55±0.22 Ma,加权平均年龄为13.4±0.1 Ma (MSWD=0.65),等时线年龄为13.6±1.6 Ma (MSWD=1.2).结果表明:(1) 岗讲矿区复式岩体侵入序列为含巨斑黑云二长花岗岩-二长花岗斑岩-花岗闪长斑岩-流纹斑岩 (深部定名为英云闪长玢岩),成岩时限为16.6~14.4 Ma,成矿时代为13.4 Ma左右,成岩成矿是一个连续的岩浆演化过程;(2) 辉钼矿中Re含量为155.4~171.1 μg/g,均值为162.9 μg/g,指示其成矿物质中有幔源成分的加入;(3) 矿床产出于中新世印度-亚洲大陆碰撞后伸展构造环境.      

河南省淅川县毛堂金矿区花岗斑岩锆石U-Pb年龄、Hf同位素特征及其地质意义

毛堂金矿是位于河南省"毛堂—蒲塘铜金矿带"上的一个小型金矿,矿体主要产于老田岩体的Ⅲ号岩体中,成矿作用与隐爆角砾岩和花岗斑岩关系密切。通过对与成矿有关的隐爆角砾岩和花岗斑岩进行LA-ICP-MS锆石U-Pb同位素测年,获得其成岩年龄分别为143.0 Ma±1.2 Ma和141.4Ma±1.5Ma,代表矿床的形成时代;对花岗斑岩进行Hf同位素测试,其εHf(t)值分布范围为-3.4～4.2,平均为1.6,显示其源区为镁铁质新生地壳。毛堂金矿形成于早白垩世,受花岗斑岩、隐爆角砾岩及其构造-裂隙控制,矿床类型属于隐爆角砾岩型金矿。     

德兴矿集区花岗闪长斑岩锆石U-Pb年龄、Hf同位素特征及其意义

德兴矿集区位于赣东北地区,是中国东部中生代钦杭成矿带中的大型铜金铅锌矿集区之一,集中了铜厂、富家坞和朱砂红斑岩铜钼(金)矿、银山银铜铅锌多金属矿和金山金矿等大型、超大型矿床。本文在系统的野外地质调查与样品采集的基础上,对铜厂、富家坞、朱砂红及银山花岗闪长斑岩进行了LA-MC-ICP-MS锆石U-Pb定年和原位Hf同位素分析。德兴矿集区花岗闪长斑岩的LA-MC-ICP-MS锆石U-Pb的4组年龄分别为:(171±1.2)Ma(铜厂)、(172±0.68)Ma(富家坞)、(173±1.3)Ma(朱砂红)、(176±1.5)Ma(银山),表明这些岩体均为中侏罗世的产物。样品Hf两阶段模式年龄平均值分别为861 Ma、876 Ma、904 Ma和941 Ma,正的εHf(t)平均值在4.34-5.54,Zr/Hf比值接近于上地幔的Zr/Hf比值。锆石Hf同位素组成显示,岩浆源区主要来源于亏损地幔组分,但在岩浆演化中遭受了古老地壳物质的混染,幔源物质在德兴矿集区花岗闪长斑岩的形成过程中发挥了重要作用。德兴矿集区4个矿床成岩成矿的最重要时期在170-175 Ma,该矿集区岩浆热液系统持续活动可能是该大型矿集区形成的重要原因。     

云南澜沧老厂花岗斑岩形成年龄及地质意义

应用锆石SHRIMPU-Pb法和辉钼矿Re-Os同位素测年法对斑岩的形成时代进行精确定年。结果表明:成矿花岗斑岩体的形成年龄为44.6±1.1Ma;辉钼矿Re-Os等时线年龄为43.78±0.78Ma;成岩成矿期与滇西新生代岩浆-成矿作用高峰期吻合。结合区域地质条件和岩浆的可能源岩年龄(126.7±3.5Ma～529.3±13Ma)等资料分析,提出花岗斑岩在成因上与印支地块与滇缅泰地块陆内俯冲碰撞引发的地幔上涌及地壳重熔作用有关,岩浆来源具壳-幔混合特征。研究还证实滇西地区喜山期存在与隐伏花岗斑岩有关的大规模成矿作用。     

黄沙坪矿区花岗岩类的锆石U-Pb年龄、Hf同位素组成及其地质意义

黄沙坪矿床是湖南最大的铅锌矿床。矿区内岩浆活动复杂,矿化类型齐全,成矿元素多样,是湘南地区斑岩-矽卡岩-热液脉型Cu多金属与W-Sn多金属复合成矿作用的典型代表。为厘清区内不同花岗质岩石的时间格架、源区特征及其与成矿的关系,本次研究对黄沙坪矿区的不同类型花岗岩进行了系统的锆石LA-ICP-MS U-Pb定年和Hf同位素组成研究,研究表明,英安斑岩、二长花岗斑岩和石英斑岩的侵位年龄分别为158.5±0.9Ma、155.2±0.4Ma、160.8±1.0Ma,石英斑岩内花岗质岩石包体可能形成于220.4±1.2Ma。另外,在二长花岗斑岩锆石中发现古元古代-新太古代的继承锆石核。不同花岗质岩石中,中晚侏罗世锆石的εHf(t)值为-7.6～-3.2,Hf同位素两阶段模式年龄为1.7～1.4Ga,表明该区花岗质岩浆主要源自中元古代的古老基底物质部分熔融。继承锆石中接近0的εHf(t)负值(-1.5～-0.07)和εHf(t)正值(0.5～6.5)暗示形成这些古老继承锆石的初始物质中有幔源物质的加入。黄沙坪矿区不同类型花岗质岩石的锆石年龄和Hf同位素特征表明,英安斑岩、二长花岗斑岩、石英斑岩可能是同源同时期岩浆演化的产物,与矿床成矿年龄(154～159Ma)接近,反映其成岩成矿具有密切的时空联系。花岗岩中存在多组古老的残留锆石,暗示了黄沙坪地区自新太古代以来经历了复杂的岩浆作用,这可能是区内Cu-Pb-Zn-W-Mo-Fe多金属复合型矿床形成的关键要素。     

钦杭成矿带大瑶山地区晚白垩世斑岩型铜矿床: 锆石U-Pb定年及Hf同位素制约

钦杭成矿带是华南地区重要的斑岩铜成矿带.前人研究表明区内斑岩铜矿床主要形成于中-晚侏罗世(180~155 Ma), 含矿斑岩为壳-幔相互作用的产物.对区内新近发现的钦杭带西南段大瑶山地区的宝山斑岩铜矿床进行研究, 结果表明其成岩成矿时代集中在晚白垩世.其中, 隐伏含矿花岗斑岩体的锆石LA-ICP-MS U-Pb年龄为91.1±0.6 Ma(1σ), 出露地表不含矿的两个花岗斑岩锆石U-Pb年龄分别为91.3±0.8 Ma(1σ)和90.1±1.0 Ma(1σ).含矿斑岩和不含矿斑岩的锆石Hf同位素组成相似, 初始ε_Hf(91 Ma)为-8.74~-5.13, 两阶段Hf模式年龄T_DM2集中在1 210~1 394 Ma.以上U-Pb-Hf同位素分析结果表明, 宝山铜矿床是一个晚白垩世早期(约91 Ma)形成的斑岩型铜矿床, 其含矿斑岩体的成因可能与中元古代地壳物质的部分熔融有关.结合前人的研究成果可知, 钦杭成矿带存在两期斑岩铜矿床成矿作用, 分别为中-晚侏罗世和晚白垩世, 其中晚白垩世成矿作用可能与华南板块边缘后碰撞伸展构造背景有关; 钦杭带西南侧大瑶山及邻区可能广泛发育有与燕山晚期岩浆活动(80~100 Ma)有关的钨-钼-铜(金)多金属矿床.      

南蒙古古生代岛弧地体中酸性岩石锆石年代学、Hf同位素特征及地质意义

南蒙古曼达洛沃-古尔班赛汗岛弧地体是中亚造山带的重要组成部分,为了探讨岛弧地体内岩浆活动及地壳演化过程与斑岩型铜多金属矿床成矿作用的成因关系,对产出在该地体内代表性斑岩铜矿床与成矿作用有关的岩石进行了岩相学、锆石年代学及Hf同位素组成分析. 哈马戈泰铜-金矿床出露的与成矿有关的岩石为花岗闪长岩-二长闪长玢岩组合,LA?MC?ICP?MS锆石定年数据显示,成岩年龄为332~324 Ma;查干苏布尔加矿区产出有二长花岗斑岩,为铜-钼矿化的容矿岩体,本次测定的成岩年龄为~372 Ma;青狐狸斑岩型铜多金属矿化与闪长岩具有成因联系,本次测定的成岩年龄为~333 Ma;奥尤特乌兰铜多金属矿区岩浆岩活动强烈,产出有二长岩和安山岩-花岗闪长岩杂岩体,本次测定的成岩年龄分别为~381 Ma和338~332 Ma. 综上所述,曼达洛沃-古尔班赛汗岛弧地体晚古生代岩浆活动主要分为3个阶段:383~369 Ma、367~363 Ma和338~321 Ma. 其中,与斑岩铜多金属矿化有成因联系的岩浆活动主要集中在375~369 Ma和338~328 Ma两个时期,可能为该区域两个最重要的成矿期. 原位锆石ε_Hf（t）位于球粒陨石演化线之上,介于+7.85~+16.14之间,部分分析点与亏损地幔值相似,显示成岩物质来源可能是亏损地幔部分熔融形成的新生物质在地壳短暂停留后再次部分熔融的产物,同时也受到了一定程度成熟地壳的混染. Hf同位素两阶段模式年龄t_DM2为331~717 Ma,表明本区发生重要的地壳增生事件的时间是新元古代至晚古生代.      

Origin of the Yinshan epithermal-porphyry Cu–Au–Pb–Zn–Ag deposit,southeastern China: insights from geochemistry,Sr–Nd and zircon U–Pb–Hf–O isotopes

The Yinshan deposit is a large epithermal-porphyry polymetallic deposit, and the timing and petrogenesis of ore-hosting porphyries have been hotly debated. We present new results from geochemical, whole-rock Sr–Nd and zircon U–Pb–Hf–O isotopic investigations. Zircon U–Pb data demonstrate that the quartz porphyry, dacitic porphyry, and quartz dioritic porphyry formed at ?172.2 ± 0.4 Ma, ?171.7 ± 0.5 Ma, and ?170.9 ± 0.3 Ma, respectively. Inherited zircon cores show significant age spreads from ?730 to ?1390 Ma. Geochemically, they are high-K calc-alkaline or shoshonitic rocks with arc-like trace element patterns. They have similar whole-rock Nd and zircon Hf isotopic compositions, yet an increasing trend in ?_Nd(t) and ?_Hf(t) values typifies the suite. Older (inherited) zircons of the three porphyries display Hf compositions comparable to those of the Jiangnan Orogen basement rocks. In situ zircon oxygen isotopic analyses reveal that they have similar oxygen isotopic compositions, which are close to those of mantle zircons. Moreover, a decreasing trend of δ¹⁸O values is present. We propose that the ore-related porphyries of the Yinshan deposit were emplaced contemporaneously and derived from partial melting of Neoproterozoic arc-derived mafic (or ultra-mafic) rocks. Modelling suggests that the quartz porphyries, dacitic porphyries, and quartz dioritic porphyries experienced ?25%, ?10%, and ?10% crustal contaminations by Shuangqiaoshan rocks. Our study provides important constraints on mantle–crust interaction in the genesis of polymetallic mineralization associated with Mesozoic magmatism in southeastern China.     

Petrogenesis of the Yangchang Mo‐bearing granite in the Xilamulun metallogenic belt,NE China: geochemistry,zircon U–Pb ages and Sr–Nd–Pb isotopes

The Yangchang granite‐hosted Mo deposit is typical of the Xilamulun metallogenic belt, which is one of the important Mo–Pb–Zn–Ag producers in China. A combination of major and trace element, Sr, Nd and Pb isotope, and zircon U–Pb age data are reported for the Yangchang batholith to constrain its petrogenesis and Mo mineralization. Zircon LA‐ICPMS U–Pb dating yields mean ages of 138 ± 2 and 132 ± 2 Ma for monzogranite and granite porphyry, respectively. The monzogranites and granite porphyries are calc‐alkaline with K₂O/Na₂O ratios of 0.75–0.92 and 1.75–4.42, respectively. They are all enriched in large‐ion lithophile elements (LILEs) and depleted in high‐field‐strength elements (HFSEs) with negative Nb and Ta anomalies in primitive‐mantle‐normalized trace element diagrams. The monzogranites have relatively high Sr (380–499 ppm) and Y (14–18 ppm) concentrations, and the granite porphyries have lower Sr (31–71 ppm) and Y (5–11 ppm) concentrations than those of monzogranites. The monzogranites and granite porphyries have relatively low initial Sr isotope ratios of 0.704573–0.705627 and 0.704281, respectively, and similar ²⁰⁶Pb/²⁰⁴Pb ratios of 18.75–18.98 and 18.48–18.71, respectively. In contrast, the ε_Nd(t) value (−3.7) of granite porphyry is lower than those of monzogranites (−1.5 to −2.7) with Nd model ages of about 1.0 Ga. These geochemical features suggest that the monzogranite and granite porphyries were derived from juvenile crustal rocks related to subduction of the Paleo‐Pacific plate under east China. Copyright © 2013 John Wiley & Sons, Ltd.     

Partial melting of subducted Southern Qiangtang crust in northern Tibet: evidence from the geochemistry and geochronology of the Riwanchaka granodiorite porphyry in Central Qiangtang

ABSTRACT

This article presents new zircon U–Pb geochronology, Hf isotopic, and whole-rock major- and trace-element geochemical data that provide insights into the petrogenesis and tectonic history of the Riwanchaka granodiorite porphyries of Central Qiangtang, Tibet. Zircon U–Pb ages of 236–230 Ma indicate an early Late Triassic age of emplacement of the porphyries, and zircon Hf isotopic data yield εHf(t) values of – 7.0 to – 1.5 and ancient zircon Hf crustal model ages (T_DM^C) of 1524–1220 Ma. The granodiorite porphyries are characterized by low K₂O contents, high Mg# values, and relatively high Cr and Ni contents. They are classified as I-type calc-alkaline granite and are considered to have formed through the anatexis of ancient mafic crustal rocks with contributions from mantle-derived components. The geochemistry and isotopic compositions of all samples are similar to those of magmatic rocks that originated in the South Qiangtang crust. However, field observations indicate that the pluton intrudes the North Qiangtang crust, and we propose that the granodiorite porphyries were derived by partial melting of subducted continental crust of the South Qiangtang terrane. These new data have been integrated with data from previous studies to construct a new model of slab rollback during northward subduction of the Southern Qiangtang continental crust at ca. 245–226 Ma, thereby improving our understanding of magmatic processes involved in continental subduction in collision settings.     

藏南冈底斯岩基东段朗县杂岩早白垩世岩浆作用: 新特提斯洋二次俯冲

新特提斯洋长期俯冲消减作用在早白垩世可能经历二次俯冲启动或板片俯冲几何形态的重大转换。确定西藏南部冈底斯岩基早白垩世岩浆作用的岩石地球化学特征和作用方式是甄别上述过程的关键,对理解新特提斯洋的俯冲演化过程至关重要。本文就冈底斯岩基东段朗县杂岩中保存的各类早白垩世岩浆岩,开展了锆石U-Pb地质年代学和Hf同位素、全岩元素和同位素（Sr-Nd）组成分析。数据结果表明：1）基性岩侵位时代为早白垩世晚期（103.6~100.8Ma）,为高钾钙碱性偏铝质岩石,锆石ε_Hf（t）=+0.3~+5.7,全岩ε_Nd（t）=-0.8和-0.3,暗示其岩浆源区具有大量俯冲沉积物或流体的混入,为沉积物熔体和流体交代的地幔楔物质部分熔融的产物,经历了一定程度的角闪石分离结晶作用;2）中性岩形成于99.8~97.6Ma,略晚于基性岩,其主量元素与基性岩具有较好的线性关系,全岩ε_Nd（t）=+1.1,具有较多的地幔物质参与,为基性岩浆进一步演化形成;3）酸性岩（脉体）记录了多阶段岩浆作用（124.1~95.3Ma）,根据同位素组成不同进一步划分为两类,第一类具有较低的全岩ε_Nd（t）值（-8.3~-6.0）,其岩浆源区显示富集特征,t_DM2=1385~1586Ma,由古老地壳物质的再熔融形成;第二类的锆石ε_Hf（t）值（-2.8~+3.2）变化较大,岩脉的锆石ε_Hf（t）=+0.4~+8.1,t_DM=428~906Ma,全岩ε_Nd（t）=+0.1和+0.8,表明岩浆源区具有不均一性,为古老地壳物质被富流体地幔岩浆改造形成;和4）镁铁质包体的主量元素与寄主花岗岩具有较好的线性关系,锆石的Hf同位素组成变化较大（ε_Hf（t）=-9.3~+4.1）,变化范围可达13个ε单位,为岩浆混合成因。寄主花岗岩和角闪辉长岩分别作为酸性和基性端元,是基性岩浆与其诱发古老地壳熔融形成的花岗质岩浆经混合形成。结合冈底斯岩基早白垩世岩浆岩的研究结果,朗县杂岩在早白垩世（124~97Ma）的岩浆作用具有明显的岩浆混合现象,锆石Hf和全岩Sr-Nd同位素组成变化较大,可达13个ε单位,其岩浆源区复杂且富含流体,代表了新特提斯洋在早期（240~144Ma）经历漫长的俯冲之后,在早白垩世时期（~120Ma）俯冲带发生跃迁或俯冲角度达到临界点,导致大量俯冲沉积物和流体沿俯冲带俯冲下去,与发生部分熔融的地幔楔物质混合,底侵导致上覆古老地壳物质的再熔融,形成早白垩世复杂的岩浆岩组合,很可能是新特提斯洋二次俯冲开始的标志。

     

Late Triassic Granites From the Quxu Batholith Shedding a New Light on the Evolution of the Gangdese Belt in Southern Tibet

The Gangdese magmatic belt formed during Late Triassic to Neogene in the southernmost Lhasa terrane of the Tibetan plateau. It is interpreted as a major component of a continental margin related to the northward subduction of the Neo-Tethys oceanic slab beneath Eurasia and it is the key in understanding the tectonic framework of southern Tibet prior to the India-Eurasia collision. It is widely accepted that northward subduction of the Neo-Tethys oceanic crust formed the Gangdese magmatic belt, but the occurrence of Late Triassic magmatism and the detailed tectonic evolution of southern Tibet are still debated. This work presents new zircon U-Pb-Hf isotope data and whole-rock geochemical compositions of a mylonitic granite pluton in the central Gangdese belt, southern Tibet. Zircon U-Pb dating from two representative samples yields consistent ages of 225.3±1.8 Ma and 229.9±1.5 Ma, respectively, indicating that the granite pluton was formed during the early phase of Late Triassic instead of Early Eocene(47–52 Ma) as previously suggested. Geochemically, the mylonitic granite pluton has a sub-alkaline composition and low-medium K calc-alkaline affinities and it can be defined as an I-type granite with metaluminous features(A/CNK1.1). The analyzed samples are characterized by strong enrichments of LREE and pronounced depletions of Nb, Ta and Ti, suggesting that the granite was generated in an island-arc setting. However, the use of tectonic discrimination diagrams indicates a continental arc setting. Zircon Lu-Hf isotopes indicate that the granite has highly positive εHf(t) values ranging from +13.91 to +15.54(mean value +14.79), reflecting the input of depleted mantle material during its magmatic evolution, consistent with Mg~# numbers. Additionally, the studied samples also reveal relatively young Hf two-stage model ages ranging from 238 Ma to 342 Ma(mean value 292 Ma), suggesting that the pluton was derived from partial melting of juvenile crust. Geochemical discrimination diagrams also suggest that the granite was derived from partial melting of the mafic lower crust. Taking into account both the spatial and temporal distribution of the mylonitic granite, its geochemical fingerprints as well as previous studies, we propose that the northward subduction of the Neo-Tethys oceanic slab beneath the Lhasa terrane had already commenced in Late Triassic(~230 Ma), and that the Late Triassic magmatic events were formed in an active continental margin that subsequently evolved into the numerous subterranes, paleo-island-arcs and multiple collision phases that form the present southern Tibet.     

西藏青草山斑岩铜金矿床含矿斑岩锆石U-Pb年代学及岩石成因

西藏青草山Cu-Au矿床是班公湖-怒江缝合带北侧新发现的具有大型远景的斑岩型矿床,但该矿床含矿斑岩的年龄、成因及源区一直未得到有效的约束.对青草山花岗闪长岩以及含矿花岗岩闪长斑岩进行了锆石年代学、Hf同位素以及岩石地球化学研究.结果显示,花岗闪长岩与含矿花岗闪长斑岩的侵入时代分别为131.2±0.3 Ma与117.9±0.8 Ma,代表了班公湖-怒江缝合带早期的成岩作用以及斑岩Cu-Au成矿作用.二者具有相似的地球化学特征,表明二者可能具有相同的岩浆源区,是不同时期同源岩浆活动的产物.结合含矿花岗闪长斑岩锆石Hf同位素组成,认为青草山含矿斑岩形成于班公湖-怒江洋壳向北俯冲过程中,是下地壳部分熔融的产物,受到了少量地幔物质的混合.      

黑龙江省跃进山铜金矿床花岗斑岩锆石U-Pb定年及地质意义

跃进山铜金矿床是完达山活动带的典型矿床,位于密山—敦化深断裂北侧。本文对含矿花岗斑岩开展了锆石LA-ICP-MS U-Pb测年、主量和微量元素的研究,厘定岩体的形成时代,探讨了成矿构造背景。结果表明与成矿密切相关的花岗斑岩的年龄为(109.17±0.91)Ma。它们为过铝质钙碱性系列岩石,富集Rb、Ba、La、Nd、Hf等元素,亏损Nb、Sr、P、Ti等元素,具俯冲带岩浆岩的基本特征,这些暗示它们形成于岛弧或活动大陆边缘环境。结合岩体的地球化学特征和完达山成矿带的构造岩浆演化,认为该矿床形成于岛弧构造背景,其形成与中生代太平洋的俯冲及早白垩世晚期东亚东部岩浆活动陆缘迁移、构造单元转化有关。     

青海南山俯冲型侵入体LA-ICP-MS锆石U-Pb定年及其地质意义

青海南山侵入体岩石类型为二长花岗岩、花岗闪长岩及英云闪长岩,具俯冲型花岗岩类的地球化学特征。通过高精度的LA-ICP-MS(激光剥蚀等离子体质谱)单颗粒锆石微区U-Pb同位素年龄测定,分别在二长花岗岩、花岗闪长岩及英云闪长岩中获得446.1±3.5Ma、447.2±5.3Ma、443.6±8.6Ma的锆石U-Pb年龄值,为成岩年龄,代表了加里东运动在祁连造山带的地质记录。3种不同岩石类型的成岩年龄可能代表了拉脊山造山带向南俯冲的时代。青海南山地区俯冲型侵入体的形成时代及构造环境的确定,对研究拉脊山造山带的构造演化及动力学机制具有重要意义。     

Petrogenesis of Late Jurassic granitoids and relationship to polymetallic deposits in southern China: The Huangshaping example

ABSTRACT

Southern Hunan Province, located in the Cathaysia Block where the Shi–Hang zone and Nanling belt meet, is characterized by extensive Mesozoic magmatism and coeval polymetallic mineralization. The Huangshaping W–Mo–Pb–Zn–(Cu) deposit is representative in this area. However, the petrogenesis of the granitoids associated with the Huangshaping deposit, and their relationships with mineralization, remain undetermined. In this paper we focus on zircon U–Pb dating, whole-rock geochemistry, and Sr–Nd–Pb–Hf isotopic compositions in order to further our understanding of these issues, as well as their regional implications. The Huangshaping granitoids are characterized by two pulses of intrusive activity: a first-stage quartz porphyry and a second-stage felsite and granite porphyry, our new data show that the quartz porphyry and felsite formed at 160.5 ± 1.3 and 156.6 ± 1.4 Ma, respectively, representing a period of Late Jurassic magmatism. Granitic enclaves within the quartz porphyry crystallized at 160.2 ± 1.6 Ma, and zircons and apatites from the enclaves exhibit Hf isotopic and geochemical compositions that suggest a Palaeoproterozoic lower crustal melt as one end-member of the magma that formed the quartz porphyry, whereas another likely end-member was coeval mantle-derived magma, as indicated by the geochemistry and Sr–Nd–Pb–Hf isotopes. However, both the felsite and granite porphyry were probably derived from the melting of metamorphic basement rocks in the upper crust. The felsite clearly formed as a result of the rapid ascent and cooling of magma, whereas the granite porphyry underwent fractional crystallization. The magma sources and evolution of the granitoids, as well as their association with the Huangshaping mineralization, suggest that melting of upper crustal components controlled the W–Mo and Pb–Zn mineralization, whereas dehydration of a subducted slab provided the Cu mineralization in southern Hunan Province.     

粤东莲花山地区多期岩浆锆石年代学、Hf同位素组成及其成矿作用

粤东莲花山地区位于我国东南沿海火山岩发育区,是我国重要的钨金成矿远景区。通过对该地区各类花岗岩进行LA-ICP-MS锆石U-Pb定年、岩石地球化学特征、锆石Lu-Hf同位素组成和微量元素研究,结果表明：莲花山地区的岩浆活动至少存在3期,其中石英闪长玢岩形成于中侏罗世（（168.0±2.2）Ma）,黑云母二长花岗岩形成于早白垩世早期（（137.5±1.9）Ma）,石英斑岩形成于早白垩世晚期（（102.0±1.5）Ma和（98.7±1.8）Ma）;岩石以钙碱性铝质-强过铝质岩浆为主,石英斑岩和流纹斑岩与成矿关系密切;各类岩浆锆石的¹⁷⁶Lu/¹⁷⁷Hf值均低于0.002,¹⁷⁶Hf/¹⁷⁷Hf值大多数小于0.282 7,ε_Hf（t）值大多数处于-2.57~1.00之间,f_Lu-Hf值为-0.99~-0.95,二阶段模式年龄主要介于1.00~0.81 Ga之间,指示成岩物质来源主要来自新元古代古老下地壳变质泥岩和变质砂岩部分熔融,有少量幔源物质加入;锆石结晶温度大多处于650~750℃之间,岩石为I型花岗岩。莲花山地区不同阶段的岩浆活动和成矿作用与区域构造转换事件相关,虽缺少高精度成矿年龄对成矿时限的限制,但根据地质事实和本次研究认为该地区主要的钨金成矿时间应略晚于石英斑岩的形成时间（（102.0~98.7）Ma）。