Shocked quartz grains in the polymict breccia of the Granby structure,Sweden–‐Verification of an impact

Abstract— The Middle Ordovician Granby structure in Sweden is generally considered the result of an asteroidal or cometary collision with Earth, although no hard evidence, i.e., shock metamorphic features or traces of the impactor, have been presented to date. In this study, drill core samples of a sedimentary breccia from the Granby structure have been investigated for microscopic shock metamorphic evidence in an attempt to verify the impact genesis of the structure. The finding of multiple sets of decorated planar deformation features (PDFs) in quartz grains in these samples provides unambiguous evidence that the structure is impact derived. Furthermore, the orientation of the PDFs, e.g., ω {101 }, π {101 } and r, z {101 }, is characteristic for impact deformation. The fact that a majority of the PDFs are decorated implies a water‐bearing target. The shocked quartz grains can be divided into two groups; rounded grains found in the breccia matrix likely originated from mature sandstone, and angular grains in fragments from crystalline target rocks. The absence of melt particles provides an estimated maximum shock pressure for the sedimentary derived quartz of 15–20 GPa and the frequency distribution of PDF orientations in the bedrock quartz implies pressures of the order of 10 GPa.     

Planar deformation features in quartz from impact‐produced polymict breccia of the Xiuyan crater,China

Abstract– The 1.8 km‐diameter Xiuyan crater is an impact structure in northeastern China, exposed in a Proterozoic metamorphic rock complex. The major rocks of the crater are composed of granulite, hornblendite, gneiss, tremolite marble, and marble. The bottom at the center of the crater covers about 100 m thick lacustrine sediments underlain by 188 m thick crater‐fill breccia. A layer of polymict breccia composed of clasts of granulite, gneiss, hornblendite, and fragments of glass as well as clastic matrix, occurs near the base, in the depth interval from 260 to 295 m. An investigation in quartz from the polymict breccia in the crater‐fill units reveals abundant planar deformation features (PDFs). Quartz with multiple sets of PDFs is found in clasts of granulite that consist of mainly quartz and feldspar, and in fine‐grained matrix of the impact‐produced polymict breccia. A universal stage was used to measure the orientation of PDFs in 70 grains of quartz from five thin sections made from the clasts of granulite of polymict breccia recovered at the depth of 290 m. Forty‐four percent of the quartz grains contain three sets of PDFs, and another 40% contain two sets of PDFs. The most abundant PDFs are rhombohedron forms of , , and with frequency of 33.5, 22.3, and 9.6%, respectively. A predominant PDF form of in quartz suggests a shock pressure >20 GPa. The occurrence of PDFs in quartz from the polymict breccia provides crucial evidence for shock metamorphism of target rocks and confirms the impact origin of this crater, which thus appears to be the first confirmed impact crater in China.     

Shocked rocks and impact glasses from the El'gygytgyn impact structure,Russia

Abstract— The El'gygytgyn impact structure is about 18 km in diameter and is located in the central part of Chukotka, arctic Russia. The crater was formed in volcanic rock strata of Cretaceous age, which include lava and tuffs of rhyolites, dacites, and andesites. A mid‐Pliocene age of the crater was previously determined by fission track (3.45 ± 0.15 Ma) and ⁴⁰Ar/³⁹Ar dating (3.58 ± 0.04 Ma). The ejecta layer around the crater is completely eroded. Shock‐metamorphosed volcanic rocks, impact melt rocks, and bomb‐shaped impact glasses occur in lacustrine terraces but have been redeposited after the impact event. Clasts of volcanic rocks, which range in composition from rhyolite to dacite, represent all stages of shock metamorphism, including selective melting and formation of homogeneous impact melt. Four stages of shocked volcanic rocks were identified: stage I (≤35 GPa; lava and tuff contain weakly to strongly shocked quartz and feldspar clasts with abundant PFs and PDFs; coesite and stishovite occur as well), stage II (35–45 GPa; quartz and feldspar are converted to diaplectic glass; coesite but no stishovite), stage III (45–55 GPa; partly melted volcanic rocks; common diaplectic quartz glass; feldspar is melted), and stage IV (>55 GPa; melt rocks and glasses). Two main types of impact melt rocks occur in the crater: 1) impact melt rocks and impact melt breccias (containing abundant fragments of shocked volcanic rocks) that were probably derived from (now eroded) impact melt flows on the crater walls, and 2) aerodynamically shaped impact melt glass “bombs” composed of homogeneous glass. The composition of the glasses is almost identical to that of rhyolites from the uppermost part of the target. Cobalt, Ni, and Ir abundances in the impact glasses and melt rocks are not or only slightly enriched compared to the volcanic target rocks; only the Cr abundances show a distinct enrichment, which points toward an achondritic projectile. However, the present data do not allow one to unambiguously identify a meteoritic component in the El'gygytgyn impact melt rocks.     

Characterization and significance of shocked quartz from the Woodleigh mpact structure,Western Australia

Abstract— We re‐examined the buried Woodleigh structure in Western Australia, which has been inferred to be a multi‐ringed, 120 km diameter impact crater, because the proposed size and possible synchronicity with one of the pre‐Mesozoic mass extinction events has attracted controversy. We undertook a detailed study of the petrology and mineralogy of a number of samples of core from the Woodleigh‐1 borehole that was drilled into the central uplift of the structure. Crystalline Proterozoic basement rocks comprising granites and gneisses in the Woodleigh‐1 core contain minor brecciation in discrete veins and reveal clear evidence of shock metamorphism over the full extent of the core. Imaging of laboratory‐etched quartz showed that a large number of grains contain shock deformation lamellae. Microstructural and crystallographic analysis of these lamellae by TEM showed that they are planar deformation features (PDFs) that have subsequently undergone annealing and water assisted recrystallization. The available geological, petrographic, and mineralogical evidence suggest that Woodleigh is an eroded impact crater that is nearer to 60 km than 120 km in diameter. Future drilling projects should better constrain the level of erosion, and may reveal any preserved impact lithologies.     

Shocked quartz grains from the Målingen structure,Sweden—Evidence for a twin crater of the Lockne impact structure

The Målingen structure in Sweden has for a long time been suspected to be the result of an impact; however, no hard evidence, i.e., shock metamorphic features or traces of the impactor, has so far been presented. Here we show that quartz grains displaying planar deformation features (PDFs) oriented along crystallographic planes typical for shock metamorphism are present in drill core samples from the structure. The shocked material was recovered from basement breccias, below the sediment infill, and the distribution of the orientation of the shock‐produced PDFs indicates that the studied material experienced low shock pressures. Based on our findings, we can exclude that the material is transported from the nearby Lockne impact structure, which means that the Målingen structure is a separate impact structure, the seventh confirmed impact structure in Sweden. Furthermore, sedimentological and biostratigraphic aspects of the deposits that fill the depression at Målingen are very similar to features at the Lockne impact structure. This implies a coeval formation age and thus also the confirmation of the first known marine target doublet impact craters on Earth (i.e., the Lockne–Målingen pair).     

Shock metamorphism investigations of quartz grains in clasts from impact breccia of the Eyreville B drill core,Chesapeake Bay impact structure,USA

Abstract– The Chesapeake Bay impact structure, approximately 85 km in diameter, has been drilled in 2005–2006 at Eyreville (Virginia, USA), to a total depth of 1766 m. In the drill cores, the abundance of shock metamorphosed material is very variable with depth. Shocked mineral and lithic clasts, as well as melt particles, are most abundant in suevitic impact breccia section (1397–1451 m depth). Shocked quartz (i.e., quartz grains with planar fractures and/or planar deformation features) and melt particles, although rare, are also dispersed in the Exmore Formation unit (444–867 m depth). Other lithologies in the Eyreville drill cores show no clear evidence of shock metamorphism. Here, we report on the investigations of 40 samples from the impact breccia section. A total of more than 27,000 quartz grains were examined in about 200 clasts. The abundance of highly shocked clasts tends to decrease with increasing depth. Crystalline clasts derived from the crystalline basement are commonly only slightly shocked (contain generally <10 rel% of shocked quartz grains). The clasts of metamorphosed sediments show a low proportion of shocked quartz grains (mostly <10 rel%). Sedimentary clasts show a wide range of proportions of shocked quartz grains, with several of them being highly shocked clasts (most values between 0 and 40 rel%). Conglomerates show the highest proportion of shocked quartz grains of all types of clasts (up to 83 rel%). Polycrystalline quartz clasts are also commonly highly shocked (contain mostly between 10 and 40 rel% of shocked quartz grains). These hard nonporous clasts are possibly more liable to show evidence of shock. The investigations suggest that the intensity of shock metamorphism is the result of several parameters, such as original position in the target (both horizontal and vertical) and the properties of each lithology (e.g., grain size, porosity, and amount of matrix). According to the universal‐stage investigations, the dominant orientations of planar deformation features in quartz are , , and also .     

Libyan Desert Glass area in western Egypt: Shocked quartz in bedrock points to a possible deeply eroded impact structure in the region

Libyan Desert Glass (LDG) is an enigmatic natural glass, about 28.5 million years old, which occurs on the floor of corridors between sand dunes of the southwestern corner of the Great Sand Sea in western Egypt, near the Libyan border. The glass occurs as centimeter‐ to decimeter‐sized, irregularly shaped, and strongly wind‐eroded pieces. The origin of the LDG has been the subject of much debate since its discovery, and a variety of exotic processes were suggested, including a hydrothermal sol‐gel process or a lunar volcanic source. However, evidence of an impact origin of these glasses included the presence of schlieren and partly or completely digested minerals, such as lechatelierite, baddeleyite (a high‐T breakdown product of zircon), and the presence of a meteoritic component in some of the glass samples. The source material of the glass remains an open question. Geochemical data indicate that neither the local sands nor sandstones from various sources in the region are good candidates to be the sole precursors of the LDG. No detailed studies of all local rocks exist, though. There are some chemical and isotopic similarity to rocks from the BP and Oasis impact structures in Libya, but no further evidence for a link between these structures and LDG was found so far. These complications and the lack of a crater structure in the area of the LDG strewn field have rendered an origin by airburst‐induced melting of surface rocks as a much‐discussed alternative. About 20 years ago, a few shocked quartz‐bearing breccias (float samples) were found in the LDG strewn field. To study this question further, several basement rock outcrops in the LDG area were sampled during three expeditions in the area. Here we report on the discovery of shock‐produced planar microdeformation features, namely planar fractures (PFs), planar deformation features (PDFs), and feather features (FFs), in quartz grains from bedrock samples. Our observations show that the investigated samples were shocked to moderate pressure, of at least 16 GPa. We interpret these observations to indicate that there was a physical impact event, not just an airburst, and that the crater has been almost completely eroded since its formation.     

Shocked lithologies at the Wanapitei impact structure,Ontario, Canada

Abstract The ～7.5 km diameter Wanapitei impact structure (46°45′N; 80°45′W) lies entirely within Lake Wanapitei in central Ontario, Canada. Impact lithologies are known only from glacial float at the southern end of the lake. Over 50% of the impact lithologies recovered from this float can be classified as suevite, <20% as highly shocked and partially melted arkosic metasediments of the target rock Mississagi Formation or, possibly, the Serpent Formation and <20% as glassy impact melt rocks. An additional <5% of the samples have similarities to the suevite but have up to 50% glass clasts and are tentatively interpreted as fall-back material. The glassy impact melt rocks fall into two textural and mineralogical types: a perlitically fractured, colorless glass matrix variant, with microlites of hypersthene with up to 11.5% Al₂O₃ and a “felted” matrix variant, with evidence of flow prior to the crystallization of tabular orthopyroxene. These melt glasses show chemical inhomogeneities on a microscopic scale, with areas of essentially SiO₂, even when appearing optically homogeneous. They are similar in bulk composition for major elements, but the felted matrix variant is ～5×more enriched in Ni, Co and Cr, the interelement ratios of which are indicative of an admixture of a chondritic projectile. Mixing models suggest that the glassy impact melt rocks can be made from the target rocks in the proportions: ～55% Gowganda wacke, ～42% Serpent arkose and ～3% Nipissing intrusives. Geologic reconstructions suggest that this is a reasonable mixture of potential target rocks at the time of impact.     

Geochemical evidence of an extraterrestrial component in impact melt breccia from the Paleoproterozoic Dhala impact structure,India

The Paleoproterozoic Dhala structure with an estimated diameter of ~11 km is a confirmed complex impact structure located in the central Indian state of Madhya Pradesh in predominantly granitic basement (2.65 Ga), in the northwestern part of the Archean Bundelkhand craton. The target lithology is granitic in composition but includes a variety of meta‐supracrustal rock types. The impactites and target rocks are overlain by ~1.7 Ga sediments of the Dhala Group and the Vindhyan Supergroup. The area was cored in more than 70 locations and the subsurface lithology shows pseudotachylitic breccia, impact melt breccia, suevite, lithic breccias, and postimpact sediments. Despite extensive erosion, the Dhala structure is well preserved and displays nearly all the diagnostic microscopic shock metamorphic features. This study is aimed at identifying the presence of an impactor component in impact melt rock by analyzing the siderophile element concentrations and rhenium‐osmium isotopic compositions of four samples of impactites (three melt breccias and one lithic breccia) and two samples of target rock (a biotite granite and a mafic intrusive rock). The impact melt breccias are of granitic composition. In some samples, the siderophile elements and HREE enrichment observed are comparable to the target rock abundances. The Cr versus Ir concentrations indicate the probable admixture of approximately 0.3 wt.% of an extraterrestrial component to the impact melt breccia. The Re and Os abundances and the ¹⁸⁷Os/¹⁸⁸Os ratio of 0.133 of one melt breccia specimen confirm the presence of an extraterrestrial component, although the impactor type characterization still remains inconclusive.     

Shocked quartz grains in the early Cambrian Vakkejokk Breccia,Sweden—Evidence of a marine impact

Here we present a study of the abundance and orientation of planar deformation features (PDFs) in the Vakkejokk Breccia, a proposed lower Cambrian impact ejecta layer in the North‐Swedish Caledonides. The presence of PDFs is widely accepted as evidence for shock metamorphism associated with cosmic impact events and their presence confirms that the Vakkejokk Breccia is indeed the result of an impact. The breccia has previously been divided into four lithological subunits (from bottom to top), viz. lower polymict breccia (LPB), graded polymict breccia (GPB), top sandstone (TS), and top conglomerate (TC). Here we show that the LPB contains no shock metamorphic features, indicating that the material derives from just outside of the crater and represents low‐shock semi‐autochthonous bombarded strata. In the overlying, more fine‐grained GPB and TS, quartz grains with PDFs are relatively abundant (2–5% of the grain population), and with higher shock levels in the upper parts, suggesting that they have formed by reworking of more distal ejecta by resurge of water toward the crater in a marine setting. The absence of shocked quartz grains in the TC indicates that this unit represents later slumps associated with weathering and erosion of the protruding crater rim. Sparse shocked quartz grains (<0.2%) were also found in sandstone beds occurring at the same stratigraphic level as the Vakkejokk Breccia 15–20 km from the inferred crater site. It is currently unresolved whether the sandstone at these distal sites is related to the impact or just contains rare reworked quartz grains with PDFs.     

Tookoonooka, a large buried early Cretaceous impact structure in the Eromanga Basin of southwestern Queensland, Australia

Abstract— The ～66 km wide Tookoonooka impact structure (27°07′S, 142°50′E) was first recognised, from seismic profiles, as a circular structure consisting of a concentric arrangement of anticlines and synclines, which surround a complex central dome, ～22 km wide. A gravity low and a central magnetic high characterize the structure. Now buried by up to 900 m of Cretaceous and Tertiary clastic sediments, the Tookoonooka structure was formed ～128 Ma ago, during deposition of the paralic Cadna-owie Formation. Thin sections from a centrally located exploration well reveal an impact melt breccia, composed of local Ordovician quartz-mica schist bedrock. Detailed study of planar deformation features (PDFs) in quartz grains from this breccia show 64 lamellae sets in 25 grains. Most of the PDF measurements correspond to ζ {112～2} andr/z {101～1}/ {011～1} crystallographic indices, with five other orientations also measured. This distribution of PDFs corresponds to that found in quartz from impact structures in porous sedimentary rock targets, thus confirming an impact origin for Tookoonooka.     

Annealing of radiation damage in zircons from Apollo 14 impact breccia 14311: Implications for the thermal history of the breccia

Impact breccia 14311, was collected from the Apollo 14 landing site as a potential sample of the underlying Fra Mauro Formation. Published zircon U‐Pb ages of >4000 Ma date the source material of the breccia and the apatite U‐Pb age of ~3940 Ma is interpreted as dating thermal resetting of the apatite U‐Pb systems. In this contribution we present new age information on the late stage thermal history of the breccia based on the annealing of radiation damage in the zircons. From Raman spectroscopic determination of the radiation damage within SIMS analytical spots on the zircons and the U and Th concentrations determined on these spots, we demonstrate that the radiation damage in the zircons has been annealed and we estimate the age of annealing at 3410 ± 80 Ma. This age is interpreted as a cooling age following heating of the breccia to above the annealing temperature of ~230 °C for stage 1 radiation damage in zircon, but below the temperature needed to reset the U‐Pb system of apatite (~500 °C). It is proposed that this thermal event was associated with the prolonged period of Mare volcanism, from 3150 to 3750 Ma, that generated massive basalt flows in the vicinity of the sample location.     

A Late Mesoproterozoic 40Ar/39Ar age for a melt breccia from the Keurusselkä impact structure,Finland

Field investigations in the eroded central uplift of the ≤30 km Keurusselkä impact structure, Finland, revealed a thin, dark melt vein that intersects the autochthonous shatter cone‐bearing target rocks near the homestead of Kirkkoranta, close to the center of the impact structure. The petrographic analysis of quartz in this melt breccia and the wall rock granite indicate weak shock metamorphic overprint not exceeding ~8–10 GPa. The mode of occurrence and composition of the melt breccia suggest its formation as some kind of pseudotachylitic breccia. ⁴⁰Ar/³⁹Ar dating of dark and clast‐poor whole‐rock chips yielded five concordant Late Mesoproterozoic miniplateau ages and one plateau age of 1151 ± 10 Ma [± 11 Ma] (2σ; MSWD = 0.11; P = 0.98), considered here as the statistically most robust age for the rock. The new ⁴⁰Ar/³⁹Ar age is incompatible with ~1.88 Ga Svecofennian tectonism and magmatism in south‐central Finland and probably reflects the Keurusselkä impact, followed by impact‐induced hydrothermal chloritization of the crater basement. In keeping with the crosscutting relationships in the outcrop and the possible influence of postimpact alteration, the Late Mesoproterozoic ⁴⁰Ar/³⁹Ar age of ~1150 Ma should be treated as a minimum age for the impact. The new ⁴⁰Ar/³⁹Ar results are consistent with paleomagnetic results that suggested a similar age for Keurusselkä, which is shown to be one of the oldest impact structures currently known in Europe and worldwide.     

Weathering features in shocked quartz from the Ries impact crater,Germany

Abstract— Shocked quartz from the ejecta of the Ries impact structure has been investigated by analytical transmission electron microscopy (ATEM). Quartz grains display numerous planar fractures (PFs) and planar deformation features (PDFs). Both are partly or fully replaced by a mineral of the kaolinite group (likely halloysite). Its formation involves fluid circulation into the dense fracture networks, dissolution and removal of the amorphous phase initially present in PDFs, and finally, precipitation and crystallization of the kaolinite group mineral from solutions resulting from the chemical alteration of adjacent minerals (feldspars and biotite). Kaolinite group minerals are typical of hydrothermal alteration at low temperature, in humid climate, and under moderately acid conditions and, thus, this alteration may not be directly related to the impact event itself. However, the weathering features were strongly enhanced by the shock‐generated microstructure, in particular by fractures that provided pathways for fluid circulation.     

Young asteroid mixing revealed in ordinary chondrites: The case of NWA 5764, a polymict LL breccia with L clasts

Polymict chondritic breccias—rocks composed of fragments originating from different chondritic parent bodies—are of particular interest because they give insights into the mixing of asteroids in the main asteroid belt (occurrence, encounter velocity, transfer time). We describe Northwest Africa (NWA) 5764, a brecciated LL6 chondrite that contains a >16 cm³ L4 clast. The L clast was incorporated in the breccia through a nondestructive, low‐velocity impact. Identical cosmic‐ray exposure ages of the L clast and the LL host (36.6 ± 5.8 Myr), suggest a short transfer time of the L meteoroid to the LL parent body of 0.1 ± 8.1 Myr, if that meteoroid was no larger than a few meters. NWA 5764 (together with St. Mesmin, Dimmitt, and Glanerbrug) shows that effective mixing is possible between ordinary chondrite parent bodies. In NWA 5764 this mixing occurred after the peak of thermal metamorphism on the LL parent body, i.e., at least several tens of Myr after the formation of the solar system. The U,Th‐He ages of the L clast and LL host, identical at about 2.9 Ga, might date the final assembly of the breccia, indicating relatively young mixing in the main asteroid belt as previously evidenced in St. Mesmin.     

Suevite breccia from the Ries crater,Germany: Origin,cooling history and devitrification of impact glasses

Abstract— The distribution and petrography of surficial suevite breccias of the Ries impact crater in Southern Germany are reviewed, and the morphology, petrography and chemical composition of impact glasses in suevite breccias and their postdepositional devitrification is synthesized. Origin and thermal history of suevite breccia and suevite glasses are inferred from these data and from recent results of cooling and crystallization experiments with suevite glass melts under controlled conditions. In a montmorillonitic groundmass, the suevite breccia contains pieces of glass, up to some decimeters in size, and crystalline rock clasts of all stages of shock metamorphism. The glass particles originated in impact melt of basement gneisses and cooled by adiabatic pressure release from ～80 GPa to atmospheric pressure during ejection from the crater. They were deposited on the ground together with the other suevite components at a temperature of ～750 °C. Fractured glass pieces in the breccia show that during deposition of the suevite the temperature was below the temperature at which undercooled melt transforms to rigid glass. The suevite cooled after deposition mainly by convection of heat by emanating gases and vapors. In chilled layers at the base and at the top of suevite deposits, the glasses are preserved in vitreous state. Between these zones, the glasses were devitrified, yet crystallization of pyroxene, plagioclase and magnetite took place below the glass-transformation temperature. Annealing experiments show that this unusual devitrification below the transformation temperature can be explained by the impact origin of suevite glasses. Due to rapid adiabatic cooling on decompression, the glasses were oversaturated with water and internally strained. Under these conditions, devitrification, especially the formation of plagioclase, was possible at temperatures below the transformation range. The origin from adiabatically cooled impact melt of deep-seated rocks distinguishes water-bearing suevite glasses from the Ries-derived, water-free moldavite tektites, which are interpreted as condensates of vaporized, surficial sediments (Engelhardt et al., 1987).     

Coesite in suevites from the Chesapeake Bay impact structure

The occurrence of coesite in suevites from the Chesapeake Bay impact structure is confirmed within a variety of textural domains in situ by Raman spectroscopy for the first time and in mechanically separated grains by X‐ray diffraction. Microtextures of coesite identified in situ investigated under transmitted light and by scanning electron microscope reveal coesite as micrometer‐sized grains (1–3 μm) within amorphous silica of impact‐melt clasts and as submicrometer‐sized grains and polycrystalline aggregates within shocked quartz grains. Coesite‐bearing quartz grains are present both idiomorphically with original grain margins intact and as highly strained grains that underwent shock‐produced plastic deformation. Coesite commonly occurs in plastically deformed quartz grains within domains that appear brown (toasted) in transmitted light and rarely within quartz of spheroidal texture. The coesite likely developed by a mechanism of solid‐state transformation from precursor quartz. Raman spectroscopy also showed a series of unidentified peaks associated with shocked quartz grains that likely represent unidentified silica phases, possibly including a moganite‐like phase that has not previously been associated with coesite.     

Sedimentological analysis of two drill cores through the crater moat‐filling breccia,Flynn Creek impact structure,Tennessee

Sedimentological (line‐logging) analysis of two drill cores, FC77‐3 and FC67‐3, situated, respectively, in the northwestern and southeastern quadrants of the Flynn Creek impact structure's crater‐moat area reveals that the ~27 m thick crater moat‐filling breccia consists of three subequal parts. These parts, which were deposited during early modification stage of this marine‐target impact structure, are distinguished on the basis of vertical trends in sorting, grain size, and counts of clasts per meter in comparison with other well‐known marine‐target impact structures, namely Lockne, Tvären, and Chesapeake Bay. The lower part is interpreted to represent mainly slump deposits, and the middle part is interpreted to represent a stage intermediate between slump and marine resurge, that is, a traction flow driven by overriding suspension flow. The upper part (size graded, and relatively well sorted and fine grained) is interpreted to represent marine resurge flow only. The upper part is capped by a relatively thin and relatively fine‐grained calcarenite to calcisiltite deposit.     

Multiple impact events on the L-chondritic parent body: Insights from SIMS U-Pb dating of Ca-phosphates in the NWA 7251 L-melt breccia

Here we report in situ secondary ionization mass spectrometry Ca-phosphate U-Pb ages for an L-impact melt breccia (NWA 7251), which are integrated with petrological and mineral chemical studies of this meteorite. NWA 7251 is a heavily shocked rock that is composed mainly of the chondrite host, impact melt portion, and melt veins (crosscutting and pervasive type). The host is an L4 chondrite that has been shocked to S4. The impact melt portion has a fine-grained igneous texture, and is composed mainly of olivine, low-Ca pyroxene, high-Ca pyroxene, and albitic glass. The impact melt was generated at pressure of >30–35 GPa and temperature of >1300–1500 °C during an impact event. The Ca-phosphate grains in the host were affected by a shock heating event. Most of the Ca-phosphate grains in the melt were neocrystallized, but relatively large grains enclosed by or adjacent to metal veins or melt globules are likely inherited. The U-Pb isotopic systematics of Ca-phosphates in NWA 7251 yield an upper intercept age of 4457 ± 56 Ma and a lower intercept age of 574 ± 82 Ma on the normal U-Pb concordia diagram. The age of 4457 ± 56 Ma is interpreted to be related to an early shocking event rather than the thermal metamorphism of the parent body. The impact melt and veins in NWA 7251 were generated at 574 ± 82 Ma, resulting from disruption of the L chondrite parent body.