气相色谱—质谱联用技术测定岩芯样品中的苯系化合物

利用气相色谱／普联用技术测定了同一井位、不同深度岩芯样品中的苯、甲苯、乙苯和二甲苯化合物。采用脂肪抽提器法和柱层析分析方法对岩芯样品进行进行预处理,得以岩芯施组分中的芳烃组合。以选择离子扫描模式,建立了标准样品的定量分析方法。方法对苯系化合物各待测组分的最小检出限均为０．５ｍｇ／Ｌ,加标回收率在９３．６％～１０９．５％。给出了岩芯样品的分离色谱图和实测结果,苯和甲苯含量在１．４～１１１．７ｎｇ／ｇ     

Application of pyrolysis–GC/MS for the characterisation of suspended particulate organic matter in the Mediterranean Sea: a comparison with the Black Sea

Suspended particulate organic matter (SPOM) both from the oligotrophic Mediterranean and from the more productive Black Sea has been analysed by pyrolysis–gas chromatography/mass spectrometry (Py–GC/MS) and by such conventional techniques as elemental analysis and fluorometry. The data achieved by the two approaches generally confirmed and complemented each other. The relative concentrations of pyrolysis products (termed markers) characteristic of chlorophyll (CHL), lipid, carbohydrate (CBH), and protein (PROT) components of SPOM have been determined. The vertical distribution of lipid markers was more uniform in the Mediterranean surface waters. Their relative abundance increased rapidly in the oxycline of the Black Sea, reaching their highest levels in the suboxic zone, where the protein composition of the SPOM changed significantly. In both seas, the relative concentrations of CHL markers increased consistently within the CHL maximum zone where the CBH markers were less abundant. No lignin markers from terrestrial vegetation were detected at significant levels in the pyrograms.     

Microstructural and metamorphic evolution of a high‐pressure granitic orthogneiss during continental subduction (Orlica–Śnieżnik dome,Bohemian Massif)

A microstructural and metamorphic study of a naturally deformed medium‐ to high‐pressure granitic orthogneiss (Orlica–?nie?nik dome, Bohemian Massif) provides evidence of behaviour of the felsic crust during progressive burial along a subduction‐type apparent thermal gradient (～10 °C km^?1). The granitic orthogneisses develops three distinct microstructural types, as follows: type I – augen orthogneiss, type II – banded orthogneiss and type III – mylonitic orthogneiss, each representing an evolutionary stage of a progressively deformed granite. Type I orthogneiss is composed of partially recrystallized K‐feldspar porphyroclasts surrounded by wide fronts of myrmekite, fully recrystallized quartz aggregates and interconnected monomineralic layers of recrystallized plagioclase. Compositional layering in the type II orthogneiss is defined by plagioclase‐ and K‐feldspar‐rich layers, both of which show an increasing proportion of interstitial minerals, as well as the deformation of recrystallized myrmekite fronts. Type III orthogneiss shows relicts of quartz and K‐feldspar ribbons preserved in a fine‐grained polymineralic matrix. All three types have the same assemblage (quartz + plagioclase + K‐feldspar + muscovite + biotite + garnet + sphene ± ilmenite), but show systematic variations in the composition of muscovite and garnet from types I to III. This is consistent with the equilibration of the three types at different positions along a prograde P?T path ranging from <15 kbar and <700 °C (type I orthogneiss) to 19–20 kbar and >700 °C (types II and III orthogneisses). The deformation types thus do not represent evolutionary stages of a highly partitioned deformation at constant P?T conditions, but reflect progressive formation during the burial of the continental crust. The microstructures of the type I and type II orthogneisses result from the dislocation creep of quartz and K‐feldspar whereas a grain boundary sliding‐dominated diffusion creep regime is the characteristic of the type III orthogneiss. Strain weakening related to the transition from type I to type II microstructures was enhanced by the recrystallization of wide myrmekite fronts, and plagioclase and quartz, and further weakening and strain localization in type III orthogneiss occurred via grain boundary sliding‐enhanced diffusion creep. The potential role of incipient melting in strain localization is discussed.     

Méthodologie de l'extraction des hydrocarbures aromatiques polycycliques. Application à des sédiments de la lagune de Bizerte (Tunisie)Methodology of extraction of polycyclic aromatic hydrocarbons. Application to sediment from the Bizerte Lagoon (Tunisia)

The marine environment is very complex, with several important chemical, biological, and sedimentological interactions. Sediments constitute a reservoir for numerous pollutants, including polycyclic aromatic hydrocarbons (PAHs). PAHs are known by their mutagenic and/or carcinogenic effect. This study evaluates contamination levels in Bizerte Lagoon with respect to PAHs. The extraction efficiency of PAHs from sediment has been evaluated using Soxhlet or ultrasonic procedures, based on the recovery of an internal standard (9,10-dihydroanthracene). Several PAHs were found, including sixteen that are reported in the priority list of pollutants of the US Environmental Protection Agency (EPA). PAHs analysis was carried out by GC–FID and GC–MS for 16 samples sampled in two seasons: summer and winter. Results permit an assessment of PAHs pollution in the Bizerte Lagoon. To cite this article: N. Mzoughi et al., C. R. Geoscience 334 (2002) 893–901.     

The structural evolution of the southern Apuan Alps: new constraints on the tectonic evolution of the Northern Apennines (Italy)Évolution structurale des Apuanes méridionales : nouvelles contraintes sur l'évolution tectonique des Apennins septentrionaux (Italie)

Structural analysis performed in the southern sector of the Apuan Alps Metamorphic Complex (AAMC) and on the overlaying Tuscan Nappe (TN) pointed out a structural evolution much more complex than that outlined till now. The comparison between the structural evolutions of the two tectonic units could provide new important constraints on the tectonic evolution of the whole belt. The two tectonic units recorded different tectonic evolution during the first stages of compression, while they shared the same deformation history later after the Tuscan Nappe overlapped the AAMC. The coupled tectonic units have been then deformed by two systems of folds, in a compressive tectonic regime. Extensional tectonics affected the units later, at upper crustal levels. To cite this article: R. Carosi et al., C. R. Geoscience 334 (2002) 339–346.