Essai sur la structure des domaines émergés autour de la Méditerranée occidentale

Résumé De travaux menés dans les zones littorales de l'Afrique du Nord et dans tout le S de l'Espagne, l'auteur tire une nouvelle définition des grands ensembles structuraux péri-méditerranéens. Ces ensembles sont, dans les Cordillères bétiques, du N au S: zones externes (Prébétique, Subbétiques, Pénibétiques), zones internes (Flyschs gaditans, Malaguides, Alpujarrides, Nevadides 1). Dans le Rif marocain, symétriquement, on rencontre du S au N: zones externes (Autochtone de l'Atlas, nappes prérifaines et intrarifaines), zones internes (Flyschs nord-rifains, Tétouanides 2), Ghomarides 3), Sebtides 4); la plupart de ces zones se poursuivent vers l'E, jusqu'en Tunisie et en Sicile.Le fait majeur, à souligner au départ, est la parfaite symétrie de la chaîne alpine de la Méditerranée occidentale: les nappes rifaines ne le cèdent pas en importance aux nappes bétiques. Les diverses unités des deux systèmes se raccordent de manière évidente par la courbure de Gibraltar. L'âge du paroxysme tectonique paraît entièrement compris entre Oligocène supérieur et Miocène supérieur, aucune preuve objective n'existant de nappes plus anciennes.La remise en place des divers ensembles structuraux dépend de l'hypothèse générale définie au départ. Il est d'abord fait allusion à l'interprétation classique, par charriages modérés, ne faisant pas appel à des modifications importantes dans l'emplacement des bassins sédimentaires, actuellement visibles en plan. Les objections à ce premier schéma paraissent déterminantes.Une deuxième interprétation, que l'auteur a déjà partiellement esquissée auparavant, sera envisagée: les unités externes (s'empilant sur elles-mêmes) et leurs socles s'enfonceraient sous les zones internes qui, par réaction, seraient poussées vers l'extérieur de la chaîne: chacune des nappes dépasserait la nappe plus basse, au cours de ce mouvement. Dans le cas de l'Espagne, avant les charriages, les domaines sédimentaires des zones internes se placeraient à l'inverse de la disposition actuelle, soit du N au S: Nevadides, Alpujarrides, Malaguides, Pénibétique et Flyschs gaditans (ultras). Du côté marocain, nous aurions de même du S au N: Sebtides, Ghomarides, Tétouanides, Flyschs nord-rifains (ultras). Cela obligerait, au total, à faire rapprocher l'un de l'autre, en profondeur, les bâtis de la Meseta ibérique et de l'Atlas marocain, d'environ 300 à 500 km, l'actuelle largeur de la mer d'Alboran (150 km) ne permettant pas de reloger les domaines de toutes les nappes. Un axe d'enfouissement serait à rechercher sous l'actuelle Méditerranée.Une troisième interprétation, proposée aujourd'hui par l'auteur, considère que la chaîne péri-méditerranéenne montre une cicatrice structurale fondamentale, qui séparerait domaines internes bétiques et rifains, d'une part, domaines bétiques et rifains plus externes, de l'autre. Cette cicatrice se couderait au niveau de Gibraltar. Les nappes internes seraient comme aspirées vers la cicatrice ainsi que, en sens inverse, les nappes externes. La reconstitution paléogéographique finale est fort satisfaisante et l'ampleur des rétrécissements sensiblement diminuée.La position du domaine des Flyschs kabyles, nord-rifains et gaditans, fait enfin l'objet d'un examen nouveau: sans rejeter l'origine ultra, déjà proposée, l'auteur envisage d'autres solutions, qui auraient l'avantage de mieux s'intégrer dans l'image proposée aujourd'hui.     

Calculated Phase Relations in the System NCKFMASH (Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O) for High-Pressure Metapelites

Petrogenetic grids in the system NCKFMASH (Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O)and the subsystems NCKMASH and NCKFASH calculated with the softwareTHERMOCALC 3.1 are presented for the P–T range 7–30kbar and 450–680°C, for assemblages involving garnet,chloritoid, biotite, carpholite, talc, chlorite, kyanite, staurolite,paragonite, glaucophane, jadeite, omphacite, diopsidic pyroxene,plagioclase, zoisite and lawsonite, with phengite, quartz/coesiteand H₂O in excess. These grids, together with calculated compatibilitydiagrams and P–T and T–X_Ca and P–X_Ca pseudosectionsfor different bulk-rock compositions, show that incorporationof Ca into the NKFMASH system leads to many of the NKFMASH invariantequilibria moving to lower pressure and/or lower temperature,which results, in most cases, in the stability of jadeite andgarnet being enlarged, but in the reduction of stability ofglaucophane, plagioclase and AFM phases. The effect of Ca onthe stability of paragonite is dependent on mineral assemblageat different P–T conditions. The calculated NCKFMASH diagramsare powerful in delineating the phase equilibria and P–Tconditions of natural pelitic assemblages. Moreover, contoursof the calculated phengite Si isopleths in P–T and P–X_Capseudosections confirm that phengite barometry in NCKFMASH isstrongly dependent on mineral assemblage. KEY WORDS: phase relations; metapelites; NCKFMASH; THERMOCALC; phengite geobarometry     

Partitioning of Ru, Rh, Pd, Re, Ir, and Au between Cr-bearing spinel, olivine, pyroxene and silicate melts

A series of high temperature experiments was undertaken to study partitioning of several highly siderophile elements (HSE; Ru, Rh, Pd, Re, Os, Ir, Pt and Au) between Cr-rich spinel, olivine, pyroxene and silicate melt. Runs were carried out on a Hawaiian ankaramite, a synthetic eucrite basalt, and a DiAn eutectic melt, at one bar, 19 kbar, and 20 kbar, respectively, in the temperature range of 1200 to 1300°C, at oxygen fugacities between the nickel-nickel oxide (NNO) and hematite-magnetite (HM) oxygen buffers. High oxygen fugacities were used to suppress the formation of HSE-rich “nuggets” in the silicate melts. The resulting oxide and silicate crystals (<100 μm) were analyzed using both SIMS and LA-ICP-MS, with a spatial resolution of 15 to 50 μm. Rhenium, Au and Pd were all found to be incompatible in Cr-rich spinel (D_Re^sp/melt = 0.0012-0.21, D_Au^sp/melt = 0.076, D_Pd^sp/melt = 0.14), whereas Rh, Ru and Ir were all found to be highly compatible (D_Rh^sp/melt = 41-530, D_Ru^sp/melt = 76-1143, D_Ir^sp/melt = 5-22000). Rhenium, Pd, Au and Ru were all found to be incompatible in olivine (D_Re^oliv/melt = 0.017-0.073, D_Pd^oliv/melt = 0.12, D_Au^oliv/melt = 0.12, D_Ru^oliv/melt = 0.23), Re is incompatible in orthopyroxene and clinopyroxene (D_Re^opx/melt = 0.013, D_Re^cpx/melt = 0.18-0.21), and Pt is compatible in clinopyroxene (D_Pt^cpx/melt = 1.5). The results are compared to and combined with previous work on HSE partitioning among spinel-structured oxides, and applied to some natural magmatic suites to demonstrate consistency.     

Carte Métallogénique de la Bulgarie

Résumé On peut, en résumé, caractériser ainsi les principales provinces de la Bulgarie: — les Rhodopes constituent une zone typiquement polymétallique avec une prépondérance soulignée de Pb, Zn; le F, Cr, Ni, y existent en quantité subordonnée; en traces viennent encore: le Ba, Mn, Cd, Sb, W, Mo, Bi, As, Au, Ag, V; — la Sredna Gora est caractérisée comme une zone de cuivre typique, avec la présence de Fe, Mn, et en quantitée subordonnée de Pb, Zn, Mo, Ti, V, Au. — les Balkans portent les particularités d'une zone polymétallique (Pb, Zn, Cu) avec fer. On y remarque souvent des gîtes individualisés de cuivre, polymétallique avec fer, argent, ainsi que des gîtes complexes. Le Mn, Ba, Au, Ag, Co, Mo, As, Hg, V, W viennent en quantité subordonnée; — la zone des Kraistides, analogue à la précédente, se caractérise par des gisements polymétalliques pauvres et des gîtes à or et scheelite. Les éléments principaux sont: Au, Ba et secondaires: Pb, Zn, Cu, V et en partie du Fe et Hg; — la plateforme mésique, outre le gaz, se caractérise par le manganèse de la dépression de Varna.

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The metallogenic map of Bulgaria displays the following four major and distinct provinces: The Rhodopes as a typically polymetallic zone, mainly with Pb and Zn, but also with F, Cr and Ni, and minor or trace amounts of Ba, Mn, Cd, Sb, Mo, Bi, As, Au, Ag, V. The Sredna-gora is a distinct copper zone, with Fe and Mn, and minor amounts of Pb, Zn, Mo, Ti, V, Au. The Balkan is again a polymetallic zone of Pb, Zn and Cu with Fe; but Cu-Fe-Ag-deposits also occur. The other elements are present in minor quantities only. The Kraiste-Zone resembles the previous one and contains low grade polymetallic and scheelite deposits. The main elements are Au, Ba, and minor quantities of Pb, Zn, Cu, V and in part Fe and Hg. The zone of the Mésie platform contains only the manganese deposits of the Varna depression, in addition to natural gas.

     

Mineralogy and geochemistry of the Texeo Cu–Co mine site (NW Spain): screening tools for environmental assessment

The Cu–Co–Ni Texeo mine has been the most important source of Cu in NW Spain since Roman times and now, approximately 40,000 m³ of wastes from mine and metallurgical operations, containing average concentrations of 9,263 mg kg⁻¹ Cu, 1,100 mg kg⁻¹ As, 549 mg kg⁻¹ Co, and 840 mg kg⁻¹ Ni, remain on-site. Since the cessation of the activity, the abandoned works, facilities and waste piles have been posing a threat to the environment, derived from the release of toxic elements. In order to assess the potential environmental pollution caused by the mining operations, a sequential sampling strategy was undertaken in wastes, soil, surface and groundwater, and sediments. First, screening field tools were used to identify hotspots, before defining formal sampling strategies; so, in the areas where anomalies were detected in a first sampling stage, a second detailed sampling campaign was undertaken. Metal concentrations in the soils are highly above the local background, reaching up to 9,921 mg kg⁻¹ Cu, 1,373 mg kg⁻¹ As, 685 mg kg⁻¹ Co, and 1,040 mg kg⁻¹ Ni, among others. Copper concentrations downstream of the mine works reach values up to 1,869 μg l⁻¹ and 240 mg kg⁻¹ in surface water and stream sediments, respectively. Computer-based risk assessment for the site gives a carcinogenic risk associated with the presence of As in surface waters and soils, and a health risk for long exposures; so, trigger levels of these elements are high enough to warrant further investigation.     

Environmental risk assessment of some potentially toxic elements in El-Tabbin region (Cairo, Egypt)

As much as 24 soil samples and 6 stream sediments from the River Nile were studied in El-Tabbin region (Great Cairo, Egypt). Twelve chemicals, potentially toxic elements posing potential environmental risk, were the object of concern in this study. Mean contents of analysed elements (in mg kg^?1) in soils and the River Nile stream sediments were the following: As_s 3.6/As_ss 1.5, Cd_s 0.33/Cd_ss 0.12, Cr_s 87.7/Cr_ss 141.5, Cu_s 40.3/Cu_ss 43.8, Hg_s 0.03/Hg_ss 0.13, Pb_s 33.3/Pb_ss 20.2, Zn_s 150/Zn_ss 109, Se_s 0.24/Se_ss 0.05, Ni_s 37.2/Ni_ss 48, Sb_s 1.25/Sb_ss 1, Ba_s 892/Ba_ss 431, V_s 103.3/V_ss 167.8. Furthermore, geochemical background values were derived for soil and stream sediment samples. The values are as follows (in mg kg^?1): As_s 1.33/As_ss 1, Cd_s 0.48/Cd_ss 0.05, Cr_s 54.7/Cr_ss 106.5, Cu_s 23.8/Cu_ss 23, Hg_s 0.025/Hg_ss 0.095, Pb_s 15.3/Pb_ss 13.5, Zn_s 70/Zn_ss 55, Se_s 0.13/Se_ss 0.05, Ni_s 19.5/Ni_ss 32.5, Sb_s 1/Sb_ss 1, Ba_s 266/Ba_ss 275, V_s 50.7/V_ss 119. More than two-thirds of soil and sediment samples exceeded established (based on literature data) risk limit values for non-polluted environment. Based on environmental risk assessment for potentially toxic elements in soils and sediments in more than 45% of total area disturbed environment (I _ER = 1–3) was documented and more than 13% of territory was characterised with highly disturbed environment (I _ER > 3).     

The relationship of elasticity and crystal structure in andalusite and sillimanite

The nine elastic constants of andalusite and sillimanite have been determined, using the technique of Brillouin scattering. They are, in megabars, for andalusite: c ₁₁=2.334, c ₂₂=2.890, c ₃₃=3.801, c ₄₄=0.995, c ₅₅=0.878, c ₆₆=1.123, c ₂₃=0.977, c ₁₃=1.162, c ₁₂=0.814; for sillimanite: c ₁₁=2.873, c ₂₂=2.319, c ₃₃=3.884, c ₄₄=1.224, c ₅₅=0.807, c ₆₆=0.893, c ₂₃=1.586, c ₁₃=0.834, c ₁₂=0.947. Both structures are characterized by chains of edge-linked coordination octahedra extending parallel to the crystallographic c direction, cross-linked by polyhedra of lower coordination. In each structure the stiffness measured parallel to c is greater than that measured normal to c. The shear moduli can be directly correlated with the relative rigidity of the cross-linking structures.     

Chemistry of rainwaters in the south Pacific area of Russia

On the south-eastern edge of Russia, the chemical composition of rainwater is controlled by sea salts, terrestrial material, as well as volcanic (Kuril islands volcanic area) and anthropogenic emissions, mostly in the southern part of the area. The predominant major ions of the Primorye, Sakhalin and the Kuril Islands rainwaters were respectively HCO₃⁻–SO₄²⁻, Ca–Na, and of Cl–Na. Concentration of trace elements changes within 1–2 orders of magnitude but some difference in the distribution of the elements between continental and island rainwater is found. The concentration of the chemical elements in the particulate fraction varies from < 10% to 90% of the total concentration (dissolved + particulate) with the following distribution: Tl, Na, Ca, Sr, Zn, Cd (< 10%)–Be, Th, Bi, Rb, U, K, Sc (10–20%)–Cu, Mn, Mg, Mo, Se, Ba, Ni, As, Ag, Cs, Co, Y, Ga, V (20–50%)–Sb, Pb, Ge, Cr, Fe, Al (50–90%).The concentration of elements of the particulate fraction of the rainwater usually is significantly different from concentrations in the crust, including both higher and lower concentrations. The terrestrial contribution to dissolved elements was evaluated and follows the decreasing order: Fe > K, Mg, Ca > Ba, Sr > Na (65–1%). Close order was found for total (dissolved and solid) concentrations. Sea salt contribution to dissolved element concentration in the rainwater decrease in the following order: Cl, Mg > K, SO₄ > Ca > HCO₃⁻, Ba, Fe (78–0.1%). Calculation of anthropogenic and volcanic inputs for two ions (Cl⁻ and SO₄²⁻) shows that anthropogenic inputs for the Vladivostok and Yuzno-Sakhalinsk cities can be evaluated as 15–20% of Cl⁻ and up to 80–90% of SO₄²⁻. Volcanic components in the Kuril Islands, where anthropogenic inputs are absent, can reach up to 76% of SO₄²⁻ and 36% of Cl⁻.     

Role of unbalanced slab resistive force in the 2004 off Sumatra mega-earthquake (<Emphasis Type="Italic">M</Emphasis><Subscript>w</Subscript> > 9.0) event

Present study addresses the role of major plate-driving forces, particularly the slab pull and slab resistive forces, for the generation of 26 December 2004 M _w > 9.0 off Sumatra megathrust earthquake. Major controls on the plate-driving forces are normally visualized through age, speed, and average dip of the slab during subduction. Wide variation in age, plate obliquity, stress obliquity, subduction rate, dip angle, and flexing depth of the subducting oceanic lithosphere between Andaman and Sumatra thus allowed us for quantitative evaluation of the slab pull (F _SP) and slab resistive (F _SR) forces in three well-defined sectors (I, II and III). Computed values of these forces in the three sectors: (1) F _SP = 1.29 × 10¹³ N/m, F _SR = 1.41 × 10¹³ N/m; sector I, (2) F _SP = 2.10 × 10¹³ N/m, F _SR = 1.13 × 10¹³ N/m; sector II, and (3) F _SP = 2.08 × 10¹³ N/m, F _SR = 2.72 × 10¹³ N/m; sector III clearly suggest a spatial variation of stress regime in the subducting oceanic lithosphere. Excess F _SR in sectors I and III are interpreted as the causative forces behind the triggering of major seismic energy bursts near Sumatra and Andaman on 26 December 2004. A gap of minimum seismic energy burst near Great Nicobar possibly was controlled by the excess of F _SP in sector II. This study further advocates that the cyclic stress, resulted from unbalanced component of slab resistive force, had a definite control on the occurrence of 2004 off Sumatra megathrust earthquake around the flexing zone of the subducting lithosphere.     

External seismic stability of vertical geosynthetic-reinforced soil walls using pseudo-static method

Analysis of external stability of vertical geosynthetic-reinforced soil (GRS) walls is very important in the seismic prone zone. The scope of this paper is to obtain required minimum reinforcement length, L _min, for external seismic stability of vertical GRS walls by pseudo-static limit equilibrium method. Then, L _min can be calculated to resist sliding, eccentricity, and bearing capacity failure modes. The parameters considered include both horizontal and vertical seismic coefficients (k _h and k _v ), surcharge load (q), wall height (H) and the properties of retained backfill, GRS, and foundation soil. Results show that L _min against sliding failure mode, L _min,S , increases more quickly than that against the other two failure modes with the increase in k _h , q, or unit weight of retained backfill, γ _b , while L _min,S decreases more quickly than that against the other two failure modes with increase in friction angle of retained backfill, ? _b , or unit weight of GRS, γ _r . For the different failure modes, the effect of k _v on L _min is not identical with the change of k _h , and in addition, L _min/H will tend to remain unchanged with the increase in H. In general, L _min against bearing capacity failure mode, L _min,BC, is larger than L _min against the other two failure modes. However, L _min,BC will be less than L _min against eccentricity failure mode, L _min,E , for k _h exceeding 0.35, or friction angle of foundation soil, ? _f , exceeding 37°, and L _min,BC will also be less than L _min,S for friction angle of GRS, ? _r , being no more than 26°.     

The crystal structure of arsentsumebite, Pb2Cu[(As, S)O4]2(OH)

Summary The crystal structure of arsentsumebite, ideally, Pb₂Cu[(As, S)O₄]₂(OH), monoclinic, space group P2₁/m, a = 7.804(8), b = 5.890(6), c = 8.964(8) ?, β = 112.29(6)°, V = 381.2 ?³, Z = 2, d_calc. = 6.481 has been refined to R = 0.053 for 898 unique reflections with I> 2σ(I). Arsentsumebite belongs to the brackebuschite group of lead minerals with the general formula Pb₂ Me(XO₄)₂(Z) where Me = Cu²⁺, Mn²⁺, Zn²⁺, Fe²⁺, Fe³⁺; X = S, Cr, V, As, P; Z = OH, H₂O. Members of this group include tsumebite, Pb₂Cu(SO₄)(PO₄)(OH), vauquelinite, Pb₂Cu(CrO₄)(PO₄)(OH), brackebuschite, Pb₂ (Mn, Fe)(VO₄)₂(OH), arsenbracke buschite, Pb₂(Fe, Zn)(AsO₄)₂(OH, H₂O), fornacite, Pb₂Cu(AsO₄)(CrO₄)(OH), and feinglosite, Pb₂(Zn, Fe)[(As, S)O₄]₂(H₂O). Arsentsumebite and all other group members contain M = M–T chains where M = M means edge-sharing between MO₆ octahedra and M–T represents corner sharing between octahedra and XO₄ tetrahedra. A structural relationship exists to tsumcorite, Pb(Zn, Fe)₂(AsO₄)₂ (OH, H₂O)₂ and tsumcorite-group minerals Me(1)Me(2)₂(XO₄)₂(OH, H₂O)₂. Received June 24, 2000; revised version accepted February 8, 2001     

Genesis of garnets in some magmatic rocks from Hungary

Summary Garnets from Miocene di-normative, medium-K andesites as well as from a Mesozoic fine-grained albite granite have been petrologically investigated. The chemical compositions of the garnets from the andesites as determined by electron microprobe (alm 57–65,pyr 14–22,gross 10–24,spess 2–5, -all in mol.-%) are compatible with the garnets being high pressure megacrysts. Garnets from the granite (alm 71–74,pyr 12–18,gross 3.5–5.5,spess 5.6–11) apparently crystallized in a low pressure environment. They are believed to have formed in an autometasomatic event.

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Die Genese von Granaten in einigen magmatischen Gesteinen Ungarns

Zusammenfassung Granate aus miozänen di-normativen, medium-K Andesiten und aus einem mesozoischen feinkörnigen Albit-Granit wurden petrologisch untersucht. Die chemische Zusammensetzung der Granate, (Alm 57–65,Pyr 14–22,Gross 10–24,Spess 2–5 Mol.-%), gemessen mittels Elektronenstrahl-Mikrosonde, macht es wahrscheinlich, daß diese Granate Hochdruck-Megakristalle sind. Die Granate im Granit (Alm 71–74,Pyr 12–18,Gross 3,5–5,5,Spess 5,6–11) kristallisierten bei niedrigen Drücken und sind wahrscheinlich das Produkt autometasomatischer Vorgänge.

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With 7 Figures     

Cervandonite-(Ce) in ores of the Berezitovoe deposit: Second finding in the world

The supposedly second finding of rare arsenosilicate cervandonite-(Ce) in the world is characterized. The mineral was recognized in the ore-bearing metasomatic rocks of the Berezitovoe gold-base metal deposit (Upper Priamurye, Russian Far East) in association with quartz, biotite, muscovite, orthoclase, garnet (almandine-spessartine), tourmaline, basic plagioclase, and sulfides. The cervandonite is represented by optically homogeneous and heterogeneous aggregates with visible crystals from 10 fum to 0.1–0.3 mm in size. Based on the microprobe analysis, the average chemical composition of the homogeneous cervandonite-(Ce) aggregates is as follows (wt %): Ce₂O₃ - 13.00, La₂O₃ - 5.70, Nd₂O₃ - 5.20, Pr₂O₃ - 1.41, Y₂O₃ - 0.77, Sm₂O₃ - 0.77, Eu₂O₃ - 0.23, Gd₂O₃ - 0.54, Dy₂O₃ - 0.31, ThO₂ - 1.12, UO₂ - 0.30, TiO₂ - 12.86, Al₂O₃ - 9.24, Fe₂O₃ - 8.93, FeO - 2.68, CaO - 0.14, SiO₂ - 19.98, As₂O₃ - 16.19. The comparative study of the cervandonite-(Ce) from the Berezitovoe deposit and the analogous minerals from the Alpine mica gneiss of Mt. Pizzo Cervandone (Central Alps) showed that the former mineral can be assigned to a new variety of cervandonite-(Ce) in terms of its compositional features. This variety is characterized by an ordered stoichiometric composition corresponding to the simpler theoretical formula (Ce,Nd,La)(Fe³⁺, Fe²⁺, Ti⁴⁺, Al)₃ (Si₂As³⁺)₃O₁₂.     

Environmental aspect of radon potential in terra rossa and eutric cambisol in Slovenia

Terra rossa and eutric cambisol soils were surveyed in Slovenia. At both sites, 6–13 boreholes were drilled in a regular 24 m × 24 m square grid. Soil samples from various depths were taken for gamma spectrometric analysis, and radon in soil gas was measured at a depth of 80 cm using an AlphaGuard instrument. The following ranges of activity concentration (Bq kg⁻¹) were obtained for ²³⁸U, ²²⁶Ra, ²²⁸Ra, ⁴⁰K and ¹³⁷Cs: in terra rossa, 64–74, 70–84, 45–49, 293–345, 20–30 and, in eutric cambisol, 55–80, 132–147, 50–57, 473–529, 106–272. Radon activity concentrations in both soils ranged from about 100 kBq m⁻³ to 370 kBq m⁻³.     

Ammonite and inoceramid bivalve faunas from the Davutlar Formation of the Devrekani–Kastamonu area, northern Turkey, and their biostratigraphical significance

The ammonite and inoceramid bivalve faunas of the Davutlar Formation of the Devrekani–Kastamonu area in central-north Turkey, are described. The formation yields an ammonite assemblage of Pseudophyllites indra (Forbes, 1846), Pachydiscus (Pachydiscus) haldemsis (Schlüter, 1867), Pachydiscus (Pachydiscus) oldhami (Sharpe, 1855), Didymoceras binodosum (Kennedy and Cobban, 1993), Bostrychoceras polyplocum (Roemer, 1841) and Baculites alavensis Santamaria Zabala, 1996. The inoceramid assemblage is Cataceramus subcompressus (Meek and Hayden, 1862), Cataceramus goldfussianus (d'Orbigny, 1846), Platyceramus vanuxemi (Meek and Hayden, 1860), Cataceramus cf. mortoni (Meek, 1876), Cataceramus pteroides (Giers, 1964), Cataceramus aff. barabini (Morton, 1834), Platyceramus pierrensis (Walaszczyk et al., 2001), “Inoceramus” convexus Hall and Meek, 1856, Cordiceramus heberti (Fallot, 1885), “Inoceramus” tenuilineatus Hall and Meek, 1856, “Inoceramus” borilensis Jolkicev, 1962, as well as some forms with no or equivocal specific affiliation. Both ammonite and inoceramid faunas suggest an early Late Campanian age for the formation, most probably Bostrychoceras polyplocum and Didymoceras donezianum ammonite Zones / Cataceramus subcompressus and “Inoceramus” tenuilineatus inoceramid Zones. Both ammonite and inoceramid assemblages are well represented throughout the Euramerican biogeographical region.     

Batiferrite, Ba[Ti2Fe10]O19, a new ferrimagnetic magnetoplumbite-type mineral from the Quaternary volcanic rocks of the western Eifel area, Germany

Summary Batiferrite, ideally Ba[Ti₂Fe₁₀]O₁₉, was found in the Quaternary volcanic rocks near üdersdorf, Graulai, and Altburg, western Eifel area, Germany. The new mineral typically occurs as euhedral platy grains in cavities of melilite- and leucite-nephelinite basalts. Associated minerals are hematite, magnetite, titanite, g?tzenite, clinopyroxene, nepheline, and biotite. It exhibits a hexagonal tabular habit flattened on {0001}, diameter 0.5–1 mm, thickness 20–125 μm, and {10&1macr;3}, {10&1macr;0} as observable forms. The mineral is opaque, of black color with submetallic lustre, and shows a ferrimagnetic behavior. VHN₅₀ is 793 with a range of 710–841 from ten indentations. The quantitative reflectance measurements of R_o/R_e on oriented grains in air and oil immersion, respectively, are [%]: for 470 nm 22.1/20.1 and 8.4/7.1, for 546 nm 21.0/19.4 and 7.8/6.6, for 589 nm 20.2/18.8 and 7.4/6.3, and for 650 nm 19.3/18.3 and 6.8/5.9. The bireflectance is distinct (air) to weak (oil), and parallel (0001) a moderate anisotropy with straight extinction can be observed. Typical microprobe analyses give [wt%] K₂O 0.28–0.33, Na₂O 0.17–0.20, SrO 0.46–0.55, BaO 11.80–12.17, MgO 1.27–1.47, Al₂O₃ 0.31–0.33, TiO₂ 13.11–13.63, MnO 2.38–2.57, Fe₂O₃ 61.36–63.12, FeO 5.49–5.86 (Fe³⁺/Fe²⁺ calculated for charge compensation), which is equivalent to (Ba_0.84Na_0.06K_0.06Sr_0.05)_1.01(Fe_8.48 ³⁺Fe_0.86 ²⁺Ti_1.82Mg_0.37Mn_0.37Al_0.06)_11.96O₁₉ as the average composition based on 19 oxygen atoms. Batiferrite is a magnetoplumbite-type mineral with hexagonal symmetry, space group P6 ₃ /mmc (no. 194), a = 5.909(1) ?, c = 23.369(4) ?, V = 706.6(2) ?³, Z = 2, and a calculated density of 5.016 gcm⁻³. The structure was refined to R1 = 0.031 for 278 unique reflections with F_o ² > 4σ (F_o ²) and R1 = 0.079 for all 452 unique observations using single crystal X-ray data. The strongest reflections of the X-ray powder diffraction pattern are [d _obs, I/I_o, (hkl)]: 2.631, 100, (114); 2.799, 80, (107); 1.478, 70, (220); 2.429, 60, (203); 1.672, 50, (217). The new mineral is comparable to the other Ba containing magnetoplumbite-type minerals haggertyite and hawthorneite, the iron content, however, is much higher and in the range of magnetoplumbite. The large cation site (A) is dominated by Ba, and four of the five remaining crystallographic cation sites in the structure are dominated by Fe (M1, 2, 3, 5), the octahedrally coordinated M4-site is dominated by Ti. No oxygen vacancy on the O3-site like in plumboferrite can be observed. Batiferrite is named for its main chemical composition and the relationship to the M-type hexaferrites (polytype 5H).

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Zusammenfassung Batiferrit, ein neues ferrimagnetisches Mineral des Magnetoplumbit-Typs aus den quart?ren Vulkaniten der West-Eifel, Deutschland Das neue Mineral Batiferrite, mit der Idealformel Ba[Ti₂Fe₁₀]O₁₉, wurde an drei Fundpunkten in den Quart?ren Vulkangesteinen der westlichen Eifel, Deutschland, in der N?he von üdersdorf, Graulai und Altburg gefunden. Das neue Mineral tritt typischerweise bl?ttchenf?rmig in kleinen Hohlr?umen von Melilith- und Leucit-Nephelininit Basalten auf. Vergesellschaftete Minerale sind H?matit, Magnetit, Titanit, G?tzenit, Klinopyroxen, Nephelin und Biotit. Der Habitus ist hexagonal tafelig nach {0001}, mit einem Durchmesser von 0.5–1 mm und einer Dicke von 20–125 μm, zus?tzlich k?nnen die Formen {10&1macr;3} und {10&1macr;0} beobachtet werden. Das Mineral ist opak, hat eine schwarze Farbe mit einem leicht metallischen Glanz, und ist ferromagnetisch. Die H?rte VHN₅₀ ist 793 mit einem Bereich von 710–841 aus 10 Eindruckbestimmungen. Die quantitativen Reflexionsmessungen von R_o/R_e an orientierten K?rnern in Luft beziehungsweise ?limmersion, ergaben [%]: für 470 nm 22.1/20.1 und 8.4/7.1, für 546 nm 21.0/19.4 und 7.8/6.6, für 589 nm 20.2/18.8 und 7.4/6.3, und für 650 nm 19.3/18.3 und 6.8/5.9. Die Bireflexion ist deutlich (Luft) bis schwach (?l) und parallel (0001) kann eine mittlere Anisotropie mit gerader Ausl?schung beobachtet werden. Eine typische Mikrosondenanalyse ergibt [wt%] K₂O 0.28–0.33, Na₂O 0.17–0.20, SrO 0.46–0.55, BaO 11.80–12.17, MgO 1.27–1.47, Al₂O₃ 0.31–0.33, TiO₂ 13.11–13.63, MnO 2.38–2.57, Fe₂O₃ 61.36–63.12, FeO 5.49–5.86 (Fe³⁺/Fe²⁺ berechnet zum Ladungsausgleich), die mittlere chemische Formel auf der Basis von 19 Sauerstoffatomen lautet (Ba_0.84Na_0.06K_0.06Sr_0.05)_1.01 (Fe_8.48 ³⁺Fe_0.86 ²⁺Ti_1.82Mg_0.37Mn_0.37Al_0.06)_11.96O ₁₉. Batiferrit ist ein Mineral der Magnetoplumbitgruppe, hat hexagonale Symmetrie mit der Raumgruppe P6₃/mmc (Nr. 194), a = 5.909(1) ?, c = 23.369(4) ?, V = 706.6(2) ?³, Z = 2, und einer berechneten Dichte von 5.016 gcm⁻³. Die Struktur wurde aus Einkristall-R?ntgendaten bis zu einem R1-Wert von 0.031 für 278 F_o ² > 4σ(F_o ²), und einem R1-Wert von 0.079 für alle 452 F_o ² verfeinert. Die st?rksten Beugungsreflexe der Pulver-R?ntgendaten sind [d_obs, I/I_o, (hkl)]: 2.631, 100, (114); 2.799, 80, (107); 1.478, 70, (220); 2.429, 60, (203); 1.672, 50, (217). Das neue Mineral weist deutliche ?hnlichkeiten zu den anderen beiden Ba-reichen Mineralen Haggertyit und Hawthorneit der Magnetoplumbit-Gruppe auf, jedoch ist der Eisengehalt wesentlich h?her und im Bereich des Minerals Magnetoplumbit. Der gro?e Kationenplatz (A) ist von Barium dominiert, vier (M1, 2, 3, 5) der restlichen fünf kristallographischen Kationenpl?tze in der Struktur sind fast ausschlie?lich mit Fe, die oktaedrisch koordinierte M4-Position ist überwiegend mit Ti besetzt. An der O3-Position konnte kein Sauerstoffdefizit wie in Plumboferrit festgestellt werden. Batiferrit ist nach seiner chemischen Beschaffenheit und nach seiner Zugeh?hrigkeit zu den M-Typ Hexaferriten (Polytyp 5H) benannt.

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Received December 14, 1999; accepted March 2, 2000     

The effect of species diversity on metal adsorption onto bacteria

In this study, we measure proton, Pb, and Cd adsorption onto the bacteria Deinococcus radiodurans, Thermus thermophilus, Acidiphlium angustum, Flavobacterium aquatile, and Flavobacterium hibernum, and we calculate the thermodynamic stability constants for the important surface complexes. These bacterial species represent a wide genetic diversity of bacteria, and they occupy a wide range of habitats. All of the species, except for A. angustum, exhibit similar proton and metal uptake. The only species tested that exhibits significantly different protonation behavior is A. angustum, an acidophile that grows at significantly lower pH than the other species of this study. We demonstrate that a single, metal-specific, surface complexation model can be used to reasonably account for the acid/base and metal adsorption behaviors of each species. We use a four discrete site non-electrostatic model to describe the protonation of the bacterial functional groups, with averaged pK_a values of 3.1 ± 0.3, 4.8 ± 0.2, 6.7 ± 0.1, and 9.2 ± 0.3, and site concentrations of (1.0 ± 0.17) × 10⁻⁴, (9.0 ± 3.0) × 10⁻⁵, (4.6 ± 1.8) × 10⁻⁵, and (6.1 ± 2.3) × 10⁻⁵ mol of sites per gram wet mass of bacteria, respectively. Adsorption of Cd and Pb onto the bacteria can be accounted for by the formation of complexes with each of the bacterial surface sites. The average log stability constants for Cd complexes with Sites 1-4 are 2.4 ± 0.4, 3.2 ± 0.1, 4.4 ± 0.1, and 5.3 ± 0.1, respectively. The average log stability constants for Pb complexes with Sites 1-4 are 3.3 ± 0.2, 4.5 ± 0.3, 6.5 ± 0.1, and 7.9 ± 0.5, respectively. This study demonstrates that a wide range of bacteria exhibit similar proton and metal adsorption behaviors, and that a single set of averaged acidity constants, site concentrations, and stability constants for metal-bacterial surface complexes yields a reasonable model for the adsorption behavior of many of these species. The differences in adsorption behavior that we observed for A. angustum demonstrate that genetic differences do exist between the cell wall functional group chemistries of some bacterial species, and that significant exceptions to the typical bacterial adsorption behavior do exist.     

Evolution and REE geochemistry of Huangsha-Tieshanlong ore-bearing granite

Our studies show that the granite bodies (γ ₅ ^{2 − 1} and γ ₅ ³ ) which constitute the Huangsha-Tieshanlong composite granitic intrusion in Jiangxi are characterized by their similarities in mineral assemblage, petrochemistry, trace element and REE distribution pattern. The values of ΣREE, ΣLREE, ΣHREE, ΣCe/ΣY, δEu and La/Yb apparently decrease from γ ₅ ^{2 − 1a} to γ ₅ ^{2 − 1b} , γ ₅ ³ and γ ₅ ³ . It is shown that the early Yenshanian W(Ta, Nb)-bearing granite (γ ₅ ^{2 − 1} ) and late Yenshanian Ta, Nb-bearing granite (γ ₅ ³ ) may have been derived from the differentiation and evolution of granitic magmas due to repeated remelting of the crust and their earlier and later intrusion. Although the earlier (γ ₅ ^{2 − 1b} and later (γ ₅ ³ ) albitized Ta, Nb-bearing granites show some obvious differences in REE content, their δEu values and La/Yb ratios are similar to each other. Therefore, it may be concluded that the early and late Ta, Nb-bearing granites were derived from a congenetic magma.     

Environmental geochemistry of toxic heavy metals in soils around Sarcheshmeh porphyry copper mine smelter plant,Rafsanjan, Kerman,Iran

The Sarcheshmeh copper mine smelter plant is one of the biggest copper producers in Iran. Long-time operation of about 25 years of the smelter plant causes release of potentially toxic heavy metals into the environment. In this paper, geochemical distribution of toxic heavy metals in 28 soil samples was evaluated around the Sarcheshmeh smelter plant. Soils developed over the nonmineralized and uncontaminated areas have an average background concentration of 41.25 mg kg⁻¹ Cu, 26.6 mg kg⁻¹ As, 12.7 mg kg⁻¹ Pb, 0.9 mg kg⁻¹ Sb, 1.9 mg kg⁻¹ Mo, 1.7 mg kg⁻¹ Sn, 0.2 mg kg⁻¹ Cd, 0.15 mg kg⁻¹ Bi, 235 mg kg⁻¹ S and 73.4 mg kg⁻¹ Zn, respectively. As a result of smelting process, the upper soil layers (0–5 cm) were polluted by Cu (>1,397 mg kg⁻¹), Cd (>3.42 mg kg⁻¹), S (>821 mg kg⁻¹), Mo (>10.3 mg kg⁻¹), Sb (>11.7 mg kg⁻¹), As (>120.6 mg kg⁻¹), Pb (>83.8 mg kg⁻¹), Zn (>214.9 mg kg⁻¹), and Sn (>3.7 mg kg⁻¹), respectively. These values are much higher than the normal concentration of the elements in the uncontaminated soil layers. The elemental values decrease with distance travelled away of the smelter plant, especially at minimum wind direction. Furthermore, high contaminated values of Cu (8,430 mg kg⁻¹), As (500 mg kg⁻¹), Pb (331 mg kg⁻¹), Mo (61 mg kg⁻¹), Sb (56.2 mg kg⁻¹), Zn (664 mg kg⁻¹), Cd (17.2 mg kg⁻¹), Bi (13.4 mg kg⁻¹), and S (3,780 mg kg⁻¹) were observed in the upper soil layers close to the smelting waste dumps. Sequential extraction analysis shows that about 270 mg kg⁻¹ Cu, 28 mg kg⁻¹ Pb, 50.33 mg kg⁻¹ Zn, and 47.84 mg kg⁻¹ As were adsorbed by Fe and Mn oxides. The carbonate phases include 151 mg kg⁻¹ Cu, 28 mg kg⁻¹ Pb, 25 mg kg⁻¹ Zn, and 32.99 mg kg⁻¹ As. Organic matter adsorbed 314.6 mg kg⁻¹ Cu and 29.18 mg kg⁻¹ Zn.     

Cadmium deposition and mobility in the sediments of an acidic oligotrophic lake

A dated core from the profoundal zone in a pristine oligotrophic acidic lake was analyzed for Cd as well as for Al, Ca, Fe, Mg, Mn, Pb, Ti and total carbon and nitrogen. Overlying water and porewater samples were also obtained on six occasions at the same site, and yielded vertical profiles of pH and dissolved Cd, Ca, Fe, Mg, Mn, sulfide, SO₄⁻², organic and inorganic carbon concentrations. These extensive porewater and sediment geochemical data were used, together with information on infaunal benthos, to decipher the sedimentary record of Cd contamination. Depth variation of sediment Ca concentrations indicate that the lake suffered from progressive acidification starting about 1950. The present-day accumulation rate of Cd (J_acc^Cd = 5.4 ± 0.4 × 10⁻¹¹ mol cm⁻² yr⁻¹) in the sediments is the sum of the flux of Cd deposited with settling particles (J_S^Cd = 3.3 ± 0.2 × 10⁻¹¹ mol cm⁻² yr⁻¹) and the fluxes of dissolved Cd across the sediment-water interface due to molecular diffusion (J_D^Cd = 1.8 ± 0.3 × 10⁻¹¹ mol cm⁻² yr⁻¹), bioturbation (J_B^Cd = 1.1 ± 0.2 × 10⁻¹⁴ mol cm⁻² yr⁻¹) and bioirrigation (J_I^Cd = 0.27 ± 0.05 × 10⁻¹¹ mol cm⁻² yr⁻¹). Biological mixing of the sediments was negligible. The shape of the vertical profile of total Cd concentration with depth in the sediment appears to be determined more by its input history than by post-depositional mobilization and redistribution in the sediment column.