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1.
Observations are presented on dilution and dispersion rates of ballast water discharged under normal operational conditions at the semi-enclosed port of Goderich, Ontario. The ballast water was tagged with Rhodamine-WT dye and microscopic magnetically-attractive tracer particles. Maximum concentrations of dye immediately after discharge were diluted to 1-5% of initial ballast tank concentrations, and within 3 days had decreased to less than 0.1% of initial concentrations. Inside the harbor, there was 10-20% of the ballast water still present after 2 days, consistent with a flushing rate of 0.8-1.15 day−1. Magnetic particles were collected up to 7.5 km outside the harbor after one day, consistent with a dilution factor of order 105 outside the harbor. The results of this study are discussed in the context of ballast water discharge standards proposed by the International Maritime Organization to minimize the introduction of aquatic nonindigenous species through ships’ ballast water and sediments.  相似文献   

2.
《Marine pollution bulletin》1987,18(10):549-558
Produced water from North Sea oil reservoirs contains substantial amounts (about 1g I−1) of non-hydrocarbon organic matter, largely as salts of acetic, propionic and butyric acids, as well as some 20–40 mg I−1 of dissolved hydrocarbons such as benzene, toluene and xylene. The non-hydrocarbon components originate in water in the oil-bearing formation. All of the organic matter can be accounted for, within analytical accuracy. The water also contains some 20–30 mg I−1 of ammoniacal nitrogen and a number of inorganic components.At peak water production from production installations in the North Sea some 1−2 × 105 tonnes yr−1 of organic acids will be discharged in the U.K. sector of the North Sea.The ready biodegradability of the organic constituents and the low toxicity of produced water have been confirmed by direct measurement; acute toxicity is unlikely at dilutions of greater than 100 fold.Dispersion has been modelled and tested in the laboratory indicating some 1000 fold dilution within less than 50 m of the discharge.The laboratory studies are supported by field observations. Any direct deleterious effects are limited to the immediate vicinity of the discharge (within a few tens of metres).  相似文献   

3.
Artificial recharge through a thick, heterogeneous unsaturated zone   总被引:2,自引:0,他引:2  
Thick, heterogeneous unsaturated zones away from large streams in desert areas have not previously been considered suitable for artificial recharge from ponds. To test the potential for recharge in these settings, 1.3 x 10(6) m(3) of water was infiltrated through a 0.36-ha pond along Oro Grande Wash near Victorville, California, between October 2002 and January 2006. The pond overlies a regional pumping depression 117 m below land surface and is located where thickness and permeability of unsaturated deposits allowed infiltration and saturated alluvial deposits were sufficiently permeable to allow recovery of water. Because large changes in water levels caused by nearby pumping would obscure arrival of water at the water table, downward movement of water was measured using sensors in the unsaturated zone. The downward rate of water movement was initially as high as 6 m/d and decreased with depth to 0.07 m/d; the initial time to reach the water table was 3 years. After the unsaturated zone was wetted, water reached the water table in 1 year. Soluble salts and nitrate moved readily with the infiltrated water, whereas arsenic and chromium were less mobile. Numerical simulations done using the computer program TOUGH2 duplicated the downward rate of water movement, accumulation of water on perched zones, and its arrival at the water table. Assuming 10 x 10(6) m(3) of recharge annually for 20 years, a regional ground water flow model predicted water level rises of 30 m beneath the ponds, and rises exceeding 3 m in most wells serving the nearby urban area.  相似文献   

4.
Microbial respiration rates were determined through a 3.2 m thick, sandy unsaturated zone in a 2.4 m diameter x 4.6 m high mesocosm. The mesocosm was maintained under near constant temperature (18 degrees to 23 degrees C) and reached steady moisture content conditions after several hundred days. Soil-gas CO2 concentrations in the mesocosm ranged from 0.09% to 3.31% and increased with depth. Respiration rates within the mesocosm were quantified over a 342-day period using measured CO2 concentrations and a transient, one-dimensional finite-element model. Microbial respiration rates were 2 x 10(-1) micrograms C.g-1.d-1 throughout most of the system, but decreased to 10(-4) to 10(-3) micrograms C.g-1.d-1 within the capillary fringe. Microbial respiration rates were also determined in minicosms (500 g sample mass) over a range in temperatures (4 degrees to 30 degrees C) and volumetric moisture contents (0.044 to 0.37). The functional dependence of CO2 production on temperature and soil-moisture content was similar for the two scales of laboratory observation. Respiration rates in the minicosms, for temperatures and moisture contents in the mesocosm, were up to an order of magnitude greater than those determined for the mesocosm. The higher respiration rates in the minicosms, compared to the mesocosm, were attributed to greater disturbance of the samples and to shorter acclimation time in the minicosms. Extrapolating the laboratory respiration rates to field conditions yielded rates that were two to three orders of magnitude greater than rates previously determined in situ for C-horizon material. Results show that in situ microbial reaction rates determined using disturbed samples in minicosms and mesocosms yielded respiration rates that greatly exceeded field conditions. Mesocosms can, however, provide a useful environment for conducting process-related research in unsaturated environments.  相似文献   

5.
From the mid-1940s through the 1980s, large volumes of waste water were discharged at the Hanford Site in southeastern Washington State, causing a large-scale rise (>20 m) in the water table. When waste water discharges ceased in 1988, ground water mounds began to dissipate. This caused a large number of wells to go dry and has made it difficult to monitor contaminant plume migration. To identify monitoring wells that will need replacement, a methodology has been developed using a first-order uncertainty analysis with UCODE, a nonlinear parameter estimation code. Using a three-dimensional, finite-element ground water flow code, key parameters were identified by calibrating to historical hydraulic head data. Results from the calibration period were then used to check model predictions by comparing monitoring wells' wet/dry status with field data. This status was analyzed using a methodology that incorporated the 0.3 cumulative probability derived from the confidence and prediction intervals. For comparison, a nonphysically based trend model was also used as a predictor of wells' wet/dry status. Although the numerical model outperformed the trend model, for both models, the central value of the intervals was a better predictor of a wet well status. The prediction interval, however, was more successful at identifying dry wells. Predictions made through the year 2048 indicated that 46% of the wells in the monitoring well network are likely to go dry in areas near the river and where the ground water mound is dissipating.  相似文献   

6.
We studied the distribution of tephra deposits discharged by the basaltic (52–54% SiO2) explosive eruption of 1973 on Tyatya Volcano (Kunashir I., Kuril Islands). We made maps showing lines of equal tephra thickness (isopachs) and lines of maximum size of pyroclastic particles (isopleths). These data were used to find the parameters of explosive activity using the standard techniques for each of the two phases of this eruption separately. The first, phreatomagmatic, phase discharged 0.008 km3 of tephra during the generation of maars on the volcano’s northern slope. The tephra mostly consisted of fragmented host rocks with admixtures of fragments of low vesiculated juvenile basalt. The phase lasted 20 hours, the rate of pyroclastic discharge was 2 × 105 kg/s; the eruptive plume reached heights of 4–6 km with wind speeds within 10 m/s. The second, magmatic, phase discharged 0.07 km3 of tephra during the generation of the Otvazhnyi scoria cone on the volcano’s southeastern slope. The tephra mostly consisted of juvenile basaltic scoria. The highly explosive Plinian part of this phase lasted 36 hours, the rate of pyroclastic discharge was 8 × 105 kg/s; the eruptive plume reached heights of 6–8 km with wind speeds of 10–20 m/s. The total tephra volume discharged by the eruption was approximately 0.08 km3; the total amount of ejected pyroclastic material (including the resulting monogenic edifices) was 0.11 km3; the volume of erupted magma was 0.05 km3 (the conversion was based on 2800 kg/m3 density); the volcanic explosivity index, or VEI, was 3. The production rate of the Tyatya plumbing system is estimated as 3 × 105 m3 magma per annum.  相似文献   

7.
Pesticides are used extensively in the finfish aquaculture industry to control sea lice infestations on farmed salmon. The most prevalent method of use is to enclose a net pen with an impervious tarpaulin and mix a pesticide solution within that enclosure. After treatment for short periods (1 h) the pesticide solution is released to the environment. Concerns have been raised that there is a potential risk to non-target aquatic organisms from those releases. The fate of dispersing pesticide solutions was measured after six simulated treatments in the Lower Bay of Fundy, New Brunswick. Three simulated treatments were done with azamethiphos and three with cypermethrin. Rhodamine dye was added to all pesticide solutions in order to facilitate tracking of the dispersing plume through real-time measurements of dye concentrations by a flow-through fluorometer coupled with a differential global positioning system (DGPS). Water samples were obtained from within the plumes at various times after release and analysed for pesticide content and toxicity to a benthic amphipod Eohaustorius estuaris. Dye concentrations were detectable for time periods after release which varied from 2 to 5.5 h. Distances travelled by the dye patches ranged from 900 to 3000 m and the dye concentrations at the final sampling period were generally 1/200-1/3000 the pre-release concentrations and cypermethrin concentrations were generally 1/1000-1/2000 the pre-release concentrations. Cypermethrin concentrations in water samples were closely correlated with dye concentrations, indicating that dye analyses were an accurate surrogate for cypermethrin concentrations. Most samples taken after the releases of azamethiphos were not toxic to test organisms in 48 h exposures and none were beyond 20 min post-release. By contrast, almost all samples taken after the release of cypermethrin, even up to 5-h post-release, were toxic. Data indicate the potential to cause toxic effects over areas of hectares from a single release of cypermethrin.  相似文献   

8.
As the number of manmade structures installed on the seafloor is increasing rapidly, we seek to understand the impact of these immobile obstacles on marine geomorphological processes, such as the evolution of bedforms. A 5.8 m diameter monopile foundation was installed at the case study offshore windfarm approximately 30 m ahead of an approaching barchan (crescent-shaped) dune. The impact of the monopile on the dune's evolution was analysed using six multibeam bathymetry surveys spanning 20 years. To substantiate this analysis, coupled three-dimensional numerical modelling of flows and sediment was conducted in which the scour inducing bed shear stresses were calculated from the modelled turbulent kinetic energy. Following the installation of the monopile, the mid-section of the dune accelerated and stretched in the direction of the wake of the monopile. Four years after the monopile's installation the rest of the dune had caught up, flattening out the slip face within half the dune's length downstream of the monopile. Due to the modified flow field, the dune was scoured deeply at the base of the monopile to a depth of 6.8 m (supported by the model results that predicted a scour depth exceeding 2 m over a period of just a few days). The surveyed volume of material scoured amounted to 8% of the total dune volume. Whilst the process of scouring occurs at a timescale of days to weeks, the dune migrated on average by 25 m/yr. The difference in the timescale of the two processes allowed the scouring to occur through the full thickness of the dune. The scoured dune profile recovered rapidly once the dune migrated downstream of the monopile. This article demonstrates how large geomorphological features can intercept and migrate past a monopile foundation without long-lasting impacts on the integrity of the feature or the foundation. © 2020 John Wiley & Sons, Ltd.  相似文献   

9.
A field study was conducted to assess purging requirements for dedicated sampling systems in conventional monitoring wells and for pumps encased in short screens and buried within a shallow sandy aquifer. Low-flow purging methods were used, and wells were purged until water quality indicator parameters (dissolved oxygen, specific conductance, turbidity) and contaminant concentrations (chromate, trichloroethylene, dichloroethylene) reached equilibrium. Eight wells, varying in depth from 4.6 to 15.2 m below ground surface, were studied. The data show that purge volumes were independent of well depth or casing volumes. Contaminant concentrations equilibrated with less than 7.5 I. of purge volume in all wells. Initial contaminant concentration values were generally within 20 percent of final values. Water quality parameters equilibrated in less than 10 L in all wells and were conservative measures for indicating the presence of adjacent formation water. Water quality parameters equilibrated faster in dedicated sampling systems than in portable systems and initial turbidity levels were lower.  相似文献   

10.
A simplified approach has been applied to analyse the mixing and entrainment processes of the engine exhaust through their interaction with the vortex wake of an aircraft. Our investigation is focused on the near field, extending from the exit nozzle until about 30 s after the wake is generated, in the vortex phase. This study was performed by using an integral model and a numerical simulation for two large civil aircraft: a two-engine Airbus 330 and a four-engine Boeing 747. The influence of the wing-tip vortices on the dilution ratio (defined as a tracer concentration) shown. The mixing process is also affected by the buoyancy effect, but only after the jet regime, when the trapping in the vortex core has occurred. In the early wake, the engine jet location (i.e. inboard or outboard engine jet) has an important influence on the mixing rate. The plume streamlines inside the vortices are subject to distortion and stretching, and the role of the descent of the vortices on the maximum tracer concentration is discussed. Qualitative comparison with contrail photograph shows similar features. Finally, tracer concentration of inboard engine centreline of B-747 are compared with other theoretical analyses and measured data.  相似文献   

11.
Fluvial bedforms generate a turbulent wake that can impact suspended-sediment settling in the passing flow. This impact has implications for local suspended-sediment transport, bedform stability, and channel evolution; however, it is typically not well-considered in geomorphologic models. Our study uses a three-dimensional OpenFOAM hydrodynamic and particle-tracking model to investigate how turbulence generated from bedforms and the channel bed influences medium sand-sized particle settling, in terms of the distribution of suspended particles within the flow field and particle-settling velocities. The model resolved the effect of an engineered bedform, which altered the flow field in a manner similar to a natural dune. The modelling scenarios alternated bed morphology and the simulation of turbulence, using detached eddy simulation (DES), to differentiate the influence of bedform-generated turbulence relative to that of turbulence generated from the channel bed. The bedform generated a turbulent wake that was composed of eddies with significant anisotropic properties. The eddies and, to a lesser degree, turbulence arising from velocity shear at the bed substantially reduced settling velocities relative to the settling velocities predicted in the absence of turbulence. The eddies tended to advect sediment particles in their primary direction, diffuse particles throughout the flow column, and reduced settling likely due to production of a positively skewed vertical-velocity fluctuation distribution. Study results suggest that the bedform wake has a significant impact on particle-settling behaviour (up to a 50% reduction in settling velocity) at a scale capable of modulating local suspended transport rates and bedform dynamics. © 2020 John Wiley & Sons, Ltd.  相似文献   

12.
The Powder River Basin (PRB) of Wyoming and Montana contains significant coal and coal bed natural gas (CBNG) resources. CBNG extraction requires the production of large volumes of water, much of which is discharged into existing drainages. Compared to surface waters, the CBNG produced water is high in sodium relative to calcium and magnesium, elevating the sodium adsorption ratio (SAR). To mitigate the possible impact this produced water may have on the quality of surface water used for irrigation, the State of Montana passed water anti‐degradation legislation, which could affect CBNG production in Wyoming. In this study, we sought to determine the proportion of CBNG produced water discharged to tributaries that reaches the Powder River by implementing a four end‐member mixing model within a Bayesian statistical framework. The model accounts for the 87Sr/86Sr, δ13CDIC, [Sr] and [DIC] of CBNG produced water and surface water interacting with the three primary lithologies exposed in the PRB. The model estimates the relative contribution of the end members to the river water, while incorporating uncertainty associated with measurement and process error. Model results confirm that both of the tributaries associated with high CBNG activity are mostly composed of CBNG produced water (70–100%). The model indicates that up to 50% of the Powder River is composed of CBNG produced water downstream from the CBNG tributaries, decreasing with distance by dilution from non‐CBNG impacted tributaries from the point sources to ~10–20% at the Montana border. This amount of CBNG produced water does not significantly affect the SAR or electrical conductivity of the Powder River in Montana. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

13.
The stability of subsurface Light Nonaqueous Phase Liquids (LNAPLs) is a key factor driving expectations for remedial measures at LNAPL sites. The conventional approach to resolving LNAPL stability has been to apply Darcy's Equation. This paper explores an alternative approach wherein single‐well tracer dilution tests with intermittent mixing are used to resolve LNAPL stability. As a first step, an implicit solution for single‐well intermittent mixing tracer dilution tests is derived. This includes key assumptions and limits on the allowable time between intermittent mixing events. Second, single‐well tracer dilution tests with intermittent mixing are conducted under conditions of known LNAPL flux. This includes a laboratory sand tank study and two field tests at active LNAPL recovery wells. Results from the sand tank studies indicate that LNAPL fluxes in wells can be transformed into formation fluxes using corrections for (1) LNAPL thicknesses in the well and formation and (2) convergence of flow to the well. Using the apparent convergence factor from the sand tank experiment, the average error between the known and measured LNAPL fluxes is 4%. Results from the field studies show nearly identical known and measured LNAPL fluxes at one well. At the second well the measured fluxes appear to exceed the known value by a factor of two. Agreement between the known and measured LNAPL fluxes, within a factor of two, indicates that single‐well tracer dilution tests with intermittent mixing can be a viable means of resolving LNAPL stability.  相似文献   

14.
Evaluating contaminants impacting wells in fractured crystalline rock requires knowledge of the individual fractures contributing water. This typically involves using a sequence of tools including downhole geophysics, flow meters, and straddle packers. In conjunction with each other these methods are expensive, time consuming, and can be logistically difficult to implement. This study demonstrates an unsteady state tracer method as a cost‐effective alternative for gathering fracture information in wells. The method entails introducing tracer dye throughout the well, inducing fracture flow into the well by conducting a slug test and then profiling the tracer concentration in the well to locate water contributing fractures where the dye has been diluted. By monitoring the development of the dilution zones within the wellbore with time, the transmissivity and the hydraulic head of the water contributing fractures can be determined. Ambient flow conditions and the contaminant concentration within the fractures can also be determined from the tracer dilution. This method was tested on a large physical model well and a bedrock well. The model well was used to test the theory underlying the method and to refine method logistics. The approach located the fracture and generated transmissivity values that were in excellent agreement with those calculated by slug testing. For the bedrock well tested, two major active fractures were located. Fracture location and ambient well conditions matched results from conventional methods. Estimates of transmissivity values by the tracer method were within an order of magnitude of those calculated using heat‐pulse flow meter data.  相似文献   

15.
1 INTRODUCTION Shanghai, Chinas largest metropolitan area with a population of about 14 million, is situated at the mouth of the Yangtze River, and bordered with the East China Sea to the east, Hangzhou Bay to the south, and the provinces of Zhejiang and Jiangsu to the west. It is a region with intensive distribution of rivers and lakes. The good geographic location and natural conditions have provided the city with superiority in its social and economic center and port city of the co…  相似文献   

16.
Output from a three‐dimensional numerical flow model (SSIIM) is used in conjunction with high‐resolution topographic and velocity data to assess such models for eco‐hydraulic applications in river channel design and habitat appraisal. A new methodology for the comparison between field measurement and model output is detailed. This involves a comparison between conventional goodness‐of‐fit approaches applied to a spatially structured (riffle and pool) sample of model and field data, and a ‘relaxation’ method based upon the spatial semivariance of model/field departures. Conventional assessment indicates that the model predicts point‐by‐point velocity characteristics on a 0·45 m mesh to within ±0·1 m s−1 over 80% of the channel area at low flow, and 50% of the area at high in‐bank flow. When a relative criterion of model fit is used, however, the model appears to perform less well: 60–70% of channel area has predicted velocities that depart from observed velocities by more than 10%. Regression analysis of observed and predicted velocities gives more cause for optimism, but all of these conventional indicators of goodness of fit neglect important spatial characteristics of model performance. Spatial semivariance is a means of supplementing model appraisal in this respect. In particular, using the relaxation approach, results are greatly improved: at a high in‐bank flow, the model results match field measurements to within 0·1 m s−1 for more than 95% of the total channel area, provided that model and field comparisons are allowed within a radius of approximately 1 m from the original point of measurement. It is suggested that this revised form of model assessment is of particular relevance to eco‐hydraulic applications, where some degree of spatial and temporal dynamism (or uncertainty) is a characteristic. The approach may also be generalized to other environmental science modelling applications where the spatial attributes of model fits are of interest. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

17.
Treatment of aromatic ring compounds, 2,4-dichlorophenoxy acetic acid (2,4-D), 2,4,5-trichloro-phenoxy acetic acid (2,4,5-T), and bisphenol A, in the artificial seawater, i.e. Allen seawater, was carried out by ozonation and titanium dioxide (TiO2) photocatalyst treatment. Each compound was degraded and varnished within 30 min by only ozonolysis at pH 9.0 and at 20 degrees C, while the TOC value of each compound decreased gradually but reached almost constant value, i.e. about 70-80% of the initial value, at even 30 min of ozonation time. Ozonolysis (30 min of ozonation time) followed by TiO2 photocatalyst treatment (50h of reaction time) was a very effective method for decreasing the TOC values of aromatic ring compounds in the artificial seawater. In consequence, TOC values of 2,4-D, 2,4,5-T, and bisphenol A could be reduced to about 28, 21, and 34% of their initial values, respectively.  相似文献   

18.
This study investigates the potential use of activated carbon prepared from the peel of Cucumis sativa fruit for the removal of malachite green (MG) dye from simulated wastewater. The effects of different system variables, adsorbent dosage, initial dye concentration, pH, and contact time were investigated and optimal experimental conditions were ascertained. The results showed that when the amount of the adsorbent increased, the percentage of dye removal increased accordingly. Optimum pH value for dye adsorption was 6.0. Maximum dye was sequestered within 50 min of the start of every experiment. The adsorption of MG followed the pseudo‐second‐order rate equation and fits the Langmuir, Freundlich, Dubinin–Radushkevich (D–R), and Tempkin equations well. The maximum removal of MG was obtained at pH 6 as 99.86% for adsorbent dose of 1 g/50 mL and 25 mg L?1 initial dye concentration at room temperature. Activated carbon developed from the peel of C. sativa fruit can be an attractive option for dye removal from diluted industrial effluents since test reaction made on simulated dyeing wastewater showed better removal percentage of MG.  相似文献   

19.
Low-salinity waters, within the upper layers of the water column, have been observed in the oceanic region of the southeastern limit of the Bay of Biscay (in March, 2007). This contribution assesses the potential role of large surface freshwater discharges from the Adour (France), Nervión, Oria, Deba, Urola, Urumea and Bidasoa (Basque Country) rivers, to explain the presence of these low-salinity waters. Such discharges, within the offshore waters, reached to at least 50 m in depth; likewise, extending over 15–20 km, in the horizontal. This pattern is confirmed by field data collected by offshore buoys, model results, and the analysis of satellite images. The presence of the low-salinity waters is corroborated by numerical simulations, performed by the ROMS (Regional Ocean Modeling System) hydrodynamic model, with the incorporation of river discharges. In order to simulate the freshwater movements and to identify their origin, particles were released at the river mouths and dispersed (by a Lagrangian particle-tracking model, LPTM), supplied by 3-hourly current fields derived from the ROMS model. The plumes of the Nervión, Oria, Urola and Urumea rivers appear to be the main factors contributing to the low-salinity field, at the offshore locations of the buoys. This pattern is related mainly to the prevailing oceano-meteorological conditions, over the period of analysis.  相似文献   

20.
The results of studying the ionospheric effects of the March 29, 2006, solar eclipse are presented. The results were obtained in measurements of local electron density (ED) at Alma-Ata vertical ionospheric sounding station and total electron content (TEC) at the Central Asia network of two-frequency receivers of the GPS navigation system. The ED decrease at the F-layer maximum reached approximately 28%, the delay of the minimum value of EC relative to the moment of the eclipse maximum phase was about 11 min, the relaxation time was 4 min, and the duration of the EC depression at the 0.5 level was 45 min. Dynamic interlayer formations were observed in the ionosphere near the eclipse maximum phase. A traveling ionospheric disturbance, probably generated at the shock wave front during the supersonic motion of the Moon’s shadow, was detected. The disturbance period and the horizontal projection of the velocity were about 90 min and ~680 m/s, respectively. The wave vector azimuth (145°) coincides with the model value of the normal to the shock front.  相似文献   

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