Anthropogenic influence on the degradation of an urban lake - The Pampulha reservoir in Belo Horizonte, Minas Gerais, Brazil

The artificial reservoir Lagoa da Pampulha in central Brazil has been increasingly affected by sediment deposition and pollution from urban and industrial sources. This study investigates water chemistry and heavy metal concentrations and their fractionation in the lake sediment using ICP-OES, ICP-MS, and XRD analyses. Fractionation analysis was done by sequential extraction under inert gas as well as after oxidation. The lake exhibits a permanent stratification with an oxygen-free hypolimnion below 2 m depth. Nutrient concentrations are enriched for phosphorous components (SRP, PO₄). In the sediment it was not possible to detect oxygen. Carbon, sulfur, and most of the analyzed heavy metals are enriched in the top sediment layer with a pronounced downward decrease, indicating the presence of an anthropogenic influence. Statistical analysis, including correlations and a Principal Component Analysis (PCA) of depth-related total concentration data, helps to distinguish presumably anthropogenic heavy metals from geogenic components. Some samples with high element concentrations in the sediment also show elevated concentrations in their pore water. Analyses of element distribution between sediment and pore water suggest a strong bonding of heavy metals to the anoxic sediment. The trend towards elevated solubility in the pore water of oxidized samples is clear for most of the analyzed elements. Fractionation analysis reveals characteristic associations of selected elements to specific mineral bonding forms. In addition, it indicates that the behavior of heavy metals in the sediment is strongly influenced by organic substances. These substances provide buffering against oxidation, acidification, and metal release. The high nutrient loading causes reducing conditions in the lake sediment. These conditions trigger the accumulation of sediments rich in S²⁻, which stabilizes the fixation of heavy elements. In the future, care must be taken to reduce the supply of contaminants and to prevent the release of heavy metals from sediments dredged for remediation purposes.     

The impact of silt trapping in large reservoirs on downstream morphology: the Yangtze River

The sediment load of the Yangtze River (China) is decreasing because of construction of dams, of which the Three Gorges Dam (TGD) is the best known example. The rate of the decline in sediment load is well known, but changes in the sediment grain size distribution have not been given much attention. The TGD mostly traps sand and silt while clay is flushed through the reservoir. A large amount of sand is available in the Yangtze River downstream of the reservoir, and therefore the pre-dam sand concentration is not substantially reduced. The availability of silt on the Yangtze River bed is limited, and it is expected that most silt will be removed from the riverbed within one to two decades. In order to evaluate the impact of the change in grain size distribution on the tidal flats of the Yangtze Estuary, a highly schematized tidal flat model is setup. This model broadly reveals that the observed deposition rates are exceptionally large because of the high sediment concentration, the abundance of silt, the seasonal dominance of waves (shaping a concave profile), and the offshore tidal asymmetry. The model further suggests that deposition rates will be limitedly influenced by reductions in clay or fine silt but strongly impacted by reductions in median to coarse silt. The response of the downstream morphology to reservoir sedimentation therefore strongly depends on the type of trapped sediment. As a consequence, silt-dominated rivers, such as the Yangtze River and the Yellow River may be more strongly impacted than sand-dominated systems.     

Chemical forms of heavy metal contaminants in sediments of Miyun reservoir

The chemical forms, spatial distribution and sources of As, Hg, Cd, Pb and Zn in sediments of the Miyun reservoir were studied. The results of sequential extraction demonstrate that most of As, Pb and Zn were bound to the residual fraction, Hg was associated with the sulfide fraction while Cd was associated with the carbonate fraction and the residual fraction. On the vertical profiles the concentrations of the heavy metals in total and each fractions mostly decreased with increasing depths in sediments, suggesting that the heavy metals input from the upstream watershed increases yearly. Summation of the residual fraction, the sulfide fraction and the carbonate fraction accounts for 60.03%―85.60% of the total heavy metal contents in the sediments, which represent the geochemical background values of the elements and relate closely to soil erosion. Results of the main factor analysis show that most sediments of the reservoir come from the upstream soil erosion, the point source pollution and domestic waste. Moreover, the microbial activities taking place on the sediment-water interface are also one of the major factors to cause the increasing content of the organic matter fraction and the iron-manganese oxide fraction. Environmental change of the reservoir water could make the removability of the heavy metals increase, leading to the increase of their concentrations in pore water in sediments, and imperiling water quality of the reservoir.     

Application of a confluence‐based sediment‐fingerprinting approach to a dynamic sedimentary catchment,New Zealand

Fine sediment is a dynamic component of the fluvial system, contributing to the physical form, chemistry and ecological health of a river. It is important to understand rates and patterns of sediment delivery, transport and deposition. Sediment fingerprinting is a means of directly determining sediment sources via their geochemical properties, but it faces challenges in discriminating sources within larger catchments. In this research, sediment fingerprinting was applied to major river confluences in the Manawatu catchment as a broad‐scale application to characterizing sub‐catchment sediment contributions for a sedimentary catchment dominated by agriculture. Stepwise discriminant function analysis and principal component analysis of bulk geochemical concentrations and geochemical indicators were used to investigate sub‐catchment geochemical signatures. Each confluence displayed a unique array of geochemical variables suited for discrimination. Geochemical variation in upstream sediment samples was likely a result of the varying geological source compositions. The Tiraumea sub‐catchment provided the dominant signature at the major confluence with the Upper Manawatu and Mangatainoka sub‐catchments. Subsequent downstream confluences are dominated by the upstream geochemical signatures from the main stem of Manawatu River. Variability in the downstream geochemical signature is likely due to incomplete mixing caused in part by channel configuration. Results from this exploratory investigation indicate that numerous geochemical elements have the ability to differentiate fine sediment sources using a broad‐scale confluence‐based approach and suggest there is enough geochemical variation throughout a large sedimentary catchment for a full sediment fingerprint model. Combining powerful statistical procedures with other geochemical analyses is critical to understanding the processes or spatial patterns responsible for sediment signature variation within this type of catchment. Copyright © 2015 John Wiley & Sons, Ltd.     

A grain-size correction for metal pollution indexes in river sediments

According to the List of Hazardous Substances of the Agency of the Toxic Substances and Disease Registry(ATSDR 2017),some metallic elements such as Pb or Cd are still considered as the most polluting elements in the world.These elements accumulate in sediments,and there are various methods available that differentiate lithogenic sources from anthropogenic sources.For that,the natural geochemical background is required,however,its definition is far from unanimous:it can be a global or local value,single or statistically estimated value,depending on the studies.Our study is focused on the Suba
e River in the state of Bahia,Northeastern Brazil,which was historically contaminated by lead metallurgy.The river sediments were sampled at 21 locations:one at the discharge point of the plant's rainwater basin,ten upstream,and ten downstream.The total contents of Fe,Ti,Mn,Pb,Zn,Cu,Cr,particle-size distribution,and organic matter were analyzed.The conventional geochemical indexes,i.e.,the pollution degree(mCd),pollution load index,and enrichment factor indicated contamination by Zn,Pb,Cr,and Cu.Then,a new enrichment factor is introduced,assuming that the sediments come from erosion of soils in the watershed.After obtaining the natural concentrations of metals in the clay,silt,and sand fractions of uncontaminated reference soils,we corrected the pollution indexes by calculating a new individual background in each sediment sample,according to its grain size distribution.This new approach provided more precise indexes in the assessment of sediment pollution,by highlighting higher contamination of Zn and Pb(around 50%)and at the same time the absence of Cr and Cu contamination,two metals not involved with the metallurgical activity.     

Distribution and accumulation of heavy metals in carbonate and reducible fractions of marine sediment from offshore mid-western Taiwan

Two marine sediment cores from offshore mid-western Taiwan were subsampled and pre-treated using a sequential extraction procedure to separate carbonate and reducible fractions. Aliquots of these extracts were analyzed to determine their chemical composition to evaluate the geochemical processes responsible for heavy metal distribution and accumulation in the coastal environment. Our data demonstrate that sedimentation rates derived from excess ²¹⁰Pb associated with metal fluxes show large increases circa A.D. 1990. A well-synchronized increase in metal flux in both geochemical fractions was found and validated by Pearson’s correlation. Principal component analysis revealed the heavy metal fluxes to be highly correlated with the sediment deposition rate, with metal contamination potentially driven by a sole contributor. This study emphasizes the changes in sedimentation rate is potentially caused by activities associated with the inland economic development during this time, rather than by raising heavy metal pollution dominated the accumulation offshore mid-western Taiwan.     

The Nature of sediments in some wetlands

Five wetlands of temporary-shallow, temporary-deep and permanent-deep types, falling in the inland, channel or stream and riverine drainage basins were studied for their sediment, chemical and textural composition. The content of clay was maximum in the inland type as against the higher content of silt and sand at the channel and riverine sites, respectively. Among the various sediment fractions only the silt particles were distributed along depth gradients. Clay particles were positively correlated with the phosphorus content only, while the organic carbon content was correlated with the levels of calcium and nitrogen in the sediments. Calcium was also positively related to phosphorus, while correlations between all other elements were insignificant. It is concluded that the hydrolytic regime is the major factor determining the nature of wetland sediments.     

Grain-size distribution,morphoscopy and elemental chemistry of suspended sediments of Pindari Glacier,Kumaon Himalaya,India

Abstract

Suspended sediment concentrations in the meltwater of Pindari Glacier were determined at regular intervals in four ablation seasons. The late ablation periods (September 1994 and October 1995) were characterized by a reduced level of sediment concentration, while the sampling periods of early ablation (May 1994 and July 1995) showed very high concentrations of suspended sediment in the meltwater. Grain size distribution shows the dominance of medium and coarse silt fractions of the mean size of the suspended sediments between 4.35 and 5.82 ø. Clay size constitutes about 7% of the total size population. The majority of the samples are poorly sorted, symmetrically to finely skewed and mesokurtic in nature. The grain shows texture of mechanical and chemical origin, in which mechanical texture is predominant on most of the grains. It was observed that the grains were mostly subangular to subrounded in shape with variable size ranges. Bulk sediment chemistry consists mostly (>70%) of the five elements, Si, Al, K, Fe and Mg. Iron (Fe) and Mn are dominant heavy metals and sediments show the elemental abundance in the order of Fe > Mn > Zn > Cu > Ni > Pb. The Chemical Index of Alteration (CIA) of suspended sediments (57) is relatively higher than in the case of average unweathered upper continental crust (~50) indicating a higher degree of weathering due to glacier grinding and crushing action. Quartz is the most dominant mineral, followed by mica, illite, feldspar and kaolinite.     

Concentration and fractionation of trace metals in surface sediments of intertidal Bohai Bay, China

Surface sediments from intertidal Bohai Bay were sampled for the geochemical and environmental assessment of six trace metals (Cd, Cr, Cu, Ni, Pb and Zn). Results indicate that sediment grain size plays an important role in controlling the distribution and fractionation of them. Metal concentrations in clayey silt sediments are all clearly higher than in sand and silty sand ones. Cd and Pb in clayey silt sediments are more mobile than in sand and silty sand ones. Two sediment quality guidelines and two geochemical normalization methods (index of geoaccumulation and enrichment factor) were used to judge the potential risk and accumulation of metals. According to the mean probable effects level quotient, the combination of studied metals may have a 21% probability of being toxic. The sediments with high fraction of clay and silt have been contaminated by trace metals to various degrees, among which Cr contributes the most to contamination.     

太湖梅梁湾沉积岩芯元素地球化学记录的多元统计分析

通过沉积岩芯元素含量垂直分布和富集因子分析,结合多元统计方法如系统聚类和模糊聚类分析,研究了太湖梅梁湾沉积岩芯元素地球化学记录的湖泊环境演化过程.以系统聚类分析和模糊聚类分析为基础,将梅梁湾地球化学记录的环境过程划分为如下几个层段:0-6cm为人类活动强烈干扰的阶段,25-50cm和55-72cm层段都是自然过程的表现,反映了流域物源的影响,而两层段元素记录的差异反映了不同自然作用驱动下的湖泊环境变化;6-25cm和50-55cm层段则是不同环境特征的过渡阶段,因此,综合应用多元统计方法可以更直观更精确地量化影响湖泊环境的因素,有助于恢复湖泊环境历史演化过程.     

Geochemical baselines of major, minor and trace elements in the tropical sediments of the Terengganu River basin, Malaysia

The geochemical baselines and distribution of 31 elements (Al, Fe, K, Na, Mg, Ca, Mn, Ba, Cr, Zr, Ni, Sr, Zn, Y, Li, Cu, Mo, Nb, Th, Co, Ga, W, Ta, Be, Ti, Ge, Se, Bi, Te, Sc and Re) and physico-chemical parameters of the tropical surface sediments of the Terengganu River basin, Malaysia, are reported. Sediments are sandy loam to sand in texture consisting of mostly quartz, low organic matter content (average-2.68%), low CEC (average-2.02 cmol(+)/kg) and mildly acidic pH1:5 (average-5.91). Concentrations of Mn, Fe, Ba, Cr, Ni, Cu, Mo and Se were measured to be above the environmental sediment quality criteria at various locations. Lake sediments registered significantly higher Al, Fe, Ti, Mg, Ca, Mn, Te and Sc concentrations as compared to the river sediments. Most of the elements investigated showed an association with silt size fraction (2-63 μm). Among the investigated metals, Mo and Fe concentrations showed an increasing (5-fold) and decreasing (3-fold) trend, respectively, along the river path from the upstream to the downstream depending on the stream pH-redox conditions. The enrichment factor values (EF 5) of Cr, Ni, Mo and Se indicated enrichment from anthropogenic activities. Alkali and alkali earth metals registered a significant depletion (EF values 0.7) as compared to the Earth's crust. Principal component analysis of the two main components (PC1, 87.4% and PC2, 8.7%) revealed a well-defined group of estuary sediments. Lake and river sediment sampling locations did not form defined groups revealing heterogeneity in the origin of geologic material and the in-stream geochemical processes. However, Cr, Ni, Mo and Se formed a separate group with elevated concentrations (e.g. Cr1,000 mg/kg) indicating contamination of sediments. This work presents the geochemical baselines of the tropical sediments as industrial development and urbanization along the north east coast of Peninsular Malaysia are advancing rapidly.     

Impact evaluation of the industrial activities in the Bay of Bakar (Adriatic Sea,Croatia): Recent benthic foraminifera and heavy metals

The Bay of Bakar is one of the most heavily polluted bays at the Eastern Adriatic. Three major industrial companies potentially endanger the bay. The concentration of major, minor and trace elements in surface sediments from thirteen stations was discussed in relation to the sediment type and foraminiferal assemblages. The distribution of major elements in the bay is influenced by geological nature of surroundings. Heavy metal distribution depends on pollution sources and on amount of mud fraction: fine-grained sediments are enriched by them in comparison with coarse-grained ones. Different sediment quality criteria complicate the pollution assessment in the bay. Heavy metal concentrations generally fall into allowed depositional values for marine environments; only area in front of the coke plant and the City of Bakar harbor is heavily polluted. Stress-tolerant foraminiferal species dominate at stations with higher concentrations of heavy metals and coarse-grained sediments consist of larger number of epifaunal taxa.     

Geochemical evidence of human impacts on deep Lake Fuxian,southwest China

Human activities in Lake Fuxian and its catchment have caused environmental changes that are preserved in the geochemical records of lake sediments. Human activities responsible for the environmental changes include agriculture, mining, industrial development, and fishery management. To elucidate human impacts on this deep water body during the past several decades, two short sediment cores were collected from the lake, dated by ¹³⁷Cs, and analyzed for several geochemical variables (total organic carbon (TOC), total nitrogen (TN), δ¹³C and heavy metals). The multi-proxy geochemical and isotopic evidence can be used to divide the limnological record into a 3-part history. Although increasing inputs of chromium (Cr) had begun as early as the 1950s, human activities, including heavy metal contamination, apparently had little effect on lacustrine production, as δ¹³C, TOC, TN and TOC/TN were relatively constant until the 1980s. Mining and industry have generated large amounts of heavy metal elements such as Zn, Pb and Cd that have been deposited into the lake since the 1980s, increasing to their highest concentrations over the last decades. Zn, Pb and Cd probably were released by industrial processes such as the manufacture of cement. Cr concentrations increased at site FB, but declined at site FZ, most likely due to the closer proximity of site FB to the source of metal production. From the middle of the 1980s, the decreased δ¹³C, and increased TOC, TN and TOC/TN suggest a broad change in lake ecology. In the 1980s, a new fish species was introduced into Lake Fuxian and fish yields increased quickly, which may mark the beginning of a change in ecosystem structure.     

Effects of bottom sediments on the survival of Enterobacter aerogenes in seawater

The survival of the coliform bacterium Enterobacter aerogenes in seawater was greatly affected by the underlying bottom sediments. The presence of sediments which contained higher concentrations of organic nutrients than the overlaying seawater prolonged the survival and even enabled growth of the bacterial cells. Results obtained from chemical analysis indicated that sediments of fine-grained, silt-clay type contained highest amounts of organic nutrients as compared with sediments with larger particle sizes such as silt and sand grains. Thus, nutrient contents of the sediments were found to be inversely proportional to sediment particle size. The degree of prolonged survival of E. aerogenes was also found to be inversely proportional to the size of the sediment particles presented. Release of the bound nutrients which became available to cells of E. aerogenes from sediments by action of waves and human activities can explain, at least in part, why high counts of coliform bacteria are obtained in coastal and beach waters.     

Sediment geochemistry of the urban Lake Paulo Gorski

The objective of this study was to evaluate the concentration and distribution of heavy metals in the sediments of Paulo Gorski Lake, as well as the metals’ bioavailability and potential ecological risk, and to define the anthropogenic and natural heavy metal contributions to the lake. The chemical elements calcium (Ca), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), iron (Fe), potassium (K), magnesium (Mg), manganese (Mn), sodium (Na), nickel (Ni), lead (Pb), and zinc (Zn) were quantified by flame atomic absorption spectrophotometry with two extraction methods to quantify the bioavailable and non-bioavailable fractions. The data were evaluated using multivariate statistics and sediment quality indices. All sediment collection points (S1, S2, S3, S4 and S5) are different in terms of the concentration of heavy metals, except for S4 and S5, which were statistically equal. The bioavailable fraction of the elements in the sediment follows the sequence Pb>Cu>Mn>Zn>Ni>Cr>phosphorus (P) for all points. The elements Co, Cr, Pb, and Zn showed moderate to considerable contamination at all points. Only points S3 and S5 had moderate ecological risk. Urbanization has been affecting Paulo Gorski Lake via the input of chemical elements, especially Co and Pb. The points most affected by heavy metal contamination are S3 and S5 when the sedimentological sensitivity factor is considered. The lake has high hydrodynamics, causing some of the contaminants that enter the system to leave it, leading to potential negative impacts downstream.     

Blanket peat erosion and sediment yield in an upland reservoir catchment in the southern Pennines,UK

This paper investigates temporal variations in fluxes of peat and other sediment in the catchment of March Haigh Reservoir, West Yorkshire. Long‐term estimates of sediment yield were derived from a study of reservoir sediments. Magnetic properties were used to correlate ten cores to a master profile dated using ²¹⁰Pb and ¹³⁷Cs. A ¹⁴C date suggests that most of the organic component of the sediment is allochthonous and derived from peat eroded from the catchment. Organic sediment yields suggest low catchment erosion rates between 1838 and 1963. Blanket peat erosion increased significantly after 1963, and peaked between 1976 and 1984. Estimates of total sediment yield range between 2 and 28 t km^?2 a^?1. These yields are significantly lower than those from some previous studies examining reservoir sedimentation in other blanket peat‐covered catchments. The low yield estimates may be due to relatively low rates of erosion in the basin, but may also be partly explained by maintenance of silt traps during the early life of the reservoir and removal of sediment by scouring. Sedimentation within the reservoir is spatially variable, and bathymetry and sediment source appear to be the dominant controls on sedimentation patterns within the reservoir. Copyright © 2005 John Wiley & Sons, Ltd.     

Estimation of sediment sources using selected chemical tracers in the Perry lake basin,Kansas,USA

The ability to achieve meaningful decreases in sediment loads to reservoirs requires a determination of the relative importance of sediment sources within the contributing basins. In an investigation of sources of fine-grained sediment （clay and silt） within the Perry Lake Basin in northeast Kansas, representative samples of channel-bank sources, surface-soil sources （cropland and grassland）, and reservoir bottom sediment were collected, chemically analyzed, and compared. The samples were sieved to isolate the 〈63μt m fraction and analyzed for selected nutrients （total nitrogen and total phosphorus）, organic and total carbon, 25 trace elements, and the radionuclide cesium-137 （^137Cs）. On the basis of substantial and consistent compositional differences among the source types, total nitrogen （TN）, total phosphorus （TP）, total organic carbon （TOC）, and ^137Cs were selected for use in the estimation of sediment sources. To further account for differences in particle-size composition between the sources and the reservoir bottom sediment, constituent ratio and clay-normalization techniques were used. Computed ratios included TOC to TN, TOC to TP, and TN to TP. Constituent concentrations （TN, TP, TOC） and activities （^137Cs） were normalized by dividing by the percentage of clay. Thus, the sediment-source estimations involved the use of seven sediment-source indicators. Within the Perry Lake Basin, the consensus of the seven indicators was that both channel-bank and surface-soil sources were important in the Atchison County Lake and Banner Creek Reservoir subbasins, whereas channel-bank sources were dominant in the Mission Lake subbasin. On the sole basis of ^137Cs activity, surface-soil sources contributed the most free-grained sediment to Atchison County Lake, and channel-bank sources contributed the most fine-grained sediment to Banner Creek Reservoir and Mission Lake. Both the seven-indicator consensus and ^137Cs indicated that channelbank sources were dominant for Perry Lake and that channel-bank sources increased in importance with distance downstream in the basin.     

Heavy Metals in Bottom Sediment in the Upper and Lower Volga

Heavy metal concentrations in bottom sediment in some reaches of the Upper (the Ivankovo Reservoir) and Lower Volga (from Volgograd to the mouth offshore area). The bottom sediment in the Ivankovo Reservoir are shown to be heavily polluted by Cu and Zn and to a lesser extent, by Co and Ni; heavy pollution with Ni and Cr and moderate pollution with Zn and Mn were recorded in the Lower Volga. Principal component procedure was used to assess bottom sediment pollution. The role of organic matter in the formation of the Ivankovo Reservoir bottom sediment pollution with heavy metals is shown to be moderate because of the weak correlation between heavy metal concentration and organic matter content of bottom sediment. The same is true for the Lower Volga because of low organic matter content of bottom sediment. The major role in the redox cycle of elements is shown to belong to Fe in the Ivankovo Reservoir and Mn in the Lower Volga.     

Flume‐ and field‐based evaluation of a time‐integrated suspended sediment sampler for the analysis of sediment properties

Suspended sediment has been identified as a vector for nutrient and contaminant transport in the fluvial environment. A time‐integrated sampler (the Phillips sampler), which emerged over a decade ago as a cost‐effective tool for in situ suspended sediment collection, is increasingly being used to collect samples for the analysis of sediment properties such as particle size composition, and nutrient and contaminant concentrations. This study evaluates the sampler under both flume and field conditions for efficiency in the mass and grain size of the suspended sediment collected. The sampler was tested in a flume using both kaolinite and sediment samples (sieved to < 180 µm) collected from the Quesnel River, British Columbia, Canada. In the kaolinite trails, the sampler preferentially collected coarser grain sizes compared to the original sediment, probably due to finer sediment remaining in suspension and therefore passing through the sampler, and also possibly due to flocculation of the kaolinite upon introduction to the flume. Conversely, the sampler collected river sediment that was finer than the original sediment, probably due to some settling of coarser sediment observed at the bottom of the flume. Once allowance was made for these operational issues associated with the flume, maximum sediment mass efficiency for kaolinite and river sediment was 43% and 87%, respectively. Sediment collected by the time‐integrated sampler during field deployment and adjacent channel bed sediment were also compared. The sampler collected sediment with a representative grain size distribution. However, there were differences in the geochemical (arsenic and selenium) concentrations of channel bed sediment and sediment collected by the Phillips sampler which may be a function of differences in the behavior of geochemical elements associated with the two types of sediment. This work suggests that further research is needed to evaluate the role of the Phillips sampler in collecting sediment for contaminant and nutrient analysis. Copyright © 2014 John Wiley & Sons, Ltd.     

Spatial variability of metals in the inter-tidal sediments of the Medway Estuary,Kent, UK

Concentrations of major and trace metals were determined in eight sediment cores collected from the inter-tidal zone of the Medway Estuary, Kent, UK. Metal associations and potential sources have been investigated using principal component analysis. These data provide the first detailed geochemical survey of recent sediments in the Medway Estuary. Metal concentrations in surface sediments lie in the mid to lower range for UK estuarine sediments indicating that the Medway receives low but appreciable contaminant inputs. Vertical metal distributions reveal variable redox zonation across the estuary and historically elevated anthropogenic inputs. Peak concentrations of Cu, Pb and Zn can be traced laterally across the estuary and their positions indicate periods of past erosion and/or non-deposition. However, low rates of sediment accumulation do not allow these sub surface maxima to be used as accurate geochemical marker horizons. The salt marshes and inter-tidal mud flats in the Medway Estuary are experiencing erosion, however the erosion of historically contaminated sediments is unlikely to re-release significant amounts of heavy metals to the estuarine system.