Geochemistry and 40Ar‐39Ar geochronology of impact‐melt clasts in feldspathic lunar meteorites: Implications for lunar bombardment history

Abstract— We studied 42 impact‐melt clasts from lunar feldspathic regolith breccias MacAlpine Hills (MAC) 88105, Queen Alexandra Range (QUE) 93069, Dar al Gani (DaG) 262, and DaG 400 for texture, chemical composition, and/or chronology. Although the textures are similar to the impactmelt clasts identified in mafic Apollo and Luna samples, the meteorite clasts are chemically distinct from them, having lower Fe, Ti, K, and P, thus representing previously unsampled impacts. The ⁴⁰Ar‐³⁹Ar ages on 31 of the impact melts, the first ages on impact‐melt samples from outside the region of the Apollo and Luna sampling sites, range from ～4 to ～2.5 Ga. We interpret these samples to have been created in at least six, and possibly nine or more, different impact events. One inferred impact event may be consistent with the Apollo impact‐melt rock age cluster at 3.9 Ga, but the meteorite impact‐melt clasts with this age are different in chemistry from the Apollo samples, suggesting that the mechanism responsible for the 3.9 Ga peak in lunar impact‐melt clast ages is a lunar‐wide phenomenon. No meteorite impact melts have ages more than 1s? older than 4.0 Ga. This observation is consistent with, but does not require, a lunar cataclysm.     

40Ar/39Ar and (U‐Th)/He model age signatures of elusive Mercurian and Venusian meteorites

No meteorites from Mercury and Venus have been conclusively identified so far. In this study, we develop an original approach based on extensive Monte Carlo simulations and diffusion models to explore the radiogenic argon (⁴⁰Ar*) and helium (⁴He*) loss behavior and the range of ⁴⁰Ar/³⁹Ar and (U‐Th)/He age signatures expected for a range of crystals if meteorites from these planets were ever to be found. We show that we can accurately date the crystallization age of a meteorite from both Mercury and Venus using the ⁴⁰Ar/³⁹Ar technique on clinopyroxene (± orthopyroxene) and that its ⁴⁰Ar/³⁹Ar age should match the Pb‐Pb age. At the surface of Mercury, phases like albite and anorthite will exhibit a complete range of ⁴⁰Ar* loss ranging from 0% to 100%, whereas merrillite and apatite will show 100% ⁴He* loss. By measuring the crystal size and diffusion parameters of a series of plagioclase crystals, one can inverse the ⁴⁰Ar* loss value to estimate the maximum temperature experienced by a rock, and narrow down the possible pre‐ejection location of the meteorite at the surface of Mercury. At the surface of Venus, plagioclase and phosphate phases will only record the age of ejection. The (U‐Th)/He systematics of merrillite and apatite will be, respectively, moderately and strongly affected by ⁴He* loss during the transit of the meteorite from its host planet to Earth. Finally, meteorites from Mercury or Venus will each have their own ⁴⁰Ar/³⁹Ar and (U‐Th)/He isotopic age and ³⁸Ar_c cosmic ray exposure age signatures over a series of different crystal types, allowing to unambiguously recognize a meteorite for any of these two planets using radiogenic and cosmogenic noble gases.     

39Ar‐40Ar “ages” and origin of excess 40Ar in Martian shergottites

Abstract— We report new ³⁹Ar‐⁴⁰Ar measurements on 15 plagioclase, pyroxene, and/or whole rock samples of 8 Martian shergottites. All age spectra suggest ages older than the meteorite formation ages, as defined by Sm‐Nd and Rb‐Sr isochrons. Employing isochron plots, only Los Angeles plagioclase and possibly Northwest Africa (NWA) 3171 plagioclase give ages in agreement with their formation ages. Isochrons for all shergottite samples reveal the presence of trapped Martian ⁴⁰Ar (⁴⁰Ar_xs), which exists in variable amounts in different lattice locations. Some ⁴⁰Ar_xs is uniformly distributed throughout the lattice, resulting in a positive isochron intercept, and other ⁴⁰Ar_xs occurs in association with K‐bearing minerals and increases the isochron slope. These samples demonstrate situations where linear Ar isochrons give false ages that are too old. After subtracting ⁴⁰Ar*that would accumulate by ⁴⁰K decay since meteorite formation and small amounts of terrestrial ⁴⁰Ar, all young age samples give similar ⁴⁰Ar_xs concentrations of ?1–2 × 10^?6cm³/g, but a variation in K content by a factor of ?80. Previously reported NASA Johnson Space Center data for Zagami, Shergotty, Yamato (Y‐) 000097, Y‐793605, and Queen Alexandra Range (QUE) 94201 shergottites show similar concentrations of ⁴⁰Ar_xs to the new meteorite data reported here. Similar ⁴⁰Ar_xs in different minerals and meteorites cannot be explained as arising from Martian atmosphere carried in strongly shocked phases such as melt veins. We invoke the explanation given by Bogard and Park (2008) for Zagami, that this ⁴⁰Ar_xs in shergottites was acquired from the magma. Similarity in ⁴⁰Ar_xs among shergottites may reveal common magma sources and/or similar magma generation and emplacement processes.     

High crustal diversity preserved in the lunar meteorite Mount DeWitt 12007 (Victoria Land,Antarctica)

The meteorite Mount DeWitt (DEW) 12007 is a polymict regolith breccia mainly consisting of glassy impact‐melt breccia particles, gabbroic clasts, feldspathic clasts, impact and volcanic glass beads, basaltic clasts, and mingled breccia clasts embedded in a matrix dominated by fine‐grained crystals; vesicular glassy veins and rare agglutinates are also present. Main minerals are plagioclase (typically An_>85) and clinopyroxene (pigeonites and augites, sometimes interspersed). The presence of tranquillityite, coupled with the petrophysical data, the O‐isotope data (Δ¹⁷O = ?0.075), and the FeO_tot/MnO ratios in olivine (91), pyroxene (65), and bulk rock (77) indicate a lunar origin for DEW 12007. Impactites consist of Al‐rich impact‐melt splashes and plagioclase‐rich meta‐melt clasts. The volcanic products belong to the very low titanium (VLT) or low titanium (LT) suites; an unusual subophitic fragment could be cryptomare‐related. Gabbroic clasts could represent part of a shallow intrusion within a volcanic complex with prevailing VLT affinity. DEW 12007 has a mingled bulk composition with relatively high incompatible element abundances and shows a high crustal diversity comprising clasts from the Moon's major terranes and rare lithologies. First‐order petrographic and chemical features suggest that DEW 12007 could be launch‐paired with other meteorites including Y 793274/981031, QUE 94281, EET 87521/96008, and NWA 4884.     

A Late Mesoproterozoic 40Ar/39Ar age for a melt breccia from the Keurusselkä impact structure,Finland

Field investigations in the eroded central uplift of the ≤30 km Keurusselkä impact structure, Finland, revealed a thin, dark melt vein that intersects the autochthonous shatter cone‐bearing target rocks near the homestead of Kirkkoranta, close to the center of the impact structure. The petrographic analysis of quartz in this melt breccia and the wall rock granite indicate weak shock metamorphic overprint not exceeding ~8–10 GPa. The mode of occurrence and composition of the melt breccia suggest its formation as some kind of pseudotachylitic breccia. ⁴⁰Ar/³⁹Ar dating of dark and clast‐poor whole‐rock chips yielded five concordant Late Mesoproterozoic miniplateau ages and one plateau age of 1151 ± 10 Ma [± 11 Ma] (2σ; MSWD = 0.11; P = 0.98), considered here as the statistically most robust age for the rock. The new ⁴⁰Ar/³⁹Ar age is incompatible with ~1.88 Ga Svecofennian tectonism and magmatism in south‐central Finland and probably reflects the Keurusselkä impact, followed by impact‐induced hydrothermal chloritization of the crater basement. In keeping with the crosscutting relationships in the outcrop and the possible influence of postimpact alteration, the Late Mesoproterozoic ⁴⁰Ar/³⁹Ar age of ~1150 Ma should be treated as a minimum age for the impact. The new ⁴⁰Ar/³⁹Ar results are consistent with paleomagnetic results that suggested a similar age for Keurusselkä, which is shown to be one of the oldest impact structures currently known in Europe and worldwide.     

40Ar/39Ar dating and cosmic‐ray exposure time of desert meteorites: Dhofar 300 and Dhofar 007 eucrites and anomalous achondrite NWA 011

Abstract— We performed high‐resolution ⁴⁰Ar‐³⁹Ar dating of mineral separates and whole‐rock samples from the desert meteorites Dhofar 300, Dhofar 007, and Northwest Africa (NWA) 011. The chronological information of all samples is dominated by plagioclase of varying grain size. The last total reset age of the eucrites Dhofar 300 and Dhofar 007 is 3.9 ± 0.1 Ga, coeval with the intense cratering period on the Moon. Some large plagioclase grains of Dhofar 007 possibly inherited Ar from a 4.5 Ga event characteristic for other cumulate eucrites. Due to disturbances of the age spectrum of NWA 011, only an estimate of 3.2–3.9 Ga can be given for its last total reset age. Secondary events causing partial ⁴⁰Ar loss ≤3.4 Ga ago are indicated by all age spectra. Furthermore, Ar extractions from distinct low temperature phases define apparent isochrons for all samples. These isochron ages are chronologically irrelevant and most probably caused by desert alterations, in which radiogenic ⁴⁰Ar and K from the meteorite and occasionally K induced by weathering are mixed, accompanied by incorporation of atmospheric Ar. Additional uptake of atmospheric Ar by the alteration phase(s) was observed during mineral separation (i.e., crushing and cleaning in ultrasonic baths). Consistent cosmic‐ray exposure ages were obtained from plagioclase and pyroxene exposure age spectra of Dhofar 300 (25 ± 1 Ma) and Dhofar 007 (13 ± 1 Ma) using the mineral's specific target element chemistry and corresponding ³⁸Ar production rates.     

40Ar‐39Ar chronology of lunar meteorites Northwest Africa 032 and 773

Abstract— The ⁴⁰Ar‐³⁹Ar dating technique has been applied to the lunar meteorites Northwest Africa 032 (NWA 032), an unbrecciated mare basalt, and Northwest Africa 773 (NWA 773), (composed of cumulate and breccia lithologies), to determine the crystallization age and timing of shock events these meteorites may have experienced. Stepped heating analyses of several different samples of NWA 032 gave complex age spectra but indistinguishable total ages with a mean of 2.779 ± 0.014 Gyr. Possible causes of the complex age spectra obtained from NWA 032 include recoil of ³⁹Ar, or the presence of pre‐shock ⁴⁰Ar incorporated into shock‐melt veins. The effects of shock veins were investigated by laser fusion of 20 small samples expected to contain varying proportions of the shock veins. The laser ages show a narrow age distribution between 2.61–2.86 Gyr and a mean of 2.73 ± 0.03 Gyr, identical to the total age of ?2.80 Gyr obtained for the bulk sample. Diffusion calculations based on the stepped heating data indicate that Ar release can be reconciled by release from feldspar (and possibly shock veins) at low temperatures followed by pyroxene at higher temperatures. The exposure age of NWA 032 is 212 ± 11 Myr, and it contains low trapped solar Ar. Stepped heating of cumulate and breccia portions of NWA 773 also give a relatively young age of 2.91 Gyr. The presence of trapped Ar in the breccia makes the age determination of this component less precise, but release of Ar appears to be from the same mineral phase, assumed to be plagioclase, in both lithologies. A marked difference in exposure age between the 2 lithologies also exists, with the breccia having spent 81 Myr longer at the lunar surface; this finding is consistent with the higher trapped Ar content of this lithology. Assuming that 2.80 Gyr and 2.91 Gyr are the crystallization ages of NWA 032 and NWA 773 respectively, these two meteorites are the youngest lunar mare basalts available for study.     

The bombardment history of the Moon as recorded by 40Ar‐39Ar chronology

New petrography and ⁴⁰Ar‐³⁹Ar ages have been obtained for 1–3 mm sized rock fragments from Apollo 16 Station 13 soil 63503 (North Ray crater ejecta) and chips from three rocks collected by Apollo 16 and Apollo 17 missions. Selection of these samples was aimed at the old ⁴⁰Ar‐³⁹Ar ages to understand the early history of the lunar magnetic field and impact flux. Fifteen samples were studied including crustal material, polymict feldspathic fragmental breccias, and impact melts. The impact ages obtained range between approximately 3.3 and 4.3 billion years (Ga). Polymict fragmental breccia 63503,1 exhibits the lowest signs of recrystallization observed and a probable old relic age of 4.547 ± 0.027. The plateau age of 4.293 ± 0.044 Ga obtained for impact melt rock 63503,13 represents the oldest known age for such a lithology. Possibly, this age represents the minimum age for the South Pole‐Aitken (SPA) Basin. In agreement with literature data, these results show that impact ages >3.9 Ga are found in lunar rocks, especially within soil 63503. Impact exhumation of deep‐seated warm crustal material onto the lunar surface is considered to explain the common 4.2 Ga ages obtained for weakly shocked samples from soil 63503 and Apollo 17. This would directly imply that one or more basin‐forming events occurred at that time. Some rock fragments showing none to limited petrologic features indicate thermal annealing. These rocks may have lost Ar while resident within the hot‐ejecta of a large basin. Concurrent with previous studies, these results lead us to advocate for a complex impact flux in the inner solar system during the initial approximately 1.3 Ga.     

The two Suvasvesi impact structures,Finland: Argon isotopic evidence for a “false” impact crater doublet

The two neighboring Suvasvesi North and South impact structures in central‐east Finland have been discussed as a possible impact crater doublet produced by the impact of a binary asteroid. This study presents ⁴⁰Ar/³⁹Ar geochronologic data for impact melt rocks recovered from the drilling into the center of the Suvasvesi North impact structure and melt rock from glacially transported boulders linked to Suvasvesi South. ⁴⁰Ar/³⁹Ar step‐heating analysis yielded two essentially flat age spectra indicating a Late Cretaceous age of ~85 Ma for the Suvasvesi North melt rock, whereas the Suvasvesi South melt sample gave a Neoproterozoic minimum (alteration) age of ~710 Ma. Although the statistical likelihood for two independent meteorite strikes in close proximity to each other is rather low, the remarkable difference in ⁴⁰Ar/³⁹Ar ages of >600 Myr for the two Suvasvesi impact melt samples is interpreted as evidence for two temporally separate, but geographically closely spaced, impacts into the Fennoscandian Shield. The Suvasvesi North and South impact structures are, thus, interpreted as a “false” crater doublet, similar to the larger East and West Clearwater Lake impact structures in Québec, Canada, recently shown to be unrelated. Our findings have implications for the reliable recognition of impact crater doublets and the apparent rate of binary asteroid impacts on Earth and other planetary bodies in the inner solar system.     

Evidence for multiple 4.0–3.7 Ga impact events within the Apollo 16 collection

In a histogram of lunar impact ages from the Apollo 16 site, there is a spike circa 3.9 Ga that has been interpreted to represent either a large number of nearly synchronous events or an abundance of samples that were affected slightly differently by the event that produced the Imbrium basin. To further scrutinize those age relationships, we extracted six centimeter‐sized clasts of impact melt from ancient regolith breccia 60016 and performed petrological and geochronological (⁴⁰Ar‐³⁹Ar) analyses. Three clasts have similar poikilitic textures, while others have porphyritic, aphanitic, or intergranular textures. Compositions and abundances of relict minerals are different in all six clasts and variously imply Mg‐suite and ferroan anorthosite target sequences. Estimated bulk compositions of four clasts are similar to previously defined group 1 Apollo 16 impact melt rocks, while the other two have higher Al₂O₃ and lower FeO+MgO compositions. All six clasts have similar K₂O and P₂O₅ concentrations, which could have been derived from a KREEP‐bearing component among target sequences. Eighteen ⁴⁰Ar/³⁹Ar analyses of the six clasts produced an age range from 3823 ± 75 to 4000 ± 23 Ma, consistent with estimates for the proposed late heavy bombardment. Four clasts have multiple temperature steps that define plateau ages. These ages are distinct, so they cannot be explained by a single impact event, such as the one that produced the Imbrium impact basin. The conclusion that these represent distinct ages remains after considering the possibility of artifacts in defining plateaus.     

The petrology,geochemistry, and age of lunar regolith breccias Miller Range 090036 and 090070: Insights into the crustal history of the Moon

Meteorites ejected from the surface of the Moon as a result of impact events are an important source of lunar material in addition to Apollo and Luna samples. Here, we report bulk element composition, mineral chemistry, age, and petrography of Miller Range (MIL) 090036 and 090070 lunar meteorites. MIL 090036 and 090070 are both anorthositic regolith breccias consisting of mineral fragments and lithic clasts in a glassy matrix. They are not paired and represent sampling of two distinct regions of the lunar crust that have protoliths similar to ferroan anorthosites. ⁴⁰Ar‐³⁹Ar chronology performed on two subsplits of MIL 090070,33 (a pale clast impact melt and a dark glassy melt component) shows that the sample underwent two main degassing events, one at ~3.88 Ga and another at ~3.65 Ga. The cosmic ray exposure data obtained from MIL 090070 are consistent with a short (~8–9 Ma) exposure close to the lunar surface. Bulk‐rock FeO, TiO₂, and Th concentrations in both samples were compared with 2‐degree Lunar Prospector Gamma Ray Spectrometer (LP‐GRS) data sets to determine areas of the lunar surface where the regolith matches the abundances observed on the sample. We find that MIL 090036 bulk rock is compositionally most similar to regolith surrounding the Procellarum KREEP Terrane, whereas MIL 090070 best matches regolith in the feldspathic highlands terrane on the lunar farside. Our results suggest that some areas of the lunar farside crust are composed of ferroan anorthosite, and that the samples shed light on the evolution and impact bombardment history of the ancient lunar highlands.     

40Ar/39Ar dating of the Araguainha impact structure,Mato Grosso,Brazil

Abstract— Pursuing the exploration of the Araguainha impact structure (Engelhardt et al., 1992), we present ⁴⁰Ar/³⁹Ar ages (1) of biotite samples from the granite, which forms the central uplift of the structure, and (2) of a melt rock, formed by the impact. Total degassing ages of biotites from granite samples range from 326 to 481 Ma. The variation is explained by Ar losses due to the oxidation of divalent Fe and by removal of K. The K loss depends on the time that the granite was exposed to weathering at particular outcrops. The oldest age of the least oxidized biotite from a granite sample, collected at a site most recently exposed, signifies that the ascending granite passed the 300° isotherm earlier than 481 Ma ago. Early Devonian Furnas sandstones, the oldest sediments exposed by the impact, were deposited on this granite basement 410–396 Ma ago. The ⁴⁰Ar/³⁹Ar analyses of two size fractions of an impact melt rock, resulting in plateau ages of 245.5 ± 3.5 Ma and 243.3 ± 3.0 Ma, respectively, indicate that the Araguainha impact occurred close to the Permian-Triassic boundary.     

Laser argon‐40‐argon‐39 age studies of Dar al Gani 262 lunar meteorite

Abstract— The laser ⁴⁰Ar‐³⁹Ar dating technique has been applied to the Dar al Gani (DaG) 262 lunar meteorite, a polymict highland regolith breccia, to determine the crystallisation age and timing of shock events experienced by this meteorite. Laser stepped‐heating analyses of three dominantly feldspathic fragments (DaG‐1, DaG‐2, and DaG‐3) revealed the presence of trapped Ar, mostly released at intermediate and high temperatures, with an ⁴⁰Ar/³⁶Ar value of ～2.8. Trapped Ar is most likely released from melt glass present as small veins within the fragments. The ⁴⁰Ar‐³⁹Ar ages determined for the three fragments are ～3.0 Ga for DaG‐1 and DaG‐2 and 2.0 Ga for DaG‐3 and probably relate to major impact events. Laser spot analyses were performed on a feldspathic clast, an impact crystalline melt basalt (ICMB), and the matrix in a polished section of DaG 262. The feldspathic and ICMB clasts have low contents of trapped Ar compared with that in the matrix. The feldspathic clast shows a wide range of ages from 3.0 to 1.7 Ga similar to those obtained by stepped heating. The younger age is interpreted as a minimum age for the last major event that assembled this meteorite. The ICMB shows two age clusters at 3.37 and 3.07 Ga, where the older age may be that of the impact event that formed the impact melt. Several cosmic‐ray exposure (CRE) ages were obtained as expected for a polymict regolith breccia. The CRE ages are 106 and 141 Ma for the feldspathic clast and the ICMB, respectively. One of the feldspathic fragments, DaG‐2, shows a range between 200–400 Ma. These CRE ages, which are similar to those determined for returned samples of the lunar regolith, indicate that the different components of DaG 262 experienced preexposure prior to assemblage of the meteorite.     

An Early Jurassic age for the Puchezh‐Katunki impact structure (Russia) based on 40Ar/39Ar data and palynology

The Puchezh‐Katunki impact structure, 40–80 km in diameter, located ~400 km northeast of Moscow (Russia), has a poorly constrained age between ~164 and 203 Ma (most commonly quoted as 167 ± 3 Ma). Due to its relatively large size, the Puchezh‐Katunki structure has been a prime candidate for discussions on the link between hypervelocity impacts and extinction events. Here, we present new ⁴⁰Ar/³⁹Ar data from step‐heating analysis of five impact melt rock samples that allow us to significantly improve the age range for the formation of the Puchezh‐Katunki impact structure to 192–196 Ma. Our results also show that there is not necessarily a simple relationship between the observed petrographic features of an impact melt rock sample and the obtained ⁴⁰Ar/³⁹Ar age spectra and inverse isochrons. Furthermore, a new palynological investigation of the postimpact crater lake sediments supports an age significantly older than quoted in the literature, i.e., in the interval late Sinemurian to early Pliensbachian, in accordance with the new radioisotopic age estimate presented here. The new age range of the structure is currently the most reliable age estimate of the Puchezh‐Katunki impact event.     

Thermal and irradiation history of lunar meteorite Dhofar 280

Dhofar 280 recorded a complex history on the Moon revealed by high‐resolution ⁴⁰Ar‐³⁹Ar dating. Thermal resetting occurred less than 1 Ga ago, and the rock was exposed to several impact events before and afterwards. The cosmic ray exposure (CRE) age spectrum indicates a 400 ± 40 Ma CRE on the lunar surface. A unique feature of this lunar sample is a partial loss of cosmogenic ³⁸Ar, resulting in a (low‐temperature) CRE age plateau of about 1 Ma. This was likely caused by the same recent impact event that reset the (low‐temperature) ⁴⁰Ar‐³⁹Ar age spectrum and preceded the short transit phase to Earth of ≤1 Ma. Dhofar 280 may be derived from KREEP‐rich lunar frontside terrains, possibly associated with the Copernicus crater or with a recent impact event on the deposits of the South Pole–Aitken basin. Although Dhofar 280 is paired with Dhofar 081, their irradiation and thermal histories on the Moon were different. An important trapped Ar component in Dhofar 280 is “orphan” Ar with a low ⁴⁰Ar/³⁶Ar ratio. It is apparently a mixture of two components, one endmember with ⁴⁰Ar/³⁶Ar = 17.5 ± 0.2 and a second less well‐constrained endmember with ⁴⁰Ar/³⁶Ar ≤10. The presence of two endmembers of trapped Ar, their compositions, and the breccia ages seem to be incompatible with a previously suggested correlation between age or antiquity and the (⁴⁰Ar/³⁶Ar)_trapped ratio (Eugster et al. 2001; Joy et al. 2011a). Alternatively, “orphan” Ar of this impact melt breccia may have an impact origin.     

40Ar‐39Ar age determinations of lunar basalt meteorites Asuka 881757, Yamato 793169, Miller Range 05035, La Paz Icefield 02205, Northwest Africa 479, and basaltic breccia Elephant Moraine 96008

Abstract— ⁴⁰Ar‐³⁹Ar data are presented for the unbrecciated lunar basaltic meteorites Asuka (A‐) 881757, Yamato (Y‐) 793169, Miller Range (MIL) 05035, LaPaz Icefield (LAP) 02205, Northwest Africa (NWA) 479 (paired with NWA 032), and basaltic fragmental breccia Elephant Moraine (EET) 96008. Stepped heating ⁴⁰Ar‐³⁹Ar analyses of several bulk fragments of related meteorites A‐881757, Y‐793169 and MIL 05035 give crystallization ages of 3.763 ± 0.046 Ga, 3.811 ± 0.098 Ga and 3.845 ± 0.014 Ga, which are comparable with previous age determinations by Sm‐Nd, U‐Pb Th‐Pb, Pb‐Pb, and Rb‐Sr methods. These three meteorites differ in the degree of secondary ⁴⁰Ar loss with Y‐793169 showing relatively high Ar loss probably during an impact event ?200 Ma ago, lower Ar loss in MIL 05035 and no loss in A‐881757. Bulk and impact melt glass‐bearing samples of LAP 02205 gave similar ages (2.985 ± 0.016 Ga and 2.874 ± 0.056 Ga) and are consistent with ages previously determined using other isotope pairs. The basaltic portion of EET 96008 gives an age of 2.650 ± 0.086 Ga which is considered to be the crystallization age of the basalt in this meteorite. The Ar release for fragmental basaltic breccia EET 96008 shows evidence of an impact event at 631 ± 20 Ma. The crystallization age of 2.721 ± 0.040 Ga determined for NWA 479 is indistinguishable from the weighted mean age obtained from three samples of NWA 032 supporting the proposal that these meteorites are paired. The similarity of ⁴⁰Ar‐³⁹Ar ages with ages determined by other isotopic systems for multiple meteorites suggests that the K‐Ar isotopic system is robust for meteorites that have experienced a significant shock event and not a prolonged heating regime.     

The Ar‐Ar age and petrology of Miller Range 05029: Evidence for a large impact in the very early solar system

Abstract– Miller Range (MIL) 05029 is a slowly cooled melt rock with metal/sulfide depletion and an Ar‐Ar age of 4517 ± 11 Ma. Oxygen isotopes and mineral composition indicate that it is an L chondrite impact melt, and a well‐equilibrated igneous rock texture with a lack of clasts favors a melt pool over a melt dike as its probable depositional setting. A metallographic cooling rate of approximately 14 °C Ma^?1 indicates that the impact occurred at least approximately 20 Ma before the Ar‐Ar closure age of 4517 Ma, possibly even shortly after accretion of its parent body. A metal grain with a Widmanstätten‐like pattern further substantiates slow cooling. The formation age of MIL 05029 is at least as old as the Ar‐Ar age of unshocked L and H chondrites, indicating that endogenous metamorphism on the parent asteroid was still ongoing at the time of impact. Its metallographic cooling rate of approximately 14 °C Ma^?1 is similar to that typical for L6 chondrites, suggesting a collisional event on the L chondrite asteroid that produced impact melt at a minimum depth of 5–12 km. The inferred minimum crater diameter of 25–60 km may have shattered the 100–200 km diameter L chondrite asteroid. Therefore, MIL 05029 could record the timing and petrogenetic setting for the observed lack of correlation of cooling rates with metamorphic grades in many L chondrites.     

Northwest Africa 482: A crystalline impact‐melt breccia from the lunar highlands

Abstract— Northwest Africa 482 (NWA 482) is a crystalline impact‐melt breccia from the Moon with highlands affinities. The recrystallized matrix and the clast population are both highly anorthositic. Clasts are all related to the ferroan anorthosite suite, and include isolated plagioclase crystals and lithic anorthosites, troctolites, and spinel troctolites. Potassium‐, rare‐earth‐element‐, and phosphorus‐bearing (KREEP) and mare lithologies are both absent, constraining the source area of this meteorite to a highland terrain with little to no KREEP component, most likely on the far side of the Moon. Glass is present in shock veins cutting through the sample and in several large melt pockets, indicating a second impact event. There are two separate events recorded in the ⁴⁰Ar‐³⁹Ar system: one at ～3750 Ma, which completely reset the K‐Ar system, and one at ?2400 Ma, which caused only partial degassing. These events could represent, respectively, crystallization of the impact‐melt breccia and later formation of the glass, or the formation of the glass and a later thermal event. The terrestrial age of the meteorite is 8.6 ± 1.3 ka. This age corresponds well with the modest amount of weathering in the rock, in the form of secondary phyllosilicates and carbonates. Based on terrestrial age and location, lithology, and chemistry, NWA 482 is unique among known lunar meteorites.     

Shergottites Dhofar 019, SaU 005, Shergotty,and Zagami: 40Ar‐39Ar chronology and trapped Martian atmospheric and interior argon

Abstract— We report a high‐resolution ⁴⁰Ar‐³⁹Ar study of mineral separates and whole‐rock samples of olivine‐phyric (Dhofar 019, Sayh al Uhaymir [SaU] 005) and basaltic (Shergotty, Zagami) shergottites. Excess argon is present in all samples. The highest (⁴⁰Ar/³⁶Ar)_trapped ratios are found for argon in pyroxene melt inclusions (?1500), maskelynite (?1200), impact glass (?1800) of Shergotty and impact glass of SaU 005 (?1200). A high (⁴⁰Ar/³⁶Ar)_trapped component‐usually uniquely ascribed to Martian atmosphere‐can also originate from the Martian interior, indicating a heterogeneous Martian mantle composition. As additional explanation of variable high (⁴⁰Ar/³⁶Ar)_trapped ratios in shocked shergottites, we suggest argon implantation from a “transient atmosphere” during impact induced degassing. The best ⁴⁰Ar‐³⁹Ar age estimate for Dhofar 019 is 642 ± 72 Ma (maskelynite). SaU 005 samples are between 700–900 Ma old. Relatively high ⁴⁰Ar‐³⁹Ar ages of melt inclusions within Dhofar 019 (1086 ± 252 Ma) and SaU 005 olivine (885 ± 66 Ma) could date entrapment of a magmatic liquid during early olivine crystallization, or reflect unrecognized excess ⁴⁰Ar components. The youngest ⁴⁰Ar‐³⁹Ar age of Shergotty separates (maskelynite) is ?370 Ma, that of Zagami is ?200 Ma. The ⁴⁰Ar‐³⁹Ar chronology of Dhofar 019 and SaU 005 indicate >1 Ga ages. Apparent ages uncorrected for trapped (e.g., Martian atmosphere, mantle) argon components approach 4.5 Ga, but are not caused by inherited ⁴⁰Ar, because excess ⁴⁰Ar is supported by ³⁶Ar_trapped. Young ages obtained by ⁴⁰Ar‐³⁹Ar and other chronometers argue for primary rather than secondary events. The cosmic ray exposure ages calculated from cosmogenic argon are 15.7 ± 0.7 Ma (Dhofar 019), 1.0–1.6 Ma (SaU 005), 2.1–2.5 Ma (Shergotty) and 2.2–3.0 Ma (Zagami).     

Establishing a 14.6 ± 0.2 Ma age for the Nördlinger Ries impact (Germany)—A prime example for concordant isotopic ages from various dating materials

Abstract– ⁴⁰Ar/³⁹Ar dating of recrystallized K‐feldspar melt particles separated from partially molten biotite granite in impact melt rocks from the approximately 24 km Nördlinger Ries crater (southern Germany) yielded a plateau age of 14.37 ± 0.30 (0.32) Ma (2σ). This new age for the Nördlinger Ries is the first age obtained from (1) monomineralic melt (2) separated from an impact‐metamorphosed target rock clast within (3) Ries melt rocks and therewith extends the extensive isotopic age data set for this long time studied impact structure. The new age goes very well with the ⁴⁰Ar/³⁹Ar step‐heating and laser probe dating results achieved from mixed‐glass samples (suevite glass and tektites) and is slightly younger than the previously obtained fission track and K/Ar and ages of about 15 Ma, as well as the K/Ar and ⁴⁰Ar/³⁹Ar age data obtained in the early 1990s. Taking all the ⁴⁰Ar/³⁹Ar age data obtained from Ries impact melt lithologies into account (data from the literature and this study), we suggest an age of 14.59 ± 0.20 Ma (2σ) as best value for the Ries impact event.