Spatial and Temporal Variability of the CO2 Fluxes in a Tropical, Highly Urbanized Estuary

The spatial and temporal variations of the flux of CO₂ were determined during 2007 in the Recife estuarine system (RES), a tropical estuary that receives anthropogenic loads from one of the most populated and industrialized areas of the Brazilian coast. The RES acts as a source of nutrients (N and P) for coastal waters. The calculated CO₂ fluxes indicate that the upstream inputs of CO₂ from the rivers are largely responsible for the net annual CO₂ emission to the atmosphere of +30 to +48 mmol m^?2 day^?1, depending on the CO₂ exchange calculation used, which mainly occurs during the late austral winter and early summer. The observed inverse relationship between the CO₂ flux and the net ecosystem production (NEP) indicates the high heterotrophy of the system (except for the months of November and December). The NEP varies between ?33 mmol m^?2 day^?1 in summer and ?246 mmol m^?2 day^?1 in winter. The pCO₂ values were permanently high during the study period (average ~4,700 μatm) showing a gradient between the inner (12,900 μatm) and lower (389 μatm) sections on a path of approximately 30 km. This reflects a state of permanent pollution in the basin due to the upstream loading of untreated domestic effluents (N/P?=?1,367:6 μmol kg^?1 and pH?=?6.9 in the inner section), resulting in the continuous mineralization of organic material by heterotrophic organisms and thereby increasing the dissolved CO₂ in estuarine waters.     

Flocculation Potential of Estuarine Particles: The Importance of Environmental Factors and of the Spatial and Seasonal Variability of Suspended Particulate Matter

Estuarine systems are complex environments where seasonal and spatial variations occur in concentrations of suspended particulate matter, in primary constituents, and in organic matter content. This study investigated in the laboratory the flocculation potential of estuarine-suspended particulate matter throughout the year in order to better identify the controlling factors and their hierarchy. Kinetic experiments were performed in the lab with a “video in lab” device, based on a jar test technique, using suspended sediments sampled every 2 months over a 14-month period at three stations in the Seine estuary (France). These sampling stations are representative of (1) the upper estuary, dominated by freshwater, and (2) the middle estuary, characterized by a strong salinity gradient and the presence of an estuarine turbidity maximum. Experiments were performed at a constant low turbulent shear stress characteristic of slack water periods (i.e., a Kolmogorov microscale >1,000 μm). Flocculation processes were estimated using three parameters: flocculation efficiency, flocculation speed, and flocculation time. Results showed that the flocculation that occurred at the three stations was mainly influenced by the concentration of the suspended particulate matter: maximum floc size was observed for concentrations above 0.1 g l⁻¹ while no flocculation was observed for concentrations below 0.004 g l⁻¹. Diatom blooms strongly enhanced flocculation speed and, to a lesser extent, flocculation efficiency. During this period, the maximum flocculation speed of 6 μm min⁻¹ corresponded to a flocculation time of less than 20 min. Salinity did not appear to automatically enhance flocculation, which depended on the constituents of suspended sediments and on the content and concentration of organic matter. Examination of the variability of 2D fractal dimension during flocculation experiments revealed restructuring of flocs during aggregation. This was observed as a rapid decrease in the floc fractal dimension from 2 to 1.4 during the first minutes of the flocculation stage, followed by a slight increase up to 1.8. Deflocculation experiments enabled determination of the influence of turbulent structures on flocculation processes and confirmed that turbulent intensity is one of the main determining factors of maximum floc size.     

Temporal and Spatial Dynamics of Estuarine Shoreline Change in the Albemarle-Pamlico Estuarine System,North Carolina,USA

Many shoreline studies rely on historical change rates determined from aerial imagery decades to over 50 years apart to predict shoreline position and determine setback distances for coastal structures. These studies may not illustrate the coastal impacts of short-duration but potentially high-impact storm events. In this study, shoreline change rates (SCRs) are quantified at five different sites ranging from marsh to sediment bank shorelines around the Albemarle-Pamlico estuarine system (APES) for a series of historical (decadal to 50-year) and short-term (bimonthly) time periods as well as for individual storm events. Long-term (historical) SCRs of approximately ?0.5 ± 0.07 m year^?1 are observed, consistent with previous work along estuarine shorelines in North Carolina. Short-term SCRs are highly variable, both spatially and temporally, and ranged from 15.8 ± 7.5 to ?19.3 ± 11.5 m year^?1 at one of the study sites. The influence of wave climate on the spatial and temporal variability of short-term erosion rates is investigated using meteorological observations and coupled hydrodynamic (Delft3D) and wave (SWAN) models. The models are applied to simulate hourly variability in the surface waves and water levels. The results indicate that in the fetch-limited APES, wind direction strongly influences the wave climate at the study sites. The wave height also has an influence on short-term SCRs as determined from the wave simulations for individual meteorological events, but no statistical correlation is found for wave height and SCRs over the long term. Despite the significantly higher rates of shoreline erosion over short time periods and from individual events like hurricanes, the cumulative impact over long time periods is low. Therefore, while the short-term response of these shorelines to episodic forcing should be taken into account in management plans, the long-term trends commonly used in ocean shoreline management can also be used to determine erosion setbacks on estuarine shorelines.     

The Response of Macrobenthic Communities to Environmental Variability in Tropical Coastal Waters

The relative contributions of spatial and temporal fluctuations are different in shaping natural communities in a tropical coastal/estuarine system. Understanding how coastal communities respond to these fluctuations is still equivocal, and thus, available data are rare. Here, multiple analytical approaches were used to identify key spatial and temporal factors, and to quantify their relative roles in shaping a macrobenthic community through space (contamination degree, physical parameters, and sediment characteristics) and time (climatic factors, season, and year). A dataset of eight sampling times was analyzed over a period of 2 years, in which macrobenthic species abundances were sampled. A total of 33 species were identified, including 18 bivalves, 5 gastropods, and 4 crustaceans. The other taxa were less diverse. The results show that there were no significant temporal changes of macrobenthic community structure, but spatial changes were significant and synchronized with environmental factors (i.e., sediment characteristics, water depth, and the distance from anthropogenic sources). This study demonstrates that spatial factors played a primary role in structuring of macrobenthic assemblages, whereas the influence of temporal factors appeared less across geographically distinct sites. Thus, temporal variation of a coastal macrobenthic community appears to be controlled by partly different processes at different scales.     

Temporal and Spatial Dynamics of Diel-Cycling Hypoxia in Estuarine Tributaries

The distribution and intensity of hypoxia (low dissolved oxygen) in estuaries is increasing worldwide due to cultural eutrophication. This study quantifies the strength of associations between the duration of diel-cycling severe hypoxia (≤2 mg O₂ l⁻¹) in bottom water (∼15 cm above bottom) of a shallow (<2 m) coastal lagoon estuary (Delaware, USA) and abiotic environmental variables (water temperature, insolation, tide, streamflow, and wind) and predicts the duration of severe hypoxia given different combinations of these variables. The intensity and spatial extent and dynamics of diel-cycling severe hypoxia events were defined. Vertical variability in dissolved oxygen (DO) concentration during the daytime was also determined. During the summers of 2001–2005, bottom DO data were collected for periods of weeks to months at multiple sites using automated sondes. Multiple linear regression (MLR) and regression tree analysis (RTA) were used to determine the relative importance of the environmental variables in predicting the number of hours of severe hypoxia per day. Key findings of the study were that severe hypoxia events of minutes to hours in duration occurred frequently in all four tributaries sampled, primarily between 0200 and 1000 hours. Severe hypoxia duration and diel-cycling amplitudes of DO concentration increased in the up-tributary direction. Hierarchically, the duration of severe hypoxia was influenced mostly by the mean daily water temperature, then by preceding days’ total insolation, percentage of morning hours (02:00 to 10:00 a.m.) ebb tide, and daily streamflow. Collectively, the variables examined by the MLR and the RTA approaches accounted for 62% and 65% of the variability in the duration of severe hypoxia, respectively. RTA demonstrated that daily mean water temperature above 26.3°C and previous day’s total insolation below 13.6 kW m⁻² were associated with the longest lasting severe hypoxic events (9.56 h). The environmental variables and combinations of conditions that modulate or augment diel-cycling hypoxia presented in this paper enhance understanding of this widespread and growing phenomenon and provide additional insight regarding the extent to which it can impact food webs in very shallow estuarine waters that often serve as nursery habitat.     

Multiple Factors driving Variability of CO2 Exchange Between the Ocean and Atmosphere in a Tropical Coral Reef Environment

In this paper, we present the results of the first automated continuous multi-year high temporal frequency study of CO₂ dynamics in a coastal coral reef ecosystem. The data cover 2.5?years of nearly continuous operation of the CRIMP-CO₂ buoy spanning particularly wet and dry seasons in southern Kaneohe Bay, a semi-enclosed tropical coral reef ecosystem in Hawaii. We interpret our observational results in the context of how rapidly changing physical and biogeochemical conditions affect the pCO₂ of surface waters and the magnitude and direction of air–sea exchange of CO₂. Local climatic forcing strongly affects the biogeochemistry, water column properties, and gas exchange between the ocean and atmosphere in Kaneohe Bay. Rainfall driven by trade winds and other localized storms generates pulses of nutrient-rich water, which exert a strong control on primary productivity and impact carbon cycling in the water column of the bay. The “La Ni?a” winter of 2005–2006 was one of the wettest winters in Hawaii in 30?years and contrasted sharply with preceding and subsequent drier winter seasons. In addition, short-term variability in physical forcing adds complexity and helps drive the response of the CO₂–carbonic acid system of the bay. Freshwater pulses to Kaneohe Bay provide nutrient subsidies to bay waters, relieving the normal nitrogen limitation of this system and driving phytoplankton productivity. Seawater pCO₂ responds to the blooms as well as to physical forcing mechanisms, leading to a relatively wide range of pCO₂ in seawater from about 250 to 650?μatm, depending on conditions. Large drawdowns in pCO₂ following storms occasionally cause bay waters to switch from being a source of CO₂ to the atmosphere to being a sink. Yet, during our study period, the southern sector of Kaneohe Bay remained a net source of CO₂ to the atmosphere on an annualized basis. The integrated net annual flux of CO₂ from the bay to the atmosphere varied between years by a factor of more than two and was lower during the wet “La Ni?a” year, than during the following year. Over the study period, the net annualized flux was 1.80?mol?C?m^?2?year^?1. Our CO₂ flux estimates are consistent with prior synoptic work in Kaneohe Bay and with estimates in other tropical coral reef ecosystems studied to date. The high degree of climatological, physical, and biogeochemical variability observed in this study suggests that automated high-frequency observations are needed to capture the short-, intermediate-, and long-term variability of CO₂ and other properties of these highly dynamic coastal coral reef ecosystems.     

Comprehensive Analysis of Fish Assemblages in Relation to Seasonal Environmental Variables in an Estuarine River of Indian Sundarbans

Fish distribution in relation to environmental variables was investigated in the Matla River of Sundarban estuarine system. A total of 64 brackish water species belonging to 38 families showing tropical and subtropical affinities were obtained upon monthly sampling of 1 year. The most abundant species were Harpadon nehereus, Gudusia chapra, Coilia neglecta, Coilia ramcarati and Liza parsia. Fish assemblages showed significant seasonal variation as was revealed from MANOVA. MDS ordination plot based on similarity in the fish assemblages revealed that premonsoonal season was distinguishable from the monsoonal and postmonsoonal seasons. Notable differences were also evident between monsoon and postmonsoon. Canonical correspondence analysis indicated that salinity, acidity, inorganic phosphate concentration and dissolved oxygen were the most important environmental variables in determining the observed variation in fish assemblages. Seasonal succession of fish populations may be related to differences in life cycle and adaptation to prevalent ecological conditions. The study therefore suggests that environmental variations in terms of changing salinity and dissolved oxygen have significant influence in structuring estuarine piscine community in this region.     

Temporal Variability in the Concentration and Stable Carbon Isotope Composition of Dissolved Inorganic and Organic Carbon in Two Montana,USA Rivers

Here we report diel (24 h) and seasonal differences in the concentration and stable carbon isotope composition of dissolved inorganic (DIC) and organic carbon (DOC) in the Clark Fork (CFR) and Big Hole (BHR) Rivers of southwestern Montana, USA. In the CFR, DIC concentration decreased during the daytime and increased at night while DOC showed an inverse temporal relationship; increasing in the daytime most likely due to release of organic photosynthates and decreasing overnight due to heterotrophic consumption. The stable isotope composition of DIC (δ¹³C-DIC) became enriched during the day and depleted over night and the δ¹³C-DOC displayed the inverse temporal pattern. Additionally, the night time molar rate of decrease in the concentration of DOC was up to two orders of magnitude smaller than the rate of increase in the concentration of DIC indicating that oxidation of DOC was responsible for only a small part of the increase in inorganic carbon. In the BHR, in two successive years (late summer 2006 & 2007), the DIC displayed little diel concentration change, however, the δ¹³C-DIC did show a more typical diel pattern characteristic of the influences of photosynthesis and respiration indicating that the isotopic composition of DIC can change while the concentration stays relatively constant. During 2006, a sharp night time increase in DOC was measured; opposite to the result observed in the CFR and may be related to the night time increase in flow and pH also observed in that year. This night time increase in DOC, flow, and pH was not observed 1 year later at approximately the same time of year. An in-stream mesocosm chamber used during 2006 showed that the night time increase in pH and DOC did not occur in water that was isolated from upstream or hyporheic contributions. This result suggests that a “pulse” of high DOC and pH water was advected to the sampling site in the BHR in 2006 and a model is proposed to explain this temporal pattern.     

Carbon Dioxide Fluxes and Their Environmental Control in a Reclaimed Coastal Wetland in the Yangtze Estuary

Large areas of natural coastal wetlands have suffered severely from human-driven damages or conversions (e.g., land reclamations), but coastal carbon flux responses in reclaimed wetlands are largely unknown. The lack of knowledge of the environmental control mechanisms of carbon fluxes also limits the carbon budget management of reclaimed wetlands. The net ecosystem exchange (NEE) in a coastal wetland at Dongtan of Chongming Island in the Yangtze estuary was monitored throughout 2012 using the eddy covariance technique more than 14 years after this wetland was reclaimed using dykes to stop tidal flooding. The driving biophysical variables of NEE were also examined. The results showed that NEE displayed marked diurnal and seasonal variations. The monthly mean NEE showed that this ecosystem functioned as a CO₂ sink during 9 months of the year, with a maximum value in September (?101.2 g C m^?2) and a minimum value in November (?8.2 g C m^?2). The annual CO₂ balance of the reclaimed coastal wetland was ?558.4 g C m^?2 year^?1. The ratio of ecosystem respiration (ER) to gross primary production (GPP) was 0.57, which suggests that 57 % of the organic carbon assimilated by wetland plants was consumed by plant respiration and soil heterotrophic respiration. Stepwise multiple linear regressions suggested that temperature and photosynthetically active radiation (PAR) were the two dominant micrometeorological variables driving seasonal variations in NEE, while soil moisture (M _s) and soil salinity (PS_s) played minor roles. For the entire year, PAR and daytime NEE were significantly correlated, as well as temperature and nighttime NEE. These nonlinear relationships varied seasonally: the maximum ecosystem photosynthetic rate (A _max), apparent quantum yield (?), and Q ₁₀ reached their peak values during summer (17.09 μmol CO₂?m^?2 s^?1), autumn (0.13 μmol CO₂?μmol^?1 photon), and spring (2.16), respectively. Exceptionally high M _s or PS_s values indirectly restricted ecosystem CO₂ fixation capacity by reducing the PAR sensitivity of the NEE. The leaf area index (LAI) and live aboveground biomass (AGB_L) were significantly correlated with NEE during the growing season. Although the annual net CO₂ fixation rate of the coastal reclaimed wetland was distinctly lower than the unreclaimed coastal wetland in the same region, it was quite high relative to many inland freshwater wetlands and estuarine/coastal wetlands located at latitudes higher than this site. Thus, it is concluded that although the net CO₂ fixation capacity of the coastal wetland was reduced by land reclamation, it can still perform as an important CO₂ sink.     

Spatiotemporal Models of an Estuarine Fish Species to Identify Patterns and Factors Impacting Their Distribution and Abundance

Understanding the distribution and abundance of organisms can be exceedingly difficult for pelagic fish species that live in estuarine environments. This is particularly so for fish that cannot be readily marked and released or otherwise tracked, such as the diminutive delta smelt, Hypomesus transpacificus, endemic to the San Francisco Estuary. The environmental factors that influence their distribution operate at multiple scales, from daily tidal cycles and local perceptual fields to seasonal and annual changes in dominant environmental gradients spanning the entire San Francisco Estuary. To quantify scale-specific patterns and factors shaping the spatiotemporal abundance dynamics of adult delta smelt, we fit a suite of models to an extensive, spatially resolved, catch survey time series from 13 annual cohorts. The best model included cohort-specific abundance indicators and daily mortality rates, a regional spatial adjustment, and haul-specific environmental conditions. The regional adjustment identified several density hot spots that were persistent across cohorts. While this model did include local environmental conditions, the gain in explained variation was relatively slight compared to that explained by the regional adjustment. Total abundance estimates were derived by multiplying habitat volume by catch density (design-based) and modeled density (model-based), with both showing severe declines in the population over the time period studied. The design-based approaches had lower uncertainty but potentially higher bias. We discuss the implications of our results for advancing the science and improving management of delta smelt, and future data collection needs.     

基于环境磁学的生态系统演化和磁性矿物的关系

以广西区岑溪市一花岗岩风化壳为研究对象,利用环境磁学原理研究其上生态系统演替过程中出现的不同磁性矿物变化特征,讨论磁性矿物对生态系统变化的响应过程。研究区磁性矿物的显著差别,显示在湿热气候条件下生物、化学风化作用的参与,对磁性矿物的转变有明显的促进作用。     

三江平原土壤碳库时空变化和影响因素研究

基于东北三江平原土壤地球化学调查数据,估算了表层土壤有机碳密度和碳储量,与全国第二次土壤普查时的土壤有机碳密度进行对比研究,分析了研究区土壤碳库储量及变化的主要影响因素.结果 表明:研究区表层土壤碳以有机碳为主,不同土壤类型有机碳密度及总碳密度有明显差异,沼泽土、泥炭土相对区内其他土壤类型的有机碳密度高,平均在8 kg...     

Spatiotemporal Variability in Dissolved Organic Matter Composition is More Strongly Related to Bacterioplankton Community Composition than to Metabolic Capability in a Blackwater Estuarine System

The composition and metabolic capability of bacterioplankton communities were examined over seasonal and spatial gradients and related to the source, composition, and quantity of dissolved organic matter (DOM) in the blackwater estuary Winyah Bay, Georgetown County, SC, USA and its tributary rivers. Bacterial community composition (BCC) was measured by terminal restriction fragment length polymorphism, and bacterial metabolic capability (BMC) was measured by defined substrate utilization patterns (Biolog GN2 plates). Spatial patterns were not important, despite the anticipated watershed effects and the well-documented influence of salinity gradients on estuarine bacterioplankton, but DOM, BCC, and BMC all showed varying degrees of temporal patterns; DOM-based groupings differentiated BCC samples better than spatiotemporal categories, but not BMC. BCC was closely related to properties describing DOM composition, particularly those related to DOM source (i.e., cypress swamps vs. in situ phytoplankton production, indicated by chlorophyll a, colored DOM spectral slope, α355/dissolved organic carbon (DOC), and DOC concentration), and to associated physicochemical variables, such as temperature, pH, and salinity. BMC was more strongly related to abiotic factors, such as temperature and dissolved nutrients, as well as to chlorophyll a and percent bioavailable DOC. In contrast with previous studies, BCC and BMC were significantly correlated in this highly heterotrophic estuary, suggesting that DOM source variability may select for specialist phylotypes above a background of generalists. This study, therefore, supports a causative pathway from DOM to BMC to BCC while suggesting that BCC and BMC may be simultaneously influenced by different suites of DOM characteristics and physicochemical parameters.     

不同类型生物土壤结皮固氮活性及对环境因子的响应研究

利用乙炔还原法对腾格里沙漠东南缘沙坡头地区3种生物土壤结皮(藻结皮、地衣结皮和苔藓结皮)的固氮活性及生物结皮固氮活性对模拟不同降雨量(1、3和5 mm)、温度(13、24和28℃)和光强(0、400和1000μmol/(m2·s))的响应进行研究.结果表明:不同类型生物结皮的固氮活性差异显著,依次为:藻结皮(16.6 ...     

准噶尔盆地上三叠统源岩TOC含量预测方法

根据对准噶尔盆地三叠系暗色泥岩在不同层段发育特征的分析,发现暗色泥岩主要发育于上三叠统,中、下三叠统 分布有限。针对准噶尔盆地上三叠统暗色泥岩实测有机碳含量数据偏少、测井曲线系列较完整的实际情况,利用声波测井 与电阻率测井重叠法,建立了准噶尔盆地上三叠统暗色泥岩有机碳含量的预测模型,并估算了主要探井上三叠统暗色泥岩 的有机碳含量。综合预测和实测有机碳含量平面分布特征发现,上三叠统有机碳含量显示有4 个相对高值区,分别位于乌 伦古坳陷的索索泉凹陷、中央坳陷带的阜康凹陷、盆1 井西凹陷和玛湖凹陷,以索素泉凹陷有机碳含量最高,阜康凹陷和 盆1 井西凹陷其次,玛湖凹陷总体较低。有机碳含量表明上三叠统为一套中等- 较好的烃源岩。     

Changes in Nutrient and Carbon Availability and Temperature as Factors Controlling Bacterial Growth in the Northern Baltic Sea

The effects of inorganic nutrient (N and P) and glucose C treatments on bacterial growth were followed for 3 days in natural surface and deep water bacterial samples during the main post-spring bloom stages of phytoplankton growth in the northern Baltic Sea. In addition, the importance of photochemical degradation of dissolved organic matter on bacterial growth was investigated vertically (0.1–2.0 m) and spatially, in a salinity gradient from river mouth to open sea. Bacterial production was consistently C limited in the surface layer, with N or both N and P as the secondary limiting nutrients from spring to early summer and in late summer, respectively. In deep water, bacterial growth showed combined temperature and C limitation, and in spring, this also appeared to be true with surface samples. The effect of 1-day sunlight pre-treatment varied from no effect up to a 44% production increase, with clear bacterial production responses only being seen at the surface (10 cm depth). The implications of bacterial C limitation for the structure and function of the surface plankton ecosystem, including its CO₂ exchange with the atmosphere are discussed.     

白令海表层沉积物中硅质生物的变化及其环境控制因素

中国首次北极科学考察在白令海采取了12个表层沉积物样品, 其中对硅质生物和陆源碎屑的详细研究发现, 它们主要由硅藻、放射虫和海绵骨针组成.其中, 硅藻在样品中的丰度均占绝对优势, 高出放射虫和海绵骨针一个数量级.它们与环境控制因素关系的分析表明, 硅藻、放射虫和海绵骨针丰度的高低及其保存程度与深度、温度、盐度和受大规模季节性气候变化控制的表层海水的高营养和高生产力, 以及陆源物质输入的变化密切相关.这一研究结果对白令海第四纪的古气候与古海洋学研究具有十分重要的意义.      

Temporal and Spatial Variability of Mesozooplankton in a Shallow Sub-Tropical Bay: Influence of Top-Down Control

Quantifying the relationship between mesozooplankton and water quality parameters identifies the factors that structure the mesozooplankton community and can be used to generate hypotheses regarding the mechanisms that control the mesozooplankton population and potentially the trophic network. To investigate this relationship, mesozooplankton and water quality data were collected in Florida Bay from 1994 to 2004. Three key characteristics were found in the mesozooplankton community structure: (1) there are significant differences between the four sub-regions of Florida Bay; (2) there is a break in May of 1997 with significant differences before and after this date; and (3) there is a positive correlation between mesozooplankton abundance and salinity. The latter two characteristics are closely correlated with predator abundance, indicating the importance of top-down control. Hypersaline periods appear to provide a refuge from predators, allowing mesozooplankton to increase in abundance despite the increased physiological stress.     

Carbon and Oxygen Isotopic Compositions: How Lacustrine Environmental Factors Respond in Northwestern and Northeastern China

Surface lake sediments,28 from Hoh Xil,24 from northeastern China,99 from Lake Bosten,31 from Ulungur and 26 from Heihai were collected to determine δ13C and δ18O values.Considering the impact factors,conductivity,alkalinity,pH,TOC,C/N and carbonate-content in the sediments,Cl,P,S,and metal element ratios of Mg/Ca,Sr/Ca,Fe/Mn of bulk sediments as environmental variables enable evaluation of their influences on δ13C and δ18O using principal component analysis(PCA) method.The closure and residence time of lakes can influence the correlation between δ13C and δ18O.Lake water will change from fresh to brackish with increasing reduction and eutrophication effects.Mg/Ca in the bulk sediment indicates the characteristic of residence time,Sr/Ca and Fe/Mn infer the salinity of lakes.Carbonate formation processes and types can influence the δ13C–δ18O correlation.δ18O will be heavier from Mg-calcite and aragonite formed in a high-salinity water body than calcite formed in freshwater conditions.When carbonate content is less than 30%,there is no relationship with either δ13C or δ18O,and also none between δ13C and δ18O.More than 30%,carbonate content,however,co-varies highly to δ13C and δ18O,and there is also a high correlation between δ13C and δ18O.Vegetation conditions and primary productivity of lakes can influence the characteristics of δ13C and δ18O,and their co-variance.Total organic matter content(TOC) in the sediments is higher with more terrestrial and submerged plants infilling.In northeastern and northwestern China,when organic matter in the lake sediments comes from endogenous floating organisms and algae,the δ13C value is high.δ13C is in the range of 4‰ to 0‰ when organic matter comes mainly from floating organisms(C/N<6);in the range of 4‰ to 8‰ when organic matter comes from diatoms(C/N=6 to 8);and 8‰ to 4‰ when organic matter comes from aquatic and terrestrial plants(C/N>8).     

江陵凹陷古新世盐湖沉积碳酸盐碳氧同位素组成及其环境意义

江陵凹陷位于江汉裂谷盆地西部, 古新世是该区富钾卤水形成的主要时期, 研究该时期古气候的演化, 对下一步找钾有重要的理论和实际意义。古新统沙市组和新沟嘴组湖相碳酸盐岩分析结果显示, 沙市组沉积碳酸盐岩δ13CPDB值介于–4.8‰ ~ –1.0‰之间, 平均值为–3.4‰; δ18OPDB值介于–5.6‰ ~ –0.6‰之间, 平均值为–3.3‰; 新沟嘴组碳酸盐岩δ13CPDB值介于–10.8‰ ~ –8.8‰之间, 平均值为–9.3‰; δ18OPDB值介于–10.2‰ ~ –6.7‰之间, 平均值为–8.6‰。沙市组碳酸盐岩样品的δ13CPDB和δ18OPDB之间具有良好的正相关性, 表明它们发育在蒸发作用明显的相对封闭的咸水湖泊体系中; 而新沟嘴组δ13CPDB和δ18OPDB之间相关性差, 指示该时期是水体滞留时间较短的开放型湖泊系统。碳氧同位素, Sr/Ba值和Mg/Ca值均说明沙市组沉积时期古盐度和蒸发/降雨大于新沟嘴组沉积时期; 古新世的岩相古地理演化说明了沙市组沉积时期古湖水面小于新沟嘴组沉积时期。江陵凹陷古新统湖泊沉积碳酸盐碳氧同位素组成的变化指示了区域古气候条件由沙市期的干热向新沟嘴期的湿润转变。显示古新统沙市组到新沟嘴组江陵凹陷古气候格局发生了重大变化, 这一变化对于沙市组时期古盐湖演化和成钾十分有利。