不同岩性火山岩孔隙度压力敏感性及其影响因素：以长岭断陷火山岩为例

为了解不同岩性火山岩孔隙度的压力敏感性,笔者选取长岭断陷安山岩、角砾凝灰岩和凝灰岩的代表性岩样,分别进行3.4、8.3、13.1、17.9、22.8、27.6、32.4、37.2 MPa多个覆压条件下的气体法孔隙度测量。结果表明,随着压力的增大,3种岩性岩样的孔隙度呈不同幅度的减小,幅度减小程度由大到小的岩性依次为凝灰岩、角砾凝灰岩、安山岩;说明凝灰岩的孔隙压力敏感性较强、角砾凝灰岩的孔隙压力敏感性居中、安山岩的孔隙压力敏感性最弱。经X射线衍射全岩分析、偏光显微镜下岩石薄片鉴定、高压压汞仪实验和基于CPMG脉冲序列的核磁共振实验分析显示,岩石组份、颗粒分选、孔径分布是影响孔隙压力敏感性的关键因素;塑性矿物体积分数越大、颗粒越小、孔径越小,相应孔隙度的压力敏感性越强。     

不同孔隙类型火山岩储层渗透率应力敏感特征

针对火山岩气藏储层岩石孔隙结构复杂、矿物组成及成岩机制与沉积砂岩不同等特点,选取尺寸较大的不同孔隙结构全直径岩芯进行渗透率应力敏感试验研究。试验结果表明,低渗火山岩气藏岩芯具有较强的应力敏感特征,岩芯渗透率的减小主要发生在有效应力小于20 MPa的范围内,但当有效应力大于30 MPa后,渗透率仍然具有一定程度的减小,这与低渗沉积砂岩具有明显的差别。岩性差异所引起的矿物组成、颗粒胶结等因素对火山岩渗透率应力敏感特征影响较小,孔隙结构差异是导致岩石渗透率应力敏感强弱差异的主要原因,其中裂缝型岩石应力敏感性最强,致密型和孔隙型岩石应力敏感性相对较弱。反复加载试验表明,钻井取芯所引起的应力释放是导致岩芯渗透率应力滞后效应的根本原因,2次加载和卸载过程中岩石孔隙发生的主要是弹性变形。岩芯高围压下的地层渗透率平均仅约为地面渗透率的50%。     

围压和孔隙结构对不同粒级砂岩孔隙度渗透率的影响实验研究

孔隙度和渗透率是储层评价的两个重要参数.岩石毛管压力曲线和核磁共振T2谱图是描述储层微观结构特征的重要参数.通过测量不同压力条件下岩心样品的孔隙度和渗透率,得到了孔隙度和渗透率随压力的变化情况.实验结果表明：孔隙度和渗透率随着压力的增加而降低,并且与压力服从对数函数变化规律.不同孔隙度渗透率区间的砂岩样品,孔隙度和渗透率随着压力变化的趋势不同.通过测量不同粒级砂岩样品的毛管压力曲线和核磁共振T2谱图,证实了孔隙结构对孔隙度和渗透率的影响,微观孔隙结构是决定渗透性好坏的关键因素.     

Changes of deformational and reservoir properties of arenaceous-argillaceous rocks due to operation of underground gas storage facilities

This paper discusses issues of the decline of the reservoir properties of arenaceous-argillaceous rocks as a result of declining porosity due to long-term operation of underground gas storage facilities. An analysis of the many-year operation of storage facilities, as well as calculation, has revealed that the active capacity of a storage reservoir gradually decreases under certain conditions of underground storage operations. We performed a series of experiments with model specimens in order to support the hypothesis of decreasing reservoir (capacity-filtration) properties because of changes in the value and structure of the pore space. These experiments showed that the cyclic loading and unloading of arenaceous-silty rocks during long-term operation of underground gas storage facilities can significantly decrease the reservoir parameters of reservoirs created within worked out gas-and-gas condensate fields. Laboratory studies of model specimens corresponding to feldspar sandstone in their composition, porosity, and strength proved that porosity considerably decreases in such reservoirs at actually existing values of formation pressure. Tests of sand performed under conditions close to those existing during the development of hydrocarbon fields also showed that their permeability gradually decreases in the process of cyclic changes of effective pressure.     

不同冷却条件对高温砂岩物理力学性质的影响

岩石工程可能会经受高温环境。岩石高温后冷却方式的不同往往会导致岩石物理力学性质产生重大变化,这对岩石工程的稳定性、渗透性等都会产生重要影响。采用核磁共振（MRI）、电镜扫描（SEM）和单轴压缩试验对100、300、500、600、800 ℃ 5种不同温度砂岩经两种不同冷却方式（自然冷却和水中冷却）后的孔隙率、孔径分布、峰值强度、峰值应变、应力-应变关系以及微观结构变化等进行研究。试验结果表明：自然冷却时,高温砂岩强度并非随温度升高而持续降低,而水冷却会导致砂岩强度持续降低,且降低幅度远超自然冷却;500 ℃可以看作不同冷却方式对砂岩孔隙率影响的临界值,超过500 ℃,水冷却方式会导致孔隙率急剧增长,大孔径（Ф 10 μm）孔隙所占比例也高于自然冷却,因此,高温砂岩工程采用水冷却方式（如隧道着火后用水灭火）要充分考虑由此可能带来渗透危害;SEM测试表明,当温度 500 ℃时,水冷却对裂纹的增宽和扩展产生促进作用;当温度达到800 ℃时,水冷却砂岩孔洞变大,裂隙更加发育,并贯通连成网络,这会导致透水性大幅提高,同时,这也是该温度水冷却导致强度急剧降低的原因之一。     

页岩气的赋存形式研究及其石油地质意义

页岩气是以游离、吸附和溶解状态赋存于暗色泥页岩中的天然气,其赋存形式具有多样性,但以游离态和吸附态为主,溶解态仅少量存在。综述了页岩气的赋存形式及其影响因素,包括页岩气成因、页岩的物质组成(有机碳含量、矿物成分、岩石含水量)、岩石结构(孔隙度、渗透率)和温度、压力等。认识影响不同形式页岩气赋存量的地质因素,有助于利用容积法评估页岩气地质储量的水平,因为游离态页岩气的含量取决于页岩的有效孔隙度和含气饱和度,而吸附态页岩气的含量则受页岩的气体吸附能力影响。认为发展页岩孔隙结构表征技术,研究页岩气在粘土矿物表面和纳米孔隙中的吸附行为,可以进一步了解不同地质条件下页岩气的赋存形式,并为页岩气的资源评价提供更为准确的参数,因此它们将是页岩气下一步研究的重点之一。     

The effect of weathering on pore geometry and compressive strength of selected rock types from Turkey

Weathering processes cause important changes in rock porosity. Besides porosity, distribution of pore sizes is significant for the identification of changes due to rock weathering and its effects on fabric. The formation of secondary porosity in different types of rock taken from different parts of Turkey was examined and the results are presented in this paper. The aim of this study was to observe changes in porosity due to weathering. Effective porosity, mercury intrusion porosimetry, and optical and scanning electron microscopy were used to evaluate the changes in pore geometry of the rocks. Additionally, the dry density, water absorption and uniaxial compressive strength of the rocks at different weathering stages were determined. Analysis of experimental data showed that microstructure of the rocks in relation to weathering is the main feature, which controls their physical and mechanical properties. The study revealed that fabric characteristics, particularly the pore and fracture geometry are very important characteristics for assessment of the behaviour of weathered rock.     

An insight into the unrest phenomena at the Campi Flegrei caldera from Vp and Vp/Vs tomography

High resolution Vp and Vp/Vs tomography of the Campi Flegrei caldera is obtained using active and passive seismic data. We find a continuous ring of high Vp anomaly that defines the caldera rim associated to the last collapse. A sharp Vp/Vs decrease is observed between 2 and 4 km depth, suggesting the absence of magmatic fluids and the presence of rock volumes with over‐pressured gas within the source region of uplift. Atmospheric water penetrating within the caldera and deep CO₂ fluids are presumably heated by a magmatic body located at depth greater than 4 km nested within the limestone layer. Along the fractures bordering the shallow high Vp rim, deep gas and CO₂ fluids up‐raise and are released in the Pozzuoli solfatara. We hypothesize that the past unrest episode is more likely due to pressure changes within the shallow geothermal reservoir located at the top of the magma intrusion.     

The impact of diagenetic fluid–rock reactions on Rotliegend sandstone composition and petrophysical properties (Altmark area, central Germany)

In the framework of the German R&D joint project CLEAN (CO₂ large-scale enhanced gas recovery in the Altmark natural gas field), Rotliegend reservoir sandstones of the Altensalzwedel block in the Altmark area (Saxony-Anhalt, central Germany) have been studied to characterise litho- and diagenetic facies, mineral content, geochemical composition, and petrophysical properties. These sands have been deposited in a playa environment dominated by aeolian dunes, dry to wet sand flats and fluvial channel fills. The sediments exhibit distinct mineralogical, geochemical, and petrophysical features related to litho- and diagenetic facies types. In sandstones of the damp to wet sandflats, their pristine red colours are preserved and porosity and permeability are only low. Rocks of the aeolian environment and most of the channel fill deposits are preferentially bleached and exhibit moderate to high porosity and permeability. Although geochemical element whole rock content in these rocks is very similar, element correlations are different. Variations in porosity and permeability are mainly due to calcite and anhydrite dissolution and differences in clay coatings with Fe-bearing illitic-chloritic composition exposed to the pore space. Moreover, mineral dissolution patterns as well as compositions (of clays and carbonate) and morphotypes of authigenic minerals (chlorite, illite) are different in red and bleached rocks. Comparison of the geochemical composition and mineralogical features of diagenetically altered sandstones and samples exposed to CO₂-bearing fluids in laboratory batch experiments exhibit similar character. Experiments prove an increase in wettability and water binding capacity during CO₂ impact.     

非饱和低渗砂岩突破压力试验研究——以柴达木盆地东部石炭系砂岩为例

突破压力是气藏开采和盖层评估中的重要参数。文章选取柴达木盆地东部石炭系低渗砂岩岩心3块,对每块岩心进行6个不同含水率下的突破压力试验。通过XRD、XRF分析方法对砂岩的矿物成分、化学成分进行定量测试;利用氦气双室法与压汞试验对砂岩的孔隙度和孔径分布特征进行分析;用CH4气体模拟渗流试验对砂岩的绝对渗透率进行分析。结果表明:研究区低渗砂岩孔隙度在9.02%~10.96%之间,平均孔隙半径在0.1082~0.3709 μm之间,绝对渗透率在0.008~0.012 mD之间,干岩石突破压力值在0.05~0.19 MPa之间,饱和岩石突破压力值在1.51~2.73 MPa之间。黏土矿物遇水膨胀对孔隙结构不会造成显著性改变,因此对突破压力没有明显影响。影响突破压力的主要因素是孔隙结构和含水率。试验结果表明突破压力与岩石孔隙大小之间呈现负相关的关系,随着平均孔径和中值半径的增大,突破压力随之降低。本研究得到了突破压力与含水率之间的定量函数关系:突破压力随含水率增加呈指数函数形式增加。     

鄂尔多斯盆地上古生界致密砂岩气田储集层特征与成因*

鄂尔多斯盆地上古生界致密砂岩储集层普遍以低孔低渗为主要特征,但在低孔低渗的背景上发育相对优质储集层。应用偏光显微镜、恒速压汞等技术手段,从碎屑岩的粒度、碎屑组分、孔隙结构等分析入手,对比神木气田、榆林气田和苏里格气田3个大气田的储集层特点,并对致密砂岩中相对优质储集层的成因进行了分析。研究认为：高石英类矿物含量、适量的可溶性组分(包括长石、火山岩岩屑及凝灰质等）及残余少量粒间孔形成的酸性流体的渗流通道是形成相对优质储集层的必要条件;而较高含量的千枚岩屑、泥板岩等软组分,在上覆地层压力作用下被压实变形、充填孔隙,造成残余粒间孔全部丧失和酸性流体渗流通道的缺乏,因而形成低孔低渗的致密砂岩储集层。     

高围压条件下孔隙介质渗透特性试验研究

为研究不同围压条件下孔隙介质的渗透性能,利用新研制的高压渗流仪,对大尺寸低渗透性软弱岩进行了系统的试验测试。试验渗透压差波动幅度仅为0.02MPa,渗出端溶液体积变化量测试精度可达0.03mL。通过溶液体积变化与时间的线性关系,稳定渗流量大小可以精确测定。以稳定压差、流量法(即稳压法),试验验证了岩石的渗透系数随着围压的增加而下降,当围压降低时,岩石渗透系数回升,但回升路径低于原始路径。根据轴向应变的变化情况,提出了室内试验应力-渗流耦合过程中渗透性的变化主要是侧向压力使孔隙、喉道产生压缩变形所致。     

Cyclic Characteristics of the Physical Properties of Key Strata in CBM Systems Controlled by Sequence Stratigraphy—An Example from the Gujiao Block

Multiple coal seams and interbedded rock assemblages formed in vertical progression due to the influence of multiple stages of sea level transgressions.Based on mercury injection experiment,low temperature liquid nitrogen experiment,porosity and permeability experiment and breakthrough pressure experiment,the vertical variation characteristics of coal-bearing strata in Gujiao block are explained in detail.The results of the mercury injection and low temperature liquid nitrogen experiments show that the pore structure characteristics fluctuate with increasing depth in the strata,with fewer micropores followed by transition pores.The BET specific surface area and average pore diameter of the Shanxi Formation are generally larger than those of the Taiyuan Formation.Due to the continuous cyclic sequence stratigraphy changes,the porosity,permeability,breakthrough pressure and breakthrough time of the samples show a certain cyclicity.Within the same sequence,the porosity is larger,and the permeability is smaller near the maximum flooding surface.Although the permeability of the sandstone samples is higher,the porosity is lower,and the breakthrough pressure and breakthrough times are greater.The strata in the study area formed in an oxidized environment that was affected by freshwater,and the pore structure of different lithologies is quite different.After the formation of sandstone,the intergranular pores generally underwent filling with secondary quartz,clay minerals and organic matter,resulting in low porosity and permeability.     

Thermally induced volume change and excess pore water pressure of soft Bangkok clay

This paper presents the results of an experimental investigation carried out to study thermally induced volume changes under drained heating condition and thermally induced excess pore water pressures under undrained heating condition of soft Bangkok clay. The clay was heated up from room temperature (25 °C) to 90 °C using a modified oedometer and a triaxial test apparatus, respectively. The clay was found to exhibit temperature induced volume changes and temperature induced excess pore water pressures, in the range of temperatures investigated, depending mainly on the stress history. A theoretical microstructure mechanism that can interpret the thermally induced volume change behaviour at different stress conditions is presented in this study. Furthermore, the thermally induced excess pore water pressure behaviour at different stress conditions is explained using the unloading–reloading hysteresis of the typical soil consolidation curve. The results of this study provide additional data that can enhance the understanding of the thermo-mechanical behaviour concepts of saturated clays.     

高孔砂岩断层内部微观结构及渗透性变化规律物理模拟

在油气勘探过程中,对于小位移断层分隔油水封闭能力的控制因素研究尚浅,野外也难以获得不同变形过程的断层带结构及其渗透性变化规律.因此,以高孔隙度纯净砂岩人造岩心为研究对象,采用自主研发的“高压~低速环形剪切装置”开展实验,实验后样品取心分别进行覆压孔渗测试、纳米CT扫描、铸体薄片分析等分析测试.以有效正应力和断层位移为实验变量开展了多组环剪实验,其研究结果表明:宏观上断层面上可观察到明显擦痕与粉末状碎裂岩,微观上确定了断层带内碎裂作用导致的颗粒粒度降低与颗粒的定向排列是孔渗降低的主要原因,断层带渗透率小于10 mD,较母岩降低2~3个数量级.随着断层有效正应力或断层滑动位移增加,断层带碎裂程度增大且粒径和孔径减小,断层带厚度增大,孔隙度和渗透率逐渐减小.这一结果可为小位移断层侧向封闭能力与油气勘探领域的研究奠定理论基础.      

异常高压气藏储层参数应力敏感性研究

异常高压气藏开采过程中,由于流体的产出,使储层岩石受力发生改变并使储层岩石发生弹塑性变形;而弹塑性变形反过来又影响到储层的孔隙度和渗透率,因此研究储层孔隙度和渗透率应力敏感性具有极其重要的意义。基于岩石力学的基本理论,推导出异常高压气藏岩石变形规律及变形方程,以此理论推导指导试验,将理论研究与实验规律相结合,在模拟地层条件下,对实际岩心样品进行了储层应力敏感性实验研究。实验研究表明,该方法能精确的描述储层孔隙度和渗透率应力敏感性,实验结果与理论推导结果完全吻合,进一步证明了理论推导的正确。     

Reservoir characteristics and methane adsorption capacity of the Upper Triassic continental shale in Western Sichuan Depression,China

The well-developed continental shale sequences in the Western Sichuan Depression are characterised by extremely low porosity and permeability, complex lithologies and strong lateral facies changes. The overall lack of proper characterisation of the shale properties has restricted gas exploration and development in the region. In this study, shales from the fifth member of the Xujiahe Formation of the Upper Triassic (T₃x⁵) are comprehensively characterised in terms of their organic geochemistry, mineral composition, microscopic pore structure and gas content. In addition, the influence of various geological factors on the adsorbed gas content is investigated. We proposed a new model for predicting the adsorption gas content of continental shale. The T₃x⁵ shale sequence is found to be rich in organic matter but with variable mineral compositions, pore types and reservoir physical properties. The porosity and permeability of shales are better than those of siltstones and fine sandstones interbedded with the shale under an overall densification background. Mesopores (2–50 nm) are common in the shale sequence, followed by micropores and then macropores. The gas-adsorption capacity of organic-rich shales increases with increasing TOC and clay-mineral contents, maturity and pressure, but decreases with increasing quartz content, carbonate minerals and temperature. The gas-adsorption capacity can thus be expressed as a function of organic matter, clay-mineral content, temperature and pressure. The calculated results are in good agreement with the experiment results and indicate that adsorption gas in the studied shales accounts for 78.9% of the total gas content.     

基于CT三维重建的注水煤岩体裂隙扩展规律研究

针对煤层注水防尘过程中注水压力设置不合理、注水渗流效果差等问题,采用CT扫描技术与RFPA软件相结合的方法,构建了可以表征注水煤岩体内部孔裂隙结构的三维细观非均匀渗流损伤数值模型。通过对经过CT三维重构的煤岩模型进行不同注水压力的渗流损伤模拟,研究了煤层注水压力对煤样的渗流破坏、渗透率演化及声发射特性变化的影响;并通过对重构的煤岩模型进行缩放处理,研究了煤岩尺寸对煤样的渗流破坏和声发射变化的影响。研究结果表明：在煤样微观裂隙扩展过程中,随着注水压力的递增,煤样损伤单元数、渗流运动的渗流场分布范围、渗透率、声发射数目和能量总体呈上升趋势,局部范围内有波动发生,发生波动的原因是由于渗流运动的渗流场与煤样裂隙内部应力场发生临界反应,致使煤样破坏单元位置发生改变;煤样渗透率由3.82×10−5 μm2上升至0.314 μm2,孔隙率由5.45%上升至48.45%,揭示了煤岩体裂隙总体上随注水压力增大而不断扩展贯通,局部上随注水压力增大而扩展趋势有所下降的影响规律;随着煤样尺寸的增加,注水破坏后煤样的孔隙率呈现先下降后逐渐平稳的趋势,声发射特性变化趋势正好与之相反,表明煤样的尺寸对注水煤岩渗流破坏有显著影响,但当煤样尺寸超过40 mm时,煤样尺寸对注水煤岩渗流破坏的影响趋于稳定。CT扫描技术与RFPA软件相结合的方法能够有效模拟注水煤岩的裂隙渗流扩展行为。     

Study of intergranular films and interstitial phases in geomaterials using high temperature centrifuge and ultrasonic method at high pressure

Water fluids in the Earth's crust may initiate a number of mineral reactions resulting in different microstructure changes, which may appear in the form of intergranular melt films and interstitial phases. Therefore, they have an essential influence on elastic wave velocities of rocks (for example, sandstone, amphibolite, basalt). The aim of the experiment was to determine the conditions of the silicate liquid and others interstitial phases distribution in the rock intergranular space.The results obtained using the ultrasonic method at temperature up to 950 °C and under fluid pressure of 300 MPa revealed that the formation of intergranular melt films and interstitial phases network depend on chemical composition of fluids. The experiments with use of a high-temperature centrifuge at temperature 1400 °C showed that the amount of melt films, higher than 6 %, is sufficient to form a system of interconnected intergranular channels. These studies can be contributed to the petrophysical and geochemical interpretation of geophysical measurements.     

柴达木盆地跃进地区E31、N1、N21碎屑岩储层特征

通过 15口井近百个铸体片的鉴定及压汞数据的分析,对跃进地区E₃1、N₁、N₂1碎屑岩储层取得如下认识 :①长石砂岩、岩屑长石砂岩、长石岩屑砂岩为主,成分成熟度和结构成熟度均较低;②储层经历压实压溶作用、成岩自生矿物胶结和溶解作用,剩余原生粒间孔占绝对优势,相同层位地层在跃东和跃西因埋藏深度不同导致成岩-孔隙演化史也不同,西区储层物性明显优于东区;③储层主要发育于水上分流河道、砂坪和辫状河道微相,碎屑的成份和结构成熟度、填隙物含量、成岩环境对储层性质有重要影响;④西区E₃1储层属高孔中渗的Ⅱ类储层,大孔细喉道组合特征,储集物性较佳,东区E₃1储层属特低孔特低渗的Ⅴ类储层,中孔微细喉道组合特征,储层物性不理想,N₁储层属低孔特低渗的Ⅳ-Ⅴ类储层,大孔小喉道组合特征,渗透率不佳.