The polymetallic Au–Ag-bearing veins of Bou Madine (Jbel Ougnat, eastern Anti-Atlas, Morocco): tectonic control and evolution of a Neoproterozoic epithermal deposit

The Bou Madine ore deposit is located SW of Jbel Ougnat, the easternmost inlier of the Anti-Atlas Pan-African belt in Morocco. The host rocks are high-K calc-alkaline volcanic rocks, that are part of the Neoproterozoic Tamerzaga-Timrachine Formation (TTF, lower PIII). The TTF consists of ignimbrites of rhyolitic to dacitic compositions, andesite flows and hypovolcanic bodies (andesite dykes and rhyolite chonoliths) emplaced along N160°E tension gashes associated with a regional N30°E sinistral fault system. The mineralization is related to a high enthalpy geothermal system, eventually evolving into a low temperature epithermal system. A regional propylitisation (T around 260 °C) overprinted the TTF rocks prior to the emplacement of the mineralization. There were two main hydrothermal stages. During the first stage, massive veins with pyrite, arsenopyrite and minor pyrrhotite and cassiterite were formed. The veins were emplaced along N160°E-trending en echelon joints related to N120°E dextral arrays. A quartz-sericite-pyrite alteration overprinted the propylites around the veins (“bleached haloes”), at temperatures up to 300–310 °C. The second stage of mineralization was coeval with dextral re-activation of the N160°E veins, in relation with a NE-ward shift of the shortening direction. First, polymetallic sulphides (sphalerite, chalcopyrite, stannite, galena) were deposited at temperatures 260 °C. Younger quartz veinlets contain arsenopyrite and minor micrometre-size sulphides and sulpho-salts, hosting the precious metals. This was the low temperature epithermal stage (≈150 °C), in relation with invading meteoric water.     

Age of the Wirgane granodiorite intrusions (Western High-Atlas, Morocco): New U–Pb constraints

U–Pb geochronological data, obtained on single zircon grains using the ion microprobe Cameca IMS 1270 (CRPG-CNRS, Nancy), indicate a Neoproterozoic age (625 ± 5 Ma) for the two intrusions of Wirgane granodiorite. This age is in variance with the previously published conclusions where the intrusions were supposed Variscan. Consequently, the Wirgane intrusions are interpreted as remnants of the Neoproterozoic basement of the Variscan belt. They are similar to the Anti-Atlas calc-alkaline intrusions of the collisional to post-collisional stages of the Pan-African orogeny. At that time, the Wirgane region was an area of continental growth to the north of the major South Atlasic Fault.     

New chronological and geochemical constraints on the genesis and geological evolution of Ponza and Palmarola Volcanic Islands (Tyrrhenian Sea, Italy)

A new geochronological and geochemical study of the volcanic rocks of the Ponza and Palmarola Islands, Pontine Archipelago, has been carried out. This archipelago is located along the boundary between the Italian continental shelf and the opening Tyrrhenian basin. It is a key area to study volcanism related to the opening of the Tyrrhenian Sea. Ponza is the oldest felsic magmatic manifestation in the central Tyrrhenian area. Previous studies suggested that Ponza volcanic activity began before 5 Ma. Twenty-five new K–Ar ages constrain the volcanic activity (rhyolitic hyaloclastites and dykes) to the last 4.2 Ma, with two episodes of quiescence between 3.7 and 3.2 Ma and between 2.9 and 1.0 Ma. A new volcanic episode dated at 3.2–2.9 Ma has been identified on the central and southern Ponza, with emplacement of pyroclastic units. At 1.0 Ma, a trachytic episode ended the volcanic activity. The near island of Palmarola exhibits rhyolitic hyaloclastites and domes dated between 1.6 and 1.5 Ma, indicating that the island was entirely built during the Early Pleistocene in a short span of time of ca. 120 ka. Although only 6–8 km apart, the two islands display significantly different geochemical signatures. Ponza rhyolites show major and trace element compositions representative of orogenic magmas of subduction/collision zones: high-K calc-alkaline and metaluminous rhyolites (Agpaitic Index [AI] and Alumina Saturation Index [ASI] <1), high LILE/HFSE (Th/Ta=16–21) and LREE/HFSE ratios (La/Nb>3), and Nb–Ta negative anomalies. In Palmarola, the orogenic character is also present, but much less marked than in Ponza: rhyolites have a peralkaline character (AI>1), lower LILE/HFSE (Th/Ta=11–15), low LREE/HFSE ratios (La/Nb=1–2) close to those of anorogenic lavas, and the Nb–Ta negative anomalies are almost absent. Y/Nb ratios indicate different magmatic sources, one similar to island-arc or active continental margin basalts for Ponza rhyolites, and the others probably involving an OIB type component for Palmarola rhyolites and Ponza trachytes. Palmarola volcanics represent a transitional magmatism: although a preserved collisional geochemical imprint, they show geochemical features approaching those of anorogenic lavas erupted in a within-plate context. The change of magmatism evidenced in this study can be related to the tectonic evolution of the area. Indeed, Hf, Ta and Rb contents suggest that the oldest Pliocene rhyolites of Ponza would emplace in a syn- to late-collisional setting, while the younger Pleistocene rhyolites of Palmarola would be emplaced in a post-collisional setting in which the orogenic character (Th/Ta) decreases and mantle influence (Nb/Ta) increases. Geochemical modeling strongly suggests that the Palmarola rhyolites represent the waning stages of a subduction-related magmatism. The K–Ar datings allow us to estimate precisely the transition of magmatism to last less than 1.3 Ma. The transitional magmas may be the result of the upwelling of asthenospheric mantle inducing melting of a metasomatized lithospheric mantle and the mixing between these two sources. This upwelling could occur during the extension of the Tyrrhenian basin, caused by the slab retreat and steepening, or during a process of slab break-off starting in the Pliocene.     

Petrography and geochemistry of the Ngaoundéré Pan-African granitoids in Central North Cameroon: Implications for their sources and geological setting

The Nagoundéré Pan-African granitoids in Central North Cameroon belong to a regional-scale massif, which is referred to as the Adamawa-Yade batholith. The granites were emplaced into a ca. 2.1 Ga remobilised basement composed of metasedimentary and meta-igneous rocks that later underwent medium- to high-grade Pan-African metamorphism. The granitoids comprise three groups: the hornblende–biotite granitoids (HBGs), the biotite ± muscovite granitoids (BMGs), and the biotite granitoids (BGs). New Th–U–Pb monazite data on the BMGs and BGs confirm their late Neoproterozoic emplacement age (ca. 615 ± 27 Ma for the BMGs and ca. 575 Ma for the BGs) during the time interval of the regional tectono-metamorphic event in North Cameroon. The BMGs also show the presence of ca. 926 Ma inheritances, suggesting an early Neoproterozoic component in their protolith.The HBGs are characterized by high Ba–Sr, and low K₂O/Na₂O ratios. They show fairly fractionated REE patterns (La_N/Yb_N 6–22) with no Eu anomalies. The BMGs are characterized by higher K₂O/Na₂O and Rb/Sr ratios. They are more REE-fractionated (La_N/Yb_N = 17–168) with strong negative Eu anomalies (Eu/Eu^* = 0.2–0.5). The BGs are characterized by high SiO₂ with K₂O/Na₂O > 1. They show moderated fractionated REE patterns (La_N/Yb_N = 11–37) with strong Eu negative anomalies (Eu/Eu^* = 0.2–0.8) and flat HREE features (Gd_N/Yb_N = 1.5–2.2). In Primitive Mantle-normalized multi-element diagrams, the patterns of all rocks show enrichment in LILE relative to HFSE and display negative Nb–Ta and Ti anomalies. All the granitoids belong to high-K calc-alkaline suites and have an I-type signature.Major and trace element data of the HBGs are consistent with differentiation of a mafic magma from an enriched subcontinental lithospheric mantle, with possible crustal assimilation. In contrast, the high Th content, the LREE-enrichment, and the presence of inherited monazite suggest that the BGs and BMGs were derived from melting of the middle continental crust. Structural and petrochemical data indicate that these granitoids were emplaced in both syn- to post-collision tectonic settings.     

Petrology and geodynamic significance of the post-collisional Pan-African magmatism in the Eastern Saghro area (Anti-Atlas, Morocco)

The Saghro Group consists of a thick volcanic-sedimentary sequence with intercalated basaltic lavas, the first magmatic event in eastern Saghro area. Nd isotopes of basaltic pillow lavas show T_DM model ages ranging from 640 to 580 Ma, which represent a maximum age for basalt eruption.Granitoids within the Saghro Group consist of a charnockitic suite, tonalites, granodiorites and monzogranites. They are high-K calc-alkaline (HKCA) with a post-collisional character, and were emplaced at high-levels in the crust. Their ages of emplacement are within the 580–560 Ma bracket, implying that the entire Saghro Group is slightly older than or partly coeval to granitoid emplacement and implying a common geodynamical setting. Sr–Nd isotopic compositions and Nd T_DM model ages point to a mixed origin, combining a juvenile mantle source and an Eburnean crustal component, which could be the West African Craton (WAC). The juvenile component in the Saghro granitoids could be the depleted upper mantle that has sourced the earlier basalts.Field observations, geochemical and geochronological data together support that, during the Pan-African orogeny, the Anti-Atlas was subjected to a regional transpressional to transtensional event. This event would have been responsible for the dissection of the northern margin of the WAC into several blocks, the development of deep sedimentary basins and the emplacement of HKCA magmas.     

Calc-alkaline Arc I-type Granitoid Associated with S-type Granite in the Pan-African Belt of Eastern Anti-Atlas (Saghro and Ougnat, South Morocco)

The Sidi Flah and Ougnat inliers are located in the eastern Anti-Atlas antiform between the Anti-Atlas Major Fault (AAMF) and South Atlas Fault (SAF). They consist of many granitoid intrusions emplaced into Neoproterozoic metasedimentary rocks and surmounted by upper Neoproterozoic A-type granites. The Sidi Flah (Saghro) and Ougnat granitoids are part of the Neoproterozoic magmatic activity related to northwards subduction of an oceanic plate beneath the Saghro continental margin. They are post-orogenic I- and S-type granitoids related to the ending of the compressional deformation in this Pan-African belt. A petrographic, geochemical and zircon typology study leads us to subdivide these rocks into three magmatic groups: (1) a medium- to high-K calc-alkaline group formed by quartz diorites and amphibole granodiorites is found in both Sidi Flah and Ougnat inliers; (2) a high-K calc-alkaline group is present in Sidi Flah. These two groups have a (deeper and) hybrid mantle-crust origin; (3) a peraluminous group in Ougnat is linked to the post-collisional setting and has a shallow crustal source. On a primitive mantle-normalized trace-element diagram, almost all of these rocks show a significant Nb depletion relative to K and La, which is typical of the calc-alkaline magmatism from the subduction-zone environment. Absence of structural marks of thrusting upon the West African craton (WAC) of this arc system and the ophiolitic suite in Bou-Azzer, and the presence of Imiter muscovite-bearing granite as part of Pan-African belt do not support the localization of northern limit of WAC at the level of SAF.     

New radiometric dating of the dykes from the Hurd Peninsula, Livingston Island, South Shetland Islands

Fifteen new K–Ar ages in the range of 79–31 Ma are partially confirmed by three ⁴⁰Ar/³⁹Ar plateaus and isochron data of 64.9±0.4, 55.5±0.1 and 52.8±0.6 Ma. The new geochronological data reveal a much more detailed picture of the subduction imprint in the Hurd Peninsula. Using cutting relationships, the dyke emplacement history is divided into four episodes. The Late Cretaceous–Paleocene dykes in the range of 80–60 Ma are related to the main magmatism in Livingston Island and most likely reflect the final stages of subduction of the proto-Pacific oceanic crust. The Early Eocene dykes (56–52 Ma) fill the gap in volcanic activity 70–50 Ma ago. They are the only magmatic event manifested at this time in the region. The 45–42 Ma dykes may be related to the intrusion of the Barnard Point tonalite. Three samples of Oligocene age appear to represent the last igneous activities on the Hurd Peninsula prior to the opening of the Bransfield Strait.     

Metamorphic evolution of the Maud Belt: P–T–t path for high-grade gneisses in Gjelsvikfjella, Dronning Maud Land, East Antarctica

A metamorphic petrological study, in conjunction with recent precise geochronometric data, revealed a complex P–T–t path for high-grade gneisses in a hitherto poorly understood sector of the Mesoproterozoic Maud Belt in East Antarctica. The Maud Belt is an extensive high-grade, polydeformed, metamorphic belt, which records two significant tectono-thermal episodes, once towards the end of the Mesoproterozoic and again towards the late Neoproterozoic/Cambrian. In contrast to previous models, most of the metamorphic mineral assemblages are related to a Pan-African tectono-thermal overprint, with only very few relics of late Mesoproterozoic granulite-facies mineral assemblages (M₁) left in strain-protected domains. Petrological and mineral chemical evidence indicates a clockwise P–T–t path for the Pan-African orogeny. Peak metamorphic (M_2b) conditions recorded by most rocks in the area (T = 709–785 °C and P = 7.0–9.5 kbar) during the Pan-African orogeny were attained subsequent to decompression from probably eclogite-facies metamorphic conditions (M_2a).The new data acquired in this study, together with recent geochronological and geochemical data, permit the development of a geodynamic model for the Maud Belt that involves volcanic arc formation during the late Mesoproterozoic followed by extension at 1100 Ma and subsequent high-grade tectono-thermal reworking once during continent–continent collision at the end of the Mesoproterozoic (M₁; 1090–1030 Ma) and again during the Pan-African orogeny (M_2a, M_2b) between 565 and 530 Ma. Post-peak metamorphic K-metasomatism under amphibolite-facies conditions (M_2c) followed and is ascribed to post-orogenic bimodal magmatism between 500 and 480 Ma.     

The LATEA metacraton (Central Hoggar, Tuareg shield, Algeria): behaviour of an old passive margin during the Pan-African orogeny

Historically, the Tuareg shield is divided into three parts bordered by mega-shear zones with the centre, the Central Polycyclic Hoggar, characterized by Archaean and Palaeoproterozoic lithologies. Nearly 10 years ago, the Tuareg shield was shown to be composed of 23 displaced terranes [Geology 22 (1994) 641] whose relationships were deciphered in Aïr to the SE [Precambr. Res. 67 (1994) 59]. The Polycyclic Central Hoggar terranes were characterized by the presence of well preserved Archaean/Palaeoproterozoic and Neoproterozoic lithologies.We show here that the terranes from Central Hoggar (Laouni, Azrou-n-Fad, Tefedest, Egéré-Aleksod) belonged to a single old passive margin, to which we gave the acronym name LATEA, which behaved as a craton during the Mesoproterozoic and the Early-Middle Neoproterozoic but was partly destabilized and dissected during the Late Neoproterozoic as a consequence of its involvement as a passive margin in the Pan-African orogen.An early Pan-African phase consisted of thrust sheets including garnet-bearing lithologies (eclogite, amphibolite, gneiss) that can be mapped and correlated in three LATEA terranes. In the Tin Begane area, P–T–t paths have been established from>15 kbar––790 °C (eclogite) to 4 kbar––500 °C (greenschist retrogression) through 12 kbar––830 °C (garnet amphibolite) and 8 kbar––700 °C (garnet gneiss), corresponding to the retrograde path of a Franciscan-type loop. Sm–Nd geochronology on minerals and laser ablation ICP-MS on garnet show the mobility of REE, particularly LREE, during the retrograde greenschist facies that affects, although slightly, some of these rocks. The amphibolite-facies metamorphism has been dated at 685 ± 19 Ma and the greenschist facies at 522 ± 27 Ma. During the thrust phase, the Archaean–Palaeoproterozoic basement was only locally affected by the Pan-African tectonics. LATEA behaved as a craton. Other juvenile terranes were also thrust early onto LATEA: the Iskel island arc at ≈850 Ma to the west of LATEA, the Serouenout terrane in the 700–620 Ma age range to the east. No subduction-related magmas have intruded LATEA during this epoch, which behaved as a passive margin.During the main Pan-African phase (625–580 Ma), LATEA was dissected by mega-shear zones that induced several hundreds km of relative displacement and allowed the emplacement of high-K calc-alkaline batholiths. Smaller movements continued till 525 Ma, accompanied by the emplacement of subcircular plutons with alkaline affinity. Here is dated the Ounane granodiorite (624 ± 15 Ma; ⁸⁷Sr/⁸⁶Sr_i=0.70839 ± 0.00016; 6WR, MSWD=0.87) and the Tisselliline granite (552 ± 15 Ma; ⁸⁷Sr/⁸⁶Sr_i=0.7074 ± 0.0001; 5WR, MSWD=1.4). Nd isotopes indicate a preponderant Palaeoproterozoic crustal source for these two plutons: _Nd=−14 to −21 at 624 Ma and T_DM=1650–2320 Ma for Ounane and _Nd=−13 to −15 at 555 Ma and T_DM=1550–1720 Ma for Tisselliline. Our model links these intrusions to a linear lithospheric delamination along mega-shear zones, allowing the hot asthenosphere to rise, melt by adiabatic pressure release and inducing the melting of the Palaeoproterozoic and Archaean lower crust.The LATEA cratonic microcontinent remained however sufficiently rigid to preserve Archaean and Palaeoproterozoic lithologies as well as Middle Neoproterozoic oceanic thrust sheets. This corresponds to the notion of metacraton [J. African Earth Sci. 34 (2002) 119], i.e. a craton that has been remobilized during an orogenic event but is still recognizable dominantly through its rheological, geochronological, isotopic and sometimes petrological characteristics.     

Single zircon ages of migmatitic gneisses and granulites in the Obudu Plateau: Timing of granulite-facies metamorphism in southeastern Nigeria

A single zircon geochronological study of gneisses from the Obudu Plateau of southeastern Nigeria, using the evaporation technique, indicates that zircons recorded several Precambrian high-grade metamorphic events (Eburnean and Pan-African). Igneous and multifaceted metamorphic zircons yielded ²⁰⁷Pb/²⁰⁶Pb ages of 2062.4 ± 0.4 Ma, 1803.8 ± 0.4 Ma and 574 ± 10 Ma, respectively and confirm for the first time that granulite-facies metamorphism affected the basement of southeastern Nigeria, resulting in the formation of charnockites and granulitic gneisses. The Pan-African high-grade event was coeval with the formation of granulites in Cameroon, Togo and Ghana and resulted from collisional processes during continental amalgamation to form the Gondwana supercontinent. The sources of the sediments, which were deposited at ≈605 Ma and metamorphosed at 574 Ma, comprise older igneous and metamorphic protoliths (including inherited xenocrystic zircons up to 2.5 Ga in age). The Palaeoproterozoic zircons seem to have survived Pan-African melting.     

Geochemistry and geochronology of the bimodal volcanic rocks of the Suguti area in the southern part of the Musoma-Mara Greenstone Belt, Northern Tanzania

The Suguti volcanic rocks of the southern Musoma-Mara greenstone belt in northern Tanzania comprise mainly of a bimodal suite of tholeiitic basalts-basaltic andesites and calc-alkaline rhyolites with a subordinate amount of intermediate rocks. Zircon U–Pb and whole rock Sm–Nd geochronology suggests that the two suites are cogenetic and were emplaced at 2755 ± 1 Ma with a common initial _Nd value of 2.1.The tholeiitic basalts are characterised by relatively flat chondrite-normalised REE patterns with La/Yb_CN ratios of 0.8–1.6 (mean = 1.0). The basalts also exhibit negative Ti and Nb anomalies in primitive mantle-normalised multi-element diagrams. The flat REE patterns, the presence of prominent negative Nb anomalies and the positive initial _Nd value of 2.1 suggest that the basalts were formed by low pressure melting of a mantle wedge in an active continental margin setting.Compared to the tholeiitic basalts, the calc-alkaline rhyolites are characterised by low abundances of the transition elements (Cr < 20 ppm, Ni < 20 ppm) and moderately high HFSE (e.g. Zr = 111–250 ppm) abundances. The rhyolites display strongly fractionated, slightly concave upward chondrite normalised REE patterns that are characterised by a slight depletion of the MREE relative to the HREE and minor to large negative Eu anomalies (Eu/Eu* = 0.3–0.9) and their epsilon Nd values range from +2.05 to +2.33. The depletion of the MREE relative to the HREE is an indication of fractionation of clinopyroxene and hornblende during petrogenesis whereas the negative Eu anomalies indicate plagioclase fractionation. The rhyolites are interpreted to have formed from the parental magma of the basalts by fractional crystallization and/or partial melting of a relatively young basaltic crust.     

Molybdenite Re–Os and albite Ar/Ar dating of Cu–Au–Mo and magnetite porphyry systems in the Yangtze River valley and metallogenic implications

The area of the Middle–Lower Yangtze River valley, Eastern China, extending from Wuhan (Hubei province) to western Zhenjiang (Jiangsu province), hosts an important belt of Cu–Au–Mo and Fe deposits. There are two styles of mineralization, i.e., skarn/porphyry/stratabound Cu–Au–Mo–(Fe) deposits and magnetite porphyry deposits in several NNE-trending Cretaceous fault-bound volcanic basins. The origin of both deposit systems is much debated. We dated 11 molybdenite samples from five skarn/porphyry Cu–Au–Mo deposits and 5 molybdenite samples from the Datuanshan stratabound Cu–Au–Mo deposit by ICP-MS Re–Os isotope analysis. Nine samples from the same set were additionally analyzed by NTIMS on Re–Os. Results from the two methods are almost identical. The Re–Os model ages of 16 molybdenite samples range from 134.7 ± 2.3 to 143.7 ± 1.6 Ma (2σ). The model ages of the five samples from the Datuanshan stratabound deposit vary from 138.0 ± 3.2 to 140.8 ± 2.0 Ma, with a mean of 139.3 ± 2.6 Ma; their isochron age is 139.1 ± 2.7 Ma with an initial Os ratio of 0.7 ± 8.1 (MSWD = 0.29). These data indicate that the porphyry/skarn systems and the stratabound deposits have the same age and suggest an origin within the same metallogenic system. Albite ⁴⁰Ar/³⁹Ar dating of the magnetite porphyry deposits indicates that they formed at 123 to 125 Ma, i.e., 10–20 Ma later. Both mineralization styles characterize transitional geodynamic regimes, i.e., the period around 140 Ma when the main NS-trending compressional regime changed to an EW-trending lithospheric extensional regime, and the period of 125–115 Ma of dramatic EW-trending lithospheric extension.     

Neoarchaean high-grade metamorphism in the Central Zone of the Limpopo Belt (South Africa): Combined petrological and geochronological evidence from the Bulai pluton

The Bulai pluton represents a calc-alkaline magmatic complex of variable deformed charnockites, enderbites and granites, and contains xenoliths of highly deformed metamorphic country rocks. Petrological investigations show that these xenoliths underwent a high-grade metamorphic overprint at peak P–T conditions of 830–860 °C/8–9 kbar followed by a pressure–temperature decrease to 750 °C/5–6 kbar. This P–T path is inferred from the application of P–T pseudosections to six rock samples of distinct bulk composition: three metapelitic garnet–biotite–sillimanite–cordierite–plagioclase–(K-feldspar)–quartz gneisses, two charnoenderbitic garnet–orthopyroxene–biotite–K-feldspar–plagioclase–quartz gneisses and an enderbitic orthopyroxene–biotite–plagioclase–quartz gneiss. The petrological data show that the metapelitic and charnoenderbitic gneisses underwent uplift, cooling and deformation before they were intruded by the Bulai Granite. This relationship is supported by geochronological results obtained by in situ LA-ICP-MS age dating. U–Pb analyses of monazite enclosed in garnet of a charnoenderbite gneiss provide evidence for a high-grade structural-metamorphic–magmatic event at 2644 ± 8 Ma. This age is significantly older than an U–Pb zircon crystallisation age of 2612 ± 7 Ma previously obtained from the surrounding, late-tectonic Bulai Granite. The new dataset indicates that parts of the Limpopo's Central Zone were affected by a Neoarchaean high-grade metamorphic overprint, which was caused by magmatic heat transfer into the lower crust in a ‘dynamic regional contact metamorphic milieu’, which perhaps took place in a magmatic arc setting.     

The giant Imiter silver deposit: Neoproterozoic epithermal mineralization in the Anti-Atlas, Morocco

The world-class Imiter silver deposit, in the Anti-Atlas Mountains of Morocco, is a Neoproterozoic epithermal vein deposit genetically associated with a felsic volcanic event, and formed within a regional extensional tectonic regime. Rhyolitic volcanism related to ore formation has been dated at 550Dž Ma by ion-probe U/Pb on zircons. The economic silver mineralization is superimposed on an older, discrete base-metal assemblage associated with calc-alkaline granodioritic magmatism. The magmatism is dated at 572LJ Ma by ion-probe U/Pb dating on zircons, and by ⁴⁰Ar/³⁹Ar dating on hydrothermal muscovites. In the Anti-Atlas Mountains, the Precambrian-Cambrian transition appears as an important period for the formation of major, productive precious-metal deposits associated with volcanic events and extensional tectonics. The Imiter silver deposit constitutes a Precambrian analogue to modern epithermal deposits.     

Geochronology and petrogenesis of the post-orogenic Cu–Ni sulfide-bearing mafic–ultramafic complexes in Jilin Province, NE China

Northeastern (NE) China is a well-documented example of a collisional zone characterized by widespread post-orogenic granites and mafic–ultramafic complexes. Based on a study of the Hongqiling and Piaohechuan Cu–Ni sulfide-bearing mafic–ultramafic complexes in central Jilin province, we present geological, petrological, geochemical and geochronological data which indicates their post-orogenic origin.The Hongqiling complex comprises pyroxenite, olivine websterite, lherzolite, gabbro and leucogabbro. Zircon U–Pb SHRIMP analyses on a leucogabbro of the Hongqiling complex yield a weighted mean ²⁰⁶Pb–²³⁸U age of 216±5 Ma. The Piaohechuan complex is composed of gabbro, pyroxenite and dolerite, exposed as dikes. A plagioclase-bearing pyroxenite has a U–Pb zircon weighted mean ²⁰⁶Pb–²³⁸U age of 217±3 Ma, identical to that of the Hongqiling complex. These ages are coeval with the emplacement of A-type granites in the area, but slightly younger than the regional metamorphism (240 Ma) and syn-orogenic granitic magmatism (246±4 Ma). This suggests that these mafic–ultramafic complexes are post-orogenic in origin. The age data also indicated a short period of lithospheric stabilization of about 30 Ma after cessation of orogenic activity.Geochemical investigation indicates that the primary mafic magma was a lithospheric mantle-derived basalt resulting from the upwelling of asthenosphere due to lithospheric delamination during post-orogenic processes. The magmatic source was contaminated by a small amount of crustal material, and subsequent crystal fractionation resulted in the Cu–Ni mineralization.The widespread occurrence of mafic–ultramafic complexes in the Xing'an–Mongolian Orogenic Belt of NE China and in the Altay–Tianshan–Junggar Orogenic Belt of Northern Xinjiang indicates that mafic intrusions are an important magmatic suite that evolved during post-orogenic processes. Portions of this mafic magma could have underplated the lower crust, and served as the heat source for associated late-stage granitic magmas.     

The Anti-Atlas Pan-African Belt (Morocco): Overview and pending questions

Between the High Atlas and the Saharan platform, the Anti-Atlas of Morocco offers large exposures of Precambrian rocks beneath the moderately folded Paleozoic series. These inliers allow reconstructing a segment of the Pan-African Belt and of its foreland at the northern outskirts of the West African Craton (WAC). From ∼ 885 Ma to ∼ 540 Ma, three periods are recognized in the Pan-African cycle. The Tonian–Cryogenian period ends with the obduction of supra-subduction ophiolite and oceanic arc material at ∼ 640 Ma. The Early Ediacaran period is marked by the development and subsequent closure of a wide marginal basin next to a likely Andean-type arc. The Late Ediacaran period is recorded by subaerial molasse deposits associated with post-collisional high-K calc-alkaline to shoshonitic magmatism. Although a wide consensus has been reached based on the number of new robust datings, several questions still remain pending, which we address taking into account relevant African and European correlations.     

Geochronology and paleomagnetism of mafic igneous rocks in the Olenek Uplift, northern Siberia: Implications for Mesoproterozoic supercontinents and paleogeography

We present a new, reliably dated Mesoproterozoic paleopole for Siberia, based on a combined geochronological and paleomagnetic study of mafic rocks within the Mesoproterozoic Sololi Group of the Olenek Uplift in northern Siberia. Ion microprobe (SHRIMP) U–Pb analysis yields crystallisation ages of 2036 ± 11 Ma for zircon from a basement granite and 1473 ± 24 Ma for baddeleyite from a large dolerite sill within the Kyutingde Formation. The baddeleyite result indicates that the lower Sololi Group is significantly older than was suggested by previous K–Ar results. Paleomagnetic analysis of the dolerite sill and related mafic intrusive rocks yields a paleopole at 33.6°N, 253.1°E, A₉₅ = 10.4°. A positive baked-contact test between the Kyutingde sill and sedimentary country rocks shows that the magnetisation is primary. Comparison of this paleopole with coeval results for Laurentia provides a revised reconstruction between Siberia and Laurentia, and implies that these two continents were parts of a single Mesoproterozoic supercontinent since at least 1473 Ma. We argue that Siberia, Laurentia, and Baltica belonged to the same supercontinent between 1473 Ma and mid-Neoproterozoic time.     

Conflicting structural and geochronological data from the Ibituruna quartz-syenite (SE Brazil): Effect of protracted “hot” orogeny and slow cooling rate?

The Ibituruna quartz-syenite was emplaced as a sill in the Ribeira-Araçuaí Neoproterozoic belt (Southeastern Brazil) during the last stages of the Gondwana supercontinent amalgamation. We have measured the Anisotropy of Magnetic Susceptibility (AMS) in samples from the Ibituruna sill to unravel its magnetic fabric that is regarded as a proxy for its magmatic fabric. A large magnetic anisotropy, dominantly due to magnetite, and a consistent magnetic fabric have been determined over the entire Ibituruna massif. The magmatic foliation and lineation are strikingly parallel to the solid-state mylonitic foliation and lineation measured in the country-rock. Altogether, these observations suggest that the Ibituruna sill was emplaced during the high temperature (~ 750 °C) regional deformation and was deformed before full solidification coherently with its country-rock. Unexpectedly, geochronological data suggest a rather different conclusion. LA-ICP-MS and SHRIMP ages of zircons from the Ibituruna quartz-syenite are in the range 530–535 Ma and LA-ICP-MS ages of zircons and monazites from synkinematic leucocratic veins in the country-rocks suggest a crystallization at ~ 570–580 Ma, i.e., an HT deformation > 35My older than the emplacement of the Ibituruna quartz-syenite. Conclusions from the structural and the geochronological studies are therefore conflicting. A possible explanation arises from ⁴⁰Ar–³⁹Ar thermochronology. We have dated amphiboles from the quartz-syenite, and amphiboles and biotites from the country-rock. Together with the ages of monazites and zircons in the country-rock, ⁴⁰Ar–³⁹Ar mineral ages suggest a very low cooling rate: < 3 °C/My between 570 and ~ 500 Ma and ~ 5 °C/My between 500 and 460 Ma. Assuming a protracted regional deformation consistent over tens of My, under such stable thermal conditions the fabric and microstructure of deformed rocks may remain almost unchanged even if they underwent and recorded strain pulses separated by long periods of time. This may be a characteristic of slow cooling “hot orogens” that rocks deformed at significantly different periods during the orogeny, but under roughly unchanged temperature conditions, may display almost indiscernible microstructure and fabric.     

Generation of Late Cretaceous silicic rocks in SE China: Age, major element and numerical simulation constraints

Rhyolite-dominating bimodal volcanic suites (rhyolite/basalt), mafic dikes and A-type granites distribute from N Zhejiang to S Fujian over 800 km in the Southeast Coast Magmatic Belt (SCMB) – the Late Yanshanian (LY) orogenic belt in SE China. Data of ⁴⁰Ar/³⁹Ar and K–Ar whole-rock ages and LA-ICPMS U–Pb zircon ages indicate that rhyolitic volcanism (101–72 Ma) is contemporaneous with the A-type granitic intrusions (100–90 Ma) and mafic dike injections (94–77 Ma). This time span is used to define the upper volcanic series in Zhejiang–Fujian areas. One striking feature of rhyolites in the SCMB is that many are strongly peraluminous (SP) and others, mostly restrict in Fujian, are peralkaline to mildly peraluminous (P-MP) and chemically resemble A-type granites. The SP character is unique among well-known large rhyolite provinces worldwide. Based on experimental works for a common thermal regime and inherited zircon age information, we suggest that SP and P-MP rhyolites represent low pressure melting of the felsic (quartzofeldspathic) granite (±metapelite) and the accompanied granodioritic, tonalitic and trondhjemitic member of the core complex assemblage, respectively, to account for the decreasing aluminosity. They could have also been contaminated by young igneous rocks, and ancient crust to a lesser degree, during ascent to the surface. Plate subduction and lithosphere extension processes, respectively, are numerically simulated for the magma generation of these rhyolites using the mafic underplating model. Results suggest that the most effective controlling factor to generate SP and associated P-MP (A-type) magmas during 95–80 Ma is thinning of the lithosphere thickness with a high exhumation rate. Under this circumstance, the core complex assemblage can be uplifted to lower level of the crust and match the constraint of experimental works.     

Geochronological framework and Pb, Sr isotope geochemistry of the Qingchengzi Pb–Zn–Ag–Au orefield, Northeastern China

The Qingchengzi orefield in northeastern China, is a concentration of several Pb–Zn, Ag, and Au ore deposits. A combination of geochronological and Pb, Sr isotopic investigations was conducted. Zircon SHRIMP U–Pb ages of 225.3 ± 1.8 Ma and 184.5 ± 1.6 Ma were obtained for the Xinling and Yaojiagou granites, respectively. By step-dissolution Rb–Sr dating, ages of 221 ± 12 Ma and 138.7 ± 4.1 Ma were obtained for the sphalerite of the Zhenzigou Zn–Pb deposit and pyrargyrite of the Ag ore in the Gaojiabaozi Ag deposit, respectively. Pb isotopic ratios of the Ag ore at Gaojiabaozi (²⁰⁶Pb/²⁰⁴Pb = 18.38 to 18.53) are higher than those of the Pb–Zn ores (²⁰⁶Pb/²⁰⁴Pb = 17.66 to 17.96; Chen et al. [Chen, J.F., Yu, G., Xue, C.J., Qian, H., He, J.F., Xing, Z., Zhang, X., 2005. Pb isotope geochemistry of lead, zinc, gold and silver deposit clustered region, Liaodong rift zone, northeastern China. Science in China Series D 48, 467–476.]). Triassic granites show low Pb isotopic ratios (²⁰⁶Pb/²⁰⁴Pb = 17.12 to 17.41, ²⁰⁷Pb/²⁰⁴Pb = 15.47 to 15.54, ²⁰⁸Pb/²⁰⁴Pb = 37.51 to 37.89) and metamorphic rocks of the Liaohe Group have high ratios (²⁰⁶Pb/²⁰⁴Pb = 18.20 to 24.28 and 18.32 to 20.06, ²⁰⁷Pb/²⁰⁴Pb = 15.69 to 16.44 and 15.66 to 15.98, ²⁰⁸Pb/²⁰⁴Pb = 37.29 to 38.61 and 38.69 to 40.00 for the marble of the Dashiqiao Formation and schist of the Gaixian Formation, respectively).Magmatic activities at Qingchengzi and in adjacent regions took place in three stages, and each contained several magmatic pulses: ca. 220 to 225 Ma and 211 to 216 Ma in the Triassic; 179 to 185 Ma, 163 to 168 Ma, 155 Ma and 149 Ma in the Jurassic, as well as ca. 140 to 130 Ma in the Early Cretaceous. The Triassic magmatism was part of the Triassic magmatic belt along the northern margin of the North China Craton produced in a post-collisional extensional setting, and granites in it formed by crustal melting induced by mantle magma. The Jurassic and Early Cretaceous magmatism was related to the lithospheric delamination in eastern China. The Triassic is the most important metallogenic stage at Qingchengzi. The Pb–Zn deposits, the Pb–Zn–Ag ore at Gaojiabaozi, and the gold deposits were all formed in this stage. They are temporally and spatially associated with the Triassic magmatic activity. Mineralization is very weak in the Jurassic. Ag ore at Gaojiabaozi was formed in the Early Cretaceous, which is suggested by the young Rb–Sr isochron age, field relations, and significantly different Pb isotopic ratios between the Pb–Zn–Ag and Ag ores. Pb isotopic compositions of the Pb–Zn ores suggest binary mixing for the source of the deposits. The magmatic end-member is the Triassic granites and the other metamorphic rocks of the Liaohe Group. Slightly different proportions of the two end-members, or an involvement of materials from hidden Cretaceous granites with slightly different Pb isotopic ratios, is postulated to interpret the difference of Pb isotopic compositions between the Pb–Zn–(Ag) and Ag ores. Sr isotopic ratios support this conclusion. At the western part of the Qingchengzi orefield, hydrothermal fluid driven by the heat provided by the now exposed Triassic granites deposited ore-forming materials in the low and middle horizons of the marbles of the Dashiqiao Formation near the intrusions to form mesothermal Zn–Pb deposits. In the eastern part, hydrothermal fluids associated with deep, hidden Triassic intrusions moved upward along a regional fault over a long distance and then deposited the ore-forming materials to form epithermal Au and Pb–Zn–Ag ores. Young magmatic activities are all represented by dykes across the entire orefield, suggesting that the corresponding main intrusion bodies are situated in the deep part of the crust. Among these, only intrusions with age of ca. 140 Ma might have released sufficient amounts of fluid to be responsible for the formation of the Ag ore at Gaojiabaozi.Our age results support previous conclusions that sphalerite can provide a reliable Rb–Sr age as long as the fluid inclusion phase is effectively separated from the “sulfide” phase. Our work suggests that the separation can be achieved by a step-resolution technique. Moreover, we suggest that pyrargyrite is a promising mineral for Rb–Sr isochron dating.