水稻土有机碳密度的空间预测分析——以浙江省长兴县为例

准确预测未采样区域SOC密度,是研究SOC演变趋势和探索土壤固碳作用对缓解全球气候变化的基础。采用泛克里格法(Universal Kriging,UK)和土壤类型法(pedological professional knowledge-based method,PKB),分别对长兴县水稻土有机碳密度进行了预测,其中,UK直接以长兴水稻土剖面资料为源数据、PKB以长兴水稻土剖面数据和长兴1∶5万数字土壤图为源数据进行预测。根据平均绝对误差(MAE)及均方根误差(RMSE)大小,评价了两种方法在县域尺度土壤有机碳密度空间预测效果。结果表明:UK的MAE(31.2)、RMSE(52.5)均大于PKB的MAE(24.7)、RMSE(43.1),说明PKB法的预测效果较好,UK法相对较差。研究表明,对土壤类型、土壤母质,以及剖面点位置等信息的综合考虑能使PKB法更好地表达土壤属性的空间特征,也更适于县域尺度土壤有机碳密度的空间预测。     

贵州省湿地碳储量与碳中和潜力分析

湿地作为缓解气候变化的关键生态系统, 在碳捕获与碳封存方面发挥着不可替代的作用。湿地碳储量和影响因素的分析以及固碳潜力的预测, 对湿地生态保护与管理、国家"双碳"目标实现具有重要意义。应用ArcGIS10.8对《贵州省湿地保护发展规划》(以下简称规划)的3个时期(分别是: 1999-2009年; 2010-2018年; 2018年至今)湿地分布图采用遥感目视解译的方式进行矢量化并根据贵州省岩溶发育强度进行分区。采用生命带研究法与生物量估算法等对贵州省湿地面积和碳储量变化进行估算分析, 对重要湿地碳储量与单位面积碳储量进行估算并与全省湿地进行对比, 采用固碳潜力计算模型对贵州省重要湿地固碳潜力进行估算, 应用Origin软件对各相关影响因子进行数据分析。结果表明: ①贵州省湿地规划前期的面积为216 526.95 hm2, 规划中期面积为209 726.85 hm2、规划后期面积为255 440.53 hm2, 总体表现为先下降再升高, 总体面积增加38 913.58 hm2; ②贵州省湿地碳储量变化为: 规划前期为5.97×105 t, 规划后期为3.78×106 t, 是规划前期的6倍以上, 碳储量增加明显。其中, 贵州省重要湿地碳储量为3.24×106 t, 占全省湿地碳储量85.71%, 固碳潜力十分显著; ③贵州省重要湿地的固碳潜力为1.14×104 t C/a, 预计到2030和2060年, 湿地总固碳量分别达到7.99×106 t C和8.34×106 t C; ④温度、DIC浓度、有机碳含量与面积对贵州省重要湿地的碳储量影响较大, 重要湿地碳储量与DIC浓度、有机碳含量以及面积呈正相关, 而与温度呈负相关关系。对贵州省的湿地碳储量估算与碳中和潜力分析不仅可以了解贵州省湿地碳封存现状, 还可为区域湿地生态系统在"3060"双碳目标的贡献上提供理论参考。      

山东省上古生界页岩气资源潜力评价

以山东省上古生界海陆过渡相富有机质泥页岩为研究对象,对泥页岩的沉积环境、厚度及分布、有机质类型及含量、有机质演化程度等资料进行分析,认为石炭-二叠纪山西组和太原组泥页岩发育厚度大而稳定,有机质类型以Ⅲ型为主,镜质体反射率一般在0.7%~1.7%之间,有机碳含量一般在1.5%~9.0%之间,是页岩气主要富集层位。以含气量不小于0.5m3/t、镜质体反射率不小于0.5%、有机碳含量平均不小于2.0%等为资源量评价标准,建立有机碳含量与含气量关系模型,估算山东省上古生界页岩气潜在地质资源总量为5 736.75×108 m~3,明确了具有勘查价值的区域有鲁西南含煤区、黄河北含煤区、阳谷-茌平含煤区和临清坳陷,为山东省上古生界页岩气下一步勘查指明了方向。     

土地利用变化对吴江市水田土壤有机碳储量的影响分析

 农业表层土壤碳库容易受人为强烈干扰,而又可以在较短的时间尺度上进行调节,当今我国经济发达地区土地利用变化必然会对土壤固碳产生重要影响。本研究以江苏省吴江市水稻土为例,利用新一代中分辨率成像光谱仪(MODIS)和TM/ETM影像提取了1984年稻田面积,以及这部分稻田在2000-2005年的土地利用变化状况。研究中以最大似然法对TM/ETM、MODIS影像应用归一化植被指数(NDVI)、增强型植被指数(EVI)和陆地水分指数(LSWI)掩膜的方法作了识别提取;同时,结合第二次全国土壤普查、2003年耕地地力调查点和吴江市农林局土肥指导站长期定位点的土壤有机碳数据估算了1984年和2000-2005年土壤碳库变化情况。结果表明:近20多年来尽管吴江市水稻土水耕熟化过程中有机碳总体呈增加的趋势,但由于大量稻田被非农用地所取代,导致土壤固碳能力大幅度下降,尤其从2001年开始从"碳汇"变成"碳源"。因此,在我国经济发达区应密切关注耕地转换成非农用地而导致的土壤有机碳的损失。     

准噶尔盆地南缘芦草沟组上段油页岩有机地球化学特征及其沉积意义

为分析准南天山山前冲断带东南侧芦草沟组上段油页岩资源潜力、沉积时的古环境特征及其垂向演化规律,并预测优质油页岩发育层位,研究采用有机地球化学方法,对准页３井油页岩进行了 TOC测试、抽提、族组分分析和气相色谱－质谱(GCＧMS)分析.分析结果表明:油页岩样品 w(TOC)平均为３．２６％,最大值为６．３０％,最小值为０．８２％.可溶有机质质量分数平均为０．２１％,最大值为０．６５％,最小值为０．０１％.总烃(HC)质量分数平
均为１１２０．５８×１０－６,最大值为３５６１．８４×１０－６,最小值为４２．９２×１０－６.油页岩有机质整体丰度较好,具有极好的生烃潜力,６５０~１１００m 层段为优质油页岩发育富集层.饱和烃质量分数平均为２４．０４％,最大值为６５．７３％,最小值为３．０３％.芳烃质量分数平均为２３．８８％,最大值为３９．４６％,最小值为１１．２４％.胶质沥青质质量分数平均为５２．０８％,最大值７８．４５％,最小值２２．０６％.CPI 最小值１．１２,最大值４．１２;轻重比指数最小值０．７３,最大值１．４５;OEP 最小值０．９８,最大值１．１６.结合 C２７ααα２０R、C２８ααα２０R、C２９ααα２０R３个“生物构型甾烷”的相对含量说明,有机质类型以腐植－腐泥型为主,母质来源以藻类、浮游生物为主.Ro、Ts/Tm、C２９ββ/(C２９αα＋C２９ββ)与 C２９αααS/(S＋R)关系表明油页岩处于未成熟晚期－低成熟阶段.Pr、Ph和 C１７、C１８ 正构烷烃的相对含量表明油页岩上部和下部沉积古环境为较开阔的海相咸水还原环境,中部为封闭的湖相半咸水过渡环境.油页岩具有分段性特征,其石油地质与沉积环境特征各不相同,优质油页岩发育于第二层段,为勘探和开采最优层段.      

重庆黔江地区下寒武统牛蹄塘组页岩气成藏条件

下寒武统牛蹄塘组是重庆黔江地区继下志留统龙马溪组之后,最有望取得页岩气勘探突破的重点层系之一,但其页岩气勘探方向仍不明确。通过钻井岩心和野外露头剖面观察,采用显微薄片、扫描电镜、全矿物-黏土矿物X衍射、有机地球化学参数等多项实验测试方法,系统分析了区内牛蹄塘组沉积环境、富有机质页岩的分布与埋深及其有机地球化学指标、储集性特征、保存条件与含气性特征等页岩气成藏条件。研究表明区内牛蹄塘组处于浅水陆棚-深水陆棚过渡沉积环境,富有机质页岩分布于地层下部,沉积厚度40～80 m;有机碳质量分数介于2.0%～6.0%,热演化程度达过成熟阶段,有机质类型以Ⅰ型为主,生烃强度5×108～20×108 m3/km2,生烃潜力较大;脆性矿物含量较高,黏土矿物以伊利石和伊/蒙混层为主,页岩储层储集空间类型多样,具低孔-超低渗特征,具备了页岩气藏发育的良好地质条件。综合各种页岩气选区评价指标表明,黔江-濯水-酉阳以西、彭水以东、北抵郁山-黔江、南至洪渡-酉阳等区域的牛蹄塘组页岩气成藏条件优越,为区内页岩气勘探有利区带。      

横县岩溶区土壤硒地球化学特征及影响因素探讨

广西横县土壤硒(Se)元素含量分布特征显示,硒含量范围0.03~2.62mg/kg,背景值0.57mg/kg。研究区土壤硒含量空间上呈中东高西低,富硒土壤占74.1%,主要分布于泥盆系、石炭系及二叠系等浅海—滨海相沉积的碳酸盐岩成土母质区;足硒土壤占比24.5%,空间上与白垩系、古近系碎屑岩母质的分布相对应。硒与TFe2O3、Pb、Cr、Ni、Zn、有机碳及p H值等呈显著相关性(p0.01),表明土壤硒含量不仅受成土母岩的影响,还受铁锰氧化物、硫化物成矿元素、有机质及p H值的影响。     

赣南地区水稻-根系土系统中硒含量影响因素分析

硒是人体必需微量元素之一,而水稻作为我国第一大主粮,其硒含量的高低与人体健康关系密切,因此研究水稻-根系土体系中硒含量的影响因素,可为富硒地区水稻种植及开发富硒农业提供科学理论依据。以赣南为研究区,采集138组水稻籽实及配套根系土样品进行了测试分析,探究赣南地区土壤理化条件对硒在水稻及其根系土中的实际影响效应,对富硒水稻及土壤进行质量综合评价,并构建富硒水稻地球化学适生模型。结果表明:赣南地区水稻根系土Se平均质量分数为0.29mg/kg,Se水平主要为足硒水平,富硒土壤仅占14.5%;有效硒(Sebio)质量分数平均为46.0μg/kg,占总硒质量分数的16.44%;水稻的Se平均质量分数为0.05mg/kg,无重金属元素超标的安全富硒水稻率达到45%,富硒水稻对Cd,Zn,Cu的生物富集能力较强。相关分析表明,根系土中Se质量分数与TFe2O3,MnO,MgO,有机碳(Corg)质量分数呈极显著正相关,与主要重金属元素存在一定程度的伴生关系。水稻Se质量分数与根系土Se,Sebio,SiO2质量分数和pH值呈极显著正相关,与Al2O3,有机碳(Corg)质量分数呈极显著负相关。单项污染指数表明研究区根系土中重金属元素基本属于清洁和尚清洁水平,Cd,Pb,As,Hg,Cu存在一些样品超标,其中Cd超标率最高;内梅罗综合污染指数表征77.0%的样品属于安全等级;富硒土壤综合评估显示研究区主要为良级富硒土壤,优级富硒土壤仅占8.7%。通过最佳子集回归分析最终选取了根系土总Se、有机质、pH值为自变量构建富硒水稻地球化学适生模型,拟合的模型可以解释水稻中Se30.6%的变异。     

泥页岩储层测井沉积学分析——以泌阳凹陷泌页HF-1井核桃园组为例

【目的】以泌阳凹陷泌页HF-1井核桃园组页岩油储层为研究对象,分析泥页岩地层测井的沉积学。【方法】通过改进的Δlog R方法,建立适合研究区泥页岩有机质含量的测井计算公式;根据计算的有机质含量,结合矿物组分含量及自然伽马能谱测井特征,分析沉积环境变化。【结果与结论】利用测井资料计算泌阳凹陷泌页HF-1井核桃园组泥页岩地层中的TOC,取得较好的效果,计算公式可在本研究区其他未取岩心的井中推广应用。泌页HF-1井核桃园组2 390～2 465 m地层由底部到顶部其沉积环境变化:湿润多雨的气候条件下基本一直处于还原环境,但是随着湖水深度逐渐变浅以及陆源物质输入的增加,地层中有机碳含量逐渐减少;其中2 432～2 461 m地层为深水还原环境,陆源物质输入较少,有利于有机质的堆积和保存,是最有利的页岩油储层赋存潜力段。     

章丘地区土壤硒的含量分布及影响因素

以章丘地区土壤为对象,系统分析了表层、深层土壤及8条剖面土壤中Se元素的含量水平,研究了土壤中Se的分布特征及其与土壤类型、成土母质、地形地貌和土壤理化性质及组分的关系。结果表明：章丘地区表层土壤中Se含量在0.1～0.8mg/kg之间,以中硒土壤为主,富硒土壤面积173km2。土壤类型中,水稻土Se平均含量水平最高,为0.55mg/kg;成土母质中以石炭—二叠纪泥页岩发育的土壤Se含量最高;剖面土壤中的Se主要在表层富集。影响章丘地区土壤Se含量分布的主要因素是成土母质、地形地貌、土壤pH、有机质及土壤中硫、铁铝氧化物等组分。     

Storage and density of soil organic carbon in urban topsoil of hilly cities: A case study of Chongqing Municipality of China

Rapid urbanization results in the conversion of natural soil to urban soil,and consequently,the storage and density of the soil carbon pools change.Taking Chongqing Municipality of China as a study case,this investigation attempts to better understand soil carbon pools in hilly cities.First,the vegetated areas in the study area were derived from QuickBird images.Then,topsoil data from 220 soil samples(0-20 cm) in the vegetated areas were collected and their soil organic carbon(SOC) densities were analyzed.Using the Kriging interpolation method,the spatial pattern of SOC was estimated.The results show that the SOC density exhibited high spatial variability in the urban topsoil of Chongqing.First,the SOC density in topsoil decreased according to slope in the order 2°-6° < 25°-90° < 0°-2° < 6°-15° < 15°-25°.Second,the newly developed areas during 2001-2010 had a lower SOC density than the areas built before 1988.Third,urban parks and gardens had a higher SOC density in topsoil,residential green land followed,and scattered street green land ranked last.For hilly cities,the variability of terrain affects the distribution of SOC.The Kriging results indicate that Kriging method combining slope with SOC density produced a high level of accuracy.The Kriging results show that the SOC density to the north of the Jialing River was higher than the south.The vegetated areas were estimated to amount to 73.5 km2 across the study area with an SOC storage of 0.192 Tg and an average density of 2.61 kg/m2.     

Estimation of storage and density of organic carbon in peatlands of China

Based on the results of the National Survey of Peat Resources(1983-1985) and the investigation results on the peatlands of China,the storage and density of the organic carbon in the peatlands of China were estimated.The total organic carbon storage(OCS) of the peatlands in China,including bare peatlands and buried peatlands,are 1.503 × 109 t,unevenly distributed over 30 provincial level administrative units and 16 climatic zones.Peatland organic carbon storage(POCS) in Sichuan(6.45 × 108 t) and Yunnan provinces(2.91 × 108 t) is the highest,accounting for 62.29% of the total POCS.Humid zone of plateau has the highest POCS of 7.14 × 108 t,especially in the Zoigê Plateau,where the POCS is 6.30 × 108 t,accounting for 41.92% of the total POCS of China.The organic carbon density(OCD) of the peatlands in China mostly ranges from 80 kg/m3 to 140 kg/m3,and the range of the maximum is 270-360 kg/m3,and the minimum is less than 80 kg/m3.Divided by the Yanshan Mountain,Taihang Mountains and Hengduan Mountains,the peatland oganic carbon density(POCD) is lower on the northwestern side than that on the southeastern side.Jiangxi Province has the highest POCD due to the ancient buried peatlands.The OCD of the bare peatlands is mostly in the range of 60-150 kg/m3,and that of the buried peatlands is more than 100 kg/m3.In the bare peatlands,the OCD generally increases from the surface layer to the below surface layer,and then decreases with the depth.Although the peatlands area in China is small,the OCS per unit area is far higher than the other soil types,so peatlands protection can effectively mitigate climate change.     

Effects of land cover on soil organic carbon stock in a karst landscape with discontinuous soil distribution

Land cover type is critical for soil organic carbon(SOC) stocks in territorial ecosystems. However, impacts of land cover on SOC stocks in a karst landscape are not fully understood due to discontinuous soil distribution. In this study, considering soil distribution, SOC content and density were investigated along positive successional stages(cropland, plantation, grassland, scrubland, secondary forest, and primary forest) to determine the effects of land cover type on SOC stocks in a subtropical karst area. The proportion of continuous soil on the ground surface under different land cover types ranged between 0.0% and 79.8%. As land cover types changed across the positive successional stages, SOC content in both the 0–20 cm and 20–50 cm soil layers increased significantly. SOC density(SOCD) within 0–100 cm soil depth ranged from 1.45 to 8.72 kg m-2, and increased from secondary forest to primary forest, plantation, grassland, scrubland, and cropland, due to discontinuous soil distribution. Discontinuous soil distribution had a negative effect on SOC stocks, highlighting the necessity for accurate determination of soil distribution in karst areas. Generally, ecological restoration had positive impacts on SOC accumulation in karst areas, but this is a slow process. In the short term, the conversion of croplandto grassland was found to be the most efficient way for SOC sequestration.     

Comparison on soil carbon stocks between urban and suburban topsoil in Beijing,China

The urban population and urbanized land in China have both increased markedly since the 1980s. Urban and suburban developments have grown at unprecedented rates with unknown consequences for ecosystem functions. In particular, the effect of rapid urbanization on the storage of soil carbon has not been studied extensively. In this study, we compared the soil carbon stocks of different land use types in Beijing Municipality. We collected 490 top-soil samples （top 20 cm） from urban and suburban sites within the Sixth Ring Road of Beijing, which cover approximately 2400 km2, and the densities of soil organic carbon （SOC）, soil inorganic carbon （SIC）, and total carbon （TC） were analyzed to determine the spatial distribution of urban and suburban soil carbon characteristics across seven land use types. The results revealed significant differences in soil carbon densities among land use types. Additionally, urban soil had significantly higher SOC and SIC densities than suburban soil did, and suburban shelterbelts and productive plantations had lower SIC densities than the other land use types. The comparison of coefficients of variance （CVs） showed that carbon content of urban topsoil had a lower variability than that of suburban topsoil. Further findings revealed that soil carbon storage increased with built-up age. Ur- ban soil built up for more than 20 years had higher densities of SOC, SIC and TC than both urban soil with less than 10 years and sub- urban soil. Correlation analyses indicated the existence of a significantly negative correlation between the SOC, SIC, and TC densities of urban soil and the distance to the urban core, and the distance variable alone explained 23.3% of the variation of SIC density and 13.8% of the variation of TC density. These results indicate that SOC and SIC accumulate in the urban topsoil under green space as a result of the conversion of agricultural land to urban land due to the urbanization in Beijing.     

BACKGROUND VALUES AND TREND DISTRIBUTION OF Cu, Zn AND Ni IN SOILS IN CHINA

The background values of Cu, Zn and Ni are discussed based on the analytical data of 21 main soil types collected from various regions in China. According to statistics of many samples, the background value of Cu is 23.4±10.2 mg/ kg (482 samples), Zn 77.9±2.39 mg/ kg (474 samples), Ni 30.0±12.8 mg/kg (482 samples).     

Spatiotemporal variation of soil organic carbon in the cultivated soil layer of dry land in the South-Western Yunnan Plateau,China

The dynamics of soil organic carbon(SOC)in cropland is one of the central issues related to both soil fertility and environmental safety. However, little information is available at county level regarding the spatiotemporal variability of SOC in the southwestern mountainous region of China. Thus, this study aimed to explore spatiotemporal changes of SOC in the cultivated soil layer of dry land in Mojiang County,Yunnan Province, China. Data were obtained from the second national soil survey(SNSS) of 1985 and soil tests for fertilizer application carried out by the Mojiang Agricultural Bureau in 2006. The ANOVA test was applied to determine any significant differences between the datasets, while semivariogram analysis was performed on geostatistics via an ordinary Kriging method in order to map spatial patterns of soil organic carbon density(SOCD). The results revealed that SOCD in the cultivated soil layer significantly decreased from 3.93 kg m~(-2) in 1985 to 2.89 kg m~(-2) in 2006, with a total soil organic carbon stock(SOCS) decrease of 41.54×10~4 t over the same period. SOCS levels fell most markedly in yellow-brown soil at a rate of51.52%, while an increase of 8.70% was found in the analysed latosol. Geostatistical analysis also showed that the recorded changes in SOCD between 1985 and2006 were spatially structured. The decreasing trend might be attributed to the combined action of intense cultivation, major crop residue removal without any protective tillage measures, unreasonable fertilization and natural climatic diversity inducing a large decrease in SOC in the studied cultivated dry land region of Mojiang County. Therefore, management measures such as protective tillage should be undertaken in order to enhance soil C sequestration.     

Carbon storage and vertical distribution in three shrubland communities in Gurbantünggüt Desert, Uygur Autonomous Region of Xinjiang, Northwest China

This study was carried out in the Gurbantünggüt Desert,Uygur Autonomous Region of Xinjiang,Northwest China in August,2009.To quantify the storage,contribution and vertical distribution patterns of plant biomass carbon (PBC)and soil organic carbon(SOC)in the study area,we investigated the carbon concentrations and its vertical distribution in three different desert shrubland communities dominated by Reaumuria soongorica,Haloxylon ammodendron+R.soongorica and Tamarix ramosissima+R.soongorica,respectively.We analyzed vertical distribution of root biomass carbon and soil carbon contents by excavating soil profiles for each dominated community.The results show that SOC is considerably the larger carbon pool in the soil layers of 1.0-3.0 m(the mean value of three shrubland communities is 38.46%)and 3.0-5.0 m(the mean value is 40.24%).In contrast,70.74%of belowground biomass carbon storage in 0-1.0 m layer,and its content decrease with increasing soil depth.The Haloxylon ammodendron+R. soongorica shrubland community has the highest belowground biomass carbon among three selected communities. This study highlights the importance of SOC stored in deep soil layers(lower than 3.0 m from the surface)in arid shrubland communities in the global carbon balance.In addition,it provides the data support for revealing deep soil solid carbon potential,and offers scientific basis for the further research in the carbon cycle of terrestrial ecosystem.     

SPATIAL AND TEMPORAL DYNAMICS OF SOIL ORGANIC CARBON IN RESERVED DESERTIFICATION AREA——A Case Study in Yulin City, Shaanxi Province, China

1INTRODUCTIONDesertification is one of the most serious land degrada-tion, which results in the deterioration of physical, che-mical, and biological characteristics of soils (UNEP, 1992). Soil organic carbon (SOC) was considered to be a key index in evaluation of soil quality, soil degradation and soil C sequestration(SCHLENGSINGER etal., 1990; FENG etal., 2002; WANG etal., 2003). Many researchers have reported the correlations among desertification restoration, soil C s…     

Assessment of soil organic carbon stock in the upper Yangtze River basin

Soil organic carbon is of great importance to terrestrial ecosystems.Studies on the amount and spatial distribution of soil organic carbon stock in various types of soil can help to better understand the role of soil in the global carbon cycle and provide a scientific basis for the assessment of the magnitude of carbon stored in a given area.Here we present estimates of soil organic carbon stock in soils in the upper reaches of the Yangtze River based on soil types as defined by Chinese Soil Taxonomy and recently compiled into a digital soil database.The results showed that the total soil organic carbon stock of the upper Yangtze River to a depth of 100 cm was 1.452×1013kg.The highest soil organic carbon stock was found in felty soils(2.419×1012kg),followed by dark brown soils(1.269×1012kg),and dark felty soils(1.139×1012kg).Chernozems and irrigation silting soils showed the lowest soil organic carbon stock,mainly due to the small total area of such soils.The soil organic carbon density of these major soil types ranged from 5.6 to 26.1 kg m-2.The average soil organic carbon density of the upper reaches of the Yangtze River was 16.4 kg m-2,which was higher than that of the national average.Soil organic carbon density indicated a distinct decreasing trend from west to east,which corresponds to the pattern of increasing temperature from cold to subtropical.