Probing the deep critical zone beneath the Luquillo Experimental Forest,Puerto Rico

Recent work has suggested that weathering processes occurring in the subsurface produce the majority of silicate weathering products discharged to the world's oceans, thereby exerting a primary control on global temperature via the well‐known positive feedback between silicate weathering and CO₂. In addition, chemical and physical weathering processes deep within the critical zone create aquifers and control groundwater chemistry, watershed geometry and regolith formation rates. Despite this, most weathering studies are restricted to the shallow critical zone (e.g. soils, outcrops). Here we investigate the chemical weathering, fracturing and geomorphology of the deep critical zone in the Bisley watershed in the Luquillo Critical Zone Observatory, Puerto Rico, from two boreholes drilled to 37.2 and 27.0 m depth, from which continuous core samples were taken. Corestones exposed aboveground were also sampled. Weathered rinds developed on exposed corestones and along fracture surfaces on subsurface rocks slough off of exposed corestones once rinds attain a thickness up to ~1 cm, preventing the corestones from rounding due to diffusion limitation. Such corestones at the land surface are assumed to be what remains after exhumation of similar, fractured bedrock pieces that were observed in the drilled cores between thick layers of regolith. Some of these subsurface corestones are massive and others are highly fractured, whereas aboveground corestones are generally massive with little to no apparent fracturing. Subsurface corestones are larger and less fractured in the borehole drilled on a road where it crosses a ridge compared with the borehole drilled where the road crosses the stream channel. Both borehole profiles indicate that the weathering zone extends to well below the stream channel in this upland catchment; hence weathering depth is not controlled by the stream level within the catchment and not all of the water in the watershed is discharged to the stream. Copyright © 2013 John Wiley & Sons, Ltd.     

Active layer hydrology in an arctic tundra ecosystem: quantifying water sources and cycling using water stable isotopes

Climate change and thawing permafrost in the Arctic will significantly alter landscape hydro‐geomorphology and the distribution of soil moisture, which will have cascading effects on climate feedbacks (CO₂ and CH₄) and plant and microbial communities. Fundamental processes critical to predicting active layer hydrology are not well understood. This study applied water stable isotope techniques (δ²H and δ¹⁸O) to infer sources and mixing of active layer waters in a polygonal tundra landscape in Barrow, Alaska (USA), in August and September of 2012. Results suggested that winter precipitation did not contribute substantially to surface waters or subsurface active layer pore waters measured in August and September. Summer rain was the main source of water to the active layer, with seasonal ice melt contributing to deeper pore waters later in the season. Surface water evaporation was evident in August from a characteristic isotopic fractionation slope (δ²H vs δ¹⁸O). Freeze‐out isotopic fractionation effects in frozen active layer samples and textural permafrost were indistinguishable from evaporation fractionation, emphasizing the importance of considering the most likely processes in water isotope studies, in systems where both evaporation and freeze‐out occur in close proximity. The fractionation observed in frozen active layer ice was not observed in liquid active layer pore waters. Such a discrepancy between frozen and liquid active layer samples suggests mixing of meltwater, likely due to slow melting of seasonal ice. This research provides insight into fundamental processes relating to sources and mixing of active layer waters, which should be considered in process‐based fine‐scale and intermediate‐scale hydrologic models. Copyright © 2016 John Wiley & Sons, Ltd.     

Internal structure of an alpine rock glacier based on crosshole georadar traveltimes and amplitudes

Rapid melting of permafrost in many alpine areas has increased the probability of catastrophic rock slides. In an attempt to provide critical structural information needed for the design and implementation of suitable mitigation procedures, we have acquired low frequency (22 MHz) cross‐hole radar data from within a fast‐moving rock glacier, an important form of alpine permafrost. Since the ice, rock and pockets of water and air found in the underground of high alpine areas have very different dielectric permittivities and electrical conductivities, the radar method was well‐suited for investigating the structure and state of the rock glacier. Our interpretation of the radar velocities and attenuations was constrained by geomorphological observations, borehole lithological logs and the results of a surface seismic survey. The radar data revealed the existence of a discontinuous 7–11 m thick ice‐rich zone distinguished by high velocities (0.14–0.17 m/ns) and low attenuations (0.04–0.09 m^?1) and a thin underlying ice‐free zone characterized by moderate velocities (0.11–0.12 m/ns) and low attenuations (0.04–0.09 m^?1). Beneath these two zones, we observed a prominent band of high velocities (0.14–0.17 m/ns) and moderately high attenuations (0.10–0.20 m^?1) associated with unconsolidated glacial sediments and numerous large air‐filled voids, which in the past were probably filled with ice. At greater depths, the variably dry to water‐saturated sediments were represented by generally lower velocities (0.08–0.10 m/ns) and higher attenuations (0.16–0.24 m^?1). The bedrock surface was represented by an abrupt ～0.03 m/ns velocity increase. We speculate that the disappearance of ice, both laterally and with depth, occurred during the past one to two decades.     

Applications of Dual-Wall Reverse-Circulation Drilling in Ground Water Exploration and Monitoring

Dual-wall reverse-circulation drilling uses flush-threaded double-wall drill pipe and high-pressure air to provide continuous return of formation and water samples. Cuttings and formation waters are not contaminated with drilling additives or mixed with other borehole material. Up-hole velocity of about 70 ft/sec provides reliable logging of water, mineral or contaminant-bearing strata. Water samples representative of specific strata may be airlifted or bailed to the surface.
In the percussion hammer system, dual-wall drill pipe is advanced through chiefly unconsolidated material by the percussion action of an above-ground pile hammer. The borehole is drilled and temporarily cased in one pass. Wells or monitoring devices are installed as the drill pipe is hydraulically retracted during construction. A rotary head may be adapted as an option to allow dual-wall rotary drilling into consolidated or crystalline formations through a percussion hammer drill string temporarily left in place as a conductor.
The complex geology and variety of geoenvironmental problems in southern California has provided a testing ground for dual-wall drilling on hazardous material site investigations. Several case histories have demonstrated the capabilities and versatility of this method, including: (1) the installation of 4-inch and 6-inch diameter gasoline monitoring and recovery wells through gravels and cobbles at a filling station where hollow-stem auger drilling failed; (2) the confirmation of a dry borehole initially drilled by direct rotary at a landfill; and (3) multiple installations of monitoring devices through municipal refuse at a city of Los Angeles landfill.     

A Stream‐Based Methane Monitoring Approach for Evaluating Groundwater Impacts Associated with Unconventional Gas Development

Gaining streams can provide an integrated signal of relatively large groundwater capture areas. In contrast to the point‐specific nature of monitoring wells, gaining streams coalesce multiple flow paths. Impacts on groundwater quality from unconventional gas development may be evaluated at the watershed scale by the sampling of dissolved methane (CH₄) along such streams. This paper describes a method for using stream CH₄ concentrations, along with measurements of groundwater inflow and gas transfer velocity interpreted by 1‐D stream transport modeling, to determine groundwater methane fluxes. While dissolved ionic tracers remain in the stream for long distances, the persistence of methane is not well documented. To test this method and evaluate CH₄ persistence in a stream, a combined bromide (Br) and CH₄ tracer injection was conducted on Nine‐Mile Creek, a gaining stream in a gas development area in central Utah. A 35% gain in streamflow was determined from dilution of the Br tracer. The injected CH₄ resulted in a fivefold increase in stream CH₄ immediately below the injection site. CH₄ and δ¹³C_CH4 sampling showed it was not immediately lost to the atmosphere, but remained in the stream for more than 2000 m. A 1‐D stream transport model simulating the decline in CH₄ yielded an apparent gas transfer velocity of 4.5 m/d, describing the rate of loss to the atmosphere (possibly including some microbial consumption). The transport model was then calibrated to background stream CH₄ in Nine‐Mile Creek (prior to CH₄ injection) in order to evaluate groundwater CH₄ contributions. The total estimated CH₄ load discharging to the stream along the study reach was 190 g/d, although using geochemical fingerprinting to determine its source was beyond the scope of the current study. This demonstrates the utility of stream‐gas sampling as a reconnaissance tool for evaluating both natural and anthropogenic CH₄ leakage from gas reservoirs into groundwater and surface water.     

Assessing Methane in Shallow Groundwater in Unconventional Oil and Gas Play Areas,Eastern Kentucky

The expanding use of horizontal drilling and hydraulic fracturing technology to produce oil and gas from tight rock formations has increased public concern about potential impacts on the environment, especially on shallow drinking water aquifers. In eastern Kentucky, horizontal drilling and hydraulic fracturing have been used to develop the Berea Sandstone and the Rogersville Shale. To assess baseline groundwater chemistry and evaluate methane detected in groundwater overlying the Berea and Rogersville plays, we sampled 51 water wells and analyzed the samples for concentrations of major cations and anions, metals, dissolved methane, and other light hydrocarbon gases. In addition, the stable carbon and hydrogen isotopic composition of methane (δ¹³C‐CH₄ and δ²H‐CH₄) was analyzed for samples with methane concentration exceeding 1 mg/L. Our study indicates that methane is a relatively common constituent in shallow groundwater in eastern Kentucky, where methane was detected in 78% of the sampled wells (40 of 51 wells) with 51% of wells (26 of 51 wells) exhibiting methane concentrations above 1 mg/L. The δ¹³C‐CH₄ and δ²H‐CH₄ ranged from ?84.0‰ to ?58.3‰ and from ?246.5‰ to ?146.0‰, respectively. Isotopic analysis indicated that dissolved methane was primarily microbial in origin formed through CO₂ reduction pathway. Results from this study provide a first assessment of methane in the shallow aquifers in the Berea and Rogersville play areas and can be used as a reference to evaluate potential impacts of future horizontal drilling and hydraulic fracturing activities on groundwater quality in the region.     

Thermal condition of Surtsey

The island Surtsey was created by a submarine volcanic eruption which started on the 14th of November 1963, 21 km southwest of the Westman Islands. Volcanic activity continued in this area for nearly 4 years. During the summer of 1979 a 181 m deep continuously cored borehole was drilled on the Surtsey island. Several temperature profiles have been measured in the hole since 1979. The results of these temperature measurements are used as the basis for a discussion of the thermal condition of Surtsey. The hypothesis that intrusions rather than pillow lavas are responsible for the excess heat content of Surtsey is favored. It is found that the 13 m thick discontinuous dike complex, observed in the drill core, is sufficient to explain the excess heat content in the vicinity of the borehole and the shape of the temperature profiles recorded. It is demonstrated that the heat transfer in Surtsey has been dominated by hydrothermal convection and that the system is vapor dominated above sea level. It is estimated that the permeability of a 40 m thick section of altered tuff below sea level is 4.1 × 10⁻¹³ m², while the permeability of the unaltered tuff above sea level is estimated as 1.2 × 10⁻¹⁰ m².     

Burying receivers for improved time‐lapse seismic repeatability: CO2CRC Otway field experiment

4D seismic is widely used to remotely monitor fluid movement in subsurface reservoirs. This technique is especially effective offshore where high survey repeatability can be achieved. It comes as no surprise that the first 4D seismic that successfully monitored the CO₂ sequestration process was recorded offshore in the Sleipner field, North Sea. In the case of land projects, poor repeatability of the land seismic data due to low S/N ratio often obscures the time‐lapse seismic signal. Hence for a successful on shore monitoring program improving seismic repeatability is essential. Stage 2 of the CO2CRC Otway project involves an injection of a small amount (around 15,000 tonnes) of CO₂/CH₄ gas mixture into a saline aquifer at a depth of approximately 1.5 km. Previous studies at this site showed that seismic repeatability is relatively low due to variations in weather conditions, near surface geology and farming activities. In order to improve time‐lapse seismic monitoring capabilities, a permanent receiver array can be utilised to improve signal to noise ratio and hence repeatability. A small‐scale trial of such an array was conducted at the Otway site in June 2012. A set of 25 geophones was installed in 3 m deep boreholes in parallel to the same number of surface geophones. In addition, four geophones were placed into boreholes of 1–12 m depth. In order to assess the gain in the signal‐to‐noise ratio and repeatability, both active and passive seismic surveys were carried out. The surveys were conducted in relatively poor weather conditions, with rain, strong wind and thunderstorms. With such an amplified background noise level, we found that the noise level for buried geophones is on average 20 dB lower compared to the surface geophones. The levels of repeatability for borehole geophones estimated around direct wave, reflected wave and ground roll are twice as high as for the surface geophones. Both borehole and surface geophones produce the best repeatability in the 30–90 Hz frequency range. The influence of burying depth on S/N ratio and repeatability shows that significant improvement in repeatability can be reached at a depth of 3 m. The level of repeatability remains relatively constant between 3 and 12 m depths.     

Generation of Hydrogen Gas as a Result of Drilling Within the Saturated Zone

Hydrogen gas was discovered within the steel casing above standing water in a percussion-drilled borehole on the Hanlord Site in south-central Washington state. In situ measurements of the borehole fluids indicated anoxic, low-Eh (<-400 mV) conditions. Ground water sampled from adjacent wells in the same formation indicated that the ground water was oxygenated. H₂ was generated during percussion drilling, due to the decomposition of borehole waters as a result of aqueous reactions with drilled sediment and steel from the drilling tools or casing. The generation of H₂ within percussion-drilled boreholes that extend below the water table may be more common than previously realized. The ambient concentration of H₂ produced during drilling was limited by microbial activity within the casing-resident fluids. H₂ was generated abiotically in the laboratory, whereby sterilized borehole slurry samples produced 100 times more H₂ than unsterilizcd samples. It appears that H₂ is metabolized by microorganisms and concentrations might be significantly greater if not for microbial metabolism.     

Probing deep weathering in the Shale Hills Critical Zone Observatory,Pennsylvania (USA): the hypothesis of nested chemical reaction fronts in the subsurface

Weathering is both an acid‐base and a redox reaction in which rocks are titrated by meteoric carbon dioxide (CO₂) and oxygen (O₂). In general, the depths of these weathering reactions are unknown. To determine such depths, cuttings of Rose Hill shale were investigated from one borehole from the ridge and four boreholes from the valley at the Susquehanna Shale Hills Observatory (SSHO). Pyrite concentrations are insignificant to depths of 23 m under the ridge and 8–9 m under the valley. Likewise, carbonate concentrations are insignificant to 22 and 2 m, respectively. In addition, a 5–6 m‐thick fractured layer directly beneath the land surface shows evidence for loss of illite, chlorite, and feldspar. Under the valley, secondary carbonates may have precipited. The limited number of boreholes and the tight folding make it impossible to prove that depth variations result from weathering instead of chemical heterogeneity within the parent shale. However, carbonate depletion coincides with the winter water table observed at ~20 m (ridge) and ~2 m depth (valley). It would be fortuitous if carbonate‐containing strata are found under ridge and valley only beneath the water table. Furthermore, pyrite and carbonate react quickly and many deep reaction fronts for these minerals are described in the literature. We propose that deep transport of O₂ initiates weathering at SSHO and many other localities because pyrite commonly oxidizes autocatalytically to acidify porewaters and open porosity. According to this hypothesis, the mineral distributions at SSHO are nested reaction fronts that overprint protolith stratigraphy. The fronts are hypothesized to lie subparallel to the land surface because O₂ diffuses to the water table and causes oxidative dissolution of pyrite. Pyrite‐derived sulfuric acid (H₂SO₄) plus CO₂ also dissolve carbonates above the water table. To understand how reaction fronts record long‐term coupling between erosion and weathering will require intensive mapping of the subsurface. Copyright © 2013 John Wiley & Sons, Ltd.     

Estimating the permeability of the Nojima Fault Zone by a hydrophone vertical seismic profiling experiment

Abstract A multi-offset hydrophone vertical seismic profiling (VSP) experiment was done in a 747 m deep borehole at Nojima Hirabayashi, Hyogo prefecture, Japan. The borehole was drilled to penetrate the Nojima Fault, which was active in the 1995 Hyogo-ken Nanbu earthquake. The purpose of the hydrophone VSP is to detect subsurface permeable fractures and permeable zones and, in the present case, to estimate the permeability of the Nojima Fault. The analysis was based on a model by which tube waves are generated when incident P-waves compress the permeable fractures (or permeable zones) intersecting the borehole and a fluid in the fracture is injected into the borehole. Permeable fractures (or permeable zones) are detected at the depths of tube wave generation, and fracture permeability is calculated from the amplitude ratio of tube wave to incident P-wave. Several generations of tube waves were detected from the VSP sections. Distinct tube waves were generated at depths of the fault zone that are characterized by altered and deformed granodiorite with a fault gouge, suggesting that permeable fractures and permeable zones exist in the fault zone. Tube wave analysis shows that the permeability of the fault gouge from 624 m to 625 m is estimated to be approximately 2 × 10⁻¹² m².     

Fluid inclusions and preliminary studies of hydrothermal alteration in core hole PLTG-1, Platanares geothermal area, Honduras

The Platanares geothermal area in western Honduras consists of more than 100 hot springs that issue from numerous hot-spring groups along the banks or within the streambed of the Quebrada de Agua Caliente (brook of hot water). Evaluation of this geothermal area included drilling a 650-m deep PLTG-1 drill hole which penetrated a surface mantling of stream terrace deposits, about 550 m of Tertiary andesitic lava flows, and Cretaceous to lower Tertiary sedimentary rocks in the lower 90 m of the drill core.Fractures and cavities in the drill core are partly to completely filled by hydrothermal minerals that include quartz, kaolinite, mixed-layer illite-smectite, barite, fluorite, chlorite, calcite, laumontite, biotite, hematite, marcasite, pyrite, arsenopyrite, stibnite, and sphalerite; the most common open-space fillings are calcite and quartz. Biotite from 138.9-m depth, dated at 37.41 Ma by replicate ⁴⁰Ar/³⁹ Ar analyses using a continuous laser system, is the earliest hydrothermal mineral deposited in the PLTG-1 drill core. This mid-Tertiary age indicates that at least some of the hydrothermal alteration encountered in the PLTG-1 drill core occured in the distant past and is unrelated to the present geothermal system. Furthermore, homogenization temperatures (T_h) and melting-point temperatures (T_m) for fluid inclusions in two of the later-formed hydrothermal minerals, calcite and barite, suggest that the temperatures and concentration of dissolved solids of the fluids present at the time these fluid inclusions formed were very different from the present temperatures and fluid chemistry measured in the drill hole.Liquid-rich secondary fluid inclusions in barite and caicite from drill hole PLTG-1 have T_h values that range from about 20°C less than the present measured temperature curve at 590.1-m depth to as much as 90°C higher than the temperature curve at 46.75-m depth. Many of the barite T_h measurements (ranging between 114° and 265°C) plot above the reference surface boiling-point curve for pure water assuming hydrostatic conditions; however, the absence of evidence for boiling in the fluid inclusions indicates that at the time the minerals formed, the ground surface must have been at least 80 m higher than at present and underwent stream erosion to the current elevation. Near-surface mixed-layer illite-smectite is closely associated with barite and appears to have formed at about the same temperature range (about 120° to 200°C) as the fluid-inclusion T_hvalues for barite. Fluid-inclusion T_h values for calcite range between about 136° and 213°C. Several of the calcite T_h values are significantly lower than the present measured temperature curve. The melting-point temperatures (T_m) of fluid-inclusion ice yield calculated salinities, ranging from near zero to as much as 5.4 wt. % NaCl equivalent, which suggest that much of the barite and calcite precipitated from fluids of significantly greater salinity than the present low salinity Platanares hot-spring water or water produced from the drill hole.     

Dispersion and radial depth of investigation of borehole modes

Sonic techniques in geophysical prospecting involve elastic wave velocity measurements that are performed by placing acoustic transmitters and receivers in a fluid‐filled borehole. The signals recorded at the receivers are processed to obtain compressional‐ and shear‐wave velocities in the surrounding formation. These velocities are generally used in seismic surveys for the time‐to‐depth conversion and other formation parameters, such as porosity and lithology. Depending upon the type of transmitter used (e.g. monopole or dipole) and as a result of eccentering, it is possible to excite axisymmetric (n= 0) , flexural (n= 1) and quadrupole (n= 2) families of modes propagating along the borehole. We present a study of various propagating and leaky modes that includes their dispersion and attenuation characteristics caused by radiation into the surrounding formation. A knowledge of propagation characteristics of borehole modes helps in a proper selection of transmitter bandwidth for suppressing unwanted modes that create problems in the inversion for the compressional‐ and shear‐wave velocities from the dispersive arrivals. It also helps in the design of a transmitter for a preferential excitation of a given mode in order to reduce interference with drill‐collar or drilling noise for sonic measurements‐while‐drilling. Computational results for the axisymmetric family of modes in a fast formation with a shear‐wave velocity of 2032 m/s show the existence of Stoneley, pseudo‐Rayleigh and anharmonic cut‐off modes. In a slow formation with a shear‐wave velocity of 508 m/s, we find the existence of the Stoneley mode and the first leaky compressional mode which cuts in at approximately the same normalized frequency ωa/V_S= 2.5 (a is the borehole radius) as that of the fast formation. The corresponding modes among the flexural family include the lowest‐order flexural and anharmonic cut‐off modes. For both the fast and slow formations, the first anharmonic mode cuts in at a normalized frequency ωa/V_S= 1.5 approximately. Cut‐off frequencies of anharmonic modes are inversely proportional to the borehole radius in the absence of any tool. The borehole quadrupole mode can also be used for estimating formation shear slownesses. The radial depth of investigation with a quadrupole mode is marginally less than that of a flexural mode because of its higher frequency of excitation.     

Spatial–temporal variations of methane emissions from the Ertan hydroelectric reservoir in southwest China

Methane emissions from hydroelectric reservoirs can comprise a considerable portion of anthropogenic methane. However, lack of data on CH₄ emissions in different geographical regions and high spatial‐temporal variability in the emission rates of reservoirs has led to uncertainties regarding regional emission estimates of CH₄. In the subtropical plateau climate region, we used the Ertan hydroelectric reservoir as a study area. The CH₄ flux at the air‐water interface was assessed by floating chambers and factors influencing emissions, including the distance from the dam, water depth, seasonal variation in wet and dry season, air‐water temperature gradient and wind speed, and was also studied through a year‐long systematic sampling and monitoring experiment. The results showed that the surface of the reservoir was a source of CH₄ during the sampling period and the annual average CH₄ flux was 2·80 ± 1·52 mg m^?2 d^?1. CH₄ flux (and its variation) was higher in the shallow water areas than in the deep‐water areas. CH₄ flux near the dam was significantly higher than that of other locations farther from the dam in the dry season. The seasonal variations of CH₄ emission in wet and dry seasons were minor and significant diurnal variations were observed in wet and dry seasons. Exponential relationships between the CH₄ flux and air‐water temperature gradient were found. Air‐water temperature gradient was an important factor influencing diurnal variations of CH₄ flux in the Ertan hydroelectric reservoir. These results indicate that systematic sampling is needed to better estimate CH₄ flux through coverage of the spatial variation of different water depths, measuring‐point distance from the dam, seasonal variation in wet and dry seasons and changes in climate factors (such as air‐water temperature gradient). Our results also provide a fundamental parameter for CH₄ emission estimation of global reservoirs. Copyright © 2010 John Wiley & Sons, Ltd.     

Using hydrogeochemical data to trace groundwater flow paths in a cold alpine catchment

Significant uncertainty remains in understanding the groundwater flow pathways in the northeastern Qinghai–Tibet Plateau. Hydrogeochemical and isotopic data as well as hydrogeological data were combined to explore the groundwater flow path in a representative cold alpine catchment in the headwater region of the Heihe River. The results indicate that the suprapermafrost groundwater chemical components were mainly affected by calcite dissolution and evaporation, whereas the geochemistry of subpermafrost groundwater was controlled by dolomite and gypsum dissolution, calcite precipitation, and albite and halite dissolution. Distinct hydrogeochemical characteristics and controlling processes suggest a poor hydraulic connectivity between the suprapermafrost and subpermafrost groundwater. The hydraulic connectivity between permafrost groundwater and groundwater in the seasonally frozen area was confirmed by their similar hydrogeochemical features. In the seasonally frozen area, a silty clay layer with low permeability separates the aquifer into the deep (depth >20 m) and shallow (depth <20 m) flow paths. The deep groundwater was characterized by the enhanced dedolomitization and enhanced cation exchange processes compared with the shallow groundwater. Groundwater in the seasonally frozen area finally discharges as base flow into the stream. These results provide useful information about the groundwater flow systems in the unique alpine gorge catchments in Qinghai–Tibet Plateau. The above findings suggest that the permafrost distribution and the aquifer structures within the seasonally frozen area have significant impact on groundwater flow paths. Cross‐validation by drilling work and hydrograph data confirms that the hydrogeochemical and isotopic tracers combined with field investigations can be relatively low‐cost tools in interpreting the groundwater flow paths in similar alpine catchments.     

VARIABILITY IN THE CHEMICAL COMPOSITION OF IN SITU SUBGLACIAL MELTWATERS

Meltwaters collected from boreholes drilled to the base of the Haut Glacier d'Arolla, Switzerland have chemical compositions that can be classified into three main groups. The first group is dilute, whereas the second group is similar to, though generally less concentrated in major ions, than contemporaneous bulk glacial runoff. The third group is more concentrated than any observed bulk runoff, including periods of flow recession. Waters of the first group are believed to represent supraglacial meltwater and ice melted during drilling. Limited solutes may be derived from interactions with debris in the borehole. The spatial pattern of borehole water levels and borehole water column stratification, combined with the chemical composition of the different groups, suggest that the second group represent samples of subglacial waters that exchange with channel water on a diurnal basis, and that the third group represent samples of water draining through a ‘distributed’ subglacial hydraulic system. High NO⁻₃ concentrations in the third group suggest that snowmelt may provide a significant proportion of the waters and that the residence time of the waters at the bed in this particular section of the distributed system is of the order of a few months. The high NO⁻₃ concentrations also suggest that some snowmelt is routed along different subglacial flowpaths to those used by icemelt. The average SO²⁻₄: (HCO⁻₃ + SO²⁻₄) ratio of the third group of meltwaters is 0.3, suggesting that sulphide oxidation and carbonate dissolution (which gives rise to a ratio of 0.5) cannot provide all the HCO⁻₃ to solution. Hence, carbonate hydrolysis may be occurring before sulphide oxidation, or there may be subglacial sources of CO₂, perhaps arising from microbial oxidation of organic C in bedrock, air bubbles in glacier ice or pockets of air trapped in subglacial cavities. The channel marginal zone is identified as an area that may influence the composition of bulk meltwater during periods of recession flow and low diurnal discharge regimes. © 1997 by John Wiley & Sons, Ltd.     

Epigenetic salt accumulation and water movement in the active layer of central Yakutia in eastern Siberia

Observations of soil moisture and salt content were conducted from May to August at Neleger station in eastern Siberia. Seasonal changes of salt and soil moisture distribution in the active layer of larch forest (undisturbed) and a thermokarst depression known as an alas (disturbed) were studied. Electric conductivity EC_e of the intact forest revealed higher concentrations that increased with depth from the soil surface into the active layer and the underlying permafrost: 1 mS cm^?1 at 1·1 m, to 2·6 mS cm^?1 at 160 cm depth in the permafrost. However, a maximum value of 5·4 mS cm^?1 at 0·6 m depth was found in the dry area of the alas. The concentration of ions, especially Na⁺, Mg²⁺, Ca²⁺, SO₄^2? and HCO₃^? in the upper layers of this long‐term disturbed site, indicates the upward movement of ions together with water. A higher concentration of solutes was found in profiles with deeper seasonal thawing. The accumulation of salts in the alas occurs from spring through into the growing season. The low concentration of salt in the surface soil layers appears to be linked to leaching of salts by rainfall. There are substantial differences between water content and electric conductivity of soil in the forest and alas. Modern salinization of the active layer in the alas is epigenetic, and it happens in summer as a result of spring water collection and high summer evaporation; the gradual salt accumulation in the alas in comparison with the forest is controlled by the annual balance of water and salts in the active layer. Present climatic trends point to continuous permafrost degradation in eastern Siberia increasing the risk of surface salinization, which has already contributed to changing the landscape by hindering the growth of forest. Copyright © 2006 John Wiley & Sons, Ltd.     

Vertical cross contamination of trichloroethylene in a borehole in fractured sandstone

Boreholes drilled through contaminated zones in fractured rock create the potential for vertical movement of contaminated ground water between fractures. The usual assumption is that purging eliminates cross contamination; however, the results of a field study conducted in a trichloroethylene (TCE) plume in fractured sandstone with a mean matrix porosity of 13% demonstrates that matrix-diffusion effects can be strong and persistent. A deep borehole was drilled to 110 m below ground surface (mbgs) near a shallow bedrock well containing high TCE concentrations. The borehole was cored continuously to collect closely spaced samples of rock for analysis of TCE concentrations. Geophysical logging and flowmetering were conducted in the open borehole, and a removable multilevel monitoring system was installed to provide hydraulic-head and ground water samples from discrete fracture zones. The borehole was later reamed to complete a well screened from 89 to 100 mbgs; persistent TCE concentrations at this depth ranged from 2100 to 33,000 microg/L. Rock-core analyses, combined with the other types of borehole information, show that nearly all of this deep contamination was due to the lingering effects of the downward flow of dissolved TCE from shallower depths during the few days of open-hole conditions that existed prior to installation of the multilevel system. This study demonstrates that transfer of contaminant mass to the matrix by diffusion can cause severe cross contamination effects in sedimentary rocks, but these effects generally are not identified from information normally obtained in fractured-rock investigations, resulting in potential misinterpretation of site conditions.     

Successful sidetracking of a well onshore Germany by integration of 3D vertical seismic profiling technology – a case study

The exploration for and exploitation of deep Lower Rotliegend gasfields onshore in North Germany often suffers from poor surface seismic imaging. This is owing to the depth of the reservoirs and a thick and complex Zechstein salt overburden. RWE Dea conducted a 3D vertical seismic profile (VSP) survey in a low‐performing production well after the borehole was plugged near total depth. Our main objective was to improve the seismic image of the reservoir zone in the vicinity of the well to determine a new landing point for a planned sidetrack. Because acquisition was in a densely populated and also partially environmentally protected area, there were surface restrictions concerning source deployment. Additionally, due to the complex geological setting, we conducted two 2D VSP field tests and thorough pre‐survey modelling to achieve the best results in terms of seismic imaging, environmental impact and reasonable cost. Deformation bands in the drill core suggest that the initial well was drilled close to a major fault, which was regarded as the main reason for the disappointing production rate. Therefore, we put special emphasis on fault detection in our processing and interpretation. Our interpretation approach used an enhanced structural mapping workflow that helped to design a sidetrack. When the sidetrack was drilled two years later, it ended up being one of the most productive wells in the field.     

Biofilm Detection in a Model Well‐Bore Environment Using Low‐Field NMR

This research addresses the challenges of the lack of non‐invasive methods and poor spatiotemporal resolution associated with monitoring biogeochemical activity central to bioremediation of subsurface contaminants. Remediation efforts often include growth of biofilm to contain or degrade chemical contaminants, such as nitrates, hydrocarbons, heavy metals, and some chlorinated solvents. Previous research indicates that nuclear magnetic resonance (NMR) is sensitive to the biogeochemical processes of biofilm accumulation. The current research focuses on developing methods to use low‐cost NMR technology to support in situ monitoring of biofilm growth and geochemical remediation processes in the subsurface. Biofilm was grown in a lab‐scale radial flow bioreactor designed to model the near wellbore subsurface environment. The Vista Clara Javelin NMR logging device, a slim down‐the‐borehole probe, collected NMR measurements over the course of eight days while biofilm was cultivated in the sand‐packed reactor. Measured NMR mean log T₂ relaxation times decreased from approximately 710 to 389 ms, indicating that the pore environment and bulk fluid properties were changing due to biofilm growth. Destructive sampling employing drop plate microbial population analysis and scanning electron and stereoscopic microscopy confirmed biofilm formation. Our findings demonstrate that the NMR logging tool can detect small to moderate changes in T₂ distribution associated with environmentally relevant quantities of biofilm in quartz sand.