Nd-isotope systematics of ∼2.7 Ga adakites, magnesian andesites, and arc basalts, Superior Province: evidence for shallow crustal recycling at Archean subduction zones

An association of adakite, magnesian andesite (MA), and Nb-enriched basalt (NEB) volcanic flows, which erupted within ‘normal’ intra-oceanic arc tholeiitic to calc-alkaline basalts, has recently been documented in ∼2.7 Ga Wawa greenstone belts. Large, positive initial ?_Nd values (+1.95 to +2.45) of the adakites signify that their basaltic precursors, with a short crustal residence, were derived from a long-term depleted mantle source. It is likely that the adakites represent the melts of subducted late Archean oceanic crust. Initial ?_Nd values in the MA (+0.14 to +1.68), Nb-enriched basalts and andesites (NEBA) (+1.11 to +2.05), and ‘normal’ intra-oceanic arc tholeiitic to calc-alkaline basalts and andesites (+1.44 to +2.44) overlap with, but extend to lower values than, the adakites. Large, tightly clustered ?_Nd values of the adakites, together with Th/Ce and Ce/Yb systematics of the arc basalts that rule out sediment melting, place the enriched source in the sub-arc mantle. Accordingly, isotopic data for the MA, NEBA, and ‘normal’ arc basalts can be explained by melting of an isotopically heterogeneous sub-arc mantle that had been variably enriched by recycling of continental material into the shallow mantle in late Archean subduction zones up to 200 Ma prior to the 2.7 Ga arc. If the late Archean Wawa adakites, MA, and basalts were generated by similar geodynamic processes as their counterparts in Cenozoic arcs, involving subduction of young and/or hot ocean lithosphere, then it is likely that late Archean oceanic crust, and arc crust, were also created and destroyed by modern plate tectonic-like geodynamic processes. This study suggests that crustal recycling through subduction zone processes played an important role for the generation of heterogeneity in the Archean upper mantle. In addition, the results of this study indicate that the Nd-isotope compositions of Archean arc- and plume-derived volcanic rocks are not very distinct, whereas Phanerozoic plumes and intra-oceanic arcs tend to have different Nd-isotopic compositions.     

The deep layers of a Paleozoic arc: geochemistry of the Copley-Balaklala series, northern California

REE, Zr, Nb concentrations and Sr, Nd isotope compositions have been measured in Copley basalts and andesites, Balaklala rhyolites, and Mule Mountain trondhjemites (northern California) which represent the deep layers of a well preserved intra-oceanic island arc of Siluro-Devonian age.⁸⁷Sr/⁸⁶Sr is shifted towards high values (up to 0.707) whereas Ce is preferentially removed from rhyolites. A large proportion of the analyzed samples including some acidic rocks shows a pronounced depletion in light REE. The ε_Nd(T) values of most Copley, Balaklala, and Mule Mountain rocks fall in the range +6 to +8 which suggests that they originated from a normal MORB-type source (ε_Nd(T) ≈ +9) contaminated with either sediments or an OIB-type component.In modern island arcs, only the shallow levels are accessible: comparison with the Copley-Balaklala-Mule Mountain Series suggests that, at depth, an immature island arc is likely to comprise thick layers of LILE-depleted tholeiites and rhyolites intensely altered by pervasive circulation of seawater. Least-square solutions of trace element models suggest that rhyolites and trondhjemites represent remelting of mafic volcanics from the arc basement rather than residual melts of basalt-andesite differentiation.     

Geochemical variation with time in the Cenezoic volcanic rocks of southwest Hokkaido, Japan

Abundances of major and trace elements were determined for the Tertiary volcanic rocks from SW Hokkaido. The Late Miocene to Pliocene volcanic rocks of this region show geochemical features similar to those of the Quaternary rocks, that is, K/Si, Th/Si and LREE/HREE ratios increasing across the arc, east to west, from the Pacific to the Japan Sea side. In contrast, the Early Miocene volcanic rocks, which are geographically restricted to the Japan Sea coast, are distinct from all later volcanics and show “within-plate” characteristics — in particular, high concentrations of HFS elements. The Quaternary basalts have low Hf/Yb ratios and Hf contents, whereas the Early Miocene basalts are high in Hf/Yb and Hf, similar to Hawaiian alkali basalts. The compositional variation with time may result from the progressive depletion of incompatible HFS elements in the mantle source. Th/Yb ratios increase from Early Miocene to Quaternary, possibly reflecting increase in the LIL element contribution to the mantle source during that time.     

Geochemistry of the Early Miocene volcanic succession of Northland,New Zealand,and implications for the evolution of subduction in the Southwest Pacific

Latest Oligocene and Early Miocene volcanic rocks occur on the Northland Peninsula, New Zealand, and record the inception of Cenozoic subduction-related volcanism in the North Island that eventually evolved to its present manifestation in the Taupo Volcanic Zone. This NW-striking Northland Arc is continuous with the Reinga Ridge and comprises two parallel belts of volcanic centres ca. 60 km apart. A plethora of tectonic models have been proposed for its origins. We acquired new trace element and Sr–Nd isotope data to better constrain such models. All Northland Arc rocks carry an arc-type trace element signature, however distinct differences exist between rocks of the eastern and western belt. Eastern belt rocks are typically andesites and dacites and have relatively evolved isotope ratios indicating assimilated crustal material, and commonly contain hornblende. Additionally some eastern belt rocks with highly evolved isotope compositions show fractionated REE compositions consistent with residual garnet, and some contain garnetiferous inclusions in addition to schistose crustal fragments. In contrast, western belt rocks are mostly basalts or basaltic andesites with relatively primitive Sr–Nd isotope compositions, do not contain hornblende and show no rare earth element evidence for cryptic amphibole fractionation. Eastern and western belt rocks contain comparable slab-derived fractions of fluid-mobile trace elements and invariably possess an arc signature. Therefore the difference between the belts may be best explained as due to variation in crustal thickness across the Northland Peninsula, where western belt centres erupted onto a thinner crustal section than eastern belt rocks.The consistent arc signature throughout the Northland arc favours an origin in response to an actual, if short-lived subduction event, rather than slab detachment as proposed in some models. No Northland Arc rocks possess a convincing adakite-like composition that might reflect the subduction of very young oceanic lithosphere such as that of the Oligocene South Fiji Basin. Therefore we favour a model in which subduction of old (Cretaceous) lithosphere drove subduction.     

143Nd/144Nd,87Sr/86Sr and trace element constraints on the petrogenesis of Aleutian island arc magmas

¹⁴³Nd/¹⁴⁴Nd,⁸⁷Sr/⁸⁶Sr and trace element results are reported for volcanic and plutonic rocks of the Aleutian island arc. The Nd and Sr isotopic compositions plot within the mantle array with ε_Nd values of from 6.5 to 9.1 and⁸⁷Sr/⁸⁶Sr ratios of from 0.70289 to 0.70342. Basalts have mildly enriched light REE abundances but essentially unfractionated heavy REE abundances, while andesites exhibit a greater degree of light to heavy REE fractionation. Both the basalts and andesites have significant large ion lithophile element to light rare earth element (LILE/LREE) enrichments. Variations in the isotopic compositions of Nd and Sr are not related to the spatial distribution of volcanoes in the arc, nor are they related to temporal differences. ε_Nd and⁸⁷Sr/⁸⁶Sr do not correlate with major element compositions but do, however, correlate with certain LILE/LREE ratios (e.g. Ba_N/La_N). Plutonic rocks have isotropic and trace element characteristics identical to some of the volcanic rocks. Rocks that make up the tholeiitic, calc-alkaline and alkaline series in the Aleutians do not come from isotopically distinct sources, but do exhibit some differing LILE characteristics.Given these elemental and isotopic constraints it is shown that the Aleutian arc magmas could not have been derived directly from homogeneous MORB-type mantle, or fresh or altered MORB subducted beneath the arc. Mixtures of partially altered MORB with deep-sea sediment can in principle account for the isotopic characteristics and most of the observed LILE/LREE enrichments. However, some samples have exceedingly high LILE/LREE enrichments which cannot be accounted for by sediment contamination alone. For these samples a more complex scenario is considered whereby dehydration and partial melting of the subducted slab, containing less than 8% sediment, produces a LILE-enriched (relative to REE) metasomatic fluid which interacts with the overlying depleted mantle wedge. The isotopic and LILE characteristics of the mantle are extremely sensitive to metasomatism by small percentages of added fluid, whereas major elements are not substantially effected, Major element compositions of Aleutian magmas are dominantly controlled by the partial melting of this mantle and subsequent crystal fractionation; whereas isotopic and LILE characteristics are determined by localized mantle heterogeneities.     

Provenance of sandstones from the Wakino Subgroup of the Lower Cretaceous Kanmon Group, northern Kyushu, Japan

Abstract The Wakino Subgroup is a lower stratigraphic unit of the Lower Cretaceous Kanmon Group. Previous studies on provenance of Wakino sediments have mainly concentrated on either petrography of major framework grains or bulk rock geochemistry of shales. This study addresses the provenance of the Wakino sandstones by integrating the petrographic, bulk rock geochemistry, and mineral chemistry approaches. The proportions of framework grains of the Wakino sandstones suggest derivation from either a single geologically heterogeneous source terrane or multiple source areas. Major source lithologies are granitic rocks and high‐grade metamorphic rocks but notable amounts of detritus were also derived from felsic, intermediate and mafic volcanic rocks, older sedimentary rocks, and ophiolitic rocks. The heavy mineral assemblage include, in order of decreasing abundance: opaque minerals (ilmenite and magnetite with minor rutile), zircon, garnet, chromian spinel, aluminum silicate mineral (probably andalusite), rutile, epidote, tourmaline and pyroxene. Zircon morphology suggests its derivation from granitic rocks. Chemistry of chromian spinel indicates that the chromian spinel grains were derived from the ultramafic cumulate member of an ophiolite suite. Garnet and ilmenite chemistry suggests their derivation from metamorphic rocks of the epidote‐amphibolite to upper amphibolite facies though other source rocks cannot be discounted entirely. Major and trace element data for the Wakino sediments suggest their derivation from igneous and/or metamorphic rocks of felsic composition. The major element compositions suggest that the type of tectonic environment was of an active continental margin. The trace element data indicate that the sediments were derived from crustal rocks with a minor contribution from mantle‐derived rocks. The trace element data further suggest that recycled sedimentary rocks are not major contributors of detritus. It appears that the granitic and metamorphic rocks of the Precambrian Ryongnam Massif in South Korea were the major contributors of detritus to the Wakino basin. A minor but significant amount of detritus was derived from the basement rocks of the Akiyoshi and Sangun Terrane. The chromian spinel appears to have been derived from a missing terrane though the ultramafic rocks in the Ogcheon Belt cannot be discounted.     

Kema terrane: A fragment of a back-arc basin of the early Cretaceous Moneron–Samarga island-arc system, East Sikhote–Alin range, Russian Far East

Abstract The Kema terrane is a suite of Barremian(?)–Aptian to Albian volcano-sedimentary rocks of Sikhote–Alin that are interpreted as deposits of the back-arc basin of the Moneron–Samarga island-arc system. Compositional features of the different-type deposits indicate a near-slope depositional environment influenced by volcanic processes. Studies of slump fold orientation testify to the accumulation of material from southeast to northwest by gravitational sliding. Compositional characteristics of terrigenous rocks suggest the major provenance for detrital material was an ensialic volcanic island arc. Petrochemical characteristics of basaltic rocks indicate that the formations studied were confined to the back part of the arc.     

Across-arc geochemical variation of Quaternary lavas in West Java, Indonesia: Mass-balance elucidation using arc basalt simulator model

The Sunda Arc of Indonesia developed along the convergent margin between the Eurasian and the Australian Plates. More than 100 Quaternary volcanic centers occur along the arc. The West Java Arc is a segment of the Sunda Arc in which more than 10 volcanic centers are located, corresponding to the 120 to 200 km depth contours of the Wadati–Benioff zone. The geochemistry of 207 Quaternary lavas from six centers across the arc was investigated. The lavas range from basalt to dacite. Incompatible element abundances increase from the volcanic front to the rear‐arc in response to a change from low‐K to high‐K suites. Nd–Sr isotope compositions of the basalts scatter between mid‐ocean ridge basalt (MORB) source mantle and Indian Ocean sediment (SED) compositions, with volcanic front low‐K basalts having more radiogenic Nd than the rear‐arc basalts. It is suggested that mixing between slab‐derived fluids mainly from the SED and melt from MORB source mantle played a significant role in determining the geochemistry of the West Java basalts. Incompatible element patterns in primitive mantle normalized multi‐element plots are almost identical across the arc, except for greater inclination and weaker positive Sr spikes in the rear‐arc basalts. This suggests a lower degree of partial melting in the rear‐arc mantle, accompanied by change in SED fluid composition between the volcanic front and the rear‐arc. The latter is confirmed by fluid‐fluxed melting model calculations using multiple trace elements and Nd and Sr isotopes. All the West Java Arc lavas require deficit of Sr from the slab SED. This may occur due to selective breakdown of Sr‐rich hydrous silicate minerals, such as zoisite, at shallower depths before the SED component reaches the depth of dehydration effective for magma genesis. The rear‐arc basalts need further Sr deficits along with lesser fluid. These features are commonly observed in many arc basalts, and are likely attributable to the same mechanism.     

The geology, petrology, and petrogenesis of Saba Island, Lesser Antilles

Saba is the northernmost volcano along the Lesser Antilles island-arc chain. The Lesser Antilles arc results from the west-northwest subduction of the Atlantic lithosphere beneath the Caribbean Plate. Sediment thickness along the trench decreases northward away from sediment sources on the continent of South America. We focused our attention on Saba precisely because it is the furthest away from documented geochemical effects in the southern arc volcanics of the large sediment thicknesses — normally attributed to both source or upper level contamination (i.e. assimilation).Field mapping, petrology, mineralogy, K–Ar dating, and geochemical analyses (major and trace element) indicate a complex history of magma petrogenesis including crystal fractionation, magma mixing, and, surprisingly, crustal assimilation. This is the first time assimilation has been documented in the northern section of the Lesser Antilles arc. Magma mixing shows up in the field as banded pumice and petrographically and mineralogically as complex zoning in phenocrysts (such as reverse zoning in plagioclase), disequilibrium mineral assemblages (e.g. quartz and olivine), and disequilibrium between minerals and whole-rock compositions (e.g. forsterite content of olivine). Mass-balance modeling of major and trace elements support our contention that crystal fractionation (including amphibole) played an important role in magma evolution. However, various geochemical trends can only be explained by assimilation-fractional crystallization based on the fact that the trends of various trace elements and trace-element ratios vary with increasing silica. Finally, we could find no evidence of sediment source contamination in the most mafic rocks. It may exist but is overprinted by the later assimilation effects.     

Geochemistry of some volcanic rocks from south-eastern sicily: Rare earth and other trace element distribution

Some trace element data for volcanic rocks found at different levels, from Tertiary to Holocene, in south-eastern Sicily (Iblean Plateau and Mt. Etna) are presented and discussed in the present paper in order to better the information about the origin and relationships of the various rock types. Four groups of volcanic rocks have been recognized on the basis of their major element chemistry: 1) low-K tholeiites, 2) associated alkali basalts to nephelinites of the Iblean Plateau (Upper Pliocene to Lower Pleistocene), 3) the basal subalkaline lavas of Mt. Etna, and 4) the alkalic suite rocks that make up the bulk of the volcano. The distribution of Rb, Sr, Ni, Cr, Co, Cu, REE, Th and Sc suggests:

1. an origin of the Iblean magmas by a different degree of partial melting of a Rb-poor and possibly slightly hetereogeneous mantle;
2. quite distinct source compositions for the Etnean magmas, relative to those of the Iblean area, on the basis of their Rb and Sr contents;
3. an origin of the alkalic rocks of Mt. Etna from independently generated magma(s) rather than by crystal fractionation of the Etnean subalkaline magmas or of a magma having the geochemical features of the Iblean alkali basalts; evidence for this is given by the distribution features of the incompatible elements showing an origin for these rocks from compositionally different parent magmas and/or an evolution under widely variable environmental conditions;
4. the primary character for the chemical differences observed in some of the Etnean subalkaline rocks that can be accounted for by different physico-chemical conditions at their source rather than by crystal fractionation processes.

     

Geochemical and petrological relations in some deccan basalts, Western Maharashtra, India

Petrographic and geochemical data are given for some basaltic rocks from the Koynaghat, Ambaghat and Panvel sections of the western Deccan volcanic province. This study confirms geochemical features established earlier for the Deccan basalts but brings out minor additional characters. Mineralogical and major-element compositions of the basaltic flows from the Koyna and Panvel sections indicate tholeiitic affinity; the Ambaghat flows exhibit a slight affinity towards alkali basalt. Rare earth element (REE) distribution patterns and trace-element abundances suggest minor fractionation of olivine and plagioclase during the evolution of the flows. The general similarity of chemical and mineralogical features over a wide area and the lack of conspicuous inter-element relationships suggest that the flows reflect the combined effects of partial melting, minor mineral fractionation and selective crustal contamination.     

Geochemistry and geochronology of Late Triassic volcanic rocks in the Chiang Khong region, northern Thailand

The Chiang Khong segment of the Chiang Khong–Lampang–Tak Volcanic Belt is composed of three broadly meridional sub‐belts of mafic to felsic volcanic, volcaniclastic, and associated intrusive rocks. Associated sedimentary rocks are largely non‐marine red beds and conglomerates. Three representative Chiang Khong lavas have Late Triassic (223–220 Ma) laser ablation inductively coupled mass‐spectroscopy U–Pb zircon ages. Felsic‐dominated sequences in the Chiang Khong Western and Central Sub‐belts are high‐K calc–alkaline rocks that range from basaltic to dominant felsic lavas with rare mafic dykes. The Western Sub‐belt lavas have slightly lower high field strength element contents at all fractionation levels than equivalent rocks from the Central Sub‐belt. In contrast, the Eastern Sub‐belt is dominated by mafic lavas and dykes with compositions transitional between E‐mid‐oceanic ridge basalt and back‐arc basin basalts. The Eastern Sub‐belt rocks have higher FeO* and TiO₂ and less light rare earth element enrichment than basalts in the high‐K sequences. Basaltic and doleritic dykes in the Western and Central sub‐belts match the composition of the Eastern Sub‐belt lavas and dykes. A recent geochemical study of the Chiang Khong rocks concluded that they were erupted in a continental margin volcanic arc setting. However, based on the dominance of felsic lavas and the mainly non‐marine associated sediments, we propose an alternative origin, in a post‐collisional extensional setting. A major late Middle to early Late Triassic collisional orogenic event is well documented in northern Thailand and Yunnan. We believe that the paucity of radiometric dates for arc‐like lavas in the Chiang Khong–Lampang–Tak Volcanic Belt that precede this orogenic event, coupled with the geochemistry of the Chiang Khong rocks, and strong compositional analogies with other post‐collisional magmatic suites, are features that are more typical of volcanic belts formed in a rapidly evolving post‐collisional, basin‐and range‐type extensional setting.     

Geochemistry of the subduction-related magmatic rocks in the Dahong Mountains, northern Hubei Province--Constraint on the existence and subduction of the eastern Mianlüe oceanic basin

The existence and subduction of the eastern Mianlue oceanic basin in the south Qinling belt are keys to understand the Qinling orogen. Based on geological mapping, several volcanic slices have been identified in Tumen, Zhoujiawan, Xiaofu and Yuantan areas, which distribute in the northern margin of the Dahong Mountains (DHM), and thrust into the Sanligang-Sanyang fault. These slices consist mainly of diabases, basaltic-andesitic lavas, pyroclastic rocks and a minor tuff. The geochemistry of the basalts, andesites, and diabases is characterized by depleting in Nb and Ta, enriching in Th and LILE (e.g.K, Rb, Ba), and undifferentiating in HFSE. These geochemical characteristics suggest that the original magma of these rocks was derived from a mantle wedge above a subduction zone, and formed in an island-arc setting in Carboniferous-early Triassic. Comparing with the ophiolites and island-arc volcanic rocks in Mianxian-Lueyang area to the west, it is reasonable to consider that there had been an oceanic basin connecting with the Mianlue ancient ocean to the westward, distributing along the south edge of the Tongbai-Dabie block. In view of the ophiolite in Huashan area and these island-arc volcanic rocks along the north of the Dahong Mountains, it is suggested that there had been a plate tectonic evolutionary history with oceanic basin rifting and subduction in this region.     

Trace element geochemistry of some continental tholeiites

Continental tholeiites from four regions (Late Cretaceous to Early Eocene Deccan Trap lavas of central India, Early Mesozoic tholeiites from the Atlantic margins of Northwest Africa-Morocco, and northeastern North America-Nova Scotia, Canada and Precambrian Coppermine River basalts from Northwest Territories, Canada) differ from MORB by higher concentrations of K, Rb, Ba and Th and to a lesser degree light REE. Their chondrite-normalized trace element patterns show negative Nb anomalies. The distribution and variation of trace elements indicate that the rocks from all the areas studied were affected by interaction with the continental crust. It is suggested that continental tholeiites have been generated from a similar source as oceanic tholeiites and many of their geochemical differences are related to crustal contamination.     

Geochemistry of the E-MORB type ophiolite and related volcanic rocks from the Wushan area,West Qinling

The mafic-ultramafic assemblages, which thrustthrust into the Wushan-Tangzang boundary fault as some blocks and outcropped in the Yuanyangzhen, Lijiahe, Lubangou and Gaojiahe area, consist mainly of meta-peridotites, gabbros and basalts. The meta-peridotites are characterized by high SiO₂ and MgO contents, low ΣREE, as well as their chondrite-normalized rare earth element patterns show some similarities to that of middle oceanic meta-peridotite. The basalts from the Yuanyangzhen, Lijiahe and Lubangou area are characterized by relatively high TiO₂ content, low Al₂O₃ content and Na₂O>>K₂O. Above all, it is the slight enrichment or flat REE distribution patterns and the unfractionated in HFS elements in the primitive-normalized trace elements distribution patterns that indicate these basalts are similar to that of the typical E-MORB. In comparison, the basalts from the Gaojiahe section are featured by depletion in Nb and Ta contents and enrichment in Th content which show that these were derived from an island-arc setting. From studies of the regional geology, petrology, geochemistry, geo-chronology and all above evidence, it can be suggested that the mafic-ultramafic rocks from the Wushan area are mainly dismembered E-MORB type ophiolite, which represent the fragments of the lithosphere of the Early-Paleozoic Qinling ocean. It is preferred that these rocks were formed in an initial mid-ocean ridge setting during the beginning stage of the oceanic basin spreading. This ophiolite together with the Gaojiahe island-arc basalts shows that there exists an ophiolitic mélange along the Wushan-Tangzang boundary fault, and marks the suture zone after the closure of the Qinling ocean in early Paleozoic.

     

Ophiolites of the Eastern Peninsulas zone (Eastern Kamchatka): Age, composition, and geodynamic diversity

Abstract   The geological, geochemical and mineralogical data of dismembered ophiolites of various ages and genesis occurring in accretionary piles of the Eastern Peninsulas of Kamchatka enables us to discriminate three ophiolite complexes: (i) Aptian–Cenomanian complex: a fragment of ancient oceanic crust, composed of tholeiite basalts, pelagic sediments, and gabbroic rocks, presently occurring in a single tectonic slices (Afrika complex) and in olistoplaques in Pikezh complex of the Kamchatsky Mys Peninsula and probably in the mélange of the Kronotsky Peninsula; (ii) Upper Cretaceous complex, composed of highly depleted peridotite, gabbro and plagiogranite, associated with island arc tholeiite, boninite, and high-alumina tholeiitic basalt of supra-subduction origin; and (iii) Paleocene–Early Eocene complex of intra-island arc or back-arc origin, composed of gabbros, dolerites (sheeted dykes) and basalts produced from oceanic tholeiite melts, and back-arc basin-like dolerites. Formation of the various ophiolite complexes is related to the Kronotskaya intra-oceanic volcanic arc evolution. The first ophiolite complex is a fragment of ancient Aptian–Cenomanian oceanic crust on which the Kronotskaya arc originated. Ophiolites of the supra-subduction zone affinity were formed as a result of repeated partial melting of peridotites in the mantle wedge up to the subduction zone. This is accompanied by production of tholeiite basalts and boninites in the Kamchatsky Mys segment and plagioclase-bearing tholeiites in the Kronotsky segment of the Kronotskaya paleoarc. The ophiolite complex with intra-arc and mid-oceanic ridge basalt geochemical characteristics was formed in an extension regime during the last stage of Kronotskaya volcanic arc evolution.     

An Archean oceanic felsic dyke swarm in a nascent arc: the Hunter Mine Group, Abitibi Greenstone Belt, Canada

The 2730-Ma-old Hunter Mine Group (HMG), a dominantly felsic subaqueous volcanic sequence, was formed during early arc construction in the Abitibi greenstone belt (Quebec, Canada). The western part of the HMG contains a felsic dyke swarm up to 1.5 km wide and traceable up-section for 2.5 km. Five distinct generations were identified: (1) aphanitic to feldspar-phyric dykes; (2) quartz-feldspar-phyric dykes with < 5% quartz phenocrysts; (3) quartz-feldspar-phyric dykes with 10–25% quartz phenocrysts; (4) dacitic feldspar-phyric dykes; and (5) mafic dykes. The felsic dykes collectively constitute more than 90% of the dyke swarm. Geochemically, they resemble modern calc-alkaline dacites and rhyolites. Their mantle-normalized incompatible trace-element patterns display a moderate enrichment of Th and light REE relative to HFSE and heavy REE as well as negative Nb, Ta, Eu and Ti anomalies. Most of the major- and trace-element abundance variations in these rocks can be explained by crystallization of feldspars. Geochemical data including depleted mantle-like _Nd values suggest that an older sialic substrate was not involved in their genesis. We infer that the felsic rocks were generated by melting of mafic oceanic crust. The swarm was emplaced during nascent oceanic island-arc development and was related to rifting of the arc. The conformably overlying MORB-like basalts and basaltic komatiites of the Stoughton-Roquemaure Group used the same conduits and further indicate splitting of the arc. HMG and associated parts of the Abitibi greenstone belts bear a strong resemblance to modern rifted intraoceanic arcs of the western Pacific.     

Oxygen- and strontium-isotopic investigations of subduction zone volcanism: the case of the Volcano Arc and the Marianas Island Arc

Recent, fresh, volcanic rocks of the intra-oceanic Mariana and Volcano Arcs were analyzed for O and Sr isotopic compositions in order to determine the source of these magmas. Fresh, non-arc, volcanic rocks from the regions surrounding the Mariana-Volcano Arcs and some DSDP sediments were also analyzed for comparison. The oxygen isotopic ratios of the arc lavas (5.5–6.8‰) exhibited a small inter-island variation that cannot be entirely explained by fractional crystallization. The Sr isotopic composition of the arc lavas is remarkably uniform (0.70332–0.70394 for the Marianas). Three models are considered in order to explain the observed isotopic characteristics: (1) bulk mixing and melting of MORB-type mantle with (a) subducted sediments, and (b) subducted oceanic crust (excluding sediments); (2) melting of a mixture of sediment-derived fluids and MORB-type mantle; and (3) melting of a mixture of sediment-derived fluids and oceanic island or “hot-spot” type mantle. The last model fits the data best. The conclusion that very small, and variable, amounts of sediment-derived fluid ( 1%) are required to explain the observed inter-island O isotopic variation, is consistent with that of other workers who used different isotopic and trace element methods. The generation of magmas in the Mariana-Volcano Arcs involves very little sediment and the source region of Mariana lavas is isotopically indistinguishable from that of hot-spot basalts.     

腾冲火山岩稀土和微量元素地球化学研究

本通过腾冲火山岩稀土和微量元素丰度的测试与分析,结合前人部分资料探讨了该区火山岩的稀土和微量元素地球化学特征：各喷发期火山岩均富集ＬＲＥＥ和Ｒｂ、Ｓｒ、Ｂａ、Ｕ、Ｔｈ等不相容元素;均具极为相似的稀土分配型式和微量元素地球化学模式,这可能反映了各其火山岩初始岩浆的同源性。     

Slab partial melts from the metasomatizing agent to adakite,Tafresh Eocene volcanic rocks,Iran

Geochemical and mineralogical characteristics of the Eocene volcanic succession in Tafresh area of the Urumieh–Dokhtar Magmatic Assemblage (UDMA) are unique in the 2000‐km‐length assemblage. Demonstrating rather steep rare earth element (REE) patterns and the widespread presence of amphibole (+biotite) phenocrysts are two distinct characters that dominate the Eocene volcanic succession of mainly andesitic composition. Coincidence of the geochemical and mineralogical characteristics of the whole volcanic succession with adakites, rather amphibole‐ (+biotite) rich dacitic (with 61–64 wt% SiO₂) stocks and dykes, is considered as the key in unraveling the role of ‘slab‐derived melt contribution’ in petrogenesis of the volcanic succession. Slab‐derived melting has been an ongoing process that metasomatized some parts of the mantle wedge from which hybrid rocks (andesites) are derived. Basalts with distinct signatures of slab melt metasomatism are yet another support for the occurrence of slab melting. Interlayering of normal, island‐arc‐type calc‐alkaline volcanic rocks with the slab‐melt metasomatized basalts and hybrid andesites suggests that the slab melting has been motivated by the subduction. Formation of the Tafresh Caldera, the likely consequence of an explosive eruption, is compatible with the volatile‐bearing nature of the adakitic volcanism in the study area. It is indicated by the ubiquitous presence of the hydrous minerals. Beneath the Tafresh area, in Eocene time, the subducting slab seems to have reached a critical high depth that is enough for the development of amphibolite–eclogite. The slab deformation, motivated by the geometry of subduction and/or the underlying mantle's steeper geotherms, is suggested to have resulted in the slab melting that helped develop a rock assemblage unique to the UDMA.