Experimental simulation of atmospheric entry of micrometeorites

Abstract— Depending on their velocity, entry angle and mass, micrometeorites suffer different degrees of heating during their deceleration in the Earth's atmosphere, leading, in most cases, to significant textural, mineralogical and chemical modifications. One of these modifications is the formation of a magnetite shell around most micrometeorites, which until now could not be reproduced, neither theoretically nor experimentally. The present study was designed to better understand the entry heating effects on micrometeorites and especially the formation of the magnetite shell. Fragments of the Murchison and Orgueil meteorites were used as analogue material in flash‐heating experiments performed in a high‐temperature furnace; effects of temperature, heating duration, and oxygen fugacity were investigated. These experiments were able to reproduce most of the micrometeorites textures, from the vesicular fine‐grained micrometeorites to the totally melted cosmic spherules. For the first time, the formation of a magnetite shell could be observed on micrometeorite analogues. We suggest that the most plausible mechanism for the formation of this shell is a peripheral partial melting with subsequent magnetite crystallization at the surface of the micrometeorite. Furthermore, with this study, it is possible to estimate the atmospheric entry conditions of micrometeorites, such as the peak temperature and the duration of flash‐heating.     

Australasian microtektites from Antarctica: XAS determination of the Fe oxidation state

The Fe oxidation state and coordination number of 29 impact glass spherules recently recovered from the Transantarctic Mountains (Antarctica) have been determined by X‐ray absorption near edge structure (XANES) spectroscopy. Based on geochemical, isotopic, and fission track data, these spherules are considered as microtektites from the Australasian tektite/microtektite strewn field. Their find location is the farthest so far discovered from the possible source crater region, and their alkali content is the lowest compared with other published data on Australasian microtektite glasses. The Fe³⁺/(Fe²⁺+Fe³⁺) ratio, determined from the analysis of the pre‐edge peak energy position and integrated intensity, is below 0.1 (±0.04) for all the samples, and is comparable to that of most tektites and microtektites from the Australasian strewn field. Also, the pre‐edge peak integrated intensity, which is sensitive to the average Fe coordination geometry, is comparable to that of other Australasian microtektites reported in the literature. The agreement of the Fe oxidation state and coordination number, between the Transantarctic Mountain microtektites (TAM) and the Australasian tektites and microtektites, further confirms the impact origin of these glass spherules and provides an independent suggestion that they represent a major extension southeastward of the Australasian strewn field. The fact that similar redox conditions are observed in tektites and microtektites within the Australasian strewn field regardless of the distance from the source crater area (up to approximately 11000 km) could be an important constraint for better understanding the different processes affecting microtektite formation and transport. The fact that the Fe oxidation state of microtektites does not increase with distance, as in the case of North American microtektites, means that thermal and redox histories of Australasian and TAM microtektites could differ significantly from those of North American microtektites.     

Ordinary chondritic micrometeorites from the Indian Ocean

Extraterrestrial particulate materials on the Earth can originate in the form of collisional debris from the asteroid belt, cometary material, or as meteoroid ablation spherules. Signatures that link them to their parent bodies become obliterated if the frictional heating is severe during atmospheric entry. We investigated 481 micrometeorites isolated from ~300 kg of deep sea sediment, out of which 15 spherules appear to have retained signatures of their provenance, based on their textures, bulk chemical compositions, and relict grain compositions. Seven of these 15 spherules contain chromite grains whose compositions help in distinguishing subgroups within the ordinary chondrite sources. There are seven other spherules which comprise either entirely of dusty olivines or contain dusty olivines as relict grains. Two of these spherules appear to be chondrules from an unequilibrated ordinary chondrite. In addition, a porphyritic olivine pyroxene (POP) chondrule‐like spherule is also recovered. The bulk chemical composition of all the spherules, in combination with trace elements, the chromite composition, and presence of dusty olivines suggest an ordinary chondritic source. These micrometeorites have undergone minimal frictional heating during their passage through the atmosphere and have retained these features. These micrometeorites therefore also imply there is a significant contribution from ordinary chondritic sources to the micrometeorite flux on the Earth.     

Sr and Nd analyses of upper Eocene spherules and their implications for target rocks

Abstract— Upper Eocene impact ejecta has been discovered all over the world. The number of upper Eocene impact layers and the geographic distribution of each layer, based on major chemical composition and biostratigraphic data, are not agreed upon. We have performed four Sr‐Nd isotopic analyses of clinopyroxene‐bearing spherules (cpx spherules) and three Sr‐Nd analyses of microtektites from five Deep Sea Drilling Project/Ocean Drilling Program (DSDP/ODP) sites in the South Atlantic and Indian Oceans. Our data support the hypothesis that there is only one cpx spherule layer in upper Eocene sediments. We also find that the microtektites associated with the cpx spherule layer in the South Atlantic and Indian Oceans are not part of the North American tektite strewn field, but belong to the same event that produced the cpx spherules. The microtektites, together with cpx spherules, are more heterogeneous than microtektites/tektites from other strewn fields. No direct link has been established between the microtektites from this study and possible target rock at the Popigai crater.     

Crumbs from the crust of Vesta: Achondritic cosmic spherules from the South Pole water well

Abstract— Ten glass cosmic spherules (CS) from the South Pole water well collection were analyzed by electron microprobe. Nine of them have Fe/Mn and Fe/Mg ratios in the range typical of chondrites. One of them (SP37‐3), along with up to six other previously analyzed CS, have nonchondritic Fe/Mn and Fe/Mg ratios that agree well with values typical of either (basaltic) howardite, eucrite, and diogenite (HED) meteorites or Martian basalts, but not of lunar samples. SP37‐3 also contains an anorthite relic grain. Anorthite has not previously been reported in cosmic spherules, but is well known in HED meteorites. The much greater frequency of HEDs among hand‐sized meteorites suggests but does not prove that HED precursors are more likely for the nonchondritic spherules. We estimate that HED‐like micrometeorites constitute ～0.5 ± 0.4% of the total population of micrometeorites in the South Pole water well, a fraction that translates to a flux of 1.6 ± 0.3 × 10^?8g HED micrometeorites/m²‐y. The ratio of HED‐like objects to carbonaceous objects is about 100 times less in micrometeorites than among hand‐size specimens. We infer that the comparative mechanical weakness of carbonaceous precursor materials tends to encourage spherule formation.     

Ocean Drilling Project Hole 689B spherules and upper Eocene microtektite and clinopyroxene-bearing spherule strewn fields

Abstract— Montanari et al. (1993) reported a positive Ir anomaly in the upper Eocene sediments from Ocean Drilling Program Hole 689B on the Maud Rise, Southern Ocean. Vonhof (1998) described microtektites and clinopyroxene-bearing (cpx) spherules associated with the Ir anomaly in Hole 689B and suggested that they belong to the North American and equatorial Pacific cpx strewn fields, respectively. We searched a suite of 27 samples taken through the spherule layer from Hole 689B, and we recovered 386 microtektites and 667 cpx spherules. We studied the petrography of the microtektites and cpx spherules and determined the major element compositions of 31 microtektites and 14 cpx spherules using energy dispersive x-ray analysis. We also determined the minor element compositions of eight microtektites using instrumental neutron activation analysis. We found that the peak abundance of cpx spherules is ～2 cm below the peak abundance of the microtektites (～128.7 m below sea floor), which suggests that the cpx spherule layer may be slightly older (～3–5 ka). The microtektites are mostly spherical and are generally transparent and colorless. They are similar to the North American microtektites in composition, the biggest differences being their generally lower Na₂O and generally higher Zr, Ba, and Ir (up to 0.3 ppb) contents. We agree with Vonhof (1998) that the Hole 689B microtektites probably belong to the North American tektite strewn field. We calculate that the number of microtektites (>125 μm)/cm² at Hole 689B is 52. This number is close to the concentration predicted by extrapolation of the trend of concentration vs. distance from the Chesapeake Bay structure, based on data from other North American microtektite-bearing sites. Thus, the North American strewn field may be at least four times larger than previously mapped. The Hole 689B cpx spherules range from translucent yellow to opaque black, but most are opaque tan to dark brown. They are generally spherical in shape and all are < 125 μm in diameter. Some contain Ni-rich spinels in addition to clinopyroxene microlites. The cpx spherules are petrographically and compositionally similar to cpx spherules previously found in the northwestern Atlantic Ocean, Caribbean Sea, Gulf of Mexico, equatorial Pacific, and eastern Indian Ocean. The abundance and widespread geographic occurrence of these spherules suggest that the strewn field may be global in geographic extent. Assuming a global extent, we estimate that there may be at least 25 billion metric tons of cpx spherules in the strewn field. Based on age, size, and geographic location, we speculate that the 100 km diameter Popigai crater in northern Siberia may be the source of the cpx spherule layer.     

Micrometeorites from the northern ice cap of the Novaya Zemlya archipelago,Russia: The first occurrence

Abstract— Glacial deposits at the margins of the ice cap of the northern island of the Novaya Zemlya archipelago, Russia, contain numerous spherules and rare scoriaceous particles thought to be extraterrestrial. The 1 Kyr old glacier has decreased in volume and coverage during the last 40 years, leaving the spherules contained in the ice at the margins of the glacier where they can be easily collected. The spherules are similar in their appearance, texture, and mineralogy to cosmic spherules found in deep‐sea sediments in Greenland and Antarctica. Silicate spherules have typical bar‐like textures (75%) or porphyritic textures (15%), while other spherules are glassy (7%). The spherules from Novaya Zemlya are altered only slightly. There are spherules consisting of iron oxides, metal cores with iron oxide rims, a continuous network of iron oxide dendrites in a glass matrix, and particles rich in chromite (3%). Some spherules contain metal droplets and relict forsterite and low‐Ca pyroxene. Silicate spherule compositions match compositions of other cosmic spherules. Both Nova Zemlya and other cosmic spherules are close to carbonaceous chondrite matrices in patterns of variations for Ca, Mg, Si, and Al, which might suggest that their predecessor was similar to carbonaceous chondrite matrices. Unmelted micrometeorites are generally depleted in Ca and Mg and enriched in Al relative to cosmic spherules. The depletion of the micrometeorites in Ca and Mg can be connected with their terrestrial alteration (Kurat et al. 1994), while the Al enrichment seems to be primary.     

Chondritic micrometeorites from the Transantarctic Mountains

Abstract– On the basis of morphological and petrographic characteristics, eight “giant” unmelted micrometeorites in the 300–1100 μm size range were selected from the Transantarctic Mountain micrometeorite collection, Victoria Land, Antarctica. Mineralogical and geochemical data obtained by means of scanning electron microscopy, electron probe microanalyses, and synchrotron X‐ray diffraction allow their classification as chondritic micrometeorites. The large size of the micrometeorites increases considerably the amount of mineralogical and geochemical information compared to micrometeorites in smaller size fractions, therefore allowing a better definition of their parent material. A large variety of material is observed: five micrometeorites are related to unequilibrated and equilibrated ordinary chondrite, one to CV chondrite, one to CM chondrite, and one to CI chondrite parent materials. Besides reporting the first occurrence of a CV‐like micrometeorite, our study shows that the abundance of chondritic material supports observations from recent studies on cosmic spherules that a large part of the micrometeorite flux in this size range is of asteroidal origin.     

Late Eocene microkrystites and microtektites at Maud Rise (Ocean Drilling Project Hole 689B; Southern Ocean) suggest a global extension of the approximately 35.5 Ma Pacific impact ejecta strewn field

Abstract— Late Eocene microtektites and microkrystites recovered from Ocean Drilling Project Hole 689B at Maud Rise (Southern Ocean) are stratigraphically and geochemically compared to spherules from the North American and Pacific strewn fields, and to devitrified spherules from the Eocene-Oligocene global stratotype section and point section in Massignano, Italy. The ODP 689B microkrystites compare well to the Pacific strewn field microkrystites, which suggests that the geographic extent of the Pacific strewn field was much larger than previously documented. The elemental composition of microtektites of ODP Hole 689B is comparable to tektites of the North American strewn field. Their ⁸⁷Sr/⁸⁶Sr ratio, however, is different. We tentatively interpret this to reflect geochemical heterogeneity within the North American strewn field but can not exclude the option that the chemical discrepancies result from the existence of a third late Eocene impact site.     

Micrometer‐ and nanometer‐sized platinum group nuggets in micrometeorites from deep‐sea sediments of the Indian Ocean

Abstract– We examined 378 micrometeorites collected from deep‐sea sediments of the Indian Ocean of which 175, 180, and 23 are I‐type, S‐type, and G‐type, respectively. Of the 175 I‐type spherules, 13 contained platinum group element nuggets (PGNs). The nuggets occur in two distinct sizes and have distinctly different elemental compositions: micrometer (μm)‐sized nuggets that are >3 μm contain dominantly Ir, Os, and Ru (iridium‐platinum group element or IPGE) and sub‐μm (or nanometer)‐sized (<1 μm) nuggets, which contain dominantly Pt, Rh, and Pd (palladium—PGE or PPGE). The μm‐sized nuggets are found only one per spherule in the cross section observed and are usually found at the edge of the spherule. By contrast, there are hundreds of nanometer‐sized nuggets distributed dominantly in the magnetite phases of the spherules, and rarely in the wüstite phases. Both the nugget types are found as separate entities in the same spherule and apparently, nugget formation is a common phenomenon among I‐type micrometeorites. However, the μm‐sized nuggets are seen in fewer specimens (～2.5% of the observed I‐type spherules). In all, we analyzed four nuggets of μm size and 213 nanometer‐sized nuggets from 13 I‐type spherules for platinum group elements. Chemically, the μm‐sized PGNs contain chondritic ratios of Os/Ir, but are depleted in the more volatile PGE (Pt, Rh, and Pd) relative to chondritic ratios. On the other hand, the nanometer‐sized nuggets contain dominantly Pt and Rh. Importantly, the refractory PGEs are conspicuous by their absence in these nanometer nuggets. Palladium, the most volatile PGE is highly depleted (<1.1%) with respect to chondritic ratios in the μm‐sized PGNs, and is observed in only 17 of 213 nanometer nuggets with concentrations that are just above the detection limit (≥0.2%). Distinct fractionation of the PGE into IPGE (Ir, Os, Ru) and PPGE seems to take place during the short span of atmospheric entry. These observations suggest several implications: (1) The observation of fractionated PGE in an Fe‐Ni system gives rise to the possibility that Earth’s core could contain fractionated PGE. (2) The present data support the processes suggested for the fractionated PGE patterns observed in the ejecta of ancient meteorite impacts. (3) Meteoric metals released in the troposphere could contain fractionated PGNs in large numbers.     

Internal structure of type I deep‐sea spherules by X‐ray computed microtomography

Abstract— The internal structures of type I spherules (melted micrometeorites rich in iron) have been investigated using synchrotron‐based computed microtomography. Variations from sphericity are small—the average ratio of the largest to the smallest semimajor axis is 1.07 ± 0.06. The X‐ray tomographs reveal interior cavities, four spherules with metal cores with diameters ranging from 57 to 143 μm and, in two spherules, high attenuation features thought to be nuggets rich in platinumgroup elements. Bulk densities range from 4.2 to 5.9 g/cm³ and average grain densities from 4.5 to 6.5 (g/cm³) with uncertainties of 10–15%. The average grain densities are those expected for materials containing mostly oxides of iron and nickel. The tomographic density measurements indicate an average void space of 5⁺⁸_‐5%. The void spaces may be contraction features or the skeletons of bubbles that formed in the molten precursors during atmospheric passage.     

The origins of I‐type spherules and the atmospheric entry of iron micrometeoroids

The Earth's extraterrestrial dust flux includes a wide variety of dust particles that include FeNi metallic grains. During their atmospheric entry iron micrometeoroids melt and oxidize to form cosmic spherules termed I‐type spherules. These particles are chemically resistant and readily collected by magnetic separation and are thus the most likely micrometeorites to be recovered from modern and ancient sediments. Understanding their behavior during atmospheric entry is crucial in constraining their abundance relative to other particle types and the nature of the zodiacal dust population at 1 AU. This article presents numerical simulations of the atmospheric entry heating of iron meteoroids to investigate the abundance and nature of these materials. The results indicate that iron micrometeoroids experience peak temperatures 300–800 K higher than silicate particles explaining the rarity of unmelted iron particles which can only be present at sizes of <50 μm. The lower evaporation rates of liquid iron oxide leads to greater survival of iron particles compared with silicates, which enhances their abundance among micrometeorites by a factor of 2. The abundance of I‐types is shown to be broadly consistent with the abundance and size of metal in ordinary chondrites and the current day flux of ordinary chondrite‐derived MMs arriving at Earth. Furthermore, carbonaceous asteroids and cometary dust are suggested to make negligible contributions to the I‐type spherule flux. Events involving such objects, therefore, cannot be recognized from I‐type spherule abundances in the geological record.     

Fragmentation and hydration of tektites and microtektites

Abstract— An examination of data collected over the last 30 years indicates that the percent of glass fragments vs. whole splash forms in the Cenozoic microtektite strewn fields increases towards the source crater (or source region). We propose that this is due to thermal stress produced when tektites and larger microtektites fall into water near the source crater while still relatively hot (>1150 °C). We also find evidence (low major oxide totals, frothing when melted) for hydration of most of the North American tektite fragments and microtektites found in marine sediments. High-temperature mass spectrometry indicates that these tektite fragments and microtektites contain up to 3.8 wt% H₂O. The H₂O-release behavior during the high-temperature mass-spectrometric analysis, plus high CI abundances (0.05 wt%), indicate that the North American tektite fragments and microtektites were hydrated in the marine environment (i.e., the H₂O was not trapped solely on quenching from a melt). The younger Ivory Coast and Australasian microtektites do not exhibit much evidence of hydration (at least not in excess of 0.5 wt% H₂O); this suggests that the degree of hydration increases with age. In addition, we find that some glass spherules (with <65 wt% SiO₂) from the upper Eocene clinopyroxene-bearing spherule layer in the Indian Ocean have palagonitized rims. These spherules appear to have been altered in a similar fashion to the splash form K/T boundary spherules. Thus, our data indicate that tektites and microtektites that generally contain >65 wt% SiO₂ can undergo simple hydration in the marine environment, while impact glasses (with <65 wt% SiO₂) can also undergo palagonitization.     

A global rain of micrometeorites following breakup of the L‐chondrite parent body—Evidence from solar wind‐implanted Ne in fossil extraterrestrial chromite grains from China

Abstract– Previous studies of limestone beds of mid‐Ordovician age from both Sweden and China show that the Earth saw an at least two orders of magnitude increase in the influx of extraterrestrial material approximately 470 Ma, following the disruption of an L‐chondrite parent body in the asteroid belt. Recovered extraterrestrial material consists of fossil meteorites and sediment‐dispersed extraterrestrial chromite (SEC) grains, both with L‐chondritic origin. Ne isotope analysis of SEC grains from one of the Swedish limestone sections revealed that the vast majority of the grains were delivered to Earth as micrometeorites. In this study, we extend the previous work, both in time and geographically, by measuring concentrations and isotopic ratios of Ne in individual SEC grains (60–120 μm in diameter) from three different beds from a contemporary Middle Ordovician limestone section in China. All of the Chinese SEC grains, 44 in total, contain surface‐implanted Ne of fractionated solar wind composition, implying that these grains were, as in the case of the Swedish SEC grains, delivered to Earth as micrometeorites. This gives further compelling evidence that the two to three orders of magnitude increase in the influx of micrometeoritic material following the breakup of the L‐chondrite parent body was indeed a global event. The rain of micrometeorites prevailed for at least 2 Myr (the estimated time of the deposition of the topmost Chinese bed) after the breakup event.     

Characterization of Antarctic micrometeorites by thermoluminescence

Abstract— In order to explore the nature and history of micrometeorites, we have measured the thermoluminescence (TL) properties of four micrometeorites, three cosmic spherules, and one irregular scoriaceous particle, that we found in a survey of 17 micrometeorites. These micrometeorites have TL sensitivities ranging from 0.017 ± 0.002 to 0.087 ± 0.009 (on a scale normalized to 4 mg of the H3.9 chondrite Dhajala). The four micrometeorites have very similar TL peak temperatures and TL peak widths, and these distinguish them from CI, most CM, CV, CO, and ordinary chondrites. However, the TL properties of these micrometeorites closely resemble those of the unusual CM chondrite MacAlpine Hills (MAC) 87300 and terrestrial forsterites. Heating experiments on submillimeter chips of a CM chondrite and a H5 chondrite suggest that these TL properties are have not been significantly affected by atmospheric passage. Thus we suggest that there is no simple linkage between these micrometeorites and the established meteorite classes, and that forsterite is an important component of these micrometeorites, as it is in many primitive solar system materials.     

Density,porosity, mineralogy,and internal structure of cosmic dust and alteration of its properties during high‐velocity atmospheric entry

X‐ray microtomography (XMT), X‐ray diffraction (XRD), and magnetic hysteresis measurements were used to determine micrometeorite internal structure, mineralogy, crystallography, and physical properties at μm resolution. The study samples include unmelted, partially melted (scoriaceous), and completely melted (cosmic spherules) micrometeorites. This variety not only allows comparison of the mineralogy and porosity of these three micrometeorite types but also reveals changes in meteoroid properties during atmospheric entry at various velocities. At low entry velocities, meteoroids do not melt and their physical properties do not change. The porosity of unmelted micrometeorites varies considerably (0–12%) with one friable example having porosity around 50%. At higher velocities, the range of meteoroid porosity narrows, but average porosity increases (to 16–27%) due to volatile evaporation and partial melting (scoriaceous phase). Metal distribution seems to be mostly unaffected at this stage. At even higher entry velocities, complete melting follows the scoriaceous phase. Complete melting is accompanied by metal oxidation and redistribution, loss of porosity (1 ± 1%), and narrowing of the bulk (3.2 ± 0.5 g cm^?3) and grain (3.3 ± 0.5 g cm^?3) density range. Melted cosmic spherules with a barred olivine structure show an oriented crystallographic structure, whereas other subtypes do not.     

Petrography and geochemistry of ejecta from the Sudbury impact event

Ejecta from the Connors Creek site in Michigan (500 km from the Sudbury Igneous Complex [SIC]), the Pine River site in western Ontario (650 km from the SIC), and the Coleraine site in Minnesota (980 km from the SIC) were petrographically and geochemically analyzed. Connors Creek was found to have approximately 2 m of ejecta, including shocked quartz, melt droplets, and accretionary lapilli; Pine River has similar deposits about 1 m in thickness, although with smaller lapilli; Coleraine contains only impact spherules in a 20 cm‐thick layer (impact spherules being similar to microkrystites or microtektites). The ejecta transition from chaotic deposits of massively bedded impactoclastic material with locally derived detritus at Connors Creek to a deposit with apparently very little detrital material that is primarily composed of melt droplets at Pine River to a deposit that is almost entirely composed of melt spherules at Coleraine. The major and trace element compositions of the ejecta confirm the previously observed similarity of the ejecta deposits to the Onaping Formation in the SIC. Platinum‐group element (PGE) concentrations from each of the sites were also measured, revealing significantly elevated PGE contents in the spherule samples compared with background values. PGE abundances in samples from the Pine River site can be reproduced by addition of approximately 0.2 wt% CI chondrite to the background composition of the underlying sediments in the core. PGE interelement ratios indicate that the Sudbury impact event was probably caused by a chondritic impactor.     

MAJOR ELEMENT COMPOSITIONAL VARIATION WITHIN AND BETWEEN DIFFERENT LATE EOCENE MICROTEKTITE STREWNFIELDS

Major element compositional overlap exists between microspherules of different microtektite layers or strewnfields. For this reason, microspherules of similar composition cannot, a priori, be assumed to belong to the same microtektite event and those of different compositions cannot, a priori, be assumed to result from different events. Nevertheless, despite major element compositional overlap between microspherules of different strewnfields, multivariate factor analysis shows microtektites and related microspherules of three stratigraphically different late Eocene layers to follow recognizably different compositional trends. The microtektite population of the North American strewnfield (Globorotalia cerroazulensis Zone) follows compositionally well defined trends and is characterized by high concentrations of SiO₂, Al₂O₃, and TiO₂. The microspherule population of the slightly older crystal-bearing Globorotalia cerroazulensis Zone microspherule layer is more heterogeneous and characterized by microspherules which are relatively enriched in FeO and MgO and relatively impoverished in SiO₂ and TiO₂. The microspherule population of the oldest microspherule layer in the uppermost Globigerapsis semiinvoluta Zone is highly heterogeneous and characterized by microspherules which are relatively enriched in CaO and impoverished in Al₂O₃ and Na₂O. Individual microspherules of this oldest late Eocene horizon often exhibit major element compositions similar to those of the lower Gl. cerroazulensis Zone layer and occasionally exhibit major element compositions similar to North American layer microtektites. Nevertheless, late Eocene microspherule occurrences can be assigned to appropriate late Eocene microtektite horizons on the basis of major element compositional trends.     

Accumulation mechanisms of micrometeorites in an ancient supraglacial moraine at Larkman Nunatak,Antarctica

We report the discovery of a large accumulation of micrometeorites (MMs) in a supraglacial moraine at Larkman Nunatak in the Grosvenor Mountains of the Transantarctic Range in Antarctica. The MMs are present in abundances of ~600 particles kg⁻¹ of moraine sediment and include a near-complete collection of MM types similar to those observed in Antarctic blue ice and within bare-rock traps in the Antarctic. The size distribution of the observed particles is consistent with those collected from snow collections suggesting the moraine has captured a representative collection of cosmic spherules with significant loss of only the smallest particles (<100 μm) by wind. The presence of microtektites with compositions similar to those of the Australasian strewn field suggests the moraine has been accumulating for 780 ka with dust-sized debris. On the basis of this age estimate, it is suggested that accumulation occurs principally through ice sublimation. Direct infall of fines is suggested to be limited by snow layers that act as barriers to accumulation and can be removed by wind erosion. MM accumulation in many areas in Antarctica, therefore, may not be continuous over long periods and can be subject to climatic controls. On the basis of the interpretation of microtektites as Australasian, Larkman Nunatak deposit is the oldest known supraglacial moraine and its survival through several glacial maxima and interglacial periods is surprising. We suggest that stationary ice produced by the specific ice flow conditions at Larkman Nunatak explains its longevity and provides a new type of record of the East Antarctic ice sheet.     

Potassium isotope abundances in Australasian tektites and microtektites

Abstract— We report electron microprobe determinations of the elemental compositions of 11 Australasian layered tektites and 28 Australasian microtektites; and ion microprobe determinations of the ⁴¹K/³⁹K ratios of all 11 tektites and 13 of the microtektites. The elemental compositions agree well with literature values, although the average potassium concentrations measured here for microtektites, 1.1‐1.6 wt%, are lower than published average values, 1.9‐2.9 wt%. The potassium isotope abundances of the Australasian layered tektites vary little. The average value of ^δ41K, 0.02 ± 0.12%₀ (1 s? mean), is indistinguishable from the terrestrial value (= 0 by definition) as represented by our standard, thereby confirming four earlier tektite analyses of Humayun and Koeberl (2004). In agreement with those authors, we conclude that evaporation has significantly altered neither the isotopic nor the elemental composition of Australasian layered tektites for elements less volatile than potassium. Although the average ⁴¹K/³⁹K ratio of the microtektites, 1.1 ± 1.7%₀ (1 s? mean), is also statistically indistinguishable from the value for the standard, the individual ratios vary over a very large range, from ?10.6 ± 1.4%₀ to +13.8 ± 1.5%₀ and at least three of them are significantly different from zero. We interpret these larger variations in terms of the evaporation of isotopically light potassium; condensation of potassium in the vapor plume; partial or complete stirring and quenching of the melts; and the possible uptake of potassium from seawater. That the average ⁴¹K/³⁹K ratio of the microtektites equals the terrestrial value suggests that the microtektite‐forming system was compositionally closed with respect to potassium and less volatile elements. The possibility remains open that ⁴¹K/³⁹K ratios of microtektites vary systematically with location in the strewn field.