Comparison of 105 years of oxygen isotope and insoluble impurity profiles from the Devon Island and Camp Century ice cores

Oxygen-isotope profiles for the Devon Island ice cap and Camp Century Greenland are affected by a number of variables, some of which must have been the same for both sites. The two δ(¹⁸O) records spanning about 120,000 years are brought into relative alignment by comparison of major δ features, and subsequent verification that the insoluble particulate concentration records were also in phase for this alignment. The difference between the δ profiles is shown to be mainly a function of the altitude of the accumulation area for Camp Century. This altitude seems to have been higher than present for the last 100,000 years, suggesting the present flow line through the site has never been shorter. The maximum altitude for the Camp Century accumulation area is 1500 m above the present site and is almost synchronous with the maximum in particulate concentration that occurs at 16,000 yr B.P. The synchronism is likely due to the maximum sea-level lowering that exposed vast areas of continental shelf to wind erosion.     

Climatic and non-climatic effects on the δO and δC compositions of Lake Awassa, Ethiopia, during the last 6.5 ka

A comparison of a 6450 ¹⁴C yr δ¹⁸O and δ¹³C record of authigenic calcite from Lake Awassa, Ethiopia, with other proxy climate records in the area suggests that the lake records long-term regional climate changes. Co-varying and increasing δ¹⁸O and δ¹³C values from 4800 BP suggest an aridification of climate after the early Holocene insolation maximum. After 4000 BP, humid conditions return until after 2800 BP when δ¹⁸O increases again, reflecting more arid conditions recorded elsewhere in Ethiopia. In addition to these long-term changes, there are abrupt decreases in both δ¹⁸O_calcite and δ¹³C_calcite immediately after tephra layers. The likeliest explanation for these abrupt decreases in isotopes is the effect of tephra on the lake's catchment vegetation. δ¹⁸O, δ¹³C and lake-level measurements from Lake Awassa since the 1970s suggest that the lake is currently isotopically sensitive to short-term (annual–decadal) climate change. However, during this period, the catchment has undergone progressive deforestation that may have caused an increase in runoff. Caution is therefore required when reconstructing palaeoclimates as a contemporary lake may not always be a good analogue for lake hydrology in the past.     

Oxygen and carbon isotope analysis of the Mooreville Chalk and late Santonian-early Campanian sea level and sea surface temperature changes, northeastern Gulf of Mexico, U.S.A.

Oxygen and carbon isotope profiles for strata of the Mooreville Chalk (upper Santonian-lower Campanian) of the eastern Gulf Coastal Plain, U.S.A., show correlations with published curves for these isotopes. The δ¹⁸O curve exhibits a strong similarity to the Exmouth Plateau δ¹⁸O curve from ODP drilling sites offshore northwestern Australia, and the δ¹³C curve can be correlated with the δ¹³C curve from the English Chalk Trunch section.A thermal maximum probably occurred in the northeastern Gulf of Mexico during the latest Santonian (83.8 Ma), as evidenced by the minimum δ¹⁸O values in the lower Mooreville beds. A δ¹³C positive excursion occurs at the same stratigraphic level, which has been recognized as the “Santonian/Campanian boundary event” worldwide. After this event, ocean surface water temperature decreased throughout the early Campanian. This carbon isotope excursion is followed by a plateau in δ¹³C values with a peak value occurring in a condensed section (80 Ma), which has been correlated to a downlap or maximum flooding surface on seismic data from offshore Alabama. The section characterized by increasing δ¹³C values corresponds to a marine transgression. The interval characterized by decreasing δ¹³C values corresponds to regression and progradation. The maximum flooding event occurred 0.8 Ma later than the thermal maximum event.The Mooreville chalk/marl cycles are most likely a product of fluctuations in siliciclastic sediment influx into the northeastern Gulf of Mexico modulated by the precession band of the Earth's orbital cycles. Higher carbon isotope values occur in the marl beds indicating that these beds were formed in a more anoxic/dysoxic environment characterized by higher clay, silt input and higher organic carbon accumulation.     

Geochemical assessment of an analogue site for an engineered landform at Ranger Uranium Mine, Northern Territory, Australia

 An essential element in identifying sites as analogues for the long-term development of soils and vegetation on engineered landforms of the rehabilitated Ranger Uranium Mine, Northern Territory, Australia, is the need to match rocks. Comparison of the geochemistry of rocks from the waste rock dump of Ranger Uranium Mine and the potential analogue site of Tin Camp Creek area, Western Arnhem Land, indicates that there are several sites along Tin Camp Creek that may be used as analogue sites. Detailed comparisons between the Ranger and Tin Camp Creek lithologies have been undertaken using a variety of techniques, including cluster analysis. It is demonstrated that at least 70% of the rocks being mined at Ranger have analogues in the Tin Camp Creek area. Received: 2 October 1996 · Accepted: 4 November 1997     

Developing oxygen isotope proxies from archaeological sources for the study of Late Holocene human–climate interactions in coastal southwest Florida

Oxygen isotopes (δ¹⁸O) derived from archaeological Mercenaria campechiensis shells and Ariopsis felis otoliths potentially provide low-latitude paleoclimate data for studying Late Holocene human–climate interactions in coastal southwest Florida. Specimens analyzed come from the Pineland site complex. Deposits record abrupt and subtle environmental changes appearing to have been climate-related and to have impacted the sedentary human residents. One archaeological shell-otolith set dates to 2nd/3rd century A.D. within the Roman Optimum (RO) climatic episode. A second set dates to 13th/14th century A.D. within the Little Ice Age (LIA). A modern shell-otolith set was analyzed for comparison. δ¹⁸O_ARAGONITE of modern and LIA shells suggest similar seasonal conditions. RO shell is 1‰ more positive during summer, suggesting higher estuarine salinity than in modern and LIA times. Modern and LIA otoliths also have similar δ¹⁸O_ARAGONITE. Estimated Winter temperatures are within measured instrument records. Summer temperatures are overestimated reflecting Summer migration into less-saline water. Estimated Summer temperatures for RO otolith are similar to today's, suggesting elevated estuarine salinity and diminished rainy season, consistent with similar aged zooarchaeological assemblages. Comparisons of two taxa aid in interpreting archaeological δ¹⁸O data; however, early results are mixed with expected profiles for RO specimens and unexpected profiles for LIA specimens.     

Evidence for Holocene environmental changes in the northern Fertile Crescent provided by pedogenic carbonate coatings

Holocene environmental changes in the northern Fertile Crescent remain poorly understood because of the scarcity of local proxy records in the region. In this study we investigated pedogenic (soil-formed) carbonate coatings on stones at the Pre-Pottery Neolithic site Göbekli Tepe as an indicator of local early-mid Holocene environmental changes. The ¹⁴C ages and stable isotopic composition of carbon and oxygen in thin (0.2–0.3 mm thick) pedogenic carbonate lamina indicate two main periods of coating formation: the early-Holocene (ca. 10000–6000 cal yr BP) and the mid-Holocene (ca. 6000–4000 cal yr BP). During the first period, there was an inverse relationship between δ¹³C and δ¹⁸O curves: a decrease in δ¹³C values coincide with an increase in δ¹⁸O values. For this period a trend towards higher temperatures is suggested. In the mid-Holocene, the mean rate of coating growth was 2–3 times higher than in the early Holocene. Both δ¹³C and δ¹⁸O reached their maximum values during this time and the direction of changes of the δ¹³C and δ¹⁸O curves became similar. The combination of data suggests that this period was the most humid in the Holocene and on average warmer than the early Holocene. At ca. 4000 cal yr BP secondary accumulation of carbonate ceased, presumably reflecting a shift to a more arid climate.     

Fractionation of silicon isotopes during biogenic silica dissolution

Silicon isotopes have been investigated for their potential to reveal both past and present patterns of silicic acid utilization, primarily by diatoms, in surface waters of the ocean. Interpretation of this proxy has thus far relied on characteristic trends in the isotope composition of the dissolved and particulate silicon pools in the upper ocean, as driven by biological fractionation during the production of biogenic silica (bSiO₂, or opal) by diatoms. However, other factors which may influence the silicon isotope composition of diatom opal, particularly post-formational aging and maturation processes, remain largely uninvestigated. Here, we report a consistent fractionation of silicon isotopes during the physicochemical dissolution of diatom bSiO₂ suspended in seawater under closed conditions. This fractionation acts counter to that occurring during bSiO₂ production and at about half its absolute magnitude, with dissolution discriminating against the release of the heavier isotopes of silicon at an enrichment factor ε_DSi–BSi of −0.55‰, corresponding to a fractionation factor α_30/28 of 0.99945. The enrichment factor did not vary with source material, indicating the lack of a significant species effect, or with temperature from 3 to 20 °C. Thus, the dissolution of bSiO₂ produces dissolved silicon with a δ³⁰Si value that is 0.55‰ more negative than its parent bSiO₂, an effect that must be accounted for when interpreting oceanic δ³⁰Si distributions. The δ³⁰Si values of both the dissolved and particulate silicon pools increased linearly as dissolution progressed, implying a measurable (±0.1‰) change in the relative δ³⁰Si of opal samples whenever the difference in preservation efficiency between them is >20%. This effect could account for 10–30% of the difference in diatom δ³⁰Si values observed between glacial and interglacial conditions. It is unlikely, however, that the inferred maximum possible change in δb³⁰SiO₂ of +0.55‰ would be manifested in situ, as a high mean percentage of dissolution would include complete loss of the more soluble members of the diatom assemblage.     

Stable isotope and C study of biogenic calcrete in a termite mound, Western Cape, South Africa, and its palaeoenvironmental significance

Late Quaternary terrestrial climate records from the semi-arid zone of the Western Cape of South Africa are rare. However, palaeoenvironmental information may be inferred from ancient termite mounds of the region. Calcrete lenses in these mounds have δ¹³C and δ¹⁸O values that show systematic changes with radiocarbon dates, which range from 33,629–36,709 to 21,676–23,256 cal yr BP. These dates confirm that these heuweltjies had been present in the landscape since the last glacial period. The decrease in δ¹³C and δ¹⁸O from 33,629–36,709 to 21,676–23,256 cal yr BP indicates that climate information is recorded by the calcretes. It is suggested that a progressive decline in air temperature and an increase in moisture availability, and a decline in abundance of C₄ or CAM plants, occurred in the region during the time heuweltjie calcite precipitated.     

Recent paleorecords document rising mercury contamination in Lake Tanganyika

Recent Lake Tanganyika Hg deposition records were derived using ¹⁴C and excess ²¹⁰Pb geochronometers in sediment cores collected from two contrasting depositional environments: the Kalya Platform, located mid-lake and more removed from watershed impacts, and the Nyasanga/Kahama River delta region, located close to the lake’s shoreline north of Kigoma. At the Kalya Platform area, pre-industrial Hg concentrations are 23 ± 0.2 ng/g, increasing to 74 ng/g in modern surface sediment, and the Hg accumulation rate has increased from 1.0 to 7.2 μg/m²/a from pre-industrial to present, which overall represents a 6-fold increase in Hg concentration and accumulation. At the Nyasanga/Kahama delta region, pre-industrial Hg concentrations are 20 ± 3 ng/g, increasing to 46 ng/g in surface sediment. Mercury accumulation rate has increased from 30 to 70 μg/m²/a at this site, representing a 2–3-fold increase in Hg concentration and accumulation. There is a lack of correlation between charcoal abundance and Hg accumulation rate in the sediment cores, demonstrating that local biomass burning has little relationship with the observed Hg concentration or Hg accumulation rates. Examined using a sediment focusing-corrected mass accumulation rate approach, the cores have similar anthropogenic atmospheric Hg deposition profiles, suggesting that after accounting for background sediment concentrations the source of accumulating Hg is predominantly atmospheric in origin. In summary, the data document an increase of Hg flux to the Lake Tanganyika ecosystem that is consistent with increasing watershed sediment delivery with background-level Hg contamination, and regional as well as global increases in atmospheric Hg deposition.     

Long wavelength magnetic anomalies from the lithosphere: Indian shield and Himalaya

A few long-range airborne magnetic profiles flown at an altitude of 7.5 km a.s.l. across the Indian shield are analysed and interpreted in terms of magnetization in the lower crust. The wavelengths of the crustal anomalies are in the range of 51–255 km and this is used to separate them from signals originating at shallow depths. Spectral analysis of these profiles provided a maximum depth of 34–41 km for the long-wavelength anomalies and 9–10 km for the shallow sources identified as Mohorovic̆ić discontinuity and the basement respectively. The magnetic “high” recorded in satellite observations over the Indian shield is interpreted as due to a bulge of 3–4 km in the Moho under the Godovari graben, with a magnetization of 200 nT in the direction of the Earth's present-day magnetic field. Similarly the magnetic lows observed over the Himalaya are interpreted in terms of thickening of the granitic part of the crust from 18 to 23.5 km with a magnetization contrast of 200 nT in the direction of the Earth's present-day magnetic field.     

Late Quaternary landscape reconstruction and geochronology in the northern Pampas of Buenos Aires province,Argentina

This paper reports the main sedimentary characteristics, soil micromorphology and optically-stimulated luminescence (OSL) ages, and details the pedosedimentary reconstruction, of the Hudson site situated in the northern Pampas of Buenos Aires province. It also provides the OSL chronology and a reinterpretation of previously reported micromorphological features for the nearby site of Gorina. Finally, the stratigraphic records of both sites are compared and the main environmental events discussed in a regional context.At Hudson, situated at a low altitude environment close to the coastal plain, the basal fine-grained paludal deposits were unconformably covered by coastal marine sediments with an OSL age of ca. 128 ka supporting its correlation with the high stand of sea level of marine isotope stage 5e. A paleosol developed on the marine deposits and the underlying paludal sediments. OSL ages suggest that soil development and its subsequent erosion occurred over some period between ca. 128 and 54 ka. Fine sediment accumulation in a paludal environment continued until prior to ca. 23 ka when the accumulation of the uppermost loess mantle started. It continued until the early Holocene when present soil development began. At Gorina, OSL ages suggest that the upper part of the pedocomplex formed at some stage between ca. 194 and 56 ka. Loess then accumulated followed by an erosional phase; loess deposition restarted by ca. 29 ka and continued until the beginning of the Holocene (ca. 9 ka) when the present land surface was established.The stratigraphic and paleoenvironmental differences exhibited by the Hudson and Gorina records result from their contrasting geomorphological settings. The OSL geochronology suggests that the last interglacial (MIS 5) at Hudson is marked by the accumulation of marine deposits (MIS 5e) and the subsequent development of a paleosol. The equivalent soil-forming interval at Gorina is represented by the upper part of the buried pedocomplex. Both at Gorina and Hudson, loess accumulation was dominant especially during MIS 2. Loess accumulation continued during MIS 1 until the early Holocene with apparently somewhat higher sedimentation rates in Hudson. Pedogenesis has been predominant during the rest of the Holocene, resulting in the formation of the surface soil profiles.     

Tracer transport in the Greenland Ice Sheet: constraints on ice cores and glacial history

The climate history and dynamics of the Greenland Ice Sheet are studied using a coupled model of the depositional provenance and transport of glacier ice, allowing simultaneous prediction of the detailed isotopic stratigraphy of ice cores at all the major Greenland sites. Adopting a novel method for reconstructing the age–depth relationship, we greatly improve the accuracy of semi-Lagrangian tracer tracking schemes and can readily incorporate an age-dependent ice rheology. The larger aim of our study is to impose new constraints on the glacial history of the Greenland Ice Sheet. Leading sources of uncertainty in the climate and dynamic history are encapsulated in a small number of parameters: the temperature and elevation isotopic sensitivities, the glacial–interglacial precipitation contrast and the effective viscosity of ice in the flow law. Comparing predicted and observed ice layering at ice core sites, we establish plausible ranges for the key model parameters, identify climate and dynamic histories that are mutually consistent and recover the past depositional elevation of ice cores to ease interpretation of their climatic records. With the coupled three-dimensional model of ice dynamics and provenance transport we propose a method to place all the ice core records on a common time scale and use discrepancies to adjust the reconstructed climate history. Analysis of simulated GRIP ice layering and borehole temperature profiles confirms that the GRIP record is sensitive to the dynamic as well as to the climatic history, but not enough to strongly limit speculation on the state of the Greenland Ice Sheet during the Eemian. In contrast, our study indicates that the Dye 3 and Camp Century ice cores are extremely sensitive to ice dynamics and greatly constrain Eemian ice sheet reconstructions. We suggest that the maximum Eemian sea-level contribution of the ice sheet was in the range of 3.5–4.5 m.     

Oxygen and carbon isotope composition of structural carbonate in weathering apatites from laterites, southern Brazil and western Senegal

The oxygen (δ¹⁸O_c) and carbon (δ¹³C_c) isotope compositions of the structural carbonate group (CO₃) in apatites from lateritic profiles were investigated. The weathering profiles, located in southern Brazil and in western Senegal, are developed on three different types of apatite-rich parent rock: carbonatite, metamorphosed marine phosphorite and sedimentary marine phosphorite. The parent rock apatites are of magmatic, hydrothermal, metamorphic and sedimentary origins. The in situ formation of apatite of weathering origin in the profiles is well documented petrographically and geochemically.The overall range of measured δ¹⁸O_c and δ¹³C_c values of apatites of weathering origin (22 to 27 SMOW for δ¹⁸O_c and −15 to −10 PDB for δ¹³C_c) is much smaller than the range of measured and/or published isotope compositions of parent rock apatites (4–35 for δ¹⁸O_c and −11 to +1 for δ¹³C_c). In any profile, the apatites of weathering origin can exhibit lower, similar or higher δ¹⁸O_c values than parent rock apatites. In contrast, their δ¹³C_c values are systematically and significantly lower than those of the parent rock apatites. Apatites formed as a result of weathering in laterites can therefore be readily distinguished from apatites of other origin on the basis of their isotope composition.Assuming that apatite CO₃ fractionates O in a way similar to calcite CO₃, the structural carbonate group of the apatites of weathering origin appears to form in approximate isotopic equilibrium with the weathering solutions. The very low δ¹³C_c values exhibited by these apatites indicate that the dominant sources of dissolved CO₂ in the soil water are organic. The isotope composition of structural carbonate in apatite of weathering origin in lateritic profiles may provide useful information for paleoenvironmental studies.     

Oxygen and hydrogen isotope geochemistry of thermal springs of the Western Cape, South Africa: Recharge at high altitude?

A number of thermal springs with temperature up to 64°C are found in the Western Cape Province of South Africa. The average δ¹³C value of gas (CO₂+CH₄) released at three springs is −22, which is consistent with an entirely biogenic origin for the C and supports previous investigations which showed that the springs are not associated with recent or nascent volcanic activity. Most springs issue from rocks of the Table Mountain Group, where faulted and highly jointed quartzites and sandstones of the Cape Fold Belt act as the main deep aquifer. The δD and δ¹⁸O values of the springs range from −46 to −18 and from −7.3 to −3.9, respectively. Although the thermal springs have isotope compositions that plot close to the local meteoric water line, their δD and δ¹⁸O values are significantly lower than ambient meteoric water or groundwater. It is, therefore, suggested that the recharge of most of the thermal springs is at a significantly higher altitude than the spring itself. The isotope ratios decrease wuth increasing distance from the west coast of South Africa, which is in part related to the continental effect. However, a negative correlation between the spring water temperature and the δ¹⁸O value in the thermal springs closest to the west coast indicates a progressive in increase in the average altitude of recharge away from the coast.     

The Greenland Ice Core Chronology 2005, 15–42 ka. Part 1: constructing the time scale

The Greenland Ice Core Chronology 2005, GICC05, is extended back to 42 ka b2k (before 2000 AD), i.e. to the end of Greenland Stadial 11. The chronology is based on independent multi-parameter counting of annual layers using comprehensive high-resolution measurements available from the North Greenland Ice Core Project, NGRIP. These are measurements of visual stratigraphy, conductivity of the solid ice, electrolytical melt water conductivity and the concentration of Na⁺, Ca²⁺, SO₄²⁻, NO₃⁻, NH₄⁺. An uncertainty estimate of the time scale is obtained from identification of ‘uncertain’ annual layers, which are counted as 0.5±0.5 years. The sum of the uncertain annual layers, the so-called maximum counting error of the presented chronology ranges from 4% in the warm interstadial periods to 7% in the cold stadials. The annual accumulation rates of the stadials and interstadials are on average one-third and half of the present day values, respectively, and the onset of the Greenland Interstadials 2, 3, and 8, based on 20 year averaged δ¹⁸O values, are determined as 23,340, 27,780, and 38,220 yr b2k in GICC05.     

Planktonic Foraminiferal and Alkenone Records of the Last Deglaciation from the Eastern Arabian Sea

The oxygen isotope record of planktonic foraminifera from tropical core MD77194 (Eastern Arabian Sea) exhibits a clear two-step deglaciation with a brief δ¹⁸O transient event. In the tropics, this δ¹⁸O maximum could correspond to a cooling or to a change in the δ¹⁸O content of sea water. In this study, past sea-surface temperature (SST) and primary production (PP) are reconstructed from foraminiferal transfer functions and compared to values estimated from alkenone measurements. SST and PP records from both proxies indicate a 1.5–2.5°C deglacial warming, coupled with a PP decrease, and a 0.5–1°C cooling during the Younger Dryas (YD). A detailed comparison between independent micropaleontological and geochemical proxies helps us identify potential biases and thus strengthen the paleo-reconstructions.     

Variations of Surface Air Temperature Over the Land Areas in and Around the Bay of Bengal

The inter-annual variation and linear trends of the surface air temperature in the regions in and around the Bay of Bengal have been studied using the time series data of monthly and annual mean temperature for 20–40 years period within 1951–1990. The study area extends from Pusma Camp of Nepal in the north and Kuala Lumpur of Malaysia in the south and between 80--100 ° E. The annual variation of temperature has also been studied using the mean monthly temperature for the variable time frames 1961–1975, 1976–1990 and 1961–1990. The trend of temperature has been analyzed using linear regression technique with the data from 1961–1990, which showed that the warming trend is dominant over the study areas except for a few stations. It has been found that Nepal shows predominant warming trends. Bangladesh and the adjacent areas of India and the northern part of Bay of Bengal adjacent to the Bangladesh coast have shown strong warming trends of the annual temperature with maximum at Dhaka (0.037 °C/year). The near equatorial zone, i.e., southern India, Sri Lanka and part of Thailand and Malaysia (Kuala Lumpur) shows warming trends in the annual mean temperature with strong warming at Pamban and Anuradhapura (around 0.04 °C/year). The cooling trends have been observed at a few stations including Port Blair, Yangoon and Cuttack. Further analysis shows the presence of prominent ENSO scale of variations with time period 4–7 years and 2–3 years for almost all the stations. The decadal mode with T >7 years is present in some data series. The results of the variations of temperature with respect to the Southern Oscillation Index (SOI) show that SOI has some negative correlation with temperature for most of the stations except those in the extreme northeast. It has been found that positive anomaly of temperature has been observed for El Niño events and negative anomaly for the La Nina events.     

Reflection of the orographic patterns in the micro- and mesoclimatic conditions

In the Polish Carpathian Mountains two altitudinal profiles were chosen. Ranging from 200 to 1,000 m asl along 20°00 and 21°30E their spatial patterns of the topographical types in the mountains and uplands, geometric configuration of concave topographies and direction of their course are different.The effects of topography on the mesoclimatic conditions in the area investigated were analyzed by the diurnal air temperature records at the 28 meteorological stations in the years 1951 – 1970. Along the two profiles, taking the points situated at the same height asl and similar altitude, the mean extreme temperatures in the particular months, as well as the values of the first and ninth deciles of the maximum and minimum temperatures were analyzed. Special consideration was given to the spatial distribution of the minimum temperature and characteristics derived, because it reflects the influence of topography in a higher degree than the maximum temperature. Since low air temperatures are the main factor for the plant growth in the Polish Carpathians, spatial differentiation of the minimum temperature regulates the rate of development of the wild and cultivated plants during the growing season.     

Experimental shear zones and magnetic fabrics

Magnetic fabric analysis has been used as a non-destructive means of detecting petrofabric development during experimentally produced multi-stage, transpressive deformations in ‘shear zones’. Artificial, magnetic-bearing silicate sands and calcite sands, bonded with Portland cement, were deformed at room temperature and at 100 and 150 MPa confining pressure. The slip-rate for the shear zone walls was 0.73 × 10⁻⁴ mm s⁻¹ and the maximum shear strains were about 0.38, across zones that were initially about 5 mm thick. The magnetic fabric ellipsoid rapidly spins so that the maximum and intermediate susceptibilities tend to become parallel to the shear zone walls throughout the sheared zone. The ellipsoid becomes increasingly oblate with progressive deformation. However, in all cases, the anisotropy is strongly influenced by the pre-deformation magnetic fabric. During deformation the cement gel collapses so that cataclasis of the mineral grains is suppressed. In the quartz-feldspar aggregates the magnetite's alignment is accommodated by particulate flow (intergranular displacements) of the grains. In the calcite aggregates stronger magnetic fabrics develop due to plastic deformation of calcite grains as well as particulate flow. However, the calcite grain fabrics are somewhat linear (L ≥ S) whereas the magnetic fabrics are planar (S >L). The preferred dimensional orientations of magnetite are weak and it is possible that the magnetic fabrics are due to intragranular rearrangements of magnetic domains.The transpressive shear zones are much more efficient than axial-symmetric shortening in the increase of anisotropy of the magnetic fabrics, especially in the case of the calcite aggregates. This suggests that flow laws derived for axial-symmetric shortening experiments may not be appropriate for non-coaxial strain histories such as those of shear zones.     

Chemistry of rainwaters in the south Pacific area of Russia

On the south-eastern edge of Russia, the chemical composition of rainwater is controlled by sea salts, terrestrial material, as well as volcanic (Kuril islands volcanic area) and anthropogenic emissions, mostly in the southern part of the area. The predominant major ions of the Primorye, Sakhalin and the Kuril Islands rainwaters were respectively HCO₃⁻–SO₄²⁻, Ca–Na, and of Cl–Na. Concentration of trace elements changes within 1–2 orders of magnitude but some difference in the distribution of the elements between continental and island rainwater is found. The concentration of the chemical elements in the particulate fraction varies from < 10% to 90% of the total concentration (dissolved + particulate) with the following distribution: Tl, Na, Ca, Sr, Zn, Cd (< 10%)–Be, Th, Bi, Rb, U, K, Sc (10–20%)–Cu, Mn, Mg, Mo, Se, Ba, Ni, As, Ag, Cs, Co, Y, Ga, V (20–50%)–Sb, Pb, Ge, Cr, Fe, Al (50–90%).The concentration of elements of the particulate fraction of the rainwater usually is significantly different from concentrations in the crust, including both higher and lower concentrations. The terrestrial contribution to dissolved elements was evaluated and follows the decreasing order: Fe > K, Mg, Ca > Ba, Sr > Na (65–1%). Close order was found for total (dissolved and solid) concentrations. Sea salt contribution to dissolved element concentration in the rainwater decrease in the following order: Cl, Mg > K, SO₄ > Ca > HCO₃⁻, Ba, Fe (78–0.1%). Calculation of anthropogenic and volcanic inputs for two ions (Cl⁻ and SO₄²⁻) shows that anthropogenic inputs for the Vladivostok and Yuzno-Sakhalinsk cities can be evaluated as 15–20% of Cl⁻ and up to 80–90% of SO₄²⁻. Volcanic components in the Kuril Islands, where anthropogenic inputs are absent, can reach up to 76% of SO₄²⁻ and 36% of Cl⁻.