The nature of the high values of the anisotropy of magnetic susceptibility of rock samples with polydomain ferromagnetics

Samples of different rocks, which possess high values of the anisotropy of magnetic susceptibility, were studied by the magneto-mineralogical and optical methods and by microprobe analysis. It was established that for the samples, which contain the pseudo-single-domain ferromagnetite elongated particles, the source of the anisotropy of magnetic susceptibility is the distribution anisotropy of not only ferromagnetic grains themselves, but also ferromagnetic patterns in the heterogeneous accessory minerals. For samples with multidomain ferromagnetic materials, the nature of the anisotropy of magnetic susceptibility is caused by the orientation of the ilmenite lamellar phase in the structures of disintegration of titanomagnetites or by the orientation of the ferromagnetic structures of disintegration in iron sulfides.     

Magnetic properties of high-Ti basaltic rocks from the Krušné hory/Erzgebirge MTS. (Bohemia/Saxony), and their relation to mineral chemistry

This study provides new thermomagnetic and petrographic data on specific basaltic rock association from the broader vicinity of the Lou?ná-Oberwiesenthal volcanic centre, western Bohemia/Saxony. Two types of volcanic rocks were recognized there: (i) high-Ti types (3.5–5.2 wt% TiO₂) represented by (mela)nephelinite s.s., and sporadically present (ii) medium-Ti types (2.5–3.5 wt% TiO₂) of olivine nephelinite, nepheline basanite and phonotephrite compositions. In order to examine the rock-magnetic behaviour, they were studied for their variations in the Curie temperature (T_C) and field-dependent susceptibility, spinel group minerals, chemistry and petrology. Magnetic susceptibility of ulvöspinel-rich titanomagnetite, as a dominant magnetic carrier, depends on the amplitude of measured magnetic field, whereas pure magnetite is field-independent. Field dependence parameter ^kHD of the studied basaltic rocks ranges from 0.8 to 18.7%, TiO₂ contents in titanomagnetite range from 12.7 to 20.1 wt.%. TiO₂ content in titanomagnetite does not correlate with whole-rock TiO₂ content (2.8 to 5.6 wt.%). The content of substituted titanium in the sublattice of magnetite is also sensitively reflected in the Curie temperature, ranging from 200 to 580°C. The spinel group minerals are designated as titanomagnetite with the dominance of ulvöspinel, magnetite and magnesioferrite components, or titanomagnetite with the magnetite, ulvöspinel and magnesioferrite components. Only two samples are characterized by a significant presence of Cr-spinel and magnesiochromite components forming cores of titanomagnetites. The titanomagnetite-bearing rocks in the studied area, likewise the low- to medium-Ti basaltic rocks from the ?eské st?edoho?í Mts., provide similar thermomagnetic curves.     

Magnetic properties of intrusive traps of the Siberian platform: Evidence for a self-reversal of the natural remanent magnetization

A combined magnetomineralogical analysis of a doleritic collection gathered from four natural outcrops in the mouth area of the Stolbovaya River revealed a spinodal pattern of the decomposition of a magnetite-ulvospinel solid solution (the stage of the “modulated structure” formation) in the ferromagnetic fraction of samples. Homogenization of exsolution structures during thermal treatment of the majority of the collected samples is shown to involve the effect of partial self-reversal of thermoremanent magnetization. A distinct dependence of the effect on the level of internal elastic stresses suggests that a reverse component of J n can arise during some phases of the spinodal stage of the solid solution decomposition in natural titanomagnetites.     

含孔隙、裂隙致密介质中多极子声波的传播特征

非常规油气藏（如致密性地层及蕴藏油气的页岩地层）的重要特征是低孔、低渗,但裂隙或裂缝比较发育.为满足非常规勘探的需求,本文将孔、裂隙介质弹性波传播理论应用于多极子声波测井的井孔声场模拟,重点研究了致密介质中裂隙发育时多极子声波的传播机理以及衰减特征.井孔声场的数值计算结果表明裂隙的存在明显改变了弹性波和井孔模式波的频散、衰减和激发强度,尤其是井壁临界折射纵波的激发谱的峰值随着频率的增加逐渐降低,这与应用经典的Biot理论下的计算结果相反,且裂隙的存在也使得饱含水和饱含气时临界折射纵波激发强度的差异变大.井孔模式波的衰减与地层横波衰减和井壁流体交换有关,井壁开孔边界下致密地层裂隙发育还使得井孔斯通利波和艾里相附近的弯曲波对孔隙流体的敏感性增强,在井壁闭孔边界条件下引起井孔模式波衰减的主要因素是裂隙引起的地层横波衰减造成的,且在截止频率附近弯曲波的衰减与地层的横波衰减一致.数值计算结果为解释非常规油气地层的声学响应特征提供了参考.     

Magnetisation of titanomagnetites from Bulgarian basalts

A number of basalt samples containing titanomagnetites, with varying degrees and modes of oxidation, have been collected from 13 sites in northern Bulgaria, the degree of oxidation being determined from Curie point and lattice parameter determination. The stability of natural remanent magnetization and artificially induced thermoremanences (TRM) has been studied in an attempt to determine whether the oxidized rocks carry a TRM inherited from their original, unoxidized state. From the samples studied, it appears that the intensity and direction of the original TRM's are retained, but that there is some loss in stability.     

Characteristic features of the implantation of Al,Mg, and Mn impurity atoms into the titanomagnetite structure

Results of microprobe analysis of titanomagnetites and hemoilmenites from Cenozoic basalts of Mongolia and Iceland, Eastern Siberia Permo-Triassic traps (the Norilsk borehole), and Proterozoic and Paleozoic dike basaltoids on the White Sea coast of the Kandalaksha Gulf (Por’ya Bay), as well as data on titanomagnetites of Primorski Krai basalts [Shcheka et al., 1980], are used to examine specific features of the implantation of impurity atoms into solid solutions with various concentrations of the ulvospinel component.     

Hydrogeochemistry of seepage water collected within the Youngcheon diversion tunnel,Korea: source and evolution of SO4‐rich groundwater in sedimentary terrain

In the Youngcheon Diversion Tunnel area, South Korea, 46 samples of tunnel seepage water (TSW) and borehole groundwater were collected from areas with sedimentary rocks (mainly sandstone and shale) and were examined for hydrogeochemical characteristics. The measured SO₄ concentrations range widely from 7·7 to 942·0 mg/l, and exceed the Korean Drinking Water Standard (200 mg/l) in about half the samples. The TDS (total dissolved solid) content generally is high (171–1461 mg/l) from more shale‐rich formations and also reflects varying degrees of water–rock interaction. The water is classified into three groups: Ca? SO₄ type (61% of the samples collected), Ca? SO₄? HCO₃ type (15%) and Ca? HCO₃ type (24%). The Ca? HCO₃ type water (mean concentrations=369 mg/l Ca, 148 mg/l HCO₃ and 23 mg/l SO₄) reflected the simple reaction between CO₂‐recharged water and calcite, whereas the more SO₄‐rich nature of Ca? SO₄ type water (mean concentrations=153 mg/l Ca, 66 mg/l HCO₃ and 416 mg/l SO₄) reflected the oxidation of pyrite in sedimentary rocks and fracture zones. Pyrite oxidation resulted in precipitation of amorphous iron hydroxide locally within the tunnel as well as in high concentrations of Ca (mean 153 mg/l) and Na (mean 49 mg/l) for TSW, and is associated with calcite dissolution resulting in pH buffering. The pyrite oxidation required for the formation of Ca? SO₄ type water was enhanced by the diffusion of oxygenated air through the fractures related to the tunnel's construction. The subsequent outgassing of CO₂ into the tunnel resulted in precipitation of iron‐bearing carbonate. Copyright © 2001 John Wiley & Sons, Ltd.     

Paleomagnetic study of a vertical sequence of traps from Mount Pavagarh,Gujrat, India

The paleomagnetism of 22 flows which range in composition from olivine basalts to rhyolite and in elevation from 450 ft. to 2680 ft., from Mount Pavagarh, situated in Gujrat, India, has been studied. The igneous activity represented by these flows belongs to the Deccan Trap Plateau Basalt Series. Sixteen flows ranging in elevation from 900 to 2680 ft. showed normal magnetization with upward inclination, consistent with the position of India in the southern hemisphere during the period of their eruption. Four flows from elevation 450 ft. to 730 ft. showed intermediate as well as discordant directions. The paleomagnetic results obtained from these flows have been correlated with those of Deccan traps from other areas. The amount of paleosecular variation represented by these flows has been estimated and compared with that from similar vertical sequences of traps studied from other areas. It has been found that the magnitude of paleosecular variation varied during the period of Deccan trap activity. An estimate of continental drift has been made from mean pole position of the several vertical sequences of traps. This indicates that a drift of the Indian landmass of the order of 24° took place during the entire period represented by the Deccan trap activity. The results of paleomagnetic studies of other sedimentary and igneous formations of Cretaceous age are reviewed in the light of recent results on Deccan traps.     

The magnetic anisotropy of basalts and its variations under oxidation of titanomagnetites

Summary Using four samples of basaltic rocks from the Bohemian Massif, Nos 201, 202, 206 and 218, the curves of rotational moments in a magnetic field of 4 × 10⁵ A/m were studied as a function of the degree of oxidation of titanomagnetites. The amplitudes of the individual harmonics were determined by harmonic analysis for samples oxidized to various degrees. It was found that the proportion of the harmonic A ₁ withsin increases with the degree of oxidation. Simultaneously, the anisotropy of the magnetic susceptibility changes in a field of 60 A/m and the structure changes from linearly parallel to plane parallel.     

Results of the study of anisotropy of elastic properties of rocks from the Luchlompolo fault zone (Pechenga region,Kola Peninsula)

Elastic characteristics of rock samples from the Luchlompolo fault zone taken from outcrop surfaces are compared with elastic characteristics of core samples of the Kola ultradeep borehole taken in an analogous interval. An inversion consisting of a discrepancy between the schistosity levels of rocks in the borehole (below the Luchlompolo fault) and their analogues at the surface (above the fault) is explained by a considerable difference in the force actions that caused the schistosity and layering of rocks in the borehole and at the surface. A kinematic scheme of the fault is constructed, and a hypothesis about the existence of an inversion point (region) in the fault zone and its probable collecting properties is put forward.An inverse dependence of variations in density characteristics of rocks on acoustic dichroism and their elastic anisotropy coefficient for transverse waves is established for the first time.     

Change of structure,phase composition and magnetic properties with the oxidation of titanomagnetites

Summary Phase, structural and magnetic changes, occurring under oxidation and at increased temperatures, are studied on four samples of magnetic fractions. The samples of magnetic fractions, containing titanomagnetites at different oxidation levels, were oxidized at a temperature of 400°C for 1, 60 and 300 mins. With the aid of X-rays and Mössbauer's spectrometry it has been proved that under oxidation non-stoichiometric titanomagnetites and titanomagnetites plus ilmenite and pseudobrookite are formed.     

Geochemistry of Cenozoic volcanic rocks in Tengchong,SW China: relationship with the uplift of the Tibetan Plateau

There are wide spread Cenozoic volcanic rocks in Tengchong (CVRT), Yunnan province, SW China. These rocks comprise three rock types: basalt, andesite (dominant type) and dacite. Most samples are sub‐alkaline, and among the sub‐alkaline rocks, most are high‐K calc‐alkaline. These rocks have a SiO₂ range of 49.1 wt.% to 66.9 wt.%. TiO₂ contents are not high and have a variation of 0.7 wt.%–1.6 wt.%. Trace element concentrations and element ratios (such as Nb/U, Ce/Pb, Nb/La, etc.) of these rocks have a large variation. ⁸⁷Sr/⁸⁶Sr values fall in the range of 0.7057–0.7093 and ¹⁴³Nd/¹⁴⁴Nd values change from 0.5120 to 0.5125. ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb ratios are in the range of 17.936–19.039, 15.614–15.810, and 38.894–39.735, respectively. These geochemical characteristics of CVRT make them resemble island‐arc volcanic rocks. We suggest that the magmas were generated in the lithospheric mantle that had already been metasomatized by previous subduction processes. By the study of the uplift history of the Tibetan Plateau, we found that the beginning of the geotectonic processes to the eruption of CVRT was coeval with one uplift event. Therefore, we propose that the uplift of the Tibetan Plateau caused collapse of the collisional orogeny in Tengchong, which further triggered the generation and eruption of the CVRT magmas.     

Rock magnetic properties and ore microscopy of the iron ore deposit of Las Truchas, Michoacan, Mexico

Iron ore and host rocks have been sampled (90 oriented samples from 19 sites) from the Las Truchas mine, western Mexico. A broad range of magnetic parameters have been studied to characterize the samples: saturation magnetization, Curie temperature, density, susceptibility, remanence intensity, Koenigsberger ratio, and hysteresis parameters. Magnetic properties are controlled by variations in titanomagnetite content, deuteric oxidation, and hydrothermal alteration. Las Truchas deposit formed by contact metasomatism in a Mesozoic volcano-sedimentary sequence intruded by a batholith, and titanomagnetites underwent intermediate degrees of deuteric oxidation. Post-mineralization hydrothermal alteration, evidenced by pyrite, epidote, sericite, and kaolin, seems to be the major event that affected the minerals and magnetic properties. Magnetite grain sizes in iron ores range from 5 to >200 μm, which suggest dominance of multidomain (MD) states. Curie temperatures are 580±5°C, characteristic of magnetite. Hysteresis parameters indicate that most samples have MD magnetite, some samples pseudo-single domain (PSD), and just a few single domain (SD) particles. AF demagnetization and IRM acquisition indicate that NRM and laboratory remanences are carried by MD magnetite in iron ores and PSD–SD magnetite in host rocks. The Koenigsberger ratio falls in a narrow range between 0.1 and 10, indicating the significance of MD and PSD magnetites.     

Characteristic magnetic properties of titanomagnetites in continental igneous rocks

Curie temperatures, hysteresis, alternating field properties and anhysteretic and ordinary susceptibilities have been used to characterize the titanomagnetites in a large collection of continental granites, diorites, syenites, anorthosites, gabbros, diabases and basalts. Low-Curie-point titanomagnetites or titanomaghemites were found only in basalts. In all shallow and deep-seated intrusive rocks, the predominant magnetic phase was nearly-titanium-free titanomagnetite with a Curie point of 520–580°C. Most felsic plutonic rocks owed their magnetic properties to coarse, discrete titanomagnetites with truly multidomain properties. Many mafic plutonic rocks (anorthosites, gabbros, norites) displayed bimodal magnetic properties, strong-field properties being due to the discrete titanomagnetites and weak-field properties being due to fine magnetite inclusions in deuterically altered silicates. The Lowrie-Fuller test and the anhysteretic induction curve were the most diagnostic tests of this bimodal behaviour. Grain-size variation within a single diabase dike or sill had a strong expression in all magnetic properties, except H_R/H_c and the Lowrie-Fuller test. On the other hand, the Lowrie-Fuller test was a sensitive indicator of changes in “effective” grain size in basalts due to the subdivision of grains by ilmenite lamellae.     

Vertical cross contamination of trichloroethylene in a borehole in fractured sandstone

Boreholes drilled through contaminated zones in fractured rock create the potential for vertical movement of contaminated ground water between fractures. The usual assumption is that purging eliminates cross contamination; however, the results of a field study conducted in a trichloroethylene (TCE) plume in fractured sandstone with a mean matrix porosity of 13% demonstrates that matrix-diffusion effects can be strong and persistent. A deep borehole was drilled to 110 m below ground surface (mbgs) near a shallow bedrock well containing high TCE concentrations. The borehole was cored continuously to collect closely spaced samples of rock for analysis of TCE concentrations. Geophysical logging and flowmetering were conducted in the open borehole, and a removable multilevel monitoring system was installed to provide hydraulic-head and ground water samples from discrete fracture zones. The borehole was later reamed to complete a well screened from 89 to 100 mbgs; persistent TCE concentrations at this depth ranged from 2100 to 33,000 microg/L. Rock-core analyses, combined with the other types of borehole information, show that nearly all of this deep contamination was due to the lingering effects of the downward flow of dissolved TCE from shallower depths during the few days of open-hole conditions that existed prior to installation of the multilevel system. This study demonstrates that transfer of contaminant mass to the matrix by diffusion can cause severe cross contamination effects in sedimentary rocks, but these effects generally are not identified from information normally obtained in fractured-rock investigations, resulting in potential misinterpretation of site conditions.     

Titanomagnetites and ilmenites from the Early Cenozoic basalts and limburgites of the Northern Tien Shan

Based on X-ray spectrometry and thermomagnetic analysis, the chemical composition is studied and the Curie points are determined for the Early Cenozoic basalts and limburgites of the Northern Tien Shan. The microprobe analysis used in combination with the thermomagnetic analysis unambiguously identified a series of homogeneous primarily magmatic titanomagnetites in the studied samples against the broad variety of grains of titanomagnetite that underwent single-phase heterophase oxidation, which are often undetectable by a microprobe alone. The titanium content or TiO₂/FeO ratio in titanomagnetites and, correspondingly, the Curie points reflect the depth of the most recent equilibrium state of the magma, i.e., the depth of the magma sources. According to the dependence of the content of primarily magmatic titanomagnetite on the source depth, the latest equilibrium state of the magmatic melt of the Northern Tien Shan occurred at a depth of 40 ± 5 km. The obtained results agree with the reduction in the seismic velocities by a few percent below the Moho revealed by seismic tomography.     

A modelling of effects of variable saturation in invaded zone near borehole on neutron tool response in the gas-bearing Miocene formations of the Carpathian foredeep,Poland

Invasion of mud filtrate from the borehole into the surrounding formation can significantly alter the response of logging tools.In this paper the neutron tool response was calculated for a gas-bearing rock crossed by the borehole.The invaded zone is characterized by variable fluid and gas saturation and is defined by a specific hyperbolic function. The saturation function is based on the characteristics of Polish Carpathian Foredeep Miocene formations reached in gas-bearing rocks. The whole system including neutron tool equipped with Am-Be neutron source and a set of neutron detectors, borehole, invaded zone, and virgin zone, was numerically modeled and used as the input to the Monte-Carlo neutron transport code. The response of each detector was calculated for different combinations of porosity and saturation of invaded zone and virgin zone.     

Magnetic monitoring of top soils of Merida (Southern Mexico)

This paper focuses on the study of the correlation between magnetic parameters with the level of contamination by heavy metals in urban soils. We report a magnetic investigation of urban soil samples from Merida, state of Yucatan, Southern Mexico. It appears that most of our samples contain ferrimagnetic minerals as the magnetic carriers, probably coming from the titanomagnetites/titanomaghemites series. This is inferred by the acquisition of isothermal remanent magnetization, which shows that most of samples are almost completely saturated at about 200 mT. The S₋₂₀₀ value (factor characterizing stability of remanent magnetization) is between 0.8 and 1.0, characteristic of ferrimagnetic minerals. The susceptibility vs. temperature measurements also point to some titanomaghemites and titanomagnetites as probable responsible for magnetization. On the other hand, measurements of magnetic susceptibility at high and low frequencies helped us to determine the high content of superparamagnetic grains in the majority of the samples, although not all of these showed high values of magnetic susceptibility. We found that the most contaminated samples by Pb and Zn showed the higher saturation isothermal remanent magnetization values, whereas the higher values in magnetic susceptibility correspond to samples contaminated by Cr. Finally, we noted that a high level in Sr decreases the magnetic susceptibility.     

孔、裂隙并存地层中的声波测井理论及多极子声场特征

在油、气储层的勘探和开发中观察到的一个现象是储层岩石中普遍存在孔隙和裂隙.随着近年来孔、裂隙介质弹性波动理论的进展,我们可以将此理论应用于测井技术,以此来指导从声波测井中测量孔、裂隙地层的声学参数.本文计算了孔、裂隙地层里充流体井眼中的多极子声场,分析了声场随裂隙介质的两个主要参数(即裂隙密度和裂隙纵横比)的变化特征.井孔声场的数值计算表明裂隙密度可以大幅度地降低井中声波纵、横波的波速和振幅.随着裂隙密度的增加,在测井频段内也可以看到纵、横波速的频散现象(这种频散在孔隙地层中一般是观察不到的).本文还研究了多极子模式波 (即单极的Stoneley波、伪瑞利波以及偶极的弯曲波)随裂隙参数的变化特征.结果表明,这些模式波的振幅激发和速度频散都受裂隙密度的影响.裂隙密度越高影响越大.此外,裂隙还对模式波的传播造成较大的衰减.相对裂隙密度而言,裂隙纵横比是一个频率控制参数,它控制裂隙对声场影响的频率区间.本文的分析结果对裂缝、孔隙型地层的声波测井具有指导意义.     

Properties of some rocks from the section of the Kola ultradeep borehole as a function of the P-T parameters

Using core samples of the Kola ultradeep borehole (SG-3) and their surface analogues, variations in the density and elastic properties of some crystalline rocks of the Earth’s crust are estimated by modeling of in situ conditions. It is shown that the bulk density and the elastic wave velocities in the rocks have a weak depth gradient. In the SG-3 section under consideration, this gradient is negative. The resulting dependences for estimating the variations in the properties of the crystalline rocks are suitable for the depth range from the surface to 20–30 km. The initial data for the linear approximation of the characteristics can be obtained from the results of tests of surface analogue samples. It is shown that the velocity anisotropy of the metamorphic rocks can vary within wide limits.