张家口组火山岩SHRIMP定年及其重大意义

区域地质填图表明,在燕山地区,近E－W走向展布的中、晚侏罗世髫髻山组火山岩和土城子组红层,被NE走向展布的张家口组火山岩不整合覆盖（河北省地质局,１９８９）。这一不整合被认为是该区燕山主造山幕的标志,代表中国东部构造带从近E－W走向彻底转变成NE走向的转折点（任纪舜等,１９９０,１９９６,１９９９）。为了查明这一构造转折点的时代,我们近几年再次在冀北滦平盆地和承德盆地进行详细的野外调查和采样,以便准确厘定这一重大构造事件的年代。现将最新取得的SHRIMP测年结果简要报道如下。SHRIMP测年样品：样品CDM…     

Paleomagnetic stratigraphy of younger basalts and intercalated plio-pleistocene tillites in Iceland

Summary This paper deals with the Plio-Pleistocene Graue Stufe in Eastern Iceland, which forms the upper part of the islands enormous pile of plateau basalts. A stratigraphy of the Graue Stufe has been established by using both paleomagnetic and petrographic criteria. Also the number and the stratigraphic position of the intercalated indurated moraines, the tillites, has been ascertained.The Graue Stufe embraces the N₂, R₁ and the lower part of the N₁ paleomagnetic period. Petrographically the lava series contains tholeiites, porphyritic basalts and olivine basalts in a fairly irregular succession.Several tillites are intercalated in the lavas. The lowermost tillites are found in the middle part of the N₂ series. As the N₂ period is of pre-Quarternary age, glaciations in Iceland must have occurred already in the Pliocene.The results from Eastern Iceland have been compared with those of some other localities of the Graue Stufe in Iceland.The paleomagnetic stratigraphy is hampered by the occurrence of some flows, showing inverted remanent magnetization. Such inverted flows are locally found both in the N₂ series and in the R₁ series. This may be ascribed to extra, short periodical reversals of the geomagnetic field.     

Obsidian hydration dating of volcanic events

Obsidian hydration dating of volcanic events had been compared with ages of the same events determined by the ¹⁴C and KAr methods at several localities. The localities, ranging in age from 1200 to over 1 million yr, include Newberry Craters, Oregon; Coso Hot Springs, California; Salton Sea, California; Yellowstone National Park, Wyoming; and Mineral Range, Utah. In most cases the agreement is quite good. A number of factors including volcanic glass composition and exposuretemperature history must be known in order to relate hydration thickness to age. The effect of composition can be determined from chemical analysis or the refractive index of the glass. Exposure-temperature history requires a number of considerations enumerated in this paper.     

火山灰锆石U-Pb定年在沉积岩定年上的应用

本文系统总结了沉积岩定年的意义和常用的定年手段,详细介绍了火山灰锆石U-Pb定年在沉积岩定年上的应用。从火山事件层的分布、火山灰夹层的识别、火山灰锆石的区分、应用实例等方面对前人的研究进行概述,旨在为科研工作者运用火山灰锆石U-Pb定年提供借鉴经验。与传统的成岩矿物K-Ar/Ar-Ar和Rb-Sr定年技术相比,火山灰锆石U-Pb定年在沉积岩定年上具有显著的优势。火山灰夹层具有广泛性和等时性,且锆石U-Pb同位素体系不容易受到扰动,因此火山灰锆石U-Pb定年是高精度沉积岩定年的首选方案。沉积岩定年涉及到野外观察、样品采集、室内岩相学观察及地质年代学分析和年龄解释等多个环节。在这些环节中,识别火山灰夹层是最关键的一点,也是一大难点。这需要明确火山灰夹层的岩石类型并了解火山事件沉积层的分布,在此基础上通过野外观察和室内研究进一步判别,这样可以更加准确地识别出火山灰夹层。此外,火山灰锆石定年需要区分火山灰锆石、碎屑锆石、继承/捕获锆石,可以通过矿物形态学和矿物化学特征来加以区分。

     

Nature of alkalic volcanic rock series

The alkalic rocks are here regarded as a category in a classification of igneous rock series (rock associations) and not as a class in petrographic systematics. The alkalic series as a whole are characterized by higher Na₂O+K₂O content than the subalkalic series in the alkali vs. SiO₂ diagram.At least three different trends (types) of differentiation appear to exist in large-scale alkalic volcanic associations. One (here designated as the Kennedy trend) starts from weakly nepheline-normative basalt and shows increasing normative nepheline with advancing fractionation to reach a phonolitic composition. Another (here called the Coombs trend) starts from hypersthene-normative basalt and shows increasing normative hypersthene and then normative quartz with advancing fractionation to reach a comenditic composition. Besides these two trends, it seems that many alkalic associations exist which show a differentiation trend starting from nepheline-normative basaltic composition and leading to hypersthenenormative, and then to quartz-normative compositions (here designated as the straddle-B type).Alkalic rocks of these three trends are higher not only in Na₂O+K₂O but also in Rb, Ba, Sr and Zr than subalkalic rocks. The alkalic basalts as a whole are characterized by higher contents of such elements and not by any degree of silica undersaturation. It is widely believed that alkalic rocks are characterized by the presence of normative nepheline as well as by the absence of orthopyroxene and pigeonite. Indeed such a relationship holds for the Kennedy trend, but it is not always valid for other types of alkalic associations. Some alkalic rocks of the Coombs trend and straddle-B type have quartz (or other silica minerals) and orthopyroxene and pigeonite.     

Paleomagnetic constraints on the paleogeography and oroclinal bending of the Devonian volcanic arc in Kazakhstan

Numerical modelling, incorporating coupling between surface processes and induced flow in the lower continental crust, is used to address the Quaternary evolution of the Gulf of Corinth region in central Greece. The post-Early Pleistocene marine depocentre beneath this Gulf overlies the northern margin of an older (Early Pleistocene and earlier) lacustrine basin, the Proto Gulf of Corinth Basin or PGCB. In the late Early Pleistocene, relief in this region was minimal but, subsequently, dramatic relief has developed, involving the creation of  900 m of bathymetry within the Gulf and the uplift by many hundreds of metres of the part of the PGCB, south of the modern Gulf, which forms the Gulf's main sediment supply. It is assumed that, as a result of climate change around 0.9 Ma, erosion of this sediment source region and re-deposition of this material within the Gulf began, both processes occurring at spatial average rates of  0.2 mm a^− 1. Modelling of the resulting isostatic response indicates that the local effective viscosity of the lower crust is  4 × 10¹⁹ Pa s, indicating a Moho temperature of  560 °C. It predicts that the  10 mm a^− 1 of extension across this  70 km wide model region, at an extensional strain rate of  0.15 Ma^− 1, is partitioned with  3 mm a^− 1 across the sediment source,  2 mm a^− 1 across the depocentre, and  5 mm a^− 1 across the ‘hinge zone’ in between, the latter value being an estimate of the extension rate on normal faults forming the major topographic escarpment at the southern margin of the Gulf. This modelling confirms the view, suggested previously, that coupling between this depocentre and sediment source by lower-crustal flow can explain the dramatic development in local relief since the late Early Pleistocene. The effective viscosity of the lower crust in this region is not particularly low; the strong coupling interpreted between the sediment source and depocentre results instead from their close proximity. In detail, the effective viscosity of the lower crust is expected to decrease northward across this model region, due to the northward increase in exposure of the base of the continental lithosphere to the asthenosphere; in the south the two are separated by the subducting Hellenic slab. The isostatic consequences of such a lateral variation in viscosity provide a natural explanation for why, since  0.9 Ma, the modern Gulf has developed asymmetrically over the northern part of the PGCB, leaving the rest of the PGCB to act as its sediment source.     

长白山地区最近一次火山喷发的热释光年龄

长白山天池在近代和历史时期有过多次喷发 ,目前仍具潜在喷发危险。因此 ,确定最后一次喷发的时代具有重要意义。在长白山白云峰至天池的坡上采集了粗面岩样品 ,通过热释光测年法中的前剂量技术测定 ,获得了各样品的 TL年龄 ,由于原先的粗面岩受到了后期火山活动时岩浆的高温烘烤 ,其热释光年龄代表了天池最后一次喷发的时代 ,距今约 5 33± 2 6 6年     

Successful application of uranium series dating of fossil bone

A novel approach to uranium series disequilibrium dating is presented and used successfully to date bones from several European archaeological and palaeontological sites. A method is described based on a proposed mechanism of uranium uptake and fixation derived from present understanding of the biochemistry of fossilizing bones and the geochemistry of uranium. Stability of uranium in fossil bone is predicted under particular conditions of local depositional environment, and the importance of the inhomogeneous distribution of uranium through bone to uranium-series dating is explained. Sample bones from several different sites have been examined, taking into account the three factors of uptake mechanism, uranium distribution and sedimentary environment, and have yielded ages in good agreement with those derived by alternative dating methods or from chronologically fixed stratigraphical positions.     

Comparison of SAR techniques for luminescence dating of sediments derived from volcanic tuff

In this investigation we evaluate several proposed optically stimulated luminescence single-aliquot regeneration (OSL SAR) procedures to determine which technique has the greatest potential to yield accurate ages for samples collected from tuff-derived alluvial sediments within the narrow, sharply incised canyon systems of the Pajarito Plateau of northern New Mexico. The SAR data collection methods evaluated are: infrared-stimulated luminescence (IRSL), post-IR blue-OSL, IRSL with TL annealing cycles on polymineral fine-grains, and blue-OSL on quartz fine sand. A single-grain laser luminescence (SGLL) procedure for quartz sand is also evaluated. Age estimates obtained from these methods are compared with radiocarbon, soil PDI (profile development index), and IRSL multi-aliquot additive dose (MAAD) age constraints. Our results indicate that the modal D_e of quartz sand SGLL dose distributions yield ages that are consistent with radiocarbon and PDI age constraints for the tuff derived sediments in this investigation and appears to be the most promising method for studies in this area. Additionally, two fine-grained polymineral methods, IRSL SAR and traditional IRSL MAAD, produced ages that were generally in agreement with the SGLL ages and with available ¹⁴C and PDI age constraints. At the present stage of research, we advocate using quartz sand SGLL in conjunction with IRSL SAR or even IRSL MAAD for polymineral fine-grains to provide the most robust and reliable luminescence age data sets for tuff-derived sediments.     

Paleomagnetic Results of th Red Soil Volcanic Rock Series of Yingfengling Section,Southern Leizhou Peninsula

The Yingfengling scetion composed of red soil and volcanic rocks can be distinguished into 8 stratigraphic units and 4 red soil-volcanic rock cycles.64 paleomagnetic-orientated samples were collected from the bottom to the top of the section.Naturel remanent magnetization and magnetic susceptibility were firstly measured.All the samples were stepwisely treated with thermal or/and alternating fields.Four clear polarity segments were recorded in the section.Compared with the geo-magnetc polarity scale,the section was formed since the late Olduvai subchron,about 1.37Ma.B.P.     

Oroclinal bending of the Middle and Late Paleozoic volcanic belts in Kazakhstan: Paleomagnetic evidence and geological implications

Paleomagnetic data on Middle- and Late-Paleozoic rocks from the central part of the Ural-Mongolian Belt in Kazakhstan are considered. The primary remanences in the Permian rocks and secondary magnetization components of the same age in pre-Permian rocks of central and northern Kazakhstan are not rotated relative to the East European Platform. In southern Kazakhstan adjoining the Tien Shan almost all data point to large, up to 90°, counterclockwise rotation of blocks. These rotations, related to the regional wrench fault zone, must be subtracted from older paleomagnetic data to ensure their correct interpretation. The paleomagnetic declinations in Upper Carboniferous rocks coincide more or less over all of Kazakhstan, whereas the Silurian and Early Devonian declinations in the north and south of Kazakhstan differ approximately by 180°. It can be suggested that the Devonian volcanic belt, having a horseshoe outline, was initially an almost rectilinear NW-trending feature. Its oroclinal bending took place in the Devonian and Early Carboniferous and completed by the Late Carboniferous. We compared the model of the Kazakh Orocline based on paleomagnetic data with the geological events in this territory. It turned out that a slow bending of an initially rectilinear subduction zone is consistent with lateral migration of active volcanism and folding inside a developing loop, whereas extension outside the loop was accompanied by subsidence and rifting. In general, the proposed model connects the main tectonic events in Kazakhstan with the movements established from paleomagnetic data.     

相山火山-侵入杂岩的反方向岩浆演化系列研究

相山因是中国最大火山岩型铀矿产地而倍受关注,相山火山-侵入杂岩从喷发-侵出-侵入,SiO2含量、Rb/Sr、Rb/Ba比值降低,而TFe（Fe2O3＋FeO）、CaO、MgO、TiO2、P2O5含量、SI（固结指数）、δEu则呈增高趋势,岩浆演化与正常岩浆房酸度逐渐增高的岩浆分异趋势相反,称反方向岩浆演化系列.不相容元素的比值如Th/U、Rb/Ba、Th/Nb、Th/Ta、La/Nb、Nb/Ta变化幅度较大,与SiO2组分没有明显的正消长或反消长关系,稀土配分曲线也不尽一致,火山喷发相、侵出相和侵入相岩石具有不同的源区性质.     

K-Ar dating on volcanic rocks in the Bonin Islands and its tectonic implication

The K-Ar dating method was applied to the volcanic rocks, the boninite and related rocks, from the Bonin Islands. Four fresh samples gave K-Ar ages of about 40 Ma. These ages suggest that the main volcanism of the Bonin Islands occurred about 40 Ma ago, as a result of the initiation of subduction of the Pacific plate at its western margin. Results of the K-Ar dating on other rocks suggest that some volcanism or thermal disturbance may have occurred 5 ~ 10 Ma ago, at least, in Chichijima.     

Statistical control chart for regime identification in volcanic time series

In an important paper, Mulargia et al. (1987) address the importance of quantitative and objective identification of different regimes of a volcano. They develop a procedure based on the two-sample Kolmogorov-Smirnov (K-S) statistic. The K-S test is a general-purpose test that discriminates between two data sets as belonging to two different regimes based on their empirical distribution functions. The empirical distribution function is designed to describe the aggregate behavior of the volcanic activity, and it is constructed from the orders of the length of the collected repose times in each data set. In this article, we use the idea of statistical process control to distinguish between the variation inherent in the observed repose times and the extraordinary variation that signals a real change in the regimes. We construct a table of control limits, and we demonstrate the procedure of regime identification based on a simple control chart. It shows a point outside the control limits almost as soon as the process enters a new regime. The basis of the statistical process control mechanism is a simple Poisson process, which is state of the art. The proposed control charting procedure is an eruption by eruption procedure, which follows the original chronological order of the eruptions. This procedure is applied to the eruptive history of the Mount Etna volcano. The application shows schematically that the procedure presents a visual interpretation of the identified regimes and can be practically translated for tabular or manual use.     

3.8 Ma:青藏高原年轻碱性玄武岩锆石离子探针U-Pb年龄测定

离子探针(SHRIMP)是一种主要用于锆石U-Pb年龄测定的仪器,已获得了大量有意义的年龄数据,但十分年轻地质体锆石年龄测定方面的报道还不多见.报道了北京离子探针中心应用SHRIMP技术测定青藏高原晚第三纪3.8 Ma碱性玄武岩的年龄结果,同时讨论了获得十分年轻地质体高精度锆石U-Pb年龄的条件.     

The Coso volcanic field reexamined: Implications for obsidian sourcing and hydration dating research

Obsidian from the Coso locality, Inyo County, California, has long been regarded by archaeologists as a single “source.” However, studies by the U.S. Geological Survey have provided evidence of geochemical variability among flows within the volcanic field. to determine whether these geochemical distinctions could be applied productively to archaeological research, nondestructive x-ray fluorescence analyses were conducted on samples recently collected from 15 obsidian-bearing loci. the results of this research show that geochemically distinct varieties of artifact-quality obsidian can be recognized within the Coso volcanic field, and subsequent nondestructive x-ray fluorescence analyses of artifacts from two nearby archaeological sites document that different geochemical varieties of obsidian were used prehistorically to manufacture tools. Implications of these results for studies of prehistoric exchange and obsidian hydration dating are discussed.     

Paleomagnetic dating of Alleghanian orogenesis and mineralisation in the Mascot–Jefferson City zinc district of East Tennessee, USA

The Mascot–Jefferson City (M-JC) Mississippi Valley-type (MVT) deposits are in the Valley and Ridge province of the Appalachian orogen in East Tennessee. They have been a major source of zinc for the USA but their age is uncertain and thus their genesis controversial. About 10 specimens from each of 37 sites have been analysed paleomagnetically using alternating field and thermal step demagnetisation methods and saturation isothermal remanence methods. The sites sample limestones, dolostones, breccia clasts and sphalerite–dolomite MVT mineralisation from mines in the Lower Ordovician Kingsport and Mascot formations of the Knox Group. The characteristic remanent magnetisation (ChRM) is carried by magnetite in the limestones, by both magnetite and pyrrhotite in the dolostones and by pyrrhotite preferentially to magnetite in the mineralisation. Mineralized sites have a more intense ChRM than non-mineralised, indicating that the mineralising and magnetisation event are coeval. Paleomagnetic breccia tests on clasts at the three sites are negative, indicating that their ChRM is post-depositional remagnetisation, and a paleomagnetic fold test is negative, indicating that the ChRM is a remagnetisation, and a post-dates peak Alleghanian deformation. The unit mean ChRM direction for the: (a) limestones gives a paleopole at 129°E, 12°N (d_p=18°, d_m=26°, N=3), indicating diagenesis formed a secondary chemical remanent magnetisation during the Late Ordovician–Early Silurian; (b) dolomitic limestones and dolostone host rocks gives a paleopole at 125.3°E, 31.9°N (d_p=5.3°, d_m=9.4°, N=7), recording regional dolomitisation at 334±14 Ma (1σ); and (c) MVT mineralisation gives a paleopole at 128.7°E, 34.0°N (d_p=2.4°, d_m=4.4°, N=25), showing that it acquired its primary chemical remanence at 316±8 Ma (1σ). The mineralisation is interpreted to have formed from hydrothermal fluid flow, either gravity or tectonically driven, after peak Alleghanian deformation in eastern Tennessee with regional dolomitisation of the host rocks occurring as part of a continuum during the 20 Ma prior to and during peak deformation.     

碧口群火山岩的时代——SHRIMP锆石U—Pb测年结果

碧口群火山岩系是从原碧口系(叶连俊等,1944,后称碧口群)中解体出来的一个岩石单元(陶洪祥等,1993)。虽经过近60年的研究,但对某些关键问题,特别是碧口群火山岩系的时代,仍存在不同认识。在早期研究阶段(20世纪40～50年代)和60～70年代的区域地质调查工作中,碧口群和横丹群被视做一个整体,并通过地层层序关系探讨其时代。如,叶连俊等(1944)提出碧口系形成于志留—泥盆纪,黄振辉(1959)则认为碧口群属寒武—志留系。80年代以来对碧口群火山岩系进行的同位素年代学和地古生物学研究给出了从新元古代(赵祥生等,1990;胡正东,1990;李耀敏,1991;秦…     

羌北-昌都地块那益雄组火山岩锆石U-Pb年代学及地球化学特征

本文对青藏高原羌北-昌都地块阿布日阿加措地区的晚二叠世那益雄组火山岩进行了年代学和地球化学研究。该火山岩主要由玄武岩、安山玄武岩、安山岩、流纹岩、凝灰岩组成,具有碱性玄武岩到酸性熔岩的特征。锆石U-Pb年代学研究表明该火山岩的形成时代为251. 1±4. 8～249. 6±1. 3 Ma之间。地球化学分析结果表明,该地区的流纹岩具有高的Si O2(74. 85%～77. 55%)和Na2O+K2O(5. 40%～6. 61%)含量,较低的MgO、K2O和Ca O含量,Al2O3含量低且稳定,里特曼指数平均为1. 15,小于3. 3。安山岩Si O2含量55. 13%～56. 28%,Na2O+K2O含量4. 13%～6. 15%,里特曼指数平均为2. 20,小于3. 3,属于钙碱性安山岩。碱性玄武岩Si O2含量51. 49%,Na2O+K2O含量6. 34%,里特曼指数为4. 73,属于碱性系列。稀土元素配分曲线为富集LREE的右倾型。另外,富集大离子亲石元素(LILE) Th、U,亏损高场强元素(HFSE) Nb、Ta等特征,均说明羌北-昌都地块阿布日阿加措地区的火山岩形成于陆缘岛弧环境。     

铀系年代学新进展——ICP-MS230Th测年

20世纪80年代中叶,R.L.Edwards等发展出TIMS230Th测年后,αcounting方法便逐步被摈弃。TIMS方法使测年精度提高了1～2个数量级,所需样品量和测量时间也大为减少。