Nitrate in the Greenland ice sheet in the years following the 1908 tunguska event

The Tunguska event on 30 June 1908 has been subjected to much speculation within different fields of research. Publication of the results of the 1961 expedition to the Tunguska area (Florensky, 1963) supports that a cometary impact caused the event. Based on this interpretation, calculations of the impactor energy release and explosion height have been reported by Ben-Menahem (1975), and velocity, mass, and density of the impactor by Petrov and Stulov (1975). Park (1978) and Turco et al., 1981, Turco et al., 1982, used these numbers to calculate a production of ca. 30 × 10⁶ tons of NO during atmospheric transit. This paper presents a high-resolution study of nitrate concentration in the Greenland ice sheet in ca. 10 years covering the Tunguska event. No signs of excess nitrate are found in three ice cores from two different sites in Greenland in the years following the Tunguska event. By comparing these results with results for other aerosols generally found in the ice, the lack of excess NO₃^? following the Tunguska event can be interpreted as indicating that the impactor nitrate production calculated by Park (1978) and Turco et al., 1981, Turco et al., 1982 are 1–2 orders of magnitude too high. To explain this it is suggested, from other lines of reasoning, that the impactor density determined by Petrov and Stulov (1975) probably is too low.     

The occulation of β Scorpii by Jupiter. IV. Diurnal temperature variations and the methane mixing ratio in the Jovian upper atmosphere

The nightime cooling of the Jovian atmosphere near the occulation level of 10¹⁴cm^?3 is calculated using the models of Strobel (1973) and Strobel and Smith (1973). The amount of cooling is found to depend on χ, the methane mixing ratio; μ the mean molecular weight; and the sunrise temperature. Using the range of sunrise (emersion) temperatures observed by Veverka et al. (1974), the overnight cooling is calculated to be 1.5–5.5°K, if reasonable assumptions are made for χ and μ. The argument may be reversed to show that the agreement in measured sunrise and sunset temperatures obtained by other observers of the β Sco occulation implies that χ cannot be significantly greater than the generally accepted value of 7 ×10^?4.     

Near-infrared studies of the satellites of Saturn and Uranus

New JHK photometry and spectrometry (1.4–2.6 μm) are presented for Enceladus, Hyperion, Phoebe, Umbriel, Titania, and Oberon. From spectral signatures, mainly in the 2-μm region, water ice is verified on Enceladus and identified on Hyperion and the three Uranian satellites. The JHK photometry shows that Phoebe is different from all other satellites and asteroids observed thus far. The new photometry corroborates the earlier conclusion by Cruikshank et al. (1977) Astrophys. J217, 1006–1010] that the Uranian satellites, as a class, have overall surface reflectances different from other water-ice-covered satellites, and the reason for the difference remains unclear. The diameters and the masses of the Uranian satellites are reviewed in light of the probable high albedo representative of ice-covered surfaces and the new dynamical studies by Greenberg, 1975, Greenberg, 1976, Greenberg, 1978.     

A laboratory atlas of the 5ν1 NH3 absorption band at 6475 Å with applications to Jupiter and Saturn

The 5ν₁ absorption band of NH₃ is displayed from 6418 to 6550 Å. The total band intensity has been measured: S_B = 0.66 cm^?1m^?1amagat^?1. Line intensities and self-broadening coefficients have been measured for some of the prominent lines. Our line intensities are in good agreement with those of Rank et al. (1966), but are about 2 times greater than those of Mason (1970). The spectrum displayed was obtained photoelectrically at a pressure of 0.061 atm, and shows many more lines than the spectrum obtained by McBride and Nicholls (1972a) at a pressure of 0.39 atm. Therefore, our new measurements can provide the basis for making a more complete rotational analysis than those of McBride and Nicholls (1972a).Since the total band absorption has previously been measured by others on moderate resolution photoelectric scans of the spectra of Jupiter and Saturn, we can use the band intensity to derive the NH₃ abundance in the atmospheres of these two planets. The NH₃ abundances in a single vertical path obtained by this method are about 10m amagat for Jupiter and 2m amagat for Saturn. These results are in agreement with previous results obtained from higher resolution photographic spectra.     

Determination of the cooling rates and nucleation histories of eight group IVA iron meteorites using local bulk Ni and P variation

Cooling rates and nucleation histories of six low-Ni and two high-Ni members of group IVA iron meteorites were calculated by a mid-taenite concentration-taenite lamella width method that included the effects of local bulk Ni and P variation. The local bulk Ni is determined experimentally as described in K. L. Rasmussen [Icarus45, 564–576 (1981)]. The local bulk P parameter, included for the first time in the present work, is estimated from the phase diagram during the simulation. Two parent bodies are suggested for group IVA. The body containing the high-Ni members had a cooling rate (～2°K/My) lower than earlier cooling rate determinations on IVA members. The variable (by a factor of 4) cooling rates found for the low-Ni members imply a raisin origin. The nucleation histories of the meteorites are interpreted as reflecting the very early shock histories of the meteorite parent bodies.     

An explication of the radiometric method for size and albedo determination

A new radiometric model for disk-integrated photometry of asteroids is presented. With empirical support from photometry of Mercury and the Moon, the model assumes that observed sunward beaming of the infrared emission is due to craters. In contrast to earlier theoretical studies of the lunar emission, the observable flux ratio between a cratered sphere and a smooth sphere is calculated for large ranges in wavelength, temperature, and phase angle. Revised diameters and albedos based on the crater model are given for 84 asteroids. The revised values are in good agreement with Morrison's (1977) radiometric results. It is shown that the systematic discrepancy between radiometric and polarimetric albedos (Zellner and Gradie, 1976) is probably a double-valued function of albedo. Some typical geometric albedos from this paper, Morrison (1977), and Zellner and Gradie (1976), respectively, are: Ceres (0.050 ± 0.005, 0.053 ± 0.004, 0.068), Vesta (0.235 ± 0.032, 0235 ± 0.11, 0.271), mean C type (0.031 ± 0.009, 0.035 ± 0.009, 0.061 ± 0.005), mean S type (0.117 ± 0.030, 0.136 ± 0.032, 0.181 ± 0.23), and mean M type (0.105 ± 0.037, 0.115 ± 0.033, 0.157 ± 0.079). Areas of disagreement between radiometry and polarimetry are underscored, and research to resolve them is suggested.     

Absolute spectrophotometry of Neptune: 3390 to 7800 Å

Absolute spectrophotometry of Neptune from 3390 to 7800 Å, with spectral resolution of 10 Å in the interval 3390–6055 and 20 Å in the interval 6055–7800 Å, is reported. The results are compared with filter photometry (Appleby, 1973; Wamsteker, 1973; Savage et al., 1980) and with synthetic spectra computed on the basis of a parameterization proposed by Podolak and Danielson (1977) for aerosol scattering and absorption. A CH₄/H₂ ratio of is derived for the convectively mixed part of Neptune's atmosphere, and constrains optical properties of hypothetical aerosol layers.     

The pole orientation of asteroid 433 Eros determined by photometric astrometry

Refinements to the pole-determination method photometric astrometry (PA) were completed in 1983 (R. C. Taylor and E. F. Tedesco, 1983, Icarus54, 13–22). A goal is to redo the pole analysis for every asteroid whose pole had been determined from earlier versions of PA: Previous PA poles are reviewed in this paper. Asteroid 433 Eros is in that collection and has redone. The result are prograde rotation; a sidereal period of 0.219588 ± 0.000005 day; and a north pole at 22° longitude, +9° latitude. The uncertainty of the pole is 10°. The pole position of Eros determined by C.D. Vesely (1971, In Physical Studies of Minor Planets (T. Gehrels, Ed.), pp. 133–140, NASA SP-267) and Dunlap (1976, Icarus28, 69–78), using earlier versions of photometric astrometry, were within 21 and 7°, respectively, of the present result.     

Spatially resolved absolute spectrophotometry of Saturn: 3390 to 8080 Å

Absolute spectrophotometry of four regions on the visible disk of Saturn (north and south polar regions, equatorial band, south “temperate” region) from 3390 to 8080 Å is reported. Spectral resolution is 10 Å in the interval 3390–6055 Å, and 20 Å; aperture size is 1.92 arcsec. The explicit purpose of our observations was to provide ground-based photometric calibration for the Pioneer Saturn Imaging Photopolarimeter (IPP). We also compare our data with earlier spectrophotometric measurements of Saturn (R.L. Younkin and G. Munch, 1963,Mem. Soc. Roy. Sci. Liege7, 123–136; W.M. Irvine and A.P. Lane, 1971,Icarus16, 10–26; T.B. McCord, T.V. Johnson, and J.H. Elias, 1971,Astrophys. J.165, 413–424) and with the M. Podolak and R.EE. Danielson (1977)Icarus30, 479–492) parameterization of “Axel Dust.” The latter reproduces the broad features but not the details of the observed spectral reflectivity (I/F). We find that large depths of clear molecular hydrogen (>14 km-am in the temperate regions) are needed to match the observed upturn in reflectivity shortward of 3800 Å.     

Variability of carbon monoxide in the mars atmosphere

In January of 1982 we measured a microwave spectrum of CO in the Martian atmosphere utilizing the rotational J = 1 → 2 transition of CO. We have analyzed data and reanalyzed the microwave spectra of R. K. Kakar, J. W. Waters, and W. J. Wilson, (Science196, 1090–1091, 1977, measured in 1975) and J. C. Good and F. P. Schloerb, (Icarus47, 166–172, 1981 measured in 1980) in order to constrain estimates of the temporal variability of CO abundance in the Martian atmosphere. Our values of CO column density from the data of Karar et al., Good and Schloerb, and our own are 1.7 ± 0.9 × 10²⁰, 3.0 ± 1.0 × 10²⁰, and 4.6 ± 2.0 × 10²⁰cm^?2, respectively. The most recent estimate of CO column density from the 1967 infrared spectra of J. Connes, P. Connes, and J.P. Maillard, (Atlas de Spectres Infarouges de Venus, Mars, Jupiter, et Saturne, Editions due Centre National de la Recherche Scientifique, Paris, 1969), is 2.0 ± 0.8 × 10²⁰ cm^?2 (L.D.G. Young and A.T. Young, Icarus30, 75–79, 1977). The large uncertainties given for the microwave measurements are due primarily to uncertainty in the difference between the continuum brightness temperature and atmospheric temperatures of Mars. We have accurately calculated the variation among the observations of the continuum (surface) brightness temperature of Mars, which is primaroly a function of the observed aspect of Mars. A more difficult problem to consider is variability of global atmospheric temperatures among the observations, particularly the effects of global dust storms and the ellipticity of the orbit of Mars. The large bars accompanying our estimates of CO column density from the three sets of microwave measurements are primarily caused by an assumed uncertainty of ±10°K in our atmospheric temperature model due to possible dust in the atmosphere. A qualitative consideration of seasonal variability of global atmospheric temperatures among the measurements suggests that there is not strong evidence for variability of the column abundance of CO on Mars, although variability of 0–100% over a time scale of several years is allowed by the data set. The implication for the variability of Mars O₂ is, crudely, a factor of two less. We found that the altitude distribution of CO in the atmosphere of Mars was not well constrained by any of the spectra, although our spectrum was marginally better fitted by an altitude increasing profile of CO mixing ratios.     

Neptune's rotation period: A correction and a speculation on the difference between photometric and spectroscopic results

An error in the Hayes and Belton (1977), Icarus32, 383–401) estimate of the rotation period of Neptune is corrected. If Neptune exhibits the same degree of limb darkening as Uranus near 4900 Å, the rotation period is 15.4 ± 3 hr. This value is compatible with a recent spectroscopic determination of Munch and Hippelein (1979) who find a period of 11.2_?1.2^+1.8 hr. However, if, as indirect evidence suggests, the law of darkening on Neptune at these wavelengths is less pronounced than on Uranus, then the above estimates may need to be lengthened by several hours. Recent photometric data are independently analyzed and are found to admit several possible periods, none of which can be confidently assumed to be correct. The period of Neptune most probably falls somewhere in the range 15–20 hr. The Hayes-Belton estimate of the period of Uranus is essentially unaffected by the above-mentioned error and remains at 24 ± 4 hr. All observers agree that the rotation period of Uranus is longer than that of Neptune.     

Infrared spectrum of Io, 2.8–5.2 μm

The reflectance spectrum of Io is presented from 2.8 to 5.2 μm, extending the earlier results of D. P. Cruikshank, T. J. Jones, and C. B. Pilcher (1978, Astrophys. J. 225, L89–L92), and demonstrating the full extent of the broad and deep spectral absorption between 3.5 and 4.8 μm. Laboratory spectra of nitrates and carborates diluted with sulfur do not satisfactorily reproduce the Io spectrum, but new information based on the recently discovered volcanic activity on the satellite lead to consideration of other classes of compounds as reported in a companion paper (F. P. Fanale, R. H. Brown, D. P. Cruikshank, and R. N. Clark, 1979, Nature280, 761–763).     

Methane absorption in the Jovian atmosphere I. The Lorentz half-width in the 3v3 band at 1.1 μm

The Lorentz half-width α_L, of the fine-structure components of the methane 3v₃R-branch in the Jovian spectrum has been measured from photoelectric observations of the singlet R(1). A value of α_L = 0.088_?0.011^+0.015Å, or 0.072_?0.009+0.009 cm^?1, has been found. Curves of growth for the 3v₃R-branch manifolds have been calculated, using the measured value of α_L and assuming a reflecting-layer atmosphere. The Walker-Hayes (1967) equivalent widths have been reanalyzed for rotational temperature and methane abundance. The half-width derived here is significantly different from a similar measurement made by C. B. Farmer (1969). The source of the discrepancy remains obscure.     

Interpretation of the infrared polarization of Venus

A contradiction in the sulfuric acid cloud hypothesis of Venus, i.e., nondetection of 4.8 μm polarization by Landau (1975), is examined on the basis of the multiple scattering calculations for the cloud model of Hansen and Hovenier (1974) including an internal heat source. Results show that the polarized thermal component cannot depolarize the scattered sunlight, and therefore a large polarization of about 13% is expected at a phase angle of 110° and wavelength of 4.8 μm, in contrast with Landau's measurements. Our computations are, however, in agreement with the measurements by S. Sato et al. (in “Proceedings, 10th Lunar and Planetary Symposium,” pp. 179–182. Institute of Space and Aeronautical Science, University of Tokyo, July 11–13, 1977).     

Martian CO abundance from the J = 1 → 0 rotational transition: Evidence for temporal variations

Mars was observed in the CO (J = 1 → 0) 2.6-mm wavelength line between 29 March and 1 April, 1980. The data were analyzed using a model atmosphere based on Viking measurements. A least-squares fit of the model to the observed line profile yielded an average CO mixing ratio of (3.2 ± 1.1) × 10^?3. This value is four times larger than that obtained by L. D. Kaplan, J. Connes, and P. Connes, 1969 (Astrophys. J.157, L187-L195) from analysis of an infrared spectrum obtained in 1967 by J. Connes, P. Connes, and J. P. Maillard, 1969 (Atlas of Near Infrared Spectra of Venus, Mars, Jupiter, and Saturn, Centre National de la Recherche Scientifique, Paris). Models of the Martian atmospheric chemistry indicate that this implied temporal variation could easily exist and that it would be due primarily to variations in the abundance of H₂O.     

Application of a radiative transfer model to bright icy satellites

A radiative transfer model, derived largely from the work of B.W. Hapke (1981, J. Geophys. Res.86, 3039–3054) and J.D. Goguen (1981, Ph.D. thesis, Cornell University, Ithaca, N.Y.), is fit to Voyager imaging observations of Europa, Mimas, Enceladus, and Rhea. It is possible to place constraints on the single-scattering albedo, the porosity of the optically active upper regolith, the single-particle phase functions, and, in the cases of Europa and Mimas, the mean slope angle of macroscopic surface features. The texture of the surfaces of the Saturnian satellites appears to be similar to the Earth's moon. However, Europa is found to have a distinctly more compact regolith and a more forward-scattering single-particle phase function.     

The mantle of Mars: Some possible geological implications of its high density

The density of the Martian mantle is estimated to be about 3.55 g/cm³ (Reasenberg, 1977). Model mineral assemblages for the Martian mantle (at 30 kbar) were calculated using a modified CIPW norm scheme by adding FeO to model terrestrial mantle compositions. The density of the resulting mineral assemblages vary with increasing FeO content. With pyrolite starting compositions for the terrestrial mantle, the resulting model Martian mantle with density of 3.55 g/cm³ is not garnet-lherzolite like the Earth; rather it is an assemblage properly called oxide-garnet wehrlite: oxide (periclase-wüstite) 2%; garnet 11%; olivine 73%; clinopyroxene 12%; with no orthopyroxene. Partial melting of such an assemblage wouldyield iron-rich, ultrabasic lavas, with extremely low viscosities. Specifically, model partial melts, assuming production from the quaternary eutectic (inferred to be near: op₇ g_{42 cpx43} ox₈) yields an ultrabasic (SiO₂, 41 to 44%) picritic alkali-basaltic melt (norm composition ne 2.5, plag 32, or 2.4, di 20, ol 37, mt 4.4 and ilm, tr), with a computed viscosity of about 12 P at 1200°C. This model for the composition of the Martian surface lavas (derived from geophysical data and petrologic arguments) is in remarkable agreement with a recently published model by Maderazzo and Huguenin (1977) (derived from reflection spectroscopy, experimental and theoretical models for weathering in the Martian environment). The result also appears to be consistent with recent interpretations (Rasool and Le Sergeant, 1977) of Viking atmospheric chemistry results, namely that the Martian crust is potassium poor. There are a number of geological implications which follow, including (1) superfluid lavas may account for some flood and erosional features observed on Mars; (2) the XRF inorganic chemistry experiment on Vikings 1 and 2 (Baird, 1976) indeed may be measuring compositions approaching primary lavas, contrary to current interpretations which favor a rather mature (weathered) soil; (3) ultrabasic (ferrokimberlitic) ash might be a major constituent of the Martian soil, especially if cosmological models concerning the incorporation of a much volatile material within the early accreting Mars are correct—a matter of current debate; (4) a number of mineral assemblages not previously considered are possible in the Martian mantle depending principally on the activity of volatile substances, (S, O, C, H); it is possible that some very unusual magmas are produced on partial melting; and (5) some ferro-granite melts might be produced by liquid immiscibility.     

Growth and sedimentation of dust grains in the primordial solar nebula

Of the formation processes in the solar system, the process of growth and sedimentation of dust grains in the primordial solar nebula is investigated for a region near the Earth's orbit. The growth equation for dust grains, which are sinking as well as being in thermal motion, is solved numerically in the wide mass range between 10^?12 and 10⁶ g. Any turbulent motions in the nebula are assumed to have already decayed when the sedimentation begins. The numerical simulation shows that the growth and sedimentation proceed faster than was found by Kusaka et al. (1970) but in accordance with the estimate of Safronov (1969) owing to a cooperative interaction of the growth and the sedimentation; that is, at about 3 × 10³ years after the beginning of the growth and sedimentation a dust layer, composed of centimeter-sized grains, is formed at the equator of the solar nebula. Furthermore, the mass density of dust grains floating in the outer layers of the nebula is found to be of the order of 10^?5 after 10⁵ years compared with that before the sedimentation. From these results, it can be estimated that at about 5 × 10³ years after the beginning of sedimentation the dust layer breaks up owing to the onset of gravitational instability.     

Interpretation of the 6818.9-Å methane feature observed on Jupiter,Saturn, and Uranus

High-resolution (0.1-Å) spectra of the 6818.9-Å methane feature obtained for Jupiter, Saturn, and Uranus by K. H. Baines, W. V. Schempp, and W. H. Smith ((1983). Icarus56, 534–542) are modeled using a doubling and adding code after J. H. Hansen ((1969). Astrophys. J.155, 565–573). The feature's rotational quantum number is estimated using the relatively homogeneous atmosphere of Saturn, with only J = 0 and J = 1 fitting the observational constraints. The aerosol content within Saturn's northern temperate region is shown to be substantially less than at the equator, indicating a haze only half as optically thick. Models of Jupiter's atmosphere are consistent with the rotational quantum-number assignment. Synthetic line profiles of the 6818.9-Å feature observed on Uranus reveal that a substantial haze exists at or above the methane condensation region with an optical depth eight times greater than previously reported. Seasonal effects are indicated. The methane column abundance is 5 ± 1 km-am. The mixing ratio of methane to hydrogen within the deep unsaturated region of the planet is 0.045 ± 0.025, based on an H₂ column abundance of 240 ± 60 km-am (W. H. Smith, W. Macy, and C. B. Pilcher (1980). Icarus43, 153–160), thus indicating that the methane comprises between one-sixth and one-half of the planet's mass. However, proper reevaluation of H₂ quadrupole features accounting for the haze reported here may significantly reduce the relative methane abundance.     

A possible rotation period for the minor planet 164 Eva

The minor planet 164 Eva passed through opposition on December 1, 1975 with a magnitude B_opp = 11.3 mag. Photoelectric observations at the Observatory of Torino, Italy, were carried out in two nights on Oct. 27/28 and Nov. 11, each with a run of about 3 hr. Two further successful photoelectric observations were carried out at the OHP, France, each with a run of about 6 hr. From all observed parts of the lightcurve a resulting synodic period of rotation of about 27.3 hr can be deduced, with a range of the total amplitude of at least Δm = 0.07 mag. With this period of 27.3 hr the minor planet 164 Eva is one more long period object, falling now between 654 Zelinda (H. J. Schober, 1975, Astron. Astrophys.44, 85–89) and 139 Juewa (J. Goguen et al., 1976, Icarus29, 137–142), at the high end in the histogram of the distribution of minor planet rotation periods.