Benthic foraminifera from the upper Collio Formation (Lower Permian, Lombardy Southern Alps): implications for the palaeogeography of the peri-Tethyan area

New palaeontological evidence points to a temporary marine transgression in the Early Permian into the Collio Basin, a major palaeogeographic feature of the present-day Southern Alps. The thick volcaniclastic succession filling the basin (Collio Formation) is widely held as deposited in alluvial to lacustrine settings. Rare calcareous foraminifers were recently found in a single sandstone interval, containing phosphate nodules, from the uppermost Collio Formation. A temporary seaway, necessary for the foraminifera to spread into a continental basin, implies that (i) the Collio Basin lake was not only an intramontane (as commonly viewed), but also a coastal lake, and (ii) its altitude did not exceed the amplitude of a first-order sea-level rise, that is, about 100 m. These constraints, along with striking similarities as to tectonic context, accumulation rates and geochemical signature, suggest that the Collio Basin was a California-type basin, resembling in particular the present-day Salton Sea (CA, USA).     

Late Palaeoproterozoic Hekou Group in Sichuan,Southwest China: geochronological framework and tectonic implications

The Palaeoproterozoic Hekou Group, an outcrop along the SW-margin of the Yangtze Block, consists of volcanic and sedimentary rocks that experienced greenschist facies metamorphism and was intruded by gabbroic and granitic plutons. The sedimentary rocks consist of coarse to fine-grained siliciclastic and carbonate rocks including quartzite, mica schists, polymictic meta-conglomerates and marble, whereas volcanic rocks consist of sodic lava and pyroclastic rocks including albitites, interbeded metatuffs, and metabasalts. Metatuffs from five layers have zircon U–Pb age of 1710 ± 18 Ma (MSWD = 1.6), 1637 ± 7 Ma (MSWD = 0.65), 1601 ± 15 Ma (MSWD = 0.94), 1661 ± 7 Ma (MSWD = 1.4), and 1718 ± 11 Ma (MSWD = 0.3) and these ages show that the Hekou Group deposited at ~1.7–1.6 Ga. The high content of light rare earth element (LREE), the low content of highrare earth element (HREE) and negative Ti anomalies, relatively high content of incompatible fluid-insoluble elements (Nb, Ta, and Th), and the high varied εNd(t) values (?6.0 to +4.6) of the metavolcanic rocks show that these rocks are formed in back-arc basin. Our study also implies that the Yangtze Block also underwent subduction-related, continental margin accretion on its SW-margin during the growth of the Nuna supercontinent at ~1.7–1.6 Ga.     

Ordovician and Cretaceous tectonothermal history of the Southern Gemericum Unit from microprobe monazite geochronology (Western Carpathians,Slovakia)

The Southern Gemericum basement in the Inner Western Carpathians experienced a polyphase regional deformation. Differences in the pre-Alpine and Alpine events have been constantly discussed. To address this, monazites from metapelites and acid metavolcanic rocks were dated using the Th–U–Pb electron microprobe method. Three monazite generations, such as Precambrian, Early Paleozoic, and Alpine, have been recognized in the greenschist facies pelites and acid metavolcanic rocks of the Southern Gemericum basement. Both inherited magmatic monazite grains in metavolcanites and rare relics of detrital monazites within the polyphase monazite grains in metapelites yielded the Precambrian age in the time span of 550–660 Ma. They prove the provenance and derivation from deeper crustal Cadomian fragments. High-Y magmatic monazites of Early Paleozoic age (444 ± 13 and 477 ± 7 Ma) have been recorded in the acid metavolcanites and their metavolcaniclastics. These ages roughly fit within the previously published magmatic zircon age determinations (at 494 ± 1.7 and 464 ± 1.7 Ma) that clearly indicate two-phase volcanic activity in the Early Paleozoic Southern Gemericum basin. The Early Paleozoic magmatic monazites were partly overprinted by the low-Y Alpine monazites (133 ± 5 and 184 ± 16 Ma) at their rims. In Al-rich metapelites, the newly formed low-Y monazites of Alpine age commonly occur, reflecting the polystage compression geodynamic evolution with three distinct peaks at 100 ± 8, 133 ± 5, and 190 ± 16 Ma, respectively. No data as the evidence of the pre-Alpine metamorphic events were observed in metapelites. Only some monazites yield the age indications for the Permian extensional thermal re-heating (260–290 Ma). The monazite age data from the Southern Gemericum basement indicate the strong overprinting due to the polyphase Alpine deformation at least in the greenschist facies conditions.     

Biostratigraphy versus isotope geochronology: Testing the Urals island arc model

Formation of the Urals volcanic-hosted massive sulphide(VHMS) deposits is considered to be related with the intra-oceanic stage of island arc(s) development in the Upper Ordoviciane Middle Devonian based on the biostratigraphic record of ore-hosting sedimentary rocks. However, the direct Re-Os dating of four known VHMS systems in the Urals gives significantly younger Re-Os isochron ages ranging from355 ± 15 Ma up to 366 ± 2 Ma. To address this discrepancy, we performed SHRIMP U-Pb dating on zircons extracted from rhyodacites(Eifelian biostratigraphic age of 393 -388 Ma) from the footwall of the Alexandrinka VHMS deposit which has a Re-Os isochron age of sulphides of 355 ± 15 Ma.New ²⁰⁶ Pb/²³⁸ U mean age of 374 ± 3 Ma(MSWD ? 1.4 and probability ? 0.11) is considered to be the crystallisation age of the host volcanic rock. This age is ca. 15 Ma younger than the Eifelian(393 -388 Ma)biostratigraphic age and overlaps the Frasniane Famennian boundary(372 ± 2 Ma), characterised by the final stages of Magnitogorsk Arc e East European continent collision. Such an inconsistency with geochronological age may be due to a reburial of conodonts during resedimentation as a result of erosion of older rocks in younger sedimentary sequences.     

Provenance of Permian Delaware Mountain Group,central and southern Delaware Basin,and implications of sediment dispersal pathway near the southwestern terminus of Pangea

ABSTRACT

The Delaware Basin is located near the southwestern end of the Alleghanian–Ouachita–Marathon orogenic belt. The basin is mostly filled by Permian clastic rocks of the Delaware Mountain Group with ramp- to shelf-carbonate rimming basin edges. The Delaware Mountain Group has been well-documented as a deep-water clastic reservoir unit in the prolific Permian Basin, but its sources and related sediment dispersal pathways remain inconclusive. In this study, a total of 55 samples of the Delaware Mountain Group were collected from whole core and sidewall core from the central and southern Delaware Basin, and sandstone modal analyses and U-Pb detrital zircon geochronology were applied to constrain their potential sources. Sandstone modal analyses show that the majority of samples fall within the transitional continental source field. Age spectra of detrital zircon from five selected samples include a prominent middle Palaeozoic age cluster (~490–275 Ma), a major Neoproterozoic to early Palaeozoic age cluster (~790–510 Ma), and a series of minor age clusters of the middle to late Mesoproterozoic (~1300–920 Ma), early Mesoproterozoic (~1600–1300 Ma), late Palaeoproterozoic (~1825–1600 Ma), and Archaean and Palaeoproterozoic (> ~1825 Ma). Integrating detrital zircon data from all potential sources and coeval sandstones from the northern Delaware Basin suggests that the majority of sediment was derived from the Appalachian foreland, the Ouachita orogenic system, and the peri-Gondwanan terranes. Variation in the abundance of the different age groups reveals a provenance shift between deposition of the Brushy Canyon Formation and the Cherry and Bell Canyon Formations. To accommodate the composition, and the stratigraphic and spatial age spectral variations, we proposed that the sediment dispersal pathway includes a transcontinental fluvial system from the Appalachian orogenic belt to the east, a regional scale fluvial system from the Ouachita orogenic belt to the north and northeast, and a local, proximal fluvial system from the peri-Gondwanan terranes to the south and southeast.     

Permian continental basins in the Southern Alps (Italy) and peri-mediterranean correlations

The Late Carboniferous to Permian continental successions of the Southern Alps can be subdivided into two main tectono-sedimentary Cycles, separated by a marked unconformity sealing a Middle Permian time gap, generally estimated at over 10 Ma. The lower cycle (1), between the Variscan crystalline basement and the Early Permian, is mainly characterised by fluvio-lacustrine and volcanic deposits of calc-alkaline acidic-to-intermediate composition, which range up to a maximum thickness of more than 2,000 m. The upper cycle (2), which is devoid of volcanics, is mostly dominated through the Mid?–Late Permian by alluvial sedimentation which covered the previous basins and the surrounding highs, giving rise to the subaerial Verrucano Lombardo-Val Gardena (Gröden) red-beds, up to about 800 m thick. The palaeontological record from the terrigenous deposits of both the above cycles consists mainly of macro- and microfloras and tetrapod footprints. The age of the continental deposits is widely discussed because of the poor chronological significance of a large number of fossils which do not allow reliable datings; however, some sections are also controlled by radiometric calibrations. The comparison with some selected continental successions in southern Europe allows to determine their evolution and set up correlations. A marked stratigraphic gap shows everywhere between the above-mentioned Cycles 1 and 2. As in the Southern Alps, the gap reaches the greatest extent during the Mid-Permian, near the Illawarra Reversal geomagnetic event (265 Ma). In western Europe, however, such as in Provence and Sardinia, the discussed gap persists upwardly to Late Permian and Early Triassic or slightly younger times, i.e. to the onset of the “Alpine sedimentary Cycle”, even though in northeastern Spain (Iberian Ranges, Balearic Islands) this gap results clearly interrupted by late Guadalupian–Lopingian deposits. The above two major tectonosedimentary cycles reflect, in our view, two main geodynamic events that affected the southern Europe after the Variscan orogenesis: the Late Carboniferous–Early Permian transformation of the Gondwana–Eurasia collisional margin into a diffuse dextral transform margin and the Middle–Late Permian opening of the Neotethys Ocean, with the onset of a generalised extensional tectonic regime and the progressive westward marine ingression.     

Petrology and geochemistry of Early Permian volcanic rocks in South Tian Shan,NW China: implications for the tectonic evolution and Phanerozoic continental growth

Situated in the southwest of the Central Asian Orogenic Belt (CAOB), the South Tian Shan (STS) Block is a key area for understanding the final accretion of the CAOB. A suite of volcanic rocks interbedded with continental sediments from the Xiaotikanlike Formation lies along the southwestern edge of the Tian Shan orogen. Laser-ablation-inductively coupled plasma-mass spectrometer U–Pb dating provided a crystallization age of 295.0 ± 2.8 Ma (MSWD = 1.3), suggesting an Early Permian magmatic event. The volcanic rocks show a variable composition, with dominant rhyolites and dacites, subordinate basaltic andesites and few basalts. The felsic rocks are enriched in K and exhibit remarkably negative anomalies in Ba, Sr, Eu, P and Ti. These anomalies associated with their high negative ε _Nd(t) values and old Nd model ages suggest that they are most likely sourced from ancient lower crustal rocks. The mafic rocks are characterized by high Mg#, Cr, Ni contents, negative Nb, Ta anomalies and pronounced enrichment in light rare earth elements as well as mild enrichment in large-ion lithophile elements. The mafic rocks are thus inferred to derive from enriched subcontinental lithospheric mantle. The petrographic and geochemical characteristics of the Xiaotikanlike Formation volcanic rocks indicate that they were generated under a post-collisional regime. Therefore, the final collision between the Tarim Craton and the Kazakhstan–Yili terrane took place before Early Permian, most probably at Late Carboniferous. Differing from other tectonic units of the CAOB, the recycling of ancient lithospheric crust played a significant role in the continental growth of the STS Block.     

Permian copper–polymetallic mineralization in the southern Great Xing’an Range,Northeast China: the Daolundaba copper–polymetallic deposit example

The Daolundaba Cu–polymetallic deposit is a newly discovered Cu–W–Sn deposit on the western slopes of the southern Great Xing’an Range, and its mineralization was related to an early Permian coarse-grained biotite granite. However, there is little information on the age of formation of the deposit. In this article, we present the results of our investigation into the age of the Daolundaba Cu–polymetallic deposit, which involved the selection of chalcopyrite and pyrrhotite samples for Rb–Sr isochron dating. A Rb–Sr isochron defined by the chalcopyrite samples yielded a Rb–Sr isochron age of 290.0 ± 11 Ma (MSWD = 1.2) with an initial Sr isotopic composition (I_Sr) of 0.71446. The pyrrhotite samples yielded a Rb–Sr isochron age of 283.0 ± 2.6 Ma (MSWD = 1.16) with an initial Sr isotopic composition (I_Sr) of 0.71447. The Rb–Sr isochron age determined from the chalcopyrite and pyrrhotite is 282.7 ± 1.7 Ma (MSWD = 1.13). These results indicate that the Daolundaba Cu–polymetallic deposit formed during the early Permian (282.7–290.0 Ma). The Rb and Sr contents of the chalcopyrite and pyrrhotite range from ~0.1325 to ~3.6810 ppm and from ~0.1219 to ~9.5740 ppm, respectively, and the initial Sr isotope ratios (I_Sr) range from 0.71047 to 0.71869, with an average of 0.714723. These isotopic characteristics indicate the ore-forming minerals of the Daolundaba Cu–polymetallic deposit originated mainly from the crust, but with small amounts of mantle material involved. The copper was derived from the associated magma whereas the W and Sn was derived from the surrounding strata. The Permian mineralization of the Xing’an–Mongolia region occurred in an active continental margin setting during subduction of the Palaeo-Asian oceanic plate beneath the Siberian Plate.     

Detrital zircon provenance evidence for an early Permian longitudinal river flowing into the Midland Basin of west Texas

ABSTRACT

Collision of Gondwana and Laurentia in the late Palaeozoic created new topography, drainages, and foreland basin systems that controlled sediment dispersal patterns on southern Laurentia. We utilize sedimentological and detrital zircon data from early Permian (Cisuralian/Leonardian) submarine-fan deposits in the Midland Basin of west Texas to reconstruct sediment dispersal pathways and palaeogeography. New sedimentological data and wire-line log correlation suggest a portion of the early Permian deposits have a southern entry point. A total of 3259 detrital zircon U-Pb and 357 εHf data from 12 samples show prominent groups of zircon grains derived from the Appalachian (500–270 Ma) and Grenville (1250–950 Ma) provinces in eastern Laurentia and the peri-Gondwana terranes (800–500 Ma) incorporated in the Alleghanian-Ouachita-Marathon orogen. Other common zircon groups of Mesoproterozoic-Archaean age are also present in the samples. The detrital zircon data suggest throughout the early Permian, Appalachia and Gondwana detritus was delivered by a longitudinal river system that flowed along the Appalachian-Ouachita-Marathon foreland into the Midland Basin. Tributary channels draining the uplifted Ouachita-Marathon hinterland brought Gondwana detritus into the longitudinal river with headwaters in the Appalachians or farther northeast. This drainage extended downstream westward and delivered sediments into the Permian Basin near the west terminus of the Laurentia-Gondwana suture. Estimated rates of deposition and proportions of zircons from more local (Grenville) versus more distal (Pan-African) sources indicate that river strength decreased throughout early Permian time. Primary sediment delivery pathway was augmented by minor input from the Ancestral Rocky Mountains and wind deflation of fluvial sediments north and east of the basin. Slope failure associated with early Permian deposition in the southeastern margin of the Midland Basin triggered gravity flows leading to submarine fan deposition.     

Sedimentology of the continental end‐Permian extinction event in the Sydney Basin,eastern Australia

Upper Permian to Lower Triassic coastal plain successions of the Sydney Basin in eastern Australia have been investigated in outcrop and continuous drillcores. The purpose of the investigation is to provide an assessment of palaeoenvironmental change at high southern palaeolatitudes in a continental margin context for the late Permian (Lopingian), across the end‐Permian Extinction interval, and into the Early Triassic. These basins were affected by explosive volcanic eruptions during the late Permian and, to a much lesser extent, during the Early Triassic, allowing high‐resolution age determination on the numerous tuff horizons. Palaeobotanical and radiogenic isotope data indicate that the end‐Permian Extinction occurs at the top of the uppermost coal bed, and the Permo‐Triassic boundary either within an immediately overlying mudrock succession or within a succeeding channel sandstone body, depending on locality due to lateral variation. Late Permian depositional environments were initially (during the Wuchiapingian) shallow marine and deltaic, but coastal plain fluvial environments with extensive coal‐forming mires became progressively established during the early late Permian, reflected in numerous preserved coal seams. The fluvial style of coastal plain channel deposits varies geographically. However, apart from the loss of peat‐forming mires, no significant long‐term change in depositional style (grain size, sediment‐body architecture, or sediment dispersal direction) was noted across the end‐Permian Extinction (pinpointed by turnover of the palaeoflora). There is no evidence for immediate aridification across the boundary despite a loss of coal from these successions. Rather, the end‐Permian Extinction marks the base of a long‐term, progressive trend towards better‐drained alluvial conditions into the Early Triassic. Indeed, the floral turnover was immediately followed by a flooding event in basinal depocentres, following which fluvial systems similar to those active prior to the end‐Permian Extinction were re‐established. The age of the floral extinction is constrained to 252.54 ± 0.08 to 252.10 ± 0.06 Ma by a suite of new Chemical Abrasion Isotope Dilution Thermal Ionization Mass Spectrometry U‐Pb ages on zircon grains. Another new age indicates that the return to fluvial sedimentation similar to that before the end‐Permian Extinction occurred in the basal Triassic (prior to 251.51 ± 0.14 Ma). The character of the surface separating coal‐bearing pre‐end‐Permian Extinction from coal‐barren post‐end‐Permian Extinction strata varies across the basins. In basin‐central locations, the contact varies from disconformable, where a fluvial channel body has cut down to the level of the top coal, to conformable where the top coal is overlain by mudrocks and interbedded sandstone–siltstone facies. In basin‐marginal locations, however, the contact is a pronounced erosional disconformity with coarse‐grained alluvial facies overlying older Permian rocks. There is no evidence that the contact is everywhere a disconformity or unconformity.     

Zircon geochronology and geochemistry to constrain the youngest eruption events and magma evolution of the Mid-Miocene ignimbrite flare-up in the Pannonian Basin,eastern central Europe

A silicic ignimbrite flare-up episode occurred in the Pannonian Basin during the Miocene, coeval with the syn-extensional period in the region. It produced important correlation horizons in the regional stratigraphy; however, they lacked precise and accurate geochronology. Here, we used U–Pb (LA-ICP-MS and ID-TIMS) and (U–Th)/He dating of zircons to determine the eruption ages of the youngest stage of this volcanic activity and constrain the longevity of the magma storage in crustal reservoirs. Reliability of the U–Pb data is supported by (U–Th)/He zircon dating and magnetostratigraphic constraints. We distinguish four eruptive phases from 15.9 ± 0.3 to 14.1 ± 0.3 Ma, each of which possibly includes multiple eruptive events. Among these, at least two large volume eruptions (>10 km³) occurred at 14.8 ± 0.3 Ma (Demjén ignimbrite) and 14.1 ± 0.3 Ma (Harsány ignimbrite). The in situ U–Pb zircon dating shows wide age ranges (up to 700 kyr) in most of the crystal-poor pyroclastic units, containing few to no xenocrysts, which implies efficient recycling of antecrysts. We propose that long-lived silicic magma reservoirs, mostly kept as high-crystallinity mushes, have existed in the Pannonian Basin during the 16–14 Ma period. Small but significant differences in zircon, bulk rock and glass shard composition among units suggest the presence of spatially separated reservoirs, sometimes existing contemporaneously. Our results also better constrain the time frame of the main tectonic events that occurred in the Northern Pannonian Basin: We refined the upper temporal boundary (15 Ma) of the youngest counterclockwise block rotation and the beginning of a new deformation phase, which structurally characterized the onset of the youngest volcanic and sedimentary phase.     

Apatite fission track and (U-Th)/He thermochronology of the Rochovce granite (Slovakia) – implications for the thermal evolution of the Western Carpathian-Pannonian region

The thermal evolution of the only known Alpine (Cretaceous) granite in the Western Carpathians (Rochovce granite) is studied by low-temperature thermochronological methods. Our apatite fission track and apatite (U-Th)/He ages range from 17.5 ± 1.1 to 12.9 ± 0.9 Ma, and 12.9 ± 1.8 to 11.3 ± 0.8 Ma, respectively. The data thus show that the Rochovce granite records a thermal event in the Middle to early Late Miocene, which was likely related to mantle upwelling, volcanic activity, and increased heat flow. During the thermal maximum between ~17 and 8 Ma, the granite was heated to temperatures ? 60 °C. Increase of cooling rates at ~12 Ma recorded by the apatic fission track and (U-Th)/He data is primarily related to the cessation of the heating event and relaxation of the isotherms associated with the termination of the Neogene volcanic activity. This contradicts the accepted concept, which stipulates that the internal parts of the Western Carpathians were not thermally affected during the Cenozoic period. The Miocene thermal event was not restricted to the investigated part of the Western Carpathians, but had regional character and affected several basement areas in the Western Carpathians, the Pannonian basin and the margin of the Eastern Alps.     

Facies and basin architecture of the Late Carboniferous Salvan-Dorénaz continental basin (Western Alps, Switzerland/France)

The Salvan‐Dorénaz Basin formed during the Late Palaeozoic within the Aiguilles‐Rouges crystalline basement (Western Alps) as an asymmetric, intramontane graben elongated in a NE–SW direction and bounded by active faults. At least 1700 m of fluvial, alluvial fan and volcanic deposits provide evidence for a strong tectonic influence on deposition with long‐term, average subsidence rates of > 0·2 mm yr^?1. The early basin fill was associated with coarse‐grained alluvial fans that were dominated by braided channels (unit I). These issued from the south‐western margin of the basin. The fans then retreated to a marginal position and were overlain by muddy floodplain deposits of an anastomosed fluvial system (unit II) that drained towards the NE. Deposition of thick muds resulted from a reduction in the axial fluvial gradient caused by accelerated tectonic subsidence. Overlying sand‐rich meandering river deposits (unit III) document a reversal in the drainage direction from the NE to the SW caused by synsedimentary tectonism, reflecting large‐scale topographic reorganization in this part of the Variscides with subsidence now preferentially in the W and SW and uplift in the E and NE. Coarse‐grained alluvial fan deposits (unit IV) repeatedly prograded into, and retreated from, the basin as documented by coarsening‐upward cycles tens of metres thick reflecting smaller scale tectonic cycles. Volcanism was active throughout the evolution of the basin, and U/Pb isotopic dating of the volcanic deposits restricts the time of basin development to the Late Carboniferous (308–295 Ma). ⁴⁰Ar/³⁹Ar ages of detrital white mica indicate rapid tectonic movements and exhumation of the nearby basement. In unit I, youngest ages are close to that of the host sediment, but the age spectrum is wide. In unit II, high subsidence and/or sedimentation rates coincide with very narrow age spectra, indicating small, homogeneous catchment areas. In unit III, age spectra became wider again and indicate growing catchment areas.     

Structural and stratigraphic evolution of Abu Dhabi in the context of Arabia

The Emirate of Abu Dhabi is famed for its coastal carbonate, sabkhas and sand dunes; it is located in the NE part of the Arabian Plate, which formed during the Late Neoproterozoic (~820–750 Ma) by the accretion of island arcs and microcontinents to early Gondwana. Most of Arabia seems to have spent its existence within the Southern Hemisphere until it crossed the Equator during the Mesozoic; parts were involved in four glaciations, two in the Proterozoic (~750–630 Ma—Iceball or Slushball Earth?), and two more in the Palaeozoic (Late Ordovician and Permo-Carboniferous transition). In the early Palaeozoic the Arabian Plate was oriented about 90° counter clockwise relative to today’s poles. Gondwana later skirted the South Pole, migrating to the other side of the planet, eventually emerging the ‘right-way up’ with the Arabian Plate oriented to the poles more or less as seen today. Cold and temperate climate conditions ensured that for much of its early existence, Arabia was the site of mainly quartz-rich deposits. Later in the Neoproterozoic, however, extensive stromatolitic carbonate deposition took the lead, culminating around the Cambro-Precambrian boundary with deposition of the extensive Ara and Hormuz evaporites. Since south Arabia’s Permo-Carboniferous glaciation, the Arabian plate has been drifting northward, crossing temperate climatic zones conducive to fluvial and aeolian sandstone deposition and, from the later Permian, to tropical shallow-marine carbonates and evaporites In parallel with the above, the rifting of Gondwana opened an oceanic trough in the Late Permian off the NE flank of Arabia. Slope carbonates and deepwater Hawasina turbidites with a clear flow to the NE were deposited until they were obducted (together with associated ophiolites) in the Late Cretaceous on the edge of the Arabian plate in Oman and Iran. The deposition of widespread Early Silurian hydrocarbon source rocks in east-central Arabia was followed in the later Permian by extensive reservoir rocks with more during the mid-Late Mesozoic, giving rise to major oilfields both on- and off-shore, including Abu Dhabi. Arabia and Africa began to separate late in the Miocene with the opening of the Red Sea and Gulf of Aden. SSW–NNE compressive stresses caused uplift and volcanic activity in west Saudi Arabia and Yemen. Some products of erosion flowed eastward into Abu Dhabi. At the NE margin of Arabia, the Tethys Ocean narrowed, the NE flank of the newly forming Zagros Mountains of Iran is being subducted beneath southern Asia. To the SE, roughly coeval crustal compression adjacent to the Gulf of Oman led to uplift of the Oman Mountains and deposition of erosional products flanking the mountains mainly to the W and SW. The Oman Mountains are currently rising at about 2 mm/a, while northern Musandam is subsiding into the Strait of Hormuz at some 6 mm/a in association with subduction of the Arabian plate margin below the Eurasian plate. Alternations between polar glaciations and interglacials over the past few 100 ka resulted in considerable climatic changes over Arabia; slow glacial build-ups lasting some 80 to 120 ka led, somewhat erratically, to a fall in sea level of up to 130 m, to strong winds and the building of systems of extensive sand dunes such as the Rub’ al Khali. The joint Tigris–Euphrates river system flowed through a desert landscape, reaching the ocean only SE of the Strait of Hormuz. The peak of the last glaciation about 21 ka was followed by its rapid collapse and flooding of the Arabian Gulf to its present level between about 12 or 10 and 6 ka, a horizontal marine advance of some 200–300 m/a. Abu Dhabi is now the site of shallow-marine carbonates offshore and classical sabkhas and carbonate-rich sand dunes onshore.     

塔里木盆地塔北隆起西部火山岩40Ar-39Ar年代学和地球化学特征

本文对塔里木盆地塔北隆起西部钻井的火山岩岩心样品进行了40Ar-39 Ar定年,五件样品的年龄值在248.75±6.5Ma至267.44±3.01Ma之间,样品的岩石地球化学分析表明火山岩为具有大陆裂谷性质的板内火山岩.结合前人研究成果,本文认为塔里木盆地火山活动不仅发生在早二叠世,塔北隆起西部地区在中-晚二叠世仍有强烈的火山活动,该火山活动是塔里木盆地早二叠世大火成岩省后期热事件的产物.     

Detrital zircon geochronology and provenance of the Chubut Group in the northeast of Patagonia,Argentina

The Chubut Group constitutes the most widespread sedimentary unit in NE Patagonia, characterized by variable-energy fluvial deposits. U–Pb analysis of detrital zircons from two sections of the Chubut Group constraint the age of the oldest sedimentary rocks in the northeast of the Somuncurá – Cañadón Asfalto Basin. In the Cañadón Williams area, at San Jorge section, 20 km NW of Telsen locality, dating of 56 detrital zircons from a medium to coarse sandstone indicated a maximum depositional age of 109 ± 1 Ma (n = 4). These sandstones were interpreted to represent shallow channels, associated with a lacustrine system. In the Telsen locality, a laser ablation analysis of 115 detrital zircons from a medium to coarse-grained sandstone, from fluvial channel facies, yielded a maximum depositional age of ca. 106 ± 1 Ma (n = 8). Both ages are consistent with volcanic events of the Barremian to Albian age in the central Patagonian Andes Region. Cathodoluminescence images of zircons from the San Jorge sample suggest an igneous origin, which is further supported by Th/U values above 0.5 in most of the grains. The distribution of the statistical modes of the main age populations of detrital zircons for the two samples [182, 185 and 189 Ma for Telsen sample (T2S) and 181 ± 1 Ma for San Jorge sample (SJS)] matches the age of the volcanic Marifil Formation. The rocks of the Marifil Formation of these ages are exposed NE to SE of the study area. The abundance of zircons of similar Jurassic ages (n = 52 for SJS and n = 105 for T2S) and the external morphology of the zircons in the sample SJS, implies a close proximity of the source area. Suggestion that the Marifil Formation was the main provenance source is also supported by northeast–southeasterly paleocurrents measured at the San Jorge and Telsen sections.     

Dating magmatic and hydrothermal processes using andradite-rich garnet U–Pb geochronometry

Andradite-rich garnet is a common U-bearing mineral in a variety of alkalic igneous rocks and skarn deposits, but has been largely neglected as a U–Pb chronometer. In situ laser ablation-inductively coupled plasma mass spectrometry U–Pb dates of andradite-rich garnet from a syenite pluton and two iron skarn deposits in the North China craton demonstrate the suitability and reliability of the mineral in accurately dating magmatic and hydrothermal processes. Two hydrothermal garnets from the iron skarn deposits have homogenous cores and zoned rims (Ad₈₆Gr₁₁ to Ad₉₈Gr₁) with 22–118 ppm U, whereas one magmatic garnet from the syenite is texturally and compositionally homogenous (Ad₇₀Gr₂₂ to Ad₇₇Gr₁₄) and has 0.1–20 ppm U. All three garnets have flat time-resolved signals obtained from depth profile analyses for U, indicating structurally bound U. Uranium is correlated with REE in both magmatic and hydrothermal garnets, indicating that the incorporation of U into the garnet is largely controlled by substitution mechanisms. Two hydrothermal garnets yielded U–Pb dates of 129 ± 2 (2σ; MSWD = 0.7) and 130 ± 1 Ma (2σ; MSWD = 0.5), indistinguishable from zircon U–Pb dates of 131 ± 1 and 129 ± 1 Ma for their respective ore-related intrusions. The magmatic garnet has a U–Pb age of 389 ± 3 Ma (2σ; MSWD = 0.6), consistent with a U–Pb zircon date of 388 ± 2 Ma for the syenite. The consistency between the garnet and zircon U–Pb dates confirms the reliability and accuracy of garnet U–Pb dating. Given the occurrence of andradite-rich garnet in alkaline and ultramafic magmatic rocks and hydrothermal ore deposits, our results highlight the potential utilization of garnet as a powerful U–Pb geochronometer for dating magmatism and skarn-related mineralization.     

Petrogenesis of early Silurian intrusions in the Sanchakou area of Eastern Tianshan,Northwest China,and tectonic implications: geochronological,geochemical, and Hf isotopic evidence

ABSTRACT

Palaeozoic intrusions in Eastern Tianshan are important for understanding the evolution of the Central Asian Orogenic Belt (CAOB). The Sanchakou intrusions situated in Eastern Tianshan (southern CAOB), are mainly quartz diorite and granodiorite. A comprehensive study of zircon U–Pb ages, zircon trace elements, whole-rock geochemistry, and Lu–Hf isotopes were carried out for the Sanchakou intrusive rocks. LA-ICP-MS zircon U–Pb dating yielded crystallization ages of 439.7 ± 2.5 Ma (MSWD = 0.63, n = 21) for the quartz diorite, and 430.9 ± 2.5 Ma (MSWD = 0.21, n = 21) and 425.5 ± 2.7 Ma (MSWD = 0.04; n = 20) for the granodiorites. These data, in combination with other Silurian ages reported for the intrusive suites from Eastern Tianshan, indicate an early Palaeozoic magmatic event in the orogen. In situ zircon Hf isotope data for the Sanchakou quartz diorite shows ε_Hf(t) values of +11.2 to +19.6, and the two granodioritic samples exhibit similar ε_Hf(t) values from +13.0 to +19.5. The Sanchakou plutons show metaluminous to weakly peraluminous, arc-type geochemical and low-K tholeiite affinities, and display trace element patterns characterized by enrichment in K, Ba, Sr, and Sm, and depletion in Nb, Ta, Pb, and Ti. The geochemical and isotopic signatures indicate that the Sanchakou dioritic and granodioritic magmas were sourced from a subducted oceanic slab, and subsequently underwent some interaction with peridotite in the mantle wedge. Combined with the regional geological history, we suggest the Sanchakou intrusions formed due to the northward subduction of the Palaeo-Tianshan Ocean beneath the Dananhu–Tousuquan arc during early Silurian time.     

U–Pb geochronology and geochemistry of late Palaeozoic volcanism in Sardinia (southern Variscides)

The latest Carboniferous to lower Permian volcanism of the southern Variscides in Sardinia developed in a regional continental transpressive and subsequent transtensile tectonic regime.Volcanism produced a wide range of intermediate-silicic magmas including medium-to high-K calc-alkaline andesites,dacites,and rhyolites.A thick late Palaeozoic succession is well exposed in the four most representative Sardinian continental basins(Nurra,Perdasdefogu,Escalaplano,and Seui-Seulo),and contains substantial stratigraphic,geochemical,and geochronological evidence of the area's complex geological evolution from the latest Carboniferous to the beginning of the Triassic.Based on major and trace element data and LA-ICP-MS U-Pb zircon dating,it is possible to reconstruct the timing of postVariscan volcanism.This volcanism records active tectonism between the latest Carboniferous and Permian,and post-dates the unroofing and erosion of nappes in this segment of the southern Variscides.In particular,igneous zircon grains from calc-alkaline silicic volcanic rocks yielded ages between299±1 and 288±3 Ma,thereby constraining the development of continental strike-slip faulting from south(Escalaplano Basin)to north(Nurra Basin).Notably,andesites emplaced in medium-grade metamorphic basement(Mt.Cobingius,Ogliastra)show a cluster of older ages at 332±12 Ma.Despite the large uncertainty,this age constrains the onset of igneous activity in the mid-crust.These new radiometric ages constitute:(1)a consistent dataset for different volcanic events;(2)a precise chronostratigraphic constraint which fits well with the biostratigraphic data and(3)insights into the plate reorganization between Laurussia and Gondwana during the late Palaeozoic evolution of the Variscan chain.     

Mineralization time and tectonic setting of the Zhengguang Au deposit in the Duobaoshan ore field,Heilongjiang Province,NE China

The Zhengguang deposit, a representative large gold deposit in the Duobaoshan ore field in NE China, is located in the northeast of the Central Asian Orogenic Belt (CAOB). Ore body emplacement was structurally controlled and occurs mainly at the contact zone between the strata of Duobaoshan Formation and an Ordovician diorite stock. The diorite rocks have a close genetic relationship with Au mineralization. Re–Os isotope dating of Au-bearing pyrite yields an isochron age of 506 ± 44 Ma (MSWD = 15). Based on present and previous dating results, it can be concluded that the Zhengguang deposit formed at ~480 Ma. The mineralization time of the Zhengguang deposit is nearly identical to those of the Duobaoshan and Tongshan deposits, indicating they are all derived from the same metallogenic system. The Duobaoshan-style porphyry Cu–Mo mineralization may exist at deeper levels at Zhengguang. The geochemical characteristics of the Zhengguang dioritic rocks presented in this paper are similar to those of bajaitic high-Mg andesite, and the magmas originated from a mantle wedge metasomatized by melts from a subducting oceanic slab at an active continental margin setting. The Ordovician magmatic–metallogenic events in the Duobaoshan ore field were caused by the westward subduction of an oceanic slab located between the Xing’an and Songliao blocks. It is worth pointing out that the Zhengguang deposit is the oldest known Phanerozoic Au deposit in NE China. Further studies of this deposit will improve understanding of the regularity of ore formation and aid mineralization forecast across the Duobaoshan region.