Desorption processes and the deuterium fractionation in molecular clouds

Several processes have been suggested as ways of returning accreted grain mantles to the gas, thus preventing the total removal of molecules from the gas phase in dark quiescent clouds. We attempt to distinguish between them by considering not only the calculated gas-phase abundances, but also the ratio of the abundances of deuterated species to non-deuterated species. We find that the D/H ratio in molecules is relatively model-independent, but that desorption due to the formation of H₂ on grains gives the best overall agreement with the observations.     

The possibility of nitrogen isotopic fractionation in interstellar clouds

The possibility of nitrogen isotopic fractionation owing to ion–molecule exchange reactions involving the most abundant N-containing species in dense interstellar clouds has been explored. We find that exchange reactions between N atoms and N-containing ions have most influence on the fractionation, although the extent of fractionation is too small to be readily detectable.     

Dense and diffuse gas in dynamically active clouds

We investigate the chemical and observational implications of repetitive transient dense core formation in molecular clouds. We allow a transient density fluctuation to form and disperse over a period of 1 Myr, tracing its chemical evolution. We then allow the same gas immediately to undergo further such formation and dispersion cycles. The chemistry of the dense gas in subsequent cycles is similar to that of the first, and a limit cycle is reached quickly (2–3 cycles). Enhancement of hydrocarbon abundances during a specific period of evolution is the strongest indicator of previous dynamical history. The molecular content of the diffuse background gas in the molecular cloud is expected to be strongly enhanced by the core formation and dispersion process. Such enhancement may remain for as long as 0.5 Myr. The frequency of repetitive core formation should strongly determine the level of background molecular enhancement.
We also convolve the emission from a synthesized dark cloud, comprised of ensembles of transient dense cores. We find that the dynamical history of the gas, and therefore the chemical state of the diffuse intercore medium, may be determined if a sufficient sample of cores is present in an ensemble. Molecular ratios of key hydrocarbons with SO and SO₂ are crucial to this distinction. Only surveys with great enough angular resolution to resolve individual cores, or very small groupings, are expected to show evidence of repetitive dynamical processing. The existence of non-equilibrium chemistry in the diffuse background may have implications for the initial conditions used in chemical models. Observed variations in the chemistries of diffuse and translucent regions may be explained by lines of sight which intersect a number of molecular cloud cores in various stages of evolution.     

Very high resolution profiles of four diffuse interstellar bands

Ultra-high-resolution  ( R ∼ 300 000)  profiles of four diffuse interstellar bands (DIBs) are presented. The λλ 5797-, 5850-, 6196- and 6379- Å DIBs were observed towards the reddened supergiant HD 24398, a line of sight free of Doppler splitting; thus the observed profiles can be considered as intrinsic to the DIB carriers. Three of the profiles show substructure which supports the hypothesis of a molecular origin for these DIBs.     

On the CH B‐X (1, 0) band in translucent clouds

We present observations of CH B‐X (1, 0) band toward 13 translucent sightlines. The given precise positions (at 3627.403, 3633.289, 3636.222 Å) are derived by means of shifting our spectra to the rest velocity frame using B‐X (0, 0) features (at 3878, 3886 and 3890 Å). The proposed oscillator strengths (equal to 0.00035, 0.00104, 0.00069, respectively) are based on f ‐values of the CH B‐X (0, 0) system, i.e. 0.00110, 0.00320, 0.00210 (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

The formation of molecular clouds

In a recent paper, Elmegreen has made a cogent case, from an observational point of view, that the lifetimes of molecular clouds are comparable to their dynamical time-scales. If so, this has important implications for the mechanisms by which molecular clouds form. In particular, we consider the hypothesis that molecular clouds may form not by in situ cooling of atomic gas, but rather by the agglomeration of the dense phase of the interstellar medium, much, if not most, of which is already in molecular form.     

Calculations on the rates, mechanisms, and interstellar importance of the reactions between C and NH2 and between N and CH2

The attempt to understand the temperature dependence of the HNC/HCN abundance ratio in interstellar clouds has been long standing and indecisive. In this paper we report quantum chemical and dynamical studies of two neutral–neutral reactions thought to be important in the formation of HNC and HCN, respectively – C+NH₂→HNC+H, and N+CH₂→HCN+H. We find that although these reactions do lead initially to the products suggested by astronomers, there is so much excess energy available in both reactions that the HCN and HNC products are able to undergo efficient isomerization reactions after production. The isomerization leads to near equal production rates of the two isomers, with HNC slightly favoured if there is sufficient rotational excitation. This result has been incorporated into our latest chemical model network of dense interstellar clouds.     

On the detection of the linear C5 molecule in the interstellar medium

An upper limit of the column density of the C₅ linear molecule in translucent interstellar clouds is estimated from high-resolution ( R =80 000) and very high signal-to-noise ratio (∼1000) echelle spectra. It is 10¹² cm⁻² per E ( B − V )=1 (two orders of magnitude lower than that of C₂).     

A search for absorption of Mg and Ca compounds in molecular clouds towards Galactic continuum sources

Absorption lines of MgH and CaH N  = 1 − 0 transitions were searched for in foreground molecular clouds towards the continuum sources associated with Sgr B2 (M) and W49A (N). None of these lines was detected with our sensitivity level of ∼20 mK. Millimetric absorption lines of MgO, MgOH, CaO and CaOH were also searched for towards Sgr B2 (M) without success. The fractional abundances relative to molecular hydrogen are ≲ 1.0 × 10⁻¹¹ for MgH, ≲ 7.9 × 10⁻¹³ for MgO, ≲ 1.6 × 10⁻¹⁰ for MgOH, ≲ 1.6 × 10⁻⁹ for CaH, ≲ 2.0 × 10⁻¹² for CaO, and ≲ 2.5 × 10⁻¹⁰ for CaOH, respectively. The low abundances measured in absorption indicate that a significant fraction of interstellar magnesium and calcium cannot be tied up in their monohydrides, monoxides and monohydroxides. The low abundance of MgH also implies that grain-surface chemistry involving magnesium is not efficient and that magnesium is depleted on to grains to a factor of ≳ 10^2.5 in well-shielded molecular clouds.     

Injection of molecules from the surfaces of grains into the gas phase chemistry of an expanding cloud

We present model results for the chemistry in an expanding cloud or clump in which molecules are injected into the gas phase from grain surfaces when the clump reaches a certain visual extinction A _v during the expansion. We consider separately injection at two different values of A _v, and include a representative large hydrocarbon, C₆H, and sulphur-bearing molecule, H₂SO₄, as well as H₂O and CO. We examine the abundances of certain molecules which have been observed in diffuse and translucent clouds, and compare the results obtained for these abundances with and without an injection during expansion. We also compare our results withpublished observations, and conclude that in most clouds an injection of molecules has occurred.     

The formation of heavy hydrocarbons in molecular clouds

Laboratory data on the conversion of solid methane into large hydrocarbons by particle radiation are used to estimate the fraction of interstellar carbon converted by this process into refractory form. We find that the maximum fraction of carbon that can be converted into refractory form during the life of a dense core within an interstellar cloud is in the range of 1–5 per cent. The implication of this result is that the conversion of enough carbon into refractory form to contribute significantly to interstellar extinction requires the frequent passage of material into and out of dense cores. If so, then interstellar clouds must exist for at least 10 Myr. However, these conclusions should be regarded as preliminary until confirmed by further laboratory studies of the particle irradiation of complex ice mixtures.     

Interstellar CO towards X Persei (HD 24534) – II. Two-component model

The observations made by the Goddard High Resolution Spectrograph (GHRS) aboard the Hubble Space Telescope ( HST ) of molecular CO in absorbing gas towards X Persei are reported. The two-component statistical equilibrium model incorporating radiative excitation of CO by line emission at the same velocity that originates in nearby molecular clouds has been used to reproduce high-resolution GHRS spectra. Earlier analysis indicates that the cloud has a complex structure and at least a two-component model should be used to obtain accurate results. The spectra obtained from the International Ultraviolet Explorer ( IUE ) were used to complement GHRS data and constrain the space of possible solutions. The new oscillator strengths recommended by Eidelsberg et al. for A–X bands have been used. The results show that one of the components may be attributed to the Perseus OB2 molecular cloud, and the other component to an extension of the Taurus dark cloud. The total CO column density N (CO)=(1.0±0.2)×10¹⁶ cm⁻² has been determined. According to the results about 85 per cent of the observed CO belongs to an extension of the Taurus dark cloud. The CO radiation that originates in nearby molecular clouds may be the dominant excitation mechanism of the observed CO. The early results of ¹³CO line analysis indicate a ¹³CO/¹²CO ratio of about 40.     

Hydrated sulphuric acid in dense molecular clouds

We consider sulphur depletion in dense molecular clouds, and suggest hydrated sulphuric acid, H₂SO₄ ·  n H₂O, as a component of interstellar dust in icy mantles. We discuss the formation of hydrated sulphuric acid in collapsing clouds and its instability in heated regions in terms of the existing hot core models and observations. We also show that some features of the infrared spectrum of hydrated sulphuric acid have correspondence in the observed spectra of young stellar objects.