Kaitianite,Ti3+2Ti4+O5, a new titanium oxide mineral from Allende

Kaitianite, Ti³⁺₂Ti⁴⁺O₅, is a new titanium oxide mineral discovered in the Allende CV3 carbonaceous chondrite. The type grain coexists with tistarite (Ti₂O₃) and rutile. Corundum, xifengite, mullite, osbornite, and a new Ti,Al,Zr‐oxide mineral are also present, although not in contact. The chemical composition of type kaitianite is (wt%) Ti₂O₃ 56.55, TiO₂ 39.29, Al₂O₃ 1.18, MgO 1.39, FeO 0.59, V₂O₃ 0.08 (sum 99.07), yielding an empirical formula of (Ti³⁺_1.75Al_0.05Ti⁴⁺_0.10Mg_0.08Fe_0.02)(Ti⁴⁺_1.00)O₅, with Ti³⁺ and Ti⁴⁺ partitioned, assuming a stoichiometry of three cations and five oxygen anions pfu. The end‐member formula is Ti³⁺₂Ti⁴⁺O₅. Kaitianite is the natural form of γ‐Ti₃O₅ with space group C2/c and cell parameters a = 10.115 Å, b = 5.074 Å, c = 7.182 Å, β = 112°, V = 341.77 Å³, and Z = 4. Both the type kaitianite and associated rutile likely formed as oxidation products of tistarite at temperatures below 1200 K, but this oxidation event could have been in a very reducing environment, even more reducing than a gas of solar composition. Based on experimental data on the solubility of Ti³⁺ in equilibrium with corundum from the literature, the absence of tistarite in or on Ti³⁺‐rich corundum (0.27–1.45 mol% Ti₂O₃) suggests that these grains formed at higher temperatures than the kaitianite (>1579–1696 K, depending on the Ti concentration). The absence of rutile or kaitianite in or on corundum suggests that any exposure to the oxidizing environment producing kaitianite in tistarite was too short to cause the precipitation of Ti‐oxides in or on associated corundum.     

Liebermannite,KAlSi3O8, a new shock-metamorphic,high-pressure mineral from the Zagami Martian meteorite

In this paper, we discuss the occurrence of liebermannite (IMA 2013-128), KAlSi₃O₈, a new, shock-generated, high-pressure tetragonal hollandite-type structure silicate mineral, in the Zagami basaltic shergottite meteorite. Liebermannite crystallizes in space group I4/m with Z = 2, cell dimensions of a = 9.15 ± 0.14 (1σ) Å, c = 2.74 ± 0.13 Å, and a cell volume of 229 ± 19 Å³ (for the type material), as revealed by synchrotron diffraction. In Zagami, liebermannite likely formed via solid-state transformation of primary igneous K-feldspar during an impact event that achieved pressures of ~20 GPa or more. The mineral name is in honor of Robert C. Liebermann, a high-pressure mineral physicist at Stony Brook University, New York, USA.     

Druse clinopyroxene in D'Orbigny angritic meteorite studied by single‐crystal X‐ray diffraction,electron microprobe analysis,and Mössbauer spectroscopy

Abstract— The crystal structure of druse clinopyroxene from the D'Orbigny angrite, (Ca_0.944 Fe²⁺_0.042 Mg_0.010Mn_0.004) (Mg_0.469Fe²⁺_0.317Fe³⁺_0.035Al_0.125Cr_0.010Ti_0.044) (Si_1.742Al_0.258) O₆, a = 9.7684(2), b = 8.9124(2), c = 5.2859(1) Å, β = 105.903(1)°, V = 442.58 ų, space group C2/c, Z = 2, has been refined to an R₁ index of 1.92% using single‐crystal X‐ray diffraction data. The unit formula, calculated from electron microprobe analysis, and the refined site scattering values were used to assign site populations. The distribution of Fe²⁺and Mg over the M1 and M2 sites suggests a closure temperature of 1000 °C. Mössbauer spectroscopy measurements were done at room temperature on a single crystal and a powdered sample. The spectra are adequately fit by a Voigt‐based quadrupole‐splitting distribution model having two generalized sites, one for Fe²⁺with two Gaussian components and one for Fe³⁺with one Gaussian component. The two ferrous components are assigned to Fe²⁺at the M1 site, and arise from two different next‐nearest‐neighbor configurations of Ca and Fe cations at the M2 site: (3Ca,0Fe) and (2Ca,1Fe). The Fe³⁺/Fe_tot ratio determined by Mössbauer spectroscopy is in agreement with that calculated from the electron microprobe analysis. The results are discussed in connection with the redox and thermal history of D'Orbigny.     

The iron record of asteroidal processes in carbonaceous chondrites

The valence of iron has been used in terrestrial studies to trace the hydrolysis of primary silicate rocks. Here, we use a similar approach to characterize the secondary processes, namely thermal metamorphism and aqueous alteration, that have affected carbonaceous chondrites. X‐ray absorption near‐edge structure spectroscopy at the Fe‐K‐edge was performed on a series of 36 CM, 9 CR, 10 CV, and 2 CI chondrites. While previous studies have focused on the relative distribution of Fe⁰ with respect to oxidized iron (Fe_ox = Fe²⁺ + Fe³⁺) or the iron distribution in some specific phases (e.g., Urey–Craig diagram; Urey and Craig 1953), our measurements enable us to assess the fractions of iron in each of its three oxidation states: Fe⁰, Fe²⁺, and Fe³⁺. Among the four carbonaceous chondrites groups studied, a correlation between the iron oxidation index (IOI = [2(Fe²⁺) + 3(Fe³⁺)]/[Fe_TOT]) and the hydrogen content is observed. However, within the CM group, for which a progressive alteration sequence has been defined, a conversion of Fe³⁺ to Fe²⁺ is observed with increasing degree of aqueous alteration. This reduction of iron can be explained by an evolution in the mineralogy of the secondary phases. In the case of the few CM chondrites that experienced some thermal metamorphism, in addition to aqueous alteration, a redox memory of the aqueous alteration is present: a significant fraction of Fe³⁺ is present, together with Fe²⁺ and sometimes Fe⁰. From our data set, the CR chondrites show a wider range of IOI from 1.5 to 2.5. In all considered CR chondrites, the three oxidation states of iron coexist. Even in the least‐altered CR chondrites, the fraction of Fe³⁺ can be high (30% for MET 00426). This observation confirms that oxidized iron has been integrated during formation of fine‐grained amorphous material in the matrix (Le Guillou and Brearley 2014; Le Guillou et al. 2015; Hopp and Vollmer 2018). Last, the IOI of CV chondrites does not reflect the reduced/oxidized classification based on metal and magnetite proportions, but is strongly correlated with petrographic types. The valence of iron in CV chondrites therefore appears to be most closely related to thermal history, rather than aqueous alteration, even if these processes can occur together (Krot et al. 2004; Brearley and Krot 2013).     

Evolution du spectre de la Nova Delphini 1967 en 1971 et 1972

Continued spectroscopic observations of Nova Del 67 during 1971 and 1972 show a general decrease of the nebular and coronal emission with respect to the local continuum. The continuous spectrum exhibits a strong Balmer emission (figure 1). Equivalent widths of Hi, Hei, Heii, Oi, [Oi], Oii, [Oii], Oiii, [Oiii], Niii, [Sii], [Aiii], [Neiii], [Nev], [Fevi], [Fevii], [Fex], [Fexi], [Fexiv], [Nixvi], [Nixv] are listed in tables 1 and 2.Figures 5 to 10 show several line profiles, which can be interpreted in terms of a model proposed by Hutchings (1972). Kinematical properties of the nova envelope do not seem to have changed in the 1968–1972 time interval. However, a study of the [Oiii] (4959 Å) line indicates that the physical conditions in the polar blobs in 1972 (T _e=10 660 K,N _e=5,5×10⁵ cm^–3) are different from those prevailing in equatorial rings (T _e=9×100 K,N _e=7×10⁵ cm^–3).

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Le matérial d'observation utilisé pour cette étude a été obtenu à l'aide de téléscopes de 120 cm, 152 cm et 193 cm de l'Observatoire de Haute-Provence (CNRS).     

Mineralogical study of brown olivine in Northwest Africa 1950 shergottite and implications for the formation mechanism of iron nanoparticles

Martian meteorites, in particular shergottites, contain darkened olivine (so‐called “brown olivine”) whose color is induced by iron nanoparticles formed in olivine during a shock event. The formation process and conditions of brown olivine have been discussed in the Northwest Africa 2737 (NWA 2737) chassignite. However, formation conditions of brown olivine in NWA 2737 cannot be applied to shergottites because NWA 2737 has a different shock history from that of shergottites. Therefore, this study observed brown olivine in the NWA 1950 shergottite and discusses the general formation process and conditions of brown olivine in shergottites. Our observation of NWA 1950 revealed that olivine is heterogeneously darkened between and within grains different from brown olivine in NWA 2737. XANES analysis showed that brown olivine contains small amounts of Fe³⁺ and TEM/STEM observation revealed that there is no SiO‐rich phase around iron metal nanoparticles. These observations indicate that iron nanoparticles were formed by a disproportionation reaction of olivine (3Fe²⁺_olivine → Fe⁰_metal + 2Fe³⁺_olivine + V_olivine, where V_olivine means a vacancy in olivine). Some parts of brown olivine show lamellar textures in SEM observation and Raman peaks in addition to those expected for olivine, implying that brown olivine experienced a phase transition (to e.g., ringwoodite). In order to induce heterogeneous darkening, heterogeneous high temperature of about 1500–1700 K and shock duration of at least ~90 ms are required. This heterogeneous high temperature resulted in high postshock temperature (>900 K) inducing back‐transformation of most high‐pressure phases. Therefore, in spite of lack of high‐pressure phases, NWA 1950 (= Martian meteorites with brown olivine) experienced higher pressure and temperature compared to other highly shocked meteorite groups.     

MgAl2O4 spinels from Allende and NWA 763 carbonaceous chondrites: Structural refinement,cooling history,and trace element contents

MgAl₂O₄ spinels from Allende and NWA 763 carbonaceous chondrites were studied by X‐ray single crystal diffraction, SEM, electron microprobe, LA‐ICP‐MS, and Raman spectroscopy. Those from Allende are almost pure, but, in one case, we found a strong FeO_tot zonation. Spinels from NWA 763 show Mg‐Fe²⁺ substitutions. Almost pure MgAl₂O₄ spinels from both meteorites underwent slow cooling and reached their intracrystalline closure temperature (T_c) in the range 460–520 °C. The NWA 763 spinel with higher FeO content shows a T_c of about 720 °C. X‐ray single crystal diffraction and Raman spectroscopy suggest a slow cooling and an ordered structure with trivalent cations in M site and divalent in T site. Among the trace elements, Ti and Co are enriched with respect to the terrestrial analogs, while Mn, Ni, and Sn show intermediate values between different terrestrial occurrences. Vanadium cannot be used as a tracer of extraterrestrial origin as for Cr‐spinels, because its content is similar in extraterrestrial and terrestrial spinels. In the zoned crystal from Allende, Co show a strong zonation similar to that of FeO.     

Thermal history of ALH 84001 meteorite by Fe2+‐Mg ordering in orthopyroxene

Abstract— A single orthopyroxene crystal from the Martian meteorite Allan Hills (ALH) 84001 was studied by X‐ray diffraction (XRD) and electron microprobe analysis (EMPA) to retrieve information about its thermal history. Both sets of data were used to measure the Fe²⁺‐Mg order degree between the M1 and M2 sites expressed by the distribution coefficient k_D. The 529 ± 30°C closure temperature (T_c) of the Fe²⁺‐Mg ordering process of ALH 84001 orthopyroxene (Fs₂₈) was calculated using Stimpfl (2005a, 2005b) ln k_D versus 1/T equation obtained for intermediate iron sample. At this T_c, the orthopyroxene cooling rate, calculated by Ganguly's (1982) numerical method, was 0.1 °C/day. This study puts new constraints on the last high‐temperature thermal episode recorded by orthopyroxene. With reference to the geological history (Treiman 1998), we ascribe this episode to the I3 event, and we interpret the T_c of 529 °C as a lower limit for this impact heating. Our data confirm that experimentally defined physical conditions for the formation of magnetite from decomposition of carbonates took place on the Martian surface during event I3.     

A vacancy‐rich,partially inverted spinelloid silicate, (Mg,Fe,Si)2(Si,□)O4, as a major matrix phase in shock melt veins of the Tenham and Suizhou L6 chondrites

A new high‐pressure silicate, (Mg,Fe,Si)₂(Si,□)O₄ with a tetragonal spinelloid structure, was discovered within shock melt veins in the Tenham and Suizhou meteorites, two highly shocked L6 ordinary chondrites. Relative to ringwoodite, this phase exhibits an inversion of Si coupled with intrinsic vacancies and a consequent reduction of symmetry. Most notably, the spinelloid makes up about 30–40 vol% of the matrix of shock veins with the remainder composed of a vitrified (Mg,Fe)SiO₃ phase (in Tenham) or (Mg,Fe)SiO₃‐rich clinopyroxene (in Suizhou); these phase assemblages constitute the bulk of the matrix in the shock veins. Previous assessments of the melt matrices concluded that majorite and akimotoite were the major phases. Our contrasting result requires revision of inferred conditions during shock melt cooling of the Tenham and Suizhou meteorites, revealing in particular a much higher quench rate (at least 5 × 10³ K s^?1) for veins of 100–500 μm diameter, thus overriding formation of the stable phase assemblage majoritic garnet plus periclase.     

Formation of orange hibonite,as inferred from some Allende inclusions

Abstract— We studied three fluffy Type A refractory inclusions from Allende that contain orange hibonite. The melilite in the present samples is very Al‐rich, averaging Åk₆, Åk₁₄, and Åk₁₂ in the three samples studied. Hibonite in two inclusions, unlike that in Murchison, has low rare earth element abundances of <10 × CI; in the other inclusion, the hibonite, melilite and perovskite have Group II‐like patterns. The hibonite and melilite in all three inclusions studied have excess ²⁶Mg consistent with (²⁶Al/²⁷Al)_I = 5 × 10^?5. Much of the hibonite and some of the spinel in these inclusions is corroded. These phases are found enclosed in melilite, but based on bulk compositions and phase equilibria, hibonite should not be an early‐crystallizing phase in these inclusions. We conclude that the hibonite and probably some of the spinel is relic. Reversely zoned melilite, rounded spinel and isotopically heavy Mg in the inclusions probably reflect reheating events that involved melting and evaporation. Alteration of the gehlenitic melilite gave rise to some rare phases, including corundum and nearly pure CaTs pyroxene. Studies have shown that blue hibonite contains Ti³⁺ while orange hibonite does not (Ihinger and Stolper, 1986; Beckett et al., 1988). Orange hibonite formed either under oxidizing conditions (such as at oxygen fugacities at least seven orders of magnitude greater than that of a solar gas at 1700 K), or under conditions reducing enough (e.g., solar) that it contained Ti³⁺, which was later oxidized in situ. Although V and Ce oxides are volatile at the temperature and range of oxygen fugacities at which orange hibonite is known to be stable, we find that (a) the hibonite is V‐rich (～1 wt% V₂O₃) and (b) there are no negative Ce anomalies in Allende hibonite. This indicates that the hibonite did not form by condensation under oxidizing conditions. In addition, there are slight excesses of Ti + Si cations relative to Mg + Fe cations (up to 0.1 of 0.8 cations per 19 oxygen anions), probably reflecting the original presence of Ti³⁺. The results of this study strongly support the suggestion (Ihinger and Stolper, 1986) that Allende hibonite originally formed under reducing conditions and was later oxidized. Oxygen fugacities within ～2–3 orders of magnitude of that of a solar gas are implied; otherwise, strong Ce and V depletions would be observed.     

Impact‐related thermal effects on the redox state of Ca‐pyroxene

Oxidation is observed in Ca‐pyroxene subjected to a range of shock pressures (21–59 GPa). Changes in the pyroxene redox ratio as measured by the changes in %Fe³⁺ ranged from 2–6 times the starting composition. Mössbauer and reflectance spectroscopy record the changing Fe³⁺ concentration as a preferential oxidation of Fe²⁺ in the M2 crystallographic site. The oxidation is also accompanied by mechanical changes in the pyroxene crystals including fracturing, linear defects, and twinning. As oxygen fugacity is often calculated using mineral redox ratios and thought to represent the prevailing fO₂ during crystallization, it is imperative to recognize that the fO₂ values measured in impact‐derived materials may represent that of the impact and not the magma source region.     

Variety of well behaved exact solutions of Einstein–Maxwell field equations: an application to Strange Quark stars, Neutron stars and Pulsars

We present a variety of well behaved classes of Charge Analogues of Tolman’s iv (1939). These solutions describe charged fluid balls with positively finite central pressure, positively finite central density; their ratio is less than one and causality condition is obeyed at the centre. The outmarch of pressure, density, pressure-density ratio and the adiabatic speed of sound is monotonically decreasing, however, the electric intensity is monotonically increasing in nature. These solutions give us wide range of parameter for every positive value of n for which the solution is well behaved hence, suitable for modeling of super dense stars. keeping in view of well behaved nature of these solutions, one new class of solutions is being studied extensively. Moreover, this class of solutions gives us wide range of constant K (0.3≤K≤0.91) for which the solution is well behaved hence, suitable for modeling of super dense stars like Strange Quark stars, Neutron stars and Pulsars. For this class of solutions the mass of a star is maximized with all degree of suitability, compatible with Quark stars, Neutron stars and Pulsars. By assuming the surface density ρ _b =2×10¹⁴ g/cm³ (like, Brecher and Caporaso in Nature 259:377, 1976), corresponding to K=0.30 with X=0.39, the resulting well behaved model has the mass M=2.12M _Θ, radius r _b ≈15.27 km and moment of inertia I=4.482×10⁴⁵ g cm²; for K=0.4 with X=0.31, the resulting well behaved model has the mass M=1.80M _Θ, radius r _b ≈14.65 km and moment of inertia I=3.454×10⁴⁵ g cm²; and corresponding to K=0.91 with X=0.135, the resulting well behaved model has the mass M=0.83M _Θ, radius r _b ≈11.84 km and moment of inertia I=0.991×10⁴⁵ g cm². For n=0 we rediscovered Pant et al. (in Astrophys. Space Sci. 333:161, 2011b) well behaved solution. These values of masses and moment of inertia are found to be consistent with other models of Neutron stars and Pulsars available in the literature and are applicable for the Crab and the Vela Pulsars.     

CO2 release due to impact devolatilization of carbonate: Results of shock experiments

A study of pure, single crystal calcite shocked to pressures from 9.0 to 60.8 GPa was conducted to address contradictory data for carbonate shock behavior. The recovered materials were analyzed optically and by transmission electron microscopy (TEM), as well as by thermogravimetry (TGA), X‐ray diffraction (XRD), and Raman‐spectroscopy. In thin section, progressive comminution of calcite is observed although grains remain birefringent to at least 60.8 GPa. TGA analysis reveals a positive correlation between percent of mass loss due to shock and increasing shock pressure (R = 0.77) and suggests that shock loading leads to the modest removal of structural volatiles in this pressure range. XRD patterns of shocked Iceland spar samples produce peaks that are qualitatively and quantitatively less intense, more diffuse, and shift to lower ^o2θ. However, the regularity observed in these shocked powder patterns suggests that structures with very uniform unit cell separations persist to shock pressures as high as 60.8 GPa. Raman spectral analyses indicate no band asymmetry and no systematic peak shifting or broadening. TEM micrographs display progressively diminishing crystallite domain sizes. Selected area electron diffraction (SAED) patterns reveal no signatures of amorphous material. These data show that essentially intact calcite is recovered at shock pressures up to 60.8 GPa with only slight mass loss (~7%). This work suggests that the amount of CO₂ gas derived from shock devolatilization of carbonate by large meteorite impacts into carbonate targets has been (substantially) overestimated.     

First Results from the Soho Ultraviolet Coronagraph Spectrometer

The SOHO Ultraviolet Coronagraph Spectrometer (UVCS/SOHO) is being used to observe the extended solar corona from 1.25 to 10 R⊙ from Sun center. Initial observations of polar coronal holes and equatorial streamers are described. The observations include measurements of spectral line profiles for HI Lα and Lβ, Ovi 1032 Å and 1037 Å, Mgx 625 Å, Fexii 1242 Å and several others. Intensities for Mgx 610 Å, Sixii 499 Å, and 520 Å, Sx 1196 Å, and 22 others have been observed. Preliminary results for derived H⁰, O⁵⁺, Mg₉₊, and Fe¹¹⁺ velocity distributions and initial indications of outflow velocities for O⁵⁺ are described. In streamers, the H⁰ velocity distribution along the line of sight (specified by the value at e^-1, along the line of sight) decreases from a maximum value of about 180 km s^-1 at 2 R⊙ to about 140 km s^-1 at 8 R⊙. The value for O⁵⁺ increases with height reaching a value of 150 km s^-1 at 4.7 R⊙. In polar coronal holes, the O⁵⁺ velocity at e^-1 is about equal to that of H⁰ at 1.7 R⊙ and significantly larger at 2.1 R⊙. The O⁵⁺ in both streamers and coronal holes were found to have anisotropic velocity distributions with the smaller values in the radial direction.     

The Gas Production Rate and Coma Structure of Comet C/1995 O1 (Hale–Bopp)

The University of Wisconsin–Madison and NASA–Goddard conducted acomprehensive multi-wavelength observing campaign of coma emissionsfrom comet Hale–Bopp, including OH 3080 Å, [O I] 6300 Å H₂O⁺ 6158 Å, H Balmer-α 6563 Å, NH₂ 6330 Å, [C I] 9850 ÅCN 3879 Å, C₂ 5141 Å, C₃ 4062 Å,C I 1657 Å, and the UV and optical continua. In thiswork, we concentrate on the results of the H₂O daughter studies.Our wide-field OH 3080 Å measured flux agrees with other, similarobservations and the expected value calculated from published waterproduction rates using standard H₂O and OH photochemistry.However, the total [O I] 6300 Å flux determined spectroscopically overa similar field-of-view was a factor of 3-4 higher than expected.Narrow-band [O I] images show this excess came from beyond theH₂O scale length, suggesting either a previously unknown source of[O I] or an error in the standard OH + ν→ O(¹ D) + H branching ratio. The Hale–Bopp OH and[O I] distributions, both of which were imaged tocometocentric distances >1 × 10⁶ km, were more spatiallyextended than those of comet Halley (after correcting for brightnessdifferences), suggesting a higher bulk outflow velocity. Evidence ofthe driving mechanism for this outflow is found in the Hα lineprofile, which was narrower than in comet Halley (though likelybecause of opacity effects, not as narrow as predicted by Monte-Carlomodels). This is consistent with greater collisional coupling betweenthe suprathermal H photodissociation products and Hale–Bopp's densecoma. Presumably because of mass loading of the solar wind by ionsand ions by the neutrals, the measured acceleration of H₂O⁺ downthe ion tail was much smaller than in comet Halley. Tailwardextensions in the azimuthal distributions of OH 3080 Å,[O I], and [C I] , as well as a Doppler asymmetry in the[O I] line profile, suggest ion-neutral coupling. While thetailward extension in the OH can be explained by increased neutralacceleration, the [O I] 6300 Å and [C I] 9850 Å emissions show 13%and >200% excesses in this direction (respectively), suggesting anon-negligible contribution from dissociative recombination of CO⁺and/or electron collisional excitation. Thus, models including theeffects of photo- and collisional chemistry are necessary for the fullinterpretation of these data.     

Fluid inclusions in microstructures of shocked quartz from the Keurusselkä impact site,Central Finland

Granitoid rock samples from the assumed center of the Keurusselkä impact site were subjected to a systematic study of fluid‐inclusion compositions and densities in various microstructures of the shocked quartz. The results are consistent with the following impact‐induced model of formation. After cessation of all major regional tectonic activity and advanced erosional uplift of the Fennoscandian shield, a meteorite impact (approximately 1.1 Ga) caused the formation of planar fractures (PFs) and planar deformation features (PDFs) and the migration of shock‐liberated metamorphic fluid (CO₂ ± H₂O) to the glass in the PDFs. Postimpact annealing of the PDFs led to the formation of CO₂ (±H₂O) fluid‐inclusion decorated PDFs. The scarce fluid‐inclusion implosion textures (IPs) suggest a shock pressure of 7.6–10 GPa. The postimpact pressure release and associated heating initiated hydrothermal activity that caused re‐opening of some PFs and their partial filling by moderate‐salinity/high temperature (>200 °C) H₂O (+ chlorite + quartz) and moderate‐density CO₂. The youngest postimpact endogenic sub‐ and nonplanar microfractures (MFs) are characterized by low‐density CO₂ and low‐salinity/low‐temperature (<200 °C) H₂O.     

A Comparison of Theoretical Si VIII Emission Line Ratios with Observations from Serts

Recent R-matrix calculations of electron impact excitation rates in N-like Si VIII are used to derive theoretical emission line intensity ratios involving 2s ²2p ³–2s2p ⁴ transitions in the 216–320 Å wavelength range. A comparison of these with an extensive dataset of solar active region, quiet-Sun, sub-flare and off-limb observations, obtained during rocket flights of the Solar EUV Research Telescope and Spectrograph (SERTS), indicates that the ratio R ₁= I(216.94 Å)/I(319.84 Å) may provide a usable electron density diagnostic for coronal plasmas. The ratio involves two lines of comparable intensity, and varies by a factor of about 5 over the useful density range of 10⁸–10¹¹ cm^?3. However R ₂= I(276.85 Å)/I(319.84 Å) and R ₃=I(277.05 Å)/I(319.84 Å) show very poor agreement between theory and observation, due to the severe blending of the 276.85 and 277.05 Å lines with Si VII and Mg VII transitions, respectively, making the ratios unsuitable as density diagnostics. The 314.35 Å feature of Si VIII also appears to be blended, with the other species contributing around 20% to the total line flux.

     

(U‐Th)/He zircon dating of Chesapeake Bay distal impact ejecta from ODP site 1073

Single crystal (U‐Th)/He dating has been undertaken on 21 detrital zircon grains extracted from a core sample from Ocean Drilling Project (ODP) site 1073, which is located ~390 km northeast of the center of the Chesapeake Bay impact structure. Optical and electron imaging in combination with energy dispersive X‐ray microanalysis (EDS) of zircon grains from this late Eocene sediment shows clear evidence of shock metamorphism in some zircon grains, which suggests that these shocked zircon crystals are distal ejecta from the formation of the ~40 km diameter Chesapeake Bay impact structure. (U‐Th/He) dates for zircon crystals from this sediment range from 33.49 ± 0.94 to 305.1 ± 8.6 Ma (2σ), implying crystal‐to‐crystal variability in the degree of impact‐related resetting of (U‐Th)/He systematics and a range of different possible sources. The two youngest zircon grains yield an inverse‐variance weighted mean (U‐Th)/He age of 33.99 ± 0.71 Ma (2σ uncertainties n = 2; mean square weighted deviation = 2.6; probability [P] = 11%), which is interpreted to be the (U‐Th)/He age of formation of the Chesapeake Bay impact structure. This age is in agreement with K/Ar, ⁴⁰Ar/³⁹Ar, and fission track dates for tektites from the North American strewn field, which have been interpreted as associated with the Chesapeake Bay impact event.     

Eutectic metal + troilite + Fe‐Mn‐Na phosphate + Al‐free chromite assemblage in shock‐produced chondritic melt of the Yanzhuang chondrite

An assemblage with FeNi metal, troilite, Fe‐Mn‐Na phosphate, and Al‐free chromite was identified in the metal‐troilite eutectic nodules in the shock‐produced chondritic melt of the Yanzhuang H6 meteorite. Electron microprobe and Raman spectroscopic analyses show that a few phosphate globules have the composition of Na‐bearing graftonite (Fe_,Mn,Na)₃(PO₄)₂, whereas most others correspond to Mn‐bearing galileiite Na(Fe,Mn)₄(PO₄)₃ and a possible new phosphate phase of Na₂(Fe,Mn)₁₇(PO₄)₁₂ composition. The Yanzhuang meteorite was shocked to a peak pressure of 50 GPa and a peak temperature of approximately 2000 °C. All minerals were melted after pressure release to form a chondritic melt due to very high postshock heat that brought the chondrite material above its liquidus. The volatile elements P and Na released from whitlockite and plagioclase along with elements Cr and Mn released from chromite are concentrated into the shock‐produced Fe‐Ni‐S‐O melt at high temperatures. During cooling, microcrystalline olivine and pyroxene first crystallized from the chondritic melt, metal‐troilite eutectic intergrowths, and silicate melt glass finally solidified at about 950–1000 °C. On the other hand, P, Mn, and Na in the Fe‐Ni‐S‐O melt combined with Fe and crystallized as Fe‐Mn‐Na phosphates within troilite, while Cr combined with Fe and crystallized as Al‐free chromite also within troilite.     

A new well behaved exact solution in general relativity for perfect fluid

We present a new spherically symmetric solution of the general relativistic field equations in isotropic coordinates. The solution is having positive finite central pressure and positive finite central density. The ratio of pressure and density is less than one and casualty condition is obeyed at the centre. Further, the outmarch of pressure, density and pressure-density ratio, and the ratio of sound speed to light is monotonically decreasing. The solution is well behaved for all the values of u lying in the range 0<u≤.186. The central red shift and surface red shift are positive and monotonically decreasing. Further, we have constructed a neutron star model with all degree of suitability and by assuming the surface density ρ _b =2×10¹⁴ g/cm³. The maximum mass of the Neutron star comes out to be M=1.591 M _Θ with radius R _b ≈12.685 km. The most striking feature of the solution is that the solution not only well behaved but also having one of the simplest expressions so far known well behaved solutions. Moreover, the good matching of our results for Vela pulsars show the robustness of our model.