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The system Mg2SiO4MgOH2O was investigated at pressures between 85 and 160 kbar and at temperatures between 750 and 1200°C. In runs for a gel with Mg/Si ratio of 3 and with 4.0 wt.-percent H2O, a dense hydrous magnesian silicate, denoted phase B by Ringwood and Major, was found at pressures from about 100 kbar to at least 160 kbar in the whole temperature range studied. In the following table the crystallographic parameters and chemical formula of phase B, determined in this study, are compared with those of the other dense hydrous silicates in Mg2SiO4MgOH2O.
Phase | Composition | Space group | Cell parameters | Density (g cm?3) | |||
β | |||||||
(Å) | (Å) | (Å) | (°) | ||||
Chondrodite | Mg5Si2O10H2 | 7.914 | 4.752 | 10.350 | 108.71 | 3.06 | |
Clinohumite | Mg9Si4O18H2 | 13.695 | 4.747 | 10.284 | 100.64 | 3.14 | |
Phase A | Mg7Si2O14H6 | 7.860 | 9.573 | 2.96 | |||
Phase B | Mg23Si8O42H6 | 10.600 | 14.098 | 10.092 | 104.05 | 3.32 |
Zone | Depth(m) | Average87Sr/86Sr | Average δ18O (%o) | Average δD (%o) |
I | 275–550 | 0.7032 | 7.3 | −63 |
II | 550–890 | 0.7029 | 6.5 | −45 |
III | 890–1050 | 0.7035 | 5.6 | −31 |
IV | 1050–1350 | 0.7032 | 5.5 | −36 |
Full-size table
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