Large-scale Hercynian west-directed tectonics in southeastern Sardinia (Italy)

Widespread Hercynian west-directed thrusting and west-facing folds, until now only reported in a limited area, are ubiquitous in the Sarrabus unit, southeastern Sardinia. Intense thrusting and imbrication in the higher tectonic levels of the Sarrabus unit potentially originated during west-directed thrusting of higher tectonic units, which have been eroded.The floor thrust of the Sarrabus unit, the Villasalto thrust, is a westdirected thrust that places the Sarrabus unit above the Gerrei and Meana Sardo units. East-west shortening in southeastern Sardinia followed north-south shortening in central Sardinia and internal deformation in the Castello Medusa-Riu Gruppa, Gerreì, Meana Sardo and Barbagia units. After restoration of movement along the Villasalto thrust, the Sarrabus unit is located east of the Gerrei and Meana Sardo unit. Therefore, it cannot be directly correlated with the Meana Sardo or the Barbagia units.     

Large-scale Hercynian West-directed tectonics in southeastern Sardinia (Italy)

Abstract

Widespread Hercynian west-directed thrusting and west-facing folds, until now only reported in a limited area, are ubiquitous in the Sarrabus unit, southeastern Sardinia. Intense thrusting and imbrication in the higher tectonic levels of the Sarrabus unit potentially originated during west-directed thrusting of higher tectonic units, which have been eroded. The floor thrust of the Sarrabus unit, the Villasalto thrust, is a west- directed thrust that places the Sarrabus unit above the Gerrei and Meana Sardo units. East-west shortening in southeastern Sardinia followed north-south shortening in central Sardinia and internal deformation in the Castello Medusa-Riu Gruppa, Gerrei, Meana Sardo and Barbagia units. After restoration of movement along the Villasalto thrust, the Sarrabus unit is located east of the Gerrei and Meana Sardo unit. Therefore, it cannot be directly correlated with the Meana Sardo or the Barbagia units. © Elsevier, Paris     

Multi-stage metamorphic re-equilibration in eclogitic rocks from the Hercynian basement of NE Sardinia (Italy)

Summary Eclogitic rocks are hosted within gneisses and migmatites of the Hercynian basement of NE Sardinia. They are characterized by two compositional layers: garnet-pyroxene rich-layers and amphibole-plagioclase layers. The former contain structural, mineralogical and compositional relics of eclogite facies re-equilibration. Four stages of evolution have been identified: an eclogite stage, a granulite stage and a retrograde amphibolite to greenschist stage. A possible pre(?)-eclogite stage is documented by inclusions of euhedral tschermakitic amphibole + zoisite within the core of garnet. This early stage was followed by an increase in pressure under which the eclogite climax developed (T up to 700 °C, P =13-15 kbar), as documented by omphacite inclusions towards the rim of garnet.Characteristic mineral reactions after the eclogitic stage are: omphacite diopside + plagioclase (symplectite) and garnet orthopyroxene + plagioclase. These reactions testify the presence of a granulite stage during which the peak of metamorphism was reached (T up to 870'C, P 10 kbar). The orthopyroxene cummingtonite + quartz and garnet + diopside hornblende + plagioclase (kelyphite) transformations indicate extensive amphibolite retrogression (T = 550650 °C, P = 3-7 kbar). Finally, actinolite and chlorite developed (greenschist stage) at falling temperature and pressure (T = 300-400 °C, P < 2-3 kbar).

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Mehrstufige metamorphe Reequilibration eklogitischer Gesteine aus dem hercynischen Basement NE Sardiniens (Italien)

Zusammenfassung Eklogitische Gesteine kommen in Gneisen und Migmatiten des hereynischen Basements in NE Sardinien vor. Sie sind durch einen modalen Zweitagenbau von einerseits Granat-Pyroxen andererseits Amphibol-Plagioklas charakterisiert. In ersteren sind Relikte einer strukturellen, mineralogischen und mineralchemischen Reequilibration unter eklogitfaziellen Bedingungen enthalten. Vier Entwicklungstadien sind unterscheidbar: ein Eklogit-, ein Granulit-, sowie ein retrogrades Amphibolit- und Grünschieferstadium. Ein mögliches prä(?)-eklogitisches Stadium ist durch die Einschlüsse von tschermakitischem Amphibol + Zoisit in Granatkernen angedeutet. Auf dieses Frühstadium folgte, dokumentiert durch Omphaziteinschlüsse im Granatrandbereich, Druckzunahme und es wurden eklogitfazielle Bedingungen (T bis zu 700 °C, P = 13-15 kbar) erreicht.Charakteristische Mineralreaktionen nach der Eklogitbildung sind Omphazit Diopsid + Plagioklas (Symplektite) und Granat Orthoyroxen + Plagioklas. Diese Reaktionen belegen das Vorliegen eines Granulitstadiums, während dem der Metamorphosehöhepunkt (T bis 870°C, P 10 kbar) erreicht wurde. Die Umwandlungen von Orthopyroxen Cummingtonit + Quarz und Granat + Diopsid Hornblende + Plagioklas (Kelyphit) belegen eine intensive retrograde amphibolitfazielle Überprägung (T = 550-650°C, P = 3-7 kbar). Aktinolith und Chlorit (Grünschieferstadium) bildeten sich bei weiter fallenden Temperaturen und Drucken (T = 300-400 °C, P < 2-3 kbar).

     

Petrology and mineralogy of granulite-facies mafic xenoliths (Sardinia, Italy): Evidence for KCl metasomatism in the lower crust

Here new mineralogical data is presented on the occurrence of K-feldspar in granulite-facies metagabbronorite xenoliths found in recent alkaline lavas from Western Sardinia, Italy. The xenoliths originated from the underplating of variably evolved subduction-related basaltic liquids, which underwent cooling and recrystallisation in the deep crust (T = 850–900 °C, P = 0.8–1.0 GPa). They consist of orthopyroxene + clinopyroxene + plagioclase porphyroclasts (An = 50–66 mol%) in a granoblastic, recrystallised, quartz-free matrix composed of pyroxene + plagioclase (An = 56–72 mol%) + Fe–Ti oxides ± K-feldspar ± biotite ± fluorapatite ± Ti-biotite. Texturally, the K-feldspar occurs in a variety of different modes. These include: (1) rods, blebs, and irregular patches in a random scattering of plagioclase grains in the form of antiperthite; (2) micro-veins along plagioclase–plagioclase and plagioclase–pyroxene grain rims; (3) myrmekite-like intergrowths with Ca-rich plagioclase along plagioclase–plagioclase grain boundaries; and (4) discrete anhedral grains (sometimes microperthitic). The composition of each type of K-feldspar is characterized by relatively high albite contents (16–33 mol%). An increasing anorthite content in the plagioclase towards the contact with the K-feldspar micro-vein and myrmekite-like intergrowths into the K-feldspar along the plagioclase–K-feldspar grain boundary are also observed. Small amounts of biotite (TiO₂ = 4.7–6.5 wt.%; F = 0.24–1.19 wt.%; Cl = 0.04–0.20 wt.%) in textural equilibrium with the granulite-facies assemblage is present in both K-feldspar-bearing and K-feldspar-free xenoliths. These K-feldspar textures suggest a likely metasomatic origin due to solid-state infiltration of KCl-rich fluids/melts. The presence of such fluids is supported by the fluorapatite in these xenoliths, which is enriched in Cl (Cl = 6–50% of the total F + Cl + OH). These lines of evidence suggest that formation of K-feldspar in the mafic xenoliths reflects metasomatic processes, requiring an external K-rich fluid source, which operated in the lower crust during and after in-situ high-T recrystallisation of relatively dry rocks.     

Rare earth elements in waters from the albitite-bearing granodiorites of Central Sardinia, Italy

With the aim of contributing to the knowledge of the geochemical behaviour and mobility of the rare earth element (REE) in the natural water systems, the ground and surface waters of the Ottana-Orani area (Central Sardinia, Italy) were sampled. The study area consists of albititic bodies included in Hercynian granodiorites. The waters have pH in the range of 6.0-8.6, total dissolved solid (TDS) of between 0.1 and 0.6 g/l, and major cation composition dominated by Ca and Na, whereas predominant anions are Cl and/or HCO₃.The pH and the major-element composition of the waters are the factors affecting the concentration of REE in solution. The concentrations of ∑REE+Y in the samples filtered at 0.4 μm vary between 140 and 1600 ng/l, with La of between 14 and 314 ng/l, and Yb of between <6 and 12 ng/l. A negative Ce anomaly, especially marked at high pH, is observed in the groundwaters. The surface waters show lower REE concentrations, which are independent of pH, and negligible Ce anomaly.Speciation calculations, carried out with the EQ3NR computer program, showed that the complexes with the CO₃²⁻ ligand are the dominant REE species at pH in the range of 6.7-8.6. The REE³⁺ ions dominate the speciation at pH <6.7 and only in the light REE (LREE).The relative concentrations of REE in water roughly reflect those in the aquifer host rocks. However, when concentrations of REE in water are normalised relative to the parent rocks, a preferential fractionation of heavy REE (HREE) into the water phase can be observed, suggesting the greater mobility and stability of HREE in aqueous solution.     

The abandoned Pb-Zn mine of Ingurtosu, Sardinia (Italy)

The Ingurtosu Pb-Zn mine, situated in the southwestern part of Sardinia, has been in production from the beginning of the last century up to 1968. The orebody consists of galena/sphalerite/barite/siderite veins in Ordovician arenaceous and phyllitic sediments, near the contact with a Hercynian batholith.

Abundant tailings were collected in a pond from which they were discharged during the winter months into the sea via the Rio Naracauli stream. Today this area of outstanding scenic beauty, is degraded by tailings and waste rock scattered all along the stream.

Material derived from mining activities was studied for grain size, mineralogical and geochemical composition. The Rio Naracauli was sampled over a length of ten kilometers at regular intervals.

The results can be summarized as follows: (a) tailings contain a varying, but often quite high, percentage of Pb; lower percentages were found for Zn and Cd; (b) a sharp increase in dissolved Zn, Cd and Pb was observed in the Rio Naracauli where it leached the tailings; and (c) tailings and waste rocks should be recycled or revegetated.     

The structural evolution of the Asinara Island (NW Sardinia,Italy)

The metamorphic basement of the Asinara island represents a key area of the Sardinia Variscan segment, because it displays an almost complete cross-section through the inner part of the Sardinia Variscan belt, where different tectono-metamorphic complexes have been juxtaposed along narrow belts of high-strain concentration. Detailed field mapping coupled with preliminary studies on the structural and metamorphic features of this small island, allow to draw a better picture of the structural frame issued from the Variscan collision in the inner zone of the belt. Three deformation phases related to crustal thickening in a compressive and transpressive, partitioned tectonic regime, followed by a later phase of extensional deformation have been recognised. In spite of a general HT/LP metamorphic overprint, linked to the post-collisional deformation phases, a relic Barrovian zoneography is still detectable. The Barrovian assemblages are preto syn-kinematic with respect to the D2 deformation phase, and pre-date the third, contractional tectonic event.

The HT/LP assemblage indicates a static growth of weakly deformed by the last deformation events. The complex geometry of the fabric associated to the D2 and D3 deformation events suggests an heterogenous deformation history with a monoclinic geometry characterized by switching of the stretching lineation orientation and a contrasting sense of displacement, probably controlled by a northward partitioned pure shear.     

High-silica zeolites in pyroclastic flows from Central Sardinia (Italy): clues on genetic processes and reserves from a mineralogical study

Mineralogy and Petrology - The island of Sardinia (Italy) presents some of the most interesting zeolite ores in Europe, most of which are associated with old pyroclastic deposits. In particular,...     

Distribution of heavy metals in the Piscinas beach sediments (SW Sardinia, Italy)

We have studied sediments of the Piscinas beach (SW Sardinia, Italy), which is supplied by two streams that wash mine dumps of abandoned lead and zinc mines at Montevecchio and Ingurtosu, situated inland from the supply basin of the beach itself. A study of the texture, mineralogy and geochemistry of the sediments was conducted for the purpose of assessing the possible influence of the mine waste on the composition of the sediments, looking for any anomalous enrichments in heavy metals. Furthermore, to evaluate and quantify metal release into the sea, samples of Posidonia oceanica, a bioaccumulator marine plant, were also examined. The results indicate that the distribution of heavy metals in the foreshore sediments is particularly affected by the contribution of the streams, while in the shoreface the distribution is affected by the currents that disperse the sediments both out to sea and southwards. The metal contents of the Posidonia oceanica are correlated with the different stages of activity of the mines. Received: 28 January 1998 · Accepted: 22 April 1998     

高武地区过铝花岗岩特征与构造环境

高武地区的过铝花岗岩主要为二长花岗岩及正长花岗岩,山德指数ALI>1 1,标准矿物刚玉分子(c)普遍>3,出现石榴石、原生白云母矿物组合,δ18O‰>10、87Sr/86Sr>0 707,属典型的S型过铝花岗岩。形成的高峰期为新元古代早中期(819-825Ma),是与Rodinia超大陆裂解背景有关的拉张构造环境的产物,而非形成于挤压构造体制。     

An analysis of debris-flow events in the Sardinia Island (Thyrrenian Sea, Italy)

On 6 December 2004, the Villagrande Strisaili area (middle-east Sardinia), was struck by debris flows; 330 mm of rainfall took place within 3 h with an hourly intensity of 120 mm, which is far more above than normal for the study area. In the urban center stony and driftwood deposits accounted for a total volume estimated as 10,000 m³. The event claimed huge amount of infrastructural loss and two human lives. According to the chronicle reports, the area experienced two debris-flow events in the last century. The present paper is the outcome of an intensive study of such debris-flow events including their physical processes and geomorphological effects through both field survey and laboratory analysis.     

Mid-crustal shear zone evolution in a syn-tectonic late Hercynian granitoid (Sila Massif,Calabria, southern Italy)

By means of petrogrological, meso- and microstructural analyses, the fabric of a syn-tectonic late Hercynian K-feldspar megacryst-bearing granodiorite is described in this paper. The granodiorite was emplaced at 293 Ma within migmatitic paragneisses which had reached the regional peak metamorphic conditions at 304–300 Ma. The granodiorite and the migmatitic paragneisses are both affected by the same ductile shear zone. In the core of the shear zone, mylonites show a clear grain-size reduction and microstructures related to deformation at high to medium temperature conditions. Migmatitic paragneisses, foliated granodiorites and mylonites mostly show concordant lineation and foliation orientations. In addition, the preferred orientation of euhedral feldspars in granodiorites indicates that the fabric anisotropy started to develop in the magmatic state. These features strongly suggest that shear deformation was active during crystallisation of granitoids and continued under subsolidus conditions. In wall rocks and mylonites, kinematic indicators such as - and -type porphyroclasts, S/C fabrics, shear bands and quartz (c) axis orientations suggest a top-to-the-W sense of shear. This is similar to the magma flow direction indicated by the tiling of euhedral feldspar megacrysts in granodiorites. Shear deformation developed, preferentially, by partitioning of strain in the granodioritic crystal mush. Geobarometry indicates that deformation took place at middle crustal levels (P=400–500 MPa). Whole rock-white mica Rb/Sr geochronological analysis of an undeformed pegmatite, crosscutting the mylonitic foliation, provided an age of 265 Ma. Timing of deformation is therefore bracketed between 293 Ma and 265 Ma.     

Sr and Nd isotopes as tracers in pedogenic studies: Evidence for Saharan dust contribution to the soils of Muravera (Sardinia,Italy)

Sr and Nd isotopes were applied to 5 soil profiles from the Muravera area, in south-eastern Sardinia.All the soils, which have developed during the Quaternary on the Lower Paleozoic metamorphic basement except for one on Eocene carbonates, are located far from major sources of pollution. Therefore, they are suitable for testing pedogenic processes and geochemical evolution to benefit for environmental studies.The Sr isotopic ratios range largely (δ⁸⁷Sr = 1.7–65.9‰), even in each soil profile. In particular, the observed increase of δ⁸⁷Sr with depth in the most of the metamorphic rock-based soils can be accounted for by the downward decrease of Sr contributions from organic matter and Saharan dust, both displaying lower isotopic ratios than the soil bedrocks. The carbonate rock-based soil exhibits δ⁸⁷Sr higher (1.7–18.1‰) than the bedrock, indicating a significant contribution of radiogenic Sr from the siliciclastic fraction of the soil, and probably from dust input. The Nd isotopic ratios are slightly variable through the profiles (ɛ_Nd from −7.8 to −14.5), confirming little mobility of Nd and Sm during the pedogenesis. Among the minerals present in the soils, phosphates, albite, and calcite are those important in providing low radiogenic Sr and Nd to organic matter of the soils.Lastly, this isotopic study has in particular allowed for evaluating the potential proportion of contribution of Saharan dust to south-eastern Sardinia, thus corroborating the findings of other studies related to soils from the central-western Mediterranean.     

Zeolitization of Oligo-Miocene volcaniclastic rocks from Logudoro (northern Sardinia, Italy)

The present study reports the results of research on volcaniclastic products from Logudoro (northern Sardinia), a reconstructed stratigraphic succession some hundreds of meters thick, comprising two different ignimbritic units separated by an epiclastic layer (generally ˜10 m thick). Clinoptilolite is the most widely distributed authigenic phase in epiclastite and unwelded units, always associated with opal-CT and sometimes with smectite. An adularia-like feldspar, cristobalite and epigenetic quartz are typical phases of welded units. Within the zeolitized units (unwelded ignimbrite and epiclastic units) clinoptilolite and opal-CT constitute the cement deriving from the transformation of the precursor rhyolitic glass, in agreement with a single zeolitization process that developed after the deposition of the entire succession. Silica increases in zeolitized rocks with respect to the precursor material, leading to hypothesize that the secondary mineralization process was favored by mineralized hydrothermal fluids preferentially circulating through the fault system of the area. Quartz veins in welded subunit and K-feldspar (adularia-like) preferentially located near the faults are in agreement with this hypothesis. The interaction of these fluids with the glassy fraction favored its dissolution and the consequent crystallization of clinoptilolite. Furthermore, the pH increase and the silica supersaturation enhanced the contemporary or subsequent precipitation of opal-CT. Received: 5 June 2000 / Accepted: 14 August 2000     

Evaluating disturbance on mediterranean karst areas: the example of Sardinia (Italy)

Evaluating the human disturbance on karst areas is a difficult task because of the complexity of these peculiar and unique environments. The human impact on karstic geo-ecosystems is increasingly important and there is an increasing need for multidisciplinary tools to assess the environmental changes in karst areas. Many disciplines, such as biology, geomorphology, hydrology and social-economical sciences are to be considered to sufficiently evaluate the impact on these intrinsically vulnerable areas. This article gives an overview of the evolution of environmental impact on karst areas of the island Sardinia (Italy). For this particular case, the most important impacts in the past 50 years are derived from the following activities, in decreasing importance: (1) mining and quarrying; (2) deforestation, agriculture and grazing; (3) building (widespread urbanisation, isolated homes, etc.) and related infrastructures (roads, sewer systems, aqueducts, waste dumps, etc.); (4) tourism; (5) military activities. To evaluate the present environmental state of these areas the Disturbance Index for Karst environments [Van Beynen and Townsend (Environ Manage 36:101–116)] is applied in a slightly modified version. Instead of considering the indicators of environmental disturbances used in the original method, this slightly modified index evaluates the disturbances causing the deterioration of the environmental attributes. In the Sardinian case study, 27 disturbances have been evaluated, giving rise to the definition of a Disturbance Index ranging between 0 (Pristine) and 1 (highly disturbed). This Disturbance Index simplifies the original KDI method, appears to adequately measure disturbance on Mediterranean karst areas and could be applied with success to other similar regions.     

Fluids in low-pressure migmatites: a fluid inclusion study of rocks from the Gennargentu Igneous Complex (Sardinia, Italy)

Summary The low-pressure emplacement of a quartz diorite body in the metapelitic rocks of the Gennargentu Igneous Complex (Sardinia, Italy) produced a contact metamorphic aureole and resulted in migmatisation of part of the aureole through partial melting. The leucosome, formed by dehydration melting involving biotite, is characterised by granophyric intergrowth and abundant magnetite crystals. A large portion of the high temperature contact aureole shows petrographic features that are intermediate between quartz diorite and migmatite s.s. (i.e. hybrid rocks). A fluid inclusion study has been performed on quartz crystals from the quartz diorite and related contact aureole rocks, i.e. migmatite sensu stricto (s.s.) and hybrid rocks. Three types of fluid inclusions have been identified: I) monophase V inclusions, II) L + V, either L-rich or V-rich aqueous saline inclusions and III) multiphase V + L + S inclusions. Microthermometric data characterised the trapped fluid as a complex aqueous system varying from H₂O–NaCl–CaCl₂ in the quartz diorite to H₂O–NaCl–CaCl₂–FeCl₂ in the migmatite and hybrid rocks. Fluid salinities range from high saline fluids (50 wt% NaCl eq.) to almost pure aqueous fluid. Liquid-vapour homogenisation temperatures range from 100 to over 400 °C with an average peak around 300 °C. Temperatures of melting of daughter minerals are between 300 and 500 °C. Highly saline liquid- and vapour-rich inclusions coexist with melt inclusions and have been interpreted as brine exsolved from the crystallising magma. Fluid inclusion data indicate the formation of fluid of high iron activity during the low-pressure partial melting and a fluid mixing process in the hybrid rocks.     

Shelf to basin transition in the Cambrian-Lower ordovician of Sardinia (Italy)

In southern and central Sardinia two different Cambrian-Lower Ordovician sedimentary belts occur. The former is exposed in southwestern Sardinia (Iglesiente and Sulcis), and is characterized by shallow-marine siliciclastic and carbonate sediments settled on a continental shelf with lowangle morphology. The latter, exposed in the Nappe Zone (central and southeastern Sardinia), consists of a thick monotonous sequence of siliciclastic deposits settled in a deeper-water basin.The comparative analysis of the sequences and their palinspastic reconstruction lead to recognize an inner and outer shelf respectively in Iglesiente and in northern Sulcis, a transition to the basin in eastern and southern Sulcis and a basin in the eastern areas of Sardinia (Nappe Zone).

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Zusammenfassung In Süd- und Zentral-Sardinien gibt es zwei unterschiedliche Sedimentgürtel im Kambrium bis Unterordovizium. Der ältere ist in Südwest-Sardinien (Iglesiente und Sulcis) aufgeschlossen. Er ist aus flachmarinen siliziklastischen und karbonatischen Sedimenten eines kontinentalen Schelfes mit flachem Relief aufgebaut. Der zweite Sedimentgürtel, aufgeschlossen in der Decken-Zone (Zentral- und SE-Sardinien) besteht aus einer mächtigen einheitlichen Folge von siliziklastischen Ablagerungen eines tieferen Beckens.Die vergleichende Analyse der Folgen und die palinspastische Rekonstruktion läßt einen inneren und einen äußeren Schelf im Gebiet von Iglesiente und nördlichen Sulcis erkennen, einen Übergang zum Becken im östlichen und südlichen Sulcis sowie ein Becken im östlichen Sardinien (Decken-Zone).

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Résumé En Sardaigne méridionale et centrale, on connaît deux ensembles sédimentaires d'âge cambro-ordovicien. Le premier, exposé dans la partie sud-occidentale de l'île (secteurs de l'Iglesiente et du Sulcis), est caractérisé par des sédiments carbonatés et terrigènes déposés sur un shelf continental morphologiquement régulier et à inclinaison faible.Le second, exposé dans la »zone des nappes« (Sardaigne orientale) est composé d'une séquence terrigène monotone déposée dans un bassin plus profond. L'analyse comparée des séquences et les reconstructions palynspastiques conduisent à reconnaître plusieurs domaines paléogéographiques: un shelf interne dans l'Iglesiente, un shelf externe dans le Sulcis septentrional, une transition vers le bassin profond dans le sud et l'est du Sulcis et ce bassin profond dans la Sardaigne orientale (»zones des nappes«).

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, . - (Iglesiente Sulcis) , , . , ( - ), , . : Iglesiente, — Sulcis, — Sulcis, — .

     

Hercynian subduction-related processes within the metamorphic continental crust in Calabria (southern Italy)

Linking the deformation history of mylonitized continental rocks to the progress of devolatilization reactions that trigger reaction softening is critical for the understanding of crustal scale processes. We have analysed the field geometries and microstructures of deformed rocks within the southern Hercynian belt in Calabria, as well as modelled the pressure–temperature–deformation (P–T–d) trajectory of a main ductile shear zone that tectonically coupled the deeper crustal Mammola Paragneiss Unit with the upper crustal Stilo–Pazzano Phyllite Unit. P–T modelling of the mylonitic Mammola Paragneiss Unit was performed through calculation of phase equilibrium diagrams with the software thermocalc in the MnNCKFMASHTO model system. The prograde P–T–d trajectory is based on the zoning profiles of garnet porphyroblasts and their mineral inclusions, primarily barroisite and epidote. P–T modelling shows that peak metamorphic conditions of ~0.9 GPa and 585°C were reached during a D_n-1 under-thrusting event. The following exhumation during the D_n mylonitic event, and contact metamorphism during D_n+1 and D_n+2 folding events, have also been modelled because they are essential to restore the previous tectono-metamorphic history. The exhumation trajectory was modelled down to 0.3 GPa with temperatures of 440–460°C, under fluid-deficient conditions, as well as the final late Carboniferous contact metamorphism up to T_max of 680–720°C. The prograde path shows clear evidence for thermal buffering during garnet growth at the expense of chlorite, with a heating-dominated stage after chlorite breakdown. Subsequently, a rheological change associated with epidote breakdown (i.e. reaction softening) occurred, highlighted by a net steepening of the P/T trajectory towards the pressure peak. On the basis of the barroisite inclusions within garnet porphyroblasts as well as the ‘hairpin’ shape of the reconstructed P–T–d path (before contact metamorphism), we infer that the unusual low T/P gradient for the Hercynian crust exposed in the Mammola Paragneiss Unit records its involvement in the Palaeotethys–Gondwana subduction beneath Laurussia during D_n-1 under-thrusting. We present a new palaeotectonic interpretation along the southern Hercynian belt in Calabria during the Upper Mississippian–Lower Pennsylvanian, that is consistent with previous geochronology studies.     

Cordieritite and Leucogranite Formation during Emplacement of Highly Peraluminous Magma: the El Pilon Granite Complex (Sierras Pampeanas, Argentina)

Cordieritites and highly peraluminous granites within the ElPilón granite complex, Sierras Pampeanas, Argentina,were emplaced during a medium-P, high-T metamorphic event duringthe initial decompression of a Cambrian orogen along the southwesternmargin of Gondwana. Very fresh orbicular and massive cordierititebodies with up to 90% cordieritite are genetically associatedwith a cordierite monzogranite pluton and a larger body of porphyriticgranodiorite. The petrogenesis of this association has beenstudied using petrographical, mineralogical, thermobarometric,geochemical, geochronological and isotope methods. The graniticmagmas were formed by anatexis of mid-crustal metamorphic rocksformed earlier in the Pampean orogeny. The cordieritites appearat the top of feeder conduits that connected the source regionlocated at