土壤粒径的光谱响应特性研究

以实验室制备的5个不同粒径水平的土壤样本和室内高光谱数据为基础,通过对光谱数据进行重采样、数学变换等预处理并进行单因素方差分析、相关性分析和回归分析,探讨土壤粒径的高光谱特性,建立了光谱数据预测土壤粒径的校正模型。结果表明,土壤粒径对反射光谱有显著的影响,波长越长影响越大;在全波段范围内土壤粒径和光谱数据都呈负相关关系,对原始光谱数据进行微分变换能增加其与土壤粒径的相关性;以反射率一阶微分建立的回归模型为反演土壤粒径的最佳模型,其建模决定系数■、预测决定系数■、预测相对偏差RPD分别为0.666,0.653,2.043,预测均方根误差RMSE为0.175。     

基于小波与包络线的土壤有机质高光谱估测

以陕西省横山县为研究区,对小波分析法与包络线去除法融合应用于土壤有机质高光谱估测的有效性进行了探究。利用陕西省横山县84个土壤样本的光谱反射率和有机质含量数据,采用小波分析法去除了部分噪声,通过光谱一阶微分变换,提高光谱反射率与有机质的相关性,采用包络线去除法提取建模因子,减少数据冗余后最终采用回归分析法建立土壤有机质的估测模型。结果表明,与未采用小波分析法建立的模型比较,建模因子的相关性提高了0.1~0.25,模型的判定系数可达0.932,提高了0.207,检验样本的均方根误差RMSE为0.107,减小了0.116。总体而言,小波分析与包络线去除法联合应用于土壤有机质高光谱估测是有效的且所建模型精度较高,但数据质量对模型精度有重要影响。     

一种考虑雪粒径变化的积雪面积反演算法

光谱混合分析能够提取亚像元信息,被广泛地应用于遥感影像目标探测之中。本文针对MODIS积雪遥感影像,基于光谱混合分析框架,利用渐进辐射传输模型建立不同粒径大小的雪反射率光谱库,提出了一种考虑端元变化及二次辐射的雪盖面积反演算法。此算法首先利用渐进辐射传输模型建立不同粒径大小积雪的反射率光谱库,然后使用序贯最大角凸锥方法获取植被、土壤与岩石、阴影的光谱库。在建立各种地物反射率光谱库之后,利用均方根误差最小的方法获取最优端元组合。在此基础上,考虑端元独立辐射以及积雪与其它地物的二次辐射过程,利用稀疏光谱混合模型获取积雪面积与雪粒径大小。实验结果表明：此方法能够同时反演雪粒径与积雪面积,反演的雪粒径相比单波段的渐进辐射传输模型小,反演的积雪面积相比MOD10A1产品精度略微提高。     

潮滩表层沉积物含水量的高光谱预测模型与反演分析

潮滩土壤含水量具有变化频率快、空间变化大的特征,是影响潮滩地表反射率的重要因素。潮滩土壤含水量的精确提取,可为潮滩特征地物信息遥感反演提供基础。本文利用江苏大丰王港潮滩4种典型沉积物、449组不同含水量对应的实测光谱曲线数据进行特征分析,构建高光谱预测模型,实现了潮滩沉积物含水量的遥感反演。研究结果表明:(1)在短波红外波段,沉积物含水量与反射率之间存在良好的分段线性相关关系,分段点对应的含水量分别为42%和62%;(2)1165nm、1336nm、1568nm和1780nm特征波段反射率,对含水量变化具有良好响应,由特征波段组合计算得到的差值水指数DWI、比值水指数RWI和归一化水指数NDWI与含水量呈显著线性相关,可有效改善单波段反射率与含水量之间的分段线性关系;(3)3个水指数中,DWI反演的含水量精度优于RWI和NDWI,且对不同含水量大小均有良好适应性,而RWI和NDWI更适合含水量变化范围中等的情况;(4)对于粉砂、砂质粉砂、粉砂质砂和砂4种沉积物类型,DWI1336,1780验证组模拟含水量与实测含水量的相关系数,分别为0.891、0.915、0.920和0.905,均方根误差分别为9.87%、3.56%、4.24%和2.98%,表明由DWI构建的高光谱遥感反演模型,可有效实现潮滩表层含水量的时空变化预测。     

湛江港海域叶绿素a浓度的高光谱遥感反演

基于表观光学法研究冬季湛江港海域高光谱遥感叶绿素a浓度的反演模型构建,结果表明,该海域单波段遥感反射率与叶绿素a浓度相关性低,波段比值和遥感反射率的一阶微分法可提高叶绿素a浓度反演精度。665nm处的遥感反射率一阶微分值与叶绿素a浓度相关性良好,相关系数可达0.84。一阶微分相关系数大于0.8的波段大部分处于叶绿素a红光强烈吸收区域,对于富营养化的湛江港海域采用一阶微分方法构建叶绿素a浓度的遥感反演模型具有合理性。     

基于土壤重金属含量指数变化的冠层光谱遥感分析

为提高水稻冠层光谱反演水稻田土壤重金属含量的精度,针对实测土壤重金属含量进行信息提取研究,对其分别进行了对数变换、最大值变换和Box-cox变换。在实验分析中,为得到土壤重金属(Cu、Pb、Cd)反演模型,将土壤重金属及其变换数据与冠层光谱及其变换后的数据进行偏最小二乘回归分析,并分析所得模型精度和稳定性。分析结果表明,对测定重金属数据进行变换能够普遍提高模型的精度与稳定性;对属重度污染重金属Pb和中度污染重金属Cd有较好的预测结果,而对未形成污染的Cu则难以形成有效的预测分析。其成果对耕地土壤重金属含量监测评价具有重要的参考价值。     

变换光谱数据对土壤氮素PLSR模型的影响研究

光谱数据变换对消除背景、噪音影响以及提取光谱特征有重要的作用,是光谱数据分析过程中的必要步骤。为了研究光谱变换处理对土壤氮素PLSR模型的影响精度,并选择最佳光谱变换处理方法,本文对原始光谱数据进行了15种典型光谱变换,通过比较不同变换光谱与土壤氮素的相关性,实现土壤氮素的PLSR精确诊断,并综合评定最佳光谱数据变换方法。结果表明,涉及微分处理后的光谱变换,尤其是先进行开方（T₈、T₁₁）、对数（T₆、T₁₂）等变换后再进行微分处理,可提高其与土壤氮素的相关性。在引入较少因子变量个数的条件下,该方法使因变量解释量达到了98%。综合考虑模型的校正、验证效果及模型复杂度（模型最佳因子变量个数）,可得出光谱平方根的一阶微分变换处理（T₈）为最佳的土壤光谱变换算法。该条件下的土壤氮素的校正模型表现为R²=0.985、RMSE_C=0.000132、F_n=6,验证模型的表现为R²=0.9853、RMSE_V=0.000162,结果表明基于T₈的光谱数据变换可实现本试验条件下土壤氮素的光谱估算。另外,可以考虑将原始光谱的一阶微分（T₉）、对数和对数倒数的一阶微分（T₆、T₇）以及平方根和对数的二阶微分（T₁₁、T₁₂）作为光谱数据变换方法。本文研究结果可为土壤氮素估算和光谱数据预处理提供技术参考。     

南方红壤侵蚀区长汀县不同生态恢复年限下芒萁叶绿素含量的高光谱估算模型

芒萁是南方红壤侵蚀区生态恢复重要的地带性草本植物,对生态系统修复具有重要作用,监测其叶绿素含量能有效诊断生长健康状况。本文以福建省长汀县朱溪流域6个不同生态恢复年限下的芒萁叶片高光谱反射数据以及实测叶绿素含量为数据源,借助高光谱遥感技术分析不同恢复年限芒萁叶片原始光谱特征,筛选出光谱敏感波段并构建光谱指数,基于相关性分析,建立芒萁叶绿素单变量以及多元逐步回归模型,并确定最佳估算模型。结果表明：高光谱指数建立的单变量估算模型中,改进红边归一化植被指数（mNDVI₇₀₅）、叶面叶绿素指数（LCI）、红边指数（Vog）、比值光谱指数（RVI_603/407）、NDVI[603,407]高光谱指数建立的二次模型精度高,建模决定系数R²均超过了0.8,其中以高光谱指数为自变量建立的多元回归模型拟合R²值（0.886）最高。综合建模精度和模型验证精度,LCI指数构建的单变量模型以及基于高光谱指数的多元回归模型是估算芒萁叶片叶绿素含量最佳模型。本研究建立的叶绿素高光谱估算模型对快速、无损地监测水保植物芒萁生长具有重要意义。     

基于几何光学模型的人工林叶面积指数遥感反演

 MODIS等全球叶面积指数(LAI)产品空间分辨率偏低(250m~7km),不能满足高空间分辨率遥感应用的需求。为获取大区域高空间分辨率LAI,有必要对物理模型用于高空间分辨率遥感影像LAI反演的可行性进行探讨。本文基于4-scale模型LAI反演算法,以甘肃省张掖为研究区,利用TM 影像实现研究区人工林LAI反演。反演算法考虑了反射率入射-观测角度对LAI与植被指数关系的影响和植被冠层尺度的集聚程度。利用地面实测LAI数据对反演结果进行验证与分析,并与NDVI经验模型进行对比,同时分析LAI反演结果对波段反射率敏感性。结果表明: 4-scale模型LAI反演结果与实测LAI一致性良好(R²=0.67,RMSE=0.50),且优于NDVI经验模型(R²=0.59,RMSE=0.67);当LAI大于2时,4-scale模型LAI反演算法误差小于NDVI经验模型,能有效避免植被指数的饱和现象;红光波段反射率减小时,引起4-scale模型LAI反演结果的变化幅度比其增大时更高,且影响程度大于近红外波段反射率。研究表明,4-scale 模型LAI反演算法可用于TM数据反演人工林LAI,模型应用普适性较强。     

粤西海域总氮遥感反演初探

总氮质量浓度是衡量水环境的主要指标之一。以粤西海域为研究对象,将实测的总氮质量浓度和水体高光谱遥感反射率数据进行回归分析处理,结果表明:无论是单波段,还是波段因子,总氮质量浓度与水体高光谱遥感反射率的相关性仅达到0.593;研究区域的总氮和悬浮物具有较好的相关性,相关系数最高可以达到0.76。通过悬浮物间接的遥感监测粤西海域的总氮是一个有效的途径。     

Combining Environmental Factors and Lab VNIR Spectral Data to Predict SOM by Geospatial Techniques

Soil organic matter(SOM) is an important parameter related to soil nutrient and miscellaneous ecosystem services. This paper attempts to improve the performance of traditional partial least square regression(PLSR) model by considering the spatial autocorrelation and soil forming factors. Surface soil samples(n = 180) were collected from Honghu City located in the middle of Jianghan Plain, China. The visible and near infrared(VNIR) spectra and six environmental factors(elevation, land use types, roughness, relief amplitude, enhanced vegetation index, and land surface water index) were used as the auxiliary variables to construct the multiple linear regression(MLR), PLSR and geographically weighted regression(GWR) models. Results showed that: 1) the VNIR spectra can increase about 39.62% prediction accuracy than the environmental factors in predicting SOM; 2) the comprehensive variables of VNIR spectra and the environmental factors can improve about 5.78% and 44.90% relative to soil spectral models and soil environmental models, respectively; 3) the spatial model(GWR) can improve about 3.28% accuracy than MLR and PLSR. Our results suggest that the combination of spectral reflectance and the environmental variables can be used as the suitable auxiliary variables in predicting SOM, and GWR is a promising model for predicting soil properties.     

Estimating purple-soil moisture content using Vis-NIR spectroscopy

Soil moisture is essential for plant growth in terrestrial ecosystems. This study investigated the visible-near infrared(Vis-NIR) spectra of three subgroups of purple soils(calcareous, neutral, and acidic) from western Chongqing, China, containing different water contents. The relationship between soil moisture and spectral reflectivity(R) was analyzed using four spectral transformations, and estimation models were established for estimating the soil moisture content(SMC) of purple soil based on stepwise multiple linear regression(SMLR) and partial least squares regression(PLSR). We found that soil spectra were similar for different moisture contents, with reflectivity decreasing with increasing moisture content and following the order neutral calcareous acidic purple soil(at constant moisture content). Three of the four spectral transformations can highlight spectral sensitivity to SMC and significantly improve the correlation between the reflectance spectra and SMC. SMLR and PLSRmethods provide similar prediction accuracy. The PLSR-based model using a first-order reflectivity differential(R ?) is more effective for estimating the SMC, and gave coefficient of determination(v2), root mean square errors of validation(RMSEV), and ratio of performance to inter-quartile distance(RPIQ)values of 0.946, 1.347, and 6.328, respectively, for the calcareous purple soil, and 0.944, 1.818, and 6.569,respectively, for the acidic purple soil. For neutral purple soil, the best prediction was obtained using the SMLR method with R ? transformation, yieldingv2,RMSEV and RPIQ values of 0.973, 0.888 and 8.791,respectively. In general, PLSR is more suitable than SMLR for estimating the SMC of purple soil.     

Carbonates and organic matter in soils characterized by reflected energy from 350-25000 nm wavelength

The soil carbon pool which is the sum of soil organic carbon(SOC) and soil inorganic carbon(SIC) is the second largest active store of carbon after the oceans and it is an important component of the global carbon cycle. Hence, accurate estimation of SOC and SIC as important carbon reservoirs in terrestrial ecosystems using fast, inexpensive and non-destructive methods is crucial for planning different climate change policies. The aim of the current research was to examine the effectiveness of Vis-NIR(visible and near-infrared spectroscopy: 350-2500 nm) and MIR(mid-infrared spectroscopy: 4000-400 cm~(-1)) to characterize and estimate soil organic matter(SOM) and carbonates as main components of soil carbon stocks in Juneqan, Charmahal va Bakhtiari, Iran. To do so, a total of 548 soil samples from this area were collected(October 2015) and analyzed in laboratory(August 2017). In order to develop models capable of predicting SOM and carbonates content, seven spectral preprocessing methods comprising Absorbance(Abs), De-trending(Det), Continuum removal(CR), Savitzky-Golay derivatives(SGD), standard normal variate transformation(SNV), multiplicative scatter correction(MSC) and Normalization by range(NBR) were conducted along with five multivariate methods including Random Forest(RF), Partial Least-Squares Regression(PLSR), Artificial Neural Network(ANN), Support Vector Machine(SVM) and Gaussian Process Regression(GPR). The content of carbonates caused spectral reflectance intensity to augment on several ranges of spectrum and strong absorption feature at 2338 nm in the Vis-NIR and 714, 850, 870, 1796, 2150 and 2510 cm~(-1) in the MIR spectra range. SOM absorbed energy in several ranges, but also showed specific peaks in MIR. Both facts are associated with the structure of carbonates and SOM and its interaction with energy. The best combination of preprocessing and calibration models for carbonates quantification in Vis-NIR spectra was Det/PLSR(R~2= 0.74, RPD= 2.19, RMSE= 6.45). For SOM, it was Det/PLSR(R~2= 0.82, RPD= 2.41, RMSE= 0.75). The Det/RF(R~2= 0.87, RPD= 2.44, RMSE= 0.66) for the quantification of SOM and MSC/RF(R~2= 0.84, RPD= 2.84, RMSE= 5.50) for carbonates in MIR spectra range showed the greatest results. The stronger occurrence of spectral bands in MIR as well as the specificity of the absorption features indicated that this range produced better predictions. The obtained results highlighted the significant role of soil spectroscopy technique in predicting SOC and soil carbonates as key components of soil carbon stocks in the study area. Therefore, this technique can be used as a more cost-effective, time saving and nondestructive alternative to traditional methods of soil analysis.     

Spectral response of different eroded soils in subtropical china: A case study in Changting County,China

Hyper-spectral data is widely used to determine soil properties. However, few studies have explored the soil spectral characteristics as response to soil erosion. This study analysed the spectral response of different eroded soils in subtropical China, and then identify the spectral characteristics and soil properties that better discriminate softs with different erosion degrees. Two methods were compared： direct identification by inherent spectral characteristics and indirect identification by predictions of critical soft properties. Results showed that the spectral curves for different degrees of erosion were similar in morphology, while overall reflectance and characteristics of specific absorption peaks were different. When the first method is applied, some differences among different eroded groups were found by integration of associated indicators. However, the index of such indicators showed apparent mixing and crossover among different groups, which reduced the accuracy of identification. For the second method, the correlation between critical soil properties, such as soil organic matter （SOM）, iron and aluminium oxides and reflectance spectra, was analysed. The correlation coefficients for the moderate eroded group were primarily between -0.3 to -0.5, which were worse than the other twogroups. However, the maximum value of R2 was obtained as 0.86 and 0.94 for the non-apparent eroded and the severe group. Furthermore, these two groups also showed some differences in the spectral response of iron complex state （Fep）, Aluminium amorphous state （Alo） and the modelling results for soil organic matter （SOM）. The study proved that it is feasible to identify different degrees of soil erosion by hyperspectral data, and that indirect identification by modelling critical soil properties and reflectance spectra is much better than direct identification. These results indicate that hyper-spectral data may represent a promising tool in monitoring and modelling soil erosion.     

Molecular Fingerprints of Soil Organic Matter in a Typical Freshwater Wetland in Northeast China

Natural wetlands are known to store huge amounts of organic carbon in their soils. Despite the importance of this storage,uncertainties remain about the molecular characteristics of soil organic matter(SOM), a key factor governing the stability of soil organic carbon(SOC). In this study, the molecular fingerprints of SOM in a typical freshwater wetland in Northeast China were investigated using pyrolysis gas-chromatography/mass-spectrometry technology(Py-GC/MS). Results indicated that the SOC, total nitrogen(TN),and total sulfur contents of the cores varied between 16.88% and 45.83%, 0.93% and 2.82%, and 1.09% and 3.79%, respectively. The bulk δ^13C and δ^15N varied over a range of 9.85‰, between –26.85‰ and –17.00‰, and between –0.126‰ and 1.002‰, respectively. A total of 134 different pyrolytic products were identified, and they were grouped into alkyl(including n-alkanes(C:0) and n-alkenes(C:1),aliphatics(Al), aromatics(Ar), lignin(Lg), nitrogen-containing compounds(Nc), polycyclic aromatic hydrocarbons(PAHs), phenols(Phs), polysaccharides(Ps), and sulfur-containing compounds(Sc). On average, Phs moieties accounted for roughly 24.11% peak areas of the total pyrolysis products, followed by Lg(19.27%), alkyl(18.96%), other aliphatics(12.39%), Nc compounds(8.08%), Ps(6.49%), aromatics(6.32%), Sc(3.26%), and PAHs(1.12%). Soil organic matter from wetlands had more Phs and Lg and less Nc moieties in pyrolytic products than soil organic matters from forests, lake sediments, pastures, and farmland.δ^13 C distribution patterns implied more C3 plant-derived soil organic matter, but the vegetation was in succession to C4 plant from C3 plant. Significant negative correlations between Lg or Ps proportions and C3 plant proportions were observed. Multiple linear analyses implied that the Ar and Al components had negative effects on SOC. Alkyl and Ar could facilitate ratios between SOC and total nitrogen(C/N), while Al plays the opposite role. Al was positively related to the ratio of dissolved organic carbon(DOC) to SOC. In summary, SOM of wetlands might characterize by more Phs and lignin and less Nc moieties in pyrolytic products. The use of Pyrolysis gas-chromatography/mass-spectrometry(Py-GC/MS) technology provided detailed information on the molecular characteristics of SOM from a typical freshwater wetland.     

水稻土有机碳密度的空间预测分析——以浙江省长兴县为例

准确预测未采样区域SOC密度,是研究SOC演变趋势和探索土壤固碳作用对缓解全球气候变化的基础。采用泛克里格法(Universal Kriging,UK)和土壤类型法(pedological professional knowledge-based method,PKB),分别对长兴县水稻土有机碳密度进行了预测,其中,UK直接以长兴水稻土剖面资料为源数据、PKB以长兴水稻土剖面数据和长兴1∶5万数字土壤图为源数据进行预测。根据平均绝对误差(MAE)及均方根误差(RMSE)大小,评价了两种方法在县域尺度土壤有机碳密度空间预测效果。结果表明:UK的MAE(31.2)、RMSE(52.5)均大于PKB的MAE(24.7)、RMSE(43.1),说明PKB法的预测效果较好,UK法相对较差。研究表明,对土壤类型、土壤母质,以及剖面点位置等信息的综合考虑能使PKB法更好地表达土壤属性的空间特征,也更适于县域尺度土壤有机碳密度的空间预测。     

稀疏格网样点的国家尺度土壤属性制图方法与应用

 国家尺度土壤属性数据是地球生物化学循环及水循环等领域研究的重要数据,目前,该尺度土壤属性数据的获取方法主要有两类:土壤属性-空间数据连接法和空间插值。为了确定哪一类方法更适合稀疏样点的国家尺度土壤属性制图,本文以中国吉林省的土壤有机质含量制图为例,采用8~32km格网样点和1∶100万土壤图,对这两类方法进行对比分析。独立样本验证结果表明,土壤属性-空间数据连接法的平均误差(ME)大于距离反比加权(IDW)插值,而平均绝对误差(MAE)和均方根误差(RMSE)都小于IDW插值。IDW插值获得的土壤属性图虽然能大致反映土壤属性空间分布的基本规律,但出现了类似"牛眼睛"的空间结构,且存在无样点区估计值不准确等问题;土壤属性-空间数据连接法尽管忽略了同种土壤类型内部的差异,保留了不同土壤类型边界处的属性值突变,但获得的土壤属性图更能反映土壤属性分布的基本规律,也具有比较详细的土壤属性空间结构。因此,在基于稀疏样点的国家尺度土壤属性制图中,土壤属性-空间数据连接法的制图效果要优于IDW空间插值法。