明沟排水与竖井排灌

本文在分析干旱细土平原区水文地质条件的基础上 ,论述了盐渍化地区在不同排水条件下水中盐份的运移和积聚的过程 ,比较了明沟排水和竖井排灌的优劣 ,从而提出竖井排灌是改良土壤盐渍化 ,防止土壤返盐的有效措施     

Investigation of slope instability induced by seepage and erosion by a particle method

A novel particle based Bluff Morphology Model (BMM) developed by the authors is extended in this paper to investigate the effect of two dimensional seepage on the stability and collapse of soil slopes and levees. To incorporate the seepage in the model, Darcy’s law is applied to the interactions among neighbouring soil particles and ghost particles are introduced along the enclosed soil boundary so that no fluid crosses the boundary. The contribution of partially saturated soils and matric suction, as well as the change in hydraulic conductivity due to seepage, are predicted well by the present model. The predicted time evolution of slope stability and seepage induced collapse are in reasonable agreement with the experimental results for homogeneous non-cohesive sand and multiple layered cohesive soils. Rapid drawdown over a sand soil is also investigated, and the location and time of the levee collapse occurrence are well captured. A toe erosion model is incorporated in the BMM model, and the location and quantity of erosion from lateral seepage flow is well predicted. The interplay of erosion, seepage and slope instability is examined.     

Adsorption of aluminium by a latosol as affected by phosphate and glutamic acid

The effect of phosphate and glutamic acid on adsorption of aluminium onto a latosol was investigated as a function of pH and ligand concentrations through batch equilibrium experiments. The results showed that adsorption of aluminium by the soil was enhanced after addition of phosphate at low pH, and this promotive effect was gradually eliminated with the increase in pH. The positive effect of phosphate on aluminium adsorption onto latosol was attributed to phosphate-induced surface negative charge and formation of ternary surface complexes involving aluminium and phosphate. While using silica as adsorbent, the inactive surfaces for phosphate, promotion of adsorption of aluminium by phosphate was also found. Then it was proposed that additional aluminium might bind to the phosphate adsorbed onto the silica in the form of surface complexes silica–aluminium–phosphate again, and the mechanism might operate in the soil systems as well. Glutamic acid exhibited no influence on the adsorption of aluminium by the soil at low pH. After increasing the pH, adsorption of aluminium was inhibited especially with the highest addition of glutamic acid, probably owing to weak affinity of complexes between glutamic acid and aluminium to the soil.     

Aqueous pyrite oxidation by dissolved oxygen and by ferric iron

Rates of aqueous, abiotic pyrite oxidation were measured in oxygen-saturated and anaerobic Fe(III)-saturated solutions with initial pH from 2 to 9. These studies included analyses of sulfite, thiosulfate, polythionates and sulfate and procedures for cleaning oxidation products from pyrite surfaces were evaluated. Pyrite oxidation in oxygen-saturated solutions produced (1) rates that were only slightly dependent on initial pH, (2) linear increases in sulfoxy anions and (3) thiosulfate and polythionates at pH > 3.9. Intermediate sulfoxy anions were observed only at high stirring rates. In anaerobic Fe(III)-saturated solutions, no intermediates were observed except traces of sulfite at pH 9. The faster rate of oxidation in Fe(III)-saturated solutions supports a reaction mechanism in which Fe(III) is the direct oxidant of pyrite in both aerobic and anaerobic systems. The proposal of this mechanism is also supported by theoretical considerations regarding the low probability of a direct reaction between paramagnetic molecular oxygen and diamagnetic pyrite. Results from a study of sphalerite oxidation support the hypothesis that thiosulfate is a key intermediate in sulfate production, regardless of the bonding structure of the sulfide mineral.     

锚杆桩加固基础与掏土纠偏施工的实践

介绍了利用锚杆静压桩加固基础与沉井掏土纠偏方法纠治某厂房的施工过程，先用锚杆静压桩加固厂房基础，然后再用沉井掏土法纠治厂房，使偏斜率由３２‰纠到了３‰的安全界限。     

节理产状分组的k均值聚类分析及其分组结果的费歇尔分布验证法

裂隙岩体内的节理往往是变化的,有时甚至变化很大。测得大量节理产状以后,对其分组是一项基础性的工作,但是如何分组目前还没有很好的理论和方法。采用快速聚类分析的方法,将节理产状的样本数据划分为不同的簇,利用极大似然估计的原理,通过数值方法求解费歇尔概率分布模型的参数,并用皮尔逊检验说明了费歇尔逊概率模型的有效性。通过不同簇的概率模型计算及其簇心的分布特性比较说明了簇数分类的适度性。利用所提出的快速聚类分析方法及其推导的计算公式,可以方便地求解费歇尔分布的参数。结合皮尔逊检验,形成了解决这类问题的系统实用的方法。     

Theoretical Equations of Vertical and Radial Consolidation by Equating Degrees of Consolidation by Settlement Analysis and Dissipation of Pore Pressure

Degree of consolidation, U, is defined in two ways: (1) by settlement analysis and (2) by dissipation of pore pressure. Equations of vertical and radial consolidations are derived by equating the above two U. The new equations are compared with the existing equations of vertical and radial consolidations. It is shown that new equation of radial consolidation is exactly same as Barron’s equation of equal strain radial consolidation while in case of vertical consolidation it is similar to later part of Terzaghi’s equation of vertical consolidation. A few possible reasons and advantages of comparison are given. The theory of rapid loading methods is based on the equality of these two degrees of consolidations. It is concluded that in rapid loading methods the next load increment can be applied at any time in radial consolidation once the effects of initial compression are over. However, in vertical consolidation it can be applied only after 60% consolidation.     

Comparison of the Complexation of Cu and Cd by Humic or Fulvic Acids and by Ligands Observed in Lake Waters

The complexation of Cu and Cd by ligands observed in filtered unfractionated lakewaters is compared to the complexation by humic and fulvic acids. Complexation parameters (conditional stability constants and ligand concentrations) of Suwannee River fulvic acids (FA), purified peat humic acids (HA) and of ligands in lakewater samples have been determined using the same methods (ligand-exchange and CSV (cathodic stripping voltammetry) or ASV (anodic stripping voltammetry)), and the same titration ranges of Cu, Cd and organic carbon concentrations. The performance of the used techniques is first evaluated in FA and HA suspensions, and gives comparable results with the literature values for the same materials, according to published models (5-site model, NICA model) and parameters. Model calculations using the WHAM model for FA and HA (Tipping, 1994) are also presented. The comparison of titrations of FA and HA with Cu and Cd with those of lakewater samples indicates that stronger ligands than FA and HA are present at low concentrations in the lakewaters. Specific strong ligands occur in particular in eutrophic lake waters, whereas in a lake with higher metal concentrations and low biological productivity the ligands more closely match the fulvic acid characteristics.     

Flocculation and dispersion of dolomite by acrylate polymers

This paper reports a study of the flocculation and dispersion of suspensions of dolomite by acrylate polymers of various molecular weights.The mechanism by which dispersion of dolomite occurs is interpreted on the basis of experimental results of dispersion tests, zeta potential and polymer adsorption measurements. From these data, it is concluded that electrostatic effects must not be ignored in explaining the behaviour of mineral suspensions.In the specific case of dolomite, the electric charge interactions appear to play a fundamental role and to be mainly responsible for the dispersion effect observed with polymers of low molecular weight (± 10,000). At high pH values (between 9.5 and 11.2), dolomite slimes can be dispersed, although the coverage of the mineral surface by the polymer is limited to 25%. On the other hand, when a polymer of high molecular weight (about 1,000,000) is used, this factor reaches values above 50%.     

痕量铁和锰的化学发光检测

评述了国内外有关铁、锰的化学发光分析进展。从发光体系、操作方式、最佳条件、干扰离子、检测限等各个方面对化学发光法测定铁、锰及其它们与其它组分同时测定中的应用进行分类评述。     

黄铁矿载金的原因和特征

对102个金矿床载金矿物的统计表明,黄铁矿是最普遍最重要的载金矿物。造成黄铁矿成为主要载金矿物的原因,有三个矿物学方面的因素,即结构因素、成核因素和电化学因素。结构因素表现在黄铁矿晶体结构中存在对硫 ［S2］2－,对硫 形成过程中对金离子具还原效应。成核因素表现在自然金成核常选择原子排布与之最接近的黄铁矿表面为衬底,以降低成核能。电化学因素表现在黄铁矿的热电性导致金离子在其表面发生电化学反应而沉淀结晶。对黄铁矿载金能力的分析表明,细粒、它形、裂隙发育程度高、As和Sb含量高以及P型的黄铁矿载金能力高,自形黄铁矿中的{210}、S面{100}及其聚形晶的载金能力高。     

Adsorption of copper and zinc by oil shale

 Oil shale is able to remove appreciable amounts of copper and zinc ions from aqueous solutions. It was noted that an increase in the adsorbent concentration with constant copper or zinc concentration resulted in greater metal removal from solution. An increase in the copper or zinc concentration with a constant sorbent concentration resulted in higher metal loading per unit weight of sorbent. For both metals, copper and zinc, equilibrium was attained after 24-h contact time. Increase in the initial pH or temperature of the metal solution resulted in an increase in the metal uptake per unit weight of the sorbent. Freundlich isotherm model was found to be applicable for the experimental data of Cu²⁺ and Zn²⁺. The results showed that oil shale could be used for the adsorption of the Cu²⁺ and Zn²⁺ with higher affinity toward Zn²⁺ ions. Addition of sodium salt to the metal solution influenced copper removal positively, but inhibited zinc removal. Received: 3 January 2000 · Accepted: 27 June 2000     

Chloride retention in forest soil by microbial uptake and by natural chlorination of organic matter

Inorganic chlorine (i.e. chloride; Cl_in) is generally considered inert in soil and is often used as a tracer of soil and ground water movements. However, recent studies indicate that substantial retention or release of Cl_in can occur in soil, but the rates and processes responsible under different environmental conditions are largely unknown. We performed ³⁶Cl tracer experiments which indicated that short-term microbial uptake and release of Cl_in, in combination with more long-term natural formation of chlorinated organic matter (Cl_org), caused Cl_in imbalances in coniferous forest soil. Extensive microbial uptake and release of Cl_in occurred over short time scales, and were probably associated with changes in environmental conditions. Up to 24% of the initially available Cl_in within pore water was retained by microbial uptake within a week in our experiments, but most of this Cl_in was released to the pore water again within a month, probably associated with decreasing microbial populations. The natural formation of Cl_org resulted in a net immobilization of 4% of the initial pore water Cl_in over four months. If this rate is representative for the area where soil was collected, Cl_org formation would correspond to a conversion of 25% of the yearly wet deposition of Cl_in. The study illustrates the potential of two Cl_in retaining processes in addition to those previously addressed elsewhere (e.g. uptake of chloride by vegetation). Hence, several processes operating at different time scales and with different regulation mechanisms can cause Cl_in imbalances in soil. Altogether, the results of the present study (1) provide evidence that Cl_in cannot be assumed to be inert in soil, (2) show that microbial exchange can regulate pore water Cl_in concentrations and (3) confirm the controversial idea of substantial natural chlorination of soil organic matter.     

应用GPS数据与重力数据确定大地水准面

作为GPS/重力边值问题理论及方法的应用,在对GPS/重力方法确定(似)大地水准面的原理进行简要介绍与分析的基础上,利用收集到的N区的600个GPS/重力数据和48个高精度GPS水准数据,计算出该区域的(似)大地水准面。通过拟合法和系统差直接改正法进行的精度分析表明,应用GPS/重力数据结合水准方法确定的该地区(似)大地水准面的精度达到厘米级精度。     

Contemporary Deposition and Long-Term Accumulation of Sediment and Nutrients by Tidal Freshwater Forested Wetlands Impacted by Sea Level Rise

Contemporary deposition (artificial marker horizon, 3.5 years) and long-term accumulation rates (²¹⁰Pb profiles, ~150 years) of sediment and associated carbon (C), nitrogen (N), and phosphorus (P) were measured in wetlands along the tidal Savannah and Waccamaw rivers in the southeastern USA. Four sites along each river spanned an upstream-to-downstream salinification gradient, from upriver tidal freshwater forested wetland (TFFW), through moderately and highly salt-impacted forested wetlands, to oligohaline marsh downriver. Contemporary deposition rates (sediment, C, N, and P) were greatest in oligohaline marsh and lowest in TFFW along both rivers. Greater rates of deposition in oligohaline and salt-stressed forested wetlands were associated with a shift to greater clay and metal content that is likely associated with a change from low availability of watershed-derived sediment to TFFW and to greater availability of a coastal sediment source to oligohaline wetlands. Long-term accumulation rates along the Waccamaw River had the opposite spatial pattern compared to contemporary deposition, with greater rates in TFFW that declined to oligohaline marsh. Long-term sediment and elemental mass accumulation rates also were 3–9× lower than contemporary deposition rates. In comparison to other studies, sediment and associated nutrient accumulation in TFFW are lower than downriver/estuarine freshwater, oligohaline, and salt marshes, suggesting a reduced capacity for surface sedimentation (short-term) as well as shallow soil processes (long-term sedimentation) to offset sea level rise in TFFW. Nonetheless, their potentially large spatial extent suggests that TFFW have a large impact on the transport and fate of sediment and nutrients in tidal rivers and estuaries.     

基于机器学习的滑坡崩塌地质灾害气象风险预警研究

在划分气象风险等级时,传统地质灾害气象风险预警方法忽略了承灾体脆弱性因素,且气象风险预报等级整体偏高,导致高等级风险区空报率较高。基于此,提出基于机器学习的滑坡、崩塌灾害气象风险预警方法。利用信息量法,分析气象因素影响程度。选取坐标点、降雨量、易发生等级,将其作为机器学习人工神经网络的输入节点,判断是否发生崩塌、滑坡灾害;针对地质灾害区域,根据影响程度计算气象引发因子指数,结合滑坡、崩塌灾害潜势度G和承灾体脆弱性M,确定气象风险预警指数R,划分预警级别,完成滑坡、崩塌灾害气象风险预警。实验结果表明,设计方法有效降低了三级预报和四级预警空报率,提升了预警精细化程度。     

Annual stream flow simulation by ARMA processes and prediction by Kalman filter

Algeria is a semi-arid country where water resources are not sufficient to cope with the important socio-economic development demands. Any sustainable development strategy is basically dependent on a rigorous management of water resources potential, which presents a true challenge to be tackled for such countries. Classic mathematical models based on time invariability and ignorance of the stochastic and non-linear nature of hydrological variables are not sufficient for simulation and prediction studies. The present study subscribes to the stochastic hydrological processes modeling and prediction in case of time-varying linear systems through adaptive Kalman filter (KF) methodology. It focuses upon stream flows as a water resources component, which is directly related to the socio-economic development meanwhile it opts for Kalman filter as principal tool of work. The main objective is the application of (KF) technique to model and predict annual streamflow volumes in Northern Algeria and the obtained results are satisfactory.     

Effects of pH and Ca competition on complexation of cadmium by fulvic acids and by natural organic ligands from a river and a lake

The technique of competitive ligand-exchange/anodic stripping voltammetry (CLE-SV) was used to investigate effects of pH and Ca concentration on cadmium complexation by fulvic acid (FA), as well as Cd speciation in two different freshwaters, a hardwater Lake Greifen and a softwater River Wyre. Binding of Cd to Suwannee river FA (10 mg/l) was determined at different pH (7–8.5) and in the presence of various concentration of Ca²⁺ (0–2 mmol/l). The results from one-ligand discrete models were compared to simulations by the WHAM VI model. In Lake Greifen, the determined dissolved [Cd²⁺] ranged from 10⁻¹³ to 10⁻¹² mol/l, and the conditional stability constant with natural ligands was log K _CdL about 9.5–10.5 (pH 8.6–8.8) with ligand concentrations of 1.2–7.8 × 10⁻⁶ mol/g C. In the softwater River Wyre, dissolved [Cd²⁺] ranged from 4 × 10⁻¹² to 1 × 10⁻¹¹ mol/l, and the ligands were weaker (log K _CdL 8.9–9.8, pH 8.0) with lower ligand concentrations (0.9–2.3 × 10⁻⁶ mol/g C). The titration curves of FA samples were close to the simulated curves by the WHAM VI model at pH 8.0–8.5, but deviated more from the model at lower pH, indicating that the results determined with CLE-SV for Cd-FA complexation are relevant to the data base in the model. Calculation of the Ca competition for Cd binding by FA showed a competition effect of similar strength as the measured one, but indicated a systematic difference between measured and modeled data at pH 7.5. Using the WHAM model for comparison with FA, the complexation of Cd by the River Wyre ligands was close to that of FA, whereas stronger complexation was observed in the Lake Greifen water. These differences may originate from different ligand composition in the lake and the river.     

Static breakage of granitic detritus by ice and water in comparison with breakage by flowing water

Temperature cycling between ?4·5±1·0°C and 13·0±2·0°C in the presence of added water caused significant breakage of granitic detritus. Because cycling with only adsorbed water present also caused breakage, fragmentation is attributed to both the combined action of ice and adsorbed water and to the latter acting alone. Breakage evidently resulted from the gradual tensile opening of pre-existing cracks, weakening then splitting grains. Surviving unbroken grains show evidence of a fatigue effect. Quartz split dominantly along pre-existing subplanar microfractures whereas feldspar and biotite split along crystal cleavages. Degree of breakage and product size distribution depend on the crystalline nature of the parent material, its previous history, and the nature and duration of the breakage process. With the first two factors the same, size distributions from adsorbed water breakage alone and from that due to adsorbed water plus ice differ slightly. Both contrast strongly with those of simulated fluviatile breakage. Whereas the latter preferentially produced 2–20 μm particles (probably debris of inter-particle collisions), static breakage split coarser grains wherever major weaknesses occurred, producing less selective product size distributions with greater proportions of loess-sized material (about 20--60 μ). Characteristic inflections in the size distribution curves of our experimentally produced debris are also shown by samples from the sola of some frost-affected soils. Partially healed microfractures in plutonic quartz are normally spaced at about 1–10 μ—approaching the downward asymptotic comminution limit for brittle solids (about 1 μ). Surficial physical processes are capable of reducing only a small proportion of plutonic quartz to this size before its storage in sediments.