苏皖辽地区新元古代微亮晶构造碳酸盐岩的沉积岩相与环境约束

国内外元古代碳酸盐岩中常见席状、透镜状、脉状和块状等形态的微亮晶碳酸盐岩。微亮晶体宏观、微观边界清晰,内部充填均一等粒结构的方解石微亮晶。宿主岩相以含泥质或粉砂质的细砂屑、粉泥屑灰岩为主,经常与风暴岩共生。微亮晶构造碳酸盐岩发育在缓坡型台地,沉积层序中常见潮汐流、风暴流侵蚀-充填和浪成交错层理与递变层理。微亮晶构造碳酸盐岩发育严格受沉积环境和岩相约束,形成于 (内缓坡深部-中缓坡浅部 )潮下带和环潮坪,风暴浪基面是其发育的最大深度。垂向序列由高频潮下带和环潮坪微层序加积而成,单个微层序顶部通常为环潮坪为纹层状含铁质有机质泥屑碳酸盐岩披盖层,是一个向上沉积动力减弱、沉积物变细和水体变浅的沉积旋回。     

Long-distance correlation between tectonic-controlled, isolated carbonate platforms by cyclostratigraphy and sequence stratigraphy in the Devonian of South China

During the early Middle Devonian in South China, an extensive carbonate platform was broken up through extension to create a complex pattern of platforms, and interplatform basins. In Givetian and Frasnian carbonate successions, five depositional facies, including peritidal, restricted shallow subtidal, semi‐restricted subtidal, intermediate subtidal and deep subtidal facies, and 18 lithofacies units are recognized from measured sections on three isolated platforms. These deposits are arranged into metre‐scale, upward‐shallowing peritidal and subtidal cycles. Nine third‐order sequences are identified from changes in cycle stacking patterns, vertical facies changes and the stratigraphic distribution of subaerial exposure indicators. These sequences mostly consist of a lower transgressive part and an upper regressive part. Transgressive packages are dominated by thicker‐than‐average subtidal cycles, and regressive packages by thinner‐than‐average peritidal cycles. Sequence boundaries are transitional zones composed of stacked, high‐frequency, thinner‐than‐average cycles with upward‐increasing intensity of subaerial exposure, rather than individual, laterally traceable surfaces. These sequences can be further grouped into catch‐up and keep‐up sequence sets from the long‐term (second‐order) changes in accommodation and vertical facies changes. Catch‐up sequences are characterized by relatively thick cycle packages with a high percentage of intermediate to shallow subtidal facies, and even deep subtidal facies locally within some individual sequences, recording long‐term accommodation gain. Keep‐up sequences are characterized by relatively thin cycle packages with a high percentage of peritidal facies within sequences, recording long‐term accommodation loss. Correlation of long‐term accommodation changes expressed by Fischer plots reveals that during the late Givetian to early Frasnian increased accommodation loss on platforms coincided with increased accommodation gain in interplatform basins. This suggests that movement on faults resulted in the relative uplift of platforms and subsidence of interplatform basins. In the early Frasnian, extensive siliceous deposits in most interplatform basins and megabreccias at basin margins correspond to exposure disconformities on platforms.     

华北地台中元古代碳酸盐岩中的微生物成因构造及其生烃潜力

华北地台中元古界主要由环潮坪石英砂岩、浅海碳酸盐岩和浅海—泻湖相暗色页岩3种沉积相组合构成,以陆表海浅水碳酸盐岩占主导。碳酸盐岩中除含有丰富的微古植物、宏观藻类和微生物建隆外,还发育大量的微生物成因构造(MISS)和微生物诱发的碳酸盐沉淀(MMCP)。微生物席和MISS构造在高于庄组上部(约1.6 Ga)和雾迷山组下部(约1.45 Ga)碳酸盐岩中尤为发育,表明活跃的微生物活动和高有机质产量。在石化微生物席中,发现有丝状、球状细菌化石和草莓状黄铁矿;围岩中发现有针状文石、花瓣状重晶石、放射状菱铁矿、铁白云石和葡萄状碳酸盐胶结物等多种自生碳酸盐矿物,指示甲烷厌氧氧化(AOM)导致的自生碳酸盐沉淀。中元古代的温暖气候和海洋分层、缺氧、硫化条件有利于微生物的高生产量和高有机质埋藏率。气隆构造和核形石状碳酸盐结核反映浅埋藏条件下活跃的成烷作用和甲烷排放,围岩和MMCP中富沥青质。华北地台中元古界富微生物席碳酸盐岩有良好的生烃潜力,有可能形成重要的烃源岩。据微生物席、MISS构造及MMCP的研究,初步估算华北地台中元古代碳酸盐岩的概略生烃潜力约为10×108t石油当量。     

Microbial Mats in the Mesoproterozoic Carbonates of the North China Platform and Their Potential for Hydrocarbon Generation

The well-preserved Mesoproterozoic succession in the North China platform consists mainly of three llthological associations including peritidal quartz sandstone, shallow marine and lagoonai dark to black shales, and shallow epeiric carbonates, with a total thickness of up to 8 000 m. In addition to well-documented microplants, macroalgae, and microbial buildups, abundant microbially induced sedimentary structures (MISS) and mat-related sediments have been recognized in these rocks. Intensive microbial mat layers and MISS are especially well preserved in the carbonates of the upper Gaoyuzhuang (高于庄) (ca. 1.5 Ga) and lower Wumishan (雾迷山) (ca. 1.45 Ga) formations, Indicating diversified microbial activities and a high organic production. In these petrified blomats, putative microbial fossils (both coccoidal and filamentous) and framboidal pyrites have been identified. The abundance of authigenic carbonate minerals in the host rocks, such as, acicular aragnnites, rosette barites, radial siderites, ankerites, and botryoidai carbonate cements, suggests authigenlc carbonate precipitation from anaerobic oxidation of methane (AOM) under anoxic/euxinic conditions. Warm climate and anoxic/euxinic conditions in the Mesoproterozoic oceans may have facilitated high microbial productivity and organic burial in sediments. Although authigenic carbonate cements may record carbonate precipitation from anaerobic methane oxidation, gas blister (or dome) structures may indicate gas release from active methanogenesls during shallow burial Bituminous fragments in mat-related carbonates also provide evidence for hydrocarbon generation. Under proper conditions, the Mesoproterozoic mat-rich carbonates will have the potential for hydrocarbon generation and serve as source rocks. On the basis of petrified biomats, a rough estimation suggests that the Mesoproterozoic carbonates of the North China platform might have a hydrocarbon production potential in theorder of 10×108t.     

A pulsed oxygenation in shallow seawater recorded by the Mesoproterozoic Wumishan Formation,North China Platform

Oxygen is crucial for the origin and early evolution of eukaryotes. However,the oxygen levels in the atmosphere and shallow ocean of Mesoproterozoic have been poorly constrained,with varying viewpoints including persistent low(equals to <0.1%~1% of the present atmosphere level,PAL),relatively high(>4%~8% of PAL),and dynamic variation. In order to further constrain the redox conditions in shallow waters where eukaryotes inhabited,the Ce anomaly of the peritidal carbonates from lower Member 4 of the Mesoproterozoic Wumishan Formation in North China was investigated. The results show that the significant negative Ce anomalies(Ce/Ce^*=0.82±0.11,n=10)occurs in the carbonate of the lower Member 4 of the Wumishan Formation with the thickness of about 150 m. The carbonate formation with the significant negative Ce anomaly is interlayered between the carbonates with inconspicuous positive Ce anomalies,which may represent a pulsed oxygenation in shallow seawater with a duration of ~5 Ma(~1480-1475 Ma). It reflects that the redox conditions of Mesoproterozoic shallow seawater fluctuated greatly rather than stable at low or relatively high level of oxygen. The results are helpful to determine the evolution of redox state of the Mesoproterozoic shallow sea,and it provides important information for studying the influence of redox state of seawater on the evolution of early eukaryotes.     

华北地台中元古界雾迷山组浅海脉冲式增氧

氧气对真核生物的起源和早期演化至关重要,但是有关元古宙中期大气和浅海氧气浓度的限定却分歧很大,目前存在持续低氧(<0.1%~1%现代大气水平,PAL)、相对高氧(>4%PAL)和动态波动等多种观点。为了进一步揭示真核生物集中分布的浅海水体的氧化还原条件,文中选择华北中元古界雾迷山组四段下部环潮坪碳酸盐岩为研究对象,通过稀土Ce异常重建当时正常浪基面之上海水的氧化还原状态。结果表明,雾迷山组四段下部1段厚约150m的碳酸盐岩地层(~1480-1475Ma)具有明显的Ce负异常(Ce/Ce^*=0.82±0.11,n=10),而下伏和上覆地层均为具弱Ce正异常的碳酸盐岩,可能代表了1次持续时间约5Ma的浅海脉冲式增氧过程。该层段的脉冲式增氧可能表明元古宙中期浅海氧气浓度存在频繁波动,并非处于稳定的低氧或相对高氧平台状态。该研究成果有助于进一步确定元古宙中期浅海氧化还原状态和演变特征,并为探讨海水氧化还原状态对早期真核生物演化的影响提供重要信息。     

Facies Analysis, Sequence Stratigraphy and Diagenetic Studies of the Jurassic Carbonates of the Kohat Basin, Northwest Pakistan: Reservoir Implications

The present study deals with the depositional facies, diagenetic processes and sequence stratigraphy of the shallow marine carbonates of the Samana Suk Formation, Kohat Basin, in order to elucidate its reservoir quality. The Samana Suk Formation consists of thin to thick-bedded, oolitic, bioclastic, dolomitic and fractured limestone. Based on the integration of outcrop, petrographic and biofacies analyses, the unit is thought to have been deposited on a gentle homoclinal ramp in peritidal, lagoonal and carbonate shoal settings. Frequent variations in microfacies based sea-level curve have revealed seven Transgressive Systems Tracts (TSTs) and six Regressive Systems Tracts (RSTs). The unit has undergone various stages of diagenetic processes, including mechanical and chemical compaction, cementation, micritization, dissolution and dolomitization. The petrographic analyses show the evolution of porosity in various depositional and diagenetic phases. The fenestral porosity was mainly developed in peritidal carbonates during deposition, while the burial dissolution and diagenetic dolomitization have greatly enhanced the reservoir potential of the rock unit, as is further confirmed by the plug porosity and permeability analyses. The porosities and permeabilities were higher in shoal facies deposited in TSTs, as compared to lagoonal and peritidal facies, except for the dolomite in mudstone, deposited during RSTs. Hence good, moderate and poor reservoir potential is suggested for shoal, lagoonal and peritidal facies, respectively.     

Sequence stratigraphic framework for mixed aeolian,peritidal and marine environments: Insights from the Pennsylvanian subtropical record of Western Pangaea

Due to difficulties in correlating aeolian deposits with coeval marine facies, sequence stratigraphic interpretations for arid coastal successions are debated and lack a unifying model. The Pennsylvanian record of northern Wyoming, USA, consisting of mixed siliciclastic–carbonate sequences deposited in arid, subtropical conditions, provides an ideal opportunity to study linkages between such environments. Detailed facies models and sequence stratigraphic frameworks were developed for the Ranchester Limestone Member (Amsden Formation) and Tensleep Formation by integrating data from 16 measured sections across the eastern side of the Bighorn Basin with new conodont biostratigraphic data. The basal Ranchester Limestone Member consists of dolomite interbedded with thin shale layers, interpreted to represent alternating deposition in shallow marine (fossiliferous dolomite) and supratidal (cherty dolomite) settings, interspersed with periods of exposure (pedogenically modified dolomites and shales). The upper Ranchester Limestone Member consists of purple shales, siltstones, dolomicrites and bimodally cross‐bedded sandstones in the northern part of the basin, interpreted as deposits of mixed siliciclastic–carbonate tidal flats. The Tensleep Formation is characterized by thick (3 to 15 m) aeolian sandstones interbedded with peritidal heteroliths and marine dolomites, indicating cycles of erg accumulation, preservation and flooding. Marine carbonates are unconformably overlain by peritidal deposits and/or aeolian sandstones interpreted as lowstand systems tract deposits. Marine transgression was often accompanied by the generation of sharp supersurfaces. Lags and peritidal heteroliths were deposited during early stages of transgression. Late transgressive systems tract fossiliferous carbonates overlie supersurfaces. Highstand systems tract deposits are lacking, either due to non‐deposition or post‐depositional erosion. The magnitude of inferred relative sea‐level fluctuations (>19 m), estimated by comparison with analogous modern settings, is similar to estimates from coeval palaeotropical records. This study demonstrates that sequence stratigraphic terminology can be extended to coastal ergs interacting with marine environments, and offers insights into the dynamics of subtropical environments.     

Cross-platform architecture of a sequence boundary in mixed siliciclastic-carbonate lithofacies, Middle Cambrian, southern Great Basin, USA

Stratigraphic analysis of mixed siliciclastic-carbonate lithofacies within the Middle Cambrian Bonanza King Formation of the southern Great Basin reveals three distinct facies associations that record a range of depositional environments from semi-arid tidal flats to deeper subtidal, restricted lagoons. Stratigraphic trends, cross-platform facies variations and correlation of individual surfaces across 250 km of the study area suggest that these mixed lithofacies were deposited in three temporally distinct phases. (1) Extensive progradation of mixed peritidal environments culminated in a prolonged episode of subaerial exposure marked by an areally extensive intraclast breccia (0·5–1·2 m thick) that we interpret to be a major Type 1 sequence-bounding disconformity. (2) Abrupt flooding of the exposed platform resulted in the deposition of mixed deeper subtidal lithofacies, including a condensed interval of fissile, fossiliferous shale. (3) Progressive shallowing and aggradational accumulation was accompanied by a decrease in siliciclastics and a shift to pure carbonate deposition. Deep-water siliciclastics and megabreccias record deposition along the base-of-slope off the Middle Cambrian shelf-edge, and are interpreted to represent lowstand deposits emplaced during the prolonged episode of subaerial exposure of the shallow shelf. The presence of fine siliciclastics in both peritidal facies and sharply overlying deeper subtidal facies of the study interval within the Bonanza King suggests a variable, but relatively continuous, influx of terrigenous material throughout an extended period of accommodation change, apparently asynchronous with respect to the predictive model of reciprocal sedimentation. We suggest that the primary siliciclastic source changed with relative sea-level position. During lowered sea level, aeolian processes acting upon the unvegetated Cambrian craton transported fine siliciclastics onto peritidal and shallow-subtidal environments. During higher sea level, coastal siliciclastic reservoirs supplied sediment that was transported for long distances by geostrophic currents flowing along the submerged platform. As opposed to many Cambro-Ordovician grand cycles that are commonly interpreted to consist of a transgressive shaly half-cycle grading upward into a regressive carbonate half-cycle, the sequence boundary within this Middle Cambrian succession occurs within siliciclastic-rich, mixed lithofacies rather than in adjoining purer carbonates, implying that some ‘grand cycles’ should not be considered synonymous with ‘sequences’. Interbasinal correlations of the Type 1 sequence boundary within the mixed unit are speculative, primarily because of the inherent imprecision of available trilobite biostratigraphy. However, there is evidence that an extended episode of subaerial exposure may have been continent-wide during the Ehmaniella trilobite biochron.     

Peritidal carbonate facies models: A review

Existing facies models for peritidal carbonates are limited in number and do not reflect the wide spectrum of possible types. The major depositional processes in peritidal carbonate environments are reviewed in order to stress the complex nature of the systems. The tidal channel model is critically discussed and it is suggested that channel deposits may be of minor importance in typical shoaling-up sequences. The possible causes of multiple asymmetrical sequences are reviewed.     

Cyclic palaeokarst surfaces in Aptian peritidal carbonate successions (Taurides, southwest Turkey): internal structure and response to mid-Aptian sea-level fall

The sedimentology and cyclic stratigraphy of palaeokarst structures in Aptian peritidal carbonate successions are interpreted using field and laboratory microfacies analyses of closely spaced samples from measured outcrop stratigraphic sections in southwest Turkey. Cycles displaying shallowing-upward metre-scale cyclicity are generally composed of lime mudstones/wackestones/packestones at the bottom and stromatolites or lime mudstones with charophytes and ostracods at the top. Subaerial exposure structures such as in situ karst breccias, dissolution vugs/pipes, mud cracks and sheet cracks are encountered at the top of the cycles. The presence of limestone layers between the successive karst breccia levels indicates that they are in situ palaeokarst structures, not recent karstifications or deep penetration from the upper palaeokarst surface down to the older strata. Palaeokarst breccia deposits are interpreted as mantling breccia formed as a result of epikarstification. Three main palaeokarst levels are recorded in nearly all sections. The sedimentology of the palaeokarst breccias, their position in cyclic peritidal carbonates and the biostratigraphic framework are used to trace the record of the global mid-Aptian sea-level fall in the southwest Taurides. The successive occurrences of three karst breccia levels close to the mid-Aptian sea-level fall correspond to falling periods of high-amplitude sea-level fluctuation within a late high-stand or early fall condition of a third-order sea level.     

微亮晶(臼齿)碳酸盐岩:21世纪全球地学研究的新热点

国际地质对比计划委员会批准启动了 IGCP44 7-元古代臼齿碳酸盐岩和地球演化项目 ( 2 0 0 1～ 2 0 0 5 )〔1〕。本文简要地回顾了臼齿碳酸盐岩的研究历史和最新进展。臼齿碳酸盐岩是一种具有类似大象臼齿的肠状褶皱构造的岩石 ,具有特殊的时限范围 (中 -新元古代 )。试图解释其成因和可能用于古大陆地层对比是本项目研究的重要课题 ,其重要意义还在于它们是解决前寒武纪生物学和地球化学事件的关键。臼齿碳酸盐岩的发育和衰退关系到地球生命起源和海洋碳酸盐岩沉积地球化学的突变。 87Sr/86 Sr年龄同位素测定证明 ,微亮晶 (臼齿 )碳酸盐消失的时限很可能为75 0 Ma。另外 ,中 -新元古代碳酸盐岩地层具有重要的生烃潜力。     

Carbonate ramp-to-deeper shale shelf transitions of an Upper Cambrian intrashelf basin, Nolichucky Formation, Southwest Virginia Appalachians

The Nolichucky Formation (0–300 m thick) formed on the Cambrian pericratonic shelf in a shallow intrashelf basin bordered along strike and toward the regional shelf edge by shallow water carbonates and by nearshore clastics toward the craton. Lateral facies changes from shallow basinal rocks to peritidal carbonates suggest that the intrashelf basin was bordered by a gently sloping carbonate ramp. Peritidal facies of the regional shelf are cyclic, upward-shallowing stromatolitic carbonates. These grade toward the intrashelf basin into shallow ramp, cross-bedded, ooid and oncolitic, intraclast grain-stones that pass downslope into deeper ramp, subwave base, ribbon carbonates and thin limestone conglomerate. Ribbon limestones are layers and lenses of trilobite packstone, parallel and wave-ripple-laminated, quartzose calcisiltite, and lime mudstone arranged in storm-generated, fining upward sequences (1–5 cm thick) that may be burrowed. Shallow basin facies are storm generated, upward coarsening and upward fining sequences of green, calcareous shale with open marine biota; parallel to hummocky laminated calcareous siltstone; and intraformational flat pebble conglomerate. There are also rare debris-flow paraconglomerate (10–60 cm thick) and shaly packstone/wackestone with trace fossils, glauconite horizons and erosional surfaces/hardgrounds. A 15-m thick tongue of cyclic carbonates within the shale package contains subtidal digitate algal bioherms which developed during a period of shoaling in the basin. Understanding the Nolichucky facies within a ramp to intrashelf basin model provides a framework for understanding similar facies which are widely distributed in the Lower Palaeozoic elsewhere. The study demonstrates the widespread effects of storm processes on pericratonic shelf sedimentation. Finally, recognition of shallow basins located on pericratonic shelves is important because such basins influence the distribution of facies and reservoir rocks, whose trends may be unrelated to regional shelf-edge trends.     

Dolomitization by penesaline sea water in Early Jurassic peritidal platform carbonates, Gibraltar, western Mediterranean

Peritidal carbonates of the Lower Jurassic (Liassic) Gibraltar Limestone Formation, which form the main mass of the Rock of Gibraltar, are replaced by fine and medium crystalline dolomites. Replacement occurs as massive bedded or laminated dolomites in the lower 100 m of an ≈460‐m‐thick platform succession. The fine crystalline dolomite has δ¹⁸Ο values either similar to, or slightly higher than, those expected from Early Jurassic marine dolomite, and δ¹³C values together with ⁸⁷Sr/⁸⁶Sr ratios that overlap with sea‐water values for that time, indicating that the dolomitizing fluid was Early Jurassic sea water. Absence of massive evaporitic minerals and/or evaporite solution‐collapse breccias in these carbonate rocks indicates that the salinity of sea water during dolomitization was below that of gypsum precipitation. The occurrence of peritidal facies, a restricted microbiota and rare gypsum pseudomorphs are also consistent with penesaline conditions (salinity 72–199‰). The medium crystalline dolomite has some δ¹⁸Ο and δ¹³C values and ⁸⁷Sr/⁸⁶Sr ratios similar to those of Early Jurassic marine dolomites, which indicates that ambient sea water was again a likely dolomitizing fluid. However, the spread of δ¹⁸Ο, δ¹³C and ⁸⁷Sr/⁸⁶Sr values indicates that dolomitization occurred at slightly increased temperatures as a result of shallow (≈500 m) burial or that dolomitization was multistage. These data support the hypothesis that penesaline sea water can produce massive dolomitization in thick peritidal carbonates in the absence of evaporite precipitation. Taking earlier models into consideration, it appears that replacement dolomites can be produced by sea water or modified sea water with a wide range of salinities (normal, penesaline to hypersaline), provided that there is a driving mechanism for fluid migration. The Gibraltar dolomites confirm other reports of significant Early Jurassic dolomitization in the western Tethys carbonate platforms.     

Depositional environment of the Krol Group of the Nainital area and its impact on the stromatolites

Depositional environment of the Krol group varied temporally from subtidal in the Manora to intertidal in the Sleepy Hollow times. The conditions that succeeded were peritidal in the Ayarpatta and supratidal in the Narainnagar times. These conditions were the main controlling factors in the growth and development of the algal stromatolites. The Manora formation, due to subtidal conditions, and the Sleepy Hollow formation, due to detrital influx, are almost devoid of stromatolites. The carbonates of the Ayarpatta formation representing a peritidal complex possess columnar and oncolitic stromatolites, while the sediments of the Narainnagar formation characterized by supratidal features contain blistered, domal and crinkled-laminar forms. The types and sizes of stromatolites therefore are governed by the depositional conditions prevailing in the sedimentary basin.     

Facies sequences on a carbonate ramp: the Carboniferous Limestone of South Wales

During early Carboniferous times a major sea-level rise led to the development of an extensive carbonate ramp over what is now South Wales. Differential subsidence and sea-level changes resulted in distinctive facies sequences in the ramp succession and a model is offered which recognizes three distinct geomorpho-tectonic settings; inner, mid- and outer ramp. The inner ramp zone occurs in the more landward part of the province and was an area undergoing little or no subsidence. The sequence is dominated by oolitic grainstones and peritidal limestones representing shoal and back shoal environments. The peritidal units are transgressive deposits consisting of stacked asymmetrical shallowing-up cycles. The sequence contains many subaerial breaks and tectonic uplift resulted in base-level changes and fluvial incision. The mid-ramp zone sequence is intermediate in thickness between the inner and outer ramp successions and consists mainly of bioclastic limestones deposited below fairweather wave base. Sedimentation periodically exceeded sea-level rise and subsidence, and regressive (progradational) oolitic sand bodies developed, the thickest of which are stacked units with up to four individual sand bodies. Storm processes were of major importance in this setting. The outer ramp zone is represented by a thick sequence of muddy bioclastic limestones deposited below storm wave base and major Waulsortian reef-mounds also developed. None of the shallowing phases seen in the other ramp zones can be detected in this sequence. Subsidence and eustatic sea-level rise seem to have been the major controls on deposition but the recognition of eustatic sea-level falls is difficult. The detailed facies model for ramp carbonates presented here may be applicable elsewhere in the geological record.     

Anatomy of a cyclically packaged Mesoproterozoic carbonate ramp in northern Canada

Carbonates in the upper member of the Mesoproterozoic Victor Bay Formation are dominated by lime mud and packaged in cycles of 20–50 m. These thicknesses exceed those of classic shallowing-upward cycles by almost a factor of 10. Stratigraphic and sedimentological evidence suggests high-amplitude, high-frequency glacio-eustatic cyclicity, and thus a cool global climate ca. 1.2 Ga.The Victor Bay ramp is one of several late Proterozoic carbonate platforms where the proportions of lime mud, carbonate grains, and microbialites are more typical of younger Phanerozoic successions which followed the global waning of stromatolites. Facies distribution in the study area is compatible with deposition on a low-energy, microtidal, distally steepened ramp. Outer-ramp facies are hemipelagic lime mudstone, shale, carbonaceous rhythmite, and debrites. Mid-ramp facies are molar-tooth limestone tempestite with microspar-intraclast lags. In a marine environment where stromatolitic and oolitic facies were otherwise rare, large stromatolitic reefs developed at the mid-ramp, coeval with inner-ramp facies of microspar grainstone, intertidal dolomitic microbial laminite, and supratidal evaporitic red shale.Deep-subtidal, outer-ramp cycles occur in the southwestern part of the study area. Black dolomitic shale at the base is overlain by ribbon, nodular, and carbonaceous carbonate facies, all of which exhibit signs of synsedimentary disruption. Cycles in the northeast are shallow-subtidal and peritidal in character. Shallow-subtidal cycles consist of basal deep-water facies, and an upper layer of subtidal molar-tooth limestone tempestite interbedded with microspar calcarenite facies. Peritidal cycles are identical to shallow-subtidal cycles except that they contain a cap of dolomitic tidal-flat microbial laminite, and rarely of red shale sabkha facies or of sandy polymictic conglomerate. A transect along the wall of a valley extending 8.5 km perpendicular to depositional strike reveals progradation of inner-ramp tidal flats over outer- and mid-ramp facies during shoaling. The maximum basinward progradation of peritidal facies coincides with a zone of slope failure that may have promoted the development of the stromatolitic reefs.The sea-level history of the Victor Bay Formation is represented by three hectometre-scale sequences. An initial flooding event resulted in deposition of the lower Victor Bay shale member. Upper-member carbonate cycles were then deposited during highstand. Mid-ramp slumping was followed by late-highstand reef development. The second sequence began with development of an inner-ramp lowstand unconformity and a thick mid-ramp lowstand wedge. A second transgression promoted a more modest phase of reef development at the mid-ramp and shallow-water deposition continued inboard. A third and final transgressive episode eventually led to flooding of the backstepping ramp.Overall consistent cycle thickness and absence of truncated cycles, as well as the high rate and amount of creation of accommodation space, suggest that the periodicity and amplitude of sea-level fluctuation were relatively uniform, and point to a eustatic rather than tectonic mechanism of relative sea-level change. High-amplitude, high-frequency eustatic sea-level change is characteristic of icehouse worlds in which short-term, large-scale sea-level fluctuations accompany rapidly changing ice volumes affected by Milankovitch orbital forcing. Packaging of cyclic Upper Victor Bay carbonates therefore supports the hypothesis of a late Mesoproterozoic glacial period, as proposed by previous workers.     

Cavity‐filling dolomite speleothems and submarine cements in the Ediacaran Dengying microbialites,South China: Responses to high‐frequency sea‐level fluctuations in an ‘aragonite–dolomite sea’

Speleothems, mostly composed of calcium carbonate, are widely present in modern karst‐originated caves, but have rarely been reported in palaeokarst systems. This study presents a novel type of dolomite speleothem and subsequent submarine dolomite cement, which are widely present in the upper Ediacaran Dengying Formation in the upper Yangtze area. These precipitated materials occur in the cavity system that cuts across several peritidal cycles. The interconnected cavity networks with irregular shapes, embayed walls, internal breccias on cavity floor and their preferential development in the shallower cycle tops (for example, tepee‐deformed beds) suggest that they were initially generated by subaerial dissolution. As the earliest infills, the hemispherical protrusions, icicle‐like pendants and ground‐up columns show similar morphological features and occurrence patterns to the cave popcorn, stalactites and stalagmites, respectively. Thus, these earliest infills are speleothems resulting from associated meteoric precipitation during subaerial exposure. The isopachous growth pattern of subsequent more extensive fibrous dolomite cements points to a submarine diagenetic environment in which they were precipitated. Microscopically, the micritic to micro‐crystalline dolomite, acicular dolomite in speleothems and the subsequent fibrous dolomite share similar crystal fabrics to metastable precursors (for example, Mg‐calcite). Meanwhile, the carbon‐oxygen isotope compositions of the speleothem and fibrous dolomite, although partly altered by burial diagenesis, share a large overlap with host rock and coeval marine carbonates all over the Yangtze Platform. For these reasons, these speleothems and fibrous cements are considered to have been initially precipitated as metastable carbonate precursors in meteoric and submarine environments, respectively, and stabilized during submarine mimetic dolomitization. The cyclic occurrence of cavity systems filled with speleothems and submarine cements reflects periodic subaerial exposure and marine flooding of broad tidal flat in the upper Yangtze area, driven by high‐frequency sea‐level fluctuations. Furthermore, the Neoproterozoic seawater chemistry that favoured early dolomitization of carbonate precursor mineralogies was an advantage for the preservation of fabrics from metastable precursor minerals.     

A review of the origin and setting of tepees and their associated fabrics

Carbonate hardgrounds often occur at the surface of shallow subtidal to supratidal, lacustrine, and subaerial carbonate shelf sediments. These are commonly disrupted and brecciated when the surface area of these crusts increases. In the subtidal environment, megapolygons form when cementation of the matrix causes the surface area of the hardgrounds to expand. Similar megapolygons form in the supratidal, lacustrine and subaerial settings when repeated incremental fracturing and fracture fill by sediment and/or cement also causes the area of the hardgrounds to expand. The arched up antiform margins of expansion megapolygons are known as tepees. The types of tepees found in the geological record include: (1) Submarine tepees which form in shallow carbonate-saturated waters where fractured and bedded marine grainstones are bound by isopachous marine-phreatic acicular and micritic cements. The surfaces of these brecciated crusts have undergone diagenesis and are bored. Unlike tepees listed below they contain no vadose pisolites or gravity cements; (2) Peritidal and lacustrine tepees are formed of crusts characterized by fenestral. pisolitic and laminar algal fabrics. This similarity in fabric makes these tepees of different origins difficult to separate. Peritidal tepees occur where the marine phreatic lens is close to the sediment surface and the climate is tropical. They are associated with fractured and bedded tidal flat carbonates. Their fracture fills contain geopetal asymmetric travertines of marine-vadose origin and/or marine phreatic travertines and/or Terra rossa sediments. The senile form of these peritidal tepees are cut by labyrinthic dissolution cavities filled by the same material. Lacustrine tepees form in the margins of shallow salinas where periodic groundwater resurgence is common. They include groundwater tepees which form over evaporitic ‘boxwork’ carbonates, and extrusion tepees which also form where periodic groundwater resurgence occurs at the margins of shallow salinas, but the dominant sediment type is carbonate mud. These latter tepee crusts are coated and crosscut by laminated micrite; the laminae extend from the fractures downward into the underlying dolomitic micrite below the crust. Both peritidal and lacustrine tepees form where crusts experience alternating phreatic and vadose conditions, in time intervals of days to years. Cement morphologies reflect this and the crusts often contain gravitational, meniscus vadose cements as well as phreatic isopachous cement rinds. (3) Caliche tepees which are developed within soil profiles in a continental setting. They are formed by laminar crusts which contain pisolites, and fractures filled by micritic laminae, microspar, spar and Terra rossa. Most of the cements are gravitational and/or meniscoid. In ancient carbonates, when their cementation and diagenetic fabric can be interpreted, tepee structures can be used as environmental indicators. They can also be used to trace the evolution of the depositional and hydrological setting.     

西南寒武、二叠系富硒碳质岩中硒结合态的比较研究

使用硒的7步连续化学提取技术,对采自贵州寒武纪牛蹄塘组和湖北恩施二叠纪茅口组富硒碳质岩中的水溶态、可交换态、有机态、元素态、酸性提取态、硫化物/硒化物态和残渣态硒进行了比较研究,应用氢化物－原子荧光法测定了岩石总硒和各结合态硒。结果表明,恩施二叠纪沙地新鲜富硒碳质硅质岩和碳质页岩中的硒主要以有机结合态和硫化物/硒化物态硒为主,残渣态硒较低;遵义松林早寒武世碳质硅质岩中的硒主要以有机结合态和硫化物态硒为主,碳质页岩与镍钼矿层中则以有机结合态、残渣态和硫化物态硒为主,斑脱岩中主要以有机结合态、元素态和可交换态硒为主。根据硒结合态的这种分布特征,推测二叠纪、寒武纪富硒碳质岩中硒初始富集的生物地球化学过程略有差异：前者碳质硅质岩中主要以微生物还原为主,碳质页岩中则是微生物还原作用和生物同化吸收或吸附兼而有之;后者主要以生物同化吸收或吸附为主,微生物还原次之。