The Geochemistry of Boron in a Landfill Monitoring Program

Ground water monitoring data collected during the past eight years at a permitted municipal solid waste (MSW) disposal facility located in the midwestern United States indicated fluctuations in typical leachate indicator parameter concentrations. Apparent trends in the data inferred leachate outbreak, generating suspicion as to the integrity of the landfill liner. Eight ground water monitoring wells were installed in three distinct geologic units at the landfill facility, including glacial drift, silurian dolomite, and a post-glacial peat fen, which is downgradient from the landfill. Piezometer nests were used to define ground water gradients at the site. Using boron as an indicator, the occurrence of analytes of concern in the downgradient monitoring wells were shown to be indicative of the natural geochemistry of site ground water. This work emphasizes the importance of understanding site hydrogeology during the interpretation of ground water quality data.     

Long-Term Confidence in Ground Water Monitoring Systems

State-of-the-art analytical techniques are capable of detecting contamination In the part per billion (ppb) range or lower. At these levels, a truly representative ground water sample Is essential to precisely evaluate ground water quality. The design specifications of a ground water monitoring system are critical in ensuring the collection of representative samples, particularly throughout the long-term monitoring period.
The potential interfaces from commonly used synthetic well casings require a thorough assessment of site, hydrogeology and the geochemical properties of ground water. Once designed, the monitoring system must be installed following guidelines that ensure adequate seals to prevent contaminant migration during the installation process or at some time in the future. Additionally, maintaining the system so the wells are in hydraulic connection with the monitored zone as well as periodically Inspecting the physical integrity of the system can prolong the usefulness of the wells for ground water quality. When ground water quality data become suspect due to potential interferences from existing monitoring wells, an appropriate abandonment technique must be employed to adequately remove or destroy the well while completely sealing the borehole.
The results of an inspection of a monitoring system comprised of six 4-inch diameter PVC monitoring wells at a hazardous well facility Indicated that the wells were improperly installed and in some cases provided a pathway for contamination. Subsequent down hole television inspections confirmed inaccuracies between construction logs and the existing system as well as identified defects in casing materials. An abandonment program was designed which destroyed the well casings in place while simultaneously providing a competent seal of the re-drilled borehole.     

Applications of Dual-Wall Reverse-Circulation Drilling in Ground Water Exploration and Monitoring

Dual-wall reverse-circulation drilling uses flush-threaded double-wall drill pipe and high-pressure air to provide continuous return of formation and water samples. Cuttings and formation waters are not contaminated with drilling additives or mixed with other borehole material. Up-hole velocity of about 70 ft/sec provides reliable logging of water, mineral or contaminant-bearing strata. Water samples representative of specific strata may be airlifted or bailed to the surface.
In the percussion hammer system, dual-wall drill pipe is advanced through chiefly unconsolidated material by the percussion action of an above-ground pile hammer. The borehole is drilled and temporarily cased in one pass. Wells or monitoring devices are installed as the drill pipe is hydraulically retracted during construction. A rotary head may be adapted as an option to allow dual-wall rotary drilling into consolidated or crystalline formations through a percussion hammer drill string temporarily left in place as a conductor.
The complex geology and variety of geoenvironmental problems in southern California has provided a testing ground for dual-wall drilling on hazardous material site investigations. Several case histories have demonstrated the capabilities and versatility of this method, including: (1) the installation of 4-inch and 6-inch diameter gasoline monitoring and recovery wells through gravels and cobbles at a filling station where hollow-stem auger drilling failed; (2) the confirmation of a dry borehole initially drilled by direct rotary at a landfill; and (3) multiple installations of monitoring devices through municipal refuse at a city of Los Angeles landfill.     

Detection of Contaminant Plumes by Borehole Geophysical Logging

Two borehole geophysical methods—electromagnetic induction and natural gamma radiation logs—were used to vertically delineate landfill leachate plumes in a glacial aquifer. Geophysical logs of monitoring wells near two land-fills in a glacial aquifer in west-central Vermont show that borehole geophysical methods can aid in interpretation of geologic logs and placement of monitoring well screens to sample landfill leachate plumes.
Zones of high electrical conductance were delineated from the electromagnetic log in wells near two landfills. Some of these zones were found to correlate with silt and clay units on the basis of drilling and gamma logs. Monitoring wells were screened specifically in zones of high electrical conductivity that did not correlate to a silt or clay unit. Zones of high electrical conductivity that did not correlate to a silt or clay unit were caused by the presence of ground water with a high specific conductance, generally from 1000 to 2370 μS/cm (microsiemens per centimeter at 25 degrees Celsius). Ambient ground water in the study area has a specific conductance of approximately 200 to 400 μS/cm. Landfill leachate plumes were found to be approximately 5 to 20 feet thick and to be near the water table surface.     

The Effect of Construction, Installation, and Development on the Turbidity of Water in Monitoring Wells in Fine-Grained Glacial Till

Twenty monitoring wells were installed in fine-grained glacial till at two sites in southeastern Wisconsin to study the effects of monitoring well construction, installation, and development on the amount of fine-grained suspended material in the well. The types of well screens used were continuous slot, factory slot, factory slot with a filter wrap, and porous piezometer tips. Some of the wells were installed before the open borehole began to fill with water; others were installed after the water levels in the lower section of the borehole had begun to rise. About half of the wells were developed by surging while the others were simply bailed without surging. Installation of the wells in the initially dry holes resulted in wells that yielded samples with very low turbidity compared to wells installed in wet holes. Water samples from wells that were surged were more turbid than those that were not. The type of construction materials investigated had no effect on the turbidity of samples from the wells.     

A Dry Injection System for the Emplacement of Filter Packs and Annular Seals in Ground Water Monitoring Wells

The reliability of filter pack and annular seal emplacements, and the degree of integrity of installed seals, are two of the most important factors to be considered when both installing and later utilizing ground water monitoring wells.
Numerous, and often costly, problems of using existing methods of installing filter packs and annular seals during the construction of ground water monitoring wells have led to the development of a technique of installing these monitoring well components using a dry injection system.
The dry injection system has been used to construct monitoring wells in extremely complex overburden/bedrock environments with a variety of drilling techniques. The system has shown that a high degree of reliability in the, construction of monitoring wells and greater confidence in obtaining representative ground water samples can be achieved over existing methods of filter pack and annular seal emplacement. The system has also been more cost effective than existing methods, especially for deep boreholes and multilevel monitoring system installations.     

A New Rapid Method for Measuring the Vertical Head Profile

This study describes a new technique for measuring the head profile in a geologic formation. The technique provides rapid, low cost information on the depth of water‐producing zones and aquitards in heterogeneous aquifers, yielding estimates of hydraulic heads in each zone while identifying any potential for cross contamination between zones. The measurements can be performed in a typical borehole in just a few hours. The procedure uses both the continuous transmissivity profile obtained by the installation (eversion) of a flexible borehole liner into an open borehole and the subsequent removal (inversion) of the same liner from the borehole. The method is possible because of the continuous transmissivity profile (T profile described by Keller et al. 2014) obtained by measuring the rate of liner eversion under a constant driving head. The hydraulic heads of producing zones are measured using the reverse head profile (RHP) method (patent no. 9,008,971) based on a stepwise inversion of the borehole liner. As each interval of the borehole is uncovered by inversion of the liner, the head beneath the liner is allowed to equilibrate to a steady‐state value. The individual hydraulic heads contributing to each measurement are calculated using the measured transmissivity for each zone. Application of the RHP method to a sedimentary bedrock borehole in New Jersey verified that it reproduced the head distribution obtained the same day in the same borehole instrumented with a multilevel sampling system.     

The Application of Television Borehole Logging to Ground Water Monitoring Programs

Borehole television has been successfully utilized to gather in situ information on boreholes and wells in several ground water monitoring programs. Borehole television surveys are proposed as a viable alternative to other downhole instruments in the subsurface investigation stages of a ground water monitoring program.
The borehole television camera used by the authors was originally developed for use in the examination of nuclear reactor cores; the camera has since been modified for use in borehole investigations. The lens attachments are capable of looking sideward or downward and include built-in lighting assemblies. Use of the camera, lenses and various support equipment are discussed.
The in situ characterization of fractures that can provide pathways for contaminant migration poses a significant challenge. Borehole television inspection can provide information on the frequency, size and orientation of these fractures. Vertical correlations of rock cores in areas where voids are present (i.e. deep mining or karst topography) can also be simplified by this technique. In addition, borehole television can also be used to check monitoring well integrity. Casing inspections are especially useful where construction details are not known. Well screens may be inspected in place to determine if rusting has enlarged the screen openings or if screens have been damaged during emplacement or well development operations (i.e. surge block, air jetting, etc.). This information may prove to be very valuable in the decision to decommission a well. Examples of these successful applications in ground water monitoring programs at several Superfund hazardous waste sites are presented.     

New Method for Continuous Transmissivity Profiling in Fractured Rock

A new method is presented to search for hydraulically transmissive features in open boreholes in bedrock. A flexible borehole liner made of a watertight, nylon fabric is filled with water to create a constant driving head to evert (reverse of invert) the liner down the hole so that the liner pushes the borehole water out into transmissive fractures or other permeable features. The descent rate is governed by the bulk transmissivity of the remaining permeable features below the liner. Initially, the liner descent rate or velocity is a measure of transmissivity (T) of the entire hole. As the everting liner passes and seals each permeable feature, changes in the liner velocity indicate the position of each feature and an estimate of T using the Thiem equation for steady radial flow. This method has been performed in boreholes with diameters ranging from 96 to 330 mm. Profiling commonly takes a few hours in holes 200‐ to 300‐m long. After arrival of the liner at the bottom of the hole, the liner acts as a seal preventing borehole cross connection between transmissive features at different depths. Liner removal allows the hole to be used for other purposes. The T values determined using this method in a dolostone aquifer were found to be similar to the values from injection tests using conventional straddle packers. This method is not a replacement for straddle‐packer hydraulic testing of specific zones where greater accuracy is desired; however, it is effective and efficient for scanning entire holes for transmissive features.     

多点渗漏垃圾填埋场三维电学检测能力及影响因素分析

通过理论分析与原位实验,研究三维电学监测系统对垃圾填埋场多渗漏点位置的检测能力,分析影响检测效果的主要因素,以为设计经济、合理、有效的实时监测系统提供依据。结果表明：膜下电位监测法具有清晰的理论基础;供电电流强弱只影响测量电位值大小,不改变其异常形态,供电强度应以保证测量电位具有较高信噪比为原则;电极系极距大小会影响对相邻漏洞的检测能力,当极距小于相邻漏洞间距时,系统可对漏点位置进行有效反映;供电电极A在填埋场顶层中部布设、B极在膜下多点相连布设的布极方式,有利于漏点检测;漏洞越大,相应位置的测量电位值越高;划痕状漏洞不易被测出。利用膜下电极系测量的电阻率剖面对漏点具有较好的反映能力,并可实现渗滤液在地下扩散过程的监测。     

A Systematic Approach to Designing a Multiphase Unsaturated Zone Monitoring Network

A systematic approach is presented for the design of a multiphase vadose zone monitoring system recognizing that, as in ground water monitoring system design, complete subsurface coverage is not practical. The approach includes identification and prioritization of vulnerable areas: select ion of cost-effective indirect monitoring methods that will provide early warning of contaminant migration: selection of direct monitoring methods for diagnostic confirmation; identification of background monitoring locations; and identification of an appropriate temporal monitoring plan. An example of a monitoring system designed for a solid waste landfill is presented and utilized to illustrate the approach and provide details of system implementation. The example design described incorporates the use of neutron moisture probes deployed in both vertical and horizontal access tubes beneath the lcachate recovery collection system of the landfill. Early warning of gaseous phase contaminant migration is monitored utilizing whole-air active soil gas sampling points deployed in gravel- filled trenches beneath the subgrade. Diagnostic confirmation of contaminant migration is provided utilizing pore- liquid samplers. Conservative tracers can be used to distinguish between chemical species released by a landfill from those attributable to other (e.g. off-site) sources or present naturally in the subsurface. A discussion of background monitoring point location is also presented.     

Strain and tilt changes measured during a water injection experiment at the Nojima Fault zone, Japan

Abstract In order to make geophysical and geological investigations of the Nojima Fault on Awaji Island, Japan, three boreholes measuring 1800 m, 800 m and 500 m deep were drilled into the fault zone. The fault is one of the seismic source faults of the 1995 Hyogo-ken Nanbu earthquake of M 7.2. A new multicomponent borehole instrument was installed at the bottom of the 800 m borehole and continuous observations of crustal strain and tilt have been made using this instrument since May 1996. A high-pressure water injection experiment within the 1800 m borehole was done in February and March 1997 to study the geophysical response, behavior, permeability, and other aspects of the fault zone. The injection site was located approximately 140 m horizontally and 800 m vertically from the instrument. Associated with the water injection, contraction of approximately 0.7 × 10⁻⁷ str (almost parallel to the fault) and tilt of approximately 1 × 10^-7 rad in the sense of upheaval toward the injection site were observed. In addition to these controlled experiments, the strainmeter and tiltmeter also recorded daily variations. We interpret strain and tilt changes to be related to groundwater discharge and increased ultra-micro seismicity induced by the injected water.     

The Effect of Three Drilling Fluids on Ground Water Sample Chemistry

Three monitoring wells were installed in borings that were constructed using water-based drilling fluids containing either (1) guar bean, (2) guar bean with breakdown additive, or (3) bentonite. These fluids were selected to observe their effect on the chemistry of subsequent water samples collected from the wells. The wells were installed to depths of 66 feet, 100.5 feet and 103 feet, respectively, in fine-to-medium sand and gravel outwash deposits near Antigo, Wisconsin. Drilling fluids were necessary to maintain an open borehole during well construction through strata containing cobbles and boulders.
The bentonite and guar drilling fluids caused temporarily elevated concentrations of chemical oxygen demand (COD) in ground water samples collected from the monitoring wells. Using standard development, purging and sampling procedures, elevated COD concentrations persisted for about 50 days for the well bored with the guar-with-additive fluid, 140 days for the bentonite well and 320 days for the guar well. Unfiltered ground water samples for all wells had greater concentrations of COD than samples filtered through a 0.45 micron filter. Sulfate concentrations also decreased with time in the guar-with-additive well and bentonite well, but not in the guar well.
The elevated COD concentrations are attributed to the large concentrations of oxidizable carbon present in the guar bean drilling fluid and in the organic polymers present in the bentonite drilling fluid. Well development and purging procedures, including borehole flushing, surging, bailing and/or chemically induced viscosity breakdown of the guar mud decreased the time before background conditions were achieved. Future research should evaluate the physical and geochemical interaction of different drilling fluid compositions with a variety of geologic matrices and drilling, well development and well purging techniques.     

Estimation of Leakage Rates Through Flexible Membrane Liners

Leakage rate calculations for both low- permeability soil liners and composite liners using flexible membrane liners (FMLs) overlying low-permeability soil are developed. Latin-Hypercube simulations with uncertainly assigned to the soil liner hydraulic conductivity value and the spatial frequency of FML holes are used to examine the variability in the liner leakage rates. The low-permeability soil hydraulic conductivity is the parameter with the greatest effect on landfill liner leakages rates. Composite liners have a significant impact on reducing leakage rates through the landfill liner.     

A New System for Ground Water Monitoring

This paper describes a new system for ground water monitoring, "the BAT System," which includes the following functions: (a) sampling of ground water in most types of soils, (b) measurement of pore water pressure, and (c) in situ measurement of hydraulic conductivity. The system can also be used for tracer tests. The system utilizes a permanently installed filter tip attached to a steel or PVC pipe. Installation is normally performed by pushing the tip down to the desired depth. The filter tip can also be buried beneath a landfill. The primary feature of the new system is that the filter tip contains a self-sealing quick coupling unit, which makes it possible to temporarily connect the filter tip to adapters for various functions, e.g. water sampling and for measurement of pore pressure and hydraulic conductivity. The new technique makes sampling of both pressurized water and gas possible. Samples are obtained directly in hermetically sealed, pre-sterilized sample cylinders. Sampling of ground water and measurement of pore pressure can be repeated over a long period of time with undiminished accuracy. This technique is also well-adapted for taking water samples from different strata in a soil profile, in both the saturated and unsaturated zones. Actual installations range from 0.5 to 60m depth.     

Drilling and Constructing Monitoring Wells with Hollow-Stem Augers Part 2: Monitoring Well Installation

The procedures used to construct monitoring wells with hollow-stem augers may vary depending on the hydrogeologic conditions at the site. In cohesive materials in which the borehole stands open, the auger column may be fully retracted from the borehole prior to the construction of the monitoring well. In non-cohesive materials in which the borehole will not stand open, the monitoring well may be constructed through the hollow axis of the auger column.
The techniques used to construct monitoring wells through the hollow axis of the auger column may vary depending on the specific site conditions and the experience of the driller. Selection of an appropriately sized diameter hollow-stem auger for the installation of the required size of well casing is necessary to permit an adequate working space between the casing and augers, through which filter pack and annular seal materials are emplaced. Assurance that the filter pack and annular seal are properly emplaced is typically limited to careful measurements taken and recorded during construction of the monitoring well.     

垃圾填埋场地下环境污染检测方法技术研究

本文应用电阻率成像观测方法对北京通州某垃圾填埋场开展了面积性测量,应用模糊数学隶属函数的理论给出了分辨地下污染状况的量化指标,并对填埋场地下环境污染状况进行了分区.钻孔资料表明,分区结果真实地反映了填埋场地下环境污染的分布状况.     

Utilization of Shallow Geophysical Sensing at Two Abandoned Municipal/Industrial Waste Landfills on the Missouri River Floodplain

In the past 30 to 40 years, floodplain areas of large rivers, such as the Missouri River, have been extensively used for large industrial and municipal landfills. Many of these sites are now causing varying degrees of ground water contamination. Rapid geophysical characterization techniques have proven useful for delineation of anomalous areas indicative of potential contaminant plumes. These methods have also resulted in a cost effective approach to the location and number of monitoring wells.
An effective technique to initially characterize ground water contamination at such landfills along the Missouri River in northwestern Missouri involved a combination of electrical resistivity and electromagnetic conductivity methods. Resistivity was used to obtain soundings of the alluvium by using a modified Wenner array and to corroborate shallow electromagnetic conductivity measurements by using short Wenner array electrode spacings.
Upon confirmation of similar measurements of the upper soils for the two methods, numerous electromagnetic conductivity traverses were made at each landfill site. The data generated from these surveys were graphed and contoured to delineate anomalous areas. Based on the geophysical study, a ground water monitoring well network was then designed for each landfill.
As a result, a minimal number of wells were required to initially characterize the ground water quality at these two sites. In general, analysis of water samples from these wells displayed good correlation with the geophysical results.     

Elements in Cottonwood Trees as an Indicator of Ground Water Contaminated by Landfill Leachate

Ground water at the Norman Landfill Research Site is contaminated by a leachate plume emanating from a closed, unlined landfill formerly operated by the city of Norman, Oklahoma, Ground water contaminated by the leachate plume is known to be elevated in the concentration of many, organic and inorganic constituents. Specific conductance, alkalinity, chloride, dissolved organic carbon, boron, sodium, strontium, and deuterium in ground water are considered to be indicators of the leachate plume at this site.
Leaf samples of broad-leafed cottonwood, Populus deltoides , were collected from 57 sites around the closed landfill. Cottonwood, a phreatophyte or "well plant," functions as a & surrogate well and serves as a ground water quality sampler. The leaf samples were combusted to ash and analyzed by instrumental neutron activation for 35 elements and by prompt-gamma instrumental neutron activation, for boron. A monitoring well was located within a few meters of a sampled cottonwood tree at 15 of the 57 sites, and ground water samples were collected from these monitoring wells simultaneously with a leaf sample. The chemical analyses of the ground water and leaf samples from these 15 sites indicated that boron, bromine, sodium, and strontium concentrations in leaves were significantly correlated with leachate indicator constituents in ground water. A point-plot map of selected percentiles indicated high concentrations of boron, bromine, and sodium in leaf ash from sites downgradient of the most recent landfill and from older landfills nearby.
Data from leaf analysis greatly extended the known areal extent of the leachate plume previously determined from a network of monitoring wells and geophysical surveys. This phytosgeochemical study provided a cost-effective method for assessing the extent of a leachate plume from an old landfill. Such a method may be useful as a preliminary sampling tool to guide the design of hydrogeochemical and geophysical studies.     

Troubled waters: Environmental applications of electrical and electromagnetic methods

The relatively new subdiscipline of environmental geophysics has grown enormously in the last five years. The size and diversity of the field, and the associated literature, is such that it is extremely difficult to keep up with even a small portion of the field. Electrical and electromagnetic (E & EM) methods, including ground penetrating radar and time-domain reflectometry, play a central role in environmental geophysics. One reason for the utility of E & EM methods in groundwater studies is the similarity in the way that current flow and fluid flow depend on the connectivity and geometry of the pores in soils and rocks. Another reason is the influence of the pore water quality on the geophysical response. More than any other geophysical technique, E & EM methods are directly affected by the presence of conductive pore fluids in the subsurface, such as leachates from landfill sites and sea water invading a coastal groundwater supply that has been placed under stress because of population expansion. The chloride ion is one of the most electrically active of the naturally-occurring ions, and allows us to detect sea water incursion; leachates from landfill sites contain the by-products of organic decay, such as acetic acid, which are generally less conductive than chloride, but nonetheless enhance the pore water and formation electrical conductivities. Landfill leachate plumes are thus easily mapped. The shallow subsurface electrical and dielectric properties exhibit hysteresis due to seasonal changes in water content; the physical properties will be different for the same degree of saturation, depending on whether the water level is rising or falling. Topographic effects are also important; an empirical correction method works well to remove a background trend in the conductivity due to changes in elevation. Heterogeneity and anisotropy of the electric properties may be related to similar effects in the hydraulic properties. New technology and the adaptation of existing technology has lead to the development of fresh instruments, such as electrode arrays towed across the ground, resistivity logging while drilling, fast-rise time TEM, NMR combined with TEM, electric quadripole, et cetera. The applications of E & EM methods cover a wide range of geographic areas and groundwater problems, but have had particularly wide use for groundwater exploration in arid and semi-arid regions, for mapping and monitoring salt-water incursion in susceptible aquifers, and for mapping and monitoring contaminants.