Paleomagnetic evidence for a pre-early Eocene (∼ 50 Ma) bending of the Patagonian orocline (Tierra del Fuego,Argentina): Paleogeographic and tectonic implications

The southernmost segment of the Andes of southern Patagonia and Tierra del Fuego forms a ～ 700 km long orogenic re-entrant with an interlimb angle of ～ 90° known as Patagonian orocline. No reliable paleomagnetic evidence has been gathered so far to assess whether this great orogenic bend is a primary arc formed over an articulated paleomargin, or is due to bending of a previously less curved (or rectilinear) chain. Here we report on an extensive paleomagnetic and anisotropy of magnetic susceptibility (AMS) study carried out on 22 sites (298 oriented cores), predominantly sampled in Eocene marine clays from the external Magallanes belt of Tierra del Fuego. Five sites (out of six giving reliable paleomagnetic results) containing magnetite and subordinate iron sulphides yield a positive fold test at the 99% significance level, and document no significant rotation since ～ 50 Ma. Thus, the Patagonian orocline is either a primary bend, or an orocline formed after Cretaceous–earliest Tertiary rotations. Our data imply that the opening of the Drake Passage between South America and Antarctica (probably causing the onset of Antarctica glaciation and global climate cooling), was definitely not related to the formation of the Patagonian orocline, but was likely the sole consequence of the 32 ± 2 Ma Scotia plate spreading. Well-defined magnetic lineations gathered at 18 sites from the Magallanes belt are sub-parallel to (mostly E–W) local fold axes, while they trend randomly at two sites from the Magallanes foreland. Our and previous AMS data consistently show that the Fuegian Andes were characterized by a N–S compression and northward displacing fold–thrust sheets during Eocene–early Miocene times (50–20 Ma), an unexpected kinematics considering coeval South America–Antarctica relative motion. Both paleomagnetic and AMS data suggest no significant influence from the E–W left-lateral Magallanes–Fagnano strike–slip fault system (MFFS), running a few kilometres south of our sampling sites. We thus speculate that strike–slip fault offset in the Fuegian Andes may range in the lower bound values (～ 20 km) among those proposed so far. In any case our data exclude any influence of strike–slip tectonics on the genesis of the great orogenic bend called Patagonian orocline.     

Ab initio study of the composition dependence of the pressure-induced spin crossover in perovskite (Mg1 − x,Fex)SiO3

We present ab initio calculations of the zero-temperature iron high- to low-spin crossover in (Mg_1 ? xFe_x)SiO₃ perovskite at pressures relevant to Earth's lower mantle. Equations of state are fit for a range of compositions and used to predict the Fe spin transition pressure and associated changes in volume and bulk modulus. We predict a dramatic decrease in transition pressure as Fe concentration increases. This trend is contrary to that seen in ferropericlase, and suggests the energetics for spin crossover is highly dependent on the structural environment of Fe. Both Local Density Approximation (LDA) and Generalized Gradient Approximation (GGA) exchange-correlation methods are used, and both methods reproduce the same compositional trends. However, GGA gives a significantly higher transition pressure than LDA. The spin transition is made easier by the decreasing spin-flip energy with pressure but is also driven by the change in volume from high to low spin. Volume trends show that high-spin Fe²⁺ is larger than Mg²⁺ even under pressure, but low-spin Fe²⁺ is smaller at ambient conditions and approximately the same size as Mg²⁺ under high pressure, indicating that low-spin Fe²⁺ is less compressible than high-spin Fe²⁺. We find large changes between high- and low-spin in the slope of volume with Fe concentration. Although these changes are small in absolute magnitude for small Fe content, they are still important when measured per Fe and could be relevant for calculating partitioning coefficients in the lower mantle.     

Surface exposure dating of young basalts (1–200 ka) in the San Francisco volcanic field (Arizona,USA) using cosmogenic 3He and 21Ne

K–Ar ages of young basalts (<500 ka) are often higher than the actual eruption age, due to low potassium contents and the frequent presence of excess Ar in olivine and pyroxene phenocrysts. Geological studies in the San Francisco and Uinkaret volcanic fields in Arizona have documented the presence of excess ⁴⁰Ar and have concluded that K–Ar ages of young basalts in these fields tend to be inaccurate. This new study in the San Francisco volcanic field presents ³He_c and ²¹Ne_c ages yielded by olivine and pyroxene collected from three Pleistocene basalt flows – the South Sheba (∼190 ka), SP (∼70 ka), and Doney Mountain (∼67 ka) lava flows, – and from one Holocene basalt, the Bonito Lava Flow (∼1.4 ka) at Sunset Crater. These data indicate that, in two of three cases, ⁴⁰Ar/³⁹Ar and K–Ar ages of the young basalts agree well with cosmic-ray surface exposure ages of the same lava flow, thus suggesting that excess ⁴⁰Ar is not always a problem in young basalt flows in the San Francisco volcanic field. The exposure age of the Bonito lava flow agrees within uncertainty with dendrochronological and archeological age determinations. K–Ar and cosmogenic ³He and ²¹Ne ages from the SP flow are in agreement and much older than the OSL age (5.5–6 ka) reported for this lava flow. Furthermore, if the non-cosmogenic ages are assumed to be accurate, the subsequent calculated production rates at South Sheba and SP flow sample sites agree well with values in the literature.     

A new electrical and mechanically detonatable shear wave source for near surface (0–30 m) seismic acquisition

We present a new, impulsive, horizontal shear source capable of performing long shot profiles in a time-efficient and repeatable manner. The new shear source is ground-coupled by eight 1/2″ (1.27 cm) × 2″ (5.08 cm) steel spikes. Blank shotshells (12-gauge) used as energy sources can be either mechanically or electrically detonated. Electrical fuses have a start time repeatability of < 50 μs. This source can be operated by a single individual, and takes only ~ 10 s between shots as opposed to ~ 30 s for six stacked hammer blows. To ensure complete safety, the shotshell holder is surrounded by a protective 6″ (15.24 cm)-thick barrel, a push-and-twist-locked breach, and a safety pin.We conducted field tests at the 17th Street Canal levee breach site in New Orleans, Louisiana (30.017° N 90.121° W) and at an instrumented test borehole at Millsaps College in Jackson, Mississippi (32.325° N 93.182° W) to compare our new source and a traditional hammer impact source. The new shear source produces a broader-band of frequencies (30–100 Hz cf. 30–60 Hz). Signal generated by the new shear source has signal-to-noise ratios equivalent to ~ 3 stacked hammer blows to the hammer impact source. Ideal source signals must be broadband in frequency, have a high SNR, be consistent, and have precise start times; all traits of the new shear source.     

Changes in phytoplankton production and upwelling intensity off A Coruña (NW Spain) for the last 28 years

Ocean Dynamics - The analysis of a 28-year-long (1989–2016) series of monthly measurements of chlorophyll concentrations and primary production rates at a shelf station off A Coruña (NW...     

Composition,pre-eruptive zonation,and geochronologic significance of the ∼450 ka Diamante Tuff,Andean Cordillera (34°S), Argentina

Vertical geochemical sampling through the Diamante Tuff establishes patterns of zonation in the pre-eruption magma. Volcanic glass demonstrates a roofward increase in Fe and Cl, and a roofward decrease in Ca. Trace elements have no measurable zonation. Welded volcanic glass shows post-eruption loss of Fe, Mg and Cl as well as K gain. Our reported glass chemistry provides robust criteria for correlation to other localities. The Diamante Tuff is an important stratigraphic marker and recognition of this unit provides age control on Quaternary deposits, allowing determination of process rates and elucidating timing of tectonic and geomorphic activity.     

Determination of post-perovskite phase transition boundary up to 4400 K and implications for thermal structure in D″ layer

We have determined the post-perovskite phase transition boundary in MgSiO₃ in a wide temperature range from 1640 to 4380 K at 119–171 GPa on the basis of synchrotron X-ray diffraction measurements in-situ at high-pressure and -temperature in a laser-heated diamond-anvil cell (LHDAC). The results show a considerably high positive Clapeyron slope of + 13.3 ± 1.0 MPa/K and a transition temperature of about 3520 ± 70 K at the core–mantle boundary (CMB) pressure. The thermal structure in D″ layer can be tightly constrained from precisely determined post-perovskite phase transition boundary and the depths of paired seismic discontinuities. These suggest that temperature at the CMB may be around 3700 K, somewhat lower than previously thought. A minimum bound on the global heat flow from the core is estimated to be 6.6 ± 0.5 TW.     

Adsorption of Au(III) and Au(I) complexes on δ-MnO2

The sorption of AuCl₄ ⁻,AuCl₂ ⁻ and Au(S₂O₃)^3- on δ-MnO₂ was investigated at pH2–11.6, 0.01 mol/L and 0.1 mol/L NaNO₃ solutions. At pH 4 in two electrolyte strength solutions, Au sorption densities on δ-MnO₂ are 0.18–0.21 and 0.28μmoL/m² for AuCl₄ ⁻ and Au(S₂O₃)₂ ^3-, respectively, and the Au surface coverage is approximate to or lower than 1%. This adsorption of the two Au complexes decreases as the solution pH increases, which conforms to the sorption regularity of the anion on δ-MnO₂. The Au sorption decreases in the sequence of Au(S₂O₃)₂ ^3- >AuCl₄ ⁻ >AuC1₂ ⁻. The intrinsic equilibrium constants (logK ^int) of the three Au complexes are 1.17–2.7, much higher than those of Cu and Cd. The hydrolysis products of AuCl₄ ^- are preferentially adsorbed by δ-MnO₂ and the inner-sphere Au-surface complexes are formed on the surface. Project supported by the National Studying-abroad Foundation, the National Natural Science Foundation of China (Grant No. 49573200) and the Australian Mining Industry.     

The Dinar Earthquake (Mw = 6.2; October 1, 1995; Afyon-Turkey) and Earthquake Hazard of the Dinar-Çivril Fault

—A moderately strong earthquake (M _w = 6.2) occurred in the town of Dinar at 17.57 UT on October 1, 1995, taking the lives of 90 people and damaging about 4500 buildings. Its epicenter is located near the Dinar-Çivril fault and its focal mechanism is linked to a northeast-southwesterly tensional stress field arising from the interaction between the subducting African plate and the overriding Aegean-Anatolian plate in the eastern Mediterranean.¶Surface cracks of the October 1 earthquake have been observed 10 km continuously along the Dinar-Çivril fault. The cracks have displayed a mode of dip-slip; however, some have also indicated lateral slip. The different modes of slip are generally in agreement with the fault plane solution and are indicators of the complex nature of the rupture process.¶In investigating the earthquake hazard of the Dinar-Çivril fault and proximity, the maximum likelihood method was used to estimate seismic hazard parameters of b-value, seismicity activity rate λ _m and the expected maximum magnitude M _max?. The data consisted of the historical data covering the period between 1800–1900 and instrumental data between 1900 and 1992. This method, allowing use of the mixed earthquake catalogue containing both historical and instrumental earthquake data, yielded values of 0.70, 1.92 and 7.14 for b, λ _m and M _max?, respectively. The recurrence time estimated for an earthquake of a magnitude of M _w = 6.2 is 123 years. The non-occurrence probabilities of such an earthquake in 1 and 50 years are 0.21 and 0.04, respectively.     

Hawaiian oral tradition describes 400 years of volcanic activity at Kīlauea

Culturally significant oral tradition involving Pele, the Hawaiian volcano deity, and her youngest sister Hi'iaka may involve the two largest volcanic events to have taken place in Hawai'i since human settlement: the roughly 60-year-long ‘Ailā’au eruption during the 15th century and the following development of Kīlauea's caldera. In 1823, Rev. William Ellis and three others became the first Europeans to visit Kīlauea's summit and were told stories about Kīlauea's activity that are consistent with the Pele–Hi'iaka account and extend the oral tradition through the 18th century. Recent geologic studies confirm the essence of the oral traditions and illustrate the potential value of examining other Hawaiian chants and stories for more information about past volcanic activity in Hawai‘i.     

Equifinality of formal (DREAM) and informal (GLUE) Bayesian approaches in hydrologic modeling?

In recent years, a strong debate has emerged in the hydrologic literature regarding what constitutes an appropriate framework for uncertainty estimation. Particularly, there is strong disagreement whether an uncertainty framework should have its roots within a proper statistical (Bayesian) context, or whether such a framework should be based on a different philosophy and implement informal measures and weaker inference to summarize parameter and predictive distributions. In this paper, we compare a formal Bayesian approach using Markov Chain Monte Carlo (MCMC) with generalized likelihood uncertainty estimation (GLUE) for assessing uncertainty in conceptual watershed modeling. Our formal Bayesian approach is implemented using the recently developed differential evolution adaptive metropolis (DREAM) MCMC scheme with a likelihood function that explicitly considers model structural, input and parameter uncertainty. Our results demonstrate that DREAM and GLUE can generate very similar estimates of total streamflow uncertainty. This suggests that formal and informal Bayesian approaches have more common ground than the hydrologic literature and ongoing debate might suggest. The main advantage of formal approaches is, however, that they attempt to disentangle the effect of forcing, parameter and model structural error on total predictive uncertainty. This is key to improving hydrologic theory and to better understand and predict the flow of water through catchments.     

Farmers’ awareness and perception of Lake Ziway (Ethiopia) and its watershed management

The article examines how heads of farmers’ households perceive the socioeconomic benefits of Lake Ziway (Ethiopia), the causes of its current degradation, and the state of land and water use management in its watershed. The investigation was based on in-depth empirical field work including a survey with 635 heads of smallholder farmers’ households via interview using semi-structured questionnaires. Further, water abstraction was estimated from three districts that border with the lake. Respondents believe that Lake Ziway provides a number of individual and collective benefits for local communities, private companies and public institution. They stated, however, that the lake is under pressure from the floriculture industry and other investment projects, high population growth and subsequent expansion of settlements and irrigation farms, high applications of agrochemicals, soil erosion, uncontrolled water abstraction, and deforestation in the watershed. The respondents further believe that these activities are degrading the lake water quality, shrinking its water volume and decreasing its fish population. After examining government’s efforts to address these activities, the majority of respondents believe that the government role in the whole watershed is weak. This study contributes to better understand the local socio-ecological coherences and the problems Lake Ziway and its watershed are facing. It also provides information regarding long-term sustainable land and water use planning strategies for the lake and management of its watershed, which could also be applied to other lakes in Ethiopia, and beyond.     

Hydrochemical dynamics of the “lake–spring” system in the crater of El Chichón volcano (Chiapas,Mexico)

El Chichón volcano (Chiapas, Mexico) erupted violently in March–April 1982, breaching through the former volcano–hydrothermal system. Since then, the 1982 crater has hosted a shallow (1–3.3 m, acidic (pH ∼ 2.2) and warm (∼ 30 °C) crater lake with a strongly varying chemistry (Cl/SO₄ = 0–79 molar ratio). The changes in crater lake chemistry and volume are not systematically related to the seasonal variation of rainfall, but rather to the activity of near-neutral geyser-like springs in the crater (Soap Pool). These Soap Pool springs are the only sources of Cl for the lake. Their geyser-like behaviour with a long-term (months to years) periodicity is due to a specific geometry of the shallow boiling aquifer beneath the lake, which is the remnant of the 1983 Cl-rich (24,000 mg/l) crater lake water. The Soap Pool springs decreased in Cl content over time. The zero-time extrapolation (1982, year of the eruption) approaches the Cl content in the initial crater lake, meanwhile the extrapolation towards the future indicates a zero-Cl content by 2009 ± 1. This particular situation offers the opportunity to calculate mass balance and Cl budget to quantify the lake–spring system in the El Chichón crater. These calculations show that the water balance without the input of SP springs is negative, implying that the lake should disappear during the dry season. The isotopic composition of lake waters (δD and δ¹⁸O) coincide with this crater lake-SP dynamics, reflecting evaporation processes and mixing with SP geyser and meteoric water. Future dome growth, not observed yet in the post-1982 El Chichón crater, may be anticipated by changes in lake chemistry and dynamics.     

Crustal structure of Northwest Zagros (Kermanshah) and Central Iran (Yazd and Isfahan) using teleseismic Ps converted phases

Receiver functions are widely employed to detect P-to-S converted waves and are especially useful to image seismic discontinuities in the crust. In this study we used the P receiver function technique to investigate the velocity structure of the crust beneath the Northwest Zagros and Central Iran and map out the lateral variation of the Moho boundary within this area. Our dataset includes teleseismic data (M _b ≥ 5.5, epicentral distance from 30° to 95°) recorded at 12 three-component short-period stations of Kermanshah, Isfahan and Yazd telemetry seismic networks. Our results obtained from P receiver functions indicate clear Ps conversions at the Moho boundary. The Moho depths were firstly estimated from the delay time of the Moho converted phase relative to the direct P wave beneath each network. Then, we used the P receiver function inversion to find the properties of the Moho discontinuity such as depth and velocity contrast. Our results obtained from PRF are in good agreement with those obtained from the P receiver function modeling. We found an average Moho depth of about 42 km beneath the Northwest Zagros increasing toward the Sanandaj-Sirjan Metamorphic Zone and reaches 51 km, where two crusts (Zagros and Central Iran) are assumed to be superposed. The Moho depth decreases toward the Urmieh-Dokhtar Cenozoic volcanic belt and reaches 43 km beneath this area. We found a relatively flat Moho beneath the Central Iran where, the average crustal thickness is about 42 km. Our P receiver function modeling revealed a shear wave velocity of 3.6 km/s in the crust of Northwest Zagros and Central Iran increasing to 4.5 km/s beneath the Moho boundary. The average shear wave velocity in the crust of UDMA as SSZ is 3.6 km/s, which reaches to 4.0 km/s while in SSZ increases to 4.3 km/s beneath the Moho.     

The crustal fluid evolution and the causes of earthquakes(Ⅲ)

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Stability of arsenopyrite and As(III) in low-temperature acidic solutions

Arsenopyrite is one of the most important pri-mary arsenic mineral. In the Eh-pH diagram of the As-O2-S-H2O system, if the total arsenic concentration (TAs) is taken to be 0.75 mg/L, the total sulfur con-centration, 32 mg/L, the temperature, 25℃and the pressure, one atmosphere pressure for the discrimina-tion of arsenic species, it may be found that under hy-pergene conditions, arsenopyrite is a moderately stable mineral. Only in the strongly alkaline and reducing environment can arsenopy…     

Seismic Intensity Zoning Map of China (1990) and Its Explanation

The Seismic Intensity Zoning Map of China(1990)was based on the probabilistic method of seismic hazard analysis.In compiling the map,the characteristics of inhomogeneity of earthquake distribution both in space and time in China are considered sufficiently,and some necessary modifications in the model of seismic hazard analysis are carried out.Based on the analysis of the seismic activity and seismotectonic environment,26 seismic provinces are divided first as the statistical elements of the seismicity analysis; the seismic potential source areas are then divided in the seismic provinces.The 733 potential source areas with various upper limit magnitudes have been divided in the country.According to the reliable time domain of earthquake data with various magnitude intervals,the b values in magnitude-frequency relationship are calculated in the seismic provinces.According to the analysis of the inhomogeneity of seismicity distribution both in space and time,the annual average occurrence rates of the eart     

Source mechanism of strong aftershocks (<Emphasis Type="Italic">M</Emphasis><Subscript>s</Subscript>⩾5.6) of the 2008/05/12 Wenchuan earthquake and the implication for seismotectonics

Dozens of >M5, hundreds of >M4, and much more >M3 aftershocks occurred after the 2008/05/12 Wenchuan earthquake, which were well recorded by permanent and portable seismic stations. After relocated with P arrival, the >M3 aftershocks show two trends of distribution, with most of the aftershocks located along the north-east strike consistent with Longmenshan fault system, yet there is a north-west trend around the epicenter. It seems that substantially more aftershocks occur in regions with crystalline bedrocks. Then we collected waveform data from National Digital Seismograph Network and regional seismograph network of China, and employed “Cut and Paste” method to obtain focal mechanisms and depths of the big aftershocks (M⩾5.6). While most of those aftershocks show thrust mechanism, there are some strike slip earthquakes in the northern-most end of the rupture. Focal mechanisms show that the events located on the southern part of central Beichuan-Yingxiu Fault (BY) are mainly thrust earthquakes, which is consistent with initial mechanism of the main shock rupture. In the north part the aftershocks along the BY are also dominated by thrust slip, which is quite different from the right slip rupture of the main shock. Around Qingchuan-Pingwu Fault, the focal mechanisms are dominated by right-slip rupture with large depths (∼18 km). So we suspected that in the north part the main shock might rupture on two faults: Beichuan Fault and Qingchuan-Pingwu Fault. The complex pattern of aftershock mechanisms argues for presence of a complicated fault system in the Longmenshan area. Supported by Knowledge Innovation Project of Chinese Academy of Sciences (Grant Nos. KZCX3-SW-153, KZCX2-YW-116-1), National Natural Science Foundation of China (Grant No. 40604004), and National Basic Technology R & D Program (Grant No. 2006BAC01B02-01-02).     

Contrasting responses of oligochaetes (Annelida) and chironomids (Diptera) to the abatement of eutrophication in Lake Neuchâtel

: Lake Neuchâtel (Switzerland) has been recovering from human-induced eutrophication since 1982. Oligochaetes and chironomid larvae were used to monitor the recovery of sediment at a depth of 40 m. In oligochaete communities, the mean proportion of individuals belonging to species indicative of oligotrophic conditions (mostly Spirosperma velutinus and Stylodrilus heringianus) increased from 16 % in 1984 to 33 % in 1992, but decreased to 11 % in 1997. Based on oligochaetes, benthic conditions deteriorated in 1997 whereas, based on the increase of oligotrophic chironomids (mostly Micropsectra), they improved. This difference was attributed to the impact of large planktonic algae whose sedimentation had altered oxygen concentrations at the water-sediment interface. Oligochaetes were more affected than chironomids because they are less mobile and they depend more on the inner sediment for their food and reproduction than the latter. However, based on the combined response of oligochaetes and chironomids, benthic recovery was stalled in 1997 but was not reversed.