Post-eruptive volcanic dome evolution as revealed by deformation and microgravity observations at Usu volcano (Hokkaido, Japan)

Usu volcano (Hokkaido, Japan) is a dacitic volcano, known for its high production rate of lava domes and crypto-domes. It is thus a good target to study processes of volcanic dome evolution (upheaval and/or relaxation). We carried out repeated GPS and microgravity surveys on the three most recent domes of Mt. Usu (1910: Meiji Shinzan; 1943–1945: Showa-Shinzan and 1977–1982: Usu-Shinzan). The repeat period was 1 to 2 months and extended from October 1996 to June 1997. We also compare new data with results from former studies. More than 20 years after the start of Usu-Shinzan dome growth, there is still subsidence at a maximum rate of about 7 to 8 cm/year. The reasons for this subsidence are discussed. Repeated gravity surveys revealed an increase of gravity on the domes (about 60±10 microgal/year for Usu-Shinzan, about 15 microgal at Showa-Shinzan and 10 to 20 microgal for Meiji-shinzan); this gravity increase exceeds that expected due to subsidence. We discuss and interpret the excess gravity change in terms of a density increase in the edifice, caused by a combination of processes (contraction of the edifice, water level change, devesiculisation, cooling and magma intrusion). Quantification of these processes at Usu volcano may help to understand the processes of evolution at domes on other volcanoes such as Merapi (Indonesia), Unzen (Japan) or Montserrat (West Indies).     

Isotopic geochemistry of acid thermal waters and volcanic gases from Zaō volcano in Japan

The chemical composition and D/H, and ratios have been determined for the acid hot waters and volcanic gases discharging from Zaō volcano in Japan. The thermal springs in Zaō volcano issue acid sulfate-chloride type waters (Zaō) and acid sulfate type waters (Kamoshika). Gases emitted at Kamoshika fumaroles are rich in CO₂, SO₂ and N₂, exclusive of H₂O. Chloride concentrations and oxygen isotope data indicate that the Zaō thermal waters issue a fluid mixture from an acid thermal reservoir and meteoric waters from shallow aquifers. The waters in the Zaō volcanic system have slight isotopic shifts from the respective local meteoric values. The isotopic evidence indicates that most of the water in the system is meteoric in origin. Sulfates in Zaō acid sulfate-chloride waters with δ³⁴S values of around +15‰, are enriched in ³⁴S compared to Zaō H₂S, while the acid sulfate waters at Kamoshika contain supergene light sulfate (δ³⁴S = + 4‰) derived from volcanic sulfur dioxide from the volcanic exhalations. The sulfur species in Zaō acid waters are lighter in δ³⁴S than those of other volcanic areas, reflecting the difference in total pressure.     

Coseismic changes in the chemical composition of volcanic gases from the Owakudani geothermal area on Hakone volcano,Japan

The chemical and isotopic compositions of volcanic gases at a borehole and a natural fumarole in the Owakudani geothermal area, Hakone volcano, Japan, have been repeatedly measured since 2001, when a seismic swarm occurred in the area. The CO₂/H₂O and CO₂/H₂S ratios were high in 2001. It increased in 2006 and again in 2008 when seismic swarms occurred beneath the geothermal area. The observed increases suggest the injection of CO₂- and SO₂-rich magmatic gas into the underlying hydrothermal reservoir, implying that the magmatic gas was episodically supplied to the hydrothermal system in 2006 and 2008. The earthquake swarms probably resulted from the injection of gas through the shallow crust accompanying the break of the sealing zone.     

Continuous chemical monitoring of volcanic gas in Izu-Oshima volcano, Japan

A new continuous monitoring system has been developed for the measurement of volcanic gas from the steam well located 3 km north from the summit of Izu-Oshima volcano, Japan. After removing the water vapor using three sequential dehydration methods, CO₂ and SO₂ contents are measured using IR sensors, and O₂ and H₂ using a zirconia sensor and a semiconductor sensor, respectively. This system has been in operation without any significant trouble for 3 years.The dehydrated volcanic gas from the well consists of a mixture of CO₂, O₂ and N₂. A decreasing trend of the CO₂ content was observed from 1995 to 1998 together with a decrease of volcanic activity. Seasonal changes have also been observed in CO₂ and O₂ contents, CO₂ being higher and O₂ lower in summer, which suggests larger contribution of magmatic components in summer. While changes in short-term variation in CO₂ and O₂ are influenced by atmospheric pressure changes; the CO₂ content correlates inversely with atmospheric pressure unlike O₂ with some hours delay. In contrast, the H₂ content increased intermittently up to 1200 ppm one to several hours after a sudden drop in the atmospheric pressure and without any apparent correlation with seasonal changes.This system allows us to study temporal variation in chemical composition of volcanic gas during quiescent periods of volcanic activity of Izu-Oshima volcano, and might help us detect anomalous changes before future eruptive events.     

Reconstruction of the eruptive history of Usu volcano,Hokkaido, Japan,inferred from petrological correlation between tephras and dome lavas

Usu volcano has erupted nine times since 1663. Most eruptive events started with an explosive eruption, which was followed by the formation of lava domes. However, the ages of several summit lava domes and craters remain uncertain. The petrological features of tephra deposits erupted from 1663 to 1853 are known to change systematically. In this study, we correlated lavas with tephras under the assumption that lava and tephra samples from the same event would have similar petrological features. Although the initial explosive eruption in 1663 was not accompanied by lava effusion, lava dome or cryptodome formation was associated with subsequent explosive eruptions. We inferred the location of the vent associated with each event from the location of the associated lava dome and the pyroclastic flow deposit distribution and found that the position of the active vent within the summit caldera differed for each eruption from the late 17th through the 19th century. Moreover, we identified a previously unrecognized lava dome produced by a late 17th century eruption; this dome was largely destroyed by an explosive eruption in 1822 and was replaced by a new lava dome during a later stage of the 1822 event at nearly the same place as the destroyed dome. This new interpretation of the sequence of events is consistent with historical sketches and documents. Our results show that petrological correlation, together with geological evidence, is useful not only for reconstructing volcanic eruption sequences but also for gaining insight into future potential disasters.     

Sr isotope diversity of hot spring and volcanic lake waters from Zao volcano,Japan

The ratio of ⁸⁷Sr/⁸⁶Sr was measured from different water samples of thermal/mineral (hot spring as well as crater lake) and meteoric origins, in order to specify the location and to verify the detailed model of a volcano-hydrothermal system beneath Zao volcano. The ratio showed a trimodal distribution for the case of thermal/mineral water: 0.7052–0.7053 (Type A, Zao hot spring), 0.7039–0.7043 (Type B, Okama crater lake and Shin-funkiko hot spring), and 0.7070–0.7073 (Type C, Gaga, Aone, and Togatta hot springs), respectively. However, in comparison, the ratio was found to be higher for meteoric waters (0.7077–0.7079). The water from the central volcanic edifice (Type B) was found to be similar to that of nearby volcanic rocks in their Sr isotopic ratio. This indicates that the Sr in water was derived from shallow volcanic rocks. The ⁸⁷Sr/⁸⁶Sr ratio for water from the Zao hot spring (Type A) was intermediate between those of the pre-Tertiary granitic and the Quaternary volcanic rocks, thus suggesting that the water had reacted with both volcanic and granitic rocks. The location of the vapor–liquid separation was determined as the boundary of the pre-Tertiary granitic and the Quaternary volcanic rocks by comparing the results of this strontium isotopic study with those of Kiyosu and Kurahashi [Kiyosu, Y., Kurahashi, M., 1984. Isotopic geochemistry of acid thermal waters and volcanic gases from Zao volcano in Japan. J. Volcanol. Geotherm. Res. 21, 313–331.].     

Halogen acids in fumarolic gases of Kilauea volcano

The water-rich condensates of fumarolic gases, obtained from degassing lavas of the 1959–60 eruption of Kilauea volcano, contain unexpectedly high concentrations of hydrofluoric and hydrochloric acids, and thereby suggest that halogens are significant constituents of basaltic magmas. Vents on the pumice hill of Kilauea Iki yielded one sample that contained, in parts per million, 21,000 HF (1.1 N) with 2,920 HCl, and another sample, 20 HF with 70,500 HCl (2.0 N). Samples from vents elsewhere on the volcano had from one-fortieth to one-thousandth as much of the two acids. A rough correlation exists between the temperature of the fumaroles (range 110 to 820°C) and the total concentration of the halogen acids. This correlation is mainly due to progressive dilution of the magmatic halogen acids by water of probable meteoric origin in fumaroles of lower temperatures. Variations in the HF/HCl ratio (range 0.0003 to 7.2) may be explained by means of two different processes whose relative importance cannot be assessed with the data at hand (1). In their migration to the surface, the acid gases may have reacted with the lava to a variable extent owing to the widely different configurations of the several vents (steaming areas in glassy pumice, glowing cracks, and drillhole in lava lake). In the reaction, relatively more HF could have reacted at temperatures around 300°C with the glassy pumice (2). There is some indication that the HF/HCl ratio increases with time,suggesting that the crystallizing lava may have released HCl early, with HF concentrated in the later exhalations. The Br/Cl ratio ranges from 0.0036 down to 0.0014, as compared to 0.0034 of seawater.     

Erosion rates of waterfalls in post‐volcanic fluvial systems around Aso volcano,southwestern Japan

Estimation of the recession rate of waterfalls is a crucial issue in bedrock river erosion because waterfall recession can cause a major impact on bedrock incision, especially when waterfall recession rates are high. Areas of active volcanoes are often characterized by many waterfalls in the volcanic edifice. This study examines recession rates of waterfalls in welded Aso‐1 ignimbrite from the Aso volcano in southwestern Japan using an empirical equation, which comprises a force/resistance index composed of measurable geomorphic parameters. The estimated recession rates are on the order of 0·01–0·07 m a^?1. The estimated rates are then validated by examining the duration and distance of their recession. The duration of waterfall recession is derived from eruptive ages of the Aso ignimbrites, giving waterfall recession distances of approximately 10 km. Although the original locations of the waterfalls suggested by the recession distances exceed the downstream limit of the present Aso‐1 ignimbrite remnants along valley floors, features of the surrounding topography are consistent with these localities being where the waterfalls formed. The use of an equation to estimate recession rates is therefore considered to be valid and practical. The contrast between the highly dissected landforms downstream of the present waterfalls and the gentle landscapes upstream of the waterfalls suggests that the rapid recession of the waterfalls is the major cause of post‐eruptive fluvial erosion into ignimbrites. Copyright © 2007 John Wiley & Sons, Ltd.     

五大连池火山与灾害预测

讨论了有关五大连池火山的构造背景，区域构造特征，历史和现代火山活动以及火山灾害及其预报和防治等等。     

Geochemistry of volcanic and hydrothermal gases of Mutnovsky volcano,Kamchatka: evidence for mantle,slab and atmosphere contributions to fluids of a typical arc volcano

We report chemical compositions (major and trace components including light hydrocarbons), hydrogen, oxygen, helium and nitrogen isotope ratios of volcanic and geothermal fluids of Mutnovsky volcano, Kamchatka. Several aspects of the geochemistry of fluids are discussed: chemical equilibria, mixing of fluids from different sources, evaluation of the parent magmatic gas composition and contributions to magmatic vapors of fluids from different reservoirs of the Kamchatkan subduction zone. Among reactive species, hydrogen and carbon monoxide in volcanic vapors are chemically equilibrated at temperatures >300°C with the SO₂-H₂S redox-pair. A metastable equilibrium between saturated and unsaturated light hydrocarbons is attained at close to discharge temperatures. Methane is disequilibrated. Three different sources of fluids from three fumarolic fields in the Mutnovsky craters can be distinguished: (1) magmatic gas from a large convecting magma body discharging through Active Funnel, a young crater with the hottest fumaroles (up to 620°C) contributing ~80% to the total volcanic gas output; (2) volcanic fluid from a separate shallow magma body beneath the Bottom Field of the main crater (96–280°C fumaroles); and (3) hydrothermal fluid with a high relative and absolute concentrations of CH₄ from the Upper Field in the main crater (96–285°C fumaroles). The composition of the parent magmatic gas is estimated using water isotopes and correlations between He and other components in the Active Funnel gases. The He-Ar-N₂ systematics of volcanic and hydrothermal fluids of Mutnovsky are consistent with a large slab-derived sedimentary nitrogen input for the nitrogen inventory, and we calculate that only ~1% of the magmatic N₂ has a mantle origin and <<1% is derived from the arc crust.     

Fumarolic gases at Mombacho volcano (Nicaragua): presence of magmatic gas species and implications for volcanic surveillance

Mombacho is a deeply dissected volcano belonging to the Quaternary volcanic chain of Nicaragua. The southern, historic collapse crater (El Crater) currently hosts a fumarolic field with a maximum temperature of 121°C. Chemical and isotopic data from five gas-sampling field campaigns carried out in 2002, 2003 and 2005 highlight the presence of high-temperature gas components (e.g. SO₂, HCl and HF), which indicate a significant contribution of juvenile magmatic fluids to the hydrothermal system feeding the gas discharges. This is strongly supported by the mantle-derived helium and carbon isotopic signatures, although the latter is partly masked by either a sedimentary subduction-related or a shallow carbonate component. The observed chemical and isotopic composition of the Mombacho fluids seems to indicate that this volcanic system, although it has not experienced eruptive events during the last centuries, can be considered active and possibly dangerous, in agreement with the geophysical data recorded in the region. Systematic geochemical monitoring of the fumarolic gas discharges, coupled with a seismic and ground deformation network, is highly recommended in order to monitor a possible new eruptive phase.     

Cone-building block-and-ash flows: the Senyama volcanic products of O’e Takayama volcano,SW Japan

The Senyama volcanic products of the late Pliocene to early Pleistocene O’e Takayama volcano overlie a 100-m-thick, late Pliocene coastal quartz-sandstone and are intruded by an early Pleistocene dacite dome. The Senyama volcanic products are the remains of a cone that retains a basal part 1.5 km across and 150–250 m high from the substrate. The cone comprises dacite block-and-ash flow deposits and minor base-surge deposits occur at the base. Single beds of the block-and-ash flow deposits are 1–16 m thick and dip inward 20–40° at the base of the cone and inward or outward 10–20° at the summit. Juvenile fragments in the block-and-ash flow deposits are non- to poorly vesicular and commonly have curviplanar surfaces and prismatic joints extending inward from the surfaces, which imply quenching and brittle fracturing of dacite lava. They are variably hydrothermally altered. Nevertheless, juvenile blocks appear to retain a uniform direction of the magnetization vector residual during thermal demagnetization between 280°C and 625°C. At the time of the eruption, the well-sorted sand of the substrate was at the coast and a good aquifer that facilitated explosive interaction of water and the ascending dacite lava. The mechanism of the explosion perhaps involved thermal contraction cracking of the dacite lava, water-inflow into the interior of the lava, and explosive expansion of the water. Initial phreatomagmatic explosions opened the vent. Succeeding phreatomagmatic or phreatomagmatic–vulcanian explosions produced block-and-ash flow deposits around the vent. Hydrothermal silver-ore deposits and manganese-oxide deposits occur in the Senyama volcanic products and the underlying sandstone, respectively. They could represent post-eruptive activity of the hydrothermal system developed in and around the cone.     

Chemical variations of magmas at Izu-Oshima volcano,Japan: plagioclase-controlled and differentiated magmas

Systematic analyses of the major-element chemistry of products of several eruptions during syn-and post-caldera stages of Izu-Oshima volcano were compiled. Comparisons of the products of large-scale eruptions in 1338?, 1421? and 1777–1778, of intermediate-scale eruptions in 1950–1951 and 1986, and of small-scale eruptions in 1954, 1964 and 1974 clearly show the existence of two types of magmas. One is “plagioclase-controlled” and the other is “differentiated” magma (multimineral-controlled); i.e. the bulk chemistry of the first magma type is controlled by plagioclase addition or removal, while that of the second type is controlled by fractionation of plagioclase, orthopyroxene, clinopyroxene, and titanomagnetite. Eruptions of Izu-Oshima volcano have occurred at the summit and along the flanks. Summit eruptions tap only plagioclase-controlled magmas, while flank eruptions supply both magma types. It is considered unlikely that both magma types would coexist in the same magma chamber based on the petrology. In the case of the 1986 eruption, the flank magma was isolated sometime in the past from the summit magma chamber or central conduit, and formed small magma pockets, where further differentiation occurred due to relatively rapid cooling. In a period of quiescence prior to the 1986 eruption, new magma was supplied to the summit magma chamber, and the summit eruption began. The dike intrusion or fracturing around the small magma pockets triggered the flank eruption of the differentiated magma. This model can be applied to the large-scale flank eruption in 1338(?) which erupted differentiated magmas. In 1421(?), the flank eruption tapped plagioclase-controlled magma. In this case, the isolated magmas from the summit magma chamber directly penetrated the flank without differentiation.