Effects of Different Carbon Sources on Denitrification Efficiency Associated with Culture Adaptation and C/N Ratio

Stringent effluent limitations for nitrogen necessitate an accurate interpretation of the design and operation conditions of biological nitrogen removal systems. In this study, the effects of the nature of the organic substrate on biomass adaptation and response to different C/N ratios in terms of denitrification efficiency were investigated. A relatively high chemical oxygen demand (COD)_utilized/NO_x–N_reduced ratio of 8.1 was obtained when an excess amount of readily biodegradable carbon was supplied, which is suggested as the conversion of substrate surplus into storage polymers. An anoxic yield of 0.64 g cell COD/g COD for a four‐compound substrate mixture (acetate, propionate, ethanol and glucose), 0.63 g cell COD/g COD for a two‐compound substrate mixture (acetate and propionate), and 0.5 g cell COD/g COD for methanol were calculated. Fluorescence in situ hybridization analysis showed that the β‐subclass of proteobacteria was dominant in the seed and in cultures adapted to both the four‐compound and the two‐compound substrate mixture, whereas in the methanol‐adapted culture significant amounts of β‐proteobacteria were detected. The biocommunity composition, the type of organic compound and the COD/NO₃–N ratio strongly influence the nitrate reduction and carbon utilization profiles. Methanol has been shown to select for a denitrifying population consisting of Paracoccus and Hyphomicrobium vulgare genera, when used as only external carbon source.     

Monitoring of Impact of Ferti‐irrigation by Post‐methanated Distillery Effluent on Groundwater Quality

The impact assessment of molasses‐based distillery‐effluent irrigation on groundwater quality around village Gajraula in the district of Jyotiba Phule Nagar, Uttar Pradesh, India was studied by sampling groundwater on monthly intervals consecutively for summer, winter and monsoon seasons during 2006–2007 and water quality parameters, viz. pH, electrical conductivity (EC), chloride (Cl^?), sulphate (SO), nitrate (NO), chemical oxygen demand (COD), total solids (TS), total dissolved solids (TDS), sodium (Na⁺), potassium (K⁺), calcium (Ca²⁺), magnesium (Mg²⁺), zinc (Zn²⁺), iron (Fe³⁺), and total coliforms (TC) were monitored. Results depicted that the values of all parameters decreased with increasing depth of water table. Sulphate, nitrate and potassium contents were maximal in agricultural site during monsoon while EC, Cl^?, TS, TDS, Na⁺, Ca²⁺, Mg²⁺, Zn, and Fe were maximal in industrial sites during summer. Groundwater samples of residential site harboured maximum coliforms especially during monsoon, highlighting threat to groundwater. Significant positive correlation matrix between coliforms with nitrate, sulphate and potassium ions explained their survival on these nutrients. To overcome this, important measures emphasizing improvement in effluent treatment technology matching site‐specific characteristics are recommended for eco‐friendly ferti‐irrigation.     

Spatial Variability of Nitrate and Ammonium in Pleistocene Aquifer of Central Yangtze River Basin

It becomes increasingly important and challenging for nitrogen pollution prevention to identify key controls for spatial variability of nitrogen in groundwater that could be affected by multiple factors, including anthropogenic input, groundwater flow, and local geochemistry. This study characterized spatial variability of both nitrate and ammonium in the Pleistocene aquifer of central Yangtze River Basin and assessed the effect of various factors in controlling nitrate and ammonium levels based on multiple statistical approaches (correlation, geostatistics, multiple liner regression). The results indicate that nitrate is mostly influenced by Cl⁻ that represents anthropogenic input, while Eh representing local redox state is a secondary variable influencing nitrate concentrations. The groundwater with elevated nitrate concentrations are estimated to occur mainly in areas with higher-permeability near-surface sediments which can facilitate more anthropogenic nitrate transport and less nitrate removal owing to more oxidized state. Ammonium is mostly correlated to Eh, followed by dissolved organic carbon (DOC), but only DOC improves significantly the accuracy of co-kriging prediction model. The groundwater with elevated ammonium concentrations are estimated to occur mainly in areas with more organic-rich sediments within or around the aquifer which can facilitate more ammonium release owing to natural organic matter consumption accompanying strong reducing conditions. The regional groundwater flow is not a factor significantly controlling nitrate or ammonium levels owing to flat topography and sluggish lateral flow.     

Spatial and temporal variations of nutrient concentration in the groundwater of a floodplain: effect of hydrology,vegetation and substrate

Spatio‐temporal variations in nitrogen and phosphorus concentrations in groundwater were analysed and related to the variations in hydrological conditions, vegetation type and substrate in an alluvial ecosystem. This study was conducted in the Illwald forest in the Rhine Plain (eastern France) to assess the removal of nutrients from groundwater in a regularly flooded area. We compared both forest and meadow ecosystems on clayey‐silty soils with an anoxic horizon (pseudogley) at 1·5–2 m depth (eutric gley soil) and a forest ecosystem on a clayey‐silty fluviosoil rich in organic matter with a gley at 0·5 m depth (calcaric gley soil). Piezometers were used to measure the nutrient concentrations in the groundwater at 2 m depth in the root layer and at 4·5 m depth, below the root layer. Lower concentrations of nitrate and phosphate in groundwater were observed under forest than under meadow, which could be explained by more efficient plant uptake by woody species than herbaceous plants. Thus NO₃‐N inputs by river floods were reduced by 73% in the shallow groundwater of the forested ecosystem, and only by 37% in the meadow. Compared with the superficial groundwater layer, the lowest level of nitrate nitrogen (NO₃‐N) and the highest level of ammonium nitrogen (NH₄‐N) were measured in the deep layer (under the gley horizon at 2·5 m depth), which suggests that the reducing potential of the anoxic horizon in the gley soils contributes to the reduction of nitrate. Nitrate concentrations were higher in the groundwater of the parcel rich in organic matter than in the one poorer in organic matter. Phosphate (PO₄‐P) concentrations in both shallow and deep groundwater are less than 62 to 76% of those found in surface water which can be related to the retention capacity of the clay colloids of these soils. Moreover, the temporal variations in nutrient concentrations in groundwater are directly related to variations in groundwater level during an annual hydrological cycle. Our results suggest that variations in groundwater level regulate spatio‐temporal variations in nutrient concentrations in groundwater as a result of the oxidation–reduction status of soil, which creates favourable or unfavourable conditions for nutrient bioavailability. The hydrological variations are much more important than those concerning substrate and type of vegetation. Copyright © 1999 John Wiley & Sons, Ltd.     

The Role of Groundwater for Lake‐Water Quality and Quantification of N Seepage

The heterogeneous nature of both groundwater discharge to a lake (inflow) and nitrate concentrations in groundwater can lead to significant errors in calculations of nutrient loading. Therefore, an integrated approach, combining groundwater flow and transport modelling with observed nitrate and ammonium groundwater concentrations, was used to estimate nitrate loading from a catchment via groundwater to an oligotrophic flow‐through lake (Lake Hampen, Denmark). The transport model was calibrated against three vertical nitrate profiles from multi‐level wells and 17 shallow wells bordering a crop field near the lake. Nitrate concentrations in groundwater discharging to the lake from the crop field were on average 70 times higher than in groundwater from forested areas. The crop field was responsible for 96% of the total nitrate loading (16.2 t NO₃/year) to the lake even though the field only covered 4.5% of the catchment area. Consequently, a small change in land use in the catchment will have a large effect on the lake nutrient balance and possible lake restoration. The study is the first known attempt to estimate the decrease of nitrate loading via groundwater to a seepage lake when an identified catchment source (a crop field) is removed.     

Treatment of Synthetic Olefin Plant Wastewater at Various Salt Concentrations in a Membrane Bioreactor

The objective of this study was to investigate the effect of salt concentration on performance of a membrane bioreactor (MBR) for treating an olefin plant wastewater. For this purpose, a lab‐scale submerged MBR with a flat‐sheet ultrafiltration membrane was used for treatment of synthetic wastewater according to oxidation and neutralization unit of olefin plant. The synthetic wastewater was adjusted to have 500 mg/L chemical oxygen demand (COD). Trials on different concentrations of sodium sulfate (Na₂SO₄) (0–20 000 ppm) in the feed were conducted under aerobic conditions in the MBR. The results showed that increasing the salt concentrations causes an increase in the effluent COD, phenol, and oil concentrations. These results are due to reduction of the membrane filtration efficiency and also decline in the microbial activity that it is indicated by decreasing the sOUR in MBR. But in all the trials, the effluent COD and oil concentration was well within the local discharge limit of 100 and 10 mg/L, respectively. These results indicate that the MBR system is highly efficient for treating the olefin plant wastewater, and although high salt concentrations decreased organic contaminant removal rates in the MBR, the effluent still met the discharge limits for treating the olefin plant wastewater.     

Characterization of groundwater quality in Kinmen Island using multivariate analysis and geochemical modelling

Kinmen is located in the south‐west of Mainland China and mainly has two islands, Large Kinmen and Leiyu. Residents in Kinmen have drunk groundwater over several decades. This work characterized the quality of groundwater in Kinmen using factor analysis (FA), cluster analysis (CA) and geochemical simulation. The factor scores were plotted spatially to illustrate the groundwater quality and were used to discuss the grouped relationship using CA. Salinization, redox and organic matter factors are identified from 17 hydrochemical measurements in 18 wells. Acidic and oxidizing groundwater with nitrate‐N pollution is distributed mainly in the west of Large Kinmen. Saline groundwater is distributed to the north‐east of Large Kinmen and in the south of Leiyu. Groundwater with organic matter is present throughout Leiyu. Five groups of the groundwater quality divided by CA can be interpreted according to one to three factors. The grouped characteristics of the groundwater quality help the local government and industries to plan the use and protection of groundwater resources. Furthermore, a geochemical simulation was used to demonstrate the formation processes of the acidic and oxidizing groundwater properties in granitic sediments. A large amount of the precipitation of the kaolinite and magnetite releases concentrations of hydrogen ion and raises the redox potential in the aquifers. Copyright © 2007 John Wiley & Sons, Ltd.     

System Performance in UASB Reactors Receiving Increasing Levels of Sulfate

Glucose‐fed high‐rate UASB reactors were tested at three COD/SO₄ ratios and hydraulic retention times to promote sulfate reducing activity and observe the effects on reactor performance. Different COD/SO₄ ratios (20, 10, and 5) resulted in changes in organic matter removal, methane production, alkalinity, dissolved sulfide and biomass concentrations and profile. The COD removal dropped from 95 to 80–84 % at the lowest COD/SO₄ ratio. Sulfate was removed at 79 to 89 % at the highest ratio and dropped to 72 to 74 % with increasing sulfate loading. Alkalinity was produced at higher levels with increasing sulfate loading. Specific methane production dropped with decreasing hydraulic retention times. Sulfate‐reducing activity used a maximum of 11.7 % of organic matter at the highest sulfate loading level, producing a slight shift to sulfate‐reducing activity in the substrate competition between sulfate‐reducing bacteria and methanogens. Increased sulfate loading at COD/SO₄ ratios of 10 and 5 caused deterioration of the concentration profile of the sludge, resulting in biomass washout and decreased volatile fraction of biosolids in the reactors.     

Protein‐like fluorescence intensity as a possible tool for determining river water quality

The results of a comparison between chemical water quality determinants and river water fluorescence on the River Tyne, NE England, demonstrate that tryptophan‐like fluorescence intensity shows statistically significant relationships between nitrate, phosphate, ammonia, biochemical oxygen demand (BOD) and dissolved oxygen. Tryptophan‐like fluorescence intensity at the 280 nm excitation/350 nm emission wavelength fluorescence centre correlates with both phosphate (r = 0·80) and nitrate (r = 0·87), whereas tryptophan‐like fluorescence intensity at the 220 nm excitation/350 nm emission wavelength centre correlates with BOD (r = 0·85), ammonia (r = 0·70) and dissolved oxygen (r = ?0·65). The strongest correlations are between tryptophan‐like fluorescence intensity and nitrate and phosphate, which in the Tyne catchment derive predominantly from point and diffuse source sewage inputs. The correlation between BOD and the tryptophan‐like fluorescence intensity suggests that this fluorescence centre is related to the bioavailable or labile dissolved organic matter pool. The weakest correlations are observed between tryptophan‐like fluorescence intensity and ammonia concentration and dissolved oxygen. The weaker correlation with ammonia is due to removal of the ammonia signal by wastewater treatment, and that with dissolved oxygen due to the natural aeration of the river such that this is not a good indicator of water quality. The observed correlations only hold true when treated sewage, sewerage overflows or cross connections, or agricultural organic pollutants dominate the water quality—this is not true for two sites where airport deicer (propylene glycol, which is non‐fluorescent) or landfill leachate (which contains high concentrations of humic and fulvic‐like fluorescent DOM) dominate the dissolved organic matter in the river. Mean annual tryptophan‐like fluorescence intensity agrees well with the General Water Quality Assessment as determined by the England and Wales environmental regulators, the Environment Agency. Copyright © 2004 John Wiley & Sons, Ltd.     

High concentration of solutes at the upper part of the saturated zone (water table) of a deep aquifer under sewage-irrigated land

The water-table region (upper 50 cm of the saturated zone) of a 25 m deep phreatic sandstone aquifer, lying under fields irrigated with sewage effluents for up to 22 yrs, was monitored in 1971 and 1984. Average concentrations of NO⁻₃, Cl⁻ and SO²⁻₄ of up to 225, 307 and 155 mg l⁻¹, respectively, were detected in the upper 50 cm of the saturated region in two research wells in 1984. These concentrations, which are related to effluent and fertilizer input to groundwater, were two to four times higher than those found deep (37–55 m) below the water table in nearby (1000 m distant) production wells. Nitrate data and the estimated transit time through the unsaturated zone (2 m yr⁻¹) support the model suggesting that the major source of nitrate pollution in the past should be related to the oxidation of soil organic matter. The SO²⁻₄/Cl⁻ ratio is found to be a useful indicator for the arrival of SO²⁻₄-fertilizers at the groundwater interface. The observations presented in this paper question the suitability of plans for using effluents as a water source for agriculture in regions which are the replenishment areas of phreatic aquifers.     

Seasonal and interannual variations of nitrate and chloride in stream waters related to spatial and temporal patterns of groundwater concentrations in agricultural catchments

Nitrate concentrations in streamwater of agricultural catchments often exhibit interannual variations, which are supposed to result from land‐use changes, as well as seasonal variations mainly explained by the effect of hydrological and biogeochemical cycles. In catchments on impervious bedrock, seasonal variations of nitrate concentrations in streamwater are usually characterized by higher nitrate concentrations in winter than in summer. However, intermediate or inverse cycles with higher concentrations in summer are sometimes observed. An experimental study was carried out to assess the mechanisms that determine the seasonal cycles of streamwater nitrate concentrations in intensive agricultural catchments. Temporal and spatial patterns of groundwater concentrations were investigated in two adjacent catchments located in south‐western Brittany (France), characterized by different seasonal variations of streamwater nitrate concentrations. Wells were drilled across the hillslope at depths ranging from 1·5 to 20 m. Dynamics of the water table were monitored and the groundwater nitrate and chloride concentrations were measured weekly over 2 years. Results highlighted that groundwater was partitioned into downslope domains, where denitrification induced lower nitrate concentrations than into mid‐slope and upslope domains. For one catchment, high subsurface flow with high nitrate concentrations during high water periods and active denitrification during low water periods explained the higher streamwater nitrate concentrations in winter than in summer. For the other catchment, the high contribution of groundwater with high nitrate concentrations smoothed or inverted this trend. Increasing bromide/chloride ratio and nitrate concentrations with depth argued for an effect of past agricultural pressure on this catchment. The relative contribution of flows in time and correlatively the spatial origin of waters, function of the depth and the location on the hillslope, and their chemical characteristics control seasonal cycles of streamwater nitrate concentrations and can influence their interannual trends. Copyright © 2004 John Wiley & Sons, Ltd.     

Unexpected nationwide nitrate declines in groundwater of Korea

Elevated levels of nitrate in groundwater are an important concern for health and the environment. The overapplication of nitrogen fertilizer to croplands is one of the major sources of high nitrate content in groundwater. In this study, we analyse the nitrate concentrations in Korean groundwater based on data from groundwater quality monitoring wells (n = 1,022–2,072), which were sampled twice annually over a recent 13‐year analysis period (2001–2013). We report that groundwater nitrate levels are decreasing, despite steadily increasing groundwater use. The maximum nitrate concentration decreased from 168.91 to 48.11 mg/L, whereas the mean values also show a gradual decreasing trend. Non‐parametric Mann–Kendall tests on nitrate concentrations also confirm the decreasing trend. The nitrate decrease is more clearly evident in agricultural groundwater as compared to domestic and drinking groundwaters. This decrease of nitrate in groundwater coincides with a large decline in nitrogen fertilizer application due to reduced cropland areas, more sustainable agricultural practices, and progressive improvement of sewage disposal services. This study proposes that the long‐term adoption of best practices in agriculture has had a positive impact on groundwater nitrate control.     

The effects of sewage organic matter on biogeochemical processes within mid-shelf sediments offshore Sydney, Australia

A laboratory incubation experiment was conducted using replicate cores collected from a muddy-sand sediment facies offshore Sydney, Australia to determine what components and processes would be affected by the addition of sewage organic matter. Sewage effluent has a solid phase composition of 40% carbon (35% organic carbon), 5% nitrogen, 1% phosphorus and 5% silicate. The molecular C:N:P ratio is 92:10:1, compared to the Redfield ratio of 106:16:1 in marine phytoplankton. Sediment cores were incubated at in situ temperature in a darkened room for periods up to 95 days. Sewage organic matter was added to the cores at three different loads equivalent to 0 (T0), 65 (T1) and 130 (T2) g m⁻² of sediment. Following the addition of sewage organic matter, fluxes of oxygen (into the sediments), ammonia and phosphate (from the sediments) increased, reflecting an enhanced organic carbon supply to the sediments. Oxygen penetrated to a depth of 6 mm in the ambient cores, but the sediment oxygen content was severely depleted following the addition of the sewage-derived organic matter. Sediment porewater data, together with nutrient flux data indicate that oxygen reduction, nitrate reduction and sulphate reduction occurs within these sediments. Following the addition of sewage organic matter, increases in total nitrogen, total phosphate and total organic carbon were measured to depths of 5 cm in the sediments, suggesting that bioturbation influences nutrient and organic carbon distributions. Additionally, irrigation of the surficial sediments may play an important role in the metabolism of organic matter. These results indicate that oxygen penetration, oxygen fluxes, nitrate concentrations within porewaters, ammonia flux rates, and solid phase concentrations of total organic carbon and nutrients may be useful indicators of sediments affected by high rates of organic matter deposition onto Sydney's offshore sediments. The EPA has recently predicted maximum deposition rates of sewage particulate matter to be approximately 1 g m⁻² day⁻¹. Because of the similarities in CNP ratios of sewage organic matter and marine organic matter, the effects of sewage organic matter and marine organic matter inputs to coastal sediments may not be easily distinguishable.     

Amelioration of Carbon Removal Prediction for an Activated Sludge Process using an Artificial Neural Network (ANN)

A dynamic simulation model of the Ankara central wastewater treatment plant (ACWTP) was evaluated for the prediction of effluent COD concentrations. Firstly, a mechanistic model of the municipal wastewater treatment process was developed based on Activated Sludge Model No. 1 (ASM1) by using a GPS‐X computer program. Then, the mechanistic model was combined with a feed‐forward back‐propagation neural network in parallel configuration. The appropriate architecture of the neural network models was determined through several iterative steps of training and testing of the models. Both models were run with the data obtained from the plant operation and laboratory analysis to predict the dynamic behavior of the process. Using these two models, effluent COD concentrations were predicted and the results were compared for the purpose of evaluation of treatment performance. It was observed that the ASM1 ANN model approach gave better results and better described the operational conditions of the plant than ASM1.     

Geologic controls on the chemical behaviour of nitrate in riverside alluvial aquifers,Korea

To investigate the origin and behaviour of nitrate in alluvial aquifers adjacent to Nakdong River, Korea, we chose two representative sites (Wolha and Yongdang) having similar land‐use characteristics but different geology. A total of 96 shallow groundwater samples were collected from irrigation and domestic wells tapping alluvial aquifers. About 63% of the samples analysed had nitrate concentrations that exceeded the Korean drinking water limit (44·3 mg l^?1 NO₃^?), and about 35% of the samples had nitrate concentrations that exceeded the Korean groundwater quality standard for agricultural use (88·6 mg l^?1 NO₃^?). Based on nitrogen isotope analysis, two major nitrate sources were identified: synthetic fertilizer (about 4‰ δ¹⁵N) applied to farmland, and animal manure and sewage (15–20‰ δ¹⁵N) originating from upstream residential areas. Shallow groundwater in the farmland generally had higher nitrate concentrations than those in residential areas, due to the influence of synthetic fertilizer. Nitrate concentrations at both study sites were highest near the water table and then progressively decreased with depth. Nitrate concentrations are also closely related to the geologic characteristics of the aquifer. In Yongdang, denitrification is important in regulating nitrate chemistry because of the availability of organic carbon from a silt layer (about 20 m thick) below a thin, sandy surface aquifer. In Wolha, however, conservative mixing between farmland‐recharged water and water coming from a village is suggested as the dominant process. Mixing ratios estimated based on the nitrate concentrations and the δ¹⁵N values indicate that water originating from the village affects the nitrate chemistry of the shallow groundwater underneath the farmland to a large extent. Copyright © 2003 John Wiley & Sons, Ltd.     

Use of an Artificial Sweetener to Identify Sources of Groundwater Nitrate Contamination

The artificial sweetener acesulfame (ACE) is a potentially useful tracer of waste water contamination in groundwater. In this study, ACE concentrations were measured in waste water and impacted groundwater at 12 septic system sites in Ontario, Canada. All samples of septic tank effluent (n = 37) had ACE >6 µg/L, all samples of groundwater from the proximal plume zones (n = 93) had ACE >1 µg/L and, almost all samples from the distal plume zones had ACE >2 µg/L. Mean mass ratios of total inorganic nitrogen/ACE at the 12 sites ranged from 680 to 3500 for the tank and proximal plume samples. At five sites, decreasing ratio values in the distal zones indicated nitrogen attenuation. These ratios were applied to three aquifers in Canada that are nitrate‐stressed and an urban stream where septic systems are present nearby to estimate the amount of waste water nitrate contamination. At the three aquifer locations that are agricultural, low ACE values (<0.02‐0.15 µg/L) indicated that waste water contributed <15% of the nitrate in most samples. In groundwater discharging to the urban stream, much higher ACE values (0.2‐11 µg/L) indicated that waste water was the likely source of >50% of the nitrate in most samples. This study confirms that ACE is a powerful tracer and demonstrates its use as a diagnostic tool for establishing whether waste water is a significant contributor to groundwater contamination or not.     

Imaging Hydrological Processes in Headwater Riparian Seeps with Time‐Lapse Electrical Resistivity

Delineating hydrologic and pedogenic factors influencing groundwater flow in riparian zones is central in understanding pathways of water and nutrient transport. In this study, we combined two‐dimensional time‐lapse electrical resistivity imaging (ERI) (depth of investigation approximately 2 m) with hydrometric monitoring to examine hydrological processes in the riparian area of FD‐36, a small (0.4 km²) agricultural headwater basin in the Valley and Ridge region of east‐central Pennsylvania. We selected two contrasting study sites, including a seep with groundwater discharge and an adjacent area lacking such seepage. Both sites were underlain by a fragipan at 0.6 m. We then monitored changes in electrical resistivity, shallow groundwater, and nitrate‐N concentrations as a series of storms transitioned the landscape from dry to wet conditions. Time‐lapse ERI revealed different resistivity patterns between seep and non‐seep areas during the study period. Notably, the seep displayed strong resistivity reductions (～60%) along a vertically aligned region of the soil profile, which coincided with strong upward hydraulic gradients recorded in a grid of nested piezometers (0.2‐ and 0.6‐m depth). These patterns suggested a hydraulic connection between the seep and the nitrate‐rich shallow groundwater system below the fragipan, which enabled groundwater and associated nitrate‐N to discharge through the fragipan to the surface. In contrast, time‐lapse ERI indicated no such connections in the non‐seep area, with infiltrated rainwater presumably perched above the fragipan. Results highlight the value of pairing time‐lapse ERI with hydrometric and water quality monitoring to illuminate possible groundwater and nutrient flow pathways to seeps in headwater riparian areas.     

Impact of the Use of Reclaimed Water on the Quality of Groundwater Resources in the Jordan Valley,Jordan

The use of reclaimed water and its impact on groundwater quality in the middle and southern parts of the Jordan Valley are investigated. The chemical analyses indicate that nitrate and bacteriological pollution is widespread, and thus, seriously affects groundwater use. During the study, 365 water samples were collected from wells and springs to determine the water chemistry and the extent of nitrate pollution. Three hydrochemical facies are identifed, i. e., (Ca–(Mg)–Na–HCO₃), (Ca–Na–SO₄–Cl) and (Ca–Na–Cl). The change of facies is accompanied by a gradual increase in the groundwater total dissolved solids (TDS), which is mainly controlled by evaporates and carbonates dissolution in the aquifer matrix. Water analyses indicate that the shallow aquifer in the study area is affected by non‐point pollution sources, primarily from natural (manure) and chemical nitrogen (N)‐fertilizers and treated wastewater used for agriculture. The concentration of nitrate in the groundwater ranges from 10 to 355 mg/L. Considerable seasonal fluctuations in groundwater quality are observed as a consequence of agricultural practices and other factors such as annual rainfall distribution and the Zarqa River flow. The noticeable levels of total coliform and Escherichia coli in the northern part of the study area may be attributed to contamination from the urban areas, intensive livestock production, and illegal dumping of sewage. Heavy metal concentrations in all samples were found to be significantly lower than the permissible limits for drinking water standards.     

Performance Evaluation of a Full‐Scale Extended Aeration System in Al‐Bireh City,Palestine

Major challenges attributed to dysfunctional wastewater treatment facilities in developing countries include lack of commitment and poor informed decision making by the higher municipal administration. This paper presents how process monitoring and control during full scale operation ensures sustainability of civic infrastructures like Al‐Bireh wastewater treatment plant (AWWTP). It is written from the perspective of practical process selection to evaluate the performance of AWWTP, a single‐sludge nitrification–denitrification process with aerobic sludge stabilization. Process monitoring data (July 2000–April 2007) from available monthly operating reports were analyzed and evaluated. Additional data on microbiological analysis and information about facility unit operations were gathered through review of published local literature and interviews with AWWTP personnel. Influent and effluent data evaluated were the chemical oxygen demand (COD), biological oxygen demand (BOD), total nitrogen (TN), and total phosphorus (TP). Despite annual and seasonal variations in AWWTP influent for COD, BOD, TN, and TP, the Palestinian wastewater reuse requirements for restricted irrigation were met. Process design and proper facility operation have direct impacts on effluent quality. The study concludes that regardless of the design capacity and process type, adequate administrative and operational management dictate the sustainability of AWWTP and reuse schemes.     

Genesis of arsenic in groundwater of North Bengal Plain using PCA: A case study of English Bazar Block,Malda District,West Bengal,India

The study area is located on the western part of the alluvium‐filled gap between the Rajmahal hills on the west and the Garo hills on the east. Groundwater occurs under unconfined condition in a thick zone of saturation within the Quaternary alluvial sediments. Three hydrochemical facies with distinct characteristics have been identified which are dominated in general by alkaline earths and weak acids. The major‐ion chemistry of the area is controlled by weathering of silicate minerals, rainfall recharge, ion‐exchange processes and anthropogenic activities such as irrigation return flow and the application of inorganic fertilizers and pesticides. A stoichiometric approach suggests that mineral dissolution and anthropogenic activities contribute 79% and 21% of the total cations dissolved in groundwater. Principal component analysis (PCA) of 42 groundwater samples using 13 chemical parameters indicates that the combined processes of recharge of groundwater from rainfall, sediment water interaction, groundwater flow, infiltration of irrigation return water (which is arsenic rich due to the use of arsenic‐bearing pesticides, wood preservatives, etc. and the pumping of arsenic‐rich groundwater for agriculture purpose), oxidation of natural or anthropogenic organic matter and the reductive dissolution of ferric iron and manganese oxides play a key role in the evolution of groundwater in the study area. Factor 2 scores, associated with the infiltration of irrigation return water and spatial distribution of arsenic concentration reveal that the groundwater of the municipal area will not be affected by arsenic in the future in spite of heavy groundwater abstraction. Another PCA with geologic, geomorphic, anthropogenic, geochemical and landuse factors indicates that arsenic concentration in groundwater increases with increasing area of mango orchards, sand lithofacies and nitrate and decreases with increasing distance of paleochannel from the monitored well and depth of bore wells. High loading on nitrate may be attributed to the use of fertilizer, pesticides, etc. in mango orchards and agricultural land. High loadings on log pCO₂, mango orchards (with negative sign) and phosphate (with positive sign) indicate that mango orchards provide the organic waste material which is decomposed to form organic carbon. The organic carbon undergoes oxidative carbon degeneration by different oxidants and increases the concentration of CO₂ in the aquifer. The reducing condition thus developed in the aquifer helps to dissolve the arsenic adsorbed on iron hydroxide or oxy‐hydroxide coated margins of sand, iron rich heavy mineral grain margins, clay minerals and Fe–Mn concretions present in the aquifer matrix. Copyright © 2007 John Wiley & Sons, Ltd.