Sedimentology and paleoenvironmental evolution of Messinian evaporites in the Iskenderun-Hatay basin complex, Southern Turkey

Messinian evaporites, which resulted from the salinity crisis during the final closure of the Mediterranean Sea, are exposed in SE Turkey. These evaporites formed in two isolated sub-basins, Iskenderun-Arsuz (IA) and Hatay-Samanda? (HS), which belong to different depositional configurations and tectonic structures. The Neogene fill of these sub-basins consists of a thick sedimentary succession that started with Early Miocene terrestrial clastics, followed by reefs (Middle Miocene) and shallow water siliciclastics (Tortonian - Early to Late Miocene) and finally Messinian evaporates. These sub-basins accumulated in a diverse range of depositional environments from very shallow to deeper water. Evaporite facies in the IA sub-basin consist of sabkhas, saline lagoons and ponds. They are mainly represented by chemical deposits such as scattered gypsum nodules and balls, nodular bedded gypsum, laminated gypsum (Type-A) and selenites (Type-S1). Evaporites in the HS sub-basin mainly consist of detrital gypsum composed of gypsum laminae (Type-B, C), gypsum arenite-rudites and deeper water selenites (≤ 20 m), and resedimented selenites (Type-S2), which were deposited on a sulfate platform with a slope-basin transitional zone. Secondary gypsum with alabastrine and porphyroblastic textures as well as satin spar veins is commonly associated with the sabkha-type evaporites of the IA sub-basin. Deeper-water clastic evaporites of the HS sub-basin have generally remained as primary gypsum or have only been slightly affected by diagenetic alterations. The isotope values (^87/86Sr; δ¹⁸O SMOW; and δ³⁴S CDT) from the different kinds of gypsum lithofacies of the sub-basin are similar to those of the Messinian evaporites in other peri-Mediterranean basins, indicating an origin from marine water without external or basinal contributions.The Messinian evaporites examined in this paper are overlain by Early Pliocene (Zanclean) deposits composed of shallow- and deep-water siliciclastics and carbonates with local intercalations of Lago-Mare-type strata. Throughout the Messinian evaporitic stage, the IA sub-basin was mainly comprised of shallow water evaporites, while the HS sub-basin underwent deepening related to regional tectonics induced by the Dead Sea Fault during the construction of the Hatay Graben.     

Depositional environments and facies of the Late Triassic Abu Ruweis Formation, Jordan

The Abu Ruweis Formation is composed of carbonates, evaporites, and mudstones, with some locally developed pelletic, oolitic and stromatolitic limestones. The lateral persistence of bedding, the purity of the evaporite rocks, the alternating arrangement of marine carbonates and evaporites indicates periodic deposition in subaqueous conditions (salina). Petrographic investigations, X-ray diffraction analysis as well as chemical analysis have shown that the outcropping evaporite beds are mainly composed of secondary gypsum, with rare anhydrite relics. Five microfacies of gypsum were recognized according to their fabrics: porphyroblastic and granoblastic gypsum showing polarization texture, gypsum pseudomorph after anhydrite laths, and satin spar gypsum. The textures they display indicate a hydration origin of precursor anhydrite, which is in turn rehydrated from primary gypsum. Some of these anhydrites were formed as a result of replacement processes of the carbonate sediments associated with the evaporites, as evidenced from the textural relationships of the carbonate and sulfate minerals. The O¹⁸ content ranges from 1.45 to 8.38% PDB and the C¹³ content ranges from −1.52 to 4.73% PDB. Trace elements analysis has shown that the Abu Ruweis dolomites are rich in strontium (up to 600 ppm), and sodium (up to 835 ppm). The isotope composition and trace elements content, as well as the petrographic characteristics point to a penecontemporaneous hypersaline dolomitization origin for the Abu Ruweis dolomites. The evaporites were deposited during a regressive lowstand systems tract, whereas the carbonates were deposited under shallow water marine conditions during a highstand systems tract. The Abu Ruweis succession represents a relatively stable arid climate within a rapidly subsiding basin. Restricted conditions were provided by the development of beach barriers.     

Diagenetic evolution of Aptian evaporites in the Namibe Basin (south‐west Angola)

The widespread and dissected nature of the Angolan gypsiferous salt residuals offers a uniquely detailed view of the lateral and vertical relations inherent to secondary evaporite textures, which typify exhumed salt masses worldwide. Such secondary textures are sometimes misinterpreted as primary evaporite textures. Thin, metre‐scale and patchy, dome‐like gypsum accumulations are well‐exposed within strongly incised present‐day river valleys along the eastern margin of the Namibe and Benguela basins (south‐west Angola). These sections are time equivalent to the main basinward subsurface evaporites (Aptian Loeme Formation) which mostly consist of halite. The gypsum (here called the Bambata Formation) is interpreted to represent the final residual product of fractional dissolution and recrystallization of the halite mass that occurred during Late Cretaceous margin uplift and continues today. This halite underwent multiple episodes of diagenetic alteration between its deposition and its final exhumation, leading to the formation of various secondary gypsum fabrics and solution‐related karst and breccia textures that typify the current evaporite outcrop. Four different diagenetic gypsum fabrics are defined: thinly bedded alabastrine, nodular alabastrine, displacive selenite rosettes and fibrous satin‐spar gypsum. Current arid conditions are responsible for a thin weathered crust developed at the top of the outcropping gypsum, but the fabrics in the main core of the current at‐surface evaporite unit mostly formed during the telogenetic stage of uplift prior to complete subaerial exposure. Alteration occurred as various dissolving and rehydrating saline minerals encountered shallow aquifers in the active phreatic and vadose zones. Geomorphological and petrographic analyses, mostly based on the cross‐cutting relations and crystallographic patterns in the outcrop, are used to propose a sequence of formation of these different fabrics.     

Study of a Neogene basin dynamics: The “Bizerte basin”, northeastern Tunisia: relevance to the global Messinian Salinity Crisis

The Messinian sediments of northeastern Tunisia were deposited under an active tectonic setting. They are organized in sequences indicating a transitional deposit from margin – littoral to lacustrine – continental facies. These series unconformably overlie the Serravallian–Tortonian silty clays packages, and are overlain by the transgressive Early Pliocene marl (Zanclean). The presence of evaporitic strata points out to the Messinian Salinity Crisis described in the peripheral basins of the western Mediterranean. The Messinian sedimentation was found to have been closely controlled by transtensive tectonics and differential subsidence at a large spatio-temporal scale. It is organized in sequences typical of a depositional environment controlled by eustatism, tectonic and maybe by climate changes. Despite the existence of some local specific sedimentological characteristics, our results corroborate previous findings that pointed out to the Messinian times as a singular period all around the Mediterranean Basin. Field and subsurface seismic profile data helped reconstructing either the sedimentary or tectonic unconformities existing between the studied Messinian series and older Neogene successions.     

The partitioning of seawater cations during the transformation of gypsum to anhydrite

The coprecipitation of Sr, Mg, Na and K with anhydrite during the dehydration of gypsum was studied in laboratory experiments. The partition coefficients of Mg and Sr between anhydrite and solution decrease with increasing temperature. The partition coefficients of the alkali-ions do not depend upon temperature, but are affected by the brine composition.The mechanism of the phase transformation gypsum → anhydrite occurs via dissolution and precipitation, when the coprecipitated-ions are repartitioned between the new phase and the solution. The partition coefficients established in this study are applicable also for primary anhydrite.During the dehydration of gypsum at elevated temperatures metastable bassanite may form as an intermediate stage. The amount of cations coprecipitated with bassanite is much larger than the amount coprecipitated with anhydrite or gypsum. This phenomenon may have an influence on the partitioning of cations during the dehydration of gypsum, particularly on Sr.The partition coefficients of seawater cations between anhydrite and the brine are similar to those between gypsum and the brine. For this reason the coprecipitated-ions are not expected to be good indicators to distinguish between primary and secondary calcium sulfate minerals.The temperature effect on the coprecipitation of Mg and Sr with anhydrite makes these ions possible indicators for the temperature at which the phase transformation occurred. This temperature corresponds to the depth of burial of the gypsum at the stage of dehydration.The coprecipitation of seawater cations with anhydrite in the natural environment was studied in two systems: A small Pleistocene evaporite lens from the Sinai Peninsula and the Triassic anhydrite of the Mohilla Formation, Israel. The coprecipitated-ion composition of these samples was used to derive the conditions under which the anhydrite was formed.     

Algal crusts, autochthonous and clastic gypsum in a cannibalistic evaporite basin: a case history from the Messinian of Northern Apennines

The Messinian Vena del Gesso Basin in the Northern Apennines is filled by very thick (up to 35 m) beds of coarse crystalline gypsum (selenite) associated with thinner carbonate and shaly (euxinic) intercalations. The conventional Usiglio model of salt fractionation does not apply to this evaporitic sequence for the following reasons: carbonate which underlies gypsum is not evaporitic but algal in origin; most gypsum did not precipitate from surface brines but at and below a sediment-water interface occupied by algal mats; a significant portion (10–80%) of gypsum beds is composed of redeposited selenite which was removed from the margins and transported toward the centre of the basin by slope-controlled currents and gravity flows (debris flows). We call this process cannibalistic because of its intraformational character (connected with evaporative fall of water level) and volumetric importance. A recurrent vertical pattern of six main facies (euxinic to gypsum fanglo-merates) is interpreted as a bathymetric, regressive cycle controlled by both sedi-mentological and tectonic-eustatic factors. The inferred environmental setting is a residual turbidite trough (Marnoso-arenacea) evolving abruptly toward lagoonal conditions and filled up to sea level by evaporitic and mechanical (mostly fluvial) processes. Repeated inundations of restricted-marine water started the depositional cycle thirteen or fourteen times.     

Depositional environments of Upper Miocene (Messinian) evaporite deposits of the Sicilian Basin*

In Sicily, Messinian evaporitic sedimentary deposits are developed under a wide variety of hypersaline conditions and in environments ranging from continental margin (subaerial), to basin-margin supratidal, to intertidal, to subtidal and out into the hypersaline basin proper. The actual water depth at the time of deposition is indeterminate; however, relative terms such as ‘wave base’ and ‘photic zone’ are utilized. The inter-fingering relationships of specific evaporitic facies having clear and recognizable physical characteristics are presented. These include sub-aerial deposits of nodular calcium sulphate formed displacively within clastic sediments; gypsiferous rudites, arenites and arenitic marls, all of which are reworked sediments and are mixed in varying degrees with other clastic materials (subaerial, supratidal, and intertidal to deep basinal deposits). Laminated calcium sulphate alternating with very thin carbonate interlaminae and having two different aspects; one being even and continuous and the other of a wavy, irregular appearance (subtidal, intertidal, and supratidal deposits). Nodular calcium sulphate beds, usually associated with wavy, irregular laminated beds (supratidal, sabkha deposits); very coarsely crystalline gypsum beds (selenite), associated with more even, laminated beds (subaqueous, intertidal to subtidal deposits); wavy anastomozing gypsum beds, composed of very fine, often broken crystals (subaqueous, current-swept deposits); halite having hopper and chevron structures (supratidal to intertidal); and halite, potash salts, etc. having continuous laminated structure (subaqueous, possibly basinal). Evidence for diagenetic changes is observed in the calcium sulphate deposits which apparently formed by tectonic stress and also by migrating hypersaline waters. These observations suggest that the common, massive form of alabastrine gypsum (or anhydrite, in the subsurface) may not always be ascribed to original depositional features, to syndiagenesis or to early diagenesis but may be the result of late diagenesis.     

The uppermost deposits of the stratigraphic succession of the Farafra Depression (Western Desert,Egypt): Evolution to a Post-Eocene continental event

This paper gives insight into continental sedimentary deposits that occur at the uppermost part of the stratigraphic succession present in the north-eastern sector of the Farafra Depression (Western Desert, Egypt). Using space imagery to complete the field work, the geology of the area has been mapped and the presence of a N–S oriented fault system is documented. The analysis of the morphotectonic features related to this fault system allows reconstructing the structural and sedimentological evolution of the area. The study indicates that the continental deposits were accumulated in alluvial systems that unconformably overlie shale and evaporitic rocks attributable to the Paleocene–Eocene Esna Formation. The deposits of the Esna Formation show soft-sediment deformation features, which include slump associated to dish and pillar sedimentary structures and provide evidence of syndepositional tectonic activity during the sedimentation of this unit. The outcrops are preserved in two areas on separated fault-bounded blocks. Proximal alluvial fan facies crop out in a dowthrown block close to the depression boundary. The proximal facies are made up mostly by polymictic conglomerates which occasionally contain boulders. The conglomerate clasts are mainly quartz, carbonate, anhydrite satin spar vein, mudrock, ironstone and nummulite fossils. The mid-fan facies consist of trough cross-bedded, rippled and cross-laminated quartzarenites with reworked glauconite grains and carbonate rock fragments, interpreted as deposited by distributary streams. The distal alluvial fan deposits consist of sandy marls that evolve toward the top of the sections into root-bioturbated lacustrine limestone beds that are locally silicified. The limestones are biomicrites containing characea, ostracods and gastropods with fenestral porosity.A number of features, including clast provenance (mainly from marine Paleocene and Eocene rocks), the observed fractural pattern (N–S direction related to the opening of the Red Sea), and the sedimentary relationships, suggests that the continental deposits were accumulated during the Oligocene–Miocene interval.     

Late-stage calcites in the Permian Capitan Formation and its equivalents, Delaware Basin margin, west Texas and New Mexico: evidence for replacement of precursor evaporites

Comparison of Upper Guadalupian fore-reef, reef and back-reef strata from outcrops in the Guadalupe Mountains with equivalent subsurface cores from the northern and eastern margins of the Delaware Basin indicates that extensive evaporite diagenesis has occurred in both areas. In both surface and subsurface sections, the original sediments were extensively dolomitized and most primary and secondary porosity was filled with anhydrite. These evaporites were emplaced by reflux of evaporitic fluids from shelf settings through solution-enlarged fractures and karstic sink holes into the underlying strata. Outcrop areas today, however, contain no preserved evaporites in reef and fore-reef sections and only partial remnants of evaporites are retained in back-reef settings. In their place, these rocks contain minor silica, very large volumes of coarse sparry calcite and some secondary porosity. The replacement minerals locally form pseudomorphs of their evaporite precursors and, less commonly, contain solid anhydrite inclusions. Some silicification, dissolution of anhydrite and conversion of anhydrite to gypsum have occurred in these strata where they are still buried at depths in excess of 1 km; however, no calcite replacements were noted from any subsurface core samples. Subsurface alteration has also led to the widespread, late-stage development of large- and small-scale dissolution breccias. The restriction of calcite cements to very near-surface sections, petrographic evidence that the calcites post-date hydrocarbon emplacement, and the highly variable but generally ‘light’carbon and oxygen isotopic signatures of the spars all indicate that calcite precipitation is a very late diagenetic (telogenetic) phenomenon. Evaporite dissolution and calcitization reactions have only taken place where Permian strata were flushed with meteoric fluids as a consequence of Tertiary uplift, tilting and breaching of regional hydrological seals. A typical sequence of alteration involves initial corrosion of anhydrite, one or more stages of hydration/dehydration during conversion to gypsum, dissolution of gypsum and precipitation of sparry calcite. Such evaporite dissolution and replacement processes are probably continuing today in near-outcrop as well as deeper settings. This study emphasizes the potential importance of telogenetic processes in evaporite diagenesis and in the precipitation of carbonate cements. The extensive mineralogical and petrophysical transformations which these strata have undergone during their uplift indicates that considerable caution must be exercised in using surface exposures to interpret subsurface reservoir parameters in evaporitic carbonate rocks.     

Messinian deposits and erosion in northern Tunisia: inferences on Strait of Sicily during the Messinian Salinity Crisis

Outcrops, offshore wells, electric logs and seismic profiles from northern Tunisia provide an opportunity to decipher the Messinian Salinity Crisis in the Strait of Sicily. Messinian deposits (including gypsum beds) near the Tellian Range reveal two successive subaerial erosional surfaces overlain by breccias and marine Zanclean clays, respectively. In the Gulf of Tunis, Messinian thick evaporites (mostly halite) are strongly eroded by a fluvial canyon infilled with Zanclean clays. The first erosional phase is referred to the intra-Messinian tectonic phase and is analogous to that found in Sicily. The second phase corresponds to the Messinian Erosional Surface that postdates the marginal evaporites, to which the entire Sicilian evaporitic series must refer. The Western and Eastern Mediterranean basins were separated during deposition of the central evaporites.     

Silicification and dolomitization of anhydrite nodules in argillaceous terrestrial deposits: an example of meteoric-dominated diagenesis from the Triassic of central Spain

Cauliflower-shaped nodules are widespread in a single red mudstone bed in the Buntsandstein (Triassic) facies of the Iberian Range. They consist mostly of quartz, dolomite and calcite, but other minerals, such as barite, kaolinite and iron oxyhydroxides, are also present. The nodules are spherical, ovoid or elongate in shape and range from 1 to 8 cm across. The surface of the nodules is irregular, and some show a pedogenic coating of microspar. The sedimentological and petrographic data suggest that the initial anhydrite nodules formed through a progressive increase in the porewater concentration of Ca²⁺ and SO₄^2– in a vadose environment, occasionally under the influence of pedogenic processes. Partial replacement of the anhydrite by megaquartz occurred under more dilute conditions in the same type of setting, as indicated by the presence of organic filaments on the quartz crystal surfaces. In type A nodules, the dissolution of the innermost anhydrite was complete, and different types of quartz cement filled the porosity. Fracturing and meteoric cementation by calcite and minor amounts of kaolinite were the latest processes affecting these nodules. In type B nodules, the dissolution of the anhydrite was incomplete, inhibiting quartz cementation and enabling later dolomitization of the anhydrite. Dolomitization appears to have been driven by sulphate reduction, as indicated by the presence of bacterial bodies within the dolomite crystals. Dedolomitization and precipitation of barite, kaolinite and calcite spar cements occurred later under the influence of meteoric solutions. The nodules may mark the former locations of the water table and provide evidence for an episode of highly evaporitic conditions throughout wide areas of the basin. Their occurrence reveals not only a complex diagenetic history but is also indicative of palaeogeographic and palaeoclimatic conditions.     

Sulphate–borate relations in an evaporitic lacustrine environment: the Sultançayir Gypsum (Miocene, western Anatolia)

Calcium-borates, mainly pandermite (priceite) and howlite, but also bakerite and colemanite, are intercalated within the Sultançayir Gypsum (Miocene, Sultançayir Basin, western Anatolia). This lacustrine unit, represented by secondary gypsum in outcrop, is characterized by: (1) a clear facies distribution of depocentral laminated lithofacies and debris-flow deposits, a wide marginal zone of sabkha deposits, and at least one selenitic shoal located toward the basin margin; (2) evaporitic cycles displaying a shallowing-upward trend; and (3) a diagenetic evolution of primary gypsum to (burial) anhydrite followed by its final re-hydration. The calcium borates precipitated only in the depocentre of the lake and were partly affected by synsedimentary reworking, indicating that they formed during very early diagenesis. The lithofacies, which are made up of a host gypsum (finely laminated) and borates (nodules, irregular masses and discontinuous bands; also fine laminations), indicate that the borates grew interstitially because of the inflow and mixing of borate-rich solutions with basinal brines. Borate growth displaced and replaced primary gypsum beneath a relatively deep depositional floor. Borate formation as free precipitates was much less common. The anhydritization of primary gypsum took place during early to late diagenesis (burial <250 m deep). This process also resulted in partial replacement of pandermite and accompanying borates (bakerite and howlite) as well as other early diagenetic minerals (celestite) by anhydrite. Final exhumation resulted in the replacement of anhydrite by secondary gypsum, and in the partial transformation of pandermite and howlite into secondary calcite.     

Evaporative systems and diagenetic patterns in the Calatayud Basin (Miocene,central Spain)

This paper concerns the evaporite units, depositional systems, cyclicity, diagenetic products and anhydritization patterns of the Calatayud Basin (nonmarine, Miocene, central Spain). In outcrop, the sulphate minerals of these shallow lacustrine evaporites consist of primary and secondary gypsum, the latter originating from the replacement of anhydrite and glauberite. In the evaporative systems of this basin, gypsiferous marshes of low salinity can be distinguished from central, saline lakes of higher salinity. In the gypsiferous marsh facies, the dominant, massive, bioturbated gypsum was partly replaced by synsedimentary chert nodules and siliceous crusts. In the saline lake facies, either cycles of gypsiferous lutite‐laminated gypsarenite or irregular alternations of laminated gypsum, nodular and banded glauberite, thenardite and nodular anhydrite precipitated. Early replacement of part of the glauberite by anhydrite also occurred. Episodes of subaerial exposure are represented by: (1) pedogenic carbonates (with nodular magnesite) and gypsiferous crusts composed of poikilitic crystals; and (2) nodular anhydrite, which formed in a sabkha. Additionally, meganodular anhydrite occurs, which presumably precipitated from ascending, highly saline solutions. The timing of anhydritization was mainly controlled by the salinity of the pore solutions, and occurred from the onset of deposition to moderate burial. Locally, a thick (>200 m) sequence of gypsum cycles developed, which was probably controlled by climatic variation. A trend of upward‐decreasing salinity is deduced from the base to the top of the evaporite succession.     

Isotope geochemistry, petrology and depositional environments of the diatomite-dominated Tripoli Formation (Lower Messinian), Sicily

ABSTRACT The Tripoli Formation (Lower Messinian) in Sicily includes diatomites irregularly alternating with marl and carbonate beds and lies, stratigraphically, between the Tortonian pelagic marls and the evaporitic Calcare di base. The relationships between mineralogy, textural features and oxygen-carbon isotopic compositions of carbonate components point to a wide variability of depositional conditions and suggest that Tripoli sedimentation occurred in small basins characterized by periodic and marked restriction from the open sea.
The isotopic values of calcite and dolomite in the diatomites suggest an evolution from normal marine towards more restricted environments. Evaporating conditions are also indicated by the occurrence of anhydrite, length-slow chalcedonic quartz and moulds of gypsum. In a more advanced stage, the precipitation of heavy δ¹⁸0 dolomite in the interstitial pores of fossil-poor diatomites denotes an environment with highly evaporated water. Mixing of meteoric and marine waters, on the other hand, might have favoured the precipitation of a dolomite characterized by relatively low δ¹⁸0 and δ¹³C values.
The deposition of marl and carbonate beds alternating with or overlying the diatomites took place in an environment with highly evaporated marine waters on the basis of δl¹⁸O values of dolomite (up to + 9.10‰) and aragonite (up to + 5.83‰), occurrence of evaporitic minerals and lack of fossils. The presence at these levels of calcite with extremely negative δ¹³C values (down to - 38.40‰), filling gypsum moulds, suggests activity of sulphate-reducing bacteria. Some aragonitic marls, however, bear evidence of deposition in relatively normal marine conditions.     

New aspects and perspectives on tsavorite deposits

Tsavorite, the vanadian variety of green grossular, is a high value economic gemstone. It is hosted exclusively in the metasedimentary formations from the Neoproterozoic Metamorphic Mozambique Belt. The deposits are mined in Kenya, Tanzania and Madagascar and other occurrences are located in Pakistan and East Antarctica. They are located within metasomatized graphitic rocks such as graphitic gneiss and calc-silicates, intercalated with meta-evaporites. Tsavorite is found as primary deposits either in nodule (type I) or in quartz vein (type II), and in placers (type III). The primary mineralizations (types I and II) are controlled by lithostratigraphy and/or structure. For the African occurrences, the protoliths of the host-rocks were deposited at the beginning of the Neoproterozoic within a marine coastal sabkha environment, located at the margin of the Congo–Kalahari cratons in the Mozambique Ocean. During the East African–Antarctican Orogeny, the rocks underwent high amphibolite to granulite facies metamorphism and the formation of tsavorite deposits occurred between 650 and 550 Ma. The nodules of tsavorite were formed during prograde metamorphism, calcium coming from sulphates and carbonates, whereas alumina, silicates, vanadium and chromium probably came from clays and chlorite. The veins were formed during the deformation of the metasedimentary platform units which experienced shearing, leading to the formation of fault-filled veins. Metasomatism developed during retrograde metamorphism. The metasedimentary sequences are characterized by the presence of evaporitic minerals such as gypsum and anhydrite, and scapolite. Evaporites are essential as they provide calcium and permit the mobilization of all the chemical elements for tsavorite formation. The H₂S–S₈ metamorphic fluids characterized in primary fluid inclusions of tsavorites and the δ¹¹B values of coeval dravite confirm the evaporitic origin of the fluids. The V₂O₃ and Cr₂O₃ contents of tsavorite range respectively from 0.05 to 7.5 wt.%, while their δ¹⁸O values are in the range of 9.5–21.1‰. The genetic model proposed for tsavorite is metamorphic, based on chemical reactions developed between an initial assemblage composed of gypsum and anhydrite, carbonates and organic matter deposited in a sabkha-like sedimentary basin.     

Sedimentology of the Cretaceous Maha Sarakham evaporites in the Khorat Plateau of northeastern Thailand

Evaporites of the Cretaceous to early Tertiary Maha Sarakham Formation on the Khorat Plateau of southeast Asia (Thailand and Laos) are composed of three depositional members that each include evaporitic successions, each overlain by non-marine clastic red beds, and are present in both the Khorat and the Sakon Nakhon sub-basins. These two basins are presently separated by the northwest-trending Phu Phan anticline. The thickness of the formation averages 250 m but is up to 1.1 km thick in some areas. In both basins it thickens towards the basin centre suggesting differential basin subsidence preceding or during sedimentation. The stratigraphy, lithological character and mineralogy of the evaporites and clastics are identical in both basins suggesting that they were probably connected during deposition. Evaporites include thick successions of halite, anhydrite and a considerable accumulation of potassic minerals (sylvite and carnallite) but contain some tachyhydrite, and minor amounts of borates. During the deposition of halite the basin was subjected to repeated inflow of fresher marine water that resulted in the formation of anhydrite marker beds. Sedimentary facies and textures of both halite and anhydrite suggest deposition in a shallow saline-pan environment. Many halite beds, however, contain a curious `sieve-like' fabric marked by skeletal anhydrite outlines of gypsum precursor crystals and are the product of early diagenetic replacement by halite of primary shallow-water gypsum. The δ³⁴S isotopic values obtained from different types of anhydrite interbedded with halite range from 14.3‰ to 17.0‰ (CDT), suggesting a marine origin for this sulphate. Bromine concentration in the halite of the Lower Member begins around 70 ppm and systematically increases upward to 400 ppm below the potash-rich zone, also suggesting evaporation of largely marine waters. In the Middle Member the initial concentration of bromine in halite is 200 ppm, rising to 450 ppm in the upper part of this member. The bromine concentration in the Upper Member exhibits uniform upward increase and ranges from 200 to 300 ppm. The presence of tachyhydrite in association with the potassic salts was probably the result of: (1) the large volumes of halite replacement of gypsum, on a bed by bed basis, releasing calcium back into the restricted waters of the basin; and (2) early hydrothermal input of calcium chloride-rich waters. The borates associated with potash-rich beds likely resulted from erosion and influx of water from surrounding granitic terrains; however, hydrothermal influx is also possible. Interbedded with the evaporites are non-marine red beds that are also evaporative, with displacive anhydrite nodules and beds and considerable amounts of displacive halite. The δ³⁴S isotopic values of this anhydrite have non-marine values, ranging from 6.4‰ to 10.9‰ (CDT). These data indicate that the Khorat and Sakhon Nakhon basins underwent periods of marine influx due to relative world sea-level rise but were sporadically isolated from the world ocean.     

Palaeogeographic and burial controls on anhydrite genesis: the Badenian basin in the Carpathian Foredeep (southern Poland, western Ukraine)

The Badenian (Middle Miocene) Ca-sulphate deposits of the fore-Carpathian basin – including the shelf and adjacent salt depocentre – have undergone varying degrees of diagenetic change: they are preserved mainly as primary gypsum in the peripheral part of the platform, whereas toward the centre of the basin, where great subsidence occurred during the Miocene, they have been totally transformed into anhydrite. The facies variation and sequence of Badenian anhydrites reflect different genetic patterns of two members of the Ca-sulphate formation. In the lower member (restricted to the platform), anhydrite formed mainly by synsedimentary anhydritization (via nodule formation), whereas in the upper member (distributed throughout the platform and depocentre) the various gypsum/anhydrite lithofacies display a continuum of distinctive anhydrite type-fabrics. These fabrics are based on petrographic features and show from the centre to the margin: (1) syndepositional, interstitial growth of displacive anhydrite; (2) early diagenetic, displacive to replacive (by replacement of former gypsum) anhydrite formation near the depositional surface; (3) early diagenetic, displacive to replacive anhydrite formation during shallow burial; and (4) late-diagenetic (and only partial) replacement of gypsum at deeper burial. The cross-shelf lateral relations of anhydrite lithofacies and fabrics suggest that the diagenesis developed as a diachronous process. These fabrics of the upper member reflect both palaeogeographic (linked to different parts of the basin) and burial controls. Anhydrite growth started very early in the basin centre, presumably related to high-salinity pore fluids; anhydritization prograded updip toward the shelf (landward in a generalized cross-section through the basin). The intensity of gypsum replacement by anhydrite was progressively attenuated landward by a decrease in the salinity of the pore fluids. In each part of the basin, the anhydrite fabric was also controlled by the texture and degree of lithification of the fine-grained primary gypsum lithofacies. Recrystallization of these anhydrite fabrics during late diagenesis, linked to deeper burial conditions, is insignificant, allowing reconstruction of the original anhydritization pattern.     

Hydrogeological characterization of a carbonate aquifer using geophysical and geochemical approach: case of the Krachoua Formation in Tataouine area,Southern Tunisia

An integrated hydrogeological investigation involving geological surface data, well data (lithostratigraphical and piezometric data) and the vertical electrical sounding (VES) method was carried out in Tataouine area, Southern Tunisia to characterize the hydrogeology and the geochemistry of the Krachoua Formation aquifer. The electrical data were used to differentiate lithostratigraphic units and characterize their hydrogeological potentialities. Major elements contents within groundwater samples were assessed and some plots and diagrams have been established in order to investigate the hydrochemical properties of this aquifer and the origin of its mineralization. The Krachoua aquifer exhibits a general drawdown of the piezometric level from 2004 to 2015 reflecting a dramatic decrease in groundwater resources due to increased groundwater abstraction during the last decades. Flow directions shows that the recharge of this aquifer considered as a free aquifer is directly ensured by rainfalls over the outcropping fractured limestones. The geometry of the Krachoua Formation aquifer is tectonically controlled and structured in horst and graben features that impacted greatly the hydrogeology and the hydrodynamics of the area. Subsequent thickness and facies variations within this aquifer influenced the reservoir quality and the groundwater flows. The increased values of salinity to the northwest of the study area seems to be mainly related to the dissolution of the Upper Liassic gypsum of Mestaoua Formation which outcrops widely and can be dissolute easily by meteoric water and contaminate the Krachoua aquifer. This fact is also supported by the sulfated and calci-magnesian chloride facies of this aquifer related to the dissolution of evaporitic rocks (gypsum, anhydrite, and halite). However low salinity values are recorded within the zone where these evaporitic rocks are relatively deep.     

Gypsum–anhydrites in 1.9 Ga Vempalle Formation,Cuddapah basin,India: A note on the Palaeoproterozoic environment and diagenetic condition

The Cuddapah basin consists of generally well-preserved Palaeoproterozoic–Neoproterozoic sedimentary and associated volcanic rocks. The detailed lithological studies of sedimentary rocks of Vempalle Formation from the narrow linear belt of 15 km, in the southern margin, show the occurrence of layered gypsum in the cherty dolostone–shale intercalated facies, red shale and phosphatic dolostone facies of the Vempalle Formation. The petromineralogical studies reveal that gypsum is in close association with anhydrites. Microscopically, three different types of gypsum and anhydrite are identified, viz., lath-shaped, equant-shaped and anhedral-shaped grains. The equant variety corresponds to a granular gypsum, whereas the anhedral grains of gypsum exist as the granular and fibrous variety as seen in the hand specimen. The presence of gypsum/anhydrite has been confirmed by the petromineralogical, X-ray diffraction and chemical analytical data. The phosphatic dolostone is the host rock for stratabound type of uranium deposit at Tummalapalle, Cuddapah district, Andhra Pradesh, which is one of the most unique types of uranium mineralisation in the world. Abundant pseudomorphs of gypsum and anhydrite relicts and discontinuous gypsum layers within these dolostones, nodules of chert and gypsum indicate the interrelationship between the diagenesis and genesis of uranium mineralisation which indicates the carbonate precipitation in the sulphate-rich hypersaline environments.     

Evolution of karst in Messinian gypsum (Monferrato,Northern Italy)

In the Tertiary Basin of Piedmont (Northern Italy) a 100-150 m thick Messinian sedimentary succession crops out, composed of pre-evaporitic clays, gypsum beds and post-evaporitic lacustrine-marine fine-grained sediments. In the Monferrato area the thickness of the evaporite sequence is highly variable (0-140 m) due to an important erosion surface formed at the end of the evaporite cycle and carved in the gypsum beds. Epigenic caves probably formed during this short intra-Messinian phase of emersion. Cave sediments contain benthonic and planctonic foraminiferal associations ranging in age from Burdigalian to Upper Pliocene. These sediments have probably been deposited in recent times, although it cannot be completely ruled out that they accumulated in caves developed in Upper Messinian times. The formation of the most important caves of this area probably started at the end of the Messinian under epigenic conditions. Possibly, those inherited caves enlarged slowly during the Quaternary in an intrastratal and confined hypogene karst system.