MAJOR ELEMENT COMPOSITIONAL VARIATION WITHIN AND BETWEEN DIFFERENT LATE EOCENE MICROTEKTITE STREWNFIELDS

Major element compositional overlap exists between microspherules of different microtektite layers or strewnfields. For this reason, microspherules of similar composition cannot, a priori, be assumed to belong to the same microtektite event and those of different compositions cannot, a priori, be assumed to result from different events. Nevertheless, despite major element compositional overlap between microspherules of different strewnfields, multivariate factor analysis shows microtektites and related microspherules of three stratigraphically different late Eocene layers to follow recognizably different compositional trends. The microtektite population of the North American strewnfield (Globorotalia cerroazulensis Zone) follows compositionally well defined trends and is characterized by high concentrations of SiO₂, Al₂O₃, and TiO₂. The microspherule population of the slightly older crystal-bearing Globorotalia cerroazulensis Zone microspherule layer is more heterogeneous and characterized by microspherules which are relatively enriched in FeO and MgO and relatively impoverished in SiO₂ and TiO₂. The microspherule population of the oldest microspherule layer in the uppermost Globigerapsis semiinvoluta Zone is highly heterogeneous and characterized by microspherules which are relatively enriched in CaO and impoverished in Al₂O₃ and Na₂O. Individual microspherules of this oldest late Eocene horizon often exhibit major element compositions similar to those of the lower Gl. cerroazulensis Zone layer and occasionally exhibit major element compositions similar to North American layer microtektites. Nevertheless, late Eocene microspherule occurrences can be assigned to appropriate late Eocene microtektite horizons on the basis of major element compositional trends.     

The Cuban Tektite Revisited

Abstract— A tektite, probably found in Cuba, was previously classified as belonging to the North American tektite strewn field on the basis of chemistry, age, isotopic, and petrographic characteristics. New major element analyses and trace element analyses show that the sample falls within the range of other North American tektites, and is close to the bediasite compositions. There are, however, some differences to normal georgiaites and bediasites. In a Na₂O/K₂O diagram the sample plots between the two distinct fields formed by georgiaites and bediasites. The rare earth elements and some lithophile trace elements are slightly enriched compared to bediasites, and much higher than in georgiaites. The discovery of tektite fragments from locations at Barbados and a DSDP site off the coast of New Jersey makes it likely that the North American strewn field is larger than previously thought, in agreement with microtektite distributions. Thus it is possible that the “Cuban” tektite really originated from Cuba.     

North American tektite debris and impact ejecta from DSDP Site 612

Abstract— A layer of tektite glass and shock-metamorphosed grains found in an upper Eocene section of core 21 from DSDP Site 612 taken on the continental slope off New Jersey may belong to the North American tektite strewn field. However, the Site 612 glasses generally have higher K₂O and lower Na₂O contents for a given SiO₂ content and different Sr and Nd isotopic compositions. In order to better define the layer, a series of samples was taken continuously through the layer at 1 cm intervals. Tektite fragments are in an 8 cm thick layer; microtektites are concentrated in the upper 4 cm, while spherules with “crystalline” textures (microkrystites) are concentrated in the lower half of the layer. Millimeter-size splash forms are mostly in the lower part of the tektite-bearing layer. Rock and mineral grains showing evidence of shock metamorphism are abundant in the upper half of the tektite-bearing layer. Coesite is abundant, and stishovite was found in one rock fragment. The size and abundance of the tektite glass and the abundance of shocked debris indicate that Site 612 is relatively close to the source crater, which may be to the north of Site 612 on the coastal plain or adjacent continental shelf.     

Nd and Sr isotopic evidence for the origin of tektite material from DSDP site 612 off the New Jersey coast

Abstract— Late Eocene tektite material from DSDP site 612 is composed of angular to spherical tektites and microtektites containing abundant vesicles and a few unmelted to partially melted mineral inclusions. The major element compositions of the 612-tektites are generally comparable to those of North American tektites, but the physical features suggest that the DSDP-612 tektites were formed by less severe shock melting. The ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd compositions of 612-tektites: a) show much wider ranges than the tightly constrained group of North American tektites and microtektites, and b) are significantly different from those of other groups of tektites. The existence of large isotopic variations in tektites from DSDP site 612 requires that they were formed from a chemically and isotopically heterogeneous material in a regime that is distinctive from that of other groups of tektites. T^ND_CHUR and T^Sr_UR model ages of the 612-tektites indicate that they were formed from a crustal source of late Precambrian mean age (800–1000 Ma) which in middle Palaeozoic time (?400 Ma) was further enriched in Rb/Sr during sedimentary processes. These source characteristics suggest that the impact which produced the 612-tektites occurred in rocks of the Appalachian orogeny or sediments derived from this orogenic belt. Potential source materials for both 612-tektites and North American tektites are present on the eastern and southeastern part of the North American continent and its adjacent shelf. The distinct isotopic differences between 612-tektites and North American tektites indicate that the two groups of tektites were either formed by the impact of more than one bolide in the same general area, or by a single impact event that sampled different layers.     

Upper Eocene tektite and impact ejecta layer on the continental slope off New Jersey

Abstract— During Leg 150 of the Ocean Drilling Project (ODP), two sites (903C and 904A) were cored that have sediments of the same biostratigraphic age as the upper Eocene tektite-bearing ejecta layer at Deep Sea Drilling Project (DSDP) Site 612. Core 45X from ODP Site 904A (～4 km north of Site 612) contains a 5 cm thick tektite-bearing ejecta layer, and Core 56 from Site 903C (～8 km north-northwest of Site 904) contains a 2 cm thick layer of impact ejecta without any tektite or impact glass. Shocked quartz and feldspar grains, with multiple sets of planar deformation features (PDFs), and abundant coesite-bearing grains are present at both sites. The major oxide contents, trace element compositions, and rare earth element (REE) patterns of the Site 904 tektites are similar to those of the Site 612 tektites and to North American tektites (especially bediasites). The ?_Sr and ?_Nd values for one composite tektite sample from Site 904 fall within the range previously obtained for the Site 612 tektites, which defines a linear trend that, if extrapolated, would intersect the values obtained for North American tektites. The water contents of eight tektite fragments from Site 904 range from 0.017 to 0.098 wt%, and, thus, are somewhat higher than is typical for tektites. The heavy mineral assemblages of the 63–125 μm size fractions from the ejecta layers at Sites 612, 903, and 904 are all similar. Therefore, we conclude that the ejecta layer at all three sites is from the same impact event and that the tektites at Sites 904 and 612 belong to the North American tektite strewn field. Clinopyroxene-bearing (cpx) spherules occur below, or in the lower part of, the main ejecta layer at all three sites. At all three sites, the cpx spherules have been partly or completely replaced with pyrite that preserved the original crystalline textures. Site 612, 903, and 904 cpx spherules are similar to those found in the Caribbean Sea, Gulf of Mexico, central equatorial Pacific, western equatorial Pacific, and eastern Indian Ocean. The cpx event appears to have preceded the North American tektite event by 10–15 ka or less. The fining-upward sequence at all three sites and concentration of the denser, unmelted impact ejecta at the top of the tektite layer at Sites 612 and 904 suggest that the tektite-bearing ejecta layers are not the result of downslope redeposition and that the unmelted ejecta landed after the glass. Geographic variations in thickness of the tektite-bearing ejecta layer, the lack of carbonate clasts in the ejecta layer, and the low CaO content of the tektite glass suggest that the ejecta (including the tektite glass) were derived from the Chesapeake Bay structure rather than from the Toms Canyon structure. A sharp decline in microfossil abundances suggests that local environmental changes caused by the impact may have had adverse effects on benthic foraminifera, radiolaria, sponges, and fish as well as the planktic foraminifera.     

Sr and Nd analyses of upper Eocene spherules and their implications for target rocks

Abstract— Upper Eocene impact ejecta has been discovered all over the world. The number of upper Eocene impact layers and the geographic distribution of each layer, based on major chemical composition and biostratigraphic data, are not agreed upon. We have performed four Sr‐Nd isotopic analyses of clinopyroxene‐bearing spherules (cpx spherules) and three Sr‐Nd analyses of microtektites from five Deep Sea Drilling Project/Ocean Drilling Program (DSDP/ODP) sites in the South Atlantic and Indian Oceans. Our data support the hypothesis that there is only one cpx spherule layer in upper Eocene sediments. We also find that the microtektites associated with the cpx spherule layer in the South Atlantic and Indian Oceans are not part of the North American tektite strewn field, but belong to the same event that produced the cpx spherules. The microtektites, together with cpx spherules, are more heterogeneous than microtektites/tektites from other strewn fields. No direct link has been established between the microtektites from this study and possible target rock at the Popigai crater.     

Australasian microtektites from Antarctica: XAS determination of the Fe oxidation state

The Fe oxidation state and coordination number of 29 impact glass spherules recently recovered from the Transantarctic Mountains (Antarctica) have been determined by X‐ray absorption near edge structure (XANES) spectroscopy. Based on geochemical, isotopic, and fission track data, these spherules are considered as microtektites from the Australasian tektite/microtektite strewn field. Their find location is the farthest so far discovered from the possible source crater region, and their alkali content is the lowest compared with other published data on Australasian microtektite glasses. The Fe³⁺/(Fe²⁺+Fe³⁺) ratio, determined from the analysis of the pre‐edge peak energy position and integrated intensity, is below 0.1 (±0.04) for all the samples, and is comparable to that of most tektites and microtektites from the Australasian strewn field. Also, the pre‐edge peak integrated intensity, which is sensitive to the average Fe coordination geometry, is comparable to that of other Australasian microtektites reported in the literature. The agreement of the Fe oxidation state and coordination number, between the Transantarctic Mountain microtektites (TAM) and the Australasian tektites and microtektites, further confirms the impact origin of these glass spherules and provides an independent suggestion that they represent a major extension southeastward of the Australasian strewn field. The fact that similar redox conditions are observed in tektites and microtektites within the Australasian strewn field regardless of the distance from the source crater area (up to approximately 11000 km) could be an important constraint for better understanding the different processes affecting microtektite formation and transport. The fact that the Fe oxidation state of microtektites does not increase with distance, as in the case of North American microtektites, means that thermal and redox histories of Australasian and TAM microtektites could differ significantly from those of North American microtektites.     

Fragmentation and hydration of tektites and microtektites

Abstract— An examination of data collected over the last 30 years indicates that the percent of glass fragments vs. whole splash forms in the Cenozoic microtektite strewn fields increases towards the source crater (or source region). We propose that this is due to thermal stress produced when tektites and larger microtektites fall into water near the source crater while still relatively hot (>1150 °C). We also find evidence (low major oxide totals, frothing when melted) for hydration of most of the North American tektite fragments and microtektites found in marine sediments. High-temperature mass spectrometry indicates that these tektite fragments and microtektites contain up to 3.8 wt% H₂O. The H₂O-release behavior during the high-temperature mass-spectrometric analysis, plus high CI abundances (0.05 wt%), indicate that the North American tektite fragments and microtektites were hydrated in the marine environment (i.e., the H₂O was not trapped solely on quenching from a melt). The younger Ivory Coast and Australasian microtektites do not exhibit much evidence of hydration (at least not in excess of 0.5 wt% H₂O); this suggests that the degree of hydration increases with age. In addition, we find that some glass spherules (with <65 wt% SiO₂) from the upper Eocene clinopyroxene-bearing spherule layer in the Indian Ocean have palagonitized rims. These spherules appear to have been altered in a similar fashion to the splash form K/T boundary spherules. Thus, our data indicate that tektites and microtektites that generally contain >65 wt% SiO₂ can undergo simple hydration in the marine environment, while impact glasses (with <65 wt% SiO₂) can also undergo palagonitization.     

Ocean Drilling Project Hole 689B spherules and upper Eocene microtektite and clinopyroxene-bearing spherule strewn fields

Abstract— Montanari et al. (1993) reported a positive Ir anomaly in the upper Eocene sediments from Ocean Drilling Program Hole 689B on the Maud Rise, Southern Ocean. Vonhof (1998) described microtektites and clinopyroxene-bearing (cpx) spherules associated with the Ir anomaly in Hole 689B and suggested that they belong to the North American and equatorial Pacific cpx strewn fields, respectively. We searched a suite of 27 samples taken through the spherule layer from Hole 689B, and we recovered 386 microtektites and 667 cpx spherules. We studied the petrography of the microtektites and cpx spherules and determined the major element compositions of 31 microtektites and 14 cpx spherules using energy dispersive x-ray analysis. We also determined the minor element compositions of eight microtektites using instrumental neutron activation analysis. We found that the peak abundance of cpx spherules is ～2 cm below the peak abundance of the microtektites (～128.7 m below sea floor), which suggests that the cpx spherule layer may be slightly older (～3–5 ka). The microtektites are mostly spherical and are generally transparent and colorless. They are similar to the North American microtektites in composition, the biggest differences being their generally lower Na₂O and generally higher Zr, Ba, and Ir (up to 0.3 ppb) contents. We agree with Vonhof (1998) that the Hole 689B microtektites probably belong to the North American tektite strewn field. We calculate that the number of microtektites (>125 μm)/cm² at Hole 689B is 52. This number is close to the concentration predicted by extrapolation of the trend of concentration vs. distance from the Chesapeake Bay structure, based on data from other North American microtektite-bearing sites. Thus, the North American strewn field may be at least four times larger than previously mapped. The Hole 689B cpx spherules range from translucent yellow to opaque black, but most are opaque tan to dark brown. They are generally spherical in shape and all are < 125 μm in diameter. Some contain Ni-rich spinels in addition to clinopyroxene microlites. The cpx spherules are petrographically and compositionally similar to cpx spherules previously found in the northwestern Atlantic Ocean, Caribbean Sea, Gulf of Mexico, equatorial Pacific, and eastern Indian Ocean. The abundance and widespread geographic occurrence of these spherules suggest that the strewn field may be global in geographic extent. Assuming a global extent, we estimate that there may be at least 25 billion metric tons of cpx spherules in the strewn field. Based on age, size, and geographic location, we speculate that the 100 km diameter Popigai crater in northern Siberia may be the source of the cpx spherule layer.     

Late Eocene microkrystites and microtektites at Maud Rise (Ocean Drilling Project Hole 689B; Southern Ocean) suggest a global extension of the approximately 35.5 Ma Pacific impact ejecta strewn field

Abstract— Late Eocene microtektites and microkrystites recovered from Ocean Drilling Project Hole 689B at Maud Rise (Southern Ocean) are stratigraphically and geochemically compared to spherules from the North American and Pacific strewn fields, and to devitrified spherules from the Eocene-Oligocene global stratotype section and point section in Massignano, Italy. The ODP 689B microkrystites compare well to the Pacific strewn field microkrystites, which suggests that the geographic extent of the Pacific strewn field was much larger than previously documented. The elemental composition of microtektites of ODP Hole 689B is comparable to tektites of the North American strewn field. Their ⁸⁷Sr/⁸⁶Sr ratio, however, is different. We tentatively interpret this to reflect geochemical heterogeneity within the North American strewn field but can not exclude the option that the chemical discrepancies result from the existence of a third late Eocene impact site.     

Establishing the link between the Chesapeake Bay impact structure and the North American tektite strewn field: The Sr‐Nd isotopic evidence

Abstract— The Chesapeake Bay impact structure, which is about 35 Ma old, has previously been proposed as the possible source crater of the North American tektites (NAT). Here we report major and trace element data as well as the first Sr‐Nd isotope data for drill core and outcrop samples of target lithologies, crater fill breccias, and post‐impact sediments of the Chesapeake Bay impact structure. The unconsolidated sediments, Cretaceous to middle Eocene in age, have ?_Sr^{t = 35.7 Ma} of +54 to +272, and ?_Nd^{t = 35.7 Ma} ranging from ?6.5 to ?10.8; one sample from the granitic basement with a T^Nd_CHUR model age of 1.36 Ga yielded an ?_Sr^{t = 35.7 Ma} of +188 and an ?_Nd^{t = 35.7 Ma} of ?5.7. The Exmore breccia (crater fill) can be explained as a mix of the measured target sediments and the granite, plus an as‐yet undetermined component. The post‐impact sediments of the Chickahominy formation have slightly higher T^Nd_CHUR model ages of about 1.55 Ga, indicating a contribution of some older materials. Newly analyzed bediasites have the following isotope parameters: +104 to +119 (?_Sr^{t = 35.7 Ma}), ?5.7 (?_Nd^{t = 35.7 Ma}), 0.47 Ga (T^Sr_UR), and 1.15 Ga (T^Nd_CHUR), which is in excellent agreement with previously published data for samples of the NAT strewn field. Target rocks with highly radiogenic Sr isotopic composition, as required for explaining the isotopic characteristics of Deep Sea Drilling Project (DSDP) site 612 tektites, were not among the analyzed sample suite. Based on the new isotope data, we exclude any relation between the NA tektites and the Popigai impact crater, although they have identical ages within 2s? errors. The Chesapeake Bay structure, however, is now clearly constrained as the source crater for the North American tektites, although the present data set obviously does not include all target lithologies that have contributed to the composition of the tektites.     

LATE EOCENE CRYSTAL-BEARING SPHERULES: TWO LAYERS OR ONE?

Late Eocene crystal-bearing spherules have been found in deep sea cores from the Caribbean Sea, Gulf of Mexico, equatorial Pacific Ocean, and eastern equatorial Indian Ocean. Keller et al. (1987) have suggested that the spherules from the western equatorial Pacific (Site 292, core 38) and eastern Indian Ocean (Site 216) are older (Globigerapsis semiinvoluta Zone) than those from the central equatorial Pacific, Gulf of Mexico, and Caribbean Sea (Globorotalia cerroazulensis Zone). The strongest argument in favor of two layers is the biostratigraphic data; however, published biostratigraphic interpretations are at odds with Keller et al.'s (1987) conclusions. Furthermore, paleomagnetic data for Site 292 seems to contradict Keller et al.'s conclusion that the spherules found in core 36 occur in sediments of the same stratigraphic age as those found in the central equatorial Pacific, Gulf of Mexico, and Caribbean Sea sites. Although the spherules from Sites 216 and 292 (core 38) do have higher average CaO, and lower average Al₂O₃ and FeO contents than the late Eocene spherules from the other sites, there is a great deal of overlap in composition. It is our opinion that the similarities in composition and petrography between the late Eocene crystal-bearing spherules are greater than the differences. Additionally, there seems to be a systematic change in composition and in amount of iridium excess from east to west when all the sites containing the crystal-bearing spherules are considered. We believe, therefore, that it is likely that the late Eocene crystal-bearing spherules all belong to a single event.     

Australasian microtektites and associated impact ejecta in the South China Sea and the Middle Pleistocene supereruption of Toba

Abstract— Australasian microtektites were discovered in Ocean Drilling Program (ODP) Hole 1143A in the central part of the South China Sea. Unmelted ejecta were found associated with the microtektites at this site and with Australasian microtektites in Core SO95–17957–2 and ODP Hole 1144A from the central and northern part of the South China Sea, respectively. A few opaque, irregular, rounded, partly melted particles containing highly fractured mineral inclusions (generally quartz and some K feldspar) and some partially melted mineral grains, in a glassy matrix were also found in the microtektite layer. The unmelted ejecta at all three sites include abundant white, opaque grains consisting of mixtures of quartz, coesite, and stishovite, and abundant rock fragments which also contain coesite and, rarely, stishovite. This is the first time that shock‐metamorphosed rock fragments have been found in the Australasian microtektite layer. The rock fragments have major and trace element contents similar to the Australasian microtektites and tektites, except for higher volatile element contents. Assuming that the Australasian tektites and microtektites were formed from the same target material as the rock fragments, the parent material for the Australasian tektites and microtektites appears to have been a fine‐grained sedimentary deposit. Hole 1144A has the highest abundance of microtektites (number/cm²) of any known Australasian microtektite‐bearing site and may be closer to the source crater than any previously identified Australasian microtektite‐bearing site. A source crater in the vicinity of 22° N and 104° E seems to explain geographic variations in abundance of both the microtektites and the unmelted ejecta the best; however, a region extending NW into southern China and SE into the Gulf of Tonkin explains the geographic variation in abundance of microtektites and unmelted ejecta almost as well. The size of the source crater is estimated to be 43 ± 9 km based on estimated thickness of the ejecta layer at each site and distance from the proposed source. A volcanic ash layer occurs just above the Australasian microtektite layer, which some authors suggest is from a supereruption of the Toba caldera complex. We estimate that deposition of the ash occurred ?800 ka ago and that it is spread over an area of at least 3.7 times 10⁷ km².     

Australasian minitektites discovered in the Indian Ocean

Abstract— Large area sampling with a box core in the Indian Ocean has led to the discovery of minitektites (>1–3.75 mm long) and a tektite fragment (～1.25 mm) occurring with microtektites belonging to the Australasian tektite strewn field. Minitektites and the microtektites are found to have similar major element compositions conforming to the Australasian tektite/microtektite chemistry. Earlier studies based on isotopic evidence, dating, and chemistry had provided evidence of a single large tektite strewn field; however, the physical association of tektites occurring with microtektites has been lacking. The present study provides such an association.     

TiO2 II: The high-pressure Zr-free srilankite endmember in impact rocks

TiO₂II, a high-pressure polymorph of titanium dioxide, is a diagnostic indicator of shock metamorphism in impact rocks. Due to its typical micro-to-nanometer scale, there are no ab initio structure solutions of natural TiO₂II, thereby generating uncertainty about its crystal structure and its known similarity with srilankite (Ti_0.67,Zr_0.33)O₂. Nanoscale electron diffraction investigation of TiO₂II from the Australasian tektite strewn field provides the first ab initio structure solution revealing a primitive orthorhombic lattice with cell parameters a = 4.547 Å, b = 5.481 Å, c = 4.891 Å, and space group Pbcn, that is, the same as srilankite and scrutinyite α-PbO₂. The linear a and c decrease, and b increase with Ti content indicate TiO₂II as Zr-free srilankite endmember in the binary system ZrO₂-TiO₂. Thereby the name srilankite should be used referring to TiO₂II, according to the International Mineralogical Association recommendations. We provide the first evidence for a topotactic subsolidus rutile-to-TiO₂II transition, founding their finely intermixing nanocrystals in the same TiO₂ crystal, where TiO₂II is within the crystal and surrounded by rutile in direct contact. They also show recurrent iso-orientation, with TiO₂II [100] parallel to rutile [100], TiO₂II [010] parallel to rutile [011], and TiO₂II [001] parallel to rutile (0–11). The rutile-TiO₂II iso-orientation suggests the compression of rutile (0–11) planes as a possible transition mechanism from rutile to TiO₂II, with a consequent shortening of ~0.5 Å per cell. The presence of TiO₂II in the distal (~1200 km) impact ejecta from the Australasian tektite strewn field indicates shock pressures of ~12–15 GPa and post-shock temperatures below 500°C followed by rapid quenching.     

2000 Å UV imaging of A 6° diameter field around theh and Chi Persei double cluster

The stellar field centred close to theh and Per double cluster is one of the 123 fields recorded in the galactic plane at 2000 Å by the balloon-borne stratospheric gondola of the SCAP-2000 programme. The analysis of the frame allows us to determine an ultraviolet colour indexU ₁-V for more than 600 stars. Among these are stars belonging to theh and Per and Tr 2 clusters and to the PER OB1 association. The prevailing extinction law is found to produce greater extinction at 1965 Å than predicted by the mean extinction law. Moreover, the clouds responsible for the extinction are situated in the local arm and distributed in two layers with a very transparent interval. The comparison of theA _v extinction and theHI and CO abundances leads us to assume the presence of a H₂ cloud in front ofh and Per, in the second absorbing layer and, therefore, in the local arm. The two absorbing layers and the molecular cloud are perhaps in the plane of the Gould belt and associated with the expanding gas detected by Lindblad. A group of hot stars centred at the same distance as this molecular cloud has been detected and could form an association of OB stars in the local arm. Other, much more distant OB stars belonging to the Perseus arm of Efremov's list. Several stars which must have a very hot companion are detected in the field.     

Spatially resolved methane band photometry of Jupiter: III. Cloud vertical structures for several axisymmetric bands and the Great Red Spot

We present cloud structure models for Jupiter's Great Red Spot, Equatorial Zone, North Tropical Zone, North and South Temperate Zones, North and South Polar Regions, and North and South Polar Hoods. The models are based on images of Jupiter in three methane bands (between 6190 and 8900 Å) and nearby continuum. Radiative transfer calculations include multiple scattering and absorption from three aerosol layers, the topmost of which is a high thin haze and the lower two are called clouds. All models are computed relative to a similar model for the South Tropical Zone which fits methane absorption data and Pioneer photometry data well. Outstanding features suggested by the model results are the transition in the upper-cloud altitude to about 3 km lower altitude from the tropical zones to temperate zones and polar regions, a N/S asymmetry in cloud thickness in the tropical and temperate zones, the presence of aerosols up to about 0.3 bar in the Great Red Spot and Equatorial Zone, the need for a significant (τ ～ 0.75 to 1.0) aerosol content in this region in the Equatorial Zone, and perhaps an even higher and thicker cloud in the South Polar Hood. The haze layer above both polar hoods may exhibit different scattering properties than the haze which covers lower latitudes. In comparing the present results with models derived from polarization and infrared observations we conclude that polarization data are sensitive to aerosols in and above the upper cloud layer but insensitive to deeper cloud structure, and the converse is true for infrared data.     

Are periodicities in crater formations and mass

Periodicities in crater formation rate and mass-extinctions are reviewed. The former exhibits a period of 30 million yr, while the latter appear to have a periodicity at 26 myr. Results obtained earlier that small craters better satisfy the adopted criterion for statistical testing is shown due to the fact that there is a strong clustering of small craters in a recent past (<10 myr). On the basis of the dataset of craters compiled by Grieve, it is shown that there are several craters for which no mass extinctions correspond. The difference in the periods of the craters and of mass extinctions and the lack of mass extinctions that correspond to large craters appear to suggest that the two periodicities are not interrelated, and large impacts merely act as triggers for the mass-extinctions; the only exception being theK/T boundary.     

(U‐Th)/He zircon dating of Chesapeake Bay distal impact ejecta from ODP site 1073

Single crystal (U‐Th)/He dating has been undertaken on 21 detrital zircon grains extracted from a core sample from Ocean Drilling Project (ODP) site 1073, which is located ~390 km northeast of the center of the Chesapeake Bay impact structure. Optical and electron imaging in combination with energy dispersive X‐ray microanalysis (EDS) of zircon grains from this late Eocene sediment shows clear evidence of shock metamorphism in some zircon grains, which suggests that these shocked zircon crystals are distal ejecta from the formation of the ~40 km diameter Chesapeake Bay impact structure. (U‐Th/He) dates for zircon crystals from this sediment range from 33.49 ± 0.94 to 305.1 ± 8.6 Ma (2σ), implying crystal‐to‐crystal variability in the degree of impact‐related resetting of (U‐Th)/He systematics and a range of different possible sources. The two youngest zircon grains yield an inverse‐variance weighted mean (U‐Th)/He age of 33.99 ± 0.71 Ma (2σ uncertainties n = 2; mean square weighted deviation = 2.6; probability [P] = 11%), which is interpreted to be the (U‐Th)/He age of formation of the Chesapeake Bay impact structure. This age is in agreement with K/Ar, ⁴⁰Ar/³⁹Ar, and fission track dates for tektites from the North American strewn field, which have been interpreted as associated with the Chesapeake Bay impact event.     

A first report of microtektites from the shell beds of southwestern Florida

The Plio‐Pleistocene Upper Tamiami Formation (Pinecrest beds) of Florida is well known for its fossiliferous shell beds, but not for its extraterrestrial material. Here we report the first occurrence of tiny (~200 μm in diameter) silica‐rich microspherules from this unit and from the state. This material was analyzed using petrographic and elemental methods using energy dispersive X‐ray spectroscopy (EDS). The majority of microspherules are glassy and translucent in reflected light with some displaying “contact pairs” (equal‐sized micro‐spherules attached to each other). Broken microspherules cleave conchoidally, often with small internal spherical vesicles, but most lack any other evidence of internal features, such as layering. Using the EDS data, the microspherules were compared to volcanic rocks, microtektites, and cosmic spherules (micrometeorites). Based on their physical characteristics and elemental compositions these are likely microtektites or a closely related type of material. The high Na content in the examined material deviates significantly from the abundances usually found in micrometeorites and tektite material; this is enigmatic and requires further study. This material may be derived from a nearby previously unknown impact event; however, more material and sites are required to confirm the source of this material. Because of the focus on molluscan fossils in southwestern Florida shell beds, microtektite material has likely been overlooked in the past, and it is probable that these microspherules are in abundance elsewhere in these units and possibly throughout the region.