Recent water quality trends and a comparison to sediment-core records for two riverine lakes of the Upper Mississippi River basin: Lake St. Croix and Lake Pepin

Long-term water quality monitoring data from two riverine lakes in the Upper Mississippi River basin, Lakes St. Croix and Pepin, were analyzed to compare the long-term average water quality conditions and land use distributions, water quality trends and loads at lake inlets and outlets, trends from long-term versus short-term monitoring records, and the ability of paleolimnological cores to accurately infer lake water quality conditions. During the 1976–2004 period, the long-term average concentrations of nutrients, suspended solids, and chlorophyll-a were consistently lower at the Lake St. Croix inlet versus the Lake Pepin inlet, which drains a greater proportion of urban and agricultural runoff. Despite these differences, nutrient trends were similar at the inlets to both lakes; reductions in total phosphorus and ammonium concentrations were attributed to improvements in point source technologies, whereas increasing nitrate concentrations were attributed to both point source changes and nonpoint source increases. Despite improvements in several water quality variables, nitrate concentrations are increasing in both lakes, sediment trends indicate persistent nonpoint source inputs to Lake Pepin, and current total phosphorus concentrations remain well above pre-1950s levels in both lakes. Since urban development and agriculture are increasing in the Lake St. Croix and Lake Pepin Watersheds, continued point source regulation and additional nonpoint source control efforts will be needed to further improve water quality in these lakes. The 1976–2004 trends for most water quality variables were similar at inlet versus outlet sites on Lake St. Croix. Trends at Lake Pepin inlet versus outlet sites were less similar, but data availability limited the comparison to the 1993–2003 period. While the truncated data record highlighted short-term trends in both lakes, the full data record was most useful for exploring general patterns in water quality. Length of monitoring record affected our ability to detect trends at the inlets to both lakes, and altered the magnitude of detected trends. During the two decades of the 1980s and 1990s, paleolimnological estimates of retained phosphorus loads were similar to those estimated from recent water quality monitoring. These similarities support the use of paleolimnological approaches to infer past water quality conditions in Lakes St. Croix and Pepin. This is one of eight papers dedicated to the “Recent Environmental History of the Upper Mississippi River” published in this special issue of the Journal of Paleolimnology. D. R. Engstrom served as guest editor of the special issue.     

Twentieth century eutrophication of the St. Croix River (Minnesota–Wisconsin,USA) reconstructed from the sediments of its natural impoundment

Evaluation of land-use effects on coastal and marine ecosystems requires better understanding of the role of rivers in regulating mass transport from terrestrial to oceanic environments. Here we take advantage of the presence of a riverine lake to use paleoecological techniques to quantify impacts of logging, European-style agriculture, urbanization and continued terrestrial disturbance on mass transport and water quality in the northern drainage of the Mississippi River. Two 2-m sediment-cores recovered in 1999 from Lake St. Croix, a natural impoundment of the St. Croix River, were dated using ²¹⁰Pb and ¹³⁷Cs, and analyzed for historical changes (c. 1840–present) in sediment magnetic susceptibility, inorganic and organic matter content, biogenic silica, fossil pigments, and diatom microfossils. Inorganic sediment accumulation increased threefold between the mid-1800s and present, whereas clear signs of eutrophication were only evident after the mid-twentieth century when biogenic silica accumulation increased sixfold, diatom accumulation rates increased 20- to 50- fold, and the diatom community shifted from predominantly benthic species to assemblages composed mainly of planktonic taxa. Similarly, fossil pigment concentrations increased during the 1960s, and diatom-inferred total phosphorus (DI-TP) increased from ~30 μg TP l⁻¹ c. 1910 to ~60 μg l⁻¹ since 1990, similar to historical records since 1980. Together, these patterns demonstrate that initial land clearance did not result in substantive declines in water quality or nutrient mass transport, instead, substantial degradation of downstream environments was restricted to the latter half of the twentieth century. This is one of eight papers dedicated to the “Recent Environmental History of the Upper Mississippi River” published in this special issue of the Journal of Paleolimnology. D. R. Engstrom served as guest editor of the special issue.     

A whole-basin stratigraphic record of sediment and phosphorus loading to the St. Croix River,USA

Lake St. Croix is a natural impoundment of the lowermost 37 km of the St. Croix River in Minnesota and Wisconsin, making this one of a few large river systems in the world possessing a long-term depositional basin at its terminus. The river’s relatively pristine condition led to its designation as a National Scenic Riverway in 1968, but increasing urbanization in its lower reaches has raised concerns about impacts on water quality. This study was initiated to reconstruct historical loadings of suspended sediment and phosphorus (P) from the sediment record in Lake St. Croix. Twenty-four piston cores, with an average length of 2 m, were collected along eight transects of the lake. Dated chronologies from ²¹⁰Pb, ¹³⁷Cs and ¹⁴C were used to calculate the rate of sediment accumulation in the lake over the past 100+ years. Diatom microfossil analysis was used to reconstruct historical lakewater P concentrations over the same time period, and sediment P analysis quantified the amount of P trapped in lake sediments. Using a whole-lake mass balance approach, the loading of sediment and P to Lake St. Croix over the last 100+ years was calculated. Beginning in 1850, sediment accumulation increased dramatically to a peak in 1950–1960 of eight times background rates prior to European settlement. The peak is driven largely by sediment contributions from small side-valley catchment tributaries to the downstream half of the lake. The total P load to the lake increased sharply after 1940 and remains high, at around four times the level of pre-European settlement conditions. The timing of peak sediment and P loading to the lake shows that early settlement activities, such as logging and the conversion of forest and prairie to agricultural land between 1850 and 1890, had only modest impacts on the lake. By contrast, the mid-1900s brought major increases in sediment and P loading to the lake, suggesting that relatively recent activities on the landscape and changes to nutrient balances in the watershed have caused the current eutrophic condition of this important recreational and natural resource. This is one of eight papers dedicated to the “Recent Environmental History of the Upper Mississippi River” published in this special issue of the Journal of Paleolimnology. D. R. Engstrom served as guest editor of the special issue.     

Historical trace metal loading to a large river recorded in the sediments of Lake St. Croix,USA

The global cycling of anthropogenic trace metals intensified during the twentieth century, impacting aquatic systems throughout the world. There are, however, few quantitative records showing the history of this contamination in large rivers. Here we present a well-dated sedimentary record of trace metal accumulation in Lake St. Croix, a natural riverine lake on the St. Croix River (Minnesota and Wisconsin, USA), revealing the history of heavy metal inputs to the river over the past 200 years. Concentrations of Hg, Pb, Ag, Cd, Cr and Zn and stable Pb isotopes were measured in eight ²¹⁰Pb-dated sediment cores collected from profundal depositional areas throughout the lake. Time trends of trace metal concentrations and accumulation rates differed greatly between the upper lake (above Valley Creek) and the lower lake, reflecting contrasting sediment sources along the flow axis of the lake. For most of the study period (1800–2000 AD), sediment deposited throughout the lake derived almost exclusively from the suspended sediment load carried by the main-stem river into the lake. From 1910 through 1970, however, large inputs of eroded soils and stream channel sediments from side-valley tributaries resulted in greatly increased sediment and trace metal accumulation in the lower lake. Anthropogenic accumulation rates of Hg, Pb, Cd, Zn, and Ag in the upper lake correlate well with those from Square Lake, a small, relatively undisturbed nearby lake that has received trace metal inputs almost exclusively via atmospheric deposition. The similarity of these records suggests that atmospheric deposition was primarily responsible for trace metal accumulation trends in upper Lake St. Croix. Trace metal accumulation in the lower lake was also strongly influenced by atmospherically derived inputs, but metal contributions from native soils were important, as well, during the period of elevated sediment inputs from side-valley tributaries. Concentrations and accumulation rates of trace metals in both upper and lower lake sediments have decreased substantially since the 1970s due to decreased atmospheric inputs and sediment loadings, but accumulation rates remain well above pre-settlement values. Metal inputs to Lake St. Croix have been far lower than those to nearby Lake Pepin, located on the Mississippi River downstream of the Minneapolis-St. Paul metropolitan area, but there nevertheless remains a clear record of anthropogenic impact on the relatively pristine St. Croix River.     

Historical rates of sediment and nutrient accumulation in marshes of the Upper St. Johns River Basin, Florida, U.S.A.

We used 210Pb-dated sediment cores from wetlands and Blue Cypress Lake, in the Upper St. Johns River Basin (USJRB), Florida, USA, to measure historical accumulation rates of bulk sediment, total carbon (C), total nitrogen (N), and total phosphorus (P). Marsh cores displayed similar stratigraphies with respect to physical properties and nutrient content. Wetland sediments typically contained > 900 mg organic matter (OM) g^–1 dry mass, > 500 mg C g^–1, and 30–40 mg N g^–1. OM, C, and N concentrations were slightly lower in uppermost sediments of most cores, but displayed no strong stratigraphic trends. Total P concentrations were relatively low in bottommost deposits (0.01–0.11 mg g^–1), but ranged from 0.38–2.67 mg g^–1 in surface sediments. The mean sediment accretion rate in the marsh since ~ 1900, 0.33 ± 0.05 cm yr^–1, was calculated from ten ²¹⁰Pb-dated cores. All sites displayed increases in accumulation rates of bulk sediment, C, N, and P since the early part of the 20th century. These trends are attributed to recent hydrologic modifications in the basin combined with high nutrient loading from agricultural, residential, and urban sources.     

Impacts of Coal-Fired Power Plants on Trace Metals and Polycyclic Aromatic Hydrocarbons (PAHs) in Lake Sediments in Central Alberta, Canada

Trace metals and polycyclic aromatic hydrocarbons (PAH) were analyzed in sediment cores from three central Alberta lakes to determine the contributions of local coal-fired power plants to contaminant loadings. In Wabamun Lake, with four power plants built since 1950 within a 35-km radius, sediment concentrations of mercury, copper, lead, arsenic and selenium have increased by 1.2- to 4-fold. Trace metal enrichments were less pronounced in Lac Ste. Anne and Pigeon Lake, situated 20 km north and 70 km south of Wabamun Lake, respectively. Total Hg flux to Wabamun Lake sediments (21–32μg m⁻² yr⁻¹) has increased 6-fold since 1950, compared to 2- and 1.5-fold increases in Lac Ste. Anne and Pigeon Lake, respectively, since circa 1900. Total PAH flux to surface sediments was 730–1100μg m⁻² yr⁻¹ in Wabamun Lake, 290–420μg m⁻² yr⁻¹ in Lac Ste. Anne, and 140–240μg m⁻² yr⁻¹ in Pigeon Lake. Without adoption of pollution-abatement technology that compensates for increases in generating capacity, continued expansion of coal-burning industry in Alberta will result in increased contaminant deposition, primarily from local sources.     

Formation and early history of Lakes Pepin and St. Croix of the upper Mississippi River

Study of Lake Pepin and Lake St. Croix began more than a century ago, but new information has permitted a closer look at the geologic history of these two riverine lakes located on the upper Mississippi River system. Drainages from large proglacial lakes Agassiz and Duluth at the end of the last glaciation helped shape the current valleys. As high-discharge outlet waters receded, tributary streams deposited fans of sediment in the incised river valleys. These tributary fans dammed the main river, forming riverine lakes. Lake Pepin was previously thought to be a single long continuous lake, extending for 80 km from its dam at the Chippewa River fan all the way up to St. Paul, with an arm extending up the St. Croix valley. Recent borings taken at bridge and dam locations show more than a single section of lake sediments, indicating a more complex history. The Minnesota and Mississippi Rivers did not always follow their current paths. Valleys cut into bedrock but now buried by glacial sediment indicate former river courses, with the most recent of these from the last interglacial period marked at the surface by chains of lakes. The morphology of the Mississippi valley bottom, and thus the morphology of Lake Pepin as it filled the valley, is reflect in part by the existence of these old valleys but also by the presence of glacial outwash terraces and the alluvial fans of tributary streams. A sediment core taken in Lake Pepin near Lake City had a piece of wood in gravels just below lake sediments that dated to 10.3 ka cal. BP, indicating that the lake formed as the Chippewa River fan grew shortly after the floodwaters of Lakes Agassiz and Duluth receded. Data from new borings indicate small lakes were dammed behind several tributary fans in the Mississippi River valley between the modern Lake Pepin and St. Paul. One tributary lake, here called Early Lake Vermillion, may have hydraulically dammed the St. Croix River, creating an incipient Lake St. Croix. The tributary fans from the Vermillion River, the Cannon River, and the Chippewa River all served to segment the main river valley into a series of riverine lakes. Later the growth of the Chippewa fan surpassed that of the Vermillion and Cannon fans to create a single large lake, here called late Lake Pepin, which extended upstream to St. Paul. Sediment cores taken from Lake Pepin did not have significant organic matter to develop a chronology from radiocarbon dating. Rather, magnetic features were matched with those from a Lake St. Croix core, which did have a known radiocarbon chronology. The Pepin delta migration rate was then estimated by projecting the elevations of the top of the buried lake sediments to the dated Lake Pepin core, using an estimated slope of 10 cm/km, the current slope of Lake Pepin sediment surface. By these approximations, the Lake Pepin delta prograded past Hastings 6.0 ka cal BP and Red Wing 1.4 ka cal BP. This is one of eight papers dedicated to the “Recent Environmental History of the Upper Mississippi River” published in this special issue of the Journal of Paleolimnology. D. R. Engstrom served as guest editor of the special issue.     

Water quality modeling and sensitivity analysis using Water Quality Analysis Simulation Program (WASP) in the Shenandoah River watershed

This study used the Water Quality Analysis Simulation Program (WASP) to simulate nutrients, dissolved oxygen (DO), and chlorophyll-a dynamics in the Shenandoah River basin and performed an uncertainty analysis to examine the complexity of these variables in water quality estimation and their influence on the Shenandoah River. Significant progress has been made; however, nutrient loads emitted into the Shenandoah River from nonpoint sources remain high. Modeling of three points on the Shenandoah River in Virginia and West Virginia provides an ideal case study since the river is classified by the Virginia Department of Environmental Quality as being impaired. The results of a sensitivity test show that model error decreases with increasing model complexity and sensitivity. The model predicted DO values that tended to be close to the measured data, while total nitrogen and phosphorus tended to be overemphasized. Our results examine the importance of temperature, stream flow, and velocity in influencing water quality between seasons and levels on the different sections of the watershed.     

Human-induced change in sedimentary trace metals and phosphorus in Chaohu Lake,China, over the past half-millennium

We present a sedimentary geochemical record of human perturbation in the watershed and related changes in trace metals (Cr, Ni, Zn and Pb), phosphorus and abundant rock-forming elements (Al, Fe, K, Mg, etc.) in Chaohu Lake over the past 500 years, a period spanning historical agricultural expansion and modern economic development. The record exhibited a stable terrestrial detrital input to Chaohu Lake before ca. 1540 AD, a period with less human perturbation of the watershed, which resulted in low and constant values of trace metals and phosphorus (TP) concentrations as well as Al, Fe, K, Mg, fine silt (<16 μm), the chemical index of alteration (CIA) and K/Na ratio. Two periods of successive marked increases in Al, Fe, K, Mg, fine silt, chemical index of alteration (CIA) and K/Na ratio occurred after ca. 1540 AD and 1950 AD. The former period apparently resulted from enhanced well-weathered topsoil erosion in the watershed related to the expansion of arable land, and the latter resulted from further enhancement of human perturbation in the watershed during the modern period. Concentrations of trace metals and TP were positively correlated with that of the rock-forming elements and fine silt. Trace metal pollution was limited during 1540–1950 AD, according to the low enrichment factors (EFs = 0.8–1.1), when an increase in trace metal concentrations was also linked to changes in detrital input. In addition to detrital regulation, pollution also contributed to an increase in TP concentrations (average EF 1.4) during 1540–1950 AD and the average accumulation rate of anthropogenic phosphorus was 87.3 mg m⁻² a⁻¹. Anthropogenic phosphorus increased further and Pb and Zn pollution also occurred after 1950 AD, reaching maximum values after 1980 AD, when the average accumulation rates of anthropogenic Zn, Pb and phosphorus (mainly in the form of NaOH-P) were 242.2, 43.3 and 811.8 mg m⁻² a⁻¹, respectively. The increase in phosphorus pollution in recent decades is probably from the domestic sewage sources of Hefei City and non-point sources related to agricultural utilization of commercial fertilizer, whereas Zn and Pb pollution is probably derived mainly from industrial sources of Hefei City, as deduced from their spatial variations in the sediments of the river mouths.     

Assessment of nutrient sources and paleoproductivity during the past century in Longgan Lake,middle reaches of the Yangtze River,China

Total organic carbon (TOC), total nitrogen (TN) and total phosphorus (TP) were determined in combination with stable isotope ratios of carbon and nitrogen (δ¹³C_Org, δ¹⁵N) in a 63 cm sediment core from Longgan Lake, located in the middle reaches of the Yangtze River, China. These geochemical and isotopic records provide a continuous history of lake productivity and trophic state of Longgan Lake since 1890. Variations of δ¹³C_Org, TOC, TN and TP indicate that primary productivity of Longgan Lake increased continuously during the last century and that the trophic state of the lake shifted from oligotrophic to mestrotrophic conditions accordingly. Anthropogenic sources of organic carbon (OC), nitrogen (N) and phosphorus (P) were distinguished from their natural background in the sediments using mass accumulation rates. Element mass accumulation rates suggested increased human activities in the lake’s catchment since 1950s, were especially the utilization of artificial fertilizers amplified the anthropogenic input of N and P into the lake. In the course of the improved availability of dissolved nutrients also primary productivity of Longgan Lake increased, resulting in an increase of the Suess-effect corrected organic carbon isotope ratios. δ¹⁵N of bulk sediments show a marked shift towards lower values around 1950 that has been attributed to the input of nitrogen from chemical fertilizers characterized by relatively depleted isotopic signatures into the lake.     

非点源营养负荷泥沙关系的建立及其应用

为满足水污染控制规划和流域水资源保护工作的需要,以几个流域的非点源污染监测资料为基础,建立了TP、TN等营养物的非点源污染负荷—泥沙定量关系,相关系数高达0.9以上。以渭河的支流黑河和陕南的汉江流域为例,具体说明了污染负荷—泥沙关系法的应用步骤和预测结果,并与水质水量相关法的结果进行了对照。结果表明,该方法可用于次暴雨及不同频率代表年的非点源营养负荷量预测。     

Middle to late Holocene initiation of the annual flood pulse in Tonle Sap Lake,Cambodia

Tonle Sap Lake, Cambodia, possesses one of the most productive inland fisheries in the world and is a vital natural resource for the country. The lake is connected to the Mekong River via the Tonle Sap River. Flow in the Tonle Sap River reverses seasonally, with water exiting the lake in the dry season and entering the lake during the summer monsoon. This flood pulse drives the lake’s biological productivity. We used Sr, Nd, and Pb isotopes and elemental concentrations in lake sediment cores to track changes in the provenance of deposits in Tonle Sap Lake. We sought to determine when the lake first began to receive water and sediment input via the Mekong River, which initiated flood pulse processes. The transition from a non-pulsing lake to the Mekong-connected system is marked by shifts to values of ⁸⁷Sr/⁸⁶Sr, ε_Nd, and ²⁰⁷Pb/²⁰⁴Pb that are characteristic of Mekong River sediments. In addition, magnetic susceptibility increased and sediment elemental composition changed. Elemental (P) measures point to enhanced phosphorus loading and C/N and isotope ratios of bulk organic matter indicate a shift to greater relative contribution of organic material from aquatic versus terrestrial environments, coinciding with the initiation of flood pulse processes. On the basis of radiocarbon dating in two cores, we estimate the initiation of the annual flood pulse occurred between ~4,450 and 3,910 cal year BP.     

Palaeovariations in the East-Asian Monsoon Regime Geochemically Recorded in Varved Sediments of Lake Sihailongwan (Northeast China, Jilin Province). Part 2: a 200-Year Record of Atmospheric Lead-210 Flux Variations and its Palaeoclimatic Implications

Palaeovariations of the atmospheric ²¹⁰Pb flux in Northeast China (Long Gang area, Jilin province), quantified by high resolution ²¹⁰Pb measurements on seasonally laminated sediments of Lake Sihailongwan are presented on decadal scale. The mean flux of unsupported ²¹⁰Pb between 1790 and 1970 for the centre of the lake basin is 517 Bq m⁻² yr⁻¹ with maximum deviations between −23% and +27% of this value. Flux rates above this average were found between 1783 and 1813, around 1836, and between 1860 and 1901. The mean ²¹⁰Pb^exc flux rates derived were clearly lower around 1821, 1908, 1930, and 1953. The ²¹⁰Pb^exc flux reached its minimum of 344 Bq m⁻² yr⁻¹ during the period 1977–1982. The atmospheric flux of unsupported ²¹⁰Pb is correlated with the precipitation frequency during the summer monsoon and shows coinciding variability with geochemical proxies that document the groundwater inflow into the lake. Al₂O₃-rich dust of remote provenance scavenged by wet-deposition in the rainy season is the major carrier of the atmospheric ²¹⁰Pb^exc flux.     

Historical changes in sediment and phosphorus loading to the upper Mississippi River: mass-balance reconstructions from the sediments of Lake Pepin

Long-term changes in sediment and phosphorus loading to the upper Mississippi River were quantified from an array of 25 sediment cores from Lake Pepin, a large natural impoundment downstream of the Minneapolis-St Paul metropolitan area. Cores were dated and stratigraphically correlated using ²¹⁰Pb, ¹³⁷Cs, ¹⁴C, magnetic susceptibility, pollen analysis, and loss-on-ignition. All cores show a dramatic increase in sediment accumulation beginning with European settlement in 1830. Accumulation rates are highest and show the greatest post-settlement increases in the upper end of the lake. Present-day sediment-phosphorus concentrations are roughly twice those of pre-settlement times, and the Fe/Al-bound fraction makes up a greater portion of the total. Diatom assemblages record a marked increase in nutrient availability over the last 200 years, changing from clear-water benthic forms and mesotrophic planktonic taxa in pre-settlement times to exclusively planktonic assemblages characteristic of highly eutrophic conditions today. Lake-water total-phosphorus concentrations, estimated by weighted averaging regression and calibration, increased from 50 to 200 μg l⁻¹ during this period. Sediment loading to Lake Pepin from the Mississippi River has increased by an order of magnitude since 1830. Modern fluxes are about 900,000 metric tons annually, and are more than 80% detrital mineral matter. About 17% of the lake’s volume in 1830 has been replaced by sediment, and at current accumulation rates the remainder will be filled in another 340 years. Phosphorus accumulation in Lake Pepin sediments has increased 15-fold since 1830, rising from 60 to 900 metric tons annually. This rise represents a sevenfold increase in phosphorus loading from the Mississippi River coupled with more efficient retention of phosphorus inflows by bottom sediments. More efficient trapping of phosphorus in Lake Pepin over the last century resulted from higher rates of sediment burial. The most dramatic changes in nutrient and sediment inputs to Lake Pepin have occurred since 1940, although gradual increases began shortly following European settlement. Sediment accumulation rates rose sharply between 1940 and 1970 and then leveled off, while phosphorus inflows record their largest increases after 1970. This is one of eight papers dedicated to the “Recent Environmental History of the Upper Mississippi River” published in this special issue of the Journal of Paleolimnology. D. R. Engstrom served as guest editor of the special issue.     

Carbon stable isotopes ratios of pelagic and littoral communities in Alchichica crater-lake, Mexico

Carbon stable isotope ratios were determined in dominant biotic components of pelagic and littoral systems in Alchichica crater-lake. Results showed that carbon signatures were significantly different between both systems. The pelagic environment was more depleted (−26.15 to −15.14 per mille) than the littoral zone (−21.03 to −17.91 per mille). The potential source end-point in the simplified pelagic community was established to be diatomaceous phytoplankton; its predicted value was −21.7 per mille. There is a clear evidence thatNodularia does not sustain the pelagic food chain. In contrast, the highly diverse littoral community was sustained by epiphytes. No allochthonous sources seemed to influence this food web.¹³C enrichment was observed along the components of both systems with fractionations of 0.8 to 1.4 per mille. The contribution of the seagrassRuppia maritima is probably associated with the detritus pathway. Carbon source partitioning between both systems was not recorded. The δ¹³C in Alchichica crater-lake was more enriched than in other saline lakes and could be attributed to different salinity and CO₂ concentrations among lakes.     

Elemental (C,N, H and P) and stable isotope (δ<Superscript>15</Superscript>N and δ<Superscript>13</Superscript>C) signatures in sediments from Zeekoevlei,South Africa: a record of human intervention in the lake

We used elemental carbon, nitrogen, phosphorus and hydrogen ratios (C/N, N/P and H/C) with total organic carbon (TOC) and total phosphorus (TP) as well as stable carbon and nitrogen isotopes (δ¹³C and δ¹⁵N) to investigate the source and depositional conditions of organic matter in sediments from Zeekoevlei, the largest freshwater lake in South Africa. Typical C/N (10–12), H/C ratios (≥1.7) and δ¹³C_organic values (−22 to −19‰) together with the increase in TOC concentration indicate elevated primary productivity in lower middle (18–22 cm) and top (0–8 cm) sections of the sediment cores. Seepage of nutrients from a nearby waste water treatment plant, rapid urbanization and heavily fertilized farming in the catchments are responsible for the increased productivity. Consistent with this, measured δ¹⁵N_organic values (∼11‰) indicate increased raw sewage input towards the top-section of the core. Although cyanobacterial blooms are evident from the low δ¹⁵N values (∼3‰) in mid-section of the core, they did not outnumber the phytoplankton population. Low N/P ratio (∼0) and high TP (100–2,200 mg l⁻¹) support cyanobacterial growth under N limited condition, and insignificant input of macrophytes towards the organic matter pool. Dredging in 1983, caused sub-aerial exposure of the suspended and surface sediments, and affected organic matter preservation in the upper mid-section (12–14 cm) of the core.     

Sediment accumulation rates in European lakes since AD 1850: trends,reference conditions and exceedence

Sediment accumulation rate (SAR) is an important physical parameter in all lakes and increases have been observed in many over the last c.100 years. This has been ascribed to changes in land-use and land-management causing accelerated catchment soil erosion and an increase in autochthonous organic matter production. The EU Water Framework Directive requires that assessment of biological, hydromorphological and chemical elements of water quality should be based on the degree to which present day conditions deviate from those expected in the absence of significant anthropogenic influence, termed reference conditions. Currently however, the reference condition for sediment accumulation rate for lakes of different types is undefined. To improve our understanding of the controls on SARs we compiled SAR and lake typology data for 207 European lakes derived from ²¹⁰Pb dated cores to assess how rates have changed through time (in 25 year classes) both overall and for lakes of different types. Seventy-one percent of these sediment cores showed surface SARs higher than “basal” (mainly nineteenth century) rates, 11% showed no change while 18% showed a decline. Lakes were then classified into lake-types using four variables: alkalinity (3 classes), altitude (3 classes), maximum depth (2 classes) and lake area (2 classes). This generated a possible 36 lake classes of which 25 were represented in the dataset. Nine lake-types contained >10 lakes. Little change in SAR occurred prior to 1900 and most increases occurred in more recent periods, in particular 1950–1975 and post-1975. This indicates a general acceleration in SAR in European lakes during the second half of the twentieth century. Reference SARs were estimated for six lake-types with the highest number of sites. European mountain lakes had the lowest reference SAR (0.005 ± 0.003 g cm⁻² yr⁻¹) while lowland, high alkalinity sites had the highest (0.03–0.04 g cm⁻² yr⁻¹). SARs for other lake-types ranged between 0.012 and 0.024 g cm⁻² yr⁻¹. Using the mountain lake-type as an example, the 1850 reference SAR appears to show good agreement with available data for lakes beyond Europe indicating these values may be more broadly applicable. Contemporary SARs in lakes of all classes showed exceedence over their defined reference SAR. This may be partly due to diagenetic processes. Greatest exceedences were found in shallow, low altitude lakes and these are considered to be the ones under the greatest threat from continued elevation of SAR. It is considered that climate change may play a progressively more important role in driving SAR in the future.     

Impacts of settlement,damming, and hydromanagement in two boreal lakes: a comparative paleolimnological study

Namakan Lake, located in shared border waters in northeastern Minnesota and northwestern Ontario, was subjected to several anthropogenic impacts including logging, damming, water-level manipulations, and perhaps climate change. We used paleolimnology to determine how these stressors impacted Namakan Lake in comparison to a control lake (Lac La Croix) that was not subject to damming and hydromanagement. One core was retrieved from each lake for ²¹⁰Pb dating and analysis of loss-on-ignition and diatom composition. ²¹⁰Pb-derived chronologies from the cores indicated that sediment accumulation increased after logging and damming in Namakan Lake; Lac La Croix showed no significant change. Loss-on-ignition analysis also showed an increase in concentration and accumulation of inorganic material after damming in Namakan Lake; again, minimal changes were observed in Lac La Croix. Diatom communities in both lakes displayed community shifts at the peak of logging. Simultaneous, post-1970s diatom community changes may reflect regional climate warming. Taxonomic richness in Namakan Lake decreased sharply after damming and the peak of logging, and was followed by a slow recovery to taxonomic richness similar to that prior to damming. Ecological variability among post-damming diatom communities, however, was greater in Namakan Lake than in Lac La Croix. A diatom calibration set was used to reconstruct historical conductivity and total phosphorus (TP). Lac La Croix showed little historical change in conductivity and TP. In contrast, conductivity increased for several decades in Namakan Lake after damming, possibly in relation to several large fires and flooding. Total phosphorus also increased in Namakan Lake after damming, with a possible decrease in the last decade to pre-damming TP levels.     

Macroinvertebrate communities in two salt affected tributaries of the Hopkins Rives,Victoria

Macroinvertebrate communities were studied in two saline tributaries of the Hopkins River, western Victoria. Monthly sampling from May to August, 1990, showed the mean salinity of Bushy Creek was 5 g L⁻¹ while in Back Creek mean salinity varied from 9 to 20 g L⁻¹ between sites. Macroinvertebrate species richness and relative abundance were measured on each sampling occasion. Cluster analysis showed that community composition varied between creeks and between sites within a creek. Bushy Creek sites were more similar to each other than to Back Creek sites. A negative relationship was found between site salinity and species richness over the range 4 to 26 g L⁻¹, although there was a wide range of salinity (up to 12 g L⁻¹) over which the relationship of species richness to salinity was not clear cut. The effects of salinity on species richness in stream communities appear to be similar to that described elsewhere in salt lakes.     

Environmental variability in Lake Naivasha,Kenya, over the last two centuries

Lake Naivasha, Kenya, is one of a number of freshwater lakes in the East African Rift System. Since the beginning of the twentieth century, it has experienced greater anthropogenic influence as a result of increasingly intensive farming of coffee, tea, flowers, and other horticultural crops within its catchment. The water-level history of Lake Naivasha over the past 200 years was derived from a combination of instrumental records and sediment data. In this study, we analysed diatoms in a lake sediment core to infer past lacustrine conductivity and total phosphorus concentrations. We also measured total nitrogen and carbon concentrations in the sediments. Core chronology was established by ²¹⁰Pb dating and covered a ~186-year history of natural (climatic) and human-induced environmental changes. Three stratigraphic zones in the core were identified using diatom assemblages. There was a change from littoral/epiphytic diatoms such as Gomphonema gracile and Cymbella muelleri, which occurred during a prolonged dry period from ca. 1820 to 1896 AD, through a transition period, to the present planktonic Aulacoseira sp. that favors nutrient-rich waters. This marked change in the diatom assemblage was caused by climate change, and later a strong anthropogenic overprint on the lake system. Increases in sediment accumulation rates since 1928, from 0.01 to 0.08 g cm⁻² year⁻¹ correlate with an increase in diatom-inferred total phosphorus concentrations since the beginning of the twentieth century. The increase in phosphorus accumulation suggests increasing eutrophication of freshwater Lake Naivasha. This study identified two major periods in the lake’s history: (1) the period from 1820 to 1950 AD, during which the lake was affected mainly by natural climate variations, and (2) the period since 1950, during which the effects of anthropogenic activity overprinted those of natural climate variation.