Geochemistry and origin of the Cretaceous sedimentary kaolin deposits,Red Sea,Egypt

This work reports, for the first time, the mineralogical and geochemical characteristics of the Cretaceous sedimentary kaolin deposits in the Red Sea area, Egypt and sheds the light on their source. Mineralogical and geochemical analyses of both bulk deposits and the sand and clay fractions of these deposits indicated that they are composed of kaolinite (average of 75 wt.%) and quartz (average of 22 wt.%). Traces of anatase (average of 1 wt.%) were identified in all kaolin samples, while traces of halite (average of 2 wt.%) and hematite (average of 1 wt.%) were reported in the majority of the analyzed samples. The clay fractions show relatively high contents of TiO₂ (average of 2.1%), Ni (average of 103 ppm), Nb (average of 98 ppm), Y (average of 67 ppm), and Zr (average of 630 ppm). Sum of the rare earth elements (ΣREE) in the clay fractions varies between 193 and 352 ppm. Chondrite-normalized REE patterns show enrichment of the light REE relative to the heavy REE ((La/Yb)_N = 9) and negative Eu anomaly (Eu*/Eu = 0.67).     

Provenance,weathering, and paleoenvironment of the Upper Cretaceous Duwi black shales,Aswan Governorate,Egypt

The mineralogy and geochemistry of the Upper Cretaceous Duwi black shales of Nile Valley district, Aswan Governorate, Egypt, have been investigated to identify the source rock characteristics, paleoweathering, and paleoenvironment of the source area. The Duwi Formation consists mainly of phosphorite and black shales and is subdivided into three members. The lower and upper members composed mainly of phosphorite beds intercalated with thin lenses of gray shales, while the middle member is mainly composed of gray shale, cracked, and filled with gypsum. Mineralogically, the Duwi black shales consist mainly of smectite and kaolinite. The non-clay minerals are dominated by quartz, calcite, phosphate, dolomite, feldspar, with little gypsum, anhydrite, iron oxides, and pyrite. Based on the CIA, PIA, and CIW values (average?=?84, 94, 95, respectively), it can be concluded that the litho-components of the studied shales were subjected to intense chemical weathering and reflect warm/humid climatic conditions in the depositional basin. The provenance discrimination diagram indicates that the nature of the source rocks probably was mainly intermediate and mafic igneous sources with subordinate recycled sedimentary rocks (Nubia Formation). Geochemical characteristics indicate that the Duwi black shales in Nile Valley district were deposited under anoxic reducing marine environments.     

Authigenic dolomite cementation in the Upper Cretaceous Phosphate Formation, Western Desert, Egypt

The Upper Cretaceous Phosphate Formation in the Western Desert of Egypt displays a characteristic facies association that includes marine phosphorites interbedded with black shales and glauconitic sandstones. The upper part of the formation is characterized by the presence of thin phosphatic beds, which are filled-extensively-with disordered and non stoichiometric (mean MgCO₃ = 41.4 ± 0.34 mol%) authigenic dolomite cement. SEM and the back scattered images of these coarse crystalline dolomite cements reveal that they display planar euhedral crystal boundaries, polymodal crystal size distribution and variable inclusion pattern. The relatively low and wide ranged δ¹⁸O (− 0.87 to − 4.15‰ VPDB) values of the dolomite cements coupled with their depleted Sr (mean = 187 ± 26 ppm) and high iron and manganese values (mean = 6851 ± 554 ppm and 11599 ± 229 ppm respectively) invoke that they were formed from mixed hypo-saline fluids within a mixing marine-meteoric zone probably during a low stand period at the vicinity of the Maastrichtian/Early Tertiary unconformity. Meanwhile, their negative δ¹³C (− 1.31 to − 3.56‰ VPDB) values argue for a possible involvement of isotopically light carbon, derived from degradation of organic matter, during their precipitation.     

Rock composition and origin of the Duwi Formation calcareous rocks, Upper Egypt

Upper Cretaceous phosphorite beds of the Duwi Formation, Upper Egypt, are intercalated with limestone, sandy limestone, marl, calcareous shales, and calcareous sandstone. Calcareous intercalations were subjected to field and detailed petrographic, mineralogical and geochemical investigations in order to constrain their rock composition and origin. Mineralogically, dolomite, calcite, quartz, francolite and feldspars are the non-clay minerals. Smectite, kaolinite and illite represent the clay minerals. Major and trace elements can be classified as the detrital and carbonate fractions based on their sources. The detrital fraction includes the elements that are derived from detrital sources, mainly clay minerals and quartz, such as Si, Al, Fe, Ti, K, Ba, V, Ni, Co, Cr, Zn, Cu, Zr, and Mo. The carbonate fraction includes the elements that are derived from carbonates, maily calcite and dolomite, such as Ca, Mg and Sr. Dolomite occurs as being dense, uniform, mosaic, very fine-to-fine, non-ferroan, and non-stoichiometrical, suggesting its early diagenetic formation in a near-shore oxidizing shallow marine environment. The close association and positive correlation between dolomite and smectite indicates the role of clay minerals in the formation of dolomite as a source of Mg^2＋ -rich solutions. Calcareous rocks were deposited in marine, oxidizing and weakly alkaline conditions, marking a semi-arid climatic period. The calcareous/argillaceous alternations are due to oscillations in clay/carbonate ratio.     

Mineralogy,geochemistry and the origin of high-phosphorus oolitic iron ores of Aswan,Egypt

The Coniacian-Santonian high-phosphorus oolitic iron ore at Aswan area is one of the major iron ore deposits in Egypt. However, there are no reports on its geochemistry, which includes trace and rare earth elements evaluation. Texture, mineralogy and origin of phosphorus that represents the main impurity in these ore deposits have not been discussed in previous studies. In this investigation, iron ores from three localities were subjected to petrographic, mineralogical and geochemical analyses. The Aswan oolitic iron ores consist of uniform size ooids with snowball-like texture and tangentially arranged laminae of hematite and chamosite. The ores also possess detrital quartz, apatite and fine-grained ferruginous chamosite groundmass. In addition to Fe₂O₃, the studied iron ores show relatively high contents of SiO₂ and Al₂O₃ due to the abundance of quartz and chamosite. P₂O₅ ranges from 0.3 to 3.4 wt.% showing strong positive correlation with CaO and suggesting the occurrence of P mainly as apatite. X-ray diffraction analysis confirmed the occurrence of this apatite as hydroxyapatite. Under the optical microscope and scanning electron microscope, hydroxyapatite occurred as massive and structureless grains of undefined outlines and variable size (5–150 μm) inside the ooids and/or in the ferruginous groundmass. Among trace elements, V, Ba, Sr, Co, Zr, Y, Ni, Zn, and Cu occurred in relatively high concentrations (62–240 ppm) in comparison to other trace elements. Most of these trace elements exhibit positive correlations with SiO₂, Al₂O₃, and TiO₂ suggesting their occurrence in the detrital fraction which includes the clay minerals. ΣREE ranges between 129.5 and 617 ppm with strong positive correlations with P₂O₅ indicating the occurrence of REE in the apatite. Chondrite-normalized REE patterns showed LREE enrichment over HREE ((La/Yb)_N = 2.3–5.4) and negative Eu anomalies (Eu/Eu* = 0.75–0.89). The oolitic texture of the studied ores forms as direct precipitation of iron-rich minerals from sea water in open space near the sediment-water interface by accretion of FeO, SiO_2, and Al₂O₃ around suspended solid particles such as quartz and parts of broken ooliths. The fairly uniform size of the ooids reflects sorting due to the current action. The geochemistry of major and trace elements in the ores reflects their hydrogenous origin. The oolitic iron ores of the Timsha Formation represent a transgressive phase of the Tethys into southern Egypt during the Coniacian-Santonian between the non-marine Turonian Abu Agag and Santonian-Campanian Um Barmil formations. The abundance of detrital quartz, positive correlations between trace elements and TiO₂ and Al₂O₃, and the abundance mudstone intervals within the iron ores supports the detrital source of Fe. This prediction is due to the weathering of adjacent land masses from Cambrian to late Cretaceous. The texture of the apatite and the REE patterns, which occurs entirely in the apatite, exhibits a pattern similar to those in the granite, thus suggesting a detrital origin of the hydroxyapatite that was probably derived from the Precambrian igneous rocks. Determining the mode of occurrence and grain size of hydroxyapatite assists in the maximum utilization of both physical and biological separation of apatite from the Aswan iron ores, and hence encourages the use of these ores as raw materials in the iron making industry.     

The origin of giant molecular clouds

The parameters of molecular clouds formed via the Parker instability with dominant radiative losses are estimated. In this scenario, the cloud parameters (such as their mean densities and masses) should depend on galactocentric radius. This dependence is determined mainly by radial variations of the gas metallicity and the flux of heating radiation in the Galaxy. Due to the development of the interchange mode of the Parker instability, the angular momentum of the clouds will not necessarily be parallel to the galactic rotation axis.     

Geochemistry, mineralogy, and radioactivity of Upper Cretaceous Abu Khruq Ring Complex, South Eastern Desert, Egypt

The upper Cretaceous Abu Khruq ring complex (ARC) is located in the South Eastern Desert between latitudes 24°00′10′′ and 24°03′15′′ N, and longitudes 33°54′50′′ and 33°58′ E and has a roughly circular shape with a diameter of 7 km. ARC is built up by major extrusion of alkaline volcanic rocks comprising mainly rhyolite porphyry and alkaline trachyte rocks at the center of the ring complex followed by successive intrusions of alkaline gabbro and syenitic rocks comprising quartz syenite (oversaturated), syenite (saturated), and nepheline syenite (undersaturated). Petrographical and geochemical studies were carried out for the rocks of the forming ARC. For mineralogical and radioactive investigations, samples were collected from the most promising locations representing the hematitized nepheline syenite, nepheline syenite pegmatites, and quartz syenite. The most important minerals comprise: phosphuranylite, zircon, monazite, xenotime, plumbopyrochlore, pyrite, huttonite, apatite, REE mineral, rutile, and atacamite. The hematitized nepheline syenite is the most U- and Th-rich rocks, where eU content in this rock ranges from 375 to 788 ppm with an average 502 ppm and the average eTh content is 2,345 ppm ranging from 1,918 to 3,067 ppm. The pegmatite syenite and quartz syenite contain relatively low concentrations of U and Th, where the average eU content are 11 and 16 ppm and average eTh contents are 27 and 327 ppm, respectively.     

Fault damage zone origin of the Teufelsmauer, Subhercynian Cretaceous Basin, Germany

Recognition of fractures as porosity-reducing deformation bands pervading all sandstone segments of the Teufelsmauer, Subhercynian Creatceous Basin, Germany, motivates a study relating the observed macroscopic and microscopic deformation to the damage zone of the nearby Harz border fault. Deformation bands, confirmed and documented by several porosity-reducing micro-mechanisms, such as cataclasis, particulate flow, pressure solution and a heavy quartz cementation, were mapped and analyzed in terms of the kinematics and deformation intensities expressed by them. Deformation band kinematics are uniform throughout the entire basin and consistent with the large-scale tectonic structures of the area. A strain intensity study highlights two narrow but long zones of deformation bands, sub-parallel to the Harz border fault. Deformation band kinematics, strain intensity, as well as micro-mechanisms are all consistent with a continuous but internally diverse deformation band damage zone of the entire Teufelsmauer structure along the Harz border fault, bringing new insights into the tectonic evolution and the origin of the heavy quartz cementation of the sandstones in the Subhercynian Cretaceous Basin.     

Composition and origin of thermal waters in the Gulf of Suez area,Egypt

Thermal waters with discharge temperatures ranging from 32 to 70°C are being discharged along the Gulf of Suez (Egypt) from springs and shallow artesian wells. A comprehensive chemical and isotopic study of these waters supports previous suggestions that the waters are paleometeoric waters from the Nubian sandstone aquifer. The chemical and isotopic compositions of solutes indicate possible contributions from Tertiary sedimentary aquifer rocks and windblown deposits (marine aerosols and/or evaporite dust) in the recharge area. There is no chemical or isotopic evidence for mixing with Red Sea water. Gas effervescence from the Hammam Faraoun thermal water contains about 4% CH₄ (δ¹³C = −32.6‰) and 0.03% He having an isotopic ratio consistent with a mixture of crustal and magmatic He (³He/⁴He = 0.26 Re). Geothermometers for the thermal waters indicate maximum equilibration temperatures near 100°C. The waters could have been heated by percolation to a depth of several km along the regional geothermal gradient.     

Rudists (Bivalvia) from a Cretaceous Platform in Northern Egypt:Taxonomy and Paleobiogeography

New well-preserved rudist materials come from the Barremian–Turonian marine formations in the Yelleg, Minsherah, Maaza, and Raghawi sections in North Sinai, northern Egypt. There, 17 discovered rudist species belonging to 13 genera and seven taxonomic families are described in detail as follows: Eoradiolites plicatus (Conrad), Eoradiolites liratus (Conrad), Praeradiolites ponsianus (?Archiac), Archaeoradiolites sp., Bournonia africana Douvillé, Bournonia fourtaui Douvillé, Biradiolites lombricalis (?Orbigny), Biradiolites zumoffeni Douvillé, Radiolites lewyi lewyi Parnes, Radiolites sauvagesi (?Hombres-Firmas), Durania arnaudi (Choffat), Toucasia carinata (Matheron), Toucasia sp., Neocaprina raghawiensis Steuber and Bachmann, Sellaea sp., Ichthyosarcolites sp. and Horoiopleura sp.. The Cenomanian deposits in the northern Eastern desert of Egypt only contain E. liratus. The domination of the Cenomanian rudist species in North Sinai, however, is attributed to changes in the platform, which passes mainly from carbonate in the north to siliciclastics in the south. The presence of Horiopleura sp. in the late Barremian–early Aptian deposits is documented for the first time, which suggests the expansion of taxa of the genus Horiopleura Douvillé to North Sinai during this interval. The age of the rudist species is documented from the late Barremian–Turonian formations, with their geographic distribution in the Mediterranean region considered..     

藏南白垩纪桑日群麻木下组埃达克岩的地球化学特征及其成因

桑日群火山岩位于冈底斯南缘火山-岩浆弧的中、东段,紧邻雅鲁藏布江缝合带的北侧,包括下部麻木下组与上部比马组中的火山岩,长期以来被认为是雅鲁藏布江新特提斯洋沿冈底斯南缘向北俯冲消减的产物,但是这些火山岩还未见系统的地球化学数据,对其成因也缺乏深入的讨论。通过对桑日群火山岩详细的地球化学研究,识别出麻木下组火山岩具有典型的埃达克岩的地球化学特征：高Sr（平均为977ug／g）,低Y（平均为10．4ug／g）、Yb（平均为0．942ug／g）含量,轻重稀土强烈分异（La／Yb平均为24．8）;另外岩石还具有相对低sr和高Nd的同位素组成（^87Sr／^86Sr）i=0．703506～0．704369,（^143Nd／^144Nd）,=0．512728～0．512778,εNd（t）平均为5．58,显示出与雅鲁藏布江蛇绿岩的MORB相似的同位素特征,表明其可能来源于新特提斯雅鲁藏布江洋岩石圈的部分熔融。而相对高的MgO（平均为4．38％）、Cr（平均为198ug／g）和Ni（平均为117ug／g）含量暗示原始的埃达克质熔体在其上升过程中与上覆地幔楔发生了反应。综合考虑新特提斯洋以及冈底斯造山带的演化历史,提出麻木下组埃达克岩可能是在早白垩世时雅鲁藏布江新特提斯洋北向俯冲消减的初始阶段由洋壳部分熔融所形成的认识。     

Groundwater hydrochemistry and origin in the south-eastern part of Wadi El Natrun,Egypt

The demand for water is rapidly increasing in Egypt, because of high population and agriculture production growth rate, which makes research of water resources necessary. The regional multi-aquifer system of the Miocene–Pleistocene age is discharged in Wadi El Natrun area. Intensive aquifer overexploitation and agricultural development in the area are related to groundwater quality deterioration. Hydrochemical and hydrogeological data was evaluated to determine the groundwater origin and quality in the south-eastern part of wadi, which appears to be more significant for water supply owing to lower groundwater salinity. The dominance of the high mineralised Cl groundwater type was found; however, also less mineralised SO₄ and HCO₃ types were identified there. Based on the ion relations, halite and gypsum dissolution and ion exchange are the most important hydrochemical processes forming the groundwater chemical composition. The Cl dominated groundwater matches the discharge part of the regional hydrogeological system. Contrary, the presence of HCO₃ and SO₄ hydrochemical types corresponds to the infiltration and transferring parts of the hydrogeological system indicating the presence of zones conducting low mineralised groundwater. The discharge area of the over-pumped aquifer in Wadi El-Natrun lies 23 m beneath the sea level with the shoreline being at the distance of 100 km, thus there is a real risk of seawater intrusion. Using the hydrochemical facies evolution diagram, four samples in the centre of the discharge area indicate advanced seawater intrusion. The zones of the highest demand for groundwater quality protection were indicated based on a spatial pattern of hydrogeochemical composition.     

Mineralogy,geochemistry and origin of Mn in the high-Mn iron ores,Bahariya Oasis,Egypt

Although Mn is one of the major impurities in the economic iron ores from the Bahariya Oasis, information on its modes of occurrence and origin is lacking in previous studies. High-Mn iron ores from El Gedida and Ghorabi–Nasser iron mines were subjected to detailed mineralogical, geochemical, and petrographic investigations using X-ray diffraction (XRD), infrared absorption spectrometry (IR), Raman spectroscopy, X-ray fluorescence (XRF), scanning electron microscopy (SEM), and electron probe microanalyzer (EPMA) to clarify the modes of occurrence of Mn in these deposits and its origin. The results showed that the MnO₂ contents range between 0.03 and 13.9 wt.%. Three mineralogical types have been identified for the Mn in the high-Mn iron ores, including: (1) inclusions within the hematite and goethite and/or Mn accumulated on their active surfaces, (2) coarse-grained and crystalline pyrolusite, and (3) fine-grained cement-like Mn oxide and hydroxide minerals (bixbyite, cryptomelane, aurorite, romanechite, manjiroite, and pyrochroite) between the Fe-bearing minerals. The Mn carbonate mineral (rhodochrosite) was detected only in the Ghorabi–Nasser high-Mn iron ores. Since IR patterns of low-Mn and high-Mn samples are almost the same, a combination of XRD analysis using non-filtered Fe-Kα radiations and Raman spectroscopy could be the best way to identify and distinguish between different Mn minerals.Assuming that both Fe and Mn were derived from the same source, the occurrence of high-Mn iron ores at the base of the stratigraphic section of the deposits overlain by the low-Mn iron ores indicated a supergene origin of the studied ores by descending solutions. The predominance of Mn oxide and hydroxide minerals in botryoidal shapes supports this interpretation. The small grain size of Mn-bearing minerals as well as the features of microbial fossils such as spherical, elliptical, and filamentous shapes of the Fe-bearing minerals suggested a microbial origin of studied iron ores.Variations in the distribution and mineralogy types of Mn in the iron ores of the Bahariya Oasis demanded detailed mineralogical and petrographic characterizations of the deposits before the beneficiation of high-Mn iron ores from the Bahariya Oasis as feedstock for the ironmaking industries in Egypt by magnetizing reduction. High Mn contents, especially in the Ghorabi–Nasser iron ore and occurrence of Mn as inclusions and/or accumulated on the surface of the Fe-bearing minerals would suggest a possible utilization of the high-Mn iron ores to produce ferromanganese alloys.     

Anatomy and evolution of a Lower Cretaceous alluvial plain: sedimentology and palaeosols in the upper Blairmore Group, south-western Alberta, Canada

The Lower Cretaceous (Albian) upper Blairmore Group is part of a thick clastic wedge that formed adjacent to the rising Cordillera in south-western Alberta. Regional transgressive intervals are superimposed on the overall regressive succession. Alluvial conglomerates, sandstones and mudstones were deposited in east-north-eastward draining fluvial systems, orientated transverse to the basin axis. Five facies associations have been identified: igneous pebble conglomerate, thick sandstone, interbedded lenticular sandstone and mudstone, thick mudstone with thin sandstone interlayers, and fossiliferous sandstone and mudstone. The facies associations are interpreted as gravelly fluvial channels, sandy fluvial channels, sand-dominated floodplains, mud-dominated floodplains, and marine shoreline deposits, respectively. Five types of palaeosols are recognized in the upper Blairmore Group based on lithology, the presence of pedogenic features (clay coatings, root traces, ferruginous nodules, slickensides, carbonate nodules) and degree of horizonization. The regional distribution of the various types of palaeosols enables a refinement of the palaeoenvironmental reconstruction permitting an assessment of the controls on floodplain evolution. In source-proximal areas, palaeosol development was inhibited by high rates of sedimentation. In source-distal locations, poor drainage resulting from high watertables, low topography and lower rates of sedimentation also inhibited palaeosol development. The best-developed palaeosols (containing Bt horizons) occur in intermediate alluvial plain positions (tectonic hinge zone) where the floodplains were most stable due to a balance between sedimentation, erosion and subsidence rates. Extrapolating from the upper Blairmore Group suggests that the tectonic hinge zone of continental foreland basins can be established by palaeosol analysis. At the hinge zone, soil development is controlled primarily by climate and tectonics and their effect on sediment supply, whereas closer to the palaeoshoreline, relative sea level fluctuations, resulting in poor drainage, may have a more significant influence.     

Contribution to the hydrogeology of the Lower Cretaceous aquifer in east Central Sinai, Egypt

The present work deals with the groundwater aquifer of the Lower Cretaceous sandstone and its sustainable development in Sinai. The studied aquifer system is the most promising groundwater system in Sinai due to its wide extension, hug storage, and good quality. The objective of this paper aims to elucidate the hydrogeological characteristics of the Lower Cretaceous aquifer. The aquifer system occurs under confined conditions. The top surface of the Lower Cretaceous dips steeply towards the southwest direction with step faults. The average sand percent of the penetrated aquifer attains 54%. The main direction of groundwater flow is generally from southwest and locally is concentric to the center of study area related to the influence of the graben block. The aquifer has a hydraulic gradient generally reaches 0.0011 m/m and attains 0.0028 in central portion of study area. The aquifer parameters (effective porosity, transmissivity, and hydraulic conductivity) increase towards the northeast direction with increasing of the sand percentage. Durov diagram plot revealed that the groundwater has been a final stage evolution represented by a NaCl water type. The groundwater salinity increases towards the central of study area coinciding with groundwater flow. The groundwater salinity of the Lower Cretaceous aquifer is brackish water and varies from 2,510 to 5,256 ppm and unsuitable for drinking and domestic purposes.     

Palynology and palynofacies of the Upper Cretaceous succession of the El-Noor-1X borehole,northwestern Egypt

Palynological and palynofacies analyses were carried out on some middle–upper Cretaceous samples from the El-Noor-1X borehole, northern Western Desert, Egypt. Palynological age has lead to a refinement of the original ages suggested by the drilling company. Upper Albian–Lower Cenomanian, Upper Cenomanian, and Turonian–Coniacian were recognized. The palaeoenvironment was interpreted on the basis of the ecological preferences of the palynomorphs. It was fluctuating between marginal to inner-middle shelf environment. Distribution of araucaroid pollen and xerophytes suggests that arid or semi-arid paleclimate prevailed during the deposition of the studied sediments. A warm tropical palaeoclimate is suggested on the basis of abundance of hygrophilous plants. Based on the recovered palynological organic matter, two palynofacies were recognized: palynofacies A for the Bahariya Formation, which suggests kerogen type III, and palynofacies B for the upper Bahariya and Abu Roash Formations, which suggests kerogen type IX. Data gathered from the theoretically estimated vitrinite reflectances, which are based on spore/pollen coloration, and visual pterographic kerogen analysis are used to define the source rock potentialities of the studied sediments.     

Palynology of some Cretaceous mudstones from southeast Aswan,Egypt: significance to regional stratigraphy

The basal mudstones from the El-Nom borehole in the Gebel Abraq area in southern Egypt have yielded a diverse and relatively well preserved terrestrial palynoflora that includes Balmeisporites holodictyus, Crybelosporites pannuceus, Foveotricolpites gigantoreticulatus, Nyssapollenites albertensis, Retimonocolpites variplicatus and Rousea delicipollis. These suggest an Albian–Cenomanian age and deposition in a fluvio-deltaic environment; no marine phytoplankton is reported. The fern-dominated palynoflora and the overwhelming presence of kaolinitic clays suggest a warm, humid palaeoclimate. According to available knowledge, the mudstones in the Gebel Abraq area, equivalents of the so-called “Timsah Formation”, might be correlated with an older rock unit, the Maghrabi Formation, based on the new palynological age assessment. This new definition of local stratigraphy implies that the Bernice sheet of geological map of Egypt [Klitzsch, E., List, F., Pöhlmann, G., 1987. Geological map of Egypt, sheet NF 36 NE Bernice, 1: 500 000. Conoco and the Egyptian General Petroleum Corporation, Cairo] ought to be reconsidered.     

Stratigraphy,sedimentology and tectonic evolution of the Upper Cretaceous/Paleogene succession in north Eastern Desert,Egypt

The stratigraphy, sedimentology and syn-depositional tectonic events (SdTEs) of the Upper Cretaceous/Paleogene (K–P) succession at four localities in north Eastern Desert (NED) of Egypt have been studied. These localities are distributed from south-southwest to north-northeast at Gebel Millaha, at North Wadi Qena, at Wadi El Dakhal, and at Saint Paul Monastery. Lithostratigraphically, four rock units have been recorded: Sudr Formation (Campanian–Maastrichtian); Dakhla Formation (Danian–Selandian); Tarawan Formation (Selandian–Thanetian) and Esna Formation (Thanetian–Ypresian). These rock units are not completely represented all over the study area because some of them are absent at certain sites and others have variable thicknesses. Biostratigrapgically, 18 planktonic foraminiferal zones have been recorded. These are in stratigraphic order: Globotruncana ventricosa Zone (Campanian); Gansserina gansseri, Contusotruncana contusa, Recimguembelina fructicosa, Pseudohastigerina hariaensis, Pseudohastigerina palpebra and Plummerita hantkenenoides zones (Maastrichtian); Praemurica incostans, Praemurica uncinata, Morozovella angulata and Praemurica carinata/Igorina albeari zones (Danian); Igorina albeari, Globanomanlina pseudomenradii/Parasubbotina variospira, Acarinina subsphaerica, Acarinina soldadoensis/Globanomanlina pseudomenardii and Morozovella velascoensis zones (Selandian/Thantian); and Acarinina sibaiyaensis, Pseudohastigerina wilcoxensis/Morozovella velascoensis zones (earliest Ypresian). Sedimentologically, four sedimentary facies belts forming southwest gently-dipping slope to basin transect have been detected. They include tidal flats, outer shelf, slumped continental slope and open marine hemipelagic facies. This transect can be subdivided into a stable basin plain plus outer shelf in the extreme southwestern parts; and an unstable slope shelf platform in the northeastern parts. The unstable slope shelf platform is characterized by open marine hemipelagic, fine-grained limestones and fine siliciclastic shales (Sudr, Dakhla, Tarawan and Esna formations). The northeastern parts are marked by little contents of planktonic foraminifera and dolomitized, slumped carbonates, intercalated with basinal facies. Tectonically, four remarkable syn-depositional tectonic events (SdTEs) controlled the evolution of the studied succession. These events took place strongly within the Campanian–Ypresian time interval and were still active till Late Eocene. These events took place at: the Santonian/Campanian (S/C) boundary; the Campanian/Maastrichtian (C/M) boundary; the Cretaceous/Paleogene (K/P) boundary; and the Middle Paleocene–Early Eocene interval. These tectonic events are four pronounced phases in the tectonic history of the Syrian Arc System (SAS), the collision of the Afro-Arabian and Eurasian plates as well as the closure of the Tethys Sea.     

Uranium isotopic evidence for the origin of the Bahariya iron deposits, Egypt

The economic iron ore deposits of Egypt are located at Bahariya Oasis in the Lower Middle Eocene limestone. The main iron minerals are goethite, hematite, siderite, pyrite, and jarosite. Manganese minerals are pyrolusite and manganite. Gangue minerals are barite, glauconite, gibbsite, alunite, quartz, halite, kaolinite, illite, smectite, palygorskite, and halloysite. Geochemical comparison between the ore and the Nubia sandstone showed that the ore is depleted in the residual elements (Al, Ti, V, and Ni) and enriched in the mobile elements (Fe, Mn, Zn, Ba, and U) which indicates that the Bahariya iron ore is not a lateritic deposit despite the deep weathering in this area. On the other hand, the Nubia sandstone showed depletion in the mobile elements, which demonstrates the leaching process in the Nubia Aquifer. The presence of such indicator minerals as jarosite, alunite, glauconite, gibbsite, palygorskite, and halloysite indicate that the ore was deposited under strong acidic conditions in fresh water.Isotopic analyses of the uranium in the amorphous and crystalline phases of the ore, in the country rocks, and dissolved in the Nubia Aquifer water, all support the conclusion that U and Fe were precipitated together from warm ascending groundwater. U and Fe display strong co-variation in the ore, and the ²³⁴U/²³⁸U activity ratio of the newly precipitated U in the country rock and the leached component of U in the groundwater are identical. There is only slightly more uranium in the amorphous phase than in the crystalline and only a slightly lower ²³⁴U/²³⁸U activity ratio, suggesting that the iron in the two phases have a similar origin. Comparison of the excess ²³⁴U in the water and in the total ore leads to the conclusion that the precipitation of the U, and by inference the iron, occurred within the last million years. However, that both precipitation and leaching of U have occurred over the last 300,000 years is evidenced by the extreme ²³⁰Th/²³⁴U disequilibria observed in some of the samples. Some of the amorphous depositional events have been very recent, perhaps within the last 10,000 years.     

Mineralogy, geochemistry, and origin of hydrothermal manganese veins at Wadi Maliek, Southern Eastern Desert, Egypt

The present work deals with the geology, mineralogy, geochemistry, and origin of the metagabbroic-hosted manganese deposits at Wadi Maliek in the southern Eastern Desert of Egypt. The manganese veins are found in the shear zones and channel ways of the fault planes within the metagabbroic rocks pointing to those hydrothermal solutions carrying manganese and iron load penetrating along these fractures. These faults are striking N 80° E?CS 80° W with dipping 65°. These veins vary in thickness from 15?cm up to 125?cm wide; each vein may show difference in thickness from bottom to top. Microscopic examinations, X-ray diffraction, infrared spectral, differential thermal (DTA), thermogravimetric (TGA), and ESEM-EDAX analyses revealed that the manganese minerals consist mainly of pyrolusite, psilomelane, and ramsdellite. Goethite and hematite are the common iron minerals. Petrographically, the manganese deposits can be classified into three ore types based on the predominance of manganese and iron minerals: manganese, manganese?Ciron, and iron ore types. The geochemistry of Maliek deposits indicated that the total averages of some major oxides in manganese, manganese?Ciron, and iron ore types are respectively as follows: SiO₂ (15.64%, 11.52%, and 20.58%), MnO (39.9%, 17.81%, and 0.77%), FeO* (7.13%, 33.31%, and 37.08%), CaO (5.89%, 5.82%, and 5.32%), and Na₂O (1.04%, 1.61%, and 1.53%). With regard to trace elements, the Maliek manganese deposits are rich in Zn, Ba, Pb, Sr, and V. Based on the geological, mineralogical, and geochemical results, the studied manganese deposits are considered to be precipitated from hydrothermal solution.