The formation of Mercury's smooth plains

There has been extensive debate about whether Mercury's smooth plains are volcanic features or impact ejecta deposits. We present new indirect evidence which supports a volcanic origin for two different smooth plains units. In Borealis Planitia, stratigraphic relations indicate at least two distinct stages of smooth plains formation. At least one of these stages must have had a volcanic origin. In the Hilly and Lineated Terrain, Petrarch and several other anomalously shallow craters apparently have been volcanically filled. Areally extensive smooth plains volcanism evidently occurred at these two widely separated areas on Mercury. These results, combined with work by other researchers on the circum-Caloris plains and the Tolstoi basin, show that smooth plains volcanism was a global process on Mercury. Present data suggest to us that the smooth and intercrater plains may represent two distinct episodes of volcanic activity on Mercury and that smooth plains volcanism may have been triggered by the Caloris impact. High-resolution and multispectral imaging from a future Mercury spacecraft could resolve many of the present uncertainties in our understanding of plains formation on Mercury.     

Identification of mercurian volcanism: Resolution effects and implications for MESSENGER

Abstract— The possibility of volcanism on Mercury has been a topic of discussion since Mariner 10 returned images of half the planet's surface showing widespread plains material. These plains could be volcanic or lobate crater ejecta. An assessment of the mechanics of the ascent and eruption of magma shows that it is possible to have widespread volcanism, no volcanism on the surface whatsoever, or some range in between. It is difficult to distinguish between a lava flow and lobate crater ejecta based on morphology and morphometry. No definite volcanic features have been identified on Mercury. However, known lunar volcanic features cannot be identified in images with similar resolutions and viewing geometries as the Mariner 10 dataset. Examination of high‐resolution, low Sun angle Mariner 10 images reveals several features which are interpreted to be flow fronts; it is unclear if these are volcanic flows or ejecta flows. This analysis implies that a clear assessment of volcanism on Mercury must wait for better data. MESSENGER (MErcury: Surface, Space ENvironment, GEochemistry, Ranging) will take images with viewing geometries and resolutions appropriate for the identification of such features.     

Mercury crater statistics from MESSENGER flybys: Implications for stratigraphy and resurfacing history

The primary crater population on Mercury has been modified by volcanism and secondary craters. Two phases of volcanism are recognized. One volcanic episode that produced widespread intercrater plains occurred during the period of the Late Heavy Bombardment and markedly altered the surface in many areas. The second episode is typified by the smooth plains interior and exterior to the Caloris basin, both of which have a different crater size-frequency distribution than the intercrater plains, consistent with a cratering record dominated by a younger population of impactors. These two phases may have overlapped as parts of a continuous period of volcanism during which the volcanic flux tended to decrease with time. The youngest age of smooth plains volcanism cannot yet be determined, but at least small expanses of plains are substantially younger than the plains associated with the Caloris basin. The spatial and temporal variations of volcanic resurfacing events can be used to reconstruct Mercury's geologic history from images and compositional and topographic data to be acquired during the orbital phase of the MESSENGER mission.     

Spectra of extremely reduced assemblages: Implications for Mercury

Abstract— We investigate the possibility that Mercury's crust is very reduced with FeO concentrations of less than ?0.1 wt%. We believe that such a surface could have a composition of enstatite, plagioclase, diopside, and sulfide, similar to the mineral assemblages found in aubritic meteorites. To test this hypothesis, we investigated the spectra of aubrites and their constituent minerals as analogs for the surface of Mercury. We found that some sulfides have distinctive absorption features in their spectra shortwards of ?0.6 μm that may be apparent in the spectrum of such an object. Determination of the surface composition of Mercury using orbital x‐ray spectroscopy should easily distinguish between a lunar highlands and enstatite basalt composition since these materials have significant differences in concentrations of Al, Mg, S, and Fe. The strongest argument against Mercury having an enstatite basalt composition is its extreme spectral redness. Significant reddening of the surface of an object (such as Mercury) is believed to require reduction of FeO to nanophase iron, thus requiring a few percent FeO in the material prior to alteration.     

Mercurian volcanism questioned

The Mariner 10 television team has argued that extensive plains on Mercury were formed by volcanism and compared them with the demonstrably lunar maria. I believe, however, that in stratigraphic relations, surface morphology, and albedo contrast, the Mercurian plains more closely resemble the lunar light plains. These lunar plains were interpreted as volcanic on the basis of data comparable to that available to the Mariner 10 investigators but have been shown by the Apollo missions to be of impact origin. The plains on Mercury might also be formed of impact materials, perhaps of impact melt or other basin ejecta that behaved more like a fluid when emplaced that did lunar basin ejecta.     

Recognizing mercurian meteorites

Abstract— With the recent realization that some meteorites may come from Mars and the Moon, it is worthwhile to consider whether meteorites from Mercury could exist in our collections and, if so, whether they could be recognized. The current state of ignorance about Mercury both increases the potential scientific value of mercurian meteorites and aggravates the problem of identifying them. Here, we review evidence supporting the possibility of impact launch and subsequent orbital evolution that could deliver rocks from Mercury to Earth and suggest criteria that could help identify a mercurian meteorite. Mercurian rocks are probably differentiated igneous rocks or breccias or melt rocks derived therefrom. Solar nebula models suggest that they are probably low in volatiles and moderately enriched in Al, Ti, and Ca oxides. Mercurian surface rocks contain no more than 5% FeO and may contain plagioclase. A significant fraction may be volcanic. They may possess an unusual isotopic composition. Most pristine mercurian rocks should have solidification ages of ～3.7 to ～4.4 Ga, but younger impact-remelted materials are possible. Because we know more about the space environment of Mercury than we do about the planet itself, surface-exposed rocks would be easiest to identify as mercurian. The unique solar-to-galactic cosmic-ray damage track ratio expected in materials exposed near the Sun may be useful in identifying a rock from Mercury. Mercury's magnetic field stands off the solar wind, so that solar-wind implants in mercurian regolith breccias may be scarce or fractionated compared to lunar ones. Mercurian regolith breccias should contain more agglutinates (or their recrystallized derivatives) and impact vapor deposits than any other and should show a higher fraction of exogenic chondritic materials than analogous lunar breccias. No known meteorite group matches these criteria. A misclassified mercurian meteorite would most likely be found among the aubrites or the anorthositic lunar meteorites.     

Mercury's albedo from Mariner 10: Implications for the presence of ferrous iron

Mariner 10 clear filter (490 nm) images of Mercury were recalibrated and photometrically normalized to produce a mosaic of nearly an entire hemisphere of the planet. Albedo contrasts are slightly larger than seen in the lunar highlands (excluding maria). Variegations indicative of compositional differences include diffuse low albedo units often overlain by smooth plains, the high albedo smooth plains of Borealis Planitia, and high-albedo enigmatic crater floor deposits. A higher level of contrast between immature crater ejecta and average mature material on Mercury compared to the Moon is consistent with a more intense space weathering environment on Mercury that results in a more mature regolith. Immature lunar highlands materials are ∼1.5 times higher in reflectance than analogous immature mercurian materials. Immature materials of the same composition would have the same reflectance on both bodies, thus this observation requires that Mercury's crust contains a significant darkening agent, either opaque minerals or ferrous iron bearing silicates, in abundances significantly higher than those of the lunar highlands. If the darkening agent is opaque minerals (e.g. ilmenite or ulvospinel) Mercury's crust may contain significant ferrous iron and yet not exhibit a 1-μm absorption band.     

Eminescu impact structure: Insight into the transition from complex crater to peak-ring basin on Mercury

Peak-ring basins represent an impact-crater morphology that is transitional between complex craters with central peaks and large multi-ring basins. Therefore, they can provide insight into the scale dependence of the impact process. Here the transition with increasing crater diameter from complex craters to peak-ring basins on Mercury is assessed through a detailed analysis of Eminescu, a geologically recent and well-preserved peak-ring basin. Eminescu has a diameter (∼125 km) close to the minimum for such crater forms and is thus representative of the transition. Impact crater size-frequency distributions and faint rays indicate that Eminescu is Kuiperian in age, geologically younger than most other basins on Mercury. Geologic mapping of basin interior units indicates a distinction between smooth plains and peak-ring units. Our mapping and crater retention ages favor plains formation by impact melt rather than post-impact volcanism, but a volcanic origin for the plains cannot be excluded if the time interval between basin formation and volcanic emplacement was less than the uncertainty in relative ages. The high-albedo peak ring of Eminescu is composed of bright crater-floor deposits (BCFDs, a distinct crustal unit seen elsewhere on Mercury) exposed by the impact. We use our observations to assess predictions of peak-ring formation models. We interpret the characteristics of Eminescu as consistent with basin formation models in which a melt cavity forms during the impact formation of craters at the transition to peak ring morphologies. We suggest that the smooth plains were emplaced via impact melt expulsion from the central melt cavity during uplift of a peak ring composed of BCFD-type material. In this scenario the ringed cluster of peaks resulted from the early development of the melt cavity, which modified the central uplift zone.     

Stratigraphy and evolution of basalts in Mare Humorum and southeastern Procellarum

Abstract— We have studied the mare basalts of Mare Humorum and southeastern Procellarum (30°W–50°W, 0°–40°S). One hundred and nine basaltic units have been identified from differences in their FeO wt% and TiO₂ wt% content, and variations in crater densities. Crater counting and reference to isotopically dated Apollo samples have provided an age for 33 major units. Some evidence for three distinct periods of volcanic activity has been found. We found that the large unit in the middle of Mare Humorum is the oldest in the basin. This supports the suggestion that the oldest central unit sank causing the lithosphere to bend and create dykes through which lava flowed to produce the outer units. No evidence of a trend in FeO wt% and TiO₂ wt% content against time is found within Mare Humorum. There appears to be no lateral trend of basalts in terms of FeO and TiO₂ wt% over the entire area with time. An increase in FeO content with time is found in the 33 major units and there is some evidence for an increase in TiO₂ in the same units. A correlation between FeO wt% and TiO₂ wt% content is evident when all 109 units are compared. A notable feature of this correlation is a sharp increase in gradient of TiO₂ wt% content when the FeO wt% content rises above about 17%.     

Exposure of spectrally distinct material by impact craters on Mercury: Implications for global stratigraphy

MESSENGER’s Mercury Dual Imaging System (MDIS) obtained multispectral images for more than 80% of the surface of Mercury during its first two flybys. Those images have confirmed that the surface of Mercury exhibits subtle color variations, some of which can be attributed to compositional differences. In many areas, impact craters are associated with material that is spectrally distinct from the surrounding surface. These deposits can be located on the crater floor, rim, wall, or central peak or in the ejecta deposit, and represent material that originally resided at depth and was subsequently excavated during the cratering process. The resulting craters make it possible to investigate the stratigraphy of Mercury’s upper crust. Studies of laboratory, terrestrial, and lunar craters provide a means to bound the depth of origin of spectrally distinct ejecta and central peak structures. Excavated red material (RM), with comparatively steep (red) spectral slope, and low-reflectance material (LRM) stand out prominently from the surrounding terrain in enhanced-color images because they are spectral end-members in Mercury’s compositional continuum. Newly imaged examples of RM were found to be spectrally similar to the relatively red, high-reflectance plains (HRP), suggesting that they may represent deposits of HRP-like material that were subsequently covered by a thin layer (∼1 km thick) of intermediate plains. In one area, craters with diameters ranging from 30 km to 130 km have excavated and incorporated RM into their rims, suggesting that the underlying RM layer may be several kilometers thick. LRM deposits are useful as stratigraphic markers, due to their unique spectral properties. Some RM and LRM were excavated by pre-Tolstojan basins, indicating a relatively old age (>4.0 Ga) for the original emplacement of these deposits. Detailed examination of several small areas on Mercury reveals the complex nature of the local stratigraphy, including the possible presence of buried volcanic plains, and supports sequential buildup of most of the upper ∼5 km of crust by volcanic flows with compositions spanning the range of material now visible on the surface, distributed heterogeneously across the planet. This emerging picture strongly suggests that the crust of Mercury is characterized by a much more substantial component of early volcanism than represented by the phase of mare emplacement on Earth’s Moon.     

Plain formation on mercury: Tectonic implications

Four major plain units, plus intermediates, are distinguished on Mercury. The chronologic relationships between these plains indicate that plains formation was a permanent process on Mercury. Their location and morphology seem to indicate a possible volcanic origin for these plains.The relationships between tectonism and volcanism seems to indicate the global contraction is not the only tectonic process on Mercury.Paper presented at the European Workshop on Planetary Sciences, organised by the Laboratorio di Astrofisica Spaziale di Frascati, and held between April 23–27, 1979, at the Accademia Nazionale del Lincei in Rome, Italy.CNES Grant No. 77005.     

Constraints on the resurfacing history of Venus from the hypsometry and distribution of volcanism,tectonism, and impact craters

Improved measurements of the target elevations of 885 impact craters on Venus indicate that they are nearly random with respect to elevation. Although a slight deficit of craters at high elevations and an excess at low elevations is observed, the differences are marginally significant. Using a high-resolution digital map and database of all major volcanic, tectonic and impact features, we examine the distribution of impacts within volcanic and tectonic features, and the distribution of volcanism and tectonism with elevation. We show that the observed crater hypsometry results from resurfacing at higher elevations by volcanic and tectonic features superimposed on less active plains.The distribution of impacts in the map units has two distinct patterns: (1) the plains and shield fields (70%) have high crater densities and low proportions of tectonized or embayed craters; and (2) the remaining volcanic and tectonic features (30%) have low crater densities and high proportions of modified craters. The plains and shield fields appear to represent a much lower level of resurfacing activity. Simple area-balance calculations indicate that resurfacing at higher elevations by tectonic and volcanic features plausibly explains the observed crater hypsometry. However, the subtlety of the effects suggests that either (1) little resurfacing has occurred during the period of crater accumulation, or (2) resurfacing acts almost equally at all elevations. The apparent low activity of the plains and their abundance at lower elevations makes it unlikely that resurfacing is balanced with respect to elevation. It appears that the plains have been mostly quiescent since their emplacement, and that subsequent resurfacing occurs mostly in the highlands as a result of volcanism, corona formation, and rifting. We estimate that since the end of plains emplacement about 14% of Venus has been resurfaced by volcanism and about 6% by tectonic deformation.     

Properties of the Hermean regolith: V. New optical reflectance spectra, comparison with lunar anorthosites, and mineralogical modelling

We present new optical (0.4-0.65 μm) spectra of Mercury and lunar pure anorthosite locations, obtained quasi-simultaneously with the Nordic Optical Telescope (NOT) in 2002. A comparative study is performed with the model of Lucey et al. (2000, J. Geophys. Res. 105, 20297-20305, and references therein) between iron-poor, mature, pure anorthosite (>90% plagioclase feldspar) Clementine spectra from the lunar farside and a combined 0.4-1.0 μm mercurian spectrum, obtained with the NOT, calculated for standard photometric geometry. Mercury is located at more extreme locations in the Lucey ratio-reflectance diagrams than any known lunar soil, specifically with respect to the extremely iron-poor mature anorthosites. Though quantitative prediction of FeO and TiO₂ abundances cannot be made without a more generally applicable model, we find qualitatively that the abundances of both these oxides must be near zero for Mercury. We utilize the theory of Hapke (2002, Icarus 157, 523-534, and references therein), with realistic photometric parameters, to model laboratory spectra of matured mineral powders and lunar soils, and remotely sensed spectra of lunar anorthosites and Mercury. An important difference between fabricated and natural powders is the high value for the internal scattering parameter necessary to interpret the spectra for the former, and the requirement of rough and non-isotropically scattering surfaces in the modelling of the latter. The mature lunar anorthosite spectra were well modelled with binary mixtures of calcic feldspars and olivines, grain sizes of 25-30 μm and a concentration of submicroscopic metallic iron (SMFe) of 0.12-0.15% in grain coatings. The mercurian spectrum is not possible to interpret from terrestrial mineral powder spectra without introducing an average particle scattering function for the bulk soil that increases in backscattering efficiency with wavelength. The observed spectrum is somewhat better predicted with binary mixture models of feldspars and pyroxenes, than with single-component regoliths consisting of either albite or diopside. Correct spectral reflectance values were predicted with a concentration of 0.1 wt% SMFe in coatings of 15-30 μm sized grains. Since reasonable cosmogonical formation scenarios for Mercury, or meteoritic infall, predict iron concentrations at least this high, we draw the conclusion that the average grain size of Mercury is about a factor of two smaller than for average returned lunar soil samples. The 0.6-2.5 μm spectrum of McCord and Clark (1979, J. Geophys. Res. 178, 745-747) is used to further limit the possible range of mineralogical composition of Mercury. It is found that an intimately mixed and matured 3:1 labradorite-to-enstatite regolith composition best matches both the optical and near-infrared spectra, yielding an abundance of ∼1.2 wt% FeO and ∼0 wt% TiO₂.     

Sequential deformation of plains at the margins of Alpha Regio,Venus: Implications for tessera formation

Abstract— The boundaries between the highly deformed tessera terrain and adjacent volcanic plains are primarily those of embayment, where the tessera are stratigraphically older than the plains. Previous studies show that <3% of these boundaries display evidence of tectonic tilting after the emplacement of the plains. One of these unusual boundaries is the western margin of Alpha Regio tessera, a zone ～ 100 km in width that separates the plains from the interior structures of Alpha. This zone is characterized by margin parallel, fine‐scale (1–5 km) fractures, graben, and ridges that truncate and postdate the broad‐scale (10–30 km) ridges and troughs of the interior of Alpha. The western margin is embayed by several volcanic plains units that are progressively tilted and deformed by graben with closer proximity to Alpha Regio. The earliest deformation of the plains consists of northeast‐trending graben ～1 km in width that are similar in morphology and spacing to graben that deform intratessera plains and plains at the eastern boundary of Alpha. Northwest‐trending graben then formed over an interval marked by the emplacement of two additional plains units; their similarity to northwest‐trending structures emanating from Eve corona and the Lada Terra rift suggests a possible genetic relationship. The tilting of the plains adjacent to western Alpha implies relative vertical movement of the margin, either uplift of tessera or downwarping of plains subsequent to the formation and relaxation of the interior of Alpha Regio. Subsidence of plains at this locale is supported by the presence of a basin to the west of Alpha surrounded by a fracture belt contiguous with western Alpha. Thus, the fractures and deformation at the western boundary of Alpha may be related to the formation of a basin to the west of Alpha with some influence from the northernmost extension of the Lada Terra rift. Such a basin is not present at a section along the eastern boundary of Alpha Regio, where the origin of tilted plains remains equivocal. We conclude that the deformation along the western margin of Alpha Regio is not directly related to the process of tessera formation but is an example of tessera modification and is consistent with the stratigraphic position of tessera as the oldest unit observed on Venus.     

The dependence of reflectance spectra of Mercury on surface terrain

Reflectance spectra of Mercury, covering the spectral range of ～0.3–1.1 μm obtained during 1963–1976, were examined for any correlations with surface terrain. Mercury's 6.1385°/day rotational rate, the phases of the planet around maximum elongations, and bidirectional reflectance spectroscopy theory were used to identify the surface area associated with each spectrum. Data from 1974–1975, re-reduced with improved standard star flux ratios, show a weak absorption band in the near infrared not see in earlier analyses. Older spectra suggest that the western longitudes of the unimaged side of Mercury are similar to the rest of the planet. Spectra of the intercrater plains in the 0–90° quadrant suggest a possible absorption band. Spectra of areas dominated by Caloris Basin with the encompassing smooth plains may show Fe²⁺ abundances in the soil comparable to lunar highlands soil. No striking differences between spectra of intercrater plains and spectra of smooth plains are found. The absorption features seen in spectra of Mercury are generally weaker than features seen in lunar spectra.     

Stratigraphy,evolution, and volume of basalts in Mare Serenitatis

Abstract– Fourteen major basaltic units in Mare Serenitatis have been identified and mapped from differences in TiO₂ wt%. The ages of these units have been inferred from their crater densities and reference to isotopically dated Apollo samples. It has been found that FeO and TiO₂ wt% of the units do not show any apparent trend with time. However, the oldest units have much greater variation in FeO and TiO₂ wt% than younger ones. No lateral trend in the age of the basaltic units is apparent within the basin. A vertical profile of Mare Serenitatis has been produced based on the depth of basalt within impact craters. The minimum depth of basalt has been estimated where craters have not exposed underlying highland material. The profile has been used to estimate the minimum volume of basalt within the basin to be ≈500,000 km³.     

Properties of the hermean regolith: iii. disk-resolved vis-NIR reflectance spectra and implications for the abundance of iron

Disk-resolved reflectance spectra of the surface of Mercury (longitudes 240-300°), obtained in the visual (vis) and near-infrared (NIR) spectral region, are presented and analyzed. The observations were made at the 2.6-m Nordic Optical Telescope with the ALFOSC low-resolution spectrograph on 20 and 22 June 1999 in the wavelength range 520-970 nm with a footprint size of 700 km on the mid-disk of Mercury. A method which enables more accurate correction for telluric line absorptions and atmospheric extinction than that applied on previously published vis-NIR spectra of Mercury is introduced. The resulting reflectance spectra are remarkably linear, lack significant absorption features, and have optical slopes comparable to remotely sensed lunar pure anorthosites. The relation between spectral slope and photometric geometry found by Warell (2002, Icarus 156, 313-317) is confirmed and is explained as caused by strongly backscattering particles with embedded submicroscopic metallic iron in a mature regolith. With the theoretical maturation model of Hapke (2001, J. Geophys. Res. 106 (E5), 10039-10073) an abundance of 0.05-0.3 wt% submicroscopic metallic iron in the regolith for silicate grain sizes in the range 10-80 μm is determined, implying a ferrous iron content in mafic minerals intrinsically lower than that of the lunar highlands. A binary crustal composition model with anorthite linearly mixed with pyroxene provides better spectral fits than a pure anorthitic composition. Comparison with mature lunar pure anorthosite spectra yields a confident upper limit to the FeO content of 3 wt% under the assumption that the surfaces are similarly matured, but this figure probably represents a considerable overestimate. The average mercurian regolith does not seem to be substantially more weathered than the most mature lunar highland soils in terms of abundance of submicroscopic metallic iron, indicating that a steady-state maturation level has been reached. However, the strong relation between optical spectral slope and photometric geometry may imply that the majority of regolith particles are more fine-grained than their lunar counterparts and that the regolith is admixed with complex agglutinate weathering products which are more abundant and more transparent than those of the lunar highlands. This is consistent with more energetic impacts and a higher rate of impact melt production in an iron-poor regolith. An observed relation between the spectral slope and latitude provides evidence that the Ostwald ripening process may be operating at equatorial latitudes on Mercury.     

An analysis of the Mariner 10 color ratio map of mercury

The results of a geological analysis of the Mariner 10 orange/UV color ratio man of Mercury (B. Hapke, C. Christman, B. Rava, and J. Mosher, Proc. Lunar Planet Sci. Conf. 11th 1980, pp. 817–822) are given. Certain errors that occured in reproducing the published version of the 1980 map are pointed out. The relationships between color and terrain are distinctly nonlunar. There is no correlation between color boundaries and the smooth plains on Mercury, in contrast to the strong correlation between color and maria-highlands contacts on the Moon. There are no large exposures of low-albedo, blue material that could be considered to be Mercurian analogs of high-FeTi lunar maria basalts on any part of Mercury imaged by Mariner 10. Three lines of evidence imply that the crust is low in Fe²⁺ and Ti⁴⁺: rays and ejecta blankets are bluer than most areas on Mercury; the Fe²⁺ band in Mercury's reflectance spectrum is very weak or nonexistent and the albedo contrasts are smaller than those on the Moon. There is no evidence in the spectral or albedo data that a lunar type of second wave of melting ever occured on Mercury; rather, the observations are most consistent with the hypothesis that the smooth plains are extrusive landforms derived from local material, possibly mobilized by the Caloris event. In several places correlations between color and topography can be explained if older, redder, higher-Fe materials underlie younger, bluer, lower-Fe surfaces. There is some evidence of late Fe-rich pyroclastic-like activity.     

Equilibrium condensation from chondritic porous IDP enriched vapor: Implications for Mercury and enstatite chondrite origins

The origin of Mercury's anomalous core and low FeO surface mineralogy are outstanding questions in planetary science. Mercury's composition may result from cosmochemical controls on the precursor solids that accreted to form Mercury. High temperatures and enrichment in solid condensates are likely conditions near the midplane of the inner solar protoplanetary disk. Silicate liquids similar to the liquids quenched in ferromagnesian chondrules are thermodynamically stable in oxygen-rich systems that are highly enriched in dust of CI-chondrite composition. In contrast, the solids surviving into the orbit of Mercury's accretion zone were probably similar to highly unequilibrated, anhydrous, interstellar organic- and presolar grain-bearing chondritic, porous interplanetary dust particles (C-IDPs). Chemical systems enriched in an assumed C-IDP composition dust produce condensates (solid+liquid assemblages in equilibrium with vapor) with super-chondritic atomic Fe/Si ratios at high temperatures, approaching 50% of that estimated for bulk Mercury. Sulfur behaves as a refractory element, but at lower temperatures, in these chemical systems. Stable minerals are FeO-poor, and include CaS and MgS, species found in enstatite chondrites. Disk gradients in volatile compositions of planetary and asteroidal precursors can explain Mercury's anomalous composition, as well as enstatite chondrite and aubrite parent body compositions. This model predicts high sulfur content, and very low FeO content of Mercury's surface rocks.     

The chronology of Mercury's geological and geophysical evolution: The vulcanoid hypothesis

Previous discussions of Mercury's evolution have assumed that its cratering chronology is tied to that of the Moon, i.e., with Caloris forming about 3.9 Gyr ago as part of a late heavy bombardment that affected all of the terrestrial planets. That assumption requires that Mercury's core formed very early, because associated expansion features are not visible, and must have been erased before the cratering flux declined. Moreover, the modest amount of global shrinkage inferred from visible compressional features on Mercury's surface implies that the core is either largely molten at present, or had largely solidified before the end of the bombardment. The former interpretation requires a significant volatile content or implausibly large internal heat sources, while the latter raises questions about how to generate the planet's magnetic field. We have investigated whether constraints on Mercury's chronology could be relaxed by effects of a Mercury-specific bombarding population of planetesimals interior to its orbit, encountering the planet only occasionally due to secular perturbations. Such “vulcanoids” could have been a significant source of early cratering. However, those in orbits that can cross Mercury's are depleted by mutual collisions in ⪅1 Gyr, and can provide at most a modest extension of the period of heavy bombardment. Further inside Mercury's orbit, lower collisional velocities might allow survival of vulcanoids to the present. We report on a search for such bodies and on observational limits to such a population. We also review evidence that Mercury's intercrater plains are of volcanic origin and mainly predate Caloris, and that scarp formation (and global contraction) mainly postdates Caloris and has continued to recent times. If global lineaments are the product of tidal despinning, they constrain core formation to the first half of the planet's lifetime. While some questions and inconsistencies remain, the preponderance of evidence suggests that Mercury differentiated early, and at least half of its core volume is presently molten, probably due to a significant content of some light element such as sulfur.