雅鲁藏布江缝合带西段基性岩地球化学和Sr-Nd-Pb同位素特征：新特提斯洋内俯冲的证据

提要：普兰蛇绿岩位于雅鲁藏布江缝合带西段,面积约650 km2,主要由方辉橄榄岩、含单辉方辉橄榄岩和透镜状纯橄岩组成,缺失堆晶岩和枕状熔岩等洋壳端元。方辉橄榄岩中普遍发育辉绿岩和辉石岩脉,地幔橄榄岩上部被块状玄武岩、玄武质火山碎屑岩、粉砂质泥岩、硅质岩和硅质灰岩覆盖。辉绿岩低K、Ti,球粒陨石标准化REE配分曲线具有N-MORB特征,富集LILE（K、Sr、Rb）,亏损HFSE（U、Th、Nb）,(143Nd/144Nd)t=0.512904~0.512909,εNd(t)=+8.6~+8.7,(87Sr/86Sr)t=0.704893~0.705310,显示俯冲带弧后盆地环境的特征。对比前人研究,认为雅鲁藏布江缝合带普遍存在洋内俯冲作用,但开始俯冲的时间不同：雅鲁藏布江缝合带中西段开始于早白垩世,而东段开始于中侏罗世。     

冀东孤山子超基性岩体矿物岩石地球化学及Sr-Nd-Pb同位素特征

孤山子超基性岩体位于华北克拉通北缘,主要由角闪石岩、辉长岩及辉石岩组成。本文通过角闪石、辉石、尖晶石的探针分析,角闪石岩、辉长岩的岩石地球化学及Sr-Nd-Pb同位素测试分析,研究孤山子超基性岩体地质地球化学特征,探讨其形成的构造环境。电子探针结果表明,角闪石属韭闪石亚族,具幔源特性;辉石属透辉石亚族,具弧堆晶岩特点;尖晶石属富Al尖晶石亚族,大量存在于辉石岩中。岩石地球化学及Sr-Nd同位素特征显示,孤山子超基性岩原岩浆几乎不受壳源物质的影响。低Mg#(0.44~0.55)及较高LREE/HREE(6.54~8.34),表明原岩浆分异程度较高。同时,全岩富集LREE、Rb、Sr、Ba等大离子亲石元素,亏损HREE、Cr、Ni、Nb、Ta、Zr、Hf等高场强元素,Sr、Nd同位素比值小,(87Sr/86Sr)ⅰ=0.70398~0.70430,εNd(t)=-1.60~-2.72,指示源岩为富集型地幔。孤山子超基性岩在晚古生代侵位于陆弧以南的沉积盆地中,地球化学特征介于弧堆晶岩和大陆裂谷岩浆岩之间。结合其大地构造背景及地球化学特征来看,孤山子超基性岩体应形成于陆缘弧后方局部伸展环境。     

西藏日喀则地区雅鲁藏布蛇绿岩地球化学特征及其源区性质

日喀则地区的蛇绿岩是西藏南部雅鲁藏布蛇绿岩带出露较好的蛇绿岩之一。对日喀则地区白朗蛇绿岩的主量、微量元素及Sr-Nd同位素研究表明,其基性岩石为钙碱性系列,主要氧化物具有低钛(0.6%~1.1%)和富镁(6.6%~8.7%)、高铝(15.3%~16.0%),以及烧失量普遍较高(2.8%~4.6%)的特征。岩石微量元素配分型式与N-MORB类似,又具有岛弧玄武岩的地球化学特征,表明蛇绿岩受到了俯冲作用的影响。Sr-Nd同位素特征表明源区为略富集的MORB型地幔。白朗蛇绿岩所代表的特提斯地幔域与印度洋地幔域具有相似的地球化学性质,进一步证实了现今的印度洋继承了特提斯地幔域的地球化学特征。     

班公湖MOR型蛇绿岩Re-Os同位素特征对班公湖-怒江特提斯洋裂解时间的制约

西藏北部班公湖MOR型蛇绿岩主要由角砾状的地幔橄榄岩和玄武岩组成,其中地幔橄榄岩主要是低Cr#尖晶石相含单斜辉石(Cpx)方辉橄榄岩和少量不含Cpx的方辉橄榄岩,玄武岩具有MORB地球化学特点。岩石地球化学特征和二元混合模拟计算表明,含Cpx方辉橄榄岩是由较为亏损的方辉橄榄岩与玄武质熔体发生反应再富集形成的,玄武质熔体和方辉橄榄岩的混合比例为1∶9至1∶4。9个含Cpx方辉橄榄岩样品(含5个重复测试样)的Re和Os含量分别为0.19×10-9~1.49×10-9和2.91×10-9~5.40×10-9,187Re/188Os变化范围为0.169±0.009(2σ)~1.833±0.183(2σ),187Os/188Os变化范围相对较小,介于0.121 13±0.000 44~0.128 53±0.000 36(2σ)之间。含Cpx方辉橄榄岩的Re-Os参考等时线年龄为254±28 Ma。由于不同比例熔体的加入造成橄榄岩具有不同的Re/Os比值,因而不同含Cpx方辉橄榄岩样品具有不同187Os/188Os比值。样品的Re含量与烧失量中的H2O没有相关性,说明蛇纹石化对样品Re-Os体系的影响可以忽略,Re-Os同位素体系在低温地质作用下能够保持相对封闭。参考等时线年龄可能代表亏损方辉橄榄岩与玄武质熔体发生反应的时间,即含Cpx方辉橄榄岩的形成年龄,它表明在该时期特提斯洋经历了一次构造热事件。这一构造岩浆热事件的时间与早期定义的班公湖-怒江特提斯洋的裂解时间晚二叠世至早三叠世较为一致,推测本文MOR型蛇绿岩地幔橄榄岩的Re-Os同位素年龄可能代表班公湖-怒江特提斯洋开始裂解的时间。     

昌宁-孟连缝合带干龙塘-弄巴蛇绿岩地球化学及Sr-Nd-Pb同位素组成研究

本文对三江古特提斯昌宁-孟连带中段弄巴-干龙塘蛇绿混杂岩进行了详细的主量、微量元素及Sr-Nd-Pb同位素地球化学研究。结果表明,弄巴玄武岩包括拉斑系列和碱性系列,弄巴拉斑玄武岩具有高TiO2和低K2O的特征,(La/Yb)N介于1.87～2.38之间,岩石的Sr-Nd-Pb同位素组成和典型MORB十分相似,结合岩石较高的Th/Yb和低的Zr/Nb值,可以认为弄巴拉斑玄武岩具有富集型洋脊玄武岩(E-MORB)的特征,可能起源于富集的地幔源区或是亏损地幔源区和地幔柱发生交代作用的结果。弄巴碱性玄武岩具有较高的TiO2(2.38%)和K2O(2.37%)含量,(La/Yb)N=11.19,富集轻稀土,表现出典型的碱性OIB的特征,可能是大洋板内热点浅部熔融的产物。干龙塘拉斑玄武岩具有高TiO2、Mg#,低K2O和亏损轻稀土等特征,表现出N-MORB的地球化学特征,岩石的Sr-Nd-Pb与MORB相似,表明岩石起源于亏损的地幔源区。     

内蒙古集宁新生代玄武岩的地幔源区特征：元素及Sr-Nd-Pb同位素地球化学证据

内蒙古集宁玄武岩区位于华北克拉通北缘,东邻汉诺坝玄武岩区。由亚碱性的拉斑玄武岩及碱性的橄榄玄武岩、碧玄岩和碱玄岩组成。玄武岩的SiO2与TiO2含量分别为44．10～52．27wt．％和1．57～2．95wt．％,Mg^#（43—63）及Ni含量（27～210ppm）变化范围较大。集宁玄武岩的微量元素原始地幔标准化曲线及REE球粒陨石标准化曲线与OIB相似,Sr、Nd同位素比值显示了较汉诺坝玄武岩富集的特征。研究表明,虽然集宁玄武岩浆经历了一定程度的橄榄石、单斜辉石的分离结晶作用,但微量元素及Sr、Nd、Ph同位素特征排除了幔源岩浆在喷发到地表过程中受到地壳物质显著混染的可能性。^143Nd／^144 Nd ^87Sr／^86Sr vs．^206Ph／^204Pb的线性相关性表明,集宁玄武岩至少来自两个地幔端元组分：EMI和PREMA,且端元组分与汉诺坝玄武岩相似。尖晶石二辉橄榄岩的低程度部分熔融（2～5％）熔体与石榴石二辉橄榄岩更低程度部分熔融（〈2％）熔体的混合,可以解释集宁玄武岩稀土元素的变化特征。推测EMI位于岩石圈地幔之内且源区深度〈70km,PREMA则来自软流圈地幔。集宁碱性玄武岩与亚碱性玄武岩之间的地球化学差异,可能只是来自岩石圈地幔的EMI型熔体和来自软流圈地幔的PREMA型熔体在形成玄武岩浆时参与混合的比例不同,暗示该地区的岩石圈地幔与软流圈地幔之间经历了强烈的相互作用。集宁玄武岩与汉诺坝玄武岩相似的Sr、Nd、Pb同位素比值及相关性,说明它们具有相似的地幔源区,汉诺坝玄武岩的地球化学差异同样可以用EMI与PREMA组分对岩浆贡献程度的不同来解释。     

内蒙古温都尔庙和巴彦敖包-交其尔蛇绿岩的元素与同位素地球化学：对古亚洲洋东部地幔域特征的限制

内蒙古中部发育的三条蛇绿岩带是华北板块和西伯利亚板块之间的缝合带。本文系统研究了其中的温都尔庙和巴彦敖包．交其尔两个蛇绿岩带中变质玄武岩的元素和Sr、Nd、Pb同位素地球化学。苏右旗温都尔庙碱性玄武岩为轻稀土富集型;岩石具有板内和大陆裂谷区玄武岩的特征,可能代表了600Ma左右,温都尔庙地区开始发育的新洋盆。采自苏左旗的巴彦敖包．交其尔玄武岩分为两类,一类呈现轻稀土富集型,呈洋岛玄武岩特征;另一类具有明显的Nb、Ta负异常,显示大洋岛孤玄武岩特征。洋岛玄武岩的存在表明古亚洲洋曾经发育洋盆,大洋岛弧玄武岩的存在表明古亚洲洋内部有大洋岩石圈之间的俯冲。将本文的古亚洲洋洋岛玄武岩与中国西南地区的特提斯洋岛玄武岩进行系统的元素和同位素地球化学特征对比表明,古亚洲洋的洋岛玄武岩显示高U／Pb（HU）和北大西洋和太平洋省的特征,而特提斯洋岛玄武岩属于印度洋省。这些说明古亚洲洋地幔域与特提斯地幔域是两个独立的构造域,它们代表了长期演化的两个不同的地幔地球化学域。     

西藏东巧蛇绿岩的地球化学特征及其形成的构造环境

西藏东巧蛇绿岩主要由变质橄榄岩、辉长岩及玄武岩等组成。变质橄榄岩以富Mg、Fe、Cr,贫Ti、ΣREE为特征。辉长岩和玄武岩的主量元素、微量元素特征显示其具有扩张洋脊拉斑玄武岩的地球化学特征,其中高场强元素Nb、Ta、zr、Hf等亏损,大离子亲石元素Rb、sr、Ba等相对富集;在球粒陨石标准化稀土元素配分模式图上为LREE亏损的平坦型,无负Eu异常,与洋中脊玄武岩的特征类似。根据其地球化学属性,推测该区蛇绿岩形成于大洋盆地扩张的构造环境。     

西藏改则县多龙SSZ型蛇绿岩的锆石U-Pb年龄、岩石地球化学及Sr-Nd同位素特征:班公湖-怒江洋晚二叠世洋内俯冲的证据

西藏改则县多龙矿集区分布着大量的SSZ型蛇绿岩残片,是班公湖-怒江蛇绿岩带的重要组成部分,本文对代表性辉绿(玢)岩进行了锆石U-Pb定年、岩石地球化学及Sr-Nd同位素分析,获得辉绿玢岩加权平均年龄为252.1±1.5Ma(MSWD=0.09,n=33),表明多龙SSZ型蛇绿岩形成于晚二叠世。岩石烧失量普遍较高(1.57%～5.23%)的特征,表明样品普遍遭受蚀变;而且具有富硅、高铝、低MgO及低Mg~#值(36.8～63.1)的特征,说明其经历过一定程度的分离结晶作用。多龙辉绿岩和辉绿玢岩富集大离子亲石元素(LILE:Rb、Cs、K、Sr、P、Pb),亏损高场强元素(HFSE:Ta、Nb、Ti、Zr、Hf);稀土元素总量为23.27×10~(-6)～58.95×10~(-6),δEu为0.83～1.35,(La/Yb)_N为0.66～1.30,具有与岛弧拉斑玄武岩类似的稀土元素和总体一致的微量元素特征。岩石(~(87)Sr/~(86)Sr)_i值为0.707345～0.708748,(~(143)Nd/~(144)Nd)_i值为0.512669～0.512705,t_(DM2)值为305～456Ma,ε_(Nd)(t)值为+6.9～+8.8,表明其岩浆源区为亏损地幔源区,其地球化学成分具有洋内弧的特征,暗示其可能是洋内俯冲作用的产物。综合分析认为,班-怒洋壳于晚二叠世时(ca.252Ma)在板块汇聚边缘发生了类似西太平洋Izu-Bonin-Mariana的洋内俯冲作用,形成兼具MOR蛇绿岩亲缘性和俯冲带SSZ蛇绿岩地球化学印记的双重属性的多龙辉绿岩及辉绿玢岩的母岩浆;母岩浆经过结晶分异、上升侵位,最终于洋内俯冲带之上的弧前盆地环境下形成多龙辉绿岩和辉绿玢岩。     

西藏纳木错西岸蛇绿岩的地球化学特征及其形成环境

西藏纳木错西岸蛇绿岩主要由变质橄榄岩、辉长辉绿岩及玄武岩等组成。变质橄榄岩以富Mg、贫Ti、贫REE元素为特征。辉绿岩和玄武岩的主量元素、微量元素特征显示其含有洋脊拉斑玄武岩和岛弧拉斑玄武岩的双重成分,其中高场强元素Nb、Ta、Zr、Hf等亏损．大离子亲石元素Rb、Sr、Ba等相对富集,具岛弧玄武岩的特点;在球粒陨石标准化稀土元素配分模式图上为LREE亏损的平坦型,无负Eu异常,与洋中脊玄武岩的特征类似。通过与典型地区作对比并应用构造环境判别图解,推测该区蛇绿岩形成于弧后盆地的构造环境。     

Platinum-group elemental geochemistry of mafic and ultramafic rocks from the Xigaze ophiolite, southern Tibet

The Xigaze ophiolite in the central part of the Yarlung–Zangbo suture zone, southern Tibet, has a well-preserved sequence of sheeted dykes, basalts, cumulates and mantle peridotites at Jiding and Luqu. Both the basalts and diabases at Jiding have similar compositions with SiO₂ ranging from 45.9 to 53.5 wt%, MgO from 3.1 to 6.8 wt% and TiO₂ from 0.87 to 1.21 wt%. Their Mg^#s [100Mg/(Mg + Fe)] range from 40 to 60, indicating crystallization from relatively evolved magmas. They have LREE-depleted, chondrite-normalized REE diagrams, suggesting a depleted mantle source. These basaltic rocks have slightly negative Nb- and Ti-anomalies, suggesting that the Xigaze ophiolite represents a fragment of mature MORB lithosphere modified in a suprasubduction zone environment. The mantle peridotites at Luqu are high depleted with low CaO (0.3–1.2 wt%) and Al₂O₃ (0.04–0.42 wt%). They display V-shaped, chondrite-normalized REE patterns with (La/Gd)_N ratios ranging from 3.17 to 64.6 and (Gd/Yb)_N from 0.02 to 0.20, features reflecting secondary metasomatism by melts derived from the underlying subducted slab. Thus, the geochemistry of both the basaltic rocks and mantle peridotites suggests that the Xigaze ophiolite formed in a suprasubduction zone.Both the diabases and basalts have Pd/Ir ratios ranging from 7 to 77, similar to MORB. However, they have very low PGE abundances, closely approximating the predicted concentration in a silicate melt that has fully equilibrated with a fractionated immiscible sulfide melt, indicating that the rocks originated from magmas that were S-saturated before eruption. Moderate degrees of partial melting and early precipitation of PGE alloys explain their high Pd/Ir ratios and negative Pt-anomalies. The mantle peridotites contain variable amounts of Pd (5.99–13.5 ppb) and Pt (7.92–20.5 ppb), and have a relatively narrow range of Ir (3.47–5.01 ppb). In the mantle-normalized Ni, PGE, Au and Cu diagram, they are relatively rich in Pd and depleted in Cu. There is a positive correlation between CaO and Pd. The Pd enrichment is possibly due to secondary enrichment by metasomatism. Al₂O₃ and Hf do not correlate with Ir, but show positive variations with Pt, Pd and Au, indicating that some noble metals can be enriched by metasomatic fluids or melts carrying a little Al and Hf. We propose a model in which the low PGE contents and high Pd/Ir ratios of the basaltic rocks reflect precipitation of sulfides and moderate degrees of partial melting. The high Pd mantle peridotites of Xigaze ophiolites were formed by secondary metasomatism by a boninitic melt above a subduction zone.     

新疆北部乌恰沟地区镁铁质侵入岩的年代学、地球化学和Sr-Nd-Pb同位素组成：对地幔源区特征和深部过程的约束

阿尔泰造山带东段的乌恰沟地区发育大量镁铁质侵入岩(岩脉或小岩体),包括闪长玢岩和具堆积结构的角闪辉长岩和橄榄辉长岩。锆石SHRIMP U-Ph同位素定年结果说明这些镁铁质岩浆的侵位时间为257．4±5．3Ma,与峨眉山玄武岩相近(259±3Ma)。在微量元素原始地幔标准化图上,它们共同的特征是富集大离子亲石元素,亏损Nb和Ta,具K和Pb的正异常,LREE相对HREE富集,即具弧火山岩的地球化学特征。同时它们之间还存在互补的地球化学特征,如闪长玢岩存在Ba、Sr、Eu、P和Ti的负异常,橄榄辉长岩具有Ba、Sr、Eu、P的正异常,而角闪辉长岩具有Ti的正异常。如果扣除围岩混染和后期流体交代的影响,这些岩石的Sr-Nd-Pb同位素组成基本一致,因此闪长玢岩和两种辉长岩分别代表同源岩浆因结晶分离作用形成的演化岩浆和堆晶岩。乌恰沟晚二叠世镁铁质侵入岩和新疆北部早二叠世与铜镍矿有关的基性-超基性杂岩体都具有与弧火山岩相似的地球化学特征,反映了被俯冲改造的陆下岩石圈地幔的地球化学特征。但是与后者相比,前者的Mg~#值、ε_(Nd)(t)值和La/Nb比明显偏低,暗示存在软流圈地幔来源物质的显著贡献。综合阿尔泰乌恰沟地区镁铁质侵入岩的年代学、地球化学和同位素组成特征,我们推测该区在晚二叠世存在地幔柱与岩石圈地幔之间的相互作用。     

Geochemical and Nd–Pb isotopic characteristics of the Tethyan asthenosphere: implications for the origin of the Indian Ocean mantle domain

It is unclear why the Pb, Nd, and Sr isotopic composition of the modern mid-ocean ridge basalts (MORB) from the Indian Ocean is different from that of the North Atlantic and Pacific Oceans. A possible explanation for this is that the Indian MORB-type isotopic signature is a long-lived regional feature of the mantle, as evidently shown by the isotopic composition of the 350 Ma MORB-like Mian-Lue northern ophiolite, which was formed in the same region presently occupied by the Indian Ocean. However, this hypothesis is in conflict with the lack of Indian MORB-type isotopic signature in a number of 150 Ma Tethyan and Indian Ocean crusts. To further constrain the origin of the Indian MORB-type isotopic signature, we analyze the geochemical and Pb, Nd, and Sr isotopic composition of representative mafic rocks from four Tethyan ophiolites ranging in age from 90 to 360 Ma. The Sr isotopic composition of the samples is unreliable due to alteration, but the age-corrected Nd and Pb isotopic ratios and geochemical data indicate that these Tethyan rocks were derived from a geochemically depleted asthenospheric source that had a clear Indian MORB-type isotopic signature. We therefore conclude that the bulk of the Indian suboceanic mantle was most probably inherited from the Tethyan asthenosphere. A few regions in both the Tethyan and Indian Oceans, however, are most probably underlain by Pacific and North Atlantic MORB-type mantle (and vice-versa) because of the flow of the asthenosphere in response to tectonic plate reorganizations that lead to openings and closures of ocean basins. The Indian MORB-type isotopic signature of the western Pacific marginal basin crusts could be due to either flow of the Indian Ocean mantle into the western Pacific or to endogenous production of such an isotopic signature from delaminated East-Asian sublithospheric materials during closure of the Tethys Ocean.     

西藏雅鲁藏布江缝合带中段日喀则地幔橄榄岩中发现金刚石等异常矿物

本文报道了雅鲁藏布江缝合带中段日喀则蛇绿岩地幔橄榄岩中发现与该带东西段蛇绿岩岩体中相似的金刚石和特殊地幔矿物群。日喀则地幔橄榄岩体以方辉橄榄岩为主,含少量二辉橄榄岩和纯橄岩,辉石岩和辉长岩呈脉状产在方辉橄榄岩中。通过重砂分选实验,在465kg的方辉橄榄岩大样中发现了30余种特殊矿物群,包括金刚石、自然金、自然铬、自然铜等自然元素矿物类;碳硅石等碳化物类;方铁矿、赤铁矿、磁铁矿、刚玉、铬尖晶石、金红石、锡石、黑钨矿等氧化物类;镍黄铁矿、方铅矿、辉钼矿、辉锑矿、闪锌矿、毒砂等硫化物类;Ag-Au等合金矿物类;橄榄石、辉石、锆石等硅酸盐岩类;白钨矿等钨酸盐岩类;萤石等氟化物类。金刚石和自然金、自然铬、自然铜连同碳硅石的发现表明岩体存在强还原环境,这套特殊矿物组合指示日喀则地幔橄榄岩可能与雅鲁藏布缝合带其他蛇绿岩一样,经历了深地幔演化过程。     

西藏日喀则蛇绿岩中石榴角闪岩的矿物、岩石地球化学特征

西藏雅鲁藏布蛇绿岩带中段日喀则地区的白朗蛇绿混杂岩中,存在作为变质底板的石榴角闪岩。本文对其进行了矿物学、变质温压条件和岩石地球化学研究。根据岩相学和矿物化学研究,日喀则石榴角闪岩经历了四个变质阶段,矿物组合分别为:Am_1+Pl_1+Ep_1+Ttn(M1);Grt-c+Cpx-e+Ep_2+Pl_2+Rt(M2);Grt-r+Ep_3/Czo_3+Cpx-l+Am_3+Pl_3+Ttn(M3)和Prh+Ab+Czo+Chl+Cal(M4)。根据SAFMCNHO体系矿物组合演化的视剖面图,结合传统的地质温压计,估算出峰期前的温压条件为560~620℃/9.1~9.8kbar;峰值为830~870℃/18.0~22.0kbar,退变质阶段保留了640~680℃/10.7~14.9kbar的温压条件,最终止于葡萄石-绿纤石的前绿片岩相变质条件;得出一条逆时针的P-T轨迹。白朗变质底板的岩性可分为三类,即石榴角闪岩、角闪辉石岩和单辉角闪岩。三种岩性具有相似的地球化学性质:主量元素具有低钛(0.92%~1.29%)、低钾(0.26%)、低钠(0.24%~2.46%)的特征。稀土元素和微量元素特征与N-MROB相似,富集大离子亲石元素(Rb、Ba、U),亏损部分高场强元素(Nb、Ti、Zr、Hf),表现出白朗蛇绿混杂岩中的石榴角闪岩等与洋中脊玄武岩有亲缘性,且叠加有俯冲上板片SSZ环境特征。白朗石榴角闪岩的存在表明日喀则蛇绿岩在形成后不久就发生了构造就位,体现了大洋内部俯冲/侵位事件。     

Melt/mantle mixing produces podiform chromite deposits in ophiolites: Implications of Re-Os systematics in the Dongqiao Neo-tethyan ophiolite, northern Tibet

Podiform chromite deposits occur in the mantle sequences of many ophiolites that were formed in supra-subduction zone (SSZ) settings. We have measured the Re-Os isotopic compositions of the major chromite deposits and associated mantle peridotites of the Dongqiao Ophiolite in the Bangong-Nujiang suture, Tibet, to investigate the petrogenesis of these rocks and their genetic relationships.The ¹⁸⁷Os/¹⁸⁸Os ratios of the chromite separates define a narrow range from 0.12318 to 0.12354, less variable than those of the associated peridotites. Previously-reported ¹⁸⁷Os/¹⁸⁸Os ratios of the Os-rich alloys enclosed in the chromitites define two clusters: 0.12645 ± 0.00004 (2 s; n = 145) and 0.12003 to 0.12194. The ultra-depleted dunites have much lower ¹⁸⁷Os/¹⁸⁸Os (0.11754, 0.11815), and the harzburgites show a wider range from 0.12107 to 0.12612. The average isotopic composition of the chromitites (¹⁸⁷Os/¹⁸⁸Os: 0.12337 ± 0.00001) is low compared with the carbonaceous chondrite value (¹⁸⁷Os/¹⁸⁸Os: 0.1260 ± 0.0013) and lower than the average value measured for podiform chromitites worldwide (0.12809 ± 0.00085). In contrast, the basalts have higher ¹⁸⁷Os/¹⁸⁸Os, ranging from 0.20414 to 0.38067, while the plagioclase-bearing harzburgite and cumulates show intermediate values of ¹⁸⁷Os/¹⁸⁸Os (0.12979 ~ 0.14206). Correspondingly, the basalts have the highest ¹⁸⁷Re/¹⁸⁸Os ratios, up to 45.4 ± 3.2, and the chromites have the lowest ¹⁸⁷Re/¹⁸⁸Os ratios, down to 0.00113 ± 0.00008. We suggest that melts/fluids, derived from the subducting slab, triggered partial melting in the overlying mantle wedge and added significant amounts of radiogenic Os to the peridotites. Mass-balance calculations indicate that a melt/mantle ratio of approximately 15:1 (melt: ¹⁸⁷Re/¹⁸⁸Os: 45.4, ¹⁸⁷Os/¹⁸⁸Os: 0.34484; mantle peridotite: ¹⁸⁷Re/¹⁸⁸Os: 0.0029, ¹⁸⁷Os/¹⁸⁸Os: 0.11754) is necessary to increase the Os isotopic composition of the chromitite deposits to its observed average value. This value implies a surprisingly low average melt/mantle ratio during the formation of the chromitite deposits. The percolating melts probably were of variable isotopic composition. However, in the chromitite pods the Os from many melts was pooled and homogenized, which is why the chromitite deposits show such a small variation in their Os isotopic composition. The results of this study suggest that the ¹⁸⁷Os/¹⁸⁸Os ratios of chromitites may not be representative of the DMM, but only reflect an upper limit. Importantly, the Os-isotope compositions of chromitites strongly suggest that such deposits can be formed by melt/mantle mixing processes.     

日喀则弧前盆地碎屑铬尖晶石地球化学与物源判别

该工作在藏南日喀则弧前盆地砂岩中发现了大量碎屑铬尖晶石。电子探针化学成分分析显示这些铬尖晶石具有高铬(铬指数Cr#为0.52~0.89)、低Fe3+含量(Fe3+/ Fe2+<0.5)、低TiO2含量(多小于0.2%)的特征,指示这些铬尖晶石来源于与洋壳俯冲作用有关的橄榄岩和火成岩,因此弧火山岩和SSZ型蛇绿岩套是其最可能的物源。考虑到日喀则弧前盆地的碎屑物主要来源于拉萨地体,而拉萨地体北侧的班公-怒江缝合带的碎屑物质不可能穿过晚白垩世时期已经隆起的冈底斯岩浆弧。笔者推测,铬尖晶石可能来自于冈底斯弧和拉萨地体内部已经消失的古蛇绿岩套。     

藏东南措美大火成岩省中OIB型镁铁质岩的全岩地球化学和锆石Hf同位素

西藏南东部新识别出来的措美大火成岩省的地幔柱头部物质成分尚未得到很好的约束。为探讨此问题,在全岩地球化学数据基础上,本文首次报道了藏东南措美大火成岩省中机布淌、打隆、措美和哲古错OIB型镁铁质岩的锆石Hf同位素和微量元素数据。本文报道的OIB型镁铁质岩包括碱性(组Ⅰ)和亚碱性(组Ⅱ)系列的辉长岩和辉绿岩,以岩墙或岩床的形式产出。这些镁铁质岩具有高的TiO₂(2.61%～4.07%)和P₂O₅(0.32%～0.51%)含量,富集轻稀土元素和高场强元素,地球化学特征类似于OIB。全岩微量元素地球化学指标显示组Ⅰ样品没有或很少受到地壳混染,组Ⅱ样品经历了较高程度的地壳混染。组Ⅰ中一件样品(JBT03-1)具有变化范围大的锆石ε_Hf(t)值(-4.8～+5.3),可能暗示其受到了地壳和/或岩石圈地幔物质的混染。本文结果表明锆石Hf同位素比全岩地球化学数据能够更为有效地识别基性岩浆是否受到地壳和/或岩石圈地幔物质混染。措美大火成岩省中的OIB型镁铁质岩样品(组Ⅰ和组Ⅱ),具有不同于俯冲带镁铁质岩和洋壳镁铁质岩的锆石稀土元素配分型式和锆石Ti温度,这可能是岩浆源区温度和成分不同的结果。综合考虑全岩地球化学和锆石Hf同位素指标,本文提出未受到地壳或岩石圈地幔混染的打隆镇辉长岩体(以组I中的DL01样品为代表)很可能代表了措美大火成岩省纯的地幔柱头部物质成分[⁸⁷Sr/⁸⁶Sr_(t)=0.7047,ε_Nd(t=+1.5,ε_Hf(t=+2.1～+5.7]。这些成分与代表白垩纪Kerguelen地幔柱头部物质的Site 1138和Bunbury Casuarina玄武岩非常相似,可能指示措美大火成岩省中的OIB型镁铁质岩本身就是Kerguelen地幔柱头部物质发生减压熔融的产物。     

西藏仲巴县穷果北部日喀则弧前盆地地层再认识

通过对区内发育完好并保留下来的白垩纪—始新世地层的研究,海相白垩纪日喀则群自下而上可划分为昂仁组、帕达那组、曲贝亚组;古新世—始新世错江顶群包括下部曲下组和上部加拉孜组,整合覆于错江顶群之上的“如角藏布砂砾岩”为弧前盆地封盆粗碎屑岩。日喀则群与错江顶群在沉积学、地层古生物学及构造地质学诸方面的差异揭示了两群之间,更确切地说,曲贝亚组与曲下组之间呈不整合接触,该不整合形成于坎潘期—马斯特里赫特期与丹尼期之间。该区日喀则弧前盆地完整的地层序列全面再现了印度板块向欧亚板块俯冲过程,两板块的碰撞和新特提斯洋的彻底关闭发生在弧前盆地封盆粗碎屑岩沉积结束以后,这比原来认识的要晚些。