Mineralogy and chemical composition of the clay fraction of Neogene shales from the Surma Group in the Bengal basin,Bangladesh

Mineralogical and chemical investigations (<2μm clay separates) of shale samples from the Neogene-age Surma Group obtained from four wells (Habiganj-11, Shahbazpur-1, Titas-11, Titas-15) in the Bengal basin, Bangladesh, were carried out in order to reveal the clay mineral composition as reservoir exploration and exploitation requires a good understanding of the clay minerals. The samples were analyzed by X-ray diffraction (XRD), scanning electron microscope (SEM) and X-Ray fluorescence spectrometry (XRF). Mineralogically, the sub-surface Surma Group shales comprise predominantly quartz, plagioclase, illite, chlorite, kaolinite, with lesser amounts of K-feldspar, dolomite and smectite, and minor to trace amounts of calcite, siderite and pyrite. The chemical composition of the <2 μm clay separates also suggests an illite and chlorite-rich composition. With increasing burial depth, the Surma Group shales are enriched in illite. The gradual decreasing of the smectite clays with depth and ultimate disappearance at greater depths (≥ 3000 m) may have been responsible for the presence of the diagenetic illite. Based on the mineralogical composition it is most likely that the illite-chlorite associations together with quartz and feldspar were predominantly detrital in origin and thus reflect the presence of a rapidly-rising source terrain not subjected to intense weathering.     

Clay mineralogy of the ocean sediments from the Wilkes Land margin,east Antarctica: implications on the paleoclimate,provenance and sediment dispersal pattern

Core U1359 collected from the continental rise off Wilkes Land, east Antarctica, is analyzed for the clay mineralogy and carbon content. The temporal variation of the clay mineralogical data shows a dominance of illite with chlorite, smectite and kaolinite in decreasing concentration. Clay mineral illite is negatively correlated with smectite which shows enrichment during 6.2–6.8, 5.5–5.8, 4.5 and 2.5 Ma. The mineralogical analyses on the silt size fraction (2–53 μm) of some selected samples were also carried out. The combined result of both the size fractions shows the presence of chlorite and illite in both size fractions, smectite and kaolinite only in clay size fraction (<2 μm) and similarity in the crystallinity and chemistry of illite in both fractions. Similar nature of illite in both fractions suggests negligible role of sorting probably due to the deposition from the waxing ice sheet. During times of ice growth, nearby cratonic east Antarctica shield provided biotite-rich sediments to the depositional site. On the other hand, the presence of smectite, only in the clay size fraction, suggests the effective role of sorting probably due to the deposition from distal source in ice retreat condition. During times of ice retreat, smectite-rich sediment derived from Ross Orogen is transported to the core site through surface or bottom water currents. Poor crystallinity of illite due to degradation further corroborates the ice retreat condition. The ice sheet proximal sediments of U1359 show that in the eastern part of Wilkes Land, the ‘warming’ was initiated during late Miocene.     

Rb-Sr geochronology of Vendian shales,the Staraya Rechka Formation,Anabar Massif,northern Siberia

Fine-grained clayey subfractions (SF) with particle sizes of 1–2, 0.6–1.0, 0.3–0.6, 0.2–0.3, 0.1–0.2, and <0.1 μm were extracted from shales of the Vendian Staraya Rechka Formation in the Anabar Massif and studied by XRD and Rb-Sr methods. All the clayey subfractions are represented by illite with high crystallinity indices, which are characteristic of the low-temperature diagenesis/catagenesis zone and grow with the decrease of the particle size. The Rb-Sr systematics in clayey subfractions combined with mineralogical data provide grounds for the conclusion that illite from clayey rocks of the Staraya Rechka Formation was forming during two periods: approximately 560 and 391–413 Ma ago. The first illite generation was likely formed in the course of lithostatic subsidence of the Staraya Rechka sediments and the second one, during the Devonian lithogenesis stage. It is assumed that age of the first generation (∼560 Ma) is close to that of the Staraya Rechka Formation. This inference is consistent with biostratigraphic, chemostratigraphic, and geochronological data obtained for both rocks of the Anabar Massif and Vendian sediments from other regions of Siberia.     

The role of tectonic shear strain on the illitization mechanism of mixed-layers illite–smectite. A case study from a fault zone in the Northern Apennines,Italy

The influence of tectonic strain on the diagenetic degree and illitization process of mixed-layers illite–smectite at shallow crustal conditions was studied. For this purpose, the modal composition of clay fraction and illite FWHM parameters of argillites deformed by a regional-scale fault zone were studied in detail by XRD, chemical analyses and by SEM observations. Analyses were performed on deformed samples of the fault rock and compared with the non-deformed rocks off the fault zone. In addition, this paper reports a detailed comparative analysis of deformed (shear surfaces and cleavage domains) and non-deformed domains (lithon cores) of a scaly fabric in the fault rock. A systematic increase in illite concentration, a decrease of Kübler index and FWHM₍₀₀₂₎ values, and an enrichment of K⁺ ions were observed in cleavage domains with respect to the non-deformed sediments off the fault zone and the lithon cores within the fault rock. Migration of K⁺-rich fluids along scaly cleavage domains causes progressive conversion of smectite-rich I–S to illite-rich I–S and thickening of illite crystallites along the c-direction. Changes in mineralogical and crystallographic parameters, therefore, seem to be strongly controlled by shear plane development in highly sheared rocks.     

Formation of chlorite during thrust fault reactivation. Record of fluid origin and P–T conditions in the Monte Perdido thrust fault (southern Pyrenees)

The chemical and isotopic compositions of clay minerals such as illite and chlorite are commonly used to quantify diagenetic and low-grade metamorphic conditions, an approach that is also used in the present study of the Monte Perdido thrust fault from the South Pyrenean fold-and-thrust belt. The Monte Perdido thrust fault is a shallow thrust juxtaposing upper Cretaceous–Paleocene platform carbonates and Lower Eocene marls and turbidites from the Jaca basin. The core zone of the fault, about 6 m thick, consists of intensely deformed clay-bearing rocks bounded by major shear surfaces. Illite and chlorite are the main hydrous minerals in the fault zone. Illite is oriented along cleavage planes while chlorite formed along shear veins (<50 μm in thickness). Authigenic chlorite provides essential information about the origin of fluids and their temperature. δ¹⁸O and δD values of newly formed chlorite support equilibration with sedimentary interstitial water, directly derived from the local hanging wall and footwall during deformation. Given the absence of large-scale fluid flow, the mineralization observed in the thrust faults records the P–T conditions of thrust activity. Temperatures of chlorite formation of about 240°C are obtained via two independent methods: chlorite compositional thermometers and oxygen isotope fractionation between cogenetic chlorite and quartz. Burial depth conditions of 7 km are determined for the Monte Perdido thrust reactivation, coupling calculated temperature and fluid inclusion isochores. The present study demonstrates that both isotopic and thermodynamic methods applied to clay minerals formed in thrust fault are useful to help constrain diagenetic and low-grade metamorphic conditions.     

Rock Mechanical Characterization of an Offshore Mudrock from Haltenbanken, Mid-Norway

Summary Rock mechanical tests and subsequent investigations in scanning electron microscopy (SEM) have been carried out on samples retrieved from the Late Cretaceous Springar Fm offshore Mid-Norway. Mineralogical and petrophysical analyses pertinent to this study have been conducted according to standard methods. The Springar Fm has a clay content of 45–50%, with smectite rich mixed-layer illite/smectite as the dominating clay mineral. Consolidated undrained (CU) triaxial tests show a geomechanically brittle behaviour at all test conditions. The brittle behaviour is mainly due to diagenetic siderite cement. During the rock mechanical consolidation phases only minor reductions in the pore volumes took place. During the induced shear deformation local orientation of small mica grains parallel to the direction of shear occurred in the vicinity of the failure zone. The small fabric changes observed in the SEM are in agreement with the low deformations seen from the CU triaxial test data of the Springar Fm.     

Catagenesis and burial metamorphism of terrigenous and volcanic sequences (section recovered by the En-Yakhinskaya parametric borehole SG-7)

Secondary alterations of Cretaceous, Jurassic, and Triassic terrigenous complexes recovered by borehole SG-7 were studied from the depth of 3620 m to 6920 m (roof of basalts). Down to the depth of ∼6770 m, the section shows a gradual intensification of catagenetic alterations of sandy rocks: the formation of pressure dissolution textures and regeneration of clastic quartz. Intensification of the transformation of clay minerals is not observed in this mineral. Variations in the contents of illite, hydromicas, mixed-layer minerals, smectite, chlorite, and kaolinite at different depths of the recovered section are related to changes in the provenance during the accumulation of sedimentary complexes. The Middle Triassic coarse-grained sandy rocks (suprabasalt sequence) are more intensely transformed: they are marked by microstylolitic textures of pressure dissolution, recrystallization blastesis of clastic quartz grains, and newly formed zoisite. The composition of clay minerals is also characterized by variation: micas are represented by sericite with ΔD = 0; Fe-chlorite and kaolinite are noted. These features suggest the absence of linear positive correlation of T and P with the subsidence depth of sedimentary complexes. Intense heating (up to 200–300°C) of the Middle Triassic suprabasalt rocks is likely caused by trap activity (intense effusion of basalt lavas). Investigation of secondary minerals in basalts recovered by borehole SG-7 revealed that the grade of their transformation matches the medium-temperature subfacies of the greenschist facies.     

Clay minerals in sediments of the hydrothermally active southern trough in the Guaymas Basin (Gulf of California)

The results of the study of clay mineral alterations in Upper Pleistocene sediments of the southern trough in the Guaymas Basin (Gulf of California) due to the influence of hydrothermal solutions and heat produced by sill intrusions are discussed. Core samples from DSDP Holes 477 and 477A were taken for the analysis of clay minerals. Application of the method of modeling X-ray diffraction patterns of oriented specimens of the finely dispersed particles made it possible to establish the phase composition of clay minerals, determine their structural parameters, and obtain reliable quantitative estimates of their contents in natural mixtures. The modeling data allowed us to characterize reliably the transformation of clay minerals in sediments of the hydrothermally active southern trough in the Guaymas Basin. In Upper Pleistocene sandy–clayey sediments of the southern trough, changes in the composition of clay minerals occurred under the influence of a long-living hydrothermal system. Its lower part (interval 170.0–257.5 m) with maximum temperatures (~300°C) was marked by the formation of chlorite. Terrigenous clay minerals are not preserved here. Saponite appears at a depth of 248 m in the chlorite formation zone. Higher in the sedimentary section, the interval 146–170 m is also barren of terrigenous clay minerals. Sediments of this interval yielded two newly formed clay minerals (chlorite and illite), which were formed at lower temperatures (above 180°C and below 300°C, approximately up to ~250°C), while the relatively low-temperature upper part (110–146 m) of the hydrothermal system (from ~140°C to ~180°C) includes the mixture of terrigenous and newly formed clay minerals. Terrigenous illite is preserved here. Illitization of the mixed-layer illite–smectite was subjected to illitization. The terrigenous montmorillonite disappeared, and chlorite–smectite with 5–10% of smectite layers were formed. In the upper interval (down to approximately 110 mbsf), the composition of terrigenous clay minerals remains unchanged. They are composed of the predominant mixed-layer illite–smectite and montmorillonite, the subordinate illite, mixed-layer chlorite–smectite with 5% of smectite layers, mixed-layer kaolinite–smectite with 30% of smectite layers, and kaolinite. This composition of clay minerals changed under the influence of sill intrusions into the sedimentary cover at 58–105 m in the section of Hole 477. The most significant changes are noted in the 8-m-thick member above the sill at 50–58 m. The upper part of this interval is barren of the terrigenous mixed-layer illite–smectite, which is replaced by the newly formed trioctahedral smectite (saponite). At the same time, the terrigenous dioctahedral smectite (montmorillonite) is preserved. The composition of terrigenous clay minerals remains unchanged at the top of the unit underlying the sill base.     

Climatic and tectonic uplift evolution since ~7 Ma in Gyirong basin, southwestern Tibet plateau: clay mineral evidence

Climate evolution associated with the uplift in Gyirong, southern margin of the Tibetan plateau, was investigated based on the clay mineralogy of the Gyirong sediments, using X-ray diffraction and scanning electron microscopy methods. The (chlorite + illite)/(kaolinite + smectite) ratio and the illite crystallinity index suggest the trend of paleoclimate evolution in Gyirong basin during ~7–1.7 Ma BP, with a warm and humid climate in ~7.0–5.8 Ma, a relative cool and dry climate in ~5.8–5.5 Ma, a relative warm and humid climate in ~5.5–2.5 Ma, and a much warmer climate in ~2.5–1.7 Ma, respectively. The fluctuating kaolinite/smectite index and calcite content and the frequent occurrence of gypsum in the episode of ~6.7–5.5 Ma suggest intense climatic fluctuations between humid and more seasonal humid conditions. Five peaks exhibit at 5.8, 4.9, 4.3, 3.6, and 2.5 Ma in the curves of illite and chlorite content and illite crystallinity. The intense uplift and tectonic-forced cooling at ~5.8 and 4.3 Ma were indicated by the high-illite crystallinity index and illite and chlorite content. A remarkable increase in illite and chlorite content associated with only little increase in illite crystallinity at ~3.6 Ma indicates a rapid uplift, but no significant climate change. And a sharp increase in illite crystallinity, while small change in illite and chlorite content at ~2.5 Ma suggests that no remarkable relief was produced by the uplift, which may take place in the whole south Tibet plateau, while cooling at 4.9 Ma is probably a record of the global climate cooling.     

Metamorphic and Thermal History of a Fore-Arc Basin: the Fossil Bluff Group, Alexander Island, Antarctica

The Himalia Ridge Formation (Fossil Bluff Group), AlexanderIsland is a 2·2-km-thick sequence of Upper Jurassic–LowerCretaceous conglomerates, sandstones and mudstones, derivedfrom an andesitic volcanic arc and deposited in a fore-arc basin.The metamorphic and thermal history of the formation has beendetermined using authigenic mineral assemblages and vitrinitereflectance measurements. Metamorphic effects include compaction,pore-space reduction, cementation and dissolution and replacementof detrital grains by clay minerals (smectite, illite/smectite,corrensite and kaolinite), calcite, chlorite, laumontite, prehnite,pumpellyite, albite and mica, with less common quartz, haematite,pyrite and epidote. The authigenic mineral assemblages exhibita depth-dependence, and laumontite and calcite exhibit a strongantipathetic relationship. Detrital organic matter in the argillaceouslayers has vitrinite reflectance values (R_o) ranging from 2·3to 3·7%. This indicates considerable thermal maturation,with a systematic increase in reflectivity with increasing depth.There is good correlation of metamorphic mineral assemblageswith chlorite crystallinity and vitrinite reflectance values—allindicating temperatures in the range of 140 ± 20°Cat the top of the sequence to 250 ± 10°C at the baseof the sequence. The temperatures suggest a geothermal gradientof 36–64°C/km and a most likely gradient of 50°C/km.It is suggested that this higher-than-average gradient for afore-arc basin resulted either from rifting during basin formationor from a late-stage arc migration event. KEY WORDS: Antarctica; diagenesis; fore-arc basin; low-temperature metamorphism; vitrinite reflectance     

Mineralogical characteristics of upper Jurassic Mikulov Marls,the Czech Republic,in relation to their thermal maturity

The Upper Jurassic Marls of Mikulov present a formation that is considered to be the most promising strata to produce hydrocarbons in the Vienna basin. The marls are composed of dark pelagic marlstones that frequently contain layers of limestone with thickness reaching several hundreds of meters. Twenty-seven core samples from selected wells located in the south-eastern portion of the Czech Republic representing depths ranging from 2300 to 4500 m were analyzed by x-ray diffraction to assess bulk mineralogy and the progress of smectite illitization.Bulk mineralogy of the Mikulov Marls comprises carbonates (mean value = 54.4 mass%), clay minerals (26.6 mass%), quartz (15.0 mass%), and feldspar (1.6 mean%). In the decreasing order, the clay mineral fraction is composed of illite/mica, kaolinite, illite-smectite, and chlorite. The amount of smectite in illite-smectite decreases with depth from 70% to 28%. There is a change from random to ordered interstratification at the depth of 3300 m. The transition from short-range ordering (R1) to long-range ordering (R3) occurs at depths greater than 4,500 m.There was a good correspondence between thermal maturity parameters: the percentage of smectite in illite-smectite structures and vitrinite reflectance as a parameter of organic matter. The increase of the metamorphic grade was compared in respect to the geothermal gradient with adjacent basins.     

Near‐isochemical evolution of clay mineral assemblages in differentially buried volcaniclastic sediments,the Late Miocene Upper Red Formation,Iran

The Upper Red Formation (URF) comprises over 1–5 km of late Miocene siliciclastic sediments in the Central Iran Basin. The formation is dominated by volcaniclastic conglomerates and arenites. The prevailing arid conditions during most of the basin's history resulted in deposition of predominantly organic‐poor, red sediments with gypsum and zeolites. This investigation concentrates on the mineralogy and geochemistry of the URF in the southern and northern margins of the basin where the formation was buried to depths of 2.4 and 6.6 km, respectively. Fine fraction mineral separates from the southern margin consist of nearly pure smectite and zeolites at a depth of 400 m and smectite with minor quartz and calcite at 1800 m. Shallow samples (1350 m) from the northern section are rich in smectite, illite/smectite with some discrete illite and chlorite. This assemblage is progressively replaced by discrete illite and chlorite with increasing burial depth so that only these two minerals are found at depths greater than 4300 m. The initial alteration process involved replacement of glass and volcanic lithics by smectite and zeolites in both margins of the basin. Increased depth of burial in the northern margin resulted in the progressive isochemical alteration of smectite to discrete illite and chlorite. Diagenesis of clay assemblages occurred essentially in a closed system. Solute products of glass hydrolysis reactions were retained in highly alkaline, saline ground waters from which zeolites, carbonates and oxides precipitated as cements. It is unlikely that these sediments were ever significantly leached by meteoric waters or by organic acids generated during burial diagenesis. Copyright © 2010 John Wiley & Sons, Ltd.     

On the origin of mixed-layered clay minerals from the San Andreas Fault at 2.5–3 km vertical depth (SAFOD drillhole at Parkfield,California)

A detailed mineralogical study is presented of the matrix of mudrocks sampled from spot coring at three key locations along the San Andreas Fault Observatory at depth (SAFOD) drill hole. The characteristics of authigenic illite–smectite (I–S) and chlorite–smectite (C–S) mixed-layer mineral clays indicate a deep diagenetic origin. A randomly ordered I–S mineral with ca. 20–25% smectite layers is one of the dominant authigenic clay species across the San Andreas Fault zone (sampled at 3,066 and 3,436 m measured depths/MD), whereas an authigenic illite with ca. 2–5% smectite layers is the dominant phase beneath the fault (sampled at 3,992 m MD). The most smectite-rich mixed-layered assemblage with the highest water content occurs in the actively deforming creep zone at ca. 3,300–3,353 m (true vertical depth of ca. 2.7 km), with I–S (70:30) and C–S (50:50). The matrix of all mudrock samples show extensive quartz and feldspar (both plagioclase and K-feldspar) dissolution associated with the crystallization of pore-filling clay minerals. However, the effect of rock deformation in the matrix appears only minor, with weak flattening fabrics defined largely by kinked and fractured mica grains. Adopting available kinetic models for the crystallization of I–S in burial sedimentary environments and the current borehole depths and thermal structure, the conditions and timing of I–S growth can be evaluated. Assuming a typical K⁺ concentration of 100–200 ppm for sedimentary brines, a present-day geothermal gradient of 35°C/km and a borehole temperature of ca. 112°C for the sampled depths, most of the I–S minerals can be predicted to have formed over the last 4–11 Ma and are probably still in equilibrium with circulating fluids. The exception to this simple burial pattern is the occurrence of the mixed layered phases with higher smectite content than predicted by the burial model. These minerals, which characterize the actively creeping section of the fault and local thin film clay coating on polished brittle slip surfaces, can be explained by the influence of either cooler fluids circulating along this segment of the fault or the flow of K⁺-depleted brines.     

南海渐新世以来粘土矿物的演变特征及意义

通过对南海北部ODP184航次1148站32.8Ma以来深海沉积物中粘土矿物组成及其变化特征的分析,发现以15.5Ma为界,下部沉积物粘土矿物组成中蒙脱石含量高达70%,上部则以伊利石和绿泥石逐步增高、蒙脱石含量明显下降为特征,揭示出该区深海沉积物中粘土矿物演变可以分为32.8～15.5Ma的构造控制期和15.5Ma以来的气候控制期。在构造控制期,粘土矿物成分记录了南海扩张演变的历史;而在气候控制期,粘土矿物特征除反映出南海北部周边总体降温的过程外,还显示了3Ma的突然降温,与该站底栖有孔虫氧同位素资料反映的全球气候变化具有很好的对比性。     

Transient electromagnetic study of basin fill sediments in the Upper San Pedro Basin,Mexico

The Upper San Pedro River Basin in Mexico and the United States is an important riparian corridor that is coming under increasing pressure from growing populations and the associated increase in groundwater withdrawal. Several studies have produced three-dimensional maps of the basin fill sediments in the US portion of the basin but little work has been done in the Mexican portion of the basin. Here, the results of a ground-based transient electromagnetic (TEM) survey in the Upper San Pedro Basin, Mexico are presented. These basin fill sediments are characterized by a 10–40 m deep unsaturated surficial zone which is composed primarily of sands and gravels. In the central portion of the basin this unsaturated zone is usually underlain by a shallow clay layer 20–50 m thick. Beneath this may be more clay, as is usually the case near the San Pedro River, or interbedded sand, silt, and clay to a depth of 200–250 m. As you move away from the river, the upper clay layer disappears and the amount of sand in the sediments increases. At 1–2 km away from the river, sands can occupy up to 50% of the upper 200–250 m of the sediment fill. Below this, clays are always present except where bedrock highs are observed. This lower clay layer begins at a depth of about 200 m in the central portion of the basin (250 m or more at distances greater than 1–2 km from the river) and extends to the bottom of most profiles to depths of 400 m. While the depth of the top of this lower clay layer is probably accurate, its thickness observed in the models may be overestimated due to the relatively low magnetic moment of the TEM system used in this study. The inversion routine used for interpretation is based on a one-dimensional geologic model. This is a layer based model that is isotropic in both the x and y directions. Several survey soundings did not meet this requirement which invalidates the inversion process and the resulting interpretation at these locations. The results from these locations were rejected.     

Sedimentary variations of geomorphic subenvironments at Al-Lith area,central-west coast of Saudi Arabia,Red Sea

Sediment characteristics are the indicators of the intensity and geological history of the processes active in an area. Their association with different geomorphic features also signifies the present day conditions of deposition. In this study, variations in sediment characteristics associated with different geomorphic features, such as the coastal zone, two islands and a lagoon in the Al-Lith area of central-west coast of Saudi Arabia have been analysed. Whereas, the detrital sediments (sand?+?mud) are common (61–87 %) in most of the subunits of the coastal zone; the nondetrital (carbonate rich) sediments are more common (54–95 %) on the two islands as well as the lagoon; indicating distinct sources of sediments in these regions. The variation of sediment texture between sand and sandy silt in most geomorphic units, also shows that they are exposed to high-energy conditions, whereas occurrence of heavy minerals in small proportions (<7 %) indicates limited inputs from land-based igneous and metamorphic rocks. Sediment mean size vs. standard deviation shows that the sediment characteristics of a geomorphic unit (e.g. beach or sand bar) on the coast and on the island are different owing to different processes responsible for their formation.     

Petrography and provenance of the Early Permian Fluvial Warchha Sandstone,Salt Range,Pakistan

The Warchha Sandstone of the Salt Range of Pakistan is a continental succession that accumulated as part of a meandering, fluvial system during Early Permian times. Several fining-upward depositional cycles are developed, each of which is composed of conglomerate, cross-bedded sandstone and, in their upper parts, bioturbated siltstone and claystone units with distinctive desiccation cracks and carbonate concretions. Clast lithologies are mainly of plutonic and low-grade metamorphic origin, with an additional minor sedimentary component. Textural properties of the sandstone are fine- to coarse-grained, poorly to moderately sorted, sub-angular to sub-rounded, and with generally loose packing. Based on modal analyses, the sandstone is dominantly a feldspathoquartzose (arkose to sub-arkose). Detrital constituents are mainly composed of monocrystalline quartz, feldspars (more K-feldspar than plagioclase) and various types of lithic clasts. XRD and SEM studies indicate that kaolinite is the dominant clay mineral and that it occurs as both allogenic and authigenic forms. However, illite, illite-smectite mixed layer, smectite and chlorite are also recognised in both pores and fractures. Much of the kaolinite was likely derived by the severe chemical weathering of previously deposited basement rocks under the influence of a hot and humid climate. Transported residual clays deposited as part of the matrix of the Warchha Sandstone show coherent links with the sandstone petrofacies, thereby indicating the same likely origin. Illite, smectite and chlorite mainly occur as detrital minerals and as alteration products of weathered acidic igneous and metamorphic rocks. Based primarily on fabric relationship, the sequence of cement formation in the Warchha Sandstone is clay (generally kaolinite), iron oxide, calcareous and siliceous material, before iron-rich illite and occasional mixed layer smectite–illite and rare chlorite. Both petrographic analysis and field characteristics of the sandstone indicate that the source areas were characterised by uplift of a moderate to high relief continental block that was weathered under the influence of hot and humid climatic conditions. The rocks weathered from the source areas included primary granites and gneisses, together with metamorphic basement rocks and minor amounts of sedimentary rocks. Regional palaeogeographic reconstructions indicate that much of the Warchha Sandstone detritus was derived from the Aravalli and Malani ranges and surrounding areas of the Indian Craton to the south and southeast, before being transported to and deposited within the Salt Range region under the influence of a semi-arid to arid climatic regime.     

Geochemistry of Cu, Co, Ni, Zn, Cd and Cr in the surficial sediments of a tropical estuary, southwest coast of India: a granulometric approach

 Geochemical characteristics of six trace metals – Cu, Co, Ni, Zn, Cd and Cr – in the bulk sediment and sand, silt and clay fractions of a tropical estuary on the southwest coast of India have been studied and discussed. In bulk sediment, the trace metal concentration is controlled mainly by the textural composition of the sample. Mud, sandy mud and sandy silt register higher concentrations of trace metals than that in sand-dominant sediments. The granulometric partitioning studies also re-affirmed the role of particle size in enriching the trace metals. The silt and clay fractions exhibit 7–8 times the enrichment of Cu and Cd compared to that in sand. The enrichment factors of Zn, Cr, Ni and Co in the silt and clay fractions, compared to that in sand, are 5–6, 4–5, 2–5 and 2–3 times, respectively. The trace metals in the sand fraction, particularly Ni and Cr, exhibit strong positive correlation with the heavy mineral content of the samples. It clearly indicates a heavy mineral pathway to the trace metals in the sand fraction. Cu and Co in silt and clay fractions exhibit a marked decrease towards the high saline zones of the estuary. This is attributed to the desorption of Cu and Co from particulate phases during estuarine mixing. Contrary to Cu and Co, the content of Zn in the clay fraction shows a marginal increase towards the estuarine mouth. This could be explained by the influx of Zn-rich contaminant discharges from Zn-smelting industries located slightly north of the estuarine mouth. The released Zn will effectively be held in the lattices of the clay mineral montmorillonite, which also exhibits a marked increase towards the estuarine mouth. The anomalously high values of Cd in some places of the Central Vembanad estuary is attributed to the local pollution. Received: 10 July 1995 · Accepted: 3 June 1996     

成岩带、近变质带与一维纳米级层状硅酸盐

运用X射线衍射分析技术，计算了成岩带、近变质带粘土矿物C^*方向的粒度。根据阿尔卑斯造山带前陆碎屑岩粘土矿物粒度与伊利石结晶指数的关系，推导出了伊利石、绿泥石、蒙脱石、伊蒙混层、高岭石和叶蜡石的c^*方向粒度变化趋势曲线。结果表明，大多数产于成岩带和近变质带的粘矿物其c6*方向粒工为几至几十纳米。成岩带和近为质带是一维天然纳为级土帮物的产地。     

Clay petrology of the Upper Triassic/Lower Jurassic terrestrial strata of the Newark Supergroup,Connecticut Valley,U.S.A.

The clay mineralogy of the Newark Supergroup (Upper Triassic/Lower Jurassic) in the Connecticut Valley was studied by X-ray diffraction analysis. Clay minerals identified in 126 samples are illite, chlorite, smectite, kaolinite, vermiculite, expandable chlorite, mixed-layer illite/smectite, mixed-layer chlorite/smectite, and mixed-layer chlorite/vermiculite. In general, the rocks are illitic with subordinate amounts of chlorite. However, the various lithofacies in the Newark Supergroup are characterized by distinct clay-mineral assemblages. Red beds of floodplain origin contain clays mainly of detrital nature with 2M illite most abundant. Subordinate amounts of chlorite, smectite, vermiculite, kaolinite and mixed-layer illite/smectite are also present. An interstratified chlorite/vermiculite occurs in red mudstone underlying basalt flows. Lacustrine gray beds are generally characterized by the clay-mineral assemblage 1Md illite + chlorite with minor amounts of smectite ane expandable chlorite. An interstratified chlorite/smectite predominates in gray mudstone associated with perennial lake cycles in the East Berlin Formation. Black shales of deeper lacustrine origin contain the assemblage 1Md ifillite + trioctahedral smectite and traces of chlorite. Illite and smectite also occur as mixed-layer phases.In many respects, the distribution of clay minerals in the Connecticut Valley can be likened to the general scheme proposed for the Permo-Triassic basins of Europe and Africa. These display both vertical and horizontal variations in clay-mineral assemblages that reflect the chemical and spatiotemporal evolution of intrabasin depositional and diagenetic environments. Chemical data indicate that magnesium, especially, was concentrated in the black muds of large perennial lakes that intermittently occupied the Connecticut rift valley. Pore waters derived from these sediments played an important role in the development of Mg-rich 2 : 1 and interstratified clay minerals during early diagenesis.