New U–Pb zircon ages of the Ediacaran–Cambrian boundary strata in South China

The Ediacaran–Cambrian transition is a critical interval marking drastic biological, oceanic and geochemical co‐evolutions in geological history, but it is poorly constrained geochronologically in South China. We here present two new sets of SIMS U–Pb zircon ages from Ediacaran–Cambrian boundary strata (Dengying, Liuchapo and Niutitang formations) deposited in the slope–basin environments of carbonate platforms. Two weighted‐mean U–Pb ages of 542.1 ± 5.0 Ma and 542.6 ± 3.7 Ma in the basal and mid‐upper Liuchapo Formation, respectively, in slope and basinal settings provide the first direct age set for the Ediacaran–Cambrian boundary in South China. Another two U–Pb ages of 524.2 ± 5.1 Ma and 522.3 ± 3.7 Ma from the base of the overlying Niutitang Formation indicate that this widespread unit in South China was deposited about 20 Ma after the onset of the Cambrian.     

The Cambrian Explosion: Plume-driven birth of the second ecosystem on Earth

The birth of modern life on Earth can be linked to the adequate supply of nutrients into the oceans. In this paper, we evaluate the relative supply of nutrients into the ocean. These nutrients entered the ocean through myriad passageways, but primarily through accelerated erosion due to uplift. In the ‘second ecosystem’, uplift is associated with plume-generation during the breakup of the Rodinia supercontinent. Although the evidence is somewhat cryptic, it appears that the second ecosystem included the demospongia back into the Cryogenian (~ 750 Ma). During the Ediacaran–Cambrian interval, convergent margin magmatism, arc volcanism and the closure of ocean basins provided a second pulse of nutrient delivery into the marine environment. A major radiation of life forms begins around 580 Ma and is represented by the diverse and somewhat enigmatic Ediacaran fauna followed by the Cambrian Explosion of modern phyla during the 540–520 Ma interval. Tectonically, the Ediacaran–Cambrian time interval is dominated by the formation of ultra-high pressure (UHP), high pressure (HP) and ultra-high temperature (UHT) orogenic belts during Gondwana orogenesis. Erosion of this extensive mountainous region delivered vast nutrients into the ocean and enhanced the explosiveness of the Cambrian radiation. The timing of final collisional orogeny and construction of the mountain belts in many of the Gondwana-forming orogens, particularly some of those in the central and eastern belts, post-date the first appearance of modern life forms. We therefore postulate that a more effective nutrient supply for the Cambrian radiation was facilitated by plume-driven uplift of TTG crust, subsequent rifting, and subduction-related nutrient systems prior to the assembly of Gondwana. In the outlined scenario, we propose that the birth of the ‘second ecosystem’ on our planet is plume-driven.     

Inherited arc signature in Ediacaran and Early Cambrian basins of the Ossa-Morena Zone (Iberian Massif,Portugal): Paleogeographic link with European and North African Cadomian correlatives

Geochemical data from clastic rocks of the Ossa-Morena Zone (Iberian Massif) show that the main source for the Ediacaran and the Early Cambrian sediments was a recycled Cadomian magmatic arc along the northern Gondwana margin. The geodynamic scenario for this segment of the Avalonian-Cadomian active margin is considered in terms of three main stages: (1) The 570–540 Ma evolution of an active continental margin evolving oblique collision with accretion of oceanic crust, a continental magmatic arc and the development of related marginal basins; (2) the Ediacaran–Early Cambrian transition (540–520 Ma) coeval with important orogenic magmatism and the formation of transtensional basins with detritus derived from remnants of the magmatic arc; and (3) Gondwana fragmentation with the formation of Early Cambrian (520–510 Ma) shallow-water platforms in transtensional grabens accompanied by rift-related magmatism. These processes are comparable to similar Cadomian successions in other regions of Gondwanan Europe and Northwest Africa. Ediacaran and Early Cambrian basins preserved in the Ossa-Morena Zone (Portugal and Spain), the North Armorican Cadomian Belt (France), the Saxo-Thuringian Zone (Germany), the Western Meseta and the Western High-Atlas (Morocco) share a similar geotectonic evolution, probably situated in the same paleogeographic West African peri-Gondwanan region of the Avalonian-Cadomian active margin.     

Neoproterozoic evolution and Cambrian reworking of ultrahigh temperature granulites in the Eastern Ghats Province,India

The time‐scales and P–T conditions recorded by granulite facies metamorphic rocks permit inferences about the geodynamic regime in which they formed. Two compositionally heterogeneous cordierite–spinel‐bearing granulites from Vizianagaram, Eastern Ghats Province (EGP), India, were investigated to provide P–T–time constraints using petrography, phase equilibrium modelling, U–Pb geochronology, the rare earth element composition of zircon and monazite, and Ti‐in‐zircon thermometry. These ultrahigh temperature (UHT) granulites preserve discrete compositional layering in which different inferred peak assemblages are developed, including layers bearing garnet–sillimanite–spinel, and others bearing orthopyroxene–sillimanite–spinel. These mineral associations cannot be reproduced by phase equilibrium modelling of whole‐rock compositions, indicating that the samples became domainal on a scale less than that of a thin section, even at UHT conditions. Calculation of the P–T stability fields for six compositional domains within which the main rock‐forming minerals are considered to have attained equilibrium suggests peak metamorphic conditions of ~6.8–8.3 kbar at ~1,000°C. In most of these domains, the subsequent evolution resulted in the growth of cordierite and final crystallization of melt at an elevated (residual) H₂O‐undersaturated solidus, consistent with <1 kbar of decompression. Concordant U–Pb ages obtained by SHRIMP from zircon (spread 1,050–800 Ma) and monazite (spread 950–800 Ma) demonstrate that crystallization of these minerals occurred during an interval of c. 250 Ma. By combining LA‐ICP‐MS U–Pb zircon ages with Ti‐in‐zircon temperatures from the same analysis sites, we show that the crust may have remained above 900°C for a minimum of c. 120 Ma between c. 1,000 and c. 880 Ma. Overall, the results suggest that, in the interval 1,050 to 800 Ma, the evolution of the Vizianagaram granulites culminated with UHT conditions from c. 1,000 Ma to c. 880 Ma, associated with minor decompression, before further zircon crystallization at c. 880–800 Ma during cooling to the solidus. However, these rocks are adjacent to the Paderu–Anantagiri–Salur crustal block to the NW that experienced counterclockwise P–T–t paths, and records similar UHT peak metamorphic conditions (7–8 kbar, ~950°C) followed by near‐isobaric cooling, and has a similar chronology during the Neoproterozoic. The limited decompression inferred at Vizianagaram may be explained by partial exhumation due to thrusting of this crustal block over the adjacent Paderu–Anantagiri–Salur crustal block. The residual granulites in both blocks have high concentrations of heat‐producing elements and likely remained hot at mid‐crustal depths throughout a period of relative tectonic quiescence in the interval 800–550 Ma. During the Cambrian Period, the EGP was located in the hinterland of the Denman–Pinjarra–Prydz orogen. A later concordant population of zircon dated at 511 ± 6 Ma records crystallization at temperatures of ~810°C. This age may record a low‐degree of melting due to limited influx of fluid into hot, weak crust in response to convergence of the Crohn craton with a composite orogenic hinterland comprising the Rayner terrane, EGP, and cratonic India.     

First evidence of the Cambrian basement in Upper Peninsula of Thailand and its implication for crustal and tectonic evolution of the Sibumasu terrane

Although the Sibumasu terrane in Asia was previously considered to be composed of Phanerozoic rocks with Cambrian crystalline basement, no reliable or direct radiometric dating evidences of such crystalline basement was ever reported. Our new in-situ zircon U/Pb dating of the Khao Tao orthogneiss yields a concordant age of 501.5 ± 7.5 Ma (2σ), which provides the first robust evidence for the Cambrian crust in Upper Peninsula of Thailand. The zircon εHf_(T) values range from + 3.7 to − 6.1 with model ages (T^C_DM) of 1244–1827 Ma, suggests a mixed crust-mantle source. The chemical similarity and spatial continuity of the Khao Tao orthogneiss with other pre-Neotethys marginal Eurasian and Sibumasu granitoids indicate the linear paleogeographic association under a similar magmatic arc-related regime along the Gondwana India–Australia margin as part of the Pan-African Orogeny system.     

Early Cambrian palaeogeography and the probable Iberia–Siberia connection

The end of the Proterozoic–beginning of the Cambrian is marked by some of the most dramatic events in the history of Earth. The fall of the Ediacaran biota, followed by the Cambrian Explosion of skeletonised bilaterians, a pronounced shift in oceanic and atmospheric chemistry and rapid climatic change from ‘snowball earth’ to ‘greenhouse’ conditions all happened within a rather geologically short period of time. These events took place against a background of the rearrangement of the prevailing supercontinent; some authors view this as a sequence of individual supercontinents such as Mesoproterozoic Midgardia, Neoproterozoic Rodinia and Early Cambrian Pannotia. Assembled in the Mesoproterozoic, this supercontinent appears to have existed through the Neoproterozoic into the Early Cambrian with periodic changes in configuration. The final rearrangement took place during the Precambrian–Cambrian transition with the Cadomian and related phases of the Pan-African orogeny. The distribution of Early Cambrian molluscs and other small shelly fossils (SSF) across all continents indicates a close geographic proximity of all major cratonic basins that is consistent with the continued existence of the supercontinent at that time. Subsequently, Rodinia experienced breakup that led to the amalgamation of Gondwana, separation of Laurentia, Baltica, Siberia and some small terranes and the emergence of oceanic basins between them. Spreading oceanic basins caused a gradual geographic isolation of the faunal assemblages that were united during the Vendian–Early Cambrian.     

SHRIMP zircon age for an Early Cambrian dolerite dyke: An intrusive phase of the Antrim Plateau Volcanics of northern Australia

The Antrim Plateau Volcanics, Australia's largest Phanerozoic flood‐basalt province, originally covered an area of at least 300 000 km² across northern Australia. Stratigraphic constraints indicate that the Antrim Plateau Volcanics are of Early Cambrian age (ca 545–509 Ma), although previous attempts to date the Antrim basalts by radiometric methods have been inconclusive. We present an ion microprobe U–Pb zircon age of 513 ± 12 Ma for the ～250 km‐long Milliwindi dolerite dyke in the west Kimberley. The dolerite is geochemically identical to basalts of the Antrim Plateau Volcanics, and was probably a feeder dyke for basalts that have since been eroded. It is suggested that the Antrim Plateau Volcanics extended hundreds of kilometres further to the west than recognised previously and may have once covered part of the Kimberley block.     

Pre-collisional (> 0.5 Ga) complexes of the Olkhon terrane (southern Siberia) as an echo of events in the Central Asian Orogenic Belt

The Olkhon terrane is a part of the Early Palaeozoic accretionary-collisional system in the northern Central Asian Orogenic Belt (CAOB). The terrane was produced by an Ordovician collision as a collage of numerous chaotically mixed tectonic units composed of rock complexes of different ages originated in different tectonic settings. The pre-collisional history of the terrane is deciphered using new data on zircon ages and chemistry of rocks from several complexes. The oldest Olkhon rocks are the 1.87–1.83 Ga granulite and gneissic granites of the Kaltygey complex, which is an exotic Palaeoproterozoic tectonic slice. The next age group consists of the Ust-Zunduk orthogneisses (807 ± 9 Ma) and the Orso amphibolites and gneisses (792 ± 10 and 844 ± 6 Ma). Samples of both complexes have negative ε_Nd(t) values. The Ust-Zunduk and Orso complexes can have formed in active margins of continents or in crustal blocks other than southern Siberia. The Ediacaran subduction-related rocks of the Olkhon complex may have formed in an island arc setting within the Palаeo-Asian Ocean (PAO). The protolith of schists after volcanic rocks has an age of 637 ± 4 Ma and shows positive ɛ_Nd(t) values. The Ediacaran/Cambrian Tonta mafic granulites (ca.545 Ma), with OIB affinity and slightly positive ɛ_Nd(t), were derived from an enriched mantle source and may represent a fragment of an oceanic island. The Cambrian Shebarta gneisses after continental-arc greywackes with negative ɛ_Nd(t) values were deposited in a back-arc basin of a microcontinent within the PAO, between 530 and 500 Ма. The Cambrian Birkhin metamorphics after PAO mature island-arc rocks have U-Pb ages of ca. 500–490 Ma and positive ɛ_Nd(t) values. All pre-collisional complexes in the Olkhon terrane have their analogues among the rocks formed during main events in the northern CAOB history. Thus the reconstructed milestones in the Olkhon terrane history appear to be an echo of events in the CAOB northern segment.     

Rapid changes of magnetic Field polarity in the late Ediacaran: Linking the Cambrian evolutionary radiation and increased UV-B radiation

Novelty in the biological world is the culmination of genetic changes often triggered by the physical environment. The most radical phase of biological evolution took place during the Cambrian Evolutionary Radiation (CER). Prior to the CER, bacterial matgrounds and associated communities of Ediacaran organisms dominated the shallow seafloor. Near the end of the Ediacaran Period, ~ 550 million years ago, many soft-bodied biota went extinct. In the Early Cambrian, animals with the ability to burrow vertically altered the ecology of the seafloor and biomineralization became commonplace. Here we link the terminal Ediacaran extinction, the Cambrian substrate revolution and the diversification of biomineralizing organisms to changes associated with the reversal frequency of the Earth's magnetic field. Beginning around 550 Ma and continuing through much of the Cambrian, the Earth's magnetic field was rapidly reversing. Models, and limited paleointensity studies, indicate that rapid reversals are a feature of an overall weaker dipole. A weakened dipole reduces the dimensions of the magnetosphere that provides a barrier to incoming cosmic radiation. Here we show that the environmental effects of that collapse include increased dosing of UVB radiation into the shallow marine environment. Increased UVB radiation in the shallow marine environment provided selective pressure favoring organisms that could detect and avoid UVB damage by burrowing vertically, moving up or down in the water column, growing protective shells and other ‘flight from light’ mechanisms. These changes took place in advance of the CER, but effectively cleared the ecological space for the subsequent changes in the later Cambrian.     

Ediacaran terrane accretion within the Arabian–Nubian Shield

The Ad Dawadimi Terrane is an Ediacaran basin of the Arabian Nubian Shield (ANS), Saudi Arabia. This basin terrane is situated in the far eastern part of the ANS and represents the youngest accretion event of the exposed ANS. Therefore, the timing of events within the basin is key to understanding both the closure of the Mozambique Ocean and the amalgamation of Gondwana along the northern East African Orogen. Here we present U/Pb detrital zircon data for the Abt Formation, the principle basin sediments of the Ad Dawadimi Terrane, along with ⁴⁰Ar/³⁹Ar ages on muscovite and whole rock Sm/Nd data. These data indicate that deep-water deposition in the Abt Basin did not end until after ca. 620 Ma and that deformation and greenschist-facies metamorphism of the Abt Formation occurred at 620 ± 3 (2σ) Ma along an active margin. This is the youngest terrane amalgamation event reported so far in the Arabian–Nubian Shield, but we suggest even younger sutures lie further east beneath the Phanerozoic cover of eastern Saudi Arabia. Our results suggest that the Ediacaran basins of the eastern ANS were not part of the Huqf basin in Oman, which was instead part of a passive margin of Neoproterozoic India, separated from the active margin of Africa by the Mozambique Ocean that probably did not close until the late Ediacaran or early Cambrian.     

Early Cambrian granitoids of North Gondwana margin in the transition from a convergent setting to intra-continental rifting (Ossa-Morena Zone,SW Iberia)

Two distinct Cambrian magmatic pulses are recognized in the Ossa-Morena Zone (SW Iberia): an early rift-(ER) and a main rift-related event. This Cambrian magmatism is related to intra-continental rifting of North Gondwana that is thought to have culminated in the opening of the Rheic Ocean in Lower Ordovician times. New data of whole-rock geochemistry (19 samples), Sm–Nd–Sr isotopes (4 samples) and ID–TIMS U–Pb zircon geochronology (1 sample) of the Early Cambrian ER plutonic rocks of the Ossa-Morena Zone are presented in this contribution. The ER granitoids (Barreiros, Barquete, Calera, Salvatierra de los Barros and Tablada granitoid Massifs) are mostly peraluminous granites. The Sm–Nd isotopic data show moderate negative εNdt values ranging from ?3.5 to +0.1 and TDM ages greatly in excess of emplacement ages. Most ER granitoids are crustal melts. However, a subset of samples shows a transitional anorogenic alkaline tendency, together with more primitive isotopic signatures, documenting the participation of lower crust or mantle-derived sources and suggesting a local transient advanced stage of rifting. The Barreiros granitoid is intrusive into the Ediacaran basement of the Ossa-Morena Zone (Série Negra succession) and has yielded a crystallization age of 524.7 ± 0.8 Ma consistent with other ages of ER magmatic pulse. This age: (1) constrains the age of the metamorphism developed in the Ediacaran back-arc basins before the intrusion of granites and (2) defines the time of the transition from the Ediacaran convergent setting to the Lower Cambrian intra-continental rifting in North Gondwana.     

Dating late Quaternary events by the combined U‐Pb LA‐ICP‐MS and (U‐Th)/He dating of zircon: A case study on Omachi Tephra suite (central Japan)

Dating of young (<1 Ma) geological events has long been a challenge for geochronologists. Combining (U‐Th)/He with U‐Pb or U‐Th‐disequilibrium dating methods offers a unique dating tool that can address this important period. We present a new methodology that combines U‐Pb LA‐ICP‐MS and (U‐Th)/He dating of zircon and use it to date two Pleistocene marker tephras (A1Pm and DPm) from the Omachi Tephra suite (Japan). A1Pm and DPm yield U‐Pb ages in the range of 350–850 and ~140–630 ka, respectively, documenting protracted periods of zircon crystallisation (100's of k.y.) prior to eruption. (U‐Th)/He ages constrain the eruption ages of the A1Pm and DPm tephras to 375 ± 13 and 97.1 ± 7.3 ka, respectively, and are in agreement with published estimates. This study demonstrates the potential of combined zircon U‐Pb LA‐ICP‐MS and (U‐Th)/He dating to constrain magmatic and eruption events in the critical ~100 ka–1 Ma interval.     

A New Progress of the Proterozoic Chronostratigraphical Division

The Precambrian, an informal chronostratigraphical unit, represents the period of Earth history from the start of the Cambrian at ca. 541 Ma back to the formation of the planet at 4567 Ma. It was originally conceptualized as a "Cryptozoic Eon" that was contrasted with the Phanerozoic Eon from the Cambrian to the Quaternary, which is now known as the Precambrian and can be subdivided into three eons, i.e., the Hadean, the Archean and the Proterozoic. The Precambrian is currently divided chronometrically into convenient boundaries, including for the establishment of the Proterozoic periods that were chosen to reflect large-scale tectonic or sedimentary features(except for the Ediacaran Period). This chronometric arrangement might represent the second progress on the study of chronostratigraphy of the Precambrian after its separation from the Phanerozoic. Upon further study of the evolutionary history of the Precambrian Earth, applying new geodynamic and geobiological knowledge and information, a revised division of Precambrian time has led to the third conceptual progress on the study of Precambrian chronostratigraphy. In the current scheme, the Proterozoic Eon began at 2500 Ma, which is the approximate time by which most granite-greenstone crust had formed, and can be subdivided into ten periods of typically 200 Ma duration grouped into three eras(except for the Ediacaran Period). Within this current scheme, the Ediacaran Period was ratified in 2004, the first period-level addition to the geologic time scale in more than a century, an important advancement in stratigraphy. There are two main problems in the current scheme of Proterozoic chronostratigraphical division:(1) the definition of the Archean–Proterozoic boundary at 2500 Ma, which does not reflect a unique time of synchronous global change in tectonic style and does not correspond with a major change in lithology;(2) the round number subdivision of the Proterozoic into several periods based on broad orogenic characteristics, which has not met with requests on the concept of modern stratigraphy, except for the Ediacaran Period. In the revised chronostratigraphic scheme for the Proterozoic, the Archean–Proterozoic boundary is placed at the major change from a reducing early Earth to a cooler, more modern Earth characterized by the supercontinent cycle, a major change that occurred at ca. 2420 Ma. Thus, a revised Proterozoic Eon(2420–542 Ma) is envisaged to extend from the Archean–Proterozoic boundary at ca. 2420 Ma to the end of the Ediacaran Period, i.e., a period marked by the progressive rise in atmospheric oxygen, supercontinent cyclicity, and the evolution of more complex(eukaryotic) life. As with the current Proterozoic Eon, a revised Proterozoic Eon based on chronostratigraphy is envisaged to consist of three eras(Paleoproterozoic, Mesoproterozoic, and Neoproterozoic), but the boundary ages for these divisions differ from their current ages and their subdivisions into periods would also differ from current practice. A scheme is proposed for the chronostratigraphic division of the Proterozoic, based principally on geodynamic and geobiological events and their expressions in the stratigraphic record. Importantly, this revision of the Proterozoic time scale will be of significant benefit to the community as a whole and will help to drive new research that will unveil new information about the history of our planet, since the Proterozoic is a significant connecting link between the preceding Precambrian and the following Phanerozoic.     

Detrital provenance evolution of the Ediacaran–Silurian Nanhua foreland basin,South China

We report here in-situ U–Pb and Hf isotopic results of detrital zircons from sixteen Cambrian–Silurian siliciclastic samples across the Nanhua foreland basin, South China. Together with published data from Ediacaran–Silurian sandstones in the region, we establish the temporal and spatial provenance evolution across the basin. Except for samples from northeast Yangtze, all other Ediacaran–Silurian samples exhibit a prominent population of 1100–900 Ma, moderate populations of 850–700 Ma and 650–490 Ma, and minor populations of 2500 Ma and 2000–1300 Ma, grossly matching that of crystalline and sedimentary rocks in northern India. Zircon Hf isotopes further reveal four episodes of juvenile crustal growth at 2.5 Ga, 1.8 Ga, 1.4 Ga and 1.0 Ga in the source regions. Utilizing the basin history and late Neoproterozoic to early Paleozoic paleogeography of South China, we conclude that the Ediacaran–Cambrian sediments in the Nanhua foreland basin were mainly sourced from northern India and adjacent orogens, and the Ordovician–Silurian sediments were derived from both locally recycled Ediacaran–Cambrian rocks and eroded Cathaysian basement. The Wuyi–Yunkai late-orogenic magmatic rocks also contributed to the Silurian sediments in the basin. The upper-Ordovician to Silurian samples in northeast Yangtze received higher proportions of local Cryogenian (850–700 Ma) magmatic rocks which were uplifted during late-Ordovician to Silurian time. We speculate that there was an Ediacaran–Cambrian collisional orogen between South China and northern India, shedding sediments to the early Nanhua foreland basin. Far-field stress during the late stage of this collisional orogeny triggered the Ordovician–Silurian intraplate Wuyi–Yunkai orogeny in South China, and erosion of the local Wuyi–Yunkai orogen further provided detritus to the late Nanhua foreland basin.     

U–Pb zircon geochronology of the Ediacaran volcano-sedimentary succession of the NE Saghro inlier (Anti-Atlas,Morocco): Chronostratigraphic correlation on the northwestern margin of Gondwana

We report a new regional correlation for the Ediacaran succession in the Anti-Atlas belt on the northwestern margin of Gondwana, based on U-Pb LA-ICP-MS zircon geochronology of volcanic rocks in the NE edge of the Saghro inlier. The thick volcano-sedimentary succession comprises a diverse suite of rhyolitic-ignimbrite, basaltic to andesitic lava fields, rhyolitic lava, mafic hydroclastic complex, fallout and surge deposits, pyroclastic dyke, interbedded clastic sediment and subvolcanic bodies.Ten volcanic rocks yield crystallization ages ranging from 573 to 547 Ma, consistent with a lower and upper Ouarzazate Supergroup affinity respectively. Inherited zircon ages range from 623 Ma to 600 Ma, analogous to zircon peaks in the older volcano-sedimentary rocks of the Bou Salda, and Saghro groups in the Anti-Atlas, suggesting the continuity of the Saghro Group beneath the Ouarzazate Supergroup at the NE edge of the Saghro inlier.Rocks with a lower Ouarzazate Supergroup affinity include lithic-poor ignimbrites which yield ages of 573.6 ± 1.9 Ma, 571.8 ± 4.2 Ma, 571.3 ± 2.6 Ma, and 567.4 ± 2.9 Ma, two fallout deposits which yield ages of 563.5 ± 2.1 Ma and 569.2 ± 1.9 Ma, a surge deposit dated at 571.6 ± 2.8 Ma and a rhyolite lava dated at 562.5 ± 3.1 Ma. Two lithic-poor ignimbrites from the upper Ouarzazate Supergroup are dated at 557.3 ± 2.6 Ma and 547.9 ± 3.1 Ma.Volcanic activity at the NE edge of the Saghro inlier is related to West African Cadomian orogenic (WACadomian) activity between 620 and 560 Ma. During this period the Saghro and Bou Salda groups were deposited, followed by the lower Ouarzazate Supergroup. Later extension along the Gondwanan margin took place close to Ediacaran – Cambrian boundary, contemporaneous with upper Ouarzazate Supergroup deposition.     

Dating of Neoproterozoic and Cambrian orogenies in Tasmania*

A coherent set of timing constraints is produced for Tasmania's Proterozoic and Cambrian geology when only mineral ages are considered and whole‐rock ages excluded. The oldest recognised event is the formation of sedimentary deposits which contain detrital zircons that indirectly indicate a depositional age younger than 1180 Ma. Partial melts of these sedimentary rocks were incorporated in Neoproterozoic, Devonian and probably Cambrian felsic magmas. Neoproterozoic granite on King Island has an age of 760 ± 12 Ma and is part of a high‐level intrusive episode that accompanied the Wickham Orogeny, an event with regionally varied strain that is represented in northwestern Tasmania by a low‐angle unconformity, by altered granitoid with a magmatic age of 777 ± 7 Ma, and by the thick turbidite pile of the Burnie and Oonah Formations with its syndepositional intrusions of Cooee Dolerite. The late Neoproterozoic was relatively quiet tectonically but by early in the Middle Cambrian a crustal collision which marked the early phase of the Tyennan Orogeny brought about high‐level emplacement of ultramafic‐bearing allochthons and deep‐seated metamorphism of quartzose sedimentary and basaltic rocks. The ultramafic allochthons carried tonalite that had crystallised only shortly before at 510 ± 6 Ma, while the deep‐seated metamorphism produced eclogite at 502 ± 8 Ma. By middle Middle Cambrian times the metamorphic rocks had been uplifted and they experienced repeated uplift during the period of Mt Read volcanism and onward to the close of the Tyennan Orogeny in the Early Ordovician, an overall period of some 20 million years from the early Middle Cambrian. Regionally varied strain was again a feature during the Tyennan Orogeny, with the Smithton area in northwestern Tasmania and King Island occupying relatively undeformed cratonic positions.     

In-situ analyses of phosphorus contents of carbonate minerals: Reconstruction of phosphorus contents of seawater from the Ediacaran to early Cambrian

The Ediacaran and Cambrian periods were one of the most important periods for the evolution of life. The biodiversity drastically expanded in the period. However, the origins are still ambiguous because surface environmental changes through the time have not been well understood yet. We conducted in-situ analyses of the phosphorus contents of carbonate minerals with a laser ablation-inductively coupled plasma-mass spectrometer (LA-ICP-MS) to estimate the phosphorus contents of seawater from the Ediacaran to the early Cambrian. Carbonate rocks contain not only the carbonate minerals but also detrital and authigenic materials such as silicate and phosphate minerals. Therefore, the whole rock compositions of carbonate rocks are not directly related with seawater composition. To avoid the influence of the involvement of the phosphate minerals, we performed the microscopic observation, elemental mapping of Si, Ca, Mg, Fe, and P contents with an electron probe microanalyzer (EPMA), and investigation of time profiles of signal intensities of Ca, Sr, Mn, P, La and Ba with the LA-ICP-MS. Especially, samples with low Mn/Sr ratios and primary textures such as oolites are suitable to estimate the primary phosphorus contents of the carbonates.The chemostratigraphy of the phosphorus contents of carbonates from the drill core and outcrop samples displays that the phosphorus contents decrease from ca. 400 ppm in the Ediacaran through ca. 200 ppm around the terminal Ediacaran and the beginning of the Cambrian to ca. 50 ppm in the early Cambrian. Previous works on ⁸⁷Sr/⁸⁶Sr chemostratigraphy from the Ediacaran to the Cambrian sections suggested relatively high continental influx in the middle Ediacaran, and around the Precambrian–Cambrian (PC/C) boundary. The high phosphorus content in the Ediacaran was possibly due to the high continental flux. On the other hand, previous works on chemostratigraphy of carbon isotope values of carbonate carbon from the Ediacaran to the Cambrian sections showed some large negative anomalies in the Ediacaran and around the Precambrian–Cambrian (PC/C) boundary, and suggested that the negative anomalies were caused by remineralization and respiration of dissolved organic matter. The degradation of the organic matter also accounts for the high phosphorus contents in the Ediacaran. The high phosphorus content of seawater favors enhancement of primary productivity and formation of phosphorites. The high phosphorus contents in the seawater possibly led to the emergence of the large, and motile organism through the enhancement of primary productivity and the consequent increase of oxygen content of the seawater.     

New chronological constraints for Cryogenian to Cambrian rocks in the Three Gorges,Weng'an and Chengjiang areas,South China

The Neoproterozoic and Cambrian were two of the most dramatic periods in the history of the Earth, because large multi-cellular animals first appeared then in the so-called “Cambrian Explosion”. To better understand this event, many paleontological and geochemical studies now focus on rocks in South China, because of the fossiliferous succession and good exposure. Since the recognition of the Yangtze Gorges and Chengjiang area as type localities of the Sinian (Ediacaran) and Meishucunian (Early Cambrian) Systems, both sections have been intensively investigated. In order to decipher the relationships between the evolution of life and surface environmental changes, it is necessary to understand their paleontological, geochemical and geo-chronological constraints.This study presents new chronological constraints for the Cryogenian to Cambrian rocks in the Three Gorges, Weng'an and Chengjiang areas, South China. We discovered two tuff layers, one at the base of the Shuijingtuo Fm at Three Gorges and the other at the bottom of the Dahai Member in Chengjiang. In addition, we collected sandstones from Neoproterozoic strata in the Three Gorges, Chengjiang and Weng'an areas for provenance analysis. Zircons, separated from the tuff layers, provide new Nano-SIMS U–Pb ages of 526.4 ± 5.4 Ma at the base of the Shuijingtuo Fm, and 523.9 ± 6.7 Ma at the bottom of the Dahai Member. The tuffaceous beds occur at an unconformity, and nodules are common in the Three Gorges, Meishucun and Taoying sections, indicating that major and relatively wide-scale volcanic and sedimentological events occurred at ca. 525 Ma. Moreover, carbonate carbon isotope chemostratigraphies at Morocco, Siberia, Three Gorges and Meishucun display different characteristics during the Tommotian. One possibility is that the South China Ocean was separated from an outer ocean at that time. Detrital zircons in sandstones have age populations at ca. 2.7, 1.8, 1.6, 1.0 and from 0.9 to 0.75 Ga. indicating that the paleo-hinterland of the Nanhua and Kangdian rift basins was geologically complex. Despite the lack of ca. 1.6 Ga rocks in the Yangtze and Cathaysia Blocks, these data are nevertheless interpreted to indicate derivation of the zircons from basement rocks in the Yangtze craton.     

The continental record of Ediacaran volcano‐sedimentary successions in southern Brazil and their global implications

The Ediacaran is one of the most important periods on Earth evolution, including the first appearance of soft‐bodied macrofossils, major climatic changes and a supposed rise in free oxygen. In southernmost Brazil, this period is represented by Camaquã Supergroup, including the Bom Jardim Group and the Acampamento Velho Formation, both of which record continental palaeoenvironmental changes in a more than 5000 m thick stratigraphic succession. Age constraints are given by seven Ar‐Ar and U‐Pb determinations on volcanic rocks, which bracket these units between c. 605 and 574 Ma, revealing the best dated and most continuous documented Ediacaran continental succession to date. Depositional systems evolution supports a Phanerozoic‐type glacial context during the last Neoproterozoic glacial event and presents the Picada das Graças Formation (580 ± 3.6 Ma) as the first dated non‐glacial unit coeval to the Gaskiers Formation.     

Metamorphic record of collision and collapse in the Ediacaran‐Cambrian Araçuaí orogen,SE‐Brazil: Insights from P–T pseudosections and monazite dating

The Araçuaí orogen is the Brazilian counterpart of the Araçuaí‐West Congo orogenic system (AWCO), a component of the Ediacaran‐Cambrian orogenic network formed during the amalgamation of West Gondwana. The northwestern portion of the Araçuaí orogen is dominated by a succession of metasedimentary rocks made up of Meso‐ to Neoproterozoic rift, passive margin and syn‐orogenic sequences, locally intruded by post‐collisional granites. These sequences are involved in three distinct tectonic units, which from west to east are: the southern Espinhaço fold‐thrust system (SE‐thrust system), the normal‐sense Chapada Acauã shear zone (CASZ) and the Salinas synclinorium. Three deformation phases were documented in the region. The first two phases (D₁ and D₂) are characterized by contractional structures and represent the collisional development stage of the orogen. The third phase (D₃) is extensional and currently viewed as a manifestation of orogenic collapse of the system. The distribution of the metamorphic mineral assemblages in the region characterizes two metamorphic domains. The M‐Domain I on the west, encompassing the SE‐thrust system and the CASZ, is marked by a syn‐collisional (syn‐D₁) Barrovian‐type metamorphism with P–T conditions increasing eastwards and reaching ~8.5 kbar at ~650°C between 575 and 565 Ma. The M‐Domain II comprises the Salinas synclinorium in the hangingwall of the CASZ, and besides the greenschist facies syn‐collisional metamorphism, records mainly a Buchan‐type metamorphic event, which took place under 3–5.5 kbar and up to 640°C at c. 530 Ma. The northwestern Araçuaí orogen exhibits, thus, a paired metamorphic pattern, in which the Barrovian and Buchan‐type metamorphic domains are juxtaposed by a normal‐sense shear zone. Lithospheric thinning during the extensional collapse of the orogen promoted ascent of the geotherms and melt generation. A large volume of granites was emplaced in the high grade and anatectic core of the orogen during this stage, and heat advected from these intrusions caused the development of Buchan facies series over a relatively large area. Renewed granite plutonism, hydrothermal activities followed by progressive cooling affected the system between 530 and 490 Ma.