鲁北平原浅层地下水有机污染特征及污染来源分析

本文在对鲁北平原水文地质条件及污染源现状分析的基础上,对浅层地下水进行了高密度的样品采集、高精度的污染物组分测试及污染程度研究,分析研究结果表明:鲁北平原浅层地下水在部分地区受到有机物污染,污染程度总体较低,个别地区出现中度污染和重度污染。检出的有机污染物共13种,个别有机物含量高。浅层地下水污染区的分布及污染程度,与油田采油区位置及石油化工企业的分布具有相关性。     

太湖流域某地区浅层地下水有机污染特征

对太湖流域某地区浅层地下水有机污染特征进行了总结，并就污染来源、污染途径和典型污染源附近浅层地下水有机污染特征等问题进行了研究。研究结果表明，该地区浅层地下水中各组分的检出率较高，但检出浓度较低，除苯在个别采样点处超出美国环保局（EPA）饮用水标准外，其余卤代烃和单环芳烃组分均没有超标；平面分布上，卤代烃和单环芳烃各组分的浓度高值点大都集中于该地区东南部的工业区内，这种空间分布特征与工业区的分布具有明显的一致性；垂向上有浅部地下水的污染程度相对较重、深部地下水较轻的特点；典型污染源周边浅层地下水的污染程度较重，但随着采样点远离污染源，地下水中各有机污染组分的浓度迅速衰减。     

考虑污染物扩散风险的场地地下水污染多层次风险评估方法

地下水中污染物具有迁移性和扩散性,会对下游敏感受体造成威胁,目前场地地下水风险评估主要关注人体健康风险,还未能综合考虑地下水污染的整体风险,尤其是忽视了污染物迁移引起的对下游敏感受体的风险。本研究基于“源-径-汇”模型构建了考虑污染物扩散风险的场地地下水污染风险评估的指标体系与风险评估模式。在指标体系构建方面,重点考虑场地地下水的污染源、迁移路径和敏感受体3个方面。在风险评估模式方面,根据场地不同地下水污染状态开展3个层次的风险评估。基于假想的铬污染场地开展了案例分析,设置了地下水污染状态的4种情景,利用Wexler溶质运移模型计算了地下水污染羽的时空变化,并针对地下水污染的不同层次开展了风险评估。结果表明,在场地地下水污染羽未到达场地边界的2种情形中,场地地下水的风险评分分别为4.0,6.2,分别属于低风险与中风险。在场地地下水污染羽到达或超出场地边界的2种情形中,场地地下水的风险评分分别为7.0,8.8,分别属于中风险与高风险。综合而言,本研究构建的方法能够用来对场地地下水进行系统全面的评估和对比,能够根据风险结果对污染场地进行有效的分级管控,为污染场地的风险管控提供技术支撑。     

中国典型有机污染场地土层岩性和污染物特征分析

目前我国存在大量待修复场地,其分布具有一定的规律性和区域性,场地地层系统结构复杂、渗透性空间异质性显著,污染物种类复杂。总结场地典型土层结构和典型污染物有助于有针对性地开展修复技术的研发。为此,本文收集并整理了全国136处有机污染场地相关资料,对其地域性、地层及污染物特征总结如下:目前我国已经开展调查与修复的有机污染场地主要集中在京津冀和沪宁杭地区;有机污染场地土层基本都含有黏土等低渗透介质,而且都具有非均质性,其中67%场地土层有强非均质性;沪宁杭地区场地土层渗透性总体低于京津冀和辽中南地区,此外我国京津冀和辽中南地区场地调查深度(20.3 m)总体大于沪宁杭地区(12.8 m);我国有机污染场地地下水中最常见的有机污染物种类为氯代溶剂,依次为氯代烷烃类(场地数量占比84%)、氯代苯类(场地数量占比46%)和氯代烯烃类(场地数量占比33%);最常见的3种氯代溶剂依次为二氯乙烷、一氯苯和三氯甲烷。     

当地下水邂逅DNA:石油类有机污染及其生物降解

地下水科学与工程研究发展到今日,已经成为一门涉及多个领域的综合性学科。地下水污染的控制和修复研究更需要跨学科的技术和知识支持,而生物修复作为一种高效低耗修复的技术成为环境领域的研究热点。微生物因其自身特性及其对污染的降解主导特征对确定有机物污染场地的永续修复具有重要意义。简要地综述了地下水有机污染及其原位修复、有机污染物和地下环境微生物的交互作用,进一步聚焦生物降解机制、生物修复和细菌研究。在此基础上以某石油污染场地地下水为例,进行了地下水中分离微生物菌株及其降解特征的实验研究。结果表明:放线菌降解效果最好,细菌和真菌次之;两两组合降解效果好于单菌,表明存在协同作用;不同菌株混合降解率较低,表明具有拮抗作用。通过动力学实验得出对TPH的降解符合一级反应动力学方程及其降解速度和降解半衰期。就微生物对有机组分降解而言,烷烃和总石油烃降解规律相似;难降解组分降解率低,后期因烷烃转化使其浓度升高;苯浓度变化不大。微生物活性实验表明:活菌总数和脱氢酶活性与降解率呈正相关变化。运用生理生化及分子生物学方法鉴定得出了具体的菌种。     

淮河水污染对环洪泽湖地区浅层地下水影响规律初探

为研究淮河水污染对环洪泽湖地区浅层地下水污染现状及其演变规律,选择位于盱眙北部平原地区鲍集作为地下水污染试验区,并在面上进行了大规模的取样,初步分析结果表明,淮河地表水常年补给浅层地下水,补给资源十分丰富,环洪泽湖地区浅层地下水已遭受严重污染.     

Groundwater contamination assessment in Al-Quwy’yia area of central Saudi Arabia using transient electromagnetic and 2D electrical resistivity tomography

Groundwater contamination is one of the most significant problems in arid countries. Al-Quwiy’yia region is an example of an area where the groundwater is contaminated as a result of infiltration of waste water in low-lying areas adjacent to inhabited zones. Such contamination poses significant environmental threats for the surrounding environment and groundwater. Surface observations and spatial distribution of contamination observed in the shallow aquifer indicate that the main contamination sources were from sewage as well as from waste water dumping. However, the main source of water supply for the whole area is groundwater abstracted from the relatively shallow aquifer. Therefore, the transient electromagnetic method (TEM) and 2D electrical resistivity tomography (2D ERT) have been applied close to the waste water dump site to characterize the response of pollution plumes. Both of these geoelectrical techniques are sensitive to electrical conductivity as well as to other physical properties, which are greatly influenced by the polluted groundwater. Therefore, it is possible to profile the contamination plumes, both vertically and horizontally, in the vicinity of the measured stations. The ERT profiles gave detailed information about the lateral distribution of the contaminated groundwater, whereas the TEM demonstrated the vertical extensions.     

某储油库地下水有机污染健康风险评价

本文以USEPA推荐使用的污染场地健康风险评价方法为基础, 结合污染场地实际情况, 分析、评价了某储油库地下水有机污染对场址内暴露人群造成的健康风险。评价结果表明: 该储油库地下水有机污染物为1,2-二氯乙烷、苯、三氯甲烷和甲苯。污染场址内的工人和居民受到的非致癌风险均小于1, 在可接受范围; 而污染对场址内的工人和居民产生的致癌风险较大, 分别为1.7×10?4、9.0×10?3, 是不可接受的。产生致癌风险的主要污染物为1, 2-二氯乙烷, 占总致癌风险的99.80%, 可致人产生多种形态的肿瘤, 并具有潜在的遗传毒性。主要暴露途径是吸入吸收, 占总致癌风险比例大于70%, 其次为口入吸收。皮肤接触暴露途径产生的致癌风险较小, 占总致癌风险比例小于1%。     

Transformation of Monoaromatic hydrocarbons to organic acids in anoxic groundwater environment

The transformation of benzene and a series of alkylbenzenes was studied in anoxic groundwater of a shallow glacial-outwash aquifer near Bemidji, Minnesota, U.S.A. Monoaromatic hydrocarbons, the most water-soluble components of crude oil, were transported downgradient of an oil spill, forming a plume of contaminated groundwater. Organic acids that were not original components of the oil were identified in the anoxic groundwater. The highest concentrations of these oxidized organic compounds were found in the anoxic plume where a decrease in concentrations of structurally related alkylbenzenes was observed. These results suggest that biological transformation of benzene and alkylbenzenes to organic acid intermediates may be an important attenuation process in anoxic environments. The transformation of a complex mixture of hydrocarbons to a series of corresponding oxidation products in an anoxic subsurface environment provides new insight into in situ anaerobic degradation processes.     

武汉市区第四系含水层地下水有机污染敏感性研究

在详细调查武汉市水文地质条件和地下水污染现状的基础上，获得了高精度的武汉市水环境中微量有机污染物的组成数据。所检测出的有机组分达30余种，以苯及相关苯系物为主，污染程度较高的地下水主要分布在人口密集区和工业，商业区，应用改进的DRASTIC模型－地下水污染敏感性评价模型，在GIS平台上，编制了武汉市区地下水污染敏感性分区图。根据其评价结果，建议集中对那些敏感性相对较高的区域采取有效的环保措施，开发利用时应作出风险评价。     

Nitrate contamination in a shallow urban aquifer in East Ukraine: evidence from hydrochemical,stable isotopes of nitrate and land use analysis

A combined hydrochemical and stable isotope approach was used to investigate the origin of nitrate in the shallow unconfined groundwater of Kharkiv city, Eastern Ukraine. The contamination was investigated in the context of land use within the catchment area. The observed enrichment of sulfate, chloride and nitrate suggests significant groundwater contamination in the shallow urban aquifer, which is widely used as drinking water source for the urban population. Characteristic nitrate/chloride ratios as well as stable isotope ratios (N and O) of nitrate in the most contaminated springs confirmed that septic waste from leaky sewer systems was the main source of nitrate contamination in the groundwater. Nitrate contamination is linked to the type of land use and sewage treatment regime in the catchment area. It is also modulated by the regional hydrogeology, which determines the susceptibility of a given aquifer toward groundwater pollution. A more quantitative assessment of nitrate sources based on the nitrate isotope analysis alone is rather difficult. However, our study confirms that the combination of hydrochemical tracers, robust land-use analysis and nitrate stable isotope measurements represents a valuable approach to identify the origin of the nitrate contamination.     

建议纳入地下水调查指标体系的有机污染物——基于迁移性和致病风险的分析

在地下水有机污染调查中,如何准确地选择测试项目,对于正确认识和评价地下水的污染状况是十分必要的.本文通过参照不同标准或规范中所选择的有机指标,依据它们的迁移性和致病风险,从258种有机物中遴选出了29种"地下水污染调查评价规范"(2006)中尚未包括的有机物(主要是除草剂和杀虫剂).建议在进行地下水有机污染调查时,依据当地的污染源情况,增加相应的监测指标,特别是要加强对致病风险高和迁移性较高有机物的重视.     

Use of a forensic geochemical technique and a hydrogeological assessment to determine the source of petroleum hydrocarbon contamination at a foreshore site in Korea

Investigations undertaken in 2013 at a foreshore site that was historically used for ship repairs in Korea indicated that soil and groundwater were contaminated with petroleum hydrocarbons over an area of 10,000 m². Groundwater investigations and modelling were undertaken to determine the characteristics of aquifers beneath the site, including the direction and rate of groundwater flow and the extent of dispersion of total petroleum hydrocarbon contamination. To identify petroleum products residing in contaminated soils, the hump of an unresolved complex mixture on the baseline found in the data of gas chromatography was used as a new method. Based on objective facts obtained from basic investigation, the current state of contamination, and discrimination of oil species, the polluter as specified in the Korean Soil Environment Conservation Act was identified.     

垃圾堆放场氯代脂肪烃对浅层地下水的污染特征初步分析

研究区是浅层地下水主要补给区，通过区内地下水监测说明，受垃圾淋滤液影响的地下水中氯代烃高值点主要集中在研究区中部；地下水中氯代烃检出值和检出率有季节性变化特征，与垃圾堆放时间和该井距垃圾场堆放场距离有密切关系，堆放时间越长，离垃圾堆放场越近，检出率、检出值越高；对地下水污染的敏感性和影响氯代烃迁移的机理方面进行了分析。     

胜利油田陆上采油区浅层地下水与土壤有机污染特征研究

本文在对胜利油田陆上采油区水文地质条件和污染源现状分析的基础上,对浅层地下水和包气带土壤进行了样品采集、污染物组分测试及污染程度研究,分析研究结果表明:胜利油田陆上采油区浅层地下水和土壤已普遍受有机物污染并形成多个有机污染区,检出的有机污染物达16种之多,个别有机物含量还很高.浅层地下水污染程度受到油田采油井数量、采油...     

下辽河平原区辽阳-鞍山地段浅层地下水污染评价

随着城市规模和城市化进程的扩大与加快,工业化程度的不断提高,区域地表水和地下水受到不同程度的污染,人类赖以生存的淡水资源面临威胁.20世纪90年代以来,我国开始关注农业污染和有机污染的研究工作.结合研究区研究情况,本次评价主要应用单因子污染指数法及综合污染指数法.综合分析了地下水评价的各种方法后,本次评价选择了单指标污染指数评价法和地下水污染综合评价法对该区进行评价.在研究区展开了野外调查,采集了浅层地下水样品110组（其中包括平行样、加标样和监控样合计20组）,每个样品测试了35项指标.评价结果表明,研究区67.4%浅层地下水受到不同程度的污染.根据本次评价,基本上反映了研究区地下水污染状况,并为有针对性的治理提供依据.     

珠江三角洲地区地下水污染调查内容综述

地下水污染问题得到我国政府的高度重视,珠江三角洲地区地下水污染调查评价于2005年展开实施,简要综述该区地下水污染调查内容,主要包括：污染源调查、地下水污染现状调查、水土测试指标的选取以及采样点的控制等。     

岩溶地区地下水污染风险评价方法探究——以地苏地下河系流域为例

岩溶地下水污染风险评价对岩溶地下水的保护、管理和合理利用具有重要意义。文章总结了近年来国内外地下水污染风险评价方面的研究进展,针对目前评价体系存在的不足,构建了适合岩溶区地下水污染风险评价体系。该方法基于欧洲模式,实现地下水防污性能评价;污染负荷评价则考虑污染物在覆盖层中的衰减过程,利用折减系数实现污染负荷量化;最后,基于GIS空间叠加分析耦合防污性能与污染负荷评价,实现区域地下水污染风险评价。文章以地苏地下河系流域为例,开展岩溶区域地下水污染风险评价,结果表明:区域整体地下水污染风险偏低,地下水中等及以上污染风险区域面积424.41 km2,占研究区总面积的39.03%,主要分布在研究区中东部地苏乡、东庙乡、六也乡局部等人类活动频繁与地苏地下河干流中下游段。地下水污染风险空间分布特征不仅显示了岩性、坡度、岩溶网络发育等自然条件对评价结果的影响,同时也反映了人类活动的影响。地势平缓,岩溶发育程度强烈,加之人类活动频繁是导致区域地下水污染风险较高的原因所在。      

Fate and transport of volatile organic compounds in glacial till and groundwater at an industrial site in Northern Ireland

Volatile organic compound (VOC) contamination of subsurface geological material and groundwater was discovered on the Nortel Monkstown industrial site, Belfast, Northern Ireland. The objectives of this study were to (1) investigate the characteristics of the geological material and its influences on contaminated groundwater flow across the site using borehole logs and hydrological evaluations, and (2) identify the contaminants and examine their distribution in the subsurface geological material and groundwater using chemical analysis. This report focuses on the eastern car park (ECP) which was a former storage area associated with trichloroethene (TCE) degreasing operations. This is where the greatest amount of volatile organic compounds (VOCs), particularly TCE, were detected. The study site is on a complex deposit of clayey glacial till with discontinuous coarser grained lenses, mainly silts, sands and gravel, which occur at 0.45–7.82 m below ground level (bgl). The lenses overall form an elongated formation that acts as a small unconfined shallow aquifer. There is a continuous low permeable stiff clayey till layer beneath the lenses that performs as an aquitard to the groundwater. Highest concentrations of VOCs, mainly TCE, in the geological material and groundwater are in these coarser lenses at ∼4.5–7 m bgl. Highest TCE measurements at 390,000 μg L⁻¹ for groundwater and at 39,000 μg kg⁻¹ at 5.7 m for geological material were in borehole GA19 in the coarse lens zone. It is assumed that TCE gained entrance to the subsurface near this borehole where the clayey till was thin to absent above coarse lenses which provided little retardation to the vertical migration of this dense non-aqueous phase liquid (DNAPL) into the groundwater. However, TCE is present in low concentrations in the geological material overlying the coarse lens zone. Additionally, VOCs appear to be associated with poorly drained layers and in peat <3.0 m bgl in the ECP. Some indication of natural attenuation as VOCs degradation products vinyl chloride (VC) and dichloromethane (DCM) also occur on the site.     

Pollution par les nitrates des nappes phréatiques sous environnement semi-urbain non assaini: example de la nappe de Yeumbeul, Sénégal

High nitrate concentrations, above the WHO guideline of 50 mg l⁻¹, were observed in samples of shallow wells reaching the Yeumbeul suburb (Senegal) area groundwater. This groundwater is exploited by 7000 houses and therefore there are health implications. Correlations between parameters such as nitrate content (NO₃⁻) in the groundwater and soil water, the distance between shallow wells and family latrines, and soil water chloride (Cl⁻) and colon bacillus content led to two possible sources of groundwater pollution: first, contamination by non impervious and shallow latrines; and second, the leaching of soil NO₃⁻ from waste organic matter carried in groundwater.