Diffusive fractionation of noble gases and helium isotopes during mantle melting

The large differences in He and Ar diffusivities in silicate minerals could result in fractionation of the He/Ar ratio during melting of the mantle, producing He/Ar ratios in the primary mantle melts that are higher than those of the bulk mantle. Modeling noble gas diffusion out of the bulk mantle into fast diffusion pathways (such as fractures or melt channels) suggests that significant (order of magnitude) He/Ar fractionation will occur if the fast diffusion channels are spaced several meters apart and the noble gas residence in these diffusion channels is of the order days to weeks. In addition, the 15% difference in ³He and ⁴He diffusivities could also produce isotopic fractionation between the melt and its solid source. Modeling the behavior of He and Ar during melting shows that small increases (few %) in ³He/⁴He should be correlated with larger variations (factor of 5) in ⁴He/⁴⁰Ar. However, in order to test this hypothesis the effects of subsequent He–Ar fractionation that occur during degassing have to be corrected. I describe a scheme that can separate He/Ar variations in the primary melt from overprinted fractionation during magmatic degassing. Using the degassing-corrected data, there is a correlation between the primary melt’s ⁴He/⁴⁰Ar and ³He/⁴He in mid-ocean ridge basalts (MORBs). The slope of the correlation is consistent with the models of preferential diffusion of ³He relative to ⁴He and of ⁴He relative to ⁴⁰Ar from the solid mantle into the melt. Diffusive fractionation of noble gases during melting of the mantle can also account for low ⁴He/⁴⁰Ar ratios commonly found in residual mantle xenoliths: preferential diffusion of He relative to Ar will produce some regions of the mantle with low ⁴He/⁴⁰Ar, the complement of the high ⁴He/⁴⁰Ar ratios in basalts. Diffusive fractionation cannot, however, account for differences between the He and Ne isotopic compositions of MORBs compared with ocean island basalts (OIBs); not only are the extremely high ³He/⁴He ratios of OIBs (up to 50 Ra) difficult to produce at reasonable mantle time and lengthscales, but also the Ne isotopic compositions of MORBs and OIBs do not lie on a single mass fractionation line, therefore cannot result from diffusive fractionation of a single mantle Ne source. If preferential diffusion of He from the solid mantle into primary melts is a significant process during generation of MORBs, then it is difficult to constrain the He concentration of the mantle: He concentrations in basalts and the He flux to the ocean essentially result from extraction of He from a larger (and unknown) volume of mantle than that that produced the basalts themselves. The He concentration of the mantle cannot be constrained until more accurate estimates of the diffusion contribution are available.     

Noble gas isotopic composition of deep underground water in Osaka plain, central Japan: Evidence for mantle He and model for new volcanism

Abstract Elemental and isotopic compositions of noble gases extracted from the bore hole water in Osaka plain, central Japan were examined. The water samples were collected from four shallow bore holes (180-450 m) and seven deep bore holes (600-1370 m) which have been used for an urban resort hot spring zone. The water temperatures of the deep bore holes were 22-50°C and that of the shallow bore holes, 13-23°C. The elemental abundance patterns show the progressive enrichment of the heavier noble gases compared with the atmospheric noble gas composition except for He, which is heavily enriched in deep bore hole water samples. ³He/⁴He ratios from the bore holes reaching the Ryoke granitic basement were higher than the atmospheric value (1.4 × 10⁻⁶), indicating a release of mantle He through the basement. The highest value of 8.2 × 10⁻⁶ is in the range of arc volcanism. On the other hand, the bore holes in sedimentary rocks overlying the basement release He enriched in radiogenic ⁴He, resulted in a low ³He/⁴He ratio of 0.5 × 10⁻⁶. ⁴He/²⁰Ne and ⁴⁰Ar/³⁶Ar ratios indicate that the air contamination is generally larger in shallow bore holes than in deep ones from each site. The helium enriched in mantle He is compatible with the previous work which suggested up-rising magma in 'Kinki Spot', the area of Osaka and western Wakayama, in spite of no volcanic activity in the area. A model to explain an initiation of magma generation beneath this area is presented.     

Pb isotopic variability in melt inclusions from the EMI–EMII–HIMU mantle end-members and the role of the oceanic lithosphere

Melt inclusions from four individual lava samples representing the HIMU (Mangaia Island), EMI (Pitcairn Island) and EMII (Tahaa Island) end member components, have heterogeneous Pb isotopic composition larger than that defined by the erupted lavas in each island. The broad linear trend in ²⁰⁷Pb/²⁰⁶Pb–²⁰⁸Pb/²⁰⁶Pb space produced by the melt inclusions from Mangaia, Tahaa and fPitcairn samples reproduces the entire trend defined by the Austral chain, the Society islands and the Pitcairn island and seamount groups. The inclusions preserve a record of melt composition of far greater isotopic diversity than that sampled in whole rock basalts. These results can be explained by mixing of a common depleted component with the HIMU, EMI and EMII lavas, respectively. We favor a model that considers the oceanic lithosphere to be that common component. We suggest that the Pb isotopic compositions of the melt inclusions reflect wall rock reaction of HIMU, EMI and EMII melts during their percolation through the oceanic lithosphere. Under these conditions, the localized rapid crystallization of olivine from primitive basalt near the reaction zone would allow the entrapment of melt inclusions with different isotopic composition.     

Martian mantle mineralogy investigated by the Lu–Hf and Sm–Nd systematics of shergottites

Chemical heterogeneities in the Martian mantle are believed to result from the crystallization of a magma ocean in the first 100 million years of its history. Shergottite meteorites from Mars are thought to retain a compositional record of such early differentiation and the resulting mineralogy at different depths. The coupled ¹⁷⁶Lu–¹⁷⁶Hf and ¹⁴⁷Sm–¹⁴³Nd isotope systematics in 9 shergottites are used here to investigate these issues. Three compositional groups in the shergottites display distinct isotope systematics. One group, commonly termed as depleted, is characterized by positive ¹⁷⁶Hf_i from + 46.2 to + 50.4 and ¹⁴³Nd_i from + 36.2 to + 39.1. Another, termed as enriched, has negative ¹⁷⁶Hf_i = − 16.5 to − 13.2 and ¹⁴³Nd_i = − 7.0 to − 6.5. The third group is intermediate between the depleted and enriched groups with positive ¹⁷⁶Hf_i = + 30.0 to + 33.4 and ¹⁴³Nd_i = + 16.9. Together, they describe mixing curves between ¹⁷⁶Hf/¹⁷⁷Hf, ¹⁴³Nd/¹⁴⁴Nd, Lu/Hf, and Sm/Nd, implying that they sample two distinct sources in the Martian mantle. All shergottites are characterized by (Sm/Nd)_source < (Sm/Nd)_sample, but (Lu/Hf)_source > (Lu/Hf)_sample. This decoupling can be explained by two successive partial melting episodes in the depleted shergottite source and localized in the Martian upper mantle. The genesis of shergottites can be modeled using non-modal equilibrium partial melting in a source initially composed of 60% olivine, 21% clinopyroxene, 9% orthopyroxene, and 10% garnet, with degrees of partial melting of 8.8% and 3.9%, respectively, for the two successive events. The enriched end-member of the shergottite mixing curve is best modeled by late-stage quenched residual melt resulting from the crystallization of a magma ocean. The depleted shergottite source may be modeled as a mixture of cumulates and residual melt, as convection in the Martian magma ocean is expected to reduce the incompatible trace element heterogeneity in the final solidified layers. Consequently, equilibrium crystallization is preferred to model the crystallization of the Martian magma ocean. The models that best explain the shergottite data are those where the magma ocean is at a depth of at least 1350 km in Mars.     

Noble gas systematics of the Réunion mantle plume source and the origin of primordial noble gases in Earth’s mantle

New noble gas data of ultramafic xenoliths from Réunion Island, Indian Ocean, further constrain the characteristics of primordial and radiogenic noble gases in Earth’s mantle plume reservoirs. The mantle source excess of nucleogenic ²¹Ne is significantly higher than for the Hawaiian and Icelandic plume reservoirs, similar to excess of radiogenic ⁴He. ⁴⁰Ar/³⁶Ar of the Réunion mantle source can be constrained to range between 8000 and 12 000, significant ¹²⁹Xe and fission Xe excess are present. Regarding the relative contribution of primordial and radiogenic rare gas nuclides, the Réunion mantle source is intermediate between Loihi- and MORB-type reservoirs. This confirms the compositional diversity of plume sources recognized in other radioisotope systematics. Another major result of this study is the identification of the same basic primordial component previously found for the Hawaiian and Icelandic mantle plumes and the MORB reservoir. It is a hybrid of solar-type He and Ne, and ‘atmosphere-like’ or ‘planetary’ Ar, Kr, Xe (Science 288 (2000) 1036). ²⁰Ne/²²Ne ratios extend to maximum values close to 12.5 (Ne-B), which is the typical signature of solar neon implanted as solar corpuscular radiation. This suggests that Earth’s solar-type noble gas inventory was acquired by small (less than km-sized) precursor planetesimals that were irradiated by an active early sun in the accretion disk after nebular gas dissipation, or, alternatively, that planetesimals incorporated constituents irradiated in transparent regions of the solar nebula. Previously, such an early irradiation scenario was suggested for carbonaceous chondrites which follow common volatile depletion trends in the sequence CI–CM–CV–Earth. In turn, CV chondrites closely match Earth’s mantle composition in ²⁰Ne/²²Ne, ³⁶Ar/²²Ne and ³⁶Ar/³⁸Ar. This indicates that mantle Ar could well be a planetary component inherited from precursor planetesimals. However, a corresponding conclusion for mantle Kr and Xe is less convincing yet, but this may be just due to the lack of appropriate ‘meteoritic’ building blocks matching terrestrial composition. Alternatively, heavy noble gases in Earth’s mantle could be due to admixing of severely fractionated air, but this effect must have affected all mantle sources to a very similar extent, e.g. by global subduction before the last homogenization of the mantle reservoirs.     

He,Ne and Ar isotopic composition of Fe-Mn crusts from the western and central Pacific Ocean and implications for their genesis

The noble gas nuclide abundances and isotopic ratios of the upmost layer of Fe-Mn crusts from the western and central Pacific Ocean have been determined. The results indicate that the He and Ar nu- clide abundances and isotopic ratios can be classified into two types: low 3He/4He type and high 3He/4He type. The low 3He/4He type is characterized by high 4He abundances of 191×10-9 cm3·STP·g-1 on average, with variable 4He, 20Ne and 40Ar abundances in the range (42.8―421)×10-9 cm3·STP·g-1, (5.40―141)×10-9 cm3·STP·g-1, and (773―10976)×10-9 cm3·STP·g-1, respectively. The high 3He/4He samples are characterized by low 4He abundances of 11.7×10-9 cm3·STP·g-1 on average, with 4He, 20Ne and 40Ar abundances in the range of (7.57―17.4)×10-9 cm3·STP·g-1, (10.4―25.5)×10-9 cm3·STP·g-1 and (5354―9050)×10-9 cm3·STP·g-1, respectively. The low 3He/4He samples have 3He/4He ratios (with R/RA ratios of 2.04―2.92) which are lower than those of MORB (R/RA=8±1) and 40Ar/36Ar ratios (447―543) which are higher than those of air (295.5). The high 3He/4He samples have 3He/4He ratios (with R/RA ratios of 10.4―12.0) slightly higher than those of MORB (R/RA=8±1) and 40Ar/36Ar ratios (293―299) very similar to those of air (295.5). The Ne isotopic ratios (20Ne/22Ne and 21Ne/22Ne ratios of 10.3―10.9 and 0.02774―0.03039, respectively) and the 38Ar/36Ar ratios (0.1886―0.1963) have narrow ranges which are very similar to those of air (the 20Ne/22Ne, 21Ne/22Ne, 38Ar/36Ar ratios of 9.80, 0.029 and 0.187, respectively), and cannot be differentiated into different groups. The noble gas nuclide abundances and isotopic ratios, together with their regional variability, suggest that the noble gases in the Fe-Mn crusts originate primarily from the lower mantle. The low 3He/4He type and high 3He/4He type samples have noble gas characteristics similar to those of HIMU (High U/Pb Mantle)- and EM (Enriched Mantle)-type mantle material, respectively. The low 3He/4He type samples with HIMU-type noble gas isotopic ratios occur in the Magellan Seamounts, Marcus-Wake Seamounts, Marshall Island Chain and the Mid-Pacific Sea- mounts whereas the high 3He/4He type samples with EM-type noble gas isotopic ratios occur in the Line Island Chain. This difference in noble gas characteristics of these crust types implies that the MagellanSeamounts, Marcus-Wake Seamounts, Marshall Is- land Chain, and the Mid-Pacific Seamounts originated from HIMU-type lower mantle material whereas the Line Island Chain originated from EM-type lower mantle material. This finding is consistent with varia- tions in the Pb-isotope and trace element signatures in the seamount lavas. Differences in the mantlesource may therefore be responsible for variations in the noble gas abundances and isotopic ratios in the Fe-Mn crusts. Mantle degassing appears to be the principal factor controlling noble gas isotopic abundances in Fe-Mn crusts. Decay of radioactive isotopes has a negligible influence on the nuclide abundances and isotopic ratios of noble gases in these crusts on the timescale of their formation.     

Osmium-strontium-neodymium-lead isotopic covariations in mid-ocean ridge basalt glasses and the heterogeneity of the upper mantle

Osmium, strontium, neodymium, and lead isotopic data have been obtained for 30 hand picked samples of basaltic glass from the Pacific, Atlantic and Indian mid-oceanic ridges. Large variations in Os isotopic ratios exist in the glasses, from abyssal peridotite-like values to radiogenic compositions similar to oceanic island basalts (¹⁸⁷Os/¹⁸⁶Os and ¹⁸⁷Os/¹⁸⁸Os ratios range from 1.06 to 1.36 and from 0.128 to 0.163, respectively). Os isotopic and elemental data suggest the existence of mixing correlations. This relationship might be ascribed to secondary contamination processes; however, such a hypothesis cannot account for the negative correlation observed between Os and Nd isotopes and the existence of complementary covariations between Os and SrPb isotopes. In this case, OsSrNdPb isotopic variations are unrelated to late post-eruption or shallow level contamination. These relationships provide strong evidence that the Os isotopic composition of the samples are derived from the mantle and thus implies a global chemical heterogeneity of the oceanic upper mantle. The results are consistent with the presence of recycled oceanic crust in the mantle sources of mid-ocean ridge basalts, and indicate that the unique composition of the upper mantle below the Indian ocean results from its contamination by a mantle component characterized by radiogenic Os and particularly unradiogenic Nd and Pb isotopic compositions.     

峨眉山超级地幔柱对四川盆地烃源岩热演化的影响

四川盆地的构造、热演化与峨眉山超级地幔柱有密切关系.峨眉山超级地幔柱对四川盆地中二叠统之下的烃源岩热演化有着十分重要的影响.在四川盆地热历史恢复的基础上,研究了峨眉山超级地幔柱对盆地内烃源岩,特别是中二叠统之下的古生界烃源岩热演化的影响.结果表明,中二叠统及下伏烃源岩的热演化受中晚二叠世发生在盆地西南方向的峨眉山超级地幔柱的影响巨大,且具地区差异性.即在靠近峨眉山地幔柱中心的地区,有机质迅速成熟并达到其成熟度的最高值(以H1井为代表),古生界烃源岩迅速进入过成熟,此后未有二次生烃;而远离峨眉山地幔柱的盆地大部分地区,古生界烃源岩在二叠纪以来具有多次生烃过程.中生界烃源岩热演化,主要和前陆盆地阶段的构造过程包括前陆沉积和断裂的逆冲推覆等相关. 在烃源岩有机质成熟度演化史的基础上,从盆地热史和烃源岩热演化的角度指出了下二叠统及之下烃源层在四川盆地不同地区油气勘探中的不同意义.     

Characteristics of mantle degassing and deep-seated geological structures in different typical fault zones of China

Large-scale fault zones play an important role in controlling and adjusting all kinds of geological proc-esses,such as deposition,magmatism,metamorphism,metallogenesis,tectonic stress field,tectonic deforma-tion,even the movement of geological massifs,earth-quakes,and they also are the key to solving geological problems concerned,especially regional and even global structures.Due to their special geological tec-tonic significance,they are one of the main research fields of tectonic geology and …     

Study of the closure temperature of (U-Th)/He in detrital zircon obtained from natural evolution samples

Zircon(U-Th)/He thermochronometry was used as an effective indicator to study the thermal history of deep sedimentary basins with high temperatures.Zircon He ages and closure temperatures are very important parameters.In this paper,detrital zircon He closure temperature was studied by establishing the evolutionary pattern between zircon He ages and burial depth of borehole samples obtained from the Cenozoic strata in the Bohai Bay and Tarim basins,which have different thermal settings.The results show that the zircon He closure temperature of natural evolution samples is 200℃,which is higher than the temperature obtained from thermal simulation experiments(183℃).The temperature range of 140-200℃corresponds to the zircon helium partial retention zone.By properly understanding zircon He closure temperatures,zircon(U-Th)/He thermochronometry can provide a correct explanation of the He ages,and significant guidance in the study of the evolution of source rocks and the process of hydrocarbon accumulation in deep sedimentary basins.     

Petrogenetic significance of high Fe/Mn ratios of the Cenozoic basalts from eastern China

The Cenozoic basalts from eastern China show commonly high Fe/Mn ratios (average = 68.6 ± 11.5) coupled with OIB-type trace element signature. The Cenozoic basalts form the northern margin and the southern margin of the North China Craton are studied in detail. Model calculations point out that the coupling feature of high Fe/Mn ratio with OIB-type trace element signature of these basalts cannot be produced by neither pyroxene/olivine crystallization nor remelting of previously melted mantle, but require partial melting of a garnet pyroxenite-rich mantle source. Combining these features of the Cenozoic basalts with the Phanerozoic lithospheric evolution of the eastern China, we suggest that the Cenozoic basalts were derived from a garnet pyroxenite-rich mantle source associated with continental crust delamination or oceanic crust subduction.     

Si- and alkali-rich melt inclusions in minerals of mantle peridotites from eastern China: Implication for lithospheric evolution

CO2 fluid inclusions in mantle minerals are an im-portant source for us to get the information of mantle fluids. Fluid inclusions are mainly composed of CO2, with minor CO, H2O, CH4, N2, H2S, SO2, F, etc., which were demonstrated by lots of Raman spec-trometer analyses in recent years. In contrast, there are very few researches on CO2-bearing melt inclusions since it is more difficult to do so. The available studies have found that the primary CO2-bearing melt inclu-sions are basaltic …     

Transitions in the style of mantle convection at high Rayleigh numbers

The pattern and style of mantle convection govern the thermal evolution, internal dynamics, and large-scale surface deformation of the terrestrial planets. In order to characterize the nature of heat transport and convective behaviour at Rayleigh numbers, Ra, appropriate for planetary mantles (between 10⁴ and 10⁸), we perform a set of laboratory experiments. Convection is driven by a temperature gradient imposed between two rigid surfaces, and there is no internal heating. As the Rayleigh number is increased, two transitions in convective behaviour occur. First we observe a change from steady to time-dependent convection at Ra≈10⁵. A second transition occurs at higher Rayleigh numbers, Ra≈5×10⁶, with large-scale time-dependent flow being replaced by isolated rising and sinking plumes. Corresponding to the latter transition, the exponent β in the power law relating the Nusselt number Nu to the Rayleigh number (NuRa^β) is reduced. Both rising and sinking plumes always consist of plume heads followed by tails. There is no characteristic frequency for the formation of plumes.     

地幔对流拖曳力对中国大陆岩石层变形的影响

采用较为符合实际岩石层变形的非线性幂指数本构关系,基于ANSYS有限元平台, 模拟了近20万年来中国大陆地区地表运动及演化过程,探讨了印度板块挤压作用和地幔对流拖曳力各自对于中国大陆地区地表形变运动格局的影响.模拟结果与观测数据的比较表明：在印度板块的挤压和地幔拖曳力联合作用下,中国及东亚大陆岩石层运动形变模式能够和现代GPS观测有较好的吻合; 印度大陆和欧亚大陆的碰撞以及印度大陆的持续向北推进、挤压所产生的应力环境,一直主导了以青藏高原为核心的我国西部地域岩石圈构造、运动和演化,但其影响随着远离青藏高原地区而逐渐变小;地幔对流产生的作用于岩石层底部的拖曳力是中国大陆（特别是远离碰撞带）岩石层运动构造变形的重要驱动力.然而在构造复杂和东部靠近太平洋板块的区域,模型预测结果和GPS观测还存在一定的差距,这说明在未来的中国大陆岩石层变形运动的数值模拟中,应当采用更为复杂的构造模型和驱动力因素.     

A hafnium isotope and trace element perspective on melting of the depleted mantle

New Hf isotope and trace element data on mid-ocean ridge basalts (MORB) from the Pacific Ocean basin are remarkably uniform (¹⁷⁶Hf/¹⁷⁷Hf≈0.28313–0.28326) and comparable to previously published data [Salters, Earth Planet. Sci. Lett. 141 (1996) 109–123; Patchett, Lithos 16 (1983) 47–51]. Atlantic MORB have ¹⁷⁶Hf/¹⁷⁷Hf ranging from 0.28302 to 0.28335 confirming the wide range originally identified by Patchett and Tatsumoto [Geophys. Res. Lett. 7 (1980) 1077–1080]. Indian MORB define an even wider range, from 0.28277 to 0.28337, but three exotic samples have very unradiogenic Hf isotope compositions. Their very low ¹⁷⁶Hf/¹⁷⁷Hf ratios, together with their trace element characteristics, require the presence of unusual plume-type material beneath the Indian ridge. All other Indian MORB have uniform Hf isotope compositions at about 0.2832, and define a small field displaced to the right of other MORB in Hf–Nd isotope space. The distinct nature of Indian MORB is best explained by the presence in Indian depleted mantle of old recycled oceanic crust and pelagic sediments. Sm/Hf ratios calculated from new high-precision rare earth element and Hf trace element data do not vary in MORB in the same way as in ocean island basalts (OIB): ratios are constant in OIB, but decrease with increasing Sm contents in MORB. The constancy of Sm/Hf in OIB is probably due to an overwhelming influence of residual garnet during melting. By contrast, the decrease of Sm/Hf in MORB is due to the effect of clinopyroxene in the residue of melting beneath ridges, an interpretation confirmed by quantitative modeling of melting. The relationship between Sm/Nd and Lu/Hf ratios in MORB does not require the presence of garnet in the residual mineralogy. The decoupling of Lu/Hf ratios and Hf isotope compositions – the so-called Hf paradox [Salters and Hart, EOS Trans. Am. Geophys. Union 70 (1989) 510] – can be explained by melting dominantly in the spinel field at shallow depths beneath mid-ocean ridges.     

Temporal evolution of lead isotope ratios in sediments of the Central Portuguese Margin: A fingerprint of human activities

Stable Pb isotope ratios (²⁰⁶Pb/²⁰⁷Pb, ²⁰⁸Pb/²⁰⁶Pb), ²¹⁰Pb, Pb, Al, Ca, Fe, Mn and Si concentrations were measured in 7 sediment cores from the west coast of the Iberian Peninsula to assess the Pb contamination throughout the last 200 years. Independently of their locations, all cores are characterized by increasing Pb/Al rends not related to grain-size changes. Conversely, decreasing trends of ²⁰⁶Pb/²⁰⁷Pb were found towards the present. This tendency suggest a change in Pb sources reflecting an increased proportion derived from anthropogenic activities. The highest anthropogenic Pb inventories for sediments younger than 1950s were found in the two shallowest cores of Cascais and Lisboa submarine canyons, reflecting the proximity of the Tagus estuary. Lead isotope signatures also help demonstrate that sediments contaminated with Pb are not constrained to estuarine–coastal areas and upper parts of submarine canyons, but are also to transferred to a lesser extent to deeper parts of the Portuguese Margin.     

中国地幔结构及物性研究的进展

对2004——2007年中国地球物理学家在地幔内部结构和物质性质方面的研究工作进行了总结. 对地幔结构的地震波速度成像,地幔介质的各向异性,地幔间断面,地幔对流,以及地幔介质物性进行了综述,指出了各方面的主要内容,使用的主要方法和主要结果. 从这4年的研究可以发现,一些原有的研究领域工作更加深入,方法更加先进,而且进行了广泛的国际合作,合作的范围也逐渐扩大,方式多样,并出现了一些新的研究方向.      

Helium isotopes in early Iceland plume picrites: Constraints on the composition of high 3He/4He mantle

A detailed study of the geochemistry of a new suite of early Iceland plume picrites shows that extremely high ³He/⁴He ratios (up to 50 R_a) are found in picrites from Baffin Island and West Greenland. High ³He/⁴He picrites display a wide range in ⁸⁷Sr/⁸⁶Sr (0.70288–0.70403), ¹⁴³Nd/¹⁴⁴Nd (0.51288–0.51308) and incompatible trace element ratios (e.g. La/Sm_n = 0.5–1.6). These overlap the complete range of compositions of mid-ocean ridge basalts and most northern hemisphere ocean island basalts, including Iceland. Crustal contamination modelling in which high-grade Proterozoic crustal basement rocks for the region are mixed with a depleted parent cannot account for the trend displayed by the Baffin Island and West Greenland picrites. This rules out the possibility that the incompatible trace element, Sr and Nd isotope range of the high ³He/⁴He picrites is due to crustal contamination. The compositional range at high ³He/⁴He is also inconsistent with derivation from a primordial-He-rich reservoir that is a residue of ancient mantle depletion. This implies that the composition of the high ³He/⁴He mantle cannot be determined simply by extrapolating ocean island basalt He–Sr–Nd–Pb–Os isotope data.The apparent decoupling of He from trace element and lithophile radiogenic isotope tracers is difficult to attain by simple mixing of a high-[He], high ³He/⁴He reservoir with various depleted and enriched He-poor mantle reservoirs. The possibility that primordial He has diffused into a reservoir with a composition typical of convecting upper mantle cannot be ruled out. If so, the process must have occurred after the development of existing mantle heterogeneity, and requires the existence of a deep, primordial He-rich reservoir.     

Geochemistry of the oldest MORB and OIB in the Isua Supracrustal Belt, southern West Greenland: Implications for the composition and temperature of early Archean upper mantle

Abstract Recent geological investigations of the Isua Supracrustal Belt (3.8 Ga), southern West Greenland, have suggested that it is the oldest accretionary complex on earth, defined by an oceanic plate‐type stratigraphy and a duplex structure. Plate history from mid‐oceanic ridge through plume magmatism to subduction zone has been postulated from analysis of the reconstructed oceanic plate stratigraphy in the accretionary complex. Comparison between field occurrence of greenstones in modern and ancient accretionary complexes reveals that two types of tholeiitic basalt from different tectonic settings, mid‐oceanic ridge basalt (MORB) and oceanic island basalt (OIB), occur. This work presents major, trace and rare earth element (REE) compositions of greenstones derived from Isua MORB and OIB, and of extremely rare relict igneous clinopyroxene in Isua MORB. The Isua clinopyroxenes (Cpx) have compositional variations equivalent to those of Cpx in modern MORB; in particular, low TiO₂ and Na₂O contents. The Isua Cpx show slightly light (L)REE‐depleted REE patterns, and the calculated REE pattern of the host magma is in agreement with that of Isua MORB. Analyses of 49 least‐altered greenstones carefully selected from approximately 1200 samples indicate that Isua MORB are enriched in Al₂O₃, and depleted in TiO₂, FeO*, Y and Zr at the given MgO content, compared with Isua OIB. In addition, Isua MORB show an LREE‐depleted pattern, whereas Isua OIB forms a flat REE pattern. Such differences suggest that the Early Archean mantle had already become heterogeneous, depending on the tectonic environment. Isua MORB are enriched in FeO compared with modern MORB. Comparison of Isua MORB with recent melting experiments shows that the source mantle had 85–87 in Mg? and was enriched in FeO. Potential mantle temperature is estimated to be approximately 1480°C, indicating that the Early Archean mantle was hotter by at most approximately 150°C than the modern mantle.     

He and Ne isotopes in oceanic crust: implications for noble gas recycling in the mantle

In an attempt to determine the helium and neon isotopic composition of the lower oceanic crust, we report new noble gas measurements on 11 million year old gabbros from Ocean Drilling Program site 735B in the Indian Ocean. The nine whole rock samples analyzed came from 20 to 500 m depth below the seafloor. Helium contents vary from 3.3×10⁻¹⁰ to 2.5×10⁻⁷ ccSTP/g by crushing and from 5.4×10⁻⁸ to 2.4×10⁻⁷ ccSTP/g by melting. ³He/⁴He ratios vary between 2.2 and 8.6 Ra by crushing and between 2.9 and 8.2 by melting. The highest R/Ra ratios are similar to the mean mid-ocean ridge basalt (MORB) ratio of 8±1. The lower values are attributed to radiogenic helium from in situ α-particle production during uranium and thorium decay. Neon isotopic ratios are similar to atmospheric ratios, reflecting a significant seawater circulation in the upper 500 m of exposed crust at this site. MORB-like neon, with elevated ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios, was found in some high temperature steps of heating experiments, but with very small anomalies compared to air. These first results from the lower oceanic crust indicate that subducted lower oceanic crust has an atmospheric ²⁰Ne/²²Ne ratio. Most of this neon must be removed during the subduction process, if the ocean crust is to be recirculated in the upper mantle, otherwise this atmospheric neon will overwhelm the upper mantle neon budget. Similarly, the high (U+Th)/³He ratio of these crustal gabbros will generate very radiogenic ⁴He/³He ratios on a 100 Ma time scale, so lower oceanic crust cannot be recycled into either MORB or oceanic island basalt without some form of processing.