The Galilean satellites: New near-infrared spectral reflectance measurements (0.65–2.5 μm) and a 0.325–5 μm summary

New near-infrared (0.65–2.5 μm) reflectance spectra of the Galilean satellites with 1.5% spectral resolution and ≈2% intensity precision are presented. These spectra more precisely define the water ice absorption features previously identified on Europa, Ganymede, and Callisto at 1.55 and 2.0 μm. In addition, previously unreported spectral features due to water ice are seen at 1.25, 1.06, 0.90, and 0.81 μm on Europa, and at 1.25, 1.04, and possibly 0.71 μm on Ganymede. Unreported absorption features in Callisto's spectrum occur at 1.2 μm, probably due to H₂O, and a weak, broad band extending from 0.75 to 0.95 μm, due possibly to other minerals. The spectrum of Io has only weak absorption features at 1.15 μm and between 0.8 and 1.0 μm. No water absorptions are positively identified in the Io spectra, indicating an upper limit of areal water frost coverage of 2% (leading and trailing sides). It is found for Callisto, Ganymede, and Europa that the water ice absorption features are due to free water and not to water bound or absorbed onto minerals. The areal coverage of water frost is ≈ 100% on Europa (trailing side), ≈65% on Ganymede (leading side), and 20–30% on Callisto (leading side). An upper limit of ≈5% bound water (in addition to the 20–30% ice) may be present on Callisto, based on the strong 3-μm band seen by other investigators. A summary of spectra of the satellites from 0.325 to about 5 μm to aid in laboratory and interpretation studies is also presented.     

Icy Galilean satellite reflectance spectra: Less ice on Ganymede and Callisto?

Recent interpretations of the reflectance spectra of the icy Galilean satellites (Europa, Ganymede, and Callisto) have implied very ice-rich surfaces, as high as 90 wt% ice even on the dark surface of Callisto. A reevaluation of the spectra, taking into account the depth of the 3-μm fundamental water ice absorption feature as well as the shorter wavelength bands, suggests that the spectra of at least Ganymede and Callisto may also be consistent with much lower ice abundances if the ice is segregated from the nonicy material. Reasonable fits to all band depths (including the shallow 1.04- and 1.25-μm bands) are obtained with around 50% areal coverage of ice on Ganymede and 10% on Callisto, the rest of the surface being occupied by carbonaceous chondrite-like material which has a strong 3-μm absorption due to bound water. Europa's spectrum probably indicates a homogeneous icy surface. The darkness beyond 3 μm, and lack of a 3.6-μm peak, for all three objects may be consistent with the presence of small quantities of sulfuric acid on the satellite surfaces.     

2.7- to 4.1-μm spectrophotometry of icy satellites of Saturn and Jupiter

We present spectrophotometry in the 27–41 μm spectral region for icy satellites of Saturn (Tethys, Dione, Rhea, Iapetus, and Hyperion) and Jupiter (Europa, Ganymede, and Callisto). The 3.6-μm reflectance peak characteristic of fine-grained water ice is observed prominently on the satellites of Saturn, faintly on the leading side of Europa, and not all on Ganymede, Callisto, or the dark side of Iapetus. The spectral reflectances of these icy satellites may be affected by their equilibrium surface temperatures and magnetospheric effects.     

Characteristic features in the spectra of Europa, Ganymede, and Callisto

The results of ground-based spectrophotometry of the icy Galilean satellites of Jupiter—Europa, Ganymede, and Callisto—are discussed. The observations were carried out in the 0.39–0.92 μm range with the use of the CCD spectrometer mounted on the 1.25-m telescope of the Crimean laboratory of the Sternberg Astronomical Institute in March 2004. It is noted that the calculated reflectance spectra of the satellites mainly agree with the analogous data of the earlier ground-based observations and investigations in the Voyager and Galileo space missions. The present study was aimed at identifying new weak absorption bands (with the relative intensity of ～3–5%) in the reflectance spectra of these bodies with laboratory measurements (Landau et al., 1962; Ramaprasad et al., 1978; Burns, 1993; Busarev et al., 2008). It has been ascertained that the spectra of all of the considered objects contain weak absorption bands of molecular oxygen adsorbed into water ice, which is apparently caused by the radiative implantation of O⁺ ions into the surface material of the satellites in the magnetosphere of Jupiter. At the same time, spectral features of iron of different valence (Fe²⁺ and Fe³⁺) values typical of hydrated silicates were detected on Ganymede and Callisto, while probable indications of methane of presumably endogenous origin, adsorbed into water ice, were found on Europa. The reflectance spectra of the icy Galilean satellites were compared to the reflectance spectra of the asteroids 51 Nemausa (C-class) and 92 Undina (X-class).     

Near-infrared spectra of the Galilean satellites: Observations and compositional implications

We have obtained reflectivity spectra of the trailing and leading sides of all four Galilean satellites with circular variable filter wheel spectrometers operating in the 0.7- to 5.5-μm spectral interval. These observations were obtained at an altitude of 41,000 ft from the Kuiper Airborne Observatory. Features seen in these data include a 2.9-μm band present in the spectra of both sides of Callisto; the well-known 1.5-μm and 2.0-μm combination bands and the previously more poorly defined 3.1-μm fundamental of water ice observed in the spectra of both sides of Europa and Ganymede; and features centered at 1.35 ± 0.1, 2.55 ± 0.1, and 4.05 ± 0.05 μm noted in the spectra of both sides of Io. In an effort to interpret these data, we have compared them with laboratory spectra as well as synthetic spectra constructed with a simple multiple-scattering theory. We attribute the 2.9-μm feature of Callisto's spectra primarily to bound water, with the product of fractional abundance of bound water and mean grain radius in micrometers equaling approximately 3.5 × 10^?1 for both sides of the satellite. The fractional amounts of water ice cover on the trailing side of Ganymede, its leading side, and the leading side of Europa were found to be 50 ± 15, 65 ± 15, and 85% or greater, respectively. The bare ground areas on Ganymede have reflectivity properties in the 0.7- to 2.5-μm spectral region comparable to those of Callisto's surface and also have significant quantities of bound water, as does Callisto. Interpretation of the spectrum for the trailing side of Europa is complicated by magnetospheric particle bombardment which causes a perceptible broadening of strong bands, but the ice cover on this side is probably comparable to that on the leading side. These irradiation effects may be responsible for much of the difference in the visual geometric albedos of the two sides of Europa. Minor, but significant, amounts of ferrous-bearing material (either ferrous salts or alkali feldspars but not olivines or pyroxenes) account for the 1.35-μm feature of Io. The two longer wavelength bands are most likely attributable to nitrate salts. Ferrous salts and nitrates can jointly also account for much of the spectral variation in Io's visible reflectivity, thereby eliminating the need to postulate large quantities of sulfur. The absence of noticeable features near 3-μm wavelength in Io's spectra leads to upper bounds of 10% on the fractional cover of water and ammonia ice and 10^?3 on the relative abundance of bound water and hydroxylated material on Io. The two sides of Io have similar compositions. We suggest that the systematic increase in fractional water ice cover from Callisto to Ganymede to Europa is bought about by variations in efficiencies of recoating the satellite's surface by interior water brought to the surface, and by the deposition of extrinsic dust. The most important component of the latter is debris, derived from the outer irregular satellites of Jupiter, which impacts the Galilean satellites at relatively low velocities. Europa has the largest water ice cover because its crust is thinnest and thus the frequency of water recoating is the greatest, and because it is farthest from the sources of low-velocity dust. While models which depict Io's surface as consisting primarily of very fine-grained ice are no longer viable, we are unable to definitively distinguish between the salt assemblage and alkali feldspar models. The salt model can better account for Io's reflectivity spectrum from 0.3 to 5 μm, but the absence of appreciable quantities of bound water and hydroxylated material may not be readily understood within the context of that model.     

Surface temperatures and retention of H2O frost on Ganymede and Callisto

Surface temperatures and ice evaporation rates are calculated for Ganymede and Callisto as a function of latitude, time of day, and albedo. The model uses surface thermal properties determined by eclipse radiometry (Morrison and Cruikshank, 1973Icarus18 224–236) and albedos determined from photometrically decalibrated Voyager images. Daytime temperatures on Callisto are roughly 8°K warmer than those in Ganymede's cratered terrain and 11°K warmer than those in Ganymede's grooved terrain. Diurnal mean ice evaporation rates are high enough on both bodies that the surface material probably consists of a very low density lag deposit of primarily silicate dust overlying a denser regolith of silicates and ice. The difference in temperature between Ganymede and Callisto is not great enough to account for the lack of bright polar caps on Callisto. This lack seems instead to reflect a real deficiency in the amount of available H₂O frost relative to Ganymede. The temperature difference between Ganymede's grooved and cratered terrains also cannot account for the strong concentration of bright ray craters in grooved terrain. This concentration suggests instead that an internal geologic process has enriched the grooved terrain in ice relative to the cratered terrain.     

Librations of the Galilean satellites: The influence of global internal liquid layers

The four Galilean satellites are thought to harbor one or even two global internal liquid layers beneath their surface layer. The iron core of Io and Ganymede is most likely (partially) liquid and also the core of Europa may be liquid. Furthermore, there are strong indications for the existence of a subsurface ocean in Europa, Ganymede, and Callisto. Here, we investigate whether libration observations can be used to prove the existence of these liquid layers and to constrain the thickness of the overlying solid layers. For Io, the presence of a small liquid core increases the libration of the mantle by a few percent with respect to an entirely solid Io and mantle libration observations could be used to determine the mantle thickness with a precision of several tens of kilometers given that the libration amplitude can be measured with a precision of 1 m. For Europa, Ganymede, and Callisto, the presence of a water ocean close to the surface increases by at least an order of magnitude the ice shell libration amplitude with respect to an entirely solid satellite. The shell libration depends essentially on the shell thickness and to a minor extent on the density difference between the ocean and the ice shell. The possible presence of a liquid core inside Europa and Ganymede has no noticeable influence on their shell libration. For a precision of several meters on the libration measurements, in agreement with the expected accuracy with the NASA/ESA EJSM orbiter mission to Europa and Ganymede, an error on the shell thickness of a few tens kilometers is expected. Therefore, libration measurements can be used to detect liquid layers such as Io’s core or water subsurface oceans in Europa, Ganymede, and Callisto and to constrain the thickness of the overlying solid surface layers.     

Evidence for frost on Rhea's surface

We have observed Rhea (S5) at 1.6 μm and 2.2 μm at Mt. Wilson using the Caltech photometer on the 1.52m and 2.54m telescopes. The infrared spectral reflectances relative to 0.55μm are 0.8 (±0.1 p.e.) at 1.65μm and 0.6 (±0.1 p.e.) at 2.2μm. Such absorption bands in the near infrared are not consistent with spectra of most rocks or minerals; even carbonaceous chondritic materials have nearly flat reflectances over this spectral region. Frosts, however, have strong absorption bands in the 1–3μm region. In particular, the broadband infrared reflectances of Rhea are similar to those of the Galilean satellites Europa (J2) and Ganymede (J3) and also the rings of Saturn (all of which are known from high resolution scans to have water frosts on their surfaces). The broadband photometry does not have sufficient resolution to identify the frost species: but Rhea's low density, high albedo and relatively flat reflectance from 0.3μm to 1.1μm as well as the low infrared reflectances reported here are consistent with the presence of water ice on Rhea's surface.     

Visible spectral reflectance measurements (0.33–1.1 μm) of the Galilean satellites at many orbital phase angles

One hundred eighty-seven reflectance spectra (0.33–1.10 μm) of the Galilean satellites have been obtained. Solar phase angle color correction coefficients were derived and the spectra corrected to a solar phase of 6°. Solar phase angle coefficients beyond 0.55 μm are presented for the first time. The spectra as a function of orbital phase angle are presented in the form of images to display hemispheric spectral variations. Io and Europa are redder on their trailing hemispheres while Callisto is redder on its leading hemisphere. Ganymede shows small longitudinal color variations despite the complex albedo structure visible in Voyager images. Comparisons of these data with previous measurements reveal that most differences can be attributed to the solar calibration. Reflectance measurements of Io at 0.73 μm observed 8.5 years apart show a 6% global reflectance decrease. However, it is difficult to unambigously attribute this particular decrease in reflectance to a change in Io's surface composition.     

The infrared spectrum of Rhea

A new infrared spectrum of the leading side of Rhea is presented in the 0.65- to 2.5 μm region with 1.5% spectral resolution and 3 to 5% data precision. Water ice absorptions previously identified at 2.02, 1.65, and 1.55 μm are confirmed and more precisely defined. The 1.25-μm water ice absorption is identified for the first time and the 1.04-μm water ice absorption is probably also present. The spectrum of the leading side of Rhea is very similar to the spectrum of the leading side of Ganymede in the 0.6- to 2.5-μm region. The Rhea spectrum is also very similar to laboratory spectra of water frost on ice blocks rather than that of an optically thick frost. The strong water ice absorption features, high albedo, and little downturn in reflectance toward shorter wavelengths from 0.6 to 0.4 μm all indicate a surface of nearly pure water ice. The surface of Rhea is probably at least 90 wt% water ice and may be as much as 98 wt%. Of the remaining constituents, neither minerals nor clathrathes can be excluded. If the surface of Rhea were a methane clathrate, the surface would still be about 90 wt% water ice.     

Ten-micron eclipse observations of Io,Europa, and Ganymede

Eclipse observations of Jupiter's satellites Io, Europa, and Ganymede have been obtained in an 8 to 14-μm band pass during 1971. The simplest thermal model able to explain the data for each satellite is a two-layer surface structure with an upper layer, only a few millimeters thick, having low thermal conductivity consistent with fine rock powder or frost, and a subsurface having high thermal conductivity consistent with solid rock or dense ice. The upper layer on Io (γ = 1100 ± 100)² appears to be different from that on Europa (γ = 3000 ± 1000) and Ganymede (γ = 3400 ± 700), but the two-layer model fits all three satellites.     

Mass-radius relationships in icy satellites after voyager

Using improved data for the masses and radii of the satellites of Jupiter and Saturn, models accounting for self-compression effects are presented for the interiors of Europa, Ganymede, Callisto, Rhea, and Titan. For the differentiated models, two different possible scenarios for heat transport are treated, as well as two different compositions for the silicate component. Undifferentiated models are also treated. In each case, the models of Ganymede, Callisto, and Titan show noticeable similarities. It is found that estimates of the ice-rock ratio are dependent upon the assumptions made about the heat transport mechanisms, the rock composition, and on the distribution of rock and ice in the satellite's interior.     

Saturn's satellites: Nuar-infrared spectrophotometry (0.6–2.5 μm) of the leading and trailing sides and compositional implications

Near-infrared spectra, 0.65–2.5 μm, are presented for Tethys, Dione, Rhea, Iapetus, and Hyperion. Water ice absorptions at 2.0, 1.5, and 1.25 μm are seen in the spectra of all five objects (except the 1.25-μm band was not detected in spectra of Hyperion) and the weak 1.04-μm ice absorption is detected on the leading and trailing sides of Rhea, and the trailing side of Dione. Upper limits to the 1.04-μm ice band depth are <0.3% for the leading side of Dione; <0.7% for the leading side of Iapetus, and the trailing side of Tethys; <1% on the trailing side of Iapetus; and <5% on the leading side of Tethys. The leading-trailing side ice band depth differences on Saturn's satellites are similar to those for the Galilean satellites, indicating possible surface modification by magnetospheric charged particle bombardment. Limits are determined for the amount of particulates, trapped gases, and amonium hydroxide on the surface. The surfaces of Saturn's satellites (except the dark side of Iapetus) are nearly pure water ice, with probably less than about 1 wt% particulate minerals. The ice could be clathrates with as much as a few weight percent trapped gases. The upper limit of amonium hydroxide depends on the spectral data precision and varies from ～ 1 wt% NH₃ for the leading side of Rhea to ～ 10 wt% NH₃ for Dione.     

Comparison and Interpretation of Spectral Characteristics of the Leading and Trailing Hemispheres of Europa and Callisto

Europa and Callisto are two “extreme members” in a sequence of the Galilean ice satellites formed at different distances from Jupiter. The difference in their mean density probably reflects the material density gradient that appeared even in the subplanetary disk of Jupiter. At the same time, general peculiarities in the composition of the surfaces of Europa and Callisto apparently characterize the accumulated effect of all subsequent evolutionary processes, including current volcanic activity on the satellite Io and its ionized material transfer in Jovian magnetosphere, as well as chemical reactions taking place under low-temperature (within ~90–130 K) and irradiation conditions. In 2016–2017, we observed the leading and trailing hemispheres of Europa and Callisto in the spectral range of 1.0–2.5 μm at 2-m telescope of Caucasian Mountain Observatory (CMO) of Sternberg Astronomical Institute (SAI) of Moscow State University (MSU). We found that, on a global scale, Europa and Callisto exhibit similar spectral characteristics and, particularly, the maxima in the distributions of sulfuric acid hydrate in the trailing hemispheres of the both moons, which agrees with the data of previous measurements. This can be considered as evidence for general ion implantation on these and other moons in the radiation belts of Jupiter. Moreover, our spectral data suggest that water ice and hydrates (clathrates) of other compounds are dominant or abundant in the leading hemispheres of Europa and Callisto. Specifically, we detected a weak absorption band of CH₄ clathrate centered at ~1.67 μm in the reflectance spectra of the leading (the band is more intense) and trailing (the band is less intense) hemispheres of Europa. Weak signs of the same absorption band are also in the reflectance spectra of Callisto measured at its different orientations.     

Infrared observations of the surface and atmosphere of Titan

Infrared photometry of Titan, Saturn, and Saturn's Rings at 3.5, 4.9, 17.8, and 18.4 μm is reported. Comparison of the albedo of Titan in the 4.9 μm “window” with the albedo of the rings and with laboratory spectra suggests that frost, possibly water ice, could be a major constituent. If thick clouds are present they must be very dark at 4.9 μm. The 17.8 and 18.4 μm data are not consistent with a clear, dense molecular hydrogen atmosphere.     

Implications from Galileo Observations on the Interior Structure and Chemistry of the Galilean Satellites

Data from the recent gravity measurements by the Galileo mission are used to construct wide ranges of interior structure and composition models for the Galilean satellites of Jupiter. These models show that mantle densities of Io and Europa are consistent with an olivine-dominated mineralogy with the ratios of Mg to Fe components depending on mantle temperature for Io and on ice shell thickness for Europa. The mantle density and composition depend relatively little on core composition. The size of the core is largely determined by the core's composition with core radius increasing with the concentration of a light component such as sulfur. For Io, the range of possible core sizes is between 38 and 53% of the satellite's radius. For Europa, there is also a substantial effect of the thickness of the ice layer which is varied between 120 and 170 km on the core size. Core sizes are between 10 and 45% of Europa's radius. The core size of Ganymede ranges between one-quarter and one-third of the surface radius depending on its sulfur content and the thickness of the ice shell. A subset of the Ganymede models is consistent with an olivine-dominated mantle mineralogy. The thickness of the silicate mantle above the core varies between 900 and 1100 km. The outermost ice shell is about 900 km in thickness and is further subdivided by pressure-induced phase transitions into ice I, ice III, ice V, and ice VI layers. Callisto should be differentiated, albeit incompletely. It is proposed that this satellite was never molten at a large scale but differentiated through the convective gradual unmixing of the ice and the metal/rock component. Bulk iron-to-silicon ratios Fe/Si calculated for the inner pair of satellites, Io and Europa, are less than the CI carbonaceous chondrite value of 1.7±0.1, whereas ratios for the outer pair, Ganymede and Callisto, cover a broad range above the chondritic value. Although the ratios are uncertain, in particular for Ganymede and Callisto, the values are sufficiently distinct to suggest a difference in composition between these two pairs of satellites. This may indicate a difference in iron-silicon fractionation during the formation of both classes of satellites in the protojovian nebula.     

Optical polarimetry of the Galilean satellites of Jupiter

New measurements of the amount of polarization of the Galilean satellites are given and, within the context of other data, are interpreted as follows. The polarization of Europa is consistent with a water-frost surface. Io has a surface of partly absorbing crystals thought to result from evaporates released from the mantle and damaged by radiation. Ganymede has alternating water-frost areas and darker terrain, possibly of a silicaceous nature. Callisto is explained as having a mantle of ice containing embedded blocks of rocks, which occurred when recent evaporation left the blocks piled at the surface in a chaotic manner. This event occurred after the vicinity of Jupiter had been cleared of small orbiting objects able to impact Callisto. Meteorites which continue to enter within the sphere of influence of Jupiter can collide with Callisto only on its leading hemisphere, which is thereby comminuted by impacts. The surface of the trailing hemisphere is not regolithic.     

Thermal migration of water on the Galilean satellites

We have modeled the thermal migration of water on the Galilean satellites under the assumption of ballistic molecular trajectories. We find that water migrating owing to solar radiation on an ice-covered satellite will build up in the temperate latitudes, in general not reaching the poles. As much as 50 m of ice may have been lost by this process from the equatorial regions of Europa over the age of the solar system. The disappearance of patches of ice—for instance, the bright rays surrounding some impact craters—from the equatorial regions of Ganymede and Callisto may approach a value (the irreversible evaporation rate) three orders of magnitude larger than the net equatorial loss rate for ice-covered Europa. The presence of water ice pole caps on Ganymede extending to the latitudes at which thermal migration becomes important suggests that some process distributed an extensive, thin covering of water on the satellite, and that the equatorial regions were subsequently cleared by the thermal process.     

Arecibo radar observations of Rhea, Dione, Tethys, and Enceladus

We have measured the bulk radar reflectance properties of the mid-size saturnian satellites Rhea, Dione, Tethys, and Enceladus with the Arecibo Observatory's 13 cm wavelength radar system during the 2004 through 2007 oppositions of the Saturn system. Comparing to the better studied icy Galilean satellites, we find that the total reflectivities of Rhea and Tethys are most similar to Ganymede while Dione is most similar to Callisto. Enceladus' reflectivity falls between those of Ganymede and Europa. The mean circular polarization ratios of the saturnian satellites range from ∼0.8 to 1.2, and are on average lower than those of the icy Galilean satellites at this wavelength although still larger than expected for single reflections off the surface. The ratio for the trailing hemisphere of Enceladus may be the exception with a value ?0.56. The 13 cm wavelength radar albedos and polarization ratios may be systematically lower than similar results from the Cassini orbiter's RADAR instrument at 2.2 cm wavelength [Ostro, S.J., and 19 colleagues, 2006. Icarus 183, 479-490]. Overall, these reflectivities and polarization properties, together with the shapes of the echo spectra, suggest subsurface multiple scattering to be the dominant reflection mechanism although operating less efficiently than on the large icy moons of Jupiter. All these saturnian moons and icy jovian moons are atmosphere-less, low temperature water ice surfaces, and any differences in radar properties may be indicative of differences in composition or the effects of various processes that modify the regolith structure. The degree of variation in radar properties with wavelength on each satellite may constrain the thickness and efficiency of the scattering layer.     

A search for temporal variability in the surface chemistry of the icy Galilean satellites

The purpose of this study was to determine if any temporal variability in the broadband UV spectral properties of the icy Galilean satellites exists, and if so, to characterize its spatial distribution as a function of longitude in order to attempt to correlate any temporal changes with satellite surface interactions with the space environment. The temporal time period examined is between 1978-1984 (referred to as the 1980s data) and those from 1995-1996 (referred to as the 1990s data). The plausible temporal characteristics detected appear to vary from one satellite to the next. For Europa possible temporal variations are concentrated on the leading, anti-jovian quadrant. Example broadband UV spectra show Europa's spectral slope decreases (and darkens) with time on the leading and anti-jovian hemispheres, but remains essentially constant with time on the trailing hemisphere. The data quality does not support any definitive temporal changes for Ganymede. Possible temporal changes seen in the Callisto data set are concentrated on the jovian hemisphere. Example broadband UV spectra for Callisto show no definitive change in slope with time. The hypothesis is that these temporal differences in UV spectral properties are caused by variations in the surface ice chemistry due to temporal variability in the space environment. It is postulated that the UV spectral changes suggested for Europa may be linked to changes in H₂O₂ concentrations, whereas the changes on Callisto may be linked to variability in SO₂ concentration.