Natural and anthropogenic influences in the northeastern coast of the Nile delta,Egypt

Landsat enhanced thematic mapper imagery (ETM) of 2002 and aerial photography of 1955, combined with published charts and field observations were used to interpret coastal changes in the zone between Kitchener drain and Damietta spit in the northeastern Nile delta, previously recognized as a vulnerable zone to the effects of any sea level rise resulting from global warming. The interpretation resulted in recognition of several changes in nine identified geomorphological land types: beach and coastal flat, coastal dunes, agricultural deltaic land, sabkhas, fish farms, Manzala lagoon, saltpans, marshes and urban centers. Reclamation of vast areas of the coastal dunes and of Manzala lagoon added about 420 km2 to the agricultural deltaic land. About 48 km2 of backshore flats, marshes, salt pans and Manzala lagoon have been converted to productive fish farms. The main urban centers have expanded; nearly 12.1 km² have been added to their areas, and new urban centers (Damietta harbor and the New Damietta city) with total area reach of ~35.3 km² have been constructed at the expense of vast areas of Manzala lagoon, coastal dunes, and backshore flats. As a consequence of human activities, the size of Manzala lagoon has been reduced to more than 65%. Shoreline changes have been determined from beach profile survey (1990–2000), and comparison of 1955 aerial photographs and ETM satellite image of 2002 reveal alongshore patterns of erosion versus accretion. The short-term rate of shoreline retreat (1990–2000) has increased in the downdrift side of Damietta harbor (≃14 m/year), whereas areas of accretion exist within the embayment of Gamasa and in the shadow of Ras El Bar detached breakwaters system, with a maximum shoreline advance of ~15 m/year. A sandy spit, 12 km long, has developed southeast of Damietta promontory. These erosion/accretion patterns denote the natural processes of wave-induced longshore currents and sediment transport, in addition, the impact of man-made coastal protection structures.     

Manzala lagoon, Nile delta, Egypt: modern sediment accumulation based on radioactive tracers

 This study was undertaken to determine whether recent anthropogenic changes in the Nile basin have affected the modern rate of sediment accumulation in the Nile delta. Excess ²¹⁰Pb, ¹³⁷Cs, and ^239,240Pu were used to develop a sediment chronology for a core from central Manzala lagoon, the delta sector which has had the highest average rate of sediment accumulation during the Holocene (to about 0.7 cm year^–1). Excess ²¹⁰Pb was detected in the top 32 cm of the core, yielding an accumulation rate of 1.2 cm year^–1, higher than the mean rate for the Holocene. A high ¹³⁷Cs/^239,240Pu ratio requires a reactor source (possibly Chernobyl) for these nuclides. Low concentrations of excess ²¹⁰Pb and weapons-fallout nuclides precluded recognition of changes in sediment accumulation rate in Manzala lagoon during this century and may limit the use of tracer radionuclides for modern sediment chronology in the Nile delta. Received: 18 March 1997 · Accepted: 22 July 1997     

Post-Aswan dam sedimentation rate of lagoons of the Nile Delta,Egypt

This study uses radiometric analysis (²¹⁰Pb and ¹³⁷Cs) of short sediment cores with high-resolution sampling (1-cm interval) to trace sedimentation rates in the Nile Delta lagoons, particularly since completion of the Aswan High Dam in 1964. A declining trend in ²¹⁰Pb_ex as calculated by the CIC model is clearly identified in about 10 cm of the upper-core sediments from the lagoons of Manzala and Edku, accompanied by two spikes of ¹³⁷Cs in cores from the lagoons of Burullus and Edku. These findings illustrate average post-dam sedimentation rates ranging from 0.22 to 0.27 cm a⁻¹ in the lagoons, in contrast with those found previously based on low-resolution sampling. The lower sedimentation rates in the lagoons are a consequence of a dramatic reduction in riverine sediment load to the coastal area as a result of the damming. Although widespread erosion occurs along the open estuarine coast, the lagoon setting remains calmer than before due to coastal diking and freshwater regulation in the delta plain in the past decades. This provides the possibility of continuously preserved radiometric records in the less-bioturbated lagoon sediments. Dating individual layers using the CRS model has revealed increasing sedimentation rates in Manzala and Burullus since the 1980s, which can largely be explained as a consequence of the reduction in lagoon area due to intensifying reclamation. The post-dam sedimentation in the shrinking lagoons may have some adverse ecological consequences due to finer sediment’s affinity with pollutants. These findings would shed light on the environmental conservation and socioeconomic development in the Nile Delta region.     

Erosion and accretion rates and their associated sediment characters along Ras El Bar coast,northeast Nile Delta,Egypt

Beach profile data, covering the coast of Ras El Bar, northeast Nile Delta, collected during the years from 1990 to 2002 combined with landsat images for the area and sedimentological investigation have been used to identify beach and nearshore seafloor sediment changes. Along the coast of Ras El Bar, two accretion sectors and one of erosion have been recognized. The first accretion sector is located west of Damietta harbour, where the harbour jetties have halted the littoral transport, while the second one is behind a system of detached breakwaters protecting Ras El Bar resort. Both the two sectors are characterized by growing shoreline with maximum rates ∼15 and 10 m/year, respectively. Also, they have maximum nearshore seafloor accretion rates of ∼18 and 22 cm/year, respectively. The erosion sector is located east of Damietta port and has a maximum rate of shoreline retreat ∼−10 m/year. Erosion of its nearshore seafloor is indicated recording a maximum rate of ∼−20 cm/year. The rate of net sediment volume change in the area indicates shifting of the accretion sector (II) westward, responding to installation of the new breakwaters unit. The two accretion sectors are characterized by dominance of moderately sorted fine sands in their shore area which change seaward into less sorting very fine sands. Beach sands of the eroded sector are poorly sorted medium grain size. The dominant constituents of heavy mineral species in beach and sea-bottom sands are the characteristic assemblages of the Nile deposits. The sands of the eroded zone are relatively enriched in monazite, zircon, tourmaline, garnet, and rutile.     

Change detection of the coastal zone east of the Nile Delta using remote sensing

The coastal zone of the Nile Delta is a promising area for energy resources and industrial activities. It also contains important wetland ecosystems. This coastal area witnessed several changes during the last century. A set of four satellite images from the multi-spectral scanner (MSS), thematic mapper (TM) and Systeme Pour l’Observation de la Terre (SPOT) sensors were utilized in order to estimate the spatio-temporal changes that occurred in the coastal zone between Damietta Nile branch and Port-Said between 1973 and 2007. Image processing applied in this study included geometric rectification; atmospheric correction; on-screen shoreline digitizing of the 1973 (MSS) and 2007 (SPOT) images for tracking the shoreline position between Damietta promontory and Port-Said; and water index approach for quantifying Manzala lagoon surface area change using 1973 (MSS), 1984 (TM) and 2003 (TM) images. Results showed that coastal erosion was severe near Damietta promontory and decreased eastward, however, accretion was observed near Port-Said. About 50% of the coastal strip was under erosion and 13% was under accretion. In addition, a remarkable decline (34.5%) of the Manzala lagoon surface area was estimated. These changes were attributed mainly to the control of the River Nile flooding and the land use change by anthropogenic activities.     

Major Ion Chemistry in a Freshwater Coastal Lagoon from Southern Brazil (Mangueira Lagoon): Influence of Groundwater Inputs

This paper characterizes major ion distributions and investigates whether groundwater exerts a major control on the chemical functioning of Mangueira Lagoon, a large (90 km long), shallow (∼4–5 m deep), and fresh coastal lagoon in southern Brazil. Water volumes equivalent to ∼80% of the total annual input are used in the summer for irrigating nearby rice plantations, the most important regional economic activity. While Na⁺ and Cl⁻ are the major ions in local groundwater, Na⁺ and HCO₃⁻ are the most enriched ions in lagoon water. The ion concentrations measured in Mangueira Lagoon were homogeneous, except for a few samples affected by rainwater and groundwater inputs. A shore-normal transect starting at the pump house of a rice irrigation canal indicated strong groundwater input at this canal. In spite of the small volume contribution (∼2% of precipitation), groundwater discharge accounts for 50–70% of major ion inputs into the lagoon, with ∼70% of the groundwater inputs being anthropogenically derived (e.g., from the rice irrigation canals). This may have serious implications for the management of the coastal water resources from Mangueira Lagoon and other similar areas as groundwater associated with agricultural systems may be contaminated by fertilizers and pesticides. The results imply that groundwater should not be neglected in dissolved species’ budgets even when its volume contribution is small.     

Biological productivity, terrigenous influence and noncrustal elements supply to the Central Indian Ocean Basin: Paleoceanography during the past ∼ 1 Ma

A 2m-long sediment core from the siliceous ooze domain in the Central Indian Ocean Basin (CIOB; 13‡03′S: 74‡44′E; water depth 5099m) is studied for calcium carbonate, total organic carbon, total nitrogen, biogenic opal, major and few trace elements (Al, Ti, Fe, K, Mg, Zr, Sc,V, Mn, Cu, Ni, Zn, Co, and Ba) to understand the productivity and intensity of terrigenous supply. The age model of the sediment core is based on U-Th dating, occurrence of Youngest Toba Tuff of ∼ 74 ka and Australasian microtektites of ∼ 770 ka. Low carbonate content (< 1%) of sediment core indicates deposition below the carbonate compensation depth. Organic carbon content is also very low, almost uniform (mean 0.2 wt%) and is of marine origin. This suggests a well-oxygenated bottom water environment during the past ∼ 1100ka. Our data suggest that during ∼ 1100 ka and ∼ 400 ka siliceous productivity was lower, complimented by higher supply of terrigenous material mostly derived from the metasedimentary rocks of High Himalayan crystalline. However, during the last ∼ 400 ka, siliceous productivity increased with substantial reduction in the terrigenous sediment supply. The results suggest that intensity of Himalayan weathering, erosion associated with monsoons was comparatively higher prior to 400 ka. Manganese, Ba, Cu, Ni, Zn, and Co have around 90% of their supply from noncrustal (excess) source and their burial to seafloor remained unaffected throughout the past ∼ 1100 ka.     

Using Landsat data to determine land use changes in Datong basin,China

The aim of this study was to determine land use changes in Datong basin using multitemporal Landsat data for the period of 1977–2006. Four dates of Landsat images from 1977, 1990, 2000, and 2006 were selected to classify the study area. Based on the supervised classification method of maximum likelihood algorithm, images were classified into six classes: water, urban, forest, agriculture, wetland, and barren land. A multidate postclassification comparison change detection algorithm was used to determine changes in land use in four intervals. It is found that (1) urban land area increased 213% due to urbanization that resulted from rapid increase of urban population and high-speed economic development, (2) agriculture area increased 34.0% due to land reclamation that resulted from rapid increase of rural population and improvement of irrigation capacity, (3) forest area decreased 20.9% due to deforestation for urban area and agricultural use, (4) barren land area decreased 78.2% due to cultivation for agricultural use, and (5) water and wetland decreased 39.1 and 67.1%, respectively, due to exploitation of surface water and decrease of recharge from groundwater to surface water that resulted from over exploitation of groundwater.     

Reservoir sediments – a witness of mining and industrial development (Malter Reservoir, eastern Erzgebirge, Germany)

The Malter Reservoir is situated about 30 km south of Dresden (eastern Germany) in a historical mining area of the eastern Erzgebirge. It was built in 1913 for the protection from floodwaters, droughts and for generating electricity. The river Rote Wei?eritz is the main source of clastic input into the lake. Geochemical and sedimentological data of gravity-and piston-cores, recovered from the deepest point of the lake, document the environmental history of the drainage area since 1963. ¹³⁷Cs dating gives an average sedimentation rate of ∼2.9 cm/year. Within the whole core, heavy metals are strongly enriched (parentheses refer to enrichment factors as compared with average shale): cadmium (290), silver (140), bismuth (90), antimony (25), lead (21), zinc (14), tin (13), uranium (9), tungsten (9), molybdenum (5), copper (4), thallium (3) and chromium (2). Enrichments are detectable for the whole registered time-period of 81 years. Peaks of up to 27 mg/kg silver, 37 mg/kg bismuth, 91 mg/kg cadmium, 410 mg/kg chromium, 240 mg/kg copper, 20 mg/kg molybdenum, 14000 mg/kg phosphorus, 740 mg/kg lead, 6,5 mg/kg antimony, 74 mg/kg tin, 52 mg/kg tungsten and 1900 mg/kg zinc reflect local events caused by human impact. Inputs from different pollution sources at different times are represented by highly variable elemental concentrations and ratios within the core. High pH values within the water and the sediment column, the large adsorption capacity of the fine-grained C_org.-rich sediment, and the presence of low Eh-values and sulphide ions in the sediment prevent the remobilisation of the toxic elements. Erosion of these contaminated sediments during floods, channel flows or resuspension during removal of the sediments may lead to a downstream transfer of pollutants. Contents of P and C_org., as well as diatom abundance, indicate a change from oligotrophic to eutrophic conditions in the lake during ∼1940–1950. This was mainly caused by high agricultural activity in the drainage area. Reduced contents of Cu, Zn, Cd and Cr since the reunification of East and West Germany are obviously caused by increasing environmental protection measures, such as wastewater purification and especially the closing of contaminating industries. Revision received: 23 September 1999 · Accepted: 17 December 1999     

Carbonate sediment transport pathways based on foraminifera: case study from Frank Sound, Grand Cayman, British West Indies

Foraminifera can be used to determine the source(s) of carbonate sediment and the directions of sediment transport in shallow, coastal lagoons such as Frank Sound on the south-central coast of Grand Cayman. These determinations, based on the distribution of foraminiferal assemblages and ‘tracer species’ (numerically abundant species that live in known physiographic units and/or ecological conditions), show that the lagoonal sediments are a mixture of grains that originated in the lagoon and forereef. The variable proportions of these foraminifera throughout the lagoon reflects the dynamic processes that control lagoonal sedimentation. Amphistegina gibbosa, Discorbis rosea, and Asterigerina carinata lived in the forereef environment. The fact that these ‘tracer species’ are found throughout Frank Sound and in the beach sands, shows that they were transported across the reef crest and the lagoon. Abrasion-resistant Archaias angulatus, a‘tracer species’ indicative of a lagoonal setting, forms up to 50% of foraminiferal assemblages found in the lagoonal sediments. Preferential winnowing of small tests from these populations indicates sorting under high energy conditions. The vertical distribution of the forereef and lagoonal foraminifera in the sediment blanket that covers the floor of Frank Sound indicates that these processes are temporally persistent. Transportation of forereef foraminifera into and around the lagoon and sorting of the lagoonal foraminifera cannot take place under ‘normal’ conditions when the tranquil lagoon is characterized by weak currents. Storms and/or hurricanes, however, generate short-lived high-energy events that can move and sort the sediment and foraminifera. At the height of a storm, water and sediment are moved over the reef and then piled and held onshore by the onshore winds and the constant flow of water over the reef and across the lagoon. These currents can mix some of the lagoonal and forereef sediments. As a storm wanes, however, the ‘piled water’ flows offshore via strong rip currents that pass into the ocean through the channels which transect the reef. These currents winnow and/or strip sediment from the lagoon and may transport lagoonal sediments into the forereef area. As a result, residual lagoonal sediment is commonly characterized by larger and abrasion-resistant foraminifera.     

Thecamoebians and palynological assemblage in Gautami-Godavari River mouth,India: Environment and sea level since 3000 years

Palaeoclimate and palaeoecological study was carried out using palynological and thecamoebian evidences buried in ∼4 m vertically exposed sediment section (12 km inland from the present shoreline) of Late Holocene age along the banks of Gautami-Godavari River and from three shallow cores from its Nilarevu tributary, Andhra Pradesh. Inferred climatic periods include (1) a basal cold/arid period (∼3000-2000 yrs BP) with dominance of Botryococcus and other fresh water algal remains coupled with abundance of 25 species of thecamoebians indicating shallow and lentic ecosystem during most of the period and (2) a relatively warm/wet conditions (since ∼2000 yrs BP) reveal lotic fresh water ecosystem characterized by the evidences of tree palynotaxa and low percentage of thecamoebians. The three shallow cores (0.5–1 m) near the mouth (∼8 km stretch) of the Nilarevu tributary reveal fluvio-marine deposition in the top 50–80 cm sediment unlike the deeper fresh water depositional environment suggesting sea water ingression in the recent decades. The study illustrates that the Gautami-Godavari River delta gradually prograded since ∼3000 yrs BP until 100–150 yrs unlike the intermittent relative sea level rise and fall recorded during the same period in the contemporary south-east deltaic areas.     

Yangtze Delta, China: Taihu lake-level variation since the 1950s, response to sea-level rise and human impact

 Hydrological records collected from water gauge stations since the 1950s demonstrate that the Taihu lake level is rising. The average rate of the lake-level rise is 0.4–1.1 mm/year during the non-flood season, resulting directly from a rise in sea level. High rates of 3.0–5.0 mm/year of rise are even recorded during the wet season. This indicates increasing human activities such as reclamation, sluicing and embanking, which significantly hinder the expulsion of extra lake water to the coast shortly after a rainfall. Generally, the lake level of the western inlet is higher than that of the eastern outlet. However, the lake-level difference between the west and east has been diminished annually from ∼10–15 cm in the 1950s to <3 cm at the present time. During non-flood seasons, the lake-level difference even appears to be reversed, indicating a retrogression of the lake flow from east to west. It is predicted that the Taihu drainage basin will lose much of its natural water-expelling ability in the next 50 years as the sea level continues to rise, and retrogression will likely occur during the flood season in the near future. Received: 13 March 1998 · Accepted: 21 July 1998     

Radiochemistry of sediments from the southern Dead Sea, Jordan

 A sediment core from the southern Dead Sea was analyzed using gamma spectroscopy as well as ²¹⁰Pb dating in order to ascertain if any radioactive contamination could be detected and to determine the sedimentation rates in the area. Results of this study show no presence of man-made radionuclides in the area. Sedimentation rates were determined to be between 0.25 and 0.4 g/cm²/year. (∼0.5 cm/year), which is in line with what would be expected assuming carbonate layers are annual varves. Received: 31 January 1997 · Accepted: 11 March 1997     

Mercury contamination in Marano Lagoon (Northern Adriatic sea,Italy): Source identification by analyses of Hg phases

Total Hg concentrations and Hg speciation were determined in bottom sediments of Marano lagoon to investigate the consequences of Hg phases on fish farms and shellfish cultivation areas. Mercury phases were separated into cinnabar (HgS) and non-cinnabar compounds, via a thermo-desorption technique, in surface and core sediments; both of which had been contaminated by industrial wastes and mining activity residues. The former are due to an industrial complex, which has been producing cellulose, chlor-alkali and textile artificial fibres since 1940. Processing and seepage wastewaters, which were historically discharged into the Aussa-Corno river system and therefore into the lagoon, have been significantly reduced since 1984 due to the construction of wastewater treatment facilities. The second source is the Isonzo River, which has been the largest contributor of Hg into the northern Adriatic Sea since the 16th century due to Hg mining at the Idrija mine (western Slovenia). Red cinnabar (HgS) derived from the mining area is mostly stable and insoluble under current environmental conditions. In contrast, organically bound Hg, such as Hg bound to humic acids, has the potential to be transformed into bioavailable Hg compounds (for example, methylmercury). The presence of the two Hg forms permitted each Hg source to be quantified. It also allowed the areas with the highest risk of Hg contamination from Hg-rich sediment to be identified; thus potentially avoiding the transfer of Hg from the sediment into the water column and eventually into living biota. The results show that Hg Enrichment Factors in bottom sediments exceed values of 10 and cinnabar dominates the central sector near the main tidal channel where tidal flux is more effective. Non-cinnabar compounds were found to be enriched in fine grained material and organic matter. In fact, up to 98% of total Hg at the Aussa-Corno river mouth and in the inner margin of the basin occurred in an organic form. This evidence, combined with the high contents of total Hg (4.1–6.6 μg g⁻¹ and EF > 10) measured in surface sediments, suggest that Hg in Marano lagoon is involved in biogeochemical transformations (e.g., methylation).     

Vertical sediment fluxes and wave-induced sediment resuspension in a shallow-water coastal lagoon

The present study describes variations in the vertical fluxes measured concurrently with sediment traps at both a shallow water (4 m) and a deeper water (7.5 m) position in a coastal lagoon in April 1995. A tripod equipped with five sediment traps (trap openings at 0.35 m, 0.75 m, 1.05 m, 1.40 m, and 1.80 m above the seabed) was placed at the shallow water position. This tripod was deployed three times during the study period and deployment periods varied between 2 d and 5 d. The second sediment trap, placed at the deep water position in the central part of the lagoon, measured vertical flux for intervals of 12 h at 1.4 m above the seabed. The horizontal distance between the sediment traps was 8 km. The average maximum vertical flux at the shallow water position reached 27.9 g m⁻² d⁻¹ during a period of high, westerly wind speeds, and a maximum vertical flux of 16.9 g m⁻² d⁻¹ was reached at the deep water position during a period of high, easterly wind speeds. Both strong resuspension events were closely related to increased wave shear stress derived from surface waves. Maximum wave-induced resuspension rate was 10 times higher at the shallow water position and 3.8 times higher at the deep water position compared with the net sedimentation rate in the lagoon. Small resuspension events occurred at the shallow water position during periods of increased current shear stress, Estimations of conditions for transport of sediment between shallow water and deep water showed that particles must be resuspended to a height between 3 m and 4 m and that current speeds must be higher than about 0.1 m s⁻¹. An average sedimentation rate of 3.8 g m⁻² d⁻¹ was obtained at the shallow water position during a period without wave shear stress and low current shear stress. This rate measured by sediment traps is similar to a net sedimentation rate in the lagoon of 4.4 g m⁻² d⁻¹, which was determined by radiocarbon dating of a sediment core (Kristensen et al. 1995).     

Metal pollution loading,Manzalah lagoon,Nile delta,Egypt: Implications for aquaculture

High cultural enrichment factors are found for Hg (13×), Pb (22.1×), and other potentially toxic metals (e.g., Sn, Zn, Cu, Ag) in the upper 20 cm of sediment cores from the southeastern Ginka subbasin of Manzalah lagoon, Nile delta, Egypt. Cores from other areas of the lagoon show little metal loading. Metal loading followed the closure of the Aswan High Dam, the availability of abundant cheap electricity, and the development of major power-based industries. Industrial wastes containing potentially toxic metals are dumped into the Nile delta drain system. The load carried by Bahr El-Baqar drain discharges into the Ginka subbasin, which acts as a sink and results in metal loading of the sediment deposited there. Further development of aquaculture in this subbasin, of food-stuff agriculture on recently reclaimed lagoon bottom, or where irrigation waters come from Bahr El-Baqar drain or its discharge should be halted or strictly limited until potentially toxic metals in the drain waters and sediment are removed and polluted input drastically reduced. This environmental assessment of heavy metals in aquaculture or agriculture development should extend to other waterbodies in the northern Nile delta, particularly Idku lagoon and lake Mariut, where industrial metal-bearing wastes discharge into the waterbodies.     

The Lake Manzala of Egypt: an ambiguous future

The Lake Manzala of Egypt has a relatively short history and its future, however, is uncertain. The lake which was the biggest coastal wetland along the Mediterranean Coast is moving toward its disappearance by two opposite forces, one of them is the shrinking of the water body by siltation of sediments coming from agricultural lands and the abundance of weeds and swamp vegetation as well as the drying practices for agriculture, whereas the other force incorporates the removal of the coastal sand bar separating the lake from the Mediterranean Sea by erosion, which should eventually lead to the conversion of the lake into a coastal embayment instead of being a closed coastal lagoon. The study provided a spatiotemporal change analysis of the lake using remotely sensed data.     

Environmental impact assessment on water quality deterioration caused by the decreased Ganges outflow and saline water intrusion in south-western Bangladesh

 This paper deals with an environmental impact assessment of low water flow in the river Ganges during a dry period at the Khulna and Mongla port areas in south-western Bangladesh. Large-scale surface water withdrawal in India after commissioning the Farakka Barrage causes a drastic fall in the Ganges low-flow condition within the Bangladesh territory during every dry period. The average lowest discharge in the Ganges is 552 m³/s, which is about 73% less than that in the pre-Farakka time. This has caused the deterioration of both surface and groundwater quality of the study area. Salinity is the principal cause of water quality degradation in the area. Present observation shows that the surface water of the area is sulphate-chloride dominated, which signifies high salinity whereas the groundwater is categorized as of medium to high salinity. To maintain the Rupsa River's maximum salinity below 1000 μS/cm the discharge in the Ganges should be ∼1500 m³/s, whereas that at Garai basin is ∼10 m³/s. If this present situation continues it will be a crippling blow to the environment of the area in the long term. An integrated multidisciplinary approach to hydrogeological research is urgently required to salvage the area from further deterioration. Received: 9 August 1999 · Accepted: 8 March 2000     

Pore water geochemistry near the sediment-water interface of a zoned, freshwater wetland in the southeastern United States

 Sediment and its associated pore water were collected from a zoned, freshwater, riparian wetland, located in the Talladega National Forest, northeastern Hale County, Alabama, to study the porewater chemistry and its spatial changes within and between the wetland ecological zones. Obvious changes in pH, Eh and element concentrations were observed between the different wetland ecological zones. Major cations (Ca, Mg, and Na) and trace elements (B, Ba, Sr, and Mn) have very good spatial correlation with Fe and Mn distributions, both in the pore water and the sediment, suggesting that adsorption on, and desorption from, iron and manganese oxyhydroxides are important processes controlling the distributions of these elements in the wetland sediment. However, an equilibrium adsorption model is not able to explain the distribution of trace elements between the pore water and sediment. A redox kinetic model gives similar vertical profiles for iron and the correlated elements as those measured in the field and thus suggests that the relative rates of ferrous iron oxidation and the reductive dissolution of ferric iron in the sediment are important variables determining the distributions of these elements in the wetland pore waters. Received: 31 October 1996 · Accepted: 27 May 1997     

Arsenic and mercury contamination in 31 cores taken in 1965, St. Anna Trough, Kara Sea, Arctic Ocean

 Several cores of 31 collected in 1965 in the St. Anna Trough, Kara Sea, have very high concentrations of Hg and As in surface/near-surface samples. Mercury contents range from 94 to 3915 ppb with a mean of 444 ppb and a baseline value of 314 ppb. Arsenic contents range from 5 to 710 ppm with a mean of 51 ppm and a baseline value of 23 ppm. The Hg and part of the As loading is likely anthropogenic from industrial activities in Siberia via atmospheric emission and deposition onto catchments. This is followed by mobilization into fluvial systems and is added to by industrial effluent discharge. Post-depositional diagenesis from depth in the cores contributes to high As values. A north-flowing bottom current transports Hg- and As-bearing suspended material from the Ob River sea discharge zone to depositional environments in the St. Anna Trough. Dumping of military materials and other wastes into the Kara Sea from the late 1940s to 1991 has likely added to Hg and As loading in the trough sediments. The bioavailability of mercury from suspended materials may be the reason why higher than normal levels of these potentially toxic elements are found in European Arctic seabirds, ringed seal and polar bear. Received: 12 December 1999 · Accepted: 23 May 2000