长英质富晶体火山岩成因——岩浆补给与晶粥再活化

火山是人类窥探深部岩浆系统的窗口。从全球范围来看,贫晶体富熔体的火山岩(尤其是玄武岩和流纹岩)大面积出露,而富晶体的长英质火山岩仅出露于破火山周围。长英质富晶体火山岩主要可分为两类：一类是成分和晶体含量均一的火山岩;另一类是成分和斑晶含量分带的火山岩。富晶体火山岩是冷储存晶粥接受岩浆反复补给后重熔、再活化,重新具备流动能力而喷发形成的,储库中先存物质的成分决定了再活化形成的富晶体火山岩的类型。富晶体火山岩的存在能够很好地解释岩浆储库具有较长的寿命而岩浆汇聚结晶的过程却是迅速的这种看似矛盾的现象。虽然近年来长英质富晶体火山岩的研究已经取得了明显的进展,但仍有许多问题亟待解决,如碎斑熔岩的成因,如何判别晶粥活化,晶粥再活化与火山喷发的关系,岩浆补给和晶粥活化的时间尺度等。对富晶体火山岩的进一步研究将有助于深入揭示熔体演化、运移、在浅部的聚集和喷发的机制,并可为建立更完善的长英质岩浆演化模型提供更多信息。     

豫西新生代基性火山岩地球化学特征及源区性质

豫西新生代基性火山岩主要为粗面玄武岩,少量碱玄岩和玄武岩。其地球化学特征表明该区基性火山岩基本代表了幔源原始岩浆的成分,结晶分异作用及地壳物质混染作用并未对本区基性火山岩产生明显影响。初步的研究表明,本区基性火山岩是富集型地幔熔体和亏损型地幔熔体混合的产物。     

Fractional crystallization and magma mixing in the Tigalak layered intrusion,the Nain anorthosite complex,Labrador

The Tigalak intrusion is a dominantly dioritic layered body, about 80 km² in area, which ranges in composition from norite to granodiorite. Local areas of the layered rocks display upward fractionation from norite to ferrodiorite. Periodic reversals of mineral composition trends record the emplacement of less fractionated dioritic magma. Heterogeneous mixtures of dioritic and granodioritic rocks occur widely in mappable lenses and layers that alternate up section and along the strike with more uniformly layered rocks. In these mixtures, chilled dioritic pillows occur abundantly in a hybrid cumulate matrix of granodiorite to diorite composition. Cross-cutting granodioritic dikes grade upward into stratigraphically-bound lensoid masses of the hybrid cumulates. It appears that the hybrid rocks formed as a result of the emplacement of the granodioritic magma through lower cumulates into the dioritic magma chamber and that the dioritic pillows represent chilled bodies of Ferich dioritic magma that commingled with cooler granodioritic magma and settled to the floor of the Tigalak magma chamber. The restricted distribution of these mixtures of hybrid cumulates and chilled pillows indicates that mixing between granodioritic and dioritic liquids was limited in time and lateral extent. Periodic injections of granodioritic liquids may have collected as a separate layer below the roof of the magma chamber and above dioritic magma.     

Geochemistry of the Adamello massif (northern Italy)

The Tertiary Adamello massif, outcropping over an area of more than 550 km² in the southern Alps (northern Italy) is composed mainly of granitoid rocks (granodiorite, tonalite, quartz diorite) with minor amounts of diorite and gabbro. The major and trace element composition of these rocks is comparable to calc-alkaline volcanic rocks of continental margins. The granitoid rocks display spatial and temporal variations in their composition, particularly in Na, P, Sr, La, Nb and Y contents and ⁸⁷Sr/⁸⁶Sr ratios. The variations were probably produced by concurrent contamination/wall-rock assimilation and fractional crystallization of high-alumina basaltic magma.     

邯邢地区燕山期角闪闪长岩系的岩浆演化——角闪石占主导的矿物分离结晶作用

通过对邯邢地区燕山期角闪闪长岩系岩石的岩相学、岩石化学和矿物化学的研究,认为岩浆的演化机制是矿物分离结晶作用,以角闪石为主的矿物分离结晶是影响岩浆成分变异的主导因素。     

辽东地区早元古代火山岩特征及其形成的动力学背景

辽东地区早元古代火山岩是下元古界辽河群地层的重要组成部分,它们由酸性和基性两套火山岩组成。前者形成于辽河裂谷发育早期的拉张裂陷阶段,属于壳源岩浆成因;后者形成于辽河裂谷发育中晚期的强烈拉张裂陷阶段,属于幔源岩浆成因。重点讨论了基性火山岩的岩石学、矿物学、岩石化学和地球化学特征,结果表明,这些基性火山岩主要为一套海底喷发的基性枕状熔岩,具有大陆拉斑玄武岩和大洋拉斑玄武岩的双重特征,是辽河裂谷由大陆壳向大洋壳演化过程中的产物。火山岩形成的动力学背景与早元古代时期热地幔对流形式的出现以及郯-庐断裂带发生右旋平移剪切活动密切相关。     

北京四合堂花岗质杂岩的两种演化趋势

北京密怀隆起西部的石城片麻岩、皂树片麻岩和云蒙山北部的片麻状花岗闪长岩是太古代同源岩浆演化形成的古深成侵入体,本文称之为四合堂花岗质杂岩。该杂岩中的石城片麻岩,皂树片麻岩的闪长质、石英门长质片麻岩—英云间长质片麻—脉状的奥长花岗岩构成了英云间长岩—奥长花岗岩演化趋势,片麻岩中的石英闪长质片麻岩与花岗间长岩—二长花岗岩构成了钙碱性演化趋势。这两个演化趋势是在不同的条件下分离的矿物相不同所致。     

浙江沿海晚中生代拉斑玄武岩浆侵位深度的讨论

浙江沿海晚中生代复合岩流中拉斑玄武岩高度富集大离子亲石元素,反映除了源区富集作用外还有地壳混染的贡献,Rb、Nb的丰度特征指示玄武岩浆主要与中、上地壳岩石发生了相互作用。用岩石化学成分计算的这种拉斑玄武岩浆熔体的平均密度为ρm = 2.678 g/cm3 , 根据岩浆与周围地壳的压力平衡关系,推算得来自地幔的玄武岩浆一直侵位到距地表约16.3km左右的中地壳时才滞留下来,并被相应的地壳物质所混染。     

福建武平岩基岩石谱系单位划分

根据近几年来在１：５万区调中采用岩石谱系单位新理论、新方法填图的成果,以及岩石成分、结构构造特征、群居关系、侵入接触类型等,将过去１：２０万区调均划属燕山早期黑云母花岗岩及细粒花岗岩的武平岩体,解体为志留纪、晚三叠世、侏罗纪、白垩纪等不同时代深成岩体,划分出中（基）性、中酸性及酸性岩等岩石类型。圈定深成岩体４０个,独立侵入体１５个,共３３个单元,归并为６个超单元,５个独立单元。并认为志留纪侵入岩浆     

安徽铜陵狮子山矿田岩浆岩锆石SHRIMP定年及其成因意义

铜陵狮子山矿田发育大量岩浆岩,且与矿田中的铜金多金属成矿关系密切。锆石SHRIMP同位素精确定年表明,矿田中的岩浆侵位年龄在132.4～142.9Ma之间,即晚侏罗世—早白垩世,属燕山早期晚阶段。矿田岩浆岩体是在同期岩浆活动中多次侵位形成的,岩浆侵入活动可以划分为分别起始于140Ma前后和约136Ma的早晚两次。从岩浆上升侵位到冷却结晶的时间间隔均较短,但其中白芒山辉石二长闪长岩冷却史相对较长,且经历了早期深部岩浆房中的分离结晶作用和后期构造脉动、岩浆上升侵位、减压受热、早期晶体再熔蚀及冷却结晶的过程。结合主量元素和微量元素地球化学研究认为,狮子山矿田岩浆演化的后期,即起源于上地幔或下地壳的原生岩浆在同化了壳源物质并聚集到岩浆房中以后,在滞留的过程中发生了一定程度的分离结晶作用,但尚未固结,成分上显示了一定的带状分布,在区域构造应力松弛及构造事件诱发下,随机地沿发育的构造裂隙先后上升侵位,冷凝结晶。     

塔里木板块东北部坡一镁铁质-超镁铁质层状侵入体岩石成因

坡一侵入体位于塔里木板块东北部坡北岩体内,是该岩体第三阶段岩浆活动形成的十几个小侵入体中的一个,锆石U-Pb年龄为278±2Ma。该侵入体属于以超镁铁质岩石为主的层状岩系,堆晶结构与韵律性堆晶层理非常发育。岩浆分异充分,形成了从纯橄岩到石英闪长岩的多种岩石类型。在超镁铁质岩石中,所有的橄榄石和大部分斜方辉石是堆晶相,少量斜方辉石是填隙相,大部分单斜辉石、褐色普通角闪石和黑云母是填隙相。在镁铁质岩石中,橄榄石和斜方辉石全部是堆晶相,单斜辉石与斜长石既可以是堆晶相,也可以是填隙相;褐色普通角闪石、黑云母和石英均为填隙相。超镁铁质岩石属拉斑玄武岩系列,镁铁质岩石属钙碱性系列。侵入体中大量存在的捕掳体、微量元素地球化学、Nd-Sr同位素组成的EMⅡ型演化趋势,充分证明了同化混染作用伴随岩浆演化过程而逐渐增强,并不断促进了岩浆的分异,而且导致了岩石化学系列的转化。PGE和亲硫元素地球化学以及硫同位素组成证明,硫主要来自于岩浆,硫化物形成于岩浆阶段,岩浆未经历过早期硫化物熔离作用,硫化物熔离起始于橄榄岩相结晶的晚期阶段,并伴随着此后的岩浆演化过程而继续熔离。硫化物熔离是岩浆自身演化和同化混染共同作用的结果。橄榄石Fo分子含量和全岩FeO含量显示,原生岩浆是苦橄质岩浆;源区物质应该是石榴石辉石岩;岩浆生成于地幔柱轴部。在塔里木板块东北部还存在分别来自于软流圈和亏损型大陆岩石圈地幔的二叠纪岩浆岩,它们都应该是塔里木大火成岩省的组成部分。     

东天山黄山东和黄山西铜镍硫化物矿床含矿超镁铁岩的成岩-成矿作用机制:来自斜长石成分的约束

东天山黄山东和黄山西镁铁-超镁铁岩是区域早二叠世大规模幔源岩浆作用的产物,赋存有两个大型岩浆铜镍硫化物矿床.黄山东和黄山西矿床的主要矿体均赋存于超镁铁岩中,其含矿超镁铁岩的成因机制研究对揭示区域铜镍硫化物成矿作用机制具有重要意义.本文对黄山东和黄山西含矿超镁铁岩进行了详细的电子背散射图像研究,发现其斜长石斑晶存在显著的不平衡结构,并系统进行了电子探针成分剖面分析.结果显示斜长石具有剧烈变化的成分环带,其中黄山东超镁铁岩斜长石An值介于48.6~75.6,黄山西含矿超镁铁岩斜长石An值介于44.9~79.2,表明两个矿床含矿超镁铁岩的母岩浆在侵位过程中发生过显著的成分变化.结合黄山东和黄山西镁铁-超镁铁杂岩体地质特征,本文认为高分异镁铁质岩浆的加入导致了低分异超镁铁质岩浆成分发生显著变化,致使岩浆硫化物熔离,以及黄山东和黄山西大型铜镍硫化物矿床的形成.      

长白山上新世以来玄武岩成分演变规律及其成因

火山岩成分的多样性是岩浆物理和化学过程在其产生、运移、存储和喷发过程中的综合反映。长白山火山区自上新世以来喷发了大量的玄武质火山岩,其成分变化范围较大(Mg O 3.2%~7.8%)。以往研究认为其成分的变化主要受地幔不均一、部分熔融程度和分离结晶的影响,没有明显地壳混染。本研究发现这些玄武岩经历了不同程度的上、下地壳的混染。同时,结合火山岩的年龄发现玄武岩地球化学成分和同位素比值随时间呈现脉动式的变化。根据87Sr/86Sr和Mg O的突变点可以分为3段:5~2Ma,2~1Ma,1~0Ma。通过定性和定量的模拟发现地幔不均一性和部分熔融程度差异造成玄武岩成分的变化有限,而分离结晶、地壳混染和岩浆补给的岩浆作用是形成玄武岩成分随时间脉动变化的主要原因。并结合能量约束-补给-混染-分离结晶算法(ECRAFC)模拟得出以下结论:天池和望天鹅喷发中心的玄武质岩浆最初都存储于同一下地壳岩浆房,可能由于上地壳构造差异导致岩浆迁移路径和存储区不同;长白山岩浆房迁移有从5~2Ma阶段由下地壳向上地壳逐渐变浅,2~1Ma阶段由上地壳向下地壳快速变深的规律,而1~0Ma阶段的玄武岩由岩浆从下地壳直接快速喷出地表形成;长白山玄武质岩浆的活动与本区的构造断裂活动密切的关系,5Ma以来,火山岩成分随时间的周期性波动可能与本区构造应力的周期性的强拉张-弱拉张过程有关。     

南澜沧江结合带火山岩岩浆成因——洋脊洋岛与弧岩浆作用的性质

在对滇西南昌宁—孟连带石炭—二叠纪火山岩和南澜沧江带二叠—三叠纪火山岩的微量元素和稀土元素研究的基础上,划分了岩浆作用类型和岩浆演化系列,探讨了岩浆源区成分特点。昌宁—孟连带玄武质岩浆的演化主要受部分熔融和分离结晶作用控制;这些岩浆可以划分为３个岩浆演化系列：（１）稀土曲线平坦型的洋脊型拉斑玄武岩浆演化系列,其岩浆起源于亏损型地幔;（２）稀土曲线中等富集型的准洋脊型拉斑玄武岩浆演化系列,其岩浆起源于过渡型地幔;（３）稀土曲线强烈富集型的洋岛型碱性玄武岩浆演化系列,其岩浆起源于富集型地幔。南澜沧江带弧火山岩的岩浆成因主要受分离结晶作用控制,也可以划分为３个岩浆演化系列：（１）二叠纪低钾拉斑—中钾钙碱性岩浆演化系列;（２）中南段的晚三叠世低钾拉斑—中钾钙碱性岩浆演化系列;（３）北段的晚三叠世钾玄岩—高钾钙碱性岩浆演化系列     

江西冷水火山—侵入杂岩体岩石化学及地球化学特征

冷水银铅锌矿的火山—侵入杂岩体出露于信江中生代火山盆地南缘。岩石化学、微量元素、稀土元素和铷锶同位素分析表明冷水火山岩及次火山岩是同源产物,是同熔岩浆分异的结果。岩浆中成矿物质Cu、Fe、Pb、Zn、S、H_2O的数量与下地壳、上地慢或洋壳物质的部分熔融程度有关。冷水火山—侵入杂岩是钙碱性岩浆于不同演化阶段形成的岩石组合并具有化学成分上的相似性和继承性。岩浆房中具有良好的分带现象,上部为富钾的流纹质岩浆,向下逐渐变为基性岩浆。岩浆由钙碱性向偏碱性演化,促使成矿元素大量富集,在一定条件下形成矿床。     

Examples of convective fractionation in high‐temperature granites from the Lachlan Fold Belt

Igneous rocks derived from high‐temperature, crystal‐poor magmas of intermediate potassic composition are widespread in the central Lachlan Fold Belt, and have been assigned to the Boggy Plain Supersuite. These rocks range in composition from 45 to 78% SiO₂, with a marked paucity of examples in the range 65–70% SiO₂, the composition dominant in most other granites of the Lachlan Fold Belt. Evidence is presented from two units of the Boggy Plain Supersuite, the Boggy Plain zoned pluton and the Nallawa complex, to demonstrate that these high‐temperature magmas solidified under a regime of convective fractionation. By this process, a magma body solidified from margin to centre as the zone of solidification moved progressively inwards. High‐temperature near‐liquidus minerals with a certain proportion of trapped interstitial differentiated melt, separated from the buoyant differentiated melt during solidification. In most cases much of this differentiated melt buoyantly rose to the top of the magma chamber to form felsic sheets that overly the solidifying main magma chamber beneath. Some of these felsic tops erupted as volcanic rocks, but they mainly form extensive high‐level intrusive bodies, the largest being the granitic part of the Yeoval complex, with an area of over 200 km². Back‐mixing of fractionated melt into the main magma chamber progressively changed the composition of the main melt, resulting in highly zoned plutons. In the more felsic part of the Boggy Plain zoned pluton back‐mixing was dominant, if not exclusive, forming an intrusive body cryptically zoned from 63% SiO₂ on the margin to 72% SiO₂ in the core. It is suggested that tonalitic bodies do not generally crystallise through convective fractionation because the differentiated melt is volumetrically small and totally trapped within the interstitial space: back‐mixing is excluded and homogeneous plutons with essentially the composition of the parental melt are formed.     

Geochemistry, Petrogenesis and Tectonic Setting of Metavolcanics and their Implications for Gold Mineralisation in Gadag Gold Field, Southern India

Gold bearing metavolcanics of Gadag Gold Field (GGF) are represented by mafic (metabasalt, metabasaltic andesite), intermediate (metaandesite) and felsic (metadacite, metarhyolite) rocks. Mafic metavolcanic rocks are low-K Fe-rich tholeiites and were derived by partial melting of the upper mantle sources with high Fe/Mg ratios and low M values. Intermediate and felsic metavolcanics were formed by remelting of these tholeiites mainly in crustal regimes. Although a complete sequence of metavolcanic rocks from mafic to intermediate to felsic fractions occurs, these products were not the result of differentiation from a single magma, crustal contamination was involved in the formation of intermediate and felsic rocks. A clear gap in the chemical composition as well as index of differentiation among the mafic, intermediate and felsic fractions indicate that these metavolcanics constitute a typical bimodal character. It is suggested that these metavolcanics were emplaced in an active continental margin or a continental island arc setting. The petrogenetic processes of formation of Fe-rich tholeiites that evolved in an active continental margin or a continental island arc setting could have provided a favourable geochemical environment for gold mineralisation under the conditions of deformation and metamorphism.     

Cr and Sr: Keys to parental magmas and processes in the Bushveld Complex, South Africa

Large layered intrusions are almost certainly periodically replenished during their protracted cooling and crystallization. The exact composition(s) of the replenishing magma(s) in the case of the Bushveld Complex, South Africa, has been debated, mainly on the basis of major element composition and likely crystallization sequences. The intrusion is dominated by orthopyroxene and plagioclase, and so their Cr and Sr contents, and likely partition coefficient values, can be used to re-investigate the appropriateness of the various proposed parental magmas. One magma type, with about 12% MgO, 1000 ppm Cr and 180 ppm Sr, can explain the genesis of the entire Lower and Critical Zones. A number of other magma compositions proposed to produce the Critical Zone fail to match these trace-element constraints by being too poor in Cr. A fundamentally different magma type was added at the base of the Main Zone, but none of the proposed compositions is consistent with the trace-element requirements. Specifically, the Cr contents are higher than predicted from pyroxene compositions. A further geological constraint is demonstrated from a consideration of the Cr budget at this level. There is an abrupt decrease from about 0.4% to 0.1% Cr₂O₃ in orthopyroxene across this Critical Zone–Main Zone transition. No realistic proportions of mixing between the residual magma at the top of the Critical Zone and any proposed added magma composition can have produced a composition that could have crystallized these low-Cr orthopyroxenes. Instead, it is suggested that the resident magma from the Upper Critical Zone was expelled from the chamber, possibly as sills into the country rocks, during influx of a dense, differentiated magma. Near the level of the Pyroxenite Marker in the Main Zone, there is further addition of a ferrobasaltic magma, with 6% MgO, 111 ppm Cr and 350 ppm Sr, that is consistent with the geochemical requirements.     

西藏仲巴地块加达钾质火山岩LA-ICP-MS锆石U-Pb年龄和地球化学特征

新生代青藏高原钾质火山岩发育,主要集中于藏北地区和拉萨地块内,仲巴地块中鲜见报道。对仲巴地块中发现的加达钾质火山岩进行研究,其岩石类型以粗面质为主,岩浆以溢流相-喷发相不间断喷发。样品普遍显示高钾高铝,低碱,偏酸性,富集轻稀土元素和大离子亲石元素,亏损高场强元素,具弱负Eu异常,贫Y和Yb,Sr含量较高,类似于典型的埃达克质岩的地球化学特征。粗面玄武安山岩样品LA-ICP-MS锆石U-Pb年龄为17.03±0.32Ma,形成时代为中新世。加达钾质火山岩浆来源于挤压增厚的下地壳部分熔融,其产出的构造背景是后碰撞伸展环境。     

海拉尔盆地乌尔逊凹陷南一段物源-沉积体系与构造背景

海拉尔盆地乌南凹陷南一段时期断裂和火山作用强烈, 导致岩石碎屑组成具有多样性。碎屑成分有火山碎屑、变质岩碎屑和其他剥蚀碎屑。碎屑多样性使本区岩性及其分区具有鲜明的特色。岩性丰度、矿物组合、阴极发光及其重矿物组合研究显示, 区内存在4个单岩性区和2个混合区。单岩性区是变质岩碎屑岩区、火山碎屑沉积岩区、熔结火山碎屑岩区和火山碎屑岩区。根据岩石中各碎屑组成的体积分数可将混合区分为正常沉积碎屑占优势的混合区和火山碎屑占优势的混合区。各单岩性区与构造单元相符合, 变质岩碎屑岩区对应乌西断阶带, 火山碎屑沉积岩区和熔结火山碎屑岩区对应巴彦塔拉构造带, 火山碎屑岩区为乌东弧形构造带的一部分。地球化学数据显示本区源岩岩浆属于壳源花岗质岩浆, 同时受到明显的幔源岩浆影响, 重稀土较富集。乌西断阶带具有高的稀土总量和不明显的Eu负异常, 变质源岩岩浆壳幔混染程度高;巴彦塔拉构造带具有低的稀土总量和明显的Eu负异常, 源岩岩浆壳幔混染程度中等;乌东弧形构造带具有高的稀土总量和明显的Eu负异常, 源岩岩浆壳幔混染程度低。Dickinson图解显示, 乌东弧形构造带源区没有深切割, 而巴彦塔拉构造带源区经过了深切割。德尔布干断裂的正滑移导致嵯岗构造片麻岩发育和嵯岗隆起相对隆升, 为乌西断阶带提供变质碎屑沉积物, 形成扇三角洲沉积体系;同时断裂又为幔源岩浆的上升提供了通道。巴彦塔拉断裂的伸展走滑使得幔源岩浆上升发生壳幔混染并发生火山喷发, 在巴彦塔拉构造带发育熔结火山碎屑岩-火山碎屑沉积岩, 塑造了火山碎屑扇三角洲沉积体系。巴彦山隆起区壳幔混染程度低, 但幔源岩浆的底垫作用导致壳源岩浆的强结晶分异作用、火山活动和地表隆升, 在乌东弧形构造带发育火山碎屑岩, 塑造了火山碎屑三角洲沉积体系。