Geochemistry of the volcano-hydrothermal system of El Chichón Volcano, Chiapas, Mexico

 The 1982 eruption of El Chichón volcano ejected more than 1 km³ of anhydrite-bearing trachyandesite pyroclastic material to form a new 1-km-wide and 300-m-deep crater and uncovered the upper 500 m of an active volcano-hydrothermal system. Instead of the weak boiling-point temperature fumaroles of the former lava dome, a vigorously boiling crater spring now discharges  / 20 kg/s of Cl-rich (∼15 000 mg/kg) and sulphur-poor ( / 200 mg/kg of SO₄), almost neutral (pH up to 6.7) water with an isotopic composition close to that of subduction-type magmatic water (δD=–15‰, δ¹⁸O=+6.5‰). This spring, as well as numerous Cl-free boiling springs discharging a mixture of meteoric water with fumarolic condensates, feed the crater lake, which, compared with values in 1983, is now much more diluted (∼3000 mg/kg of Cl vs 24 030 mg/kg), less acidic (pH=2.6 vs 0.56) and contains much lower amounts of S ( / 200 mg/kg of SO₄, vs 3550 mg/kg) with δ³⁴S=0.5–4.2‰ (+17‰ in 1983). Agua Caliente thermal waters, on the southeast slope of the volcano, have an outflow rate of approximately 100 kg/s of 71  °C Na–Ca–Cl water and are five times more concentrated than before the eruption (B. R. Molina, unpublished data). Relative N₂, Ar and He gas concentrations suggest extensional tectonics for the El Chichón volcanic centre. The ³He/⁴He and ⁴He/²⁰Ne ratios in gases from the crater fumaroles (7.3R_a, 2560) and Agua Caliente hot springs (5.3R_a, 44) indicate a strong magmatic contribution. However, relative concentrations of reactive species are typical of equilibrium in a two-phase boiling aquifer. Sulphur and C isotopic data indicate highly reducing conditions within the system, probably associated with the presence of buried vegetation resulting from the 1982 eruption. All Cl-rich waters at El Chichón have a common source. This water has the appearence of a "partially matured" magmatic fluid: condensed magmatic vapour neutralized by interaction with fresh volcaniclastic deposits and depleted in S due to anhydrite precipitation. Shallow ground waters emerging around the volcano from the thick cover of fresh pumice deposits (Red waters) are Ca–SO₄–rich and have a negative oxygen isotopic shift, probably due to ongoing formation of clay at low temperatures. Received: 21 July 1997 / Accepted: 4 December 1997     

Volcanic history of El Chichón Volcano (Chiapas, Mexico) during the Holocene, and its impact on human activity

2 abundance and depletion in MgO, CaO, TiO₂, as well as trace and rare earth elements. This suggests segregation of olivine and orthopyroxene from the melt. Since human settlements in southeast Mexico and Central America can be traced as far back as approximately 2500 years BP, most of these events probably affected human activity. In fact, there are reports of pottery shards and other artifacts in deposits from the eruption of 1250 BP. Pottery fragments in deposits of an eruption that took place 2500 BP are also reported in this paper. Thus, the impact of the volcano on human activities has been frequent, with most of the repose intervals lasting between 100 to 600 years. The impact of the eruptions was probably of greater than local extent, because airfall tephra could reach distant sites and possibly even affect weather. The eruptive history of El Chichón also offers clues in the investigation of the Maya civilization. Several researchers have considered the volcano as an important factor in the answer to some intriguing questions such as the extensive use of volcanic ash in Late Classic Maya ceramics or, of greater importance, the causes of the collapse of the Classic Maya civilization. Received : 4 May 1998 / Accepted: 1 November 1999     

Simulating CO<Subscript>2</Subscript> transport into the ocean from a CO<Subscript>2</Subscript> lake at the seafloor using a <Emphasis Type="Italic">z</Emphasis>- and a <Emphasis Type="Italic">σ</Emphasis>-coordinate model

The ocean takes up approximately 2 GT carbon per year due to the enhanced CO₂ concentrations in the atmosphere. Several options have been suggested in order to reduce the emissions of CO₂ into the atmosphere, and among these are CO₂ storage in the deep ocean. Topographic effects of dissolution and transport from a CO₂ lake located at 3,000-m depth have been studied using the z-coordinate model Massachusetts Institute of Technology general circulation model (MITgcm) and the σ-coordinate model Bergen ocean model (BOM). Both models have been coupled with the general ocean turbulence model (GOTM) in order to account for vertical subgrid processes. The chosen vertical turbulence mixing scheme includes the damping effect from stable stratification on the turbulence intensity. Three different topographic scenarios are presented: a flat bottom and the CO₂ lake placed within a trench with depths of 10 and 20 m. The flat case scenario gives good correlation with previous numerical studies of dissolution from a CO₂ lake. When topography is introduced, it is shown that the z-coordinate model and the σ-coordinate model give different circulation patterns in the trench. This leads to different dissolution rates, 0.1 μmol cm^− 2 s^− 1 for the scenario of a 20-m-deep trench using BOM and 0.005–0.02 μmol cm^− 2 s^− 1 for the same scenario using the MITgcm. The study is also relevant for leakages of CO₂ stored in geological formations and to the ocean.     

Hydrochemical dynamics of the “lake–spring” system in the crater of El Chichón volcano (Chiapas,Mexico)

El Chichón volcano (Chiapas, Mexico) erupted violently in March–April 1982, breaching through the former volcano–hydrothermal system. Since then, the 1982 crater has hosted a shallow (1–3.3 m, acidic (pH ∼ 2.2) and warm (∼ 30 °C) crater lake with a strongly varying chemistry (Cl/SO₄ = 0–79 molar ratio). The changes in crater lake chemistry and volume are not systematically related to the seasonal variation of rainfall, but rather to the activity of near-neutral geyser-like springs in the crater (Soap Pool). These Soap Pool springs are the only sources of Cl for the lake. Their geyser-like behaviour with a long-term (months to years) periodicity is due to a specific geometry of the shallow boiling aquifer beneath the lake, which is the remnant of the 1983 Cl-rich (24,000 mg/l) crater lake water. The Soap Pool springs decreased in Cl content over time. The zero-time extrapolation (1982, year of the eruption) approaches the Cl content in the initial crater lake, meanwhile the extrapolation towards the future indicates a zero-Cl content by 2009 ± 1. This particular situation offers the opportunity to calculate mass balance and Cl budget to quantify the lake–spring system in the El Chichón crater. These calculations show that the water balance without the input of SP springs is negative, implying that the lake should disappear during the dry season. The isotopic composition of lake waters (δD and δ¹⁸O) coincide with this crater lake-SP dynamics, reflecting evaporation processes and mixing with SP geyser and meteoric water. Future dome growth, not observed yet in the post-1982 El Chichón crater, may be anticipated by changes in lake chemistry and dynamics.     

Continuous soil CO<Superscript>2</Superscript> and discrete plume SO<Subscript>2</Subscript> measurements at Mt. Etna (Italy) during 1997–2000: a contribution to volcano monitoring

Continuous monitoring of soil CO₂ dynamic concentration (which is proportional to the CO₂ flux through the soil) was carried out at a peripheral site of Mt. Etna during the period November 1997–September 2000 using an automated station. The acquired data were compared with SO₂ flux from the summit craters measured two to three times a week during the same period. The high frequency of data acquisition with both methods allowed us to analyze in detail the time variations of both parameters. Anomalous high values of soil CO₂ dynamic concentration always preceded periods of increased flux of plume SO₂, and these in turn were followed by periods of summit eruptions. The variations were modeled in terms of gas efflux increase due to magma ascent to shallow depth and its consequent depressurization and degassing. This model is supported by data from other geophysical and volcanological parameters. The rates of increase both of soil CO₂ dynamic concentration and of plume SO₂ flux are interpreted to be positively correlated both to the velocity of magma ascent within the volcano and to lava effusion rate once magma is erupted at the surface. Low rates of the increase were recorded before the nine-month-long 1999 subterminal eruption. Higher rates of increase were observed before the violent summit eruption of September-November 1999, and the highest rates were observed during shorter and very frequent spike-like anomalies that preceded the sequence of short-lived but very violent summit eruptions that started in late January 2000 and continued until late June of the same year. Furthermore, the time interval between the peaks of CO₂ and SO₂ in a single sequence of gas anomalies is likely to be controlled by magma ascent velocity.Editorial responsibility: H. Shinohara     

Automated,high time-resolution measurements of SO<Subscript>2</Subscript> flux at Soufrière Hills Volcano,Montserrat

We report here the first results from an automated, telemetered UV scanning spectrometer system for monitoring SO ₂ emission rates at Soufrière Hills Volcano, Montserrat. Two spectrometers receive light by way of a motor-driven stepping prism and telescope in order to make vertical scans of the volcanic plume. Spectral data from these spectrometers, situated 2,800 m apart and 4,500 m from the volcano, are relayed back to the observatory every 4–5 s via radio modems. A full scan of the plume is accomplished every 1–6 min by the (time-synchronised) spectrometers and a SO ₂ emission rate is calculated using the SO ₂ slant concentrations, scan angles and plume speeds estimated from the wind speed from a telemetered weather station near to the volcano. The plume's position and dimensions are calculated using the angular data from the two spectrometers. The plume height varies significantly diurnally and seasonally and is important in order to minimise the error on SO ₂ emission rates. The new scanning system (Scanspec) provides SO ₂ emission rates from 08:00 to 16:00 h local time every day. Preliminary results highlight a number of features of the SO ₂ time series and plume dynamics and give our first indications of the errors and limits of detection of this system. SO ₂ emission rates vary widely on all time scales (minutes, days, months). This new system has already provided the first real and consistent indication that SO ₂ emission rates vary on a minutes to hours basis, which can be correlated with volcanic activity (for example, rockfall and pyroclastic flow activity). It is anticipated that this system at Soufrière Hills will yield information on shallow processes occurring on short time scales (periods of minutes to hours) as well as deep processes relating to magma supply rates, which will be associated with longer wavelength SO ₂ signals of weeks to months.     

Structural analysis and interpretation of the surface deformation associated with the Ning’er,Yunnan Province,China <Emphasis Type="Italic">M</Emphasis><Subscript>S</Subscript>6.4 earthquake of June 3, 2007

The seismogenic fault and the dynamic mechanism of the Ning’er, Yunnan Province M_S6.4 earthquake of June 3, 2007 are studied on the basis of the observation data of the surface fissures, sand blow and water eruption, landslide and collapse associated with the earthquake, incorporating with the data of geologic structures, focal mechanism solutions and aftershock distribution for the earthquake area. The observation of the surface fissures reveals that the Banhai segment of the NW-trending Ning’er fault is dominated by right-lateral strike-slip, while the NNE-trending fault is dominated by left-lateral strike-slip. The seismo-geologic hazards are concentrated mainly within a 330°-extending zone of 13.5 km in length and 4 km in width. The major axis of the isoseismal is also oriented in 330° direction, and the major axis of the seismic intensity VIII area is 13.5 km long. The focal mechanism solutions indicate that the NW-trending nodal plane of the Ning’er M_S6.4 earthquake is dominated by right-lateral slip, while the NE-trending nodal plane is dominated by left-lateral slip. The preferred distribution orientation of the aftershocks of M_S≥2 is 330°, and the focal depths are within the range of 3～12 km, predominantly within 3～10 km. The distribution of the aftershocks is consistent with the distribution zone of the seismo-geologic hazards. All the above-mentioned data indicate that the Banhai segment of the Ning’er fault is the seismogenic fault of this earthquake. Moreover, the driving force of the Ning’er earthquake is discussed in the light of the active block theory. It is believed that the northward pushing of the Indian plate has caused the eastward slipping of the Qinghai-Tibetan Plateau, which has been transformed into the southeastern-southernward squeezing of the southwest Yunnan region. As a result, the NW-trending faults in the vicinity of the Ning’er area are dominated by right-lateral strike-slip, while the NE-trending faults are dominated by left-lateral strike-slip. This tectonic framework might be the main cause of the frequent occurrence of M_S6.0～6.9 earthquakes in the area.     

<Emphasis Type="Italic">Homo erectus pekinensis’s</Emphasis> age and environment— with discussion on the relationship among<Emphasis Type="Italic">Homo erectos</Emphasis> from Beijing,Nanjing and Chenjiawo

This paper inspects the relationship betweenHomo erectus from Beijing, Nanjing and Chenjiawo on the viewpoint of environmental variations. Pieces of evidence show that Nanjing and ChenjiawoHomo erectus lived in glacial age at the Marine Oxygen Isotope Stage (MIS) 16, whileHomo erectus pekinensis in major interglacial age at MISs 15-13. It is also recovered that the cave deposits in Tangshan, Nanjing, and Zhoukoudian, Beijing, as well as the deposits at theHomo erectus site in Chenjiawo, have undergone some similar development process. All of them originated from early-middle Middle Pleistocene, and have gone through the test of the major glacial age at MIS 16 and the major interglacial period at the paleosol stage S₅. At the same time, they were also closely connected with some environment events, such as the uplift of the Qinghai-Xizang Plateau, the formation of glaciations and the loess accumulations.