The origin of Samoa: new evidence from Sr, Nd, and Pb isotopes

We report Sr, Nd and Pb isotope ratios and parent and daughter element concentrations in 34 volcanic rocks from Samoa. The highly undersaturated post-erosional volcanics, which have erupted in Recent to Historic time along a 250-km-long fissure, have isotopic compositions that define fields distinct from those of the tholeiitic to alkalic lavas of the older Samoan shield volcanoes. Most shield lavas have²⁰⁶Pb/²⁰⁴Pb of 18.9–19.4,⁸⁷Sr/⁸⁶Sr of 0.7045–0.7055 and⁸⁷Sr/⁸⁶Sr (to 0.7075). In general, isotopic compositions of the shield lavas are similar to those of the Marquesas and Society Islands. Post-erosional samples have lower²⁰⁶Pb/²⁰⁴Pb and¹⁴³Nd/¹⁴⁴Nd and higher⁸⁷Sr/⁸⁶Sr than most shield lavas. The most striking feature of the post-erosional data is a negative correlation between²⁰⁷Pb/²⁰⁴Pb and²⁰⁶Pb/²⁰⁴Pb. This suggests that post-erosional lavas are derived from mixtures of the shield source and a high-²⁰⁷Pb/²⁰⁴Pb,⁸⁷Sr/⁸⁶Sr, low-²⁰⁶Pb/²⁰⁴Pb and¹⁴³Nd/¹⁴⁴Nd post-erosional source which may contain recycled ancient sediment. This enriched mantle domain may also underlie the Ontong-Java and Manihiki Plateaus to the north and west. Although both the Samoan shield and post-erosional lavas show chemical characteristics often associated with mantle plumes, only the shield volcanism can plausibly be related to a plume. The post-erosional eruptions appear to be the result of flexure and rifting due to plate bending at the northern termination of the Tonga Trench.     

Identification of recycled continental material in the mantle from Sr,Nd and Pb isotope investigations

Pb, Nd and Sr isotope compositions of oceanic basalts have been used to identify recycled components of continent derivation in the mantle. The isotopic compositions of Sr, Nd and Pb, together with U, Pb, Sm, Nd, Rb, and Sr abundances have been determined for back-arc basalt glasses from the Scotia Sea and Parece Vela and West Philippine Basins, in addition to basalts from South Sandwich Islands, Ascension, St. Helena and Tristan da Cunha. Comparisons made between the isotopic compositions of South Sandwich Islands basalts and Atlantic MORB glasses permit the identification of recycled components of continent derivation in the source of the island arc basalts. Recycled Sr of continent derivation is also recognisable in back-arc basalt glasses from the Scotia Sea and Parece Vela and West Philippine Basins. However, contemporary reinjection of material with the isotopic structures similar to those identified as a component of island arc and back-arc regions cannot be the sole or dominant influence on the fine structure observed in MORB glasses from the Atlantic Ocean, nor the isotopic compositions of Tristan da Cunha, St. Helena and Ascension basalts. Recycled materials are likely to have been responsible for the generation of these heterogeneities only if they have been stored in the mantle for periods of time exceeding 10⁹ years.     

Interpretation of Nd,Sr and Pb isotope data from Archean migmatites in Lofoten-Vesterålen,Norway

Sm-Nd data for the Archean granulite and amphibolite facies migmatites of Langøy and Hinnøy in Vesterålen are presented which indicate that their protoliths formed ～2.6 AE ago. Rubidium and U loss during a granulite facies metamorphism at ～1.8 AE caused serious disturbance of total-rock U-Pb and Rb-Sr systems. Therefore these systems do not provide any precise age information for the granulite facies migmatites. For the amphibolite facies migmatites of Vesterålen both SmNd, RbSr and PbPb total-rock systems give model ages of ～2.6 AE. The results on both granulite and amphibolite facies rocks are thus in agreement. Previous interpretations based on PbPb data, which indicated an age of 3.41 AE for the Archean terrane of Vesterålen, are not valid.One SmNd model age from the granulite facies migmatites at Moskenesøy in Lofoten indicates that the protoliths of these migmatites formed ～2.0 AE ago and are thus not related to the Vesterålen migmatites.     

Correlated Nd,Sr and Pb isotope variation in Walvis Ridge basalts and implications for the evolution of their mantle source

Basement intersected in DSDP holes 525A, 528 and 527 on the Walvis Ridge consists of submarine basalt flows and pillows with minor intercalated sediments. These holes are situated on the crest and mid and lower northwest flank of a NNW-SSE-trending ridge block which would have closely paralleled the paleo mid-ocean ridge [13, 14]. The basalts were erupted approximately 70 m.y. ago, an age equivalent to that of immediately adjacent oceanic crust in the Angola Basin and consistent with formation at the paleo mid-ocean ridge [14]. The basalt types vary from aphyric quartz tholeiites on the ridge crest to highly plagioclase phyric olivine tholeiites on the ridge flank. These show systematic differences in incompatible trace element and isotopic composition. Many element and isotope ratio pairs form systematic trends with the ridge crest basalts at one end and the highly phyric ridge flank basalts at the other.The low ¹⁴³Nd/¹⁴⁴Nd (0.51238), ²⁰⁶Pb/²⁰⁴Pb (17.54), ²⁰⁸Pb/²⁰⁴Pb (15.47), ²⁰⁸Pb/²⁰⁴Pb (38.14) and high⁸⁷Sr/⁸⁶Sr (0.70512) ratios of the ridge crest basalts suggest derivation from an old Nd/Sm-, Rb/Sr- and Pb/U-enriched mantle source. This isotopic signature is similar to that of alkaline basalts on Tristan de Cunha but offset to significantly lower Nd and Pb isotopic ratios. The isotopic ratio trends may be extrapolated beyond the ridge flank basalts with higher¹⁴³Nd/¹⁴⁴Nd (0.51270), ²⁰⁶Pb/²⁰⁴Pb (18.32), ²⁰⁷Pb/²⁰⁴Pb (15.52), ²⁰⁸Pb/²⁰⁴Pb (38.77) and lower ⁸⁷Sr/⁸⁶Sr (0.70417) ratios in the direction of increasingly Nd/Sm-, Rb/Sr- and Pb/U-depleted source compositions. These isotopic correlations are equally consistent with mixing od depleted and enriched end member melts or partial melting of an inhomogenous, variably enriched mantle source. However, observe ZrBaNbY interelement relationships are inconsistent with any simple two-component model of magma mixing, as might result from the rise of a lower mantle plume through the upper mantle. Incompatible element and Pb isotopic systematics also preclude extensive involvement of depleted (N-type) MORB material or its mantle sources. In our preferred petrogenetic model the Walvis Ridge basalts were derived by partial melting of mantle similar to an enriched (E-type) MORB source which had become heterogeneous on a small scale due to the introduction of small-volume melts and metasomatic fluids.     

Some Pb and Sr isotopic measurements on eclogites from the Roberts Victor mine,South Africa

Five nodules of eclogite, one nodule of garnet peridotite and one sample of kimberlite from the Roberts Victor mine were analyzed for concentrations of U, Th, Pb, Rb and Sr and isotopic compositions of Pb and Sr. In the eclogites, U content ranges from 0.09 to 0.26 ppm, Th from 0.35 to 1.1 ppm, Pb from 0.79 to 5.5 ppm, Rb from 2.1 to 28 ppm and Sr from 133 to 346 ppm;²⁰⁶Pb/²⁰⁴Pb ratios range from 14.8 to 18.5,²⁰⁷Pb/²⁰⁴Pb from 14.9 to 15.7,²⁰⁸Pb/²⁰⁴Pb from 35.2 to 38.5. The garnet peridotite contains 0.22 ppm U, 0.97 ppm Th, 1.05 ppm Pb, 6.9 ppm Rb and 108 ppm Sr and the kimberlite contains 2.5 ppm U, 30 ppm Th, 37 ppm Pb, 113 ppm Rb and 2040 ppm Sr. The lead in the eclogites has two components, a lead pyroextractable at 1100–1200° and a non-pyroextractable residual lead. In three of the eclogites, which are to some extent altered, a proportion of the pyroextractable lead may be contaminating lead from the kimberlite, but an altered kyanite eclogite does not appear to be contaminated by this same kimberlite. The pyroextractable lead from a less altered eclogite contains a much larger proportion of²⁰⁶Pb. Compositions calculated for the residual leads vary greatly. In many of the pyroextraction runs the primary eclogitic phases disappeared and the new phases plagioclase, clinopyroxene and a magnetic iron compound were formed. Why part of the lead should have been retained by these new phases is not understood.     

Major element, trace element, and Sr, Nd and Pb isotope studies of Cenozoic basalts from the South China Sea

The whole rock K-Ar ages of basalts from the South China Sea basin vary from 3.8 to 7.9 Ma, which suggest that intra-plate volcanism after the cessation of spreading of the South China Sea (SCS) is comparable to that in adjacent regions around the SCS, i.e., Leiqiong Peninsula, northern margin of the SCS, Indochina block, and so on. Based on detailed petrographic studies, we selected many fresh ba-saltic rocks and measured their major element, trace element, and Sr-Nd-Pb isotope compositions. Geochemical characteristics of major element and trace element show that these basaltic rocks belong to alkali basalt magma series, and are similar to OIB-type basalt. The extent of partial melting of mantle rock in source region is very low, and magma may experience crystallization differentiation and cu-mulation during the ascent to or storing in the high-level magma chamber. Sr-Nd-Pb isotopic data of these basaltic rocks imply an inhomogeneous mantle below the South China Sea. The nature of magma origin has a two end-member mixing model, one is EM2 (Enriched Mantle 2) which may be originated from mantle plume, the other is DMM (Depleted MORB Mantle). Pb isotopic characteristics show the Dupal anomaly in the South China Sea, and combined with newly found Dupal anomaly at Gakkel ridge in Arctic Ocean, this implies that Dupal anomaly is not only limited to South Hemisphere. In variation diagrams among Sr, Nd and Pb, the origin nature of mantle below the SCS is similar to those below Leiqiong peninsula, northern margin of the SCS and Indochina peninsula, and is different from those below north and northeast China. This study provides geochemical constraints on Hainan mantle plume.     

Trace element transport rates in subduction zones: evidence from Th, Sr and Pb isotope data for Tonga-Kermadec arc lavas

Trace element and Th, Sr and Pb isotope data for young lavas from the Tonga-Kermadec arc in the southwest Pacific suggest that geochemical variations in the lavas along the arc are linked to differences in the material being subducted beneath the arc. Lavas from the southern (Kermadec) segment of the arc have relatively radiogenic Pb isotope compositions, which reflects a contribution from subducted sediment. In contrast, much of the Pb in Tonga lavas is derived from the altered oceanic crust in the subducting Pacific Plate, and lavas from the northernmost Tonga islands of Tafahi and Niuatoputapu contain Pb and Sr derived from the subducted part of the Louisville Seamount Chain. The origin of the Pb in the lavas from these two islands can thus be traced to a point on the subducting slab, and this observation is used to estimate the rate at which trace elements are transported beneath the arc. Our calculations suggest that fluid-soluble elements such as U, Sr and Pb are transported from the subducted slab, across the mantle wedge and back to the surface in lavas over a period of approximately 2–3 Ma, and that magmas are erupted at the surface less than 350 ka after the melts are generated in the mantle wedge.     

Triassic alkaline intrusives in the Yanliao-Yinshan area: their chronology, Sr, Nd and Pb isotopic characteristics and their implication

Dated isotopic ages for 15 alkaline intrusives in the Yanliao-Yinshan area, ranging from 268 to 190 Ma, ten of which are from 250 to 208 Ma, indicate that most of them were formed in the Triassic Epoch. All the E_Nd(t) ratios from - 17.19 to -3.21 averaging -7.09, the E_Sr(t) ratios fmm 11.7 to71.5 averaging 36.63, and the I_sr(t) ratios from 0.705 0 to 0.709 3 averaging 0.706 8, show their characteristics of enrichment. On the E_Nd (t) virus E_Sr(t) correlation diagram, the samples from these intmsives were plotted within the enriched mantle trend lines and just outside, demonstrating their close connection to materials from the enriched mantle reservoir, taking into account the same Pb isotopic composition as that of the mantle.     

A Sr,Nd, Hf,and Pb isotope perspective on the genesis and long-term evolution of alkaline magmas from Erebus volcano,Antarctica

We report new Nd, Hf, Sr, and high-precision Pb isotopic data for 44 lava and tephra samples from Erebus volcano. The samples cover the entire compositional range from basanite to phonolite and trachyte, and represent all three phases of the volcanic evolution from 1.3 Ma to the present. Isotopic analyses of 7 samples from Mt. Morning and the Dry Valley Drilling Project (DVDP) are given for comparison. The Erebus volcano samples have radiogenic ²⁰⁶Pb/²⁰⁴Pb, unradiogenic ⁸⁷Sr/⁸⁶Sr, and intermediate ¹⁴³Nd/¹⁴⁴Nd and ¹⁷⁶Hf/¹⁷⁷Hf, and lie along a mixing trajectory between the two end-member mantle components DMM and HIMU. The Erebus time series data show a marked distinction between the early-phase basanites and phonotephrites, whose Nd, Hf, Sr, and Pb isotope compositions are variable (particularly Pb), and the current ‘phase-three’ evolved phonolitic lavas and bombs, whose Nd, Hf, Sr, and Pb isotope compositions are essentially invariant. Magma mixing is inferred to play a fundamental role in establishing the isotopic and compositional uniformity in the evolved phase-three phonolites. In-situ analyses of Pb isotopes in melt inclusions hosted in an anorthoclase crystal from a 1984 Erebus phonolite bomb and in an olivine from a DVDP basanite are uniform and identical to the host lavas within analytical uncertainties. We suggest that, in both cases, the magma was well mixed at the time melt inclusions were incorporated into the different mineral phases.     

O, S, Sr, and Pb isotope variations in volcanic rocks from the Northern Mariana Islands: implications for crustal recycling in intra-oceanic arcs

Quaternary lavas from the Northern Mariana Islands have respective O- and S-isotope ranges ofδ¹⁸O = +5.7 to +6.6 (‰ SMOW) andδ³⁴S = +2.0to+20.7 (‰ CDT). Chemically evolved andesites and dacites with meanδ¹⁸O = +6.3 ± 0.2 are slightly enriched in¹⁸O with respect to unfractionated basalts of<53%SiO₂ with meanδ¹⁸O = +6.0 ± 0.1. This¹⁸O enrichment can be explained in terms of differentiation of parental mafic magmas havingδ¹⁸O values between +5.7 to +6.2‰ through closed-system crystal fractionation because the lavas from all nine islands of the arc define a coherentδ¹⁸OSiO₂ trend. The S-isotope composition of oxidized magmas is not modified extensively through the degassing of SO₂; therefore, the meanδ³⁴S value of ca. +11‰ for the Mariana lavas is considered to be representative of their source region.The enrichment of¹⁸O and³⁴S in Mariana Arc parental magmas relative to ocean floor basalts withδ¹⁸O ca. + 5.7‰ andδ³⁴S = ca.0.3‰ is attributed to the recycling of¹⁸O- and³⁴S-rich crustal components (sediment withδ¹⁸O = ca. + 25‰ and seawater sulfate withδ³⁴S = ca. +20‰ into the upper mantle source region for these arc magmas. This interpretation is consistent with enrichments of radiogenic Sr and Pb in the same lavas relative to ocean-floor basalts erupted either side of the arc, which are presumed to share a common upper mantle source. This enrichment is considered to reflect the mixing of two components, one having a typical upper mantle composition and the other having a more radiogenic character similar to that of western Pacific pelagic sediments.     

Major element, REE, and Pb, Nd and Sr isotopic geochemistry of Cenozoic volcanic rocks of eastern China: implications for their origin from suboceanic-type mantle reservoirs

Major- and rare-earth-element (REE) concentrations and UThPb, SmNd, and RbSr isotope systematics are reported for Cenozoic volcanic rocks from northeastern and eastern China. These volcanic rocks, characteristically lacking the calc-alkaline suite of orogenic belts, were emplaced in a rift system which formed in response to the subduction of the western Pacific plate beneath the eastern Asiatic continental margin. The rocks sampled range from basanite and alkali olivine basalt, through olivine tholeiite and quartz tholeiite, to potassic basalts, alkali trachytes, pantellerite, and limburgite. These rock suites represent the volcanic centers of Datong, Hanobar, Kuandian, Changbaishan and Wudalianchi in northeastern China, and Mingxi in the Fujian Province of eastern China.The major-element and REE geochemistry is characteristic of each volcanic suite broadly evolving through cogenetic magmatic processes. Some of the outstanding features of the isotopic correlation arrays are as follows: (1) NdSr shows an anticorrelation within the field of ocean island basalts, extending from the MORB end-member to an enriched, time-averaged high Rb/Sr and Nd/Sr end-member (EM1), (2) SrPb also shows an anticorrelation, similar to that of Hawaiian and walvis Ridge basalts, (3) NdPb shows a positive correlation, and (4) the ²⁰⁷Pb/²⁰⁴Pb vs ²⁰⁶Pb/²⁰⁴Pb plot shows linear arrays parallel to the general trend (NHRL) for MORB on both sides of the geochron, although in the ²⁰⁸Pb/²⁰⁴Pb vs ²⁰⁶Pb/²⁰⁴Pb plot the linear array is significantly displaced above the NHRL in a pattern similar to that of the oceanic island basalts that show the Dupal signatures. In all isotope correlation patterns, the data arrays define two different mantle components—a MORB-like component and an enriched mantle component. The isotopic data presented here clearly demonstrate the existence of Dupal compositions in the sources of the continental volcanic rocks of eastern China. We suggest that the subcontinental mantle beneath eastern China served as the reservoir for the EMI component, and that the MORB component was either introduced by subduction of the Kula-Pacific Ridge beneath the Asiatic plate in the Late Cretaceous, as proposed by Uyeda and Miyashiro, or by upwellings in the subcontinental asthenosphere due to subduction.     

Isotopic geochemistry (O,Sr, Pb) of the Golda Zuelva and Mboutou anorogenic complexes,North Cameroun: mantle origin with evidence for crustal contamination

The annular (6–8 km diameter) Golda Zuelva and Mboutou anorogenic complexes of North Cameroun are composed of a suite of alkaline plutonic rocks ranging from olivine gabbro to amphibole and biotite granite. For the Mboutou complex there are two overlapping centres. In the Golda Zuelva complex the plutonic rocks are associated with a later hawaiite to rhyolite volcanic suite. A Rb/Sr whole rock isochron gives an age of 66±3 Ma for the Golda Zuelva granites, with initial⁸⁷Sr/⁸⁶Sr ratio of 0.7020, and demonstrates that plutonism and volcanism were essentially contemporaneous and probably cogenetic. For Golda Zuelva and the north Mboutou centre¹⁸O/¹⁶O (5.6–6.2),⁸⁷Sr/⁸⁶Sr (0.7030–0.7045) and Pb isotopic ratios (²⁰⁷Pb/²⁰⁴Pb: 15.60–15.64) support a mantle origin for the initial magmas. Unlike Sr isotopes, the O isotopic ratios of the granitic end members at Golda Zuelva (～7.5) indicate crustal contamination. Post-magmatic alteration was not significant.For the younger south Mboutou centre the O-, Sr- and Pb-isotopic data indicate more extensive magma-crust interaction and in a different (higher level?) crustal environment with δ¹⁸O granite=3.3‰,⁸⁷Sr/⁸⁶Sr ratios up to 0.706 and Pb isotopic ratios more markedly displaced from the oceanic volcanic field. The low-¹⁸O granites probably record, at least in part, a magmatic process with subsequent minor post-magmatic alteration effects. The major and trace element systematics between the north and south Mboutou centres are directly comparable. The evolution of the magmas were dominated by fractional crystallisation and progressive crustal contamination processes.     

K/Rb and (Sr/Sr)0 ratios of dredged submarine basalts

K/Rb and (⁸⁷Sr/⁸⁶Sr)₀ ratios were measured for 14 submarine basalts dredged from seamounts in the Pacific Ocean. The K/Rb ranges from 200 to 700, which is significantly lower than that of oceanic ridge tholeiites. Petrographic examination and the low value of K/Rb indicate that seamount basalts are alkaline.     

Comments on the use of Ti,Zr, Y,Sr, K,P and Nb in classification of basaltic magmas

The distribution of Ti, Zr, Y, Sr, K, P and Nb has been investigated at 55 sample sites within a single basaltic flow, the Cliefden Outcrop, which has adjusted to low-grade metamorphism of the prehnite-pumpellyite facies. The cluster of points in the plot of Ti, Zr and Y as proposed by Pearce and Cann shows that the ratio of these elements has remained relatively constant after metamorphism and would therefore have significance in attempts at classification of magma type. Likewise a plot involving Nb, Y, Zr and P as proposed by Floyd and Winchester shows only restricted scatter and appears useful. However, plots involving Sr or K show a scatter that is clearly related to metamorphic processes. Consequently, plots involving these two elements are likely to be of little use in classification in this case.Low-grade metamorphism is common, variable and not always recognized. The study concerned one style of alteration and revealed problems in the application of some classification schemes. Consequently it is apparent that much more rigorous testing is needed before classification schemes can be generally applied to sequences of basaltic rocks.     

Pb, Nd, and Sr isotopic constraints on the origin of Miocene basaltic rocks from northeast Hokkaido, Japan: Implications for opening of the Kurile back-arc basin

Late Miocene (7–9 Ma) basaltic rocks from the Monbetsu‐Kamishihoro graben in northeast Hokkaido have chemical affinities to certain back‐arc basin basalts (referred to herein as Hokkaido BABB). Pb‐, Nd‐ and Sr‐isotopic compositions of the Hokkaido BABB and arc‐type volcanic rocks (11–13 Ma and 4–4.5 Ma) from the nearby region indicate mixing between the depleted mantle and an EM II‐like enriched component (e.g. subducted pelagic sediment) in the magma generation. At a given ⁸⁷Sr/⁸⁶Sr, Hokkaido BABB have slightly lower ¹⁴³Nd/¹⁴⁴Nd and slightly less radiogenic ²⁰⁶Pb/²⁰⁴Pb compared with associated arc‐type lavas, but both these suites are difficult to distinguish solely on the basis of isotopic compositions. These isotopic data indicate that while generation of the Hokkaido BABB involves smaller amounts of the EM II‐like enriched component than do associated arc lavas, Hokkaido BABB are isotopically distinct from basalts produced at normal back‐arc basin spreading centers. Instead, northeast Hokkaido BABB are more similar to basalts erupted during the initial rifting stage of back‐arc basins. The Monbetsu‐Kamishihoro graben may have developed in association with extension that formed the Kurile Basin, suggesting that opening of the basin continued until late Miocene (7–9 Ma).     

Possible origin of K-rich volcanic rocks from Virunga,East Africa,by metasomatism of continental crustal material: Pb,Nd and Sr isotopic evidence

The isotopic compositions of Sr, Nd and Pb together with the abundances of Rb, Sr, U and Pb have been determined for mafic and felsic potassic alkaline rocks from the young Virunga volcanic field in the western branch of the East African rift system.⁸⁷Sr/⁸⁶Sr varies from 0.7055 to 0.7082 in the mafic rocks and from 0.7073 to 0.7103 in the felsic rocks. The latter all come from one volcano, Sabinyo. Sabinyo rocks have negative ε_Ndvalues ofε_Nd = ?10. Nd and Sr isotopic variations in the basic potassic rocks are correlated and plot between Sabinyo and previously reported [1] compositions (ε_Nd = +2.5;⁸⁷Sr/⁸⁶Sr≈ 0.7047) for Nyiragongo nephelinites. The Pb isotopic compositions for Sabinyo rocks are nearly uniform and average²⁰⁶Pb/²⁰⁴Pb≈ 19.4,²⁰⁷Pb/²⁰⁴Pb= 15.79–15.84,²⁰⁸Pb/²⁰⁴Pb≈ 41.2. The basic potassic rocks have similar²⁰⁶Pb/²⁰⁴Pb values but range in²⁰⁷Pb/²⁰⁴Pb and²⁰⁸Pb/²⁰⁴Pb from the Sabinyo values to less radiogenic compositions.Excellent correlations of⁸⁷Sr/⁸⁶Sr with Rb/Sr, 1/Sr and²⁰⁷Pb/²⁰⁶Pb for Sabinyo rocks suggest these to be members of a hybrid magma series. However, the nearly uniform Pb compositions for this series points to radiogenic growth of⁸⁷Sr in the magma source region following an event which homogenized the isotopic compositions but not Rb/Sr. The Rb-Sr age derived from the erupted Sabinyo isochron-mixing line is consistent with the ～500 Myr Pb-Pb age from Nyiragongo [1], which suggests that this event affected all Virunga magma sources. The event can again be traced in the Pb-Pb, Pb-Sr and Nd-Sr isotopic correlations for all Virunga rocks, including Nyiragongo, when allowances are made for radiogenic growth subsequent to this mixing or incomplete homogenization event. Inferred parent/daughter element fractionations point to a metasomatic event during which a mantle fluid invaded two lithospheric reservoirs: a +ε_Nd reservoir sampled by the Nyiragongo nephelinites and suggested to be the subcontinental mantle and a ?ε_Nd reservoir sampled by the mafic and felsic potasssic volcanism. Whether this ?ε_Nd reservoir is the crust, continental crustal material in the mantle or anomalous mantle cannot be decided from the data. The simplest answer, that this reservoir is the continental crust, seems to be at variance with experimental evidence suggesting a subcrustal origin for basic potassic magmas. Partial melting of the ancient metasomatised lithospheric domains and ensuing volcanism seems to be entirely a response to decompression and rising geotherms during rifting and thinning of the lithosphere.     

腾冲、长白山、五大连池新生代火山岩Sr、Nd、Pb同位素地球化学特征

概括了腾冲、长白山、五大连池新生代火山岩岩石学、岩石化学基本特征,探讨了Ｓｒ、Ｎｄ、Ｐｂ同位素地球化学特征和岩浆源区性质。腾冲火山岩为高钾钙碱性岩系,高８７Ｓｒ／８６Ｓｒ、高２０６Ｐｂ／２０４Ｐｂ、２０８Ｐｂ／２０４Ｐｂ、低１４３Ｎｄ／１４４Ｎｄ,岩浆源区为俯冲带再循环富集地幔。长白山火山岩为超钾钙碱性岩系,低Ｓｒ高８７Ｓｒ／８６Ｓｒ,εＮｄ为－２３—＋２９,Ｐｂ同位素组成变化不大,岩浆源区为俯冲带再循环地幔。五大连池火山岩为超钾碱性岩系,高８７Ｓｒ／８６Ｓｒ、低１４３Ｎｄ／１４４Ｎｄ和２０６Ｐｂ／２０４Ｐｂ、２０８Ｐｂ／２０４Ｐｂ,岩浆源区为地幔内部交代作用所产生的富集地幔。     

Surface-wave magnitude corrections for intermediate and deep earthquakes

The small amplitudes of surface waves for intermediate and deep-focus earthquakes lead to too low values of the surface-wave magnitudes. On the basis of available material, average magnitude corrections are deduced, which increase with focal depth and amount to 0.1–0.5 for focal depths of 50 100 km and to 0.5–0.7 for depths of 100–700 km.     

Low-degree melting of a metasomatized lithospheric mantle for the origin of Cenozoic Yulong monzogranite-porphyry,east Tibet: Geochemical and Sr–Nd–Pb–Hf isotopic constraints

SHRIMP zircon U–Pb dating, mineral chemical, element geochemical and Sr–Nd–Pb–Hf isotopic data have been determined for the Yulong monzogranite-porphyry in the eastern Tibet, China. The Yulong porphyry was emplaced into Triassic strata at about 39 Ma. The rocks are weakly peraluminous and show shoshonitic affinity, i.e., alkalis-rich, high K₂O contents with high K₂O / Na₂O ratios, enrichment in LREE and LILE. They also show some affinities with the adakite, e.g., high SiO₂ and Al₂O₃, and low MgO contents, depleted in Y and Yb, and enrichment in Sr with high Sr / Y and La / Yb ratios, and no Eu anomalies. The Yulong porphyry has radiogenic ⁸⁷Sr / ⁸⁶Sr (0.7063–0.7070) and unradiogenic ¹⁴³Nd / ¹⁴⁴Nd (ε_Nd = − 2.0 to − 3.0) ratios. The Pb isotopic compositions of feldspar phenocrysts separated from the Yulong porphyry show a narrow range of ²⁰⁶Pb / ²⁰⁴Pb ratios (18.71–18.82) and unusually radiogenic ²⁰⁷Pb / ²⁰⁴Pb (15.65–15.67) and ²⁰⁸Pb / ²⁰⁴Pb (38.87–39.00) ratios. In situ Hf isotopic composition of zircons that have been SHRIMP U–Pb dated is characterized by clearly positive initial ε_Hf values, ranging from + 3.1 to + 5.9, most between + 4 and + 5. Phenocryst clinopyroxene geothermometry of the Yulong porphyry indicates that the primary magmas had anomalously high temperature (> 1200 °C). The source depth for the Yulong porphyry is at least 100 km inferred by the metasomatic volatile phase (phlogopite–carbonate) relations. Detailed geochemical and Sr–Nd–Pb–Hf isotopic compositions not only rule out fractional crystallization or assimilation-fractional crystallization processes, but also deny the possibility of partial melting of subducted oceanic crust or basaltic lower crust. Instead, low degree (1–5%) partial melting of a metasomatized lithosphere (phlogopite–garnet clinopyroxenite) is compatible with the data. This example gives a case study that granite can be derived directly by partial melting of an enriched lithospheric mantle, which is important to understand the source and origin of diverse granites.