Plume-lithosphere interactions in the ocean basins: constraints from the source mineralogy

Trace element relationships of near-primary alkalic lavas from La Grille volcano, Grande Comore, in the Indian Ocean, as well as those of the Honolulu volcanic series, Oahu, Hawaii, show that their sources contain amphibole and/or phlogopite. Small amounts of each mineral (2% amphibole in the source of La Grille and 0.5% phlogopite plus some amphibole in the source of the Honolulu volcanics) and a range of absolute degrees of partial melting from 1 to 5% for both series are consistent with the observed trace element variation. Amphibole and phlogopite are not stable at the temperatures of convecting upper mantle or upwelling thermal plumes from the deep mantle; however, they are stable at pressure-temperature conditions of the oceanic lithospheric mantle. Therefore, the presence of amphibole and/or phlogopite in the magma source region of volcanics is strong evidence for lithospheric melting, and we conclude that the La Grille and the Honolulu series formed by melting of the oceanic lithospheric mantle.

The identification of amphibole ± phlogopite in the source region of both series implies that the metasomatism by fluids or volatile-rich melts occurred prior to melting. The presence of hydrous phases results in a lower solidus temperature of the lithospheric mantle, which can be reached by conductive heating by the thermal plumes. Isotope ratios of the La Grille and the Honolulu series display a restricted range in composition and represent compositional end-members for each island. Larger isotopic variations in shield lavas, represented by the contemporaneous Karthala volcano on Grande Comore and the older Koolau series on Oahu, reflect interaction of the upwelling thermal plumes with the lithospheric mantle rather than the heterogeneity of deep-seated mantle plume sources or entrainment of mantle material in the rising plume. Literature OsSr isotope ratio covariations constrain the process of plume-lithosphere interaction as occurring through mixing of plume melts and low-degree melts from the metasomatized oceanic lithospheric mantle.

The characterization of the lithospheric mantle signature allows the isotopic composition of the deep mantle plume components to be identified, and mixing relationships show that the Karthala and Koolau plume end-members have nearly uniform isotopic compositions. Based on independent arguments, isotopic variations on Heard and Easter islands have been shown to be a result of mixing between deep plume sources having distinct isotopic compositions with lithosphere or shallow asthenospheric mantle. To the extent that these case studies are representative of oceanic island volcanism, they indicate that interaction with oceanic lithospheric mantle plays an important role in the compositions of lavas erupted during the shield-building stage of plume magmatism, and that isotopic compositions of deep mantle plume sources are nearly uniform on the scale that they are sampled by melting.     

Paleobathymetry of the crest of spreading ridges related to the age of ocean basins

Measurements of the crest of the spreading ridge in the young ocean basins of the Afar region and Gulf of Aden and in the mature Indian, Atlantic, and Pacific Oceans show that the depth of the ridge crest is correlated (r = 0.99) with the logarithm of the age of the ocean basin. Ridge crests in a very young basin (Afar) are at sea level, at about 1.5 km in young basins (Gulf of Aden), and at about 2.6 km in mature basins (Indian, Atlantic, Pacific). A new curve that relates crestal depth and age of the ocean basin is coupled with the existing depth/age curve for oceanic crust in a comprehensive scheme which can be used for relating depth and age of oceanic crust.     

Cascading ocean basins: numerical simulations of the circulation and interbasin exchange in the Azov-Black-Marmara-Mediterranean Seas system

In this paper, we use the unstructured grid model SCHISM to simulate the thermohydrodynamics in a chain of baroclinic, interconnected basins. The model shows a good skill in simulating the horizontal circulation and vertical profiles of temperature, salinity, and currents. The magnitude and phases of the seasonal changes of circulation are consistent with earlier observations. Among the mesoscale and subbasin-scale circulation features that are realistically simulated are the anticyclonic coastal eddies, the Sebastopol and Batumi eddies, the Marmara Sea outflow around the southern coast of the Limnos Island, and the pathway of the cold water originating from the shelf. The superiority of the simulations compared to earlier numerical studies is demonstrated with the example of model capabilities to resolve the strait dynamics, gravity currents originating from the straits, high-salinity bottom layer on the shallow shelf, as well as the multiple intrusions from the Bosporus Strait down to 700 m depth. The warm temperature intrusions from the strait produce the warm water mass in the intermediate layers of the Black Sea. One novel result is that the seasonal intensification of circulation affects the interbasin exchange, thus allowing us to formulate the concept of circulation-controlled interbasin exchange. To the best of our knowledge, the present numerical simulations, for the first time, suggest that the sea level in the interior part of the Black Sea can be lower than the sea level in the Marmara Sea and even in some parts of the Aegean Sea. The comparison with observations shows that the timings and magnitude of exchange flows are also realistically simulated, along with the blocking events. The short-term variability of the strait transports is largely controlled by the anomalies of wind. The simulations demonstrate the crucial role of the narrow and shallow strait of Bosporus in separating the two pairs of basins: Aegean-Marmara Seas from one side and Azov-Black Seas from the other side. The straits of Kerch and Dardanelles provide sufficient interbasin connectivity that prevents large phase lags of the sea levels in the neighboring basins. The two-layer flows in the three straits considered here show different dependencies upon the net transport, and the spatial variability of this dependence is also quite pronounced. We show that the blocking of the surface flow can occur at different net transports, thus casting doubt on a previous approach of using simple relationships to prescribe (steady) outflow and inflow. Specific attention is paid to the role of synoptic atmospheric forcing for the basin-wide circulation and redistribution of mass in the Black Sea. An important controlling process is the propagation of coastal waves. One major conclusion from this research is that modeling the individual basins separately could result in large inaccuracies because of the critical importance of the cascading character of these interconnected basins.     

Petrogenesis of acid rocks of the deccan traps

The acid rocks of the Deccan Traps including microgranites, felsites, rhyolites and related rocks are contined to tectonically weak zones in Western India. The significance of their distribution is discussed and the opinions expressed on the genesis of the rocks are critically reviewed. In their formation, fractional crystallization of tholeiitie basalt magma, which is supposed to be the parental one, was aided in certain localities by the melting of the sialic crust and assimilation or partial melting of the pre-Deccan Trap rocks. Evidence for the latter is found in the gradational contacts of the acid rocks with the earlier rocks, their association with cruptive centres or faulted zones and absence of any definite trend of variation in petrographical and chemical characters. Some of the rhyolitic rocks are also formed due to hydrothermal alteration of sedimentaries along the Narmada Valley.     

Peralkaline acid volcanic rocks of oceanic islands

Occurrences of peralkaline acid volcanic rocks on oceanic islands are reviewed. Peralkaline differentiates are usually associated with mildly alkaline or transitional basalts and often with related sodic intermediate rocks. A compositional gap between basaltic and salic rocks is not invariably present. Although a comenditic end member is more usual in the oceanic suites, pantellerites are particularly well developed on Socorro Island and also on Gran Canaria where they form extensive ignimbrite sheets. There may be a genetic distinction between peralkaline rocks of islands which lie near the crests of oceanic rises and those which are built on broad submarine plateaux.     

The ages of the lunar maria and the filling of the mare basins

The age discrepancy between lunar highlands and mare is examined in terms of a hydrostatic head model incorporating an impact crater being fed continuously from depth with basaltic magma. It is shown that if the age difference is attributed to the filling time of the impact basin, the dimensions of the volcanic feeder conduits are of the order of a few metres.     

First- and higher-order dynamical controls on water exchanges between tidal basins and the open ocean. A case study for the East Frisian Wadden Sea

Observational data, high-resolution numerical modelling results and a simple analytical theory are combined in this paper to demonstrate the dependence of the volume transports through tidal inlets on topographical or morphological parameters of a Wadden Sea system. The area of interest covers the East Frisian Wadden Sea and consists of seven weakly connected tidal basins. The observations include time series of tidal gauge data and surface currents measured at a pile station in the backbarrier basin of the island Langeoog, as well as several ADCP transects in the Accumer Ee tidal inlet. The numerical simulations are based on the 3-D primitive equation General Estuarine Transport Model (GETM) with a horizontal resolution of 200 m and terrain following vertical coordinates. The model is forced at its open boundaries with sea-level data from an operational model for the German Bight (German Hydrographic Office). The simple theoretical concepts presented illustrate the effect of topography (hypsometry) in the tidal basins on the temporal variability of the exchange of water. This topographic control is effectuated through the bottom slope in the areas prone to drying and flooding. For our study area it takes about twice as long from slack water to maximum flood current than from slack water to maximum ebb current. The underlying physics of this signal modulation from a more or less harmonic forcing at the open-sea boundary and the quantification of the contributing physical processes are the major results of this paper. Estimates based simply on volume conservation are consistent with observations and results from numerical modelling, but they do not completely capture the actual non-linear tidal response. Our analysis shows that at least during part of the tidal cycle characteristic topographic parameters of the inlet/bay system have a major impact on the rate of exchange of waters between the Wadden Sea and the open ocean. This impact is especially strong during the transition between flood and ebb conditions. The possible morphodynamic responses are also addressed focusing on some common (universal) topographic features in seven tidal basins.Responsible Editor: Hans Burchard     

The thorium isotope content of ocean water

²³²Th concentrations of surface and deep Pacific Ocean waters are 0.01–0.02 dpm/1000 kg (60 pgm/kg). The²³⁰Th activity is 0.03–0.13 dpm/1000 kg in surface waters and 0.3–2.7 dpm/1000 kg in deep waters. Chemical residence times based on in situ production from parent isotopes are about the same for²³⁰Th and²²⁸Th in surface waters (1–5 years) but are ten times greater for²³⁰Th in deep waters (10–100 years). Apparently there are additional sources of²³⁰Th into deep waters. At MANOP site S manganese nodule tops are enriched in Th isotopes by adsorption of Th from seawater and not by incorporation of Th-rich particulates.     

The nonlinear spin-up of a stratified ocean

Abstract

The adjustment of a nonlinear, quasigeostrophic, stratified ocean to an impulsively applied wind stress is investigated under the assumption that barotropic advection of vortex tube length is the most important nonlinearity. The present study complements the steady state theories which have recently appeared, and extends earlier, dissipationless, linear models.

In terms of Sverdrup transport, the equation for baroclinic evolution is a forced advection-diffusion equation. Solutions of this equation subject to a “tilted disk” Ekman divergence are obtained analytically for the case of no diffusion and numerically otherwise. The similarity between the present equation and that of a forced barotropic fluid with bottom topography is shown.

Barotropic flow, which is assumed to mature instantly, can reverse the tendency for westward propagation, and thus produce regions of closed geostrophic contours. Inside these regions, dissipation, or equivalently the eddy field, plays a central role. We assume that eddy mixing effects a lateral, down-gradient diffusion of potential vorticity; hence, within the closed geostrophic contours, our model approaches a state of uniform potential vorticity. The solutions also extend the steady-state theories, which require weak diffusion, by demonstrating that homogenization occurs for moderately strong diffusion.

The evoiution of potential vorticity and the thermocline are examined, and it is shown that the adjustment time of the model is governed by dissipation, rather than baroclinic wave propagation as in linear theories. If dissipation is weak, spin-up of a nonlinear ocean may take several times that predicted by linear models, which agrees with analyses of eddy-resolving general circulation models. The inclusion of a western boundary current may accelerate this process, although dissipation will still play a central role.     

The importance of ocean temperature to global biogeochemistry

Variations in the mean temperature of the ocean, on time scales from millennial to millions of years, in the past and projected for the future, are large enough to impact the geochemistry of the carbon, oxygen, and methane geochemical systems. In each system, the time scale of the temperature perturbation is key. On time frames of 1-100 ky, atmospheric CO₂ is controlled by the ocean. CO₂ temperature-dependent solubility and greenhouse forcing combine to create an amplifying feedback with ocean temperature; the CaCO₃ cycle increases this effect somewhat on time scales longer than ∼5-10 ky. The CO₂/T feedback can be seen in the climate record from Vostok, and a model including the temperature feedback predicts that 10% of the fossil fuel CO₂ will reside in the atmosphere for longer than 100 ky. Timing is important for oxygen, as well; the atmosphere controls the ocean on short time scales, but ocean anoxia controls atmospheric pO₂ on million-year time scales and longer. Warming the ocean to Cretaceous temperatures might eventually increase pO₂ by approximately 25%, in the absence of other perturbations. The response of methane clathrate to climate change in the coming century will probably be small, but on longer time scales of 1-10 ky, there may be a positive feedback with ocean temperature, amplifying the long-term climate impact of anthropogenic CO₂ release.     

The overlooked role of the ocean in mercury cycling in the Arctic

The rapid and high bioaccumulation of mercury in marine mammals and its spatial and temporal variations have been a major puzzle in the Arctic. While extensive efforts have been focussed on the monitoring and chemistry of atmospheric mercury depletion events, a recent mass budget estimate of mercury in the Arctic suggests that we have overlooked the role of the ocean itself. Only through focussed studies on Hg dynamics in the Arctic Ocean under a changing climate are we going to understand what the risk of mercury is to those marine ecosystems and the people who rely on them.     

The equatorial dynamics of a deep homogeneous ocean

Abstract

The flow properties of an homogeneous fluid which is bounded by two concentric spheres and two meridional planes which intersect along a diameter of the spheres are investigated. The spheres rotate about this diameter with slightly different angular velocities. As in the axisymmetric case studied by Proudman (1956) and Stewartson (1966) the viscous terms in the equations of motion are important only in boundary layers on the spheres and on the cylinder C which circumscribes the inner sphere and which has generators parallel to the axis of rotation, provided the Ekman number E is small. In the inviscid region the velocities are independent of the coordinate measuring distance along the axis of rotation and are much weaker, by a factor 0(E ^½), than the velocities in the Ekman layer on the driving surface (outer sphere). (It is assumed that the reference frame is fixed in the slower rotating inner sphere.) If the separation of the spheres is small compared to their radii then the asymmetric circulation inside C is characterized by an intense jet along the western wall. Loss of fluid from this jet sustains the eastward and northward flow in the inviscid interior where motion is driven by the suction of the Ekman layer on the outer sphere. (Geophysical conventions have been adopted.) Outside C an intense current is present on the eastern, not western, wall while motion in the inviscid region is westward, and away from the axis of rotation. Though there is no transport across C in the inviscid region, the meridional transport of the Ekman layer on the outer sphere is continuous across C and increases, through suction, as the equator is approached until it drains into an eastward flowing equatorial current of width 0(E ^1/7). The eastern boundary current outside C and shear layers on C carry this fluid to the intersection of C and the western wall where it feeds the western boundary current inside C.

The relation between this study and the experiments of Baker and Robinson (1970) is discussed.     

The effect of cracks on the thermal expansion of rocks

Thermal expansion during the first heating cycle at atmospheric pressure was measured in several directions in seven igneous rocks between 25° and 400°C at slow heating rates. The coefficient of thermal expansion measured under these conditions increases more rapidly as temperature is increased than the average thermal expansion coefficient of the constituent minerals. The “extra” expansion is attributed to the formation of cracks by differential expansion of mineral grains. The presence of such cracks in the rocks during the cooling part of the cycle and during any subsequent heating and cooling cycles will result in a substantial decrease in the coefficient of thermal expansion as compared to that measured during the first heating cycles. The effect of cracks initially present in a rock was studied by measuring the full tensor of the coefficient of thermal expansion on two rocks with anisotropic crack distributions. In these two rocks the coefficient of thermal expansion is least in the direction perpendicular to the plane of greatest crack concentration. The implication of our data is that thermal expansion depends greatly on the fracture state of the rock. Both the fractures in the rock and the boundary conditions on the rock are significant for the interpretation of thermal expansion measurements and for their application to other problems.     

The magnetic anisotropy of hematite bearing rocks

Summary The high field torque curves of hematite bearing rocks are not caused by directional differences in the energy of magnetization to saturation, but rather by the couple between the ferromagnetic moment and the applied field. An expression, derived for the high field torque curve of a single crystal of hematite, whose basal plane makes an arbitrary angle with the plane of rotation of the applied field, is found to be in excellent agreement with experiment. Furthermore it is shown that the Fourier spectrum of hematite bearing rocks should in general contain significant higher harmonics and that therefore the high field method is not particularly suitable for determining the preferred crystalline alignment of hematite bearing rocks.     

The composition of nutrient fluxes from contrasting UK river basins

Accurate estimates of N and P loads were obtained for four contrasting UK river basins over a complete annual cycle. The fractionation of these loads into dissolved and particulate, and inorganic and organic components allowed a detailed examination of the nutrient load composition and of the factors influencing both the relative and absolute magnitude of these components. The particulate phosphorus (TPP) loads account for 26–75% of the annual total phosphorus (TP) transport and are predominantly inorganic. The inorganic (PIP) and organic (POP) fractions of the TPP loads represent 20–47% and 6–28% of the annual TP transport, respectively. In contrast, the particulate nitrogen loads (TPN) represent 8% or less of the annual total nitrogen (TN) loads and are predominately organic. For dissolved P transport, the dissolved inorganic fraction (DIP) is more important, representing 15–70% of the TP loads, whereas the dissolved organic fraction (DOP) represents only 3–9% of the TP loads. The TN loads are dominated by the dissolved component and more particularly the total oxidized fraction (TON), which is composed of nitrate and nitrite and represents 76–82% of the annual TN transport. The remaining dissolved N species, ammonium (NH₄-N) and organic N (DON) account for 0·3–1·2% and 13–16% of the annual TN transport, respectively. The TPN and TPP fluxes closely reflect the suspended sediment dynamics of the study basins, which are in turn controlled by basin size and morphology. The dissolved inorganic nutrient fluxes are influenced by point source inputs to the study basins, especially for P, although the TON flux is primarily influenced by diffuse source contributions and the hydrological connectivity between the river and its catchment area. The dissolved organic fractions are closely related to the dissolved organic carbon (DOC) dynamics, which are in turn influenced by land use and basin size. The magnitude of the NH₄-N fraction was dependent on the proximity of the monitoring station to point source discharges, because of rapid nitrification within the water column. However, during storm events, desorption from suspended sediment may be temporarily important. Both the magnitude and relative contribution of the different nutrient fractions exhibit significant seasonal variability in response to the hydrological regime, sediment mobilization, the degree of dilution of point source inputs and biological processes. © 1998 John Wiley & Sons, Ltd.     

Hack's law of debris-flow basins

Hack's law was originally derived from basin statistics for varied spatial scales and regions.The exponent value of the law has been shown to vary between 0.47 and 0.70,causing uncertainty in its application.This paper focuses on the emergence of Hack's law from debris-flow basins in China.Over 5,000 debris-flow basins in different regions of China with drainage areas less than 100km2 are included in this study.Basins in the different regions are found to present similar distributions.Hack's law is derived fi'om maximum probability and conditional distributions,suggesting that the law should describe some critical state of basin evolution.Results suggest the exponent value is approximately 0.5.Further analysis indicates that Hack's law is related to other scaling laws underlying the evolution of a basin and that the exponent is not dependent on basin shape but rather on the evolutionary stage.A case study of a well known debris-flow basin further confirms Hack's law and its implications in basin evolution.