海水中矿物质颗粒吸收和散射特性Mie理论分析

利用Mie理论模型对不同粒径分布和复折射率的矿物质颗粒吸收和散射特性进行了模拟计算.颗粒的衰减和散射效率随着参数ρ的增大呈现出振幅依次减小的一系列有规则的振荡变化,而吸收效率则随着ρ的增加而增大;随着颗粒吸收性的增强,散射效率和吸收效率随着ρ的增大最终都将趋近极限值1.对于矿物质颗粒群,颗粒群的粒度分布变化对散射和后向散射特性影响很大,小粒径粒子对散射和后向散射的贡献比较大;折射率实部以及虚部变化对散射特性均有影响,颗粒的吸收性越强,则散射会相应地减弱;粒度分布以及折射率虚部对吸收系数也存在较大的影响,但是折射率实部对吸收系数的影响不大.     

Eddy diffusivity and coherent mesoscale eddy analysis in the Southern Ocean

The spatial distribution of eddy diffusivity, basic characteristics of coherent mesoscale eddies and their relationship are analyzed from numerical model outputs in the Southern Ocean. Mesoscale fluctuation information is obtained by a temporal-spatial filtering method, and the eddy diffusivity is calculated using a linear regression analysis between isoneutral thickness flux and large-scale isoneutral thickness gradient. The eddy diffusivity is on the order of O (103 m2/s) with a significant spatial variation, and it is larger in the area with strong coherent mesoscale eddy activity. The mesoscale eddies are mainly located in the upper ocean layer, with the average intensity no larger than 0.2. The mean radius of the coherent mesoscale cyclonic (anticyclonic) eddy gradually decays from (121.2±10.4) km ((117.8±9.6) km) at 30°S to (43.9±5.3) km ((44.7±4.9) km) at 65°S. Their vertical penetration depths (lifespans) are deeper (longer) between the northern side of the Subpolar Antarctic Front and 48°S. The normalized eddy diffusivity and coherent mesoscale eddy activity show a significant positive correlation, indicating that coherent mesoscale eddy plays an important role in eddy diffusivity.     

Effect of vertical viscosity and diffusivity on tropical ocean circulation

Response of the tropical ocean to a uniform zonal wind is studied numerically and analytically. In addition to the Equatorial Undercurrent and surface westward flows on both sides of the equator, an eastward flow at the pycnocline depth is formed at several degrees latitude in both hemispheres. This subsurface eastward flow first appears in the eastern part of the ocean and extends to the west. Then it gradually decreases in speed, and at a steady state the speed is of the order of 1cm sec^–1. The spatial distribution of this subsurface flow is similar to the Subsurface Countercurrent, but the speed is one order smaller than that observed. The obtained thermostad is obscure compared with that observed. Whole of the time evolution produced by a numerical model can be accounted for by linear wave dynamics in a multi-layer model including vertical diffusion and friction. Although diffusion and friction are essential to maintain this subsurface flow, changes in the values of coefficients for vertical viscosity and diffusivity and also in initial density stratification lead only to a minor change in the speed of the subsurface eastward flow. It is concluded that a subsurface eastward flow with speed exceeding 10 cm sec^–1 accompanied by a distinctive thermostad structure cannot be explained by linear wave dynamics including vertical dissipation.     

Modeling of the eddy viscosity by breaking waves

Breaking wave induced nearsurface turbulence has important consequences for many physical and biochemical processes including water column and nutrients mixing,heat and gases exchange across air-sea interface.The energy loss from wave breaking and the bubble plume penetration depth are estimated.As a consequence,the vertical distribution of the turbulent kinetic energy(TKE),the TKE dissipation rate and the eddy viscosity induced by wave breaking are also provided.It is indicated that model results are found to be consistent with the observational evidence that most TKE generated by wave breaking is lost within a depth of a few meters near the sea surface.High turbulence level with intensities of eddy viscosity induced by breaking is nearly four orders larger than υwl(=κuwz),the value predicted for the wall layer scaling close to the surface,where uw is the friction velocity in water,κ with 0.4 is the von Kármán constant,and z is the water depth,and the strength of the eddy viscosity depends both on wind speed and sea state,and decays rapidly through the depth.This leads to the conclusion that the breaking wave induced vertical mixing is mainly limited to the near surface layer,well above the classical values expected from the similarity theory.Deeper down,however,the effects of wave breaking on the vertical mixing become less important.     

Relationship between the grid size and the coefficient of lateral eddy viscosity in the finite difference computation of the linear vorticity equation in the ocean

The finite difference analog of the linear vorticity equation for the mass transport in the ocean does not hold good unless the grid size is smaller than a certain number.I thank Profs. YaleMintz, AkioArakawa and TaroMatsuno for their valuable suggestions.     

海水悬浮物浓度原位测量技术进展

海水悬浮物指海水中的悬浮颗粒物和浮游微生物等，对海水悬浮物浓度进行准确的测量具有重要的意义。海水悬浮物浓度测量技术，无论是传统方法（即现场采水），还是现代方法（即间接测量方式，包括光学法和声学法等）都有一定的不足。本文主要综述了几种海水悬浮物浓度间接测量方法、国内外有关海水原位过滤测量的技术研发进展及深海原位微孔过滤技术。最后，对海水悬浮物原位过滤技术的发展方向进行了探讨。     

Mobilization of metals from riverine suspended matter in seawater

Suspended matter from rivers in the Russian Far East was leached by seawater to assess the extent of Zn, Cd, Pb, and Cu release from the land-derived solids to estuarine and coastal waters. The concentration of solids in the leaching experiments was 0.25 g/l. The suspended matter used varied in metal content from background levels to heavily contaminated.The concentration of Zn, Cd, Pb, and Cu in the leaching solution after 1, 4, 24, 48, and 96 h was determined by anodic stripping voltammetry. Measurable Cd was transferred from river suspended matter to seawater with both background and elevated Cd concentrations, though the amount of Cd released was different. The increase in Zn and Pb in solution was observed only at the enriched concentration of metals in the suspended solids. The Cu transfer into solution was more pronounced from material with elevated Cu concentration, but the amount of degradable organic matter in the solid phase was more important.The losses of metals from the riverine solids varied from 60% to 80% of total concentration for Cd to negligible for Pb, independent of contamination. The Zn loss depended on the initial concentration in the solids and decreased from 11–16% for the heavily contaminated suspended matter to 3–8% for the moderately enriched ones and to negligible for the pristine solids. Cu loss varied from 1% to 30% of total content, with no clear dependence on concentration in the suspended matter.The significance of additional input of dissolved metals to estuarine and coastal waters from remobilization was assessed by comparison with the initial concentration of dissolved metals in river water. Such experiments could be used to assess the water quality impact of atmospheric fallout of contaminated solids and storm drainage from the urbanized areas, in addition to river suspended matter studies.     

Relationship between the suspended particulate matter and microorganisms in the White Sea waters

During the summer periods of 2003–2005, the spatial and vertical distributions of the suspended particulate matter and bacteria in stratified and homogeneous waters of the White Sea was studied. The results of the study of various quantitative characteristics of the suspended particulate matter (first of all, the area of the surface and the volumetric and mass concentrations) and the abundance of microorganisms in the water are discussed. A direct correlation between the value of the surface area of the suspended particulate matter and the total number of bacteria in the water is revealed. However, it was manifested only during the early summer period of the observations and was not expressed at the end of the summer. The enhanced surface area of the suspended particulate matter can indicate the higher biochemical activity of its particles. The influence of the pelitic fraction on the bacteria abundance in different parts of the sea during the summer is estimated.     

Relationship between tissue phosphorus and seawater phosphate in the brown alga Hormosira banksii

We measured tissue phosphorus content of high and low intertidal Hormosira banksii to test the hypothesis that tissue phosphorus content would be greater in individuals from the low intertidal because of greater total uptake associated with longer immersion in seawater. Moreover, we predicted that tissue phosphorus would be greater at sites where the seawater contained higher phosphate concentrations. There was a positive, linear relationship between local seawater phosphate concentrations and tissue phosphorus content of H. banksii from high and low intertidal zones at six different sites in winter. However, there were no comparable relationships in summer, even though the range of seawater phosphate concentration was similar in both seasons. The phosphorus contents of low intertidal H. banksii were significantly greater than high intertidal H. banksii in winter, but not in summer. Reasons for these differences may be related to greater access to seawater phosphate in low intertidal algae (than those in the high intertidal) in winter, followed by greater utilisation of the internal phosphorus between winter and summer, due to faster growth rates in the low intertidal.     

海水悬浮颗粒物中不同形态磷的测定

分别采用硫酸过硫酸钾作为氧化剂进行高压消解和用浓度为1 mol/dm³盐酸浸泡提取,然后用磷钼蓝分光光度法测定海水悬浮颗粒物、沉积物中的总磷和无机磷,用差减法得到有机磷。悬浮颗粒物总磷(PTP)和无机磷(PIP)质量浓度分别为(632.4～651.7)×10^-6和(436.6～452.6)×10^-6时,其相对标准偏差小于1.44%。悬浮颗粒物总磷、无机磷和有机磷的回收率分别为97.2%～101.3%,97.8%～100.4%和97.3%～102.3%。所建立的分析方法可用于海水、河口水悬浮颗粒物及沉积物中不同形态磷的测定。     

Fatty-acid methyl esters dissolved in seawater and associated with suspended particulate material

Methyl esters of saturated and unsaturated fatty acids were isolated as trace components from organic material suspended in seawater. Methyl palmitate and methyl stearate were accumulated from the filtrate by adsorption onto Amberlite XAD-2 resin. Identification of most methyl esters is based on the comparison of gas chromatographic retention indices and mass spectrometric fragmentation with those of authentic standard compounds. In cases where reference substances were not available, identification is based on mass spectrometric and gas chromatographic properties of the unknown compounds.     

An approximate solution of wave-modified Ekman current for gradually varying eddy viscosity

An approximate steady solution of the wave-modified Ekman current is presented for gradually varying eddy viscosity by using the WKB method with the variation of parameters technique. The parameters involved in the solution can be determined by the two-dimensional wavenumber spectrum of ocean waves, wind speed, the Coriolis parameter and the densities of air and water. The solution reduces to the exact solution when the eddy viscosity is taken as a constant. As illustrative examples, for a fully developed wind-generated sea with different wind speeds and a few proposed gradually varying eddy viscosities, the current profiles calculated from the approximate solutions are compared with those of the exact solutions or numerical ones by using the Donelan and Pierson wavenumber spectrum, the WAM wave model formulation for wind input energy to waves, and wave energy dissipation converted to currents. It is shown that the approximate solution presented has an elegant form and yet would be valid for any given gradually varying eddy viscosity. The applicability of the solution method to the real ocean is discussed following the comparisons with published observational data and with the results from a large eddy simulation of the Ekman layer.     

Estimates of the lateral eddy diffusivity in the Indian Ocean as derived from drifter data

The Global Drifter Program data set is applied to develop 2° × 2° bin estimates of the lateral eddy diffusivity K in the Indian Ocean (IO) by means of a modification of the Davis approach. The calculations were performed relative to the seasonal change in the mean currents, which is especially important in the case of monsoon-driven circulation in the IO. Estimates of K were found to be below 1 × 10⁴ m²/s almost every-where in the IO. The spatial variations of K were analyzed in relation to the instabilities of the ocean circulation.     

台湾海峡西部海水二氧化碳体系各分量与环境因子的相关性

据１９８４年５月至１９８５年２月调查资料，计算了该水体中二氧化碳体系各分量的含量，研究了它们与ｐＨ，ＨＣＯ＾－３／ＣＯ＾２－３，Ａｌｋ，ＤＩＮ，ＰＯ＾３－４－９，Ｃｈｌ－ａＤＯ，Ｓ，ｔ等环境因子的相关性。结果表明ＰＣＯ３，ＣＯ２（Ｔ），ＨＣＯ＾－３，ＣＯ＾２－３与ｐＨ，ＨＣＯ＾－３／ＣＯ＾２－３呈极显著的线性相关；ＨＣＯ＾－３，ＣＯ＾２－３ΣＣＯ２与Ａｌｋ也呈非常显著的线性相关。     

基于电导率测定海水悬沙含量试验研究

为了寻求一种简单、快速、连续确定悬浮泥沙含量的方法,以高含沙量海区黄河口泥沙为研究对象,利用电导率仪测定了不同悬浮泥沙含量水体的电导率,建立起了悬浮泥沙含量与电导率之间的关系,并对影响上述关系的因素进行了分析,结果表明,悬浮泥沙含量与电导率之间有很好的线性关系;盐度、颗粒粒径对电导率具有一定的影响,其中盐度的影响最大,颗粒粒径的影响较小。在盐度变化范围有限的高悬沙含量海区,用电导率的方法来实现现场监测悬浮泥沙含量是可行的。     

夏季黄海、东海鞭毛虫的丰度与悬浮颗粒物的关系

对2001年8月黄海中部和南部以及东海北部海洋鞭毛虫的丰度及其与悬浮颗粒物的数量关系进行了研究,发现调查区域内的鞭毛虫丰度为44~12 600个/cm3,它们在悬浮颗粒中所占的比例可达60%以上.悬浮颗粒物的粒径谱可以分为平缓型、驼峰型、浮游生物型和混合型.鞭毛虫丰度的变化与悬浮颗粒物的数量分布具有相似的变化趋势,整体上来说,两者数量的相关性显著,而不同的粒径谱类型中,两者的关系有不同的特点.对两者的数量关系进行了初步的探讨,并为今后海域生态调查中鞭毛虫丰度的快速估计提供一条新的途径.     

西北太平洋中尺度涡半径与涡动能的统计关系

中尺度涡的半径与涡动能之间的关系及其内在机制的研究,对我们理解中尺度涡旋的三维结构特征及其变异规律有很大的帮助。本文利用AVISO卫星高度计融合数据,基于流场几何特征的识别方法对西北太平洋(10°～52°N, 120°～180°E)的中尺度涡进行了识别追踪,并由此分析了该区域内中尺度涡的半径与涡动能(Eddy Kinetic Energy, EKE)的统计关系。结果表明该区域中尺度涡的半径与EKE之间存在类似翻转高斯函数的递增关系,特别是在涡旋半径达到一定程度后,EKE将不随半径的变大而继续增强。而且该关系与纬度密切相关,相同半径条件下,涡旋的EKE近似与其所在纬度的第一斜压Rossby变形半径的平方呈反比。进一步分析表明该统计关系与中尺度涡所处的发展阶段没有明显的联系。该结果为建立一个实用性的参数化、归一化的中尺度涡模型提供了一定的理论基础。     

Feeding of copepods on natural suspended particles in Tokyo Bay

Community grazing rates of copepods were estimated from data taken during three cruises in Tokyo Bay, based on bottle incubations and a temporal variation of gut fluorescence. Special attention was paid to the feeding selectivity in the estimations. Differential grazing was observed in the copepod communities:Acartia omorii, abundant in February, selectively fed on the particles of dominant size classes, whileOithona davisae, dominant throughout the year, andCentropages abdominalis selected large particles (>20µm). The maximum filtering rates on certain size classes were several times the average. In addition, a 34-hr investigation of the gut fluorescence of copepods revealed nocturnal feeding inParacalanus spp.,Pseudodiaptomus marinus andOithona davisae.Copepod communities collected with a net (95-µm mesh opening) were estimated to graze, in February 3.0%, in August 3.1–4.5% and in November 4.2–11.9% of the standing crops of phytoplankton or suspended particles per day.     

The distribution of suspended particles in the Southern Beaufort Sea

The Mackenzie River estuary serves as an avenue for suspended particles to pass seaward. The horizontal distribution of surface suspended particles is compartible with the distribution of low-salinity surface waters. The water structure in the shelf area is highly stratified in summer due to a thin upper layer of low-salinity which has a high concentration of suspended particles. The concentration of suspended particles decreases with depth, but near the bottom a turbid layer had often been observed. It is likely that bottom current energy high enough to erode and maintain in suspension the bottom sediments below 15m in diameter does occur over this shelf area.