Solar-wind interactions with the moon: Role of oxygen ions

The solar-wind interacts directly with the lunar surface due to tenuous atmosphere and magnetic field. The interaction results in an almost complete absorption of the solar-wind corpuscles producing no upstream bowshock but a cavity downstream. The solar-wind oxygen ionic species induce and undergo a complex set of reactions with the elements of the lunar minerals and the solar-wind derived trapped gases. The oxygen concentration indegeneous to the lunar surface material is about 60 at.%. Some of these oxygen are displaced from their crystal lattice locations by interactions of the solar-wind corpuscles. A small fraction of these displaced oxygen is in active state. The solar-wind oxygen species flux is about 6×10⁴ cm^–2 s^–1. Besides inducing and undergoing various reactions these species become trapped as oxygen atoms in the lunar grains. Only a portion of these trapped oxygen atoms is in active state. For the contribution of oxygen atoms and molecules from the lunar surface grains to the atmosphere and their reactions with other species, the diffusion coefficients of oxygen atom and molecule should be known. However their values in the highly radiation-damaged lunar surface material are not known. The coefficients are calculated by using the apparent lifetimes of atomic and molecular oxygen in the lunar material. The atmospheric concentration of oxygen atoms and molecules near the lunar surface are found to be about 20 and 3 cm^–3, respectively. These values appear to be very reasonable in comparison with the experimental data. The Apollo 17 lunar orbital UV spectrometer data indicate the atomic oxygen concentration is <8×10¹ cm^–3. The Apollo 17 lunar surface mass spectrometer (sensitivity: 1 count=2×10² molecules cm^–3) did not detect any oxygen molecules on the dayside of the Moon, but the sunrise concentration was reported to be 1±×10³ cm^–3. At the time of the sample collection on the Moon the oxygen content in the trapped gas layer was partly as oxygen atoms and partly as oxygen molecules. At the time of sample analysis on the Earth the concentrations of these two species did not change appreciably.     

Lunar Water: A Brief Review

One of the most exciting recent developments in the field of lunar science has been the unambiguous detection of water (either as OH or H₂O) or water ice on the Moon through instruments flown on a number of orbiting spacecraft missions. At the same time, continued laboratory-based investigations of returned lunar samples by Apollo missions using high-precision, low-detection, analytical instruments have for the first time, provided the absolute abundance of water (present mostly as structurally bound OH⁻ in mineral phases) in lunar samples. These new results suggest that the Moon is not an anhydrous body, questioning conventional wisdom, and indicating the possibility of a wet lunar interior and the presence of distinct reservoirs of water on the lunar surface. However, not all recent results point to a wet Moon and it appears that the distribution of water on the Moon may be highly heterogeneous. Additionally, a number of sources are likely to have contributed to the water inventory of the Moon ranging from primordial water to meteorite-derived water ice through to the water formed during the reaction of solar-wind hydrogen with the lunar soil. Water on the Moon has implications for future astrobiological investigations as well as for generating resources in situ during future exploration of the Moon and other airless bodies in the Solar System.     

Solar-wind interactions with the moon: Nature and composition of nitrogen compounds

The lunar atmosphere and magnetic field are very tenuous. The solar wind, therefore, interacts directly with the lunar surface material and the dominant nature of interaction is essentially complete absorption of solar-wind particles by the surface material resulting in no upstream bowshock, but a cavity downstream. The solar-wind nitrogen ion species induce and undergo a complex set of reactions with the elements of lunar material and the solar-wind-derived trapped elements. The nitrogen concentration indigeneous to the lunar surface material is practically nil. Therefore any nitrogen and nitrogen compounds found in the lunar surface material are due to the solar-wind implantation of nitrogen ions. The flux of the solar-wind nitrogen ion species is about 6×10³ cm^–2 s^–1. Since there is no evidence for accumulation of nitrogen species in the lunar surface material, the outflux of nitrogen species from the lunar material to the atmosphere is the same as the solar-wind nitrogen ion flux. The species of the outflux are primarily NO and NH₃, and their respective concentrations in the near surface lunar atmosphere are found by calculation to be 327 and 295 cm^–3. The calculated concentration of NH₃ seems to be consistent with the sunrise concentration results of the mass spectrometer implanted on the lunar surface. This is not the case for the concentration of NO. According to the presently calculated concentration value of NO, the mass spectrometer should have detected NO at sunrise, but no report was made for its detection. There is also discrepancy about the concentration of N₂ which is explained in this paper. The concentrations of nitrogen species in the lunar material at the time of sample collection on the Moon remained about the same when the samples were analyzed on the Earth. However, no specific experiment was planned to detect the nitrogen species in the lunar material samples.     

Simulating OH/H2O formation by solar wind at the lunar surface

We simulate the OH/H₂O production from the action of keV protons on the lunar regolith using a vacuum chamber and a mass analyzer to examine the molecular products released from olivine and SiO₂ powders during their irradiation by deuterium ions. The measured mass spectra, showing the OD/D₂O signature, confirm the possibility of OH/H₂O formation on the lunar surface by solar-wind hydrogen.     

Formation of the lunar atmosphere

Measurements of⁴⁰Ar and helium made by the Apollo 17 lunar surface mass-spectrometer are used in the synthesis of atmospheric supply and loss mechanisms. The argon data indicate that about 8% of the⁴⁰Ar produced in the Moon due to decay of⁴⁰K is released to the atmosphere and subsequently lost. Variability of the atmospheric abundance of argon requires that the source be localized, probably in an unfractionated, partially molten core. If so, the radiogenic helium released with the argon amounts to 10% of the atmospheric helium supply. The total rate of helium escape from the Moon accounts for only 60% of the solar windα particle influx. This seems to require a nonthermal escape mechanism for trapped solar-wind gases, probably involving weathering of exposed soil grain surfaces by solar wind protons.     

Lunar atmospheric H2 detections by the LAMP UV spectrograph on the Lunar Reconnaissance Orbiter

We report on the detection of H₂ as seen in our analysis of twilight observations of the lunar atmosphere observed by the LAMP instrument aboard NASA’s Lunar Reconnaissance Orbiter. Using a large amount of data collected on the lunar atmosphere between September 2009 and March 2013, we have detected and identified, the presence of H₂ in the native lunar atmosphere, for the first time. We derive a surface density for H₂ of 1.2 ± 0.4 × 10³ cm⁻³ at 120 K. This is about 10 times smaller than originally predicted, and several times smaller than previous upper limits from the Apollo era data.     

Laboratory studies on seismic and electrical properties of the moon

Laboratory measurements of seismic wave velocities and electrical properties of Apollo lunar samples and similar material of terrestrial origin are discussed in this paper. Measurements of the electrical properties show that in the frequency range above a few hundred Hz the outer region of the Moon may be considered as a low loss dielectric. This observation supports a longstanding speculation that dry, powdered rocks in which the dielectric loss tangent is frequency-independent over a wide range of frequency are present in the uppermost lunar surface layers. The surface layers of the Moon are likely to have an extremely low electrical conductivity. Thus future electromagnetic probing of the Moon to a few hundred kilometer depth is possible in the few kHz frequency range. Based on ultrasonic experiments with pressure as a variable, we next present the elastic constants and equations of state of lunar materials and characteristic dispersion of seismic wave velocities of the Moon. We find thatP andS wave velocities increase sharply within the first 30 km depth and then level off gradually. Combining this observation with lunar seismic and geophone data, we believe that the first 30 km of the Moon may be interpreted as a scattering region. If H₂O exists on the Moon, H₂O may occur at some shallow depth beneath the outermost surface layer in solid ice interlocking cracks and pores and mineral grains. The rocks in this permafrost state have relatively low seismic velocity and highQ. If permafrost does exist, we would expect a wide range of electrical conductivity and dielectric constant. Future electromagnetic probing of the Moon should yield very usefull information on the physical state of the lunar interior; when this electrical information is combined with the seismic information, we should learn much more about the internal constitution and the state of the Moon than is known today.     

Water and other volatiles on the moon: A review

This paper presents a review of research findings on the various forms of water on the Moon. First, this is the water of the Moon’s interior, which has been detected by sensitive mass spectrometric analysis of basaltic glasses delivered by the Apollo 15 and Apollo 17 missions. The previous concepts that lunar magmas are completely dehydrated have been disproved. Second, this is H₂O and/or OH in a thin layer (a few upper millimeters) of the lunar regolith, which is likely a result of bombardment of the oxygen contained in the lunar regolith with solar wind protons. This form of water is highly unstable and quite easily escapes from the surface, possibly being one of the sources of the water ice reservoirs at the Moon’s poles. Third, this is water ice associated with other frozen gases in cold traps at the lunar poles. Its possible sources are impacts of comets and meteorites, the release of gas from the Moon’s interior, and solar wind protons. The ice trapped at the lunar polars could be of practical interest for further exploration of the Moon.     

The velocity structure of the lunar crust

Seismic refraction data, obtained at the Apollo 14 and 16 sites, when combined with other lunar seismic data, allow a compressional wave velocity profile of the lunar near-surface and crust to be derived. The regolith, although variable in thickness over the lunar surface, possesses surprisingly similar seismic properties. Underlying the regolith at both the Apollo 14 Fra Mauro site and the Apollo 16 Descartes site is low-velocity brecciated material or impact derived debris. Key features of the lunar seismic velocity profile are: (i) velocity increases from 100–300 m s^–1 in the upper 100 m to 4 km s^–1 at 5 km depth, (ii) a more gradual increase from 4 km s^–1 to 6 km s^–1 at 25 km depth, (iii) a discontinuity at a depth of 25 km and (iv) a constant value of 7 km s^–1 at depths from 25 km to about 60 km. The exact details of the velocity variation in the upper 5 to 10 km of the Moon cannot yet be resolved but self-compression of rock powders cannot duplicate the observed magnitude of the velocity change and the steep velocity-depth gradient. Other textural or compositional changes must be important in the upper 5 km of the Moon. The only serious candidates for the lower lunar crust are anorthositic or gabbroic rocks.Paper dedicated to Professor Harold C. Urey on the occasion of his 80th birthday on 29 April, 1973.     

Paleocratering of the Moon: Review of post-Apollo data

As a result of the dating of lunar samples, we are in a position to utilize the lunar surface as a recorder of environmental conditions in the Earth-Moon neighborhood in the past. Plots of crater density vs rock age at different lunar landing sites can be used to date unexplored lunar provinces. These plots also demonstrate evolution in the population of planetesimals that struck the Moon. Prior to 4.1 aeons ago, the cratering rate on the Moon was at least 10³ times the present rate, and the rate declined with a half-life less than 8×10⁷ yr. During the interval from 4.1 to 3.2 aeons ago, the number of planetesimals showed an exponential decay with a half-life about 3×10⁸ yr, corresponding to sweep-up of particles from solar orbits somewhat similar to those of Apollo asteroids. A more nearly constant cratering rate applied in the last three aeons. These data indicate that the Moon displays at least the final stages of an ancient accretion process; they also set certain conditions on possible capture processes relating to the Moon's origin. Pre-Apollo expectations that the Moon would provide a Rosetta Stone for interpreting solar system history and planet formation thus appear justified.Paper given at Philadelphia meeting of American Association for Advancement of Science, December, 1971.     

Lunar meteorites from Oman

Abstract– Sixty named lunar meteorite stones representing about 24 falls have been found in Oman. In an area of 10.7 × 10³ km² in southern Oman, lunar meteorite areal densities average 1 g km^?2. All lunar meteorites from Oman are breccias, although two are dominated by large igneous clasts (a mare basalt and a crystalline impact‐melt breccia). Among the meteorites, the range of compositions is large: 9–32% Al₂O₃, 2.5–21.1% FeO, 0.3–38 μg g^?1 Sm, and <1 to 22.5 ng g^?1 Ir. The proportion of nonmare lunar meteorites is higher among those from Oman than those from Antarctica or Africa. Omani lunar meteorites extend the compositional range of lunar rocks as known from the Apollo collection and from lunar meteorites from other continents. Some of the feldspathic meteorites are highly magnesian (high MgO/[MgO + FeO]) compared with most similarly feldspathic Apollo rocks. Two have greater concentrations of incompatible trace elements than all but a few Apollo samples. A few have moderately high abundances of siderophile elements from impacts of iron meteorites on the Moon. All lunar meteorites from Oman are contaminated, to various degrees, with terrestrial Na, K, P, Zn, As, Se, Br, Sr, Sb, Ba, U, carbonates, or sulfates. The contamination is not so great, however, that it seriously compromises the scientific usefulness of the meteorites as samples from randomly distributed locations on the Moon.     

Formation of a ‘magma ocean’ on the terrestrial planets due to the blanketing effect of an impact-induced atmosphere

We show that the surface of a planet growing by planetesimal impact is heated over the melting temperature of the surface materials due to the blanketing effect of an impact induced H₂O atmosphere with the present H₂O abundance of the Earth even when the accretion time is as long as 10⁸ years. Hence, a magma ocean covering the entire surface was formed on the Earth and Moon and other terrestrial planets during their formations.     

Shallow lunar structure determined from the passive seismic experiment

Data relevant to the shallow structure of the Moon obtained at the Apollo seismic stations are compared with previously published results of the active seismic experiments. It is concluded that the lunar surface is covered by a layer of low seismic velocity (V _p ? 100 m s^?1), which appears to be equivalent to the lunar regolith defined previously by geological observations. This layer is underlain by a zone of distinctly higher seismic velocity at all of the Apollo landing sites. The regolith thicknesses at the Apollo 11, 12, and 15 sites are estimated from the shear-wave resonance to be 4.4, 3.7, and 4.4 m, respectively. These thicknesses and those determined at the other Apollo sites by the active seismic experiments appear to be correlated with the age determinations and the abundances of extralunar components at the sites.     

Volatile emission on the moon; Possible sources and release mechanisms

Evidence for very recent emission of volatiles on the Moon is primarily of four types: (1) transient lunar optical events observed by Earth-based astronomers; (2) excursions on Apollo SIDE and mass spectrometer instruments; (3) localized Rn²²²/Po²¹⁰ enhancements on the lunar surface detected by Apollo 15 and 16 orbital alpha spectrometers; (4) presence in lunar fines of retrapped Ar⁴⁰ and other volatiles. Available evidence indicates that the release rate of volatile substances into the lunar atmosphere is not steady, but instead sporadic and episodic. Rn²²²/Po²¹⁰ anomalies are at locations that are among those from which transient events have most often been reported (edges of maria, certain specific craters), and are probably related to them. Volatiles emitted at maria rims may originate in the Moon's fluid core, reaching the surface through deep cylindrical fault systems that ring the maria borders. The sources of volatiles emitted at craters such as Aristarchus or Tsiolkovsky, which possess floors which are cracked or filled with dark lava and possess central peaks, are more likely to be local pockets of magma or trapped gas at shallower depths. The volatiles are produced directly by radioactive decay (He⁴, Ar⁴⁰, Rn) and by heating (other volatiles). The release by heating can occur either during melting or by ‘bakeout’ of unmelted materials. Release of gas into the lunar atmosphere is probably triggered by buildup of its own pressure. This may be assisted by tidal forces exerted on the Moon by the Earth. In addition to independent release, volatile emission is also expected to accompany other lunar activity, such as ash flows, if any lunar volcanism is presently active.

     

The phase dependence of brightness and color of the lunar surface: a study based on integral photometric data

A procedure of an a posteriori correction of the available data on the integral photometry of the Moon is described. This procedure reduces the regular errors of the integral phase curves caused by variations of the libration parameters; the effect due to libration can reach 4%. A method allowing the integral measurements of the Moon to be compared correctly with the photometric measurements of the lunar areas or laboratory samples imitating the lunar soil has been developed. To approximate the phase curves of integral albedo in the phase-angle range from 6° to 120°, we proposed a simple empirical formula A _eq(α) = m _l e ^?ρα + m ₂ e ^?0.7α, where α is the phase angle, ρ is the factor of effective roughness, and m ₁ + m ₂ is the surface albedo at a zero phase angle. An empirical phase dependence of the slope of the lunar spectrum in the 360–1060 nm range has been obtained. The results may be used to test various theoretical models of the light scattering by the lunar surface and to calibrate the data of ground-based and space-borne spectrophotometric observations.     

The role of submicrometer aerosols and macromolecules in H2 formation in the titan haze

Previous studies of the photochemistry of small molecules in Titan’s atmosphere found it difficult to have hydrogen atoms removed at a rate sufficient to explain the observed abundance of unsaturated hydrocarbons. One qualitative explanation of the discrepancy nominated catalytic aerosol surface chemistry as an efficient sink of hydrogen atoms, although no quantitative study of this mechanism was attempted. In this paper, we quantify how haze aerosols and macromolecules may efficiently catalyze the formation of hydrogen atoms into H₂. We describe the prompt reaction model for the formation of H₂ on aerosol surfaces and compare this with the catalytic formation of H₂ using negatively charged hydrogenated aromatic macromolecules. We conclude that the PRM is an efficient mechanism for the removal of hydrogen atoms from the atmosphere to form H₂ with a peak formation rate of ∼ 70 cm⁻³ s⁻¹ at 420 km. We also conclude that catalytic H₂ formation via hydrogenated anionic macromolecules is viable but much less productive (a maximum of ∼ 0.1 cm⁻³ s⁻¹ at 210 km) than microphysical aerosols.     

Some characteristic magnetic properties of lunar materials

One of the typical magnetic characteristics of lunar materials is the composition of their ferromagnetic constituent. Lunar breccias often contain kamacite (less than 7 weight per cent of Ni content) as well as almost pure metallic iron. Metallic ferromagnetics in most igneous rocks are almost pure iron, but the kamacite phase also has been found in some Apollo 15 igneous rocks. It seems likely therefore the metallic ferromagnetics in the lunar crust are more or less similar to those in chondrites.Another typical magnetic characteristic of lunar materials is the presence of a considerable amount of superparamagnetically fine particles of metallic iron. A higher relative content of such fine iron particles results in a higher value of the ratio of magnetic susceptibility (o) to saturation magnetization (I _s), a smaller ratio of the coercive force (H _c) to remanence coercive force (H _RC), and an extremely higher ratio of the viscous component (I _v) to the stable one (I _s) of the remanent magnetization.Communication presented at the Lunar Science Institute Conference on Geophysical and Geochemical Exploration of the Moon and Planets, January 10–12, 1973.     

An intrinsic volatility scale relevant to the Earth and Moon and the status of water in the Moon

The notion of a dry Moon has recently been challenged by the discovery of high water contents in lunar apatites and in melt inclusions within olivine crystals from two pyroclastic glasses. The highest and most compelling water contents were found in pyroclastic glasses that are not very common on the lunar surface. To obtain more representative constraints on the volatile content of the lunar interior, we measured the Zn content, a moderately volatile element, of mineral and rock fragments in lunar soils collected during Apollo missions. We here confirm that the Moon is significantly more depleted in Zn than the Earth. Combining Zn with existing K and Rb data on similar rocks allows us to anchor a new volatility scale based on the bond energy of nonsiderophile elements in their condensed phases. Extrapolating the volatility curve to H shows that the bulk of the lunar interior must be dry (≤1 ppm). This contrasts with the water content of the mantle sources of pyroclastic glasses, inferred to contain up to approximately 40 ppm water based on H₂O/Ce ratios. These observations are best reconciled if the pyroclastic glasses derive from localized water‐rich heterogeneities in a dominantly dry lunar interior. We argue that, although late addition of 0.015% of a chondritic veneer to the Moon seems required to explain the abundance of platinum group elements (Day et al. 2007), the volatile content of the added material was clearly heterogeneous.     

IBEX-Lo observations of energetic neutral hydrogen atoms originating from the lunar surface

In this paper we present quantitative results of observations of energetic neutral atoms (ENAs) originating from the lunar surface. These ENAs, which are hydrogen atoms, are the result of the solar wind protons being reflected from and neutralised at the surface of the Moon. These measurements were made with IBEX-Lo on NASA's IBEX satellite. From these measurements we derive the energy spectrum of the ENAs, their flux, and the lunar albedo for ENAs (i.e., the ratio of ENAs to the incoming solar wind protons). The energy spectra of the ENAs clearly show that their origin is directly from the solar wind via backscattering, and that they are not sputtered atoms. From several observation periods we derived an average global albedo of A_H=0.09±0.05. From the observed energy spectra we derive a generic spectrum for unshielded bodies in the solar wind.     

Cosmic ray interactions with lunar materials: Nature and composition of species formed

The solar and galactic cosmic rays interact directly with lunar surface materials, and the dominant nature of interactions is essentially the complete absorption of corpuscles. These corpuscles damage the lattice structure, and induce a complex set of reactions in the materials producing various species. The cosmic ray damage of the lattice would not produce an amorphous layer, similar to that produced by the solar wind, because the solar wind erosion rate is faster than the cosmic ray-induced amorphous layer formation rate. The species formation rate considered in this paper are those produced by protons, the dominant component of cosmic rays. Protons produce H, H₂, OH, H₂O, and hydrogenated species of carbon, nitrogen, sulfur, etc. These species, while migrating in the material, encounter oncoming cosmic ray corpuscles, and undergo a complex set of reactions. Although a variety of species are produced by protons, the dominant contributor to the atmosphere is H₂. The H₂ flux (molecules cm^–2 sec^–1) is about 1.5 × 10⁵ as compared to the H flux of 8.4 × 10¹ and the H₂O flux of 4.6 × 10^–2. These fluxes are about 10^–3 smaller than the fluxes of the same species produced by the solar wind protons. Thus the contributions of the cosmic ray-induced species to the atmosphere is very small compared to the solar wind-induced species. Although simulated experiments showed high concentractions of OH and H₂O in the terrestrial materials of lunar type, these species concentrations in the lunar materials under the lunar environment is much smaller than those observed in the simulated experiments.