A geochemical method for removing the effect of tephra on lake diatom oxygen isotope records

The analysis of oxygen isotope ratios (δ¹⁸O) in biogenic silica (e.g. diatoms, sponge spicules, phytoliths) is an increasingly utilised palaeoclimatic proxy for lakes and oceans, providing an alternative to carbonate δ¹⁸O. Currently, the problems associated with the cleaning and extraction of pure diatom silica, especially from lake sediments, may compromise the precision associated with δ¹⁸O_diatom records. This is because, despite improvements in cleaning techniques, it is still difficult to remove silica-containing contaminants (e.g. tephra, silts and clays) from biogenic silica. Where it has proved difficult to remove all the silica bearing contaminants from a sample, mass balance calculations involving point counting have been used, but these are inherently inaccurate as they only consider the surface area of the contaminant, rather than volume. The new method described here assesses the volume of contamination in each sample of biogenic silica by using major and trace element geochemistry, allowing the δ¹⁸O of the contamination to be removed from the biogenic silica δ¹⁸O value by linear mass balance. In this case, diatom silica was contaminated with tephra, however the method should also be applicable to other contaminants such as silts and clays.     

Density-induced settling of tephra through organic lakesediments

Tephras are often used in paleolimnology and other stratigraphicapplications as a chronostratigraphic marker. Where analytical errors inradiocarbon or other dating methods make precise comparison between sitesdifficult, tephras provide an absolute stratigraphic reference that can be usedto assess the relative ages of events across a region. Applications oftephrochronology typically make the assumption that a tephra is deposited atwhat was the top of the stratigraphic sequence at the time of deposition, andthat the contact between the tephra and underlying sediments is anisochron. This paper presents evidence from two lakes in western Canadawhich suggest that tephras may be very mobile within the sedimentary column,particularly in low-density organic lake sediments. Analysis of sedimentcores from Copper Lake, Alberta, suggest that the 6730 BP Mazama tephra moveddown-core by the equivalent of more than 3000 years. A vertical exposureof the Holocene sediments from Doal Lake, Yukon Territory, reveals that the1200 BP White River (WR) tephra, found throughout the southern Yukon, moveddown-sequence through organic lake sediments, to a stratum dating toapproximately 10,000 BP, creating conformable tephra beds at that level. Thistype of stratigraphic displacement has important consequences for the use oftephrochronology in lakes and other soft-sediment environments andunderscores the importance of properly identifying tephras and criticallyassessing their stratigraphic context within a lake core.     

Changing sedimentation patterns due to historical land-use change in Frenchman’s Bay,Pickering, Canada: evidence from high-resolution textural analysis

This study examines the anthropogenic alteration of sedimentation in Frenchman’s Bay in Lake Ontario, using high-resolution particle size analysis in two 200 cm cores. Lithofacies were determined using the particle size data of both the terrigenous sediment and terrigenous sediment + diatom fractions. Terrigenous particle size data from the centre of the lagoon provided the most representative record of anthropogenic impacts. Three distinctive lithofacies were recognized: (1) a Natural Wetland (NW) lithofacies (106–200 cm) had an average mean particle size of 49.4 μm, a mode of 29.4 μm and an average standard deviation of 119.1 μm; (2) an Agricultural and Deforestation (AD) lithofacies (40–105 cm) had a statistically significant lower average mean (30.8 μm), mode (13.5 μm), and standard deviation (48.5) μm; (3) an Urbanized (U) lithofacies (0–40 cm) showed a continued trend towards smaller particle sizes with an average mean of 21.2 μm, a mode of 9.4 μm, and an average standard deviation of 32.7 μm. The lithofacies correlated with previously identified trends in thecamoebian biofacies and magnetic susceptibility data showing post-colonial lagoon eutrophication and increased overland soil erosion. The up-core trend towards finer and less variable particle sizes is attributed to erosion of fine-grained watershed sediments (glacial Lake Iroquois silts and clay) during land-clearance and modification of natural drainage patterns. The influx of silts and clays into the lagoon is also recorded by increased sediment accumulation rates and a reduction in seasonal sediment variability in the wetland. Based on the ²¹⁰Pb dates, sedimentation rates increased at 1850 ±56 AD (AD lithofacies) and suggest an exponentially increasing trend in accumulation rates. Increasing sedimentation rates can be attributed to the progressive loss of native vegetation and intensified erosion of Lake Iroquois deposits via stream and hillslope erosion. Ecologically, the increased input of fine-grained sediments into the wetland has resulted in reduced water clarity and has altered the wetland substrate contributing to wetland loss in Frenchman’s Bay.     

生物硅在东南极湖泊古初级生产力研究中的应用

本文对南极中山站区的莫愁湖和大明湖沉积物中生物硅、有机质等环境指标进行了分析,并在对比研究的基础上,探讨了生物硅在重建东南极湖泊沉积生态环境记录研究中的应用.研究结果表明,大量保存较好的硅藻出现在东南极淡水湖泊沉积物中,生物硅含量在深度剖面上表现出显著波动,与有机质等生物地球化学指标具有一致的垂向变化趋势,表明它们具有...     

A paleoclimate record for the past 250,000 years from Summer Lake, Oregon, USA. 1. chronology and magnetic proxies for lake level

This study presents the age control and environmental magnetism components of a new, late Pleistocene paleoclimate record for the Great Basin of western North America. Two new cores from the Summer Lake sub-basin of pluvial Lake Chewaucan, Oregon, USA are correlated to basin margin outcrops on the basis of tephrochronology, lithostratigraphy, sediment magnetism and paleomagnetic secular variation. Eleven tephra layers were found in the cores that correlate to tephra identified previously in the outcrop. The Olema ash was also found in one of the cores; its stratigraphic position, relative to 3 dated tephra layers, indicates that its age is 50-55 ka, somewhat younger than has been previously reported. The Summer Lake sediments are divided into deep and shallow lake lithosomes based on sedimentary features. The stratigraphic position of these lithosomes support the tephra-based correlations between the outcrop and the cores. These sediments contain a well resolved record of the Mono Lake Excursion (MLE) and an earlier paleomagnetic excursion as well as a high quality replication of the paleosecular variation immediately above the MLE.Relative sedimentation rates increased dramatically toward the depocenter during intervals of low-lake level. In contrast, during intervals of high-lake level, relative sedimentation rates were comparable along the basin axis from the basin margin to the depocenter. The magnetic mineralogy of the Summer Lake sediments is dominated by pseudo-single domain (titano)magnetite and intervals of high/low magnetite concentration coincide with lithosomes that indicate high/low lake levels. Magnetic grain size also varies in accord with bulk sediment grain size as indicated by the silt/clay ratio. To a first order, variations in magnetic parameters, especially those attributable to the concentration of magnetic minerals, correlate well with global glacial/interglacial oscillations as indicated by marine oxygen isotope stages. This relationship can be explained by increased dissolution of (titano)magnetite minerals as lake level dropped and the lake became more productive biologically. This inference is supported by a correspondence between lower concentrations of magnetite with higher levels of total organic carbon and vice-versa.     

Biological and Geochemical Record of Anthropogenic Impacts in Recent Sediments from Lake Pupuke, Auckland City, New Zealand

Frozen sediment cores from Lake Pupuke in Auckland City, New Zealand, contain a high resolution decadal to annual scale record of changing lake paleoenvironments and geochemistry that reflects changing landuse and hydrology in the catchment over the past c. 190 years. A reliable chronology is available from AMS ¹⁴C and ²¹⁰Pb dating of the sediments, with the timing of the older part of the record supported by the first appearance of pollen of introduced Pinus and Plantago lanceolata associated with European settlement of Auckland in the early 1840s. Diatom stratigraphy, sediment elemental and carbon isotope geochemistry reflect changes in sediment sources and lake conditions commensurate with European development of the Lake Pupuke catchment, in particular enhanced algal productivity controlled by the influx of nutrients after c. 1920 AD. Attempts to prevent nuisance algal blooms in 1933, 1934 and 1939 using CuSO₄ addition produced Cu spikes in the sediment that allowed confirmation of the accuracy of the ²¹⁰Pb chronology. Hence, the elemental and isotopic composition of the Lake Pupuke sediments reflect the timing of significant anthropogenic activities, rather than climatic variations, that have occurred within the watershed over the past c. 190 years. The comparison of records of land use change in the catchment with the multi-proxy record of changes in the sediments usually allowed unambiguous identification of the signatures of change and their causes.     

Late holocene paleoclimatic and paleobiologic records from sediments of Devils Lake,North Dakota

An 84 cm sediment core collected from the center of Devils Lake, North Dakota, was analyzed at 1-cm intervals for,²¹⁰Pb,¹³⁷Cs, sediment conductivity, the concentrations of, biogenic silica, total organic carbon, carbon to nitrogen ratio, and the carbon and nitrogen isotopic composition of the organic fraction. Variations in²¹⁰Pb activities in the upper 20 centimeters indicate that sediment accumulations rates in Devils Lake are not constant, and that accumulation rates were highest during periods of high lake level. The mean sedimentation accumulation rate was calculated as 0.24 cm^–1 yr. The¹³⁷Cs profile is characterized by near-surface maximum concentrations, possibly the result of redistribution of¹³⁷Cs during salinity excursions.Biogenic silica is strongly correlated to lake level in Devils Lake. Periods of low lake level (characterized by high sediment conductivity) correspond to low biogenic silica concentrations. The trends in biogenic silica are attributed to variations in diatom productivity in the lake and to variations in sediment accumulation rates. Based on biogenic silica content and the composition of organic matter in the sediment (total organic carbon, carbon:nitrogen ratio and the ¹³C and ¹⁵N composition of total organic matter), paleobiologic conditions of Devils Lake during low lake stands were characterized by, (1) decreased primary productivity, (2) decreased input of detrital organic matter, and (3) increased nitrogen availability.During the 350 years of sediment accumulation represented by the 84-cm sediment core Devils Lake has experienced two periods of sustained high lake level; one between about 130 and 170 years ago (1820 to 1860 A.D.) and the second between 270 and 310 years ago (1680 to 1720 A.D.). Devils Lake experienced a period of intense drying about 260 years ago (1720 A.D.).     

Palaeovariations in the East-Asian Monsoon Regime Geochemically Recorded in Varved Sediments of Lake Sihailongwan (Northeast China, Jilin Province). Part 1: Hydrological Conditions and Dust Flux

The varved sediments of the dimictic Lake Sihailongwan (Long Gang mountain area, Jilin Province, Northeast China) represent a palaeoclimatic archive which documents the local precipitation frequency during the summer monsoon, and variations in the aeolian flux of dust with their remote sources in the arid and semi-arid regions of inner Asia. Based on a detailed discussion of sediment genesis in Lake SHL, dust flux rates and palaeohydrological conditions were reconstructed on a decadal scale over the past 220 years. The aeolian influx by dry and wet deposition was quantified and characterised in its chemical composition. Photosynthetic production in the lake is positively correlated with the inflow of nutrient-rich groundwater. The groundwater discharge largely reflects the strength of the summer monsoon. Net accumulation rates for biogenic silica were determined for annually laminated sediments from the centre of the U-shaped lake basin based on sediment data. In a Si-balance model of the modern lake, the depositional flux of biogenic silica could be independently quantified on the base of hydrochemical monitoring data. Comparison of the both estimates allowed to asses the focussing of the particle flux in the lake. Though water retention in Lake SHL is rather high (ca. 30 years), changes in the hydrological conditions are sensitively recorded in the sediments because (i) nutrient-rich groundwater discharges into the productive zone of the lake, (ii) a substantial proportion of the total dissolved Si-inventory of the mixed lake (ca. 30%) is annually consumed by diatom growth, and (3) sediment accumulation is substantially focussed towards the flat bottom of the lake basin. The bulk siliciclastic sediment fraction (ca. 75 wt.%) largely originates from influx of dust of remote provenance. In sediment thin-sections, the dry-deposited dust fraction is microscopically identifiable as seasonal silt layer. Aeolian input by wet-deposition shows a distinctly higher variability than the influx of dust by dry-deposition. As diatom production, wet-deposition of dust is positively correlated with the rainfall during the summer monsoon. The inferred positive correlation between rainfall and dust flux during the summer monsoon implies that dust deposition is determined by the out-wash efficiency of mineral particles for a permanent high atmospheric dust concentration over Northeast China in the last 220 years.     

The late Holocene paleohydrology of Pine Lake, Alberta: a multiproxy investigation

This paper reports on a high-resolution, multi-proxy, late-Holocene study from a lake in the Aspen Parkland of southern Alberta, Canada. A sediment core spanning the last 4000+ yrs from Pine Lake was analyzed for charcoal, granulometry, grain roundness, tephra content, geochemistry, mineralogy and pollen. This multi-proxy record indicates: (1) increasing anoxia causing a shift in S deposition from gypsum to pyrite due to increasing moisture availability in the late Holocene; (2) a decrease in Mg flux into the lake due to the development of the aspen forest, which reduced water flow through the Mg-rich shallow sand aquifer; the aspen forest expansion was in turn induced by the extirpation of plains bison prior to settlement; and (3) a change in the upland fire regime from frequent low-biomass grass fires to less frequent but higher biomass under-story fires, also as a result of the expansion of the aspen forest. Not only are the different proxies sensitive to different rates and magnitudes of change, they also show different sensitivities to different types of hydrological change: the mineralogy and geochemistry are sensitive to changes in water level and redox potential, and to changes in the relative strengths of the aquifers feeding the lake, while the granulometry is sensitive to total hydrological balance. Thus, apparently contradictory proxy results should be viewed as complementary.     

Image analysis as a method to quantify sediment components

Varved lake sediments, with their annual to seasonal resolution, have a high potential for inferring past environmental and climatic conditions. To fully utilize the information present in varved records, high-resolution analyses, which often are time-consuming and difficult to perform, are desirable. The investigation reported here aims at (i) developing image analysis as a method for estimating annual accumulation rates of sediment components such as minerogenic matter, organic matter and biogenic silica, and (ii) assessing the relative importance of these components for changes in varve thickness. Image analysis was used to digitize the grey-scale variations and to measure the varve thickness of 540 varves (476-1015 AD) from Lake Kassjön in northern Sweden. From the 35 cm long digitized sediment sequence, 108 consecutive five-year samples were cut out quantitatively, and relationships between grey-scale variations and sediment dry mass and individual sediment components were assessed. There is a strong correlation between corrected grey-scale (i.e. the product of grey-scale and varve thickness) and the dry mass accumulation rate (r = 0.90, p < 0.001). With a stepwise multiple regression a significant model (R² = 0.81) between corrected grey-scale and the accumulation rates of minerogenic matter (r = 0.90, p < 0.001) and biogenic silica (r 0.26, p < 0.012) was obtained. Considering the minor contribution and weak significance of biogenic silica, image analysis can be used as a fast and non-destructive method to infer past annual accumulation rates of dry mass and minerogenic matter in Kassibn. The model of the relationship between changes in varve thickness, and water content and accumulation rates of sediment components has little predictive power (R² = 0.45). The result shows that the varve thickness in Kassjön, at least during the period 476-1015 AD, is not determined by a single sediment component but partly depends on interactions between the major sediment components.     

北极新奥尔松地区湖泊沉积物色素含量变化及环境意义

大量的古气候资料和现代器测数据表明,最近100年来北极气候经历了明显的变暖过程,这必然会对脆弱的极地湖泊生态系统产生影响。以北极新奥尔松地区的湖泊沉积柱样为研究对象,对其中4种色素(叶绿素及其衍生物CD、总胡萝卜素TC、蓝藻叶黄素Myx和颤藻黄素Osc)进行了分析,结合其他物化指标如碳酸钙含量、TOC等,从历史演化的角度重点探讨了新奥尔松地区最近100年以来湖泊初级生产力演化过程。结果表明,在相对寒冷的小冰期,气候对湖泊中藻类的生长不利,湖泊生产力下降,沉积物中色素含量出现低值,生物硅含量降低;表层5cm(对应约1890AD)沉积物中有机质含量显著升高,各色素含量均明显增加,表明小冰期后气温上升,导致湖泊藻类生长迅速,湖泊生产力大大提高,但此时生物硅仍保持在相对较低的水平,这可能与其他藻类的竞争生长有关。最近100年,沉积物中Osc/Myx比值不断降低,表明该湖泊中蓝藻含量不断上升,暗示北极地区人类活动的增强可能导致湖泊营养水平增加。     

Compositional changes in sediments of subalpine lakes,Uinta Mountains (Utah): evidence for the effects of human activity on atmospheric dust inputs

Sediments in Marshall and Hidden Lakes in the Uinta Mountains of northeastern Utah contain records of atmospheric mineral-dust deposition as revealed by differences in mineralogy and geochemistry of lake sediments relative to Precambrian clastic rocks in the watersheds. In cores spanning more than a thousand years, the largest changes in composition occurred within the past approximately 140 years. Many elements associated with ore deposits (Ag, As, Bi, Cd, Cu, In, Mo, Pb, S, Sb, Sn, and Te) increase in the lake sediments above depths that correspond to about AD 1870. Sources of these metals from mining districts to the west of the Uinta Mountains are suggested by (1) the absence of mining and smelting of these metals in the Uinta Mountains, and (2) lower concentrations of most of these elements in post-settlement sediments of Hidden Lake than in those of Marshall Lake, which is closer to areas of mining and the densely urbanized part of north-central Utah that is termed the Wasatch Front, and (3) correspondence of Pb isotopic compositions in the sediments with isotopic composition of ores likely to have been smelted in the Wasatch Front. A major source of Cu in lake sediments may have been the Bingham Canyon open-pit mine 110 km west of Marshall Lake. Numerous other sources of metals beyond the Wasatch Front are likely, on the basis of the widespread increases of industrial activities in western United States since about AD 1900. In sediment deposited since ca. AD 1945, as estimated using ^239+240Pu activities, increases in concentrations of Mn, Fe, S, and some other redox-sensitive metals may result partly from diagenesis related to changes in redox. However, our results indicate that these elemental increases are also related to atmospheric inputs on the basis of their large increases that are nearly coincident with abrupt increases in silt-sized, titanium-bearing detrital magnetite. Such magnetite is interpreted as a component of atmospheric dust, because it is absent in catchment bedrock. Enrichment of P in sediments deposited after ca. AD 1950 appears to be caused largely by atmospheric inputs, perhaps from agricultural fertilizer along with magnetite-bearing soil.     

The response of sedimentation in three varved lacustrine sequences to air temperature,precipitation and human impact

Human activity and climatic forcing have influenced sedimentation in three of Finland's deepest lakes during the last centuries. High-resolution sediment sequences of Lake Päijänne, Lake Pääjärvi and Lake Pyhäjärvi represent records of the last 440 years, 839 years and 633 years, respectively. The accumulation rates of dry matter, organic carbon and biogenic silica refer to changes in human activity in the catchments. However, they also reveal the importance of climatic forcing on lake sediment deposition. A significant correlation was found between instrumentally measured records of temperature (163 years) and precipitation (148 years), and varve thickness. Warm winter months indicating a short ice-cover period have the strongest control on varve thickness. This shows that wind-driven resuspension of littoral material is the forcing mechanism of climate on lake sediments. The long-term human-induced erosion pulses observed may even have magnified the climatic signals in some cases. Nevertheless, increased anthropogenic field erosion in the catchment, and the associated leaching of bioavailable nutrients, hampers the observation of climate signals, especially during the last 50 years, in the lakes studied.This is the second paper a series of papers published in this issue on high-resolution paleolimnology. These papers were presented at the Sixth International Palaeolimnology Symposium held 19-April, 1993 at the Australian National University, Canberra, Australia. Dr A. F. Lotter and Dr. M. Sturm served as guest editors for these papers.     

Response of a Lake Michigan coastal lake to anthropogenic catchment disturbance

A paleolimnological investigation of post-European sediments in a Lake Michigan coastal lake was used to examine the response of Lower Herring Lake to anthropogenic impacts and its role as a processor of watershed inputs. We also compare the timing of this response with that of Lake Michigan to examine the role of marginal lakes as early warning indicators of potential changes in the larger connected system and their role in buffering Lake Michigan against anthropogenic changes through biotic interactions and material trapping. Sediment geochemistry, siliceous microfossils and nutrient-related morphological changes in diatoms, identified three major trophic periods in the recent history of the lake. During deforestation and early settlement (pre-1845–1920), lake response to catchment disturbances results in localized increases in diatom abundances with minor changes in existing communities. In this early phase of disturbance, Lower Herring Lake acts as a sediment sink and a biological processor of nutrient inputs. During low-lake levels of the 1930s, the lake goes through a transitional period characterized by increased primary productivity and a major shift in diatom communities. Post-World War II (late 1940s–1989) anthropogenic disturbances push Lower Herring Lake to a new state and a permanent change in diatom community structure dominated by Cyclotella comensis. The dominance of planktonic summer diatom species associated with the deep chlorophyll maximum (DCM) is attributed to epilimnetic nutrient depletion. Declining Si:P ratios are inferred from increased sediment storage of biogenic silica and morphological changes in the silica content of Aulacoseira ambigua and Stephanodiscus niagarae. Beginning in the late 1940s, Lower Herring Lake functions as a biogeochemical processor of catchment inputs and a carbon, nutrient and silica sink. Microfossil response to increased nutrients and increased storage of biogenic silica in Lower Herring Lake and other regional embayments occur approximately 20–25 years earlier than in a nearby Lake Michigan site. Results from this study provide evidence for the role of marginal lakes and bays as nutrient buffering systems, delaying the impact of anthropogenic activities on the larger Lake Michigan system.     

Biogeochemistry of silica in Devils Lake: implications for diatom preservation

Diatom-salinity records from sediment cores have been used to construct climate records of saline-lake basins. In many cases, this has been done without thorough understanding of the preservation potential of the diatoms in the sediments through time. The purpose of this study was to determine the biogeochemistry of silica in Devils Lake and evaluate the potential effects of silica cycling on diatom preservation. During the period of record, 1867–1999, lake levels have fluctuated from 427 m above sea level in 1940 to 441.1 m above sea level in 1999. The biogeochemistry of silica in Devils Lake is dominated by internal cycling. During the early 1990s when lake levels were relatively high, about 94% of the biogenic silica (BSi) produced in Devils Lake was recycled in the water column before burial. About 42% of the BSi that was incorporated in bottom sediments was dissolved and diffused back into the lake, and the remaining 58% was buried. Therefore, the BSi accumulation rate was about 3% of the BSi assimilation rate. Generally, the results obtained from this study are similar to those obtained from studies of the biogeochemistry of silica in large oligotrophic lakes and the open ocean where most of the BSi produced is recycled in surface water. During the mid 1960s when lake levels were relatively low, BSi assimilation and water-column dissolution rates were much higher than when lake levels were high. The BSi assimilation rate was as much as three times higher during low lake levels. Even with the much higher BSi assimilation rate, the BSi accumulation rate was about three times lower because the BSi water-column dissolution rate was more than 99% of the BSi assimilation rate compared to 94% during high lake levels. Variations in the biogeochemistry of silica with lake level have important implications for paleolimnologic studies. Increased BSi water-column dissolution during decreasing lake levels may alter the diatom-salinity record by selectively removing the less resistant diatoms. Also, BSi accumulation may be proportional to the amount of silica input from tributary sources. Therefore, BSi accumulation chronologies from sediment cores may be effective records of tributary inflow.     

海鸟活动在东南极中山站区莫愁湖沉积物中的记录

本文对采自东南极拉斯曼丘陵中山站区的莫愁湖沉积物的元素、氨基酸和Sr同位素组成进行了详细的地球化学分析。结果表明莫愁湖沉积物中Zn、Cu、F、S、P、Se等六种元素具有共同的物质来源,其标型组合特征很可能揭示了莫愁湖沉积物在历史时期曾受到过企鹅等海鸟粪的影响,沉积物中酸溶相Sr同位素组成则确认了海洋源Sr的生物地球化学转移过程。酸溶相87Sr/86Sr值和研究区的新鲜海鸟粪酸溶相Sr同位素组成基本一致,都非常接近于海洋来源锶同位素组成(87Sr/86Sr=0.7092),并且沉积物中的生物元素Zn、Cu、F、S、P、Se含量和酸溶相Sr浓度具有非常高的统计相关性。酸溶相的87Sr/86Sr比值和反映湖泊中藻类等生物自然生成量的氨基酸含量表现出明显的负相关关系,进一步揭示了莫愁湖沉积物在历史时期曾受到企鹅等海鸟活动的影响。上述研究结果为更深入地研究该地区的生态、气候和环境的演变历史及其相互作用提供了有价值的参考资料。     

Record of Late Pleistocene Glaciation and Deglaciation in the Southern Cascade Range. I. Petrological Evidence from Lacustrine Sediment in Upper Klamath Lake, Southern Oregon

Petrological and textural properties of lacustrine sediments from Upper Klamath Lake, Oregon, reflect changing input volumes of glacial flour and thus reveal a detailed glacial history for the southern Cascade Range between about 37 and 15 ka. Magnetic properties vary as a result of mixing different amounts of the highly magnetic, glacially generated detritus with less magnetic, more weathered detritus derived from unglaciated parts of the large catchment. Evidence that the magnetic properties record glacial flour input is based mainly on the strong correlation between bulk sediment particle size and parameters that measure the magnetite content and magnetic mineral freshness. High magnetization corresponds to relatively fine particle size and lower magnetization to coarser particle size. This relation is not found in the Buck Lake core in a nearby, unglaciated catchment. Angular silt-sized volcanic rock fragments containing unaltered magnetite dominate the magnetic fraction in the late Pleistocene sediments but are absent in younger, low magnetization sediments. The finer grained, highly magnetic sediments contain high proportions of planktic diatoms indicative of cold, oligotrophic limnic conditions. Sediment with lower magnetite content contains populations of diatoms indicative of warmer, eutrophic limnic conditions. During the latter part of oxygen isotope stage 3 (about 37–25 ka), the magnetic properties record millennial-scale variations in glacial-flour content. The input of glacial flour was uniformly high during the Last Glacial Maximum, between about 21 and 16 ka. At about 16 ka, magnetite input, both absolute and relative to hematite, decreased abruptly, reflecting a rapid decline in glacially derived detritus. The decrease in magnetite transport into the lake preceded declines in pollen from both grass and sagebrush. A more gradual decrease in heavy mineral content over this interval records sediment starvation with the growth of marshes at the margins of the lake and dilution of detrital material by biogenic silica and other organic matter.     

Estimation of carbonate, total organic carbon, and biogenic silica content by FTIR and XRF techniques in lacustrine sediments

Major components of lacustrine sediments, such as carbonates, organic matter, and biogenic silica, provide significant paleoenvironmental information about lake systems. Fourier transform infrared spectroscopy (FTIR) and scanning X-ray fluorescence (XRF) techniques are fast, cost effective, efficient methods to determine the relative abundances of these components. We investigate the potential of these techniques using sediments from two large lakes, Lake Malawi in Africa and Lake Qinghai in China. Our results show statistically significant correlations of conventionally measured concentrations of carbonate (%CaCO₃), total organic carbon (%TOC), and biogenic silica (%BSi), with absorbance in the corresponding FTIR spectral regions and with XRF elemental ratios including calcium:titanium (Ca/Ti), incoherent:coherent X-ray scatter intensities (Inc/Coh), and silicon:titanium (Si/Ti), respectively. The correlation coefficients (R) range from 0.66 to 0.96 for comparisons of FTIR results and conventional measurements, and from 0.70 to 0.90 for XRF results and conventional measurements. Both FTIR and XRF techniques exhibit great potential for rapid assessment of inorganic and organic contents of lacustrine sediments. However, the relationship between XRF-ratios or FTIR-absorbances and abundances of corresponding sedimentary components can vary with sediment source and lithology.     

Paleolimnology and Paleoclimate Studies in Upper Klamath Lake, Oregon

The subsiding Upper Klamath Lake Basin contains sediments that were continuously deposited in a shallow, freshwater lake for more than 40 000 years. Well dated by radiometric methods and containing volcanic ashes of known age, these sediments constitute a valuable paleoclimate record. Sediment constituents and properties that reflect past climatic conditions in the area include pollen, diatoms, sediment geochemistry, and sediment magnetic properties. Many of these proxy measurements are also useful for comparing natural conditions in the lake to conditions following human settlement. Because of its location, the paleoclimate record from Upper Klamath Lake is valuable for comparisons to offshore marine records and as part of latitudinal transects of paleoclimate records along the west coast of the Americas.     

Mid-late Holocene anthropogenic and natural variations in geochemistry and sedimentation in the Yazoo Basin: Clark Lake,Sharkey County,Mississippi

A 4000-yr history at Clark Lake reveals natural variations in sediment geochemistry and nutrient levels and anthropogenic influence on twentieth century sedimentation rates. Sediment texture and ridge and swale topography indicate that the channel system creating Clark Lake is now occupied by the Yazoo River. Between 1.24 and 0.60 m (2522–865 cal yr BP), total carbon percentages and the C/N ratio average 42% and 17, respectively. The base of the 1650-yr interval and onset of high organic activity in the lake coincides with the abandonment of the Yazoo Meander Belt. The top of the interval is marked by a drop in C/N ratio to 11 and a geochemical transition zone. No change in the rate of sediment accumulation or clay mineralogy was observed despite increased cumulative percentages of Al, Fe, K, Mg, Mn, Ca, and Na. The decrease in organic activity at 865 cal yr BP is attributed to unfavorable growth conditions related to the entrenchment of the Yazoo River and changes in the hydroperiod of the area. Significant floodplain alteration was completed in 1978, but the only major effect was increased sedimentation in the late twentieth century due to the completion of the Whittington Auxiliary Channel.